POWDER GLASS GLASS PASTE
AGC Glass Powders for Electronics POWDER GLASS AGC Glass Pastes for Electronics GLASS PASTE Product Catalog Advanced Material Division ASAHI GLASS CO., LTD. AGC Electronics 1-5-1 Marunouchi Chiyoda-Ku, Tokyo 100-8405 Japan URL http://www.agc.com/fritpaste/ November 2014 Product lines The Asahi powder and paste business made their breakthrough in 1956, with the mass production of low-melting and crystalized type glass powder used for CRT sealing. AGC is taking up the challenge of harnessing and integrating our glass, chemistry and ceramics technologies, exploiting our strengths in design and analysis to expand the application of glass as a high-performance electronic material, and moving actively into lead-free glasses. POWDER GLASS GLASS PREFORM GLASS PASTE P.2 POWDER GLASS AGC powder glass is available in a wide range of products variants for use in applications from flat display panels, thick-film circuit boards, and Glass-Ceramic Multilayer Substrate. From the original melt, through grinding, to the final sieving, Asahi Glass's proprietary technology is used under the strictest quality control regime. The track record established over many years has won these products the full confidence of industrial users, particularly in terms of ease of use and fast technical service unrivalled by competitors, and ensures that they fully meet every need. Applications for Powder Glass Sealants Purpose of Seal Items Sealed Glass-Glass Glass-Ceramic Glass-Metal Ceramic-Ceramic Glass-Glass Glass-Ceramic Ceramics Metals Frit seals Binders Coatings Main Applications PDP Fluorescent indicator tubes IC packages thick-film glass paste thick-film metal paste Alumina substrate The following criteria should govern your selection of Powder Glass: ●Thermal expansion coefficient It is normally desirable to apply press to the glass after sealing, so choose a powder glass with a thermal expansion coefficient smaller than that of the materials being sealed by between 0 and 15×10 -7/℃. ●Sealing temperature To form a good seal, the powder glass should properly wet the material being sealed, so raise its temperature above the softening point of the glass. ●Seal atmosphere In Air or nitorgen ●Chemical resistance Powder glass consisting primarily of SiO 2 has excellent acid and water resistance. Powder glass consisting primarily of B2O3-PbO or B2O3-ZnO has slightly lower acid resistance. ●Particle size Particles of powder glass for molds or paints generally pass 100～150 mesh, while those for screen-printing generally pass 250～325 mesh. Various types of particle distribution are available by request. R2O ・ ・ ・ ・ ・ R can be any alkali metal (K, Na or Li) RO ・ ・ ・ ・ ・ RO can be any alkaline earth metal (Mg, Ca, Sr or Ba) Thermal expansion coefficient ・ ・ ・ The average ratio by which the glass expands when heating through 1℃. Transformation point ・ ・ ・ The temperature at which the glass structure changes, with viscosity of approx. 1013.3 poise. (Values are the temperature on the shoulder at the first thermal absorption region on the DTA curve. The exception specified in the list individually.) Softening point ・ ・ ・ The temperature at which glass deforms under its own weight, with a viscosity of about 107.6 poise. (Values are temperature at the peak of the second thermal absorption region on the DTA curve. The exception specified in the list individually.) Crystallization temperature ・ ・ ・ The temperature at which the heat of crystallization of a crystalline glass reaches a maximum while it is being heated. (The peak temperature for thermal dissipation on the DTA curve.) Sealing temperature ・ ・ ・ The temperature suitable for actual operations Average particle size ・ ・ ・ Mean particle diameter. (Permeability method) Particle size (centre value) ・ ・ ・ Median particle diameter. (Laser diffraction method) Sieving size ・ ・ ・ ・ ・ 100 mesh : mesh size of 149μm 150 mesh : mesh size of 105μm 200 mesh : mesh size of 74μm 250 mesh : mesh size of 63μm 325 mesh : mesh size of 44μm P.3 POWDER GLASS Powder Glass for Binder Code ASF1216 ASF1330 ASF1370 ASF1373 ASF1380 ASF1500 ASF1550 ASF102X ASF1094 ASF1096 ASF1098 ASF1099 ASF1100 ASF1100B ASF1109 ASF1317 ASF1560 ASF1561 ASF1620B ASF1700 ASF1702 ASF1717 ASF1780 ASF1891 ASF1891F ASF1898B ASF1930 ASF1939 ASF1941B KF9173 LS-5-300M SK-231-300 Developing Products 1097C2 1991Y10 200GF CB001 JP-1 K-301 K-303 K-304 K-807 K-808 K-834 K-835 K-836 TM-1 TM-5 *1 Transformation point of ＴＭＡ curve. Glass Type PbO・SiO2 PbO・B2O3 PbO・SiO2・B2O3 PbO・SiO2 PbO・SiO2 PbO・SiO2・Al2O3・RO PbO・B2O3・ZnO SiO2・B2O3 Bi2O3・B2O3 Bi2O3・B2O3 Bi2O3・B2O3・ZnO ZnO・Bi2O3・B2O3 Bi2O3・B2O3 Bi2O3・B2O3 Bi2O3・ZnO・B2O3 SiO2・RO SiO2・ZnO・RO SiO2・ZnO・RO ZnO・B2O3・SiO2 SiO2・RO・ZnO RO・SiO2・ZnO SiO2・RO SiO2・B2O3・RO ZnO・B2O3・SiO2 ZnO・B2O3・SiO2 RO・B2O3・ZnO SiO2・TiO2 RO・SiO2・B2O3 RO・SiO2・B2O3 Bi2O3・B2O3 SiO2・RO・R2O Bi2O3・RO・B2O3 SiO2・B2O3・Bi2O3 SiO2・B2O3・R2O SiO2・RO SiO2・RO・Al2O3 PbO・SiO2 SiO2・B2O3・RO SiO2・B2O3・RO SiO2・B2O3・RO SiO2・RO・B2O3 SiO2・RO・B2O3 B2O3・RO・ZnO B2O3・ZnO SiO2・RO・TiO2 SiO2・B2O3・TiO2 SiO2・TiO2 Firing Condition Temp.-Time Thermal Expansion Coeff. （℃－min） 600-10 500-15 650-15 700-15 800-15 850-15 550-15 850-60 550-10 400-15 600-10 600-10 460-30 460-30 580-5 810-10 850-15 850-10 850-15 850-15 950-15 850-10 850-15 800-10 800-10 600-10 800-15 850-15 700-15 500-10 580-20 （×10-7/℃） 63 92 51 84 62 59 47 28 79 120 54 42 113 107 65 55 73 75 55 72 119 35 52 66 63 106 112 88 90 98 106 84 650-10 600-10 750-30 900-10 865-30 490-60 490-60 770-10 800-10 800-10 800-10 69 150 95 90 40 89 129 105 73 68 82 43 94 82 97 *2 Third inflection point on DTA curve CTE Temp range （℃） Specific Gravity 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 50-350 4.3 5.6 3.8 4.0 3.8 3.0 4.7 2.2 5.4 6.7 5.5 4.7 6.3 6.3 5.1 3.1 3.3 3.4 3.7 3.6 3.8 3.3 2.5 3.5 3.5 3.4 2.8 3.7 3.7 6.4 2.9 5.1 50-350 50-350 50-300 50-300 50-600 30-300 30-250 30-250 30-300 30-300 30-300 30-300 30-300 50-500 50-500 5.2 2.8 2.5 3.8 3.5 3.1 2.9 2.9 3.5 3.3 4.0 3.8 4.2 3.7 3.2 Viscosity Property ( DTA ) Transformation Softening Crystallization Point Point Temp. （℃） （℃） （℃） 468 576 380 445 465 615 550 435*1 555 690 693 803 450 540 495 *1 762 466 526 355 405 465 441 535 475 562 380 440 510 382 520 461 537 585 730 670 780 815 640 750 892 570 656 759 680 813 890 679 807 911 677 808 846 538 783 488 587 710 495 589 707 442 526 570 660 805 620 716 591 683 *2 403 459 476 553*2 775 491 557*2 520 404 466 700 637 561 373 444 655 667 516 542 718 606 629 605 524 650 770 829 634＊2 431*2 504*2 738*2 761*2 587*2 613*2 774*2 702 729 900 662 511 613 631 667 840 819 Average Particle （µm） 2.0 2.1 2.7 2.0 2.3 2.0 1.7 1.6 3.1 3.5 4.0 - Particle Property Particle Size Sieving Size （D50） Mesh Pass （µm） 1.7 325 325 1.9 250 6.3 325 4.9 325 3.8 325 1.3 325 1.0 24 0.8 150 1.0 325 3.0 100 3.5 100 5.2 150 1.1 325 2.8 325 1.5 325 2.2 325 3.5 325 4.5 150 325 2.6 325 2.5 325 4.9 325 2.8 325 1.5 325 1.1 200 3.0 100 1.3 325 1.2 325 100 325 12.0 325 5.8 2.0 4.0 3.8 1.0 3.8 9.0 8.0 8.0 5.0 14.0 8.0 12.0 3.0 3.1 2.2 325 100 150 250 100 300 300 300 100 100 300 100 300 100 100 Color After Firing Glass Characteristics Yellow-White Gray White White White White White Yellow Yellow White White Brown-Yellow Yellow Green White White White White Gray White White White White Black White - Vitreous Vitreous Vitreous Vitreous Vitreous Devitrifying Devitrifying Vitreous Vitreous Devitrifying Devitrifying Devitrifying Devitrifying Devitrifying Vitreous Vitreous Devitrifying Devitrifying Devitrifying Devitrifying Devitrifying Devitrifying Vitreous Devitrifying Devitrifying Vitreous Devitrifying Vitreous Vitreous Vitreous Devitrifying Vitreous White White White White White White White White White White White White White Vitreous Vitreous Vitreous Devitrifying Vitreous Devitrifying Devitrifying Vitreous Vitreous Vitreous Devitrifying Devitrifying Devitrifying Devitrifying Devitrifying P.4 POWDER GLASS Powder Glass for Low Temperature sealing Code 7570 7575BF 7583BF ASF1290A4 7574 9079-150 ASF2511C BNL115BB FP-74 KF9173 FP-74 Developing Products 1991Y10 F1290NY01 FP-67 KFI0115 KP312 KP312E LFP-A50Z TNS031W TNS062-ZB Glass Type Firing Condition Temp.-Time PbO・B2O3・Al2O3 PbO・ZnO PbO・ZnO PbO・B2O3 ZnO・B2O3・SiO2 SnO・P2O5 Bi2O3・ZnO Bi2O3・ZnO SnO・P2O5 Bi2O3・B2O3 SnO・P2O5 （℃－min） 500-5 450－60 450－60 430－10 775-30 480-10 470-10 500-10 480-10 520-20 480-10 SiO2・B2O3・R2O PbO・B2O3 SnO・P2O5 Bi2O3・B2O3 SnO・P2O5 SnO・P2O5 SnO・P2O5 V2O5 TeO2・V2O5 600-10 430-10 480-10 470-10 430-10 430-10 460-10 430-10 380-10 Thermal Viscosity Property ( DTA ) Particle Property CTE Glass Specific Transformation Softening Crystallization Average Particle Size Sieving Size Expansion Temp range Character Gravity Coeff. Point Point Temp. Particle （D50） Mesh Pass （℃） istics （×10-7/℃） （℃） （℃） （℃） （µm） （µm） *1 84 30-300 5.4 378 447 100 6.3 Vitreous 89 6.4 320 375 3.7 100 Devitrifying 30-300 84 6.1 325 370 4.2 150 Devitrifying 30-300 105 6.3 332 394 ー 3.9 325 Vitreous 30-300 *1 37 30-500 3.6 567 10.2 100 Devitrifying 647 *1 122 30-250 3.8 13 150 Vitreous 287 344 82 30-300 6.4 351 8 100 Vitreous 400*1 *1 71 30-300 7.3 355 5.0 100 Vitreous 399 30-250 3.4 355 4.6 100 Vitreous 63 275 *1 98 30-300 6.4 403 3.5 100 Vitreous 459 30-250 3.4 355 4.6 100 Vitreous 63 275 150 78 81 105 128 70 45 105 84 50-350 30-300 30-250 30-300 30-250 30-250 30-250 30-250 30-250 2.8 5.6 3.6 7.4 3.8 3.5 3.8 3.9 4.0 404 334 280 350 280 282 270 298 270 525 405 345*1 400*1 325*1 343*1 348*1 362 325 - - 4 3.0 10 5 6 11 1.0 11.0 100 325 150 200 150 150 300 325 Vitreous Vitreous Vitreous Vitreous Vitreous Vitreous Vitreous Vitreous Vitreous Color After Firing Major Application White Black Gray White White Gray Black Black Black Black Seathed heaters Soda-Lime Glass sealing Ceramic sealing Stainless sealing AlN sealing White White Black Yellow Gray Black Black Black Black Metal sealing Soda-Lime Glass sealing Ceramic sealing Ceramic sealing Seathed heaters Ceramic sealing Soda-Lime Glass sealing Stainless sealing Ceramic sealing Non-Alkali Glass sealing *1 Third inflection point on DTA curve y Substrate Powder Glass for Glass-Ceramic Multilayer Code ASF102M ASF102X ASF102Y ASF1700F FF201 Developing Products DL828 FF202 ZX-1 Glass Type Firing Condition Temp.-Time SiO2・B2O3 SiO2・B2O3 SiO2・B2O3 SiO2・RO・ZnO SiO2・B2O3・Al2O3 （℃－min） 850-60 850-60 850-60 850-60 900-60 SiO2・B2O3・R2O SiO2・Al2O3・RO SiO2・Al2O3・RO 900-60 900-60 900-60 Thermal Viscosity Property ( DTA ) Electrical Property CTE Specific Transformation Softening Crystallization Dielectric Dielectric Expansion Measuring Temp range Gravity Coeff. Point Point Temp. Constant Loss Condition （℃） -4 （×10-7/℃） （℃） （℃） （℃） ε tanδ（X10 ） 28 50-350 2.2 495 *1 790 4.0 1MHｚ 25℃ 28 50-350 2.2 495 *1 762 4.0 1MHｚ 25℃ 28 50-350 2.2 495 *1 775 4.0 1MHｚ 25℃ 72 25-300 3.6 671 810 923 9.0 1MHｚ 25℃ 50 40-750 2.6 720 840 1040 6.0 1MHｚ 25℃ 35 89 75 25-300 30-300 25-300 2.3 3.5 2.9 712 750 861 801*2 875 961 959 4.2 6.6 6 1MHｚ 25℃ 16GHｚ 25℃ Average Particle （µm） - Particle Property Particle Size Sieving Size （D50） Mesh Pass （µm） 3.3 24 1.0 24 1.3 24 1.8 200 17 100 1.0 4.7 2.5 - Major Application Glass Characteristi cs Multilayer Substrate Multilayer Substrate Multilayer Substrate Multilayer Substrate Multilayer Substrate Vitreous Vitreous Vitreous Devitrifying Devitrifying Low ε Low ε Low ε Multilayer Substrate Multilayer Substrate Multilayer Substrate Vitreous Devitrifying Devitrifying Low ε High CTE Low tan δ Feature Low ε *1 Transformation point of ＴＭＡ curve. *2 Third inflection point on DTA curve P.5 GLASS PASTE AGC glass pastes consist of powder glass and the vehicle. They are widely used in the electronics industry for applications requiring extremely high precision and reliability, such as thick-film hybrid ICs, thermal print heads, etc., in which they have an excellent track record. Long years of experience and advanced technical know-how, from the design of recipes for the ingredients, through the melting and grinding to the mixing of the paste, and the strictest quality control regime, are the secrets of our integrated production system. Our continuous ongoing policy of improvement ensures that our pastes secure the widest possible use throughout the electronics industry, with improving ease of use and other distinctive features. Be sure to remember the following considerations when using Asahi Dielectric Glass Pastes: ●Storage locations Avoid direct exposure to sunlight and store in a cool, well-ventilated place. Please use within six months of receipt. Please ask the sales person about expiry date of each pastes. ●Adjusting viscosity Pastes have been prepared for use without further adjustment but, if necessary, recommended thinner can be used to adjust their viscosity. ●Mixing Mix thoroughly before use, taking particular care not to cause air bubbles. ●Application Pastes should be applied in a well-ventilated area. Take particular care not to continue breathing the vapor for any considerable length of time, and do not allow the paste to remain in contact with the skin. P.6 GLASS PASTE AGC Overcoat Glass Paste for Hybrid IC Code Glass Type SiO2・B2O3・PbO AP5346 B2O3・ZnO・PbO AP5550 B2O3・ZnO・PbO AP5551 SiO2・PbO AP5840N Developing Products SiO2・ZnO・Bi2O3 5033NF1 SiO2・B2O3・R2O 5102Y SiO2・B2O3・Bi2O3 AP5094D SiO2・B2O3・ZnO YPT525 Bi2O3・B2O3・ZnO YPT531E Firing Condition Temp.-Time （℃－min） 510-5 550-5 550-5 550-5 Viscosity Property ( DTA ) Electrical Property Thermal Expansion Specific Transformation Softening Crystallization Insulation Breakdown Gravity Coeff. Point Point Temp. Resistance Voltage ε （×10-7/℃） （℃） （℃） （℃） （Ω） （Ｖ） 10 >500 8～12 73 400 490 >10 47 455 540 >500 7～12 >1010 10 47 455 540 >500 7～12 >10 61 2.2 460 560 - 580-10 850-60 520-10 580-30 590-30 90 28 85 72 77 - 450 450 470 500 565 775 510 580 590 600 - - - 5～7 11～13 tanδ （％） <0.5 <0.5 <0.5 - Paste Viscosity Surface Roughness Particle Property Glass Average Particle Size Ra Rz η10 Viscosity Characteristics ratio Particle （D50） （µm） （µm） （Pa・s） η10/η50 （μm） （μm） 170 2.0 1.2 － Vitreous 150 2.1 2.0 － Devitrifying 150 2.1 2.0 － Devitrifying 80 1.4 2.0 － Vitreous 100 100 110 100 100 1.4 - - - - 1.9 1.3 0.7 2.5 2.5 Devitrifying Vitreous Vitreous Vitreous Vitreous Color Paste Green White Green Green Fired Glass Green White Green Green Black White Yellow White White Black Clear Yellow Clear Clear AGC Dielectric Crossover Paste for Hybrid IC Code AP5576VE AP5577 AP5578 AP5700C AP5701C AGC Dielectric Code AP5761D AP5762D AP5762-10 Viscosity Property ( DTA ) Electrical Property Thermal Expansion Specific Transformation Softening Crystallization Insulation Breakdown Gravity Coeff. Point Point Temp. Resistance Voltage ε （℃－min） （×10-7/℃） （℃） （℃） （℃） （Ω） （Ｖ） SiO2・ZnO・RO 850-10 53 670 785 830 ＞1000 9～14 >1012 SiO2・ZnO・RO 850-10 53 1.9 670 785 830 ＞1000 10～16 >1012 12 SiO2・ZnO・RO 850-10 53 1.9 670 785 830 ＞1000 12～17 >10 SiO2・ZnO・RO 850-10 72 680 815 890 ＞1000 9～14 >1012 SiO2・ZnO・RO 850-10 72 680 815 890 ＞1000 9～14 >1012 Paste for Alumina Substrate Glazing of Print Head ●By controlling crystalline Viscosity Property ( DTA ) Electrical Property Firing Condition Thermal Temp.-Time Expansion Specific Transformation Softening Crystallization Insulation Breakdown Glass Type Gravity Coeff. Point Point Temp. Resistance Voltage ε （℃－min） （×10-7/℃） （℃） （℃） （℃） （Ω） （Ｖ） SiO2・B2O3・RO 1275-60 69 710 870 SiO2・RO 1270-30 65 765 925 SiO2・RO 1200-60 65 1.8 765 925 Glass Type Firing Condition Temp.-Time Paste Viscosity Surface Roughness Particle Property Color Glass Average Particle Size η10 Ra Rz Viscosity Characteristics ratio tanδ Particle （D50） Paste Fired （％） （µm） （µm） Glass （Pa・s） η10/η50 （μm） （μm） ＜0.2 190 2.4 1.6 － Devitrifying Orange White ＜0.3 190 1.7 1.6 － Devitrifying Blue Blue 190 1.8 1.6 － Devitrifying Black Black ＜0.2 200 2.3 1.6 Partially Orange White ＜0.2 200 2.3 1.6 Partially Blue Blue refraction, a smooth-surface glaze can be formed, (AP5761D, AP5762D) Paste Viscosity Surface Roughness Color Particle Property Glass Average Particle Size η10 Ra Rz Viscosity Characteristics Paste ratio tanδ Particle （D50） Fired （％） （µm） （µm） Glass （Pa・s） η10/η50 （μm） （μm） 160 2.2 5.2 Vitreous Orange Clear 160 1.9 5.0 Vitreous Blue Clear 150 1.7 5.0 Vitreous Black Black AGC Overcoat Glass Paste for Print Head Code AP5349 AP5352B AP5564G AP5565H AP5568 AP5316A AP5317*3 AP5717*3 Developing Products 5315HT101-A5 THN24 Glass Type Firing Condition Temp.-Time PbO・B2O3・SiO2 PbO・B2O3・SiO2 SiO2・B2O3・PbO SiO2・PbO SiO2・PbO SiO2・B2O3・RO SiO2・B2O3・RO SiO2・ZnO・RO （℃－min） 810-10 810-10 830-10 830-10 830-10 810-10 850-10 850-10 SiO2・B2O3・RO SiO2・B2O3・RO 780-10 830-10 Viscosity Property ( DTA ) Electrical Property Thermal Expansion Specific Transformation Softening Crystallization Insulation Breakdown Gravity Coeff. Point Point Temp. Resistance Voltage ε （×10-7/℃） （℃） （℃） （℃） （Ω） （Ｖ） 62 460 ＞1500 63 455 51 565 *1 670 58 623 *1 678 *2 59 555 55 2.3 580 720 ＞1500 45 2.0 580 750 35 2.2 675 800 830 68 60 1.9 2.0 625 630 780 760 - - ＞1500 ＞1500 - tanδ （％） - Surface Roughness Paste Viscosity η10 Ra Rz Viscosity ratio （Pa・s） η10/η50 （μm） （μm） 105 2.7 ＜0.8 110 2.4 ＜0.1 100 2.6 ＜0.3 130 3.1 ＜0.3 90 2.5 ＜0.3 85 1.6 ＜1.5 90 1.8 ＜0.8 150 1.3 100 100 - ＜0.8 ＜0.3 Particle Property Color Glass Average Particle Size Characteristics Particle （D50） Paste Fired （µm） （µm） Glass 1.5 Vitreous Gray Brown 1.5 Vitreous Black Black 0.8 0.9 Vitreous Orange Clear 0.7 Vitreous Blue Clear 0.8 Vitreous White Clear 1.5 Vitreous Gray Gray 1.5 Vitreous Gray Gray 2.5 Devitrifying White White - 2.0 2.0 Vitreous Vitreous Gray Blue Gray Blue ●Outstanding surface flatness, resistance to wear, and heat resistance make them ideal as over coats for various kinds of print heads, including heaters, image sensors and thermal heads. *3 AP5317 and AP5717 are for AIN coat. (AP5317 : Top layer, AP5717 : Bottom layer) AGC Low Tememperature sealing Glass Paste Code Glass Type Firing Condition Temp.-Time （℃－min） Developing Products SiO2・B2O3・PbO 5290E 5115HT1 Bi2O3・ZnO TNS062-Z27-TP12 TeO2・V2O5 430-10 450-10 380-10 Viscosity Property ( DTA ) Electrical Property Thermal Expansion Specific Transformation Softening Crystallization Insulation Breakdown Gravity Coeff. Point Point Temp. Resistance Voltage ε （×10-7/℃） （℃） （℃） （℃） （Ω） （Ｖ） 78 75 80 3.1 3.4 2.2 340 355 270 405 415 325 - - - - tanδ （％） - Paste Viscosity Surface Roughness Particle Property Glass Average Particle Size Ra Rz η10 Viscosity Characteristics ratio Particle （D50） （µm） （µm） （Pa・s） η10/η50 （μm） （μm） 90 100 140 2.5 2.5 2.6 - - - 3.5 - Vitreous Vitreous Vitreous Color Paste Fired Glass White Gray Brown White Black Brown P.7
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