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Preliminary Program, 46th Silicon Symposium at UC Davis Sunday 2:00-‐4:00pm 4:00-‐5:30pm 4:00-‐4:30pm 4:40-‐5:10pm 5:30-‐7:30pm Check-‐in Symposium Welcome and Opening Scientific Session Matthias Driess, Technische Universität Berlin From Divalent Silicon Monocations to Zero-‐valent Neutral Silicon Complexes (“Silylones”) Jillian Buriak, University of Alberta Illuminating the Mechanisms of Silicon Surface Chemistry Opening Reception – sponsored by Gelest (featuring Northern CA wineries and local beer from Davis Sudwerk Brewery) Monday 8:00-‐9:00am 9:00am-‐12:30pm Check-‐in, Coffee & Tea – sponsored by Siltech Scientific Talks, Session 1A Scientific Talks, Session 1B Michael Sailor Martin Oestreich 9:00-‐9:30am In Vivo Imaging and Drug Delivery With Targeted Catalytic Si–H bond activation with Lewis acids Porous Silicon Nanoparticles Monica Trincado Mark Fink Ni Complexes as Catalysts for Reversible 9:40-‐10:00am Vinyl terminated silicon nanoparticles: Silane Dehydrogenation and synthesis, characterization, and reactions Hydrosilylation Reactions Gerardo González-‐García Chen Cheng 13
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Application of Solid-‐state C and Si CP/MAS NMR Catalytic Silylation of Unactivated C-‐H Bonds 10:05-‐10:25am and STEM-‐EDX Spectroscopies to the and Its Application Toward Functionalization Characterization of Silica-‐Collagen Composite of Complex Molecules 10:30-‐11:00am Coffee & Tea – sponsored by Siltech Bogdan Marciniec Sheryl Wiskur Synthesis of difunctionalized double decker Enantioselective Silylation: Substrate Scope 11:00-‐11:30am silsesquioxane and heterosilsesquioxane derivatives via and Mechanistic Investigations TM-‐catalyzed reactions Richard Laine Alexander Zabula Escaping the Tyranny of Carbothermal Reduction. 11:40am-‐12:00pm Pyridoannulated Silylenes and their Conversion of Biowaste Silica to Alkoxysilanes Analogs: structure and reactivity without using Silicon James Lewicki Philip Boudjouk Smart composites. synthesis, characterization and 12:05-‐12:25pm Silicon-‐Based Coordination Polymers as application of well-‐defined, hierarchical silicone/carbon Supramolecular Assembly Templates architectures with novel physical properties 12:30-‐3:00pm Lunch Break and Free Time (Symposium Lunch at Gunrock Pub, registration required) 3:00-‐3:30pm Coffee & Tea before afternoon session – sponsored by Silatronix 3:30-‐5:30pm Scientific Talks, Session 2A Scientific Talks, Session 2B Michinori Suginome Jonathan Veinot 3:30-‐4:00pm Interplay of Silicon and Boron in Catalysis Adventures in Silicon Nanocrystal Surface Chemistry 4:10-‐4:30pm 4:35-‐4:55pm 5:00-‐5:20pm 5:30-‐7pm 7-‐9pm Allegra Liberman-‐Martin Aldehyde Hydrosilylation catalyzed by a neutral bis(perfluorocatecholato)silicon compound Yixuan Yu Silicon Nanocrystal Superlattices Lisa Rosenberg Julia Zaikina Borane-‐catalyzed Derivatization of polysilanes: scope, Mg2Si composites for high temperature limitations, and insights into over-‐reduction chemistry thermoelectric applications Takeru Torigoe Xiaotang Lu Enabling oxidative conversion of RSiMe3 to alkanols by Colloidal Synthesis of luminescent silicon chemoselective C–H borylation at methyl group on Si nanorods Dinner Break Poster Session and Wine Tasting on the SCC Patio Terrace – Sponsored by Wacker (featuring Northern CA boutique wineries and local beer from Davis Sudwerk Brewery) Preliminary Program, 46th Silicon Symposium at UC Davis Tuesday 8:30-‐9:00am 9am-‐12pm Coffee & Tea – sponsored by Wacker Scientific Talks, Session 3A Scientific Talks, Session 3B Keith Woerpel Barry Arkles 9:00-‐9:30am Silylene Transfer Reactions as New Methods Silicone Elastomers with Exceptional Elongation for Stereoselective Synthesis Wei Chen Shintaro Ishida Minimization of Hydrophobic Recovery A stable disilyne having bulky alkyl groups and 9:40-‐10:00am of Commercial Silicone Substrates after its palladium and platinum complexes Oxygen Plasma Treatment Talena Rambarran Kim Baines 10:05-‐10:25am ‘Clickable’ silicones: complimentary silicone The addition of nitro compounds and isonitriles to elastomers for adhesive interfaces tetramesityldisilene 10:30-‐11:00am Coffee & Tea – sponsored by Wacker Andrew Guenthner Reinhold Tacke 11:00-‐11:20am Effect of silicon substitution on packing and Reactivity Studies with Donor-‐Stabilized melting of cyanate ester monomers Bis(amidinato)-‐ and Bis(Guanidinato)silylenes SiSlam2015 (in SCC MPR) 11:30am-‐12:00pm 3-‐minute poster talks to be presented by the finalists for Student/Postdoc Poster Awards Poster awards sponsored by Springer and Chemistry of Materials 12:00-‐3:00pm Lunch Break and Free Time 3-‐3:30pm Coffee & Tea – sponsored by Silatronix 3:30-‐5:30pm Scientific Talks, Session 4A Scientific Talks, Session 4B Kazuyuki Kuroda Michael Brook 3:30-‐4:00pm Role Of Organic And Organosilicon Compounds Hydrosilanes + B(C6F5)3 initiate the group transfer In The Formation Of Silica-‐Based Nanomaterials polymerization of methyl methacrylate Janet Braddock-‐Wilking Masafumi Unno 4:10-‐4:30pm Synthesis and Characterization of Luminescent Synthesis of cyclic silanols with long alkyl chains 2,7-‐Disubstituted silafluorenes Colleen Scott Joseph Mabry 4:35-‐4:55pm Direct arylation polymerization synthesis of a Fluorinated Silsesquioxanes: Structure, Solubility, series of new silole-‐benzazole copolymers and Wetting Rebekka Klausen Harold Kung 5:00-‐5:30pm Molecular silicon for electronics Bifunctional Structures Derived from Silyl Ester Bonds 5:30-‐7pm Dinner Break Poster Session and Wine Tasting on the SCC Patio Terrace – sponsored by Gelest 7-‐9pm (featuring Northern CA boutique wineries and local beer from Davis Sudwerk Brewery) Thank you to the sponsors of the 46th Silicon Symposium! Preliminary Program, 46th Silicon Symposium at UC Davis Wednesday 8:30-‐9:00am 9:00am-‐12:30pm 9:00-‐9:30am 9:40-‐10:00am 10:05-‐10:25am 10:30-‐11:00am 11:00-‐11:30am 11:40am-‐12:00pm 12:05-‐12:25pm 12:30-‐3:00pm 3:00-‐3:30pm 3:30-‐5:30pm 3:30-‐4:00pm 4:10-‐4:30pm 4:35-‐4:55pm 5:00-‐5:20pm 6:00-‐9:00pm Coffee & Tea – sponsored by Siltech Scientific Talks, Session 5A Scientific Talks, Session 5B Don Tilley Thomas Fässler New Bond Activations, Transformations, and Alkali Metal Silicides for Silicon Based Materials Hydrosilylation Catalysis in Transition Metal–
and as Precursors for Silicon-‐rich Molecules Silicon Chemistry Kirill Kovnir Peter Gaspar Synthesis, characterization, and exfoliation of Unsaturated carbene analogs with triplet ground the silicon and germanium monopnictides states: silylenes, germylenes, stannylenes Hongzhi Liu Michael Haas Hybrid Porous Materials Derived from Relatively stable Germenolates based on 1,4-‐
Octavinylsilsesquioxane digermacyclohexasilanes Coffee & Tea – sponsored by Siltech Andrea Goforth Ashes to ashes and dust to dust: size and Ryan Trovitch compositional evolution of silicon nanoparticles The development and application of and their photoluminescence properties over manganese hydrosilylation catalysts time and with environmental changes Fan Sui Jerry Larson, Gelest Influence of YbP nano composite on the Sustainable hydrosilylations: a fixed-‐bed catalyst thermoelectric properties of n type SiGe alloys Robert Ruckle Paul Lickiss Reactive Silicone Homopolymers and Organosilanols as Homogeneous Direct copolymers with Organic Polymers Amide Bond Formation Catalysts Lunch Break and Free Time Coffee & Tea before afternoon session – sponsored by Wacker Scientific Talks, Session 6A Scientific Talks, Session 6B Bob West David Scheschkewitz Silicones: why do they behave like silicones? Low-‐valent Maingroup Compounds with Multiple Functionalities Tom McCarthy Marius Arz PDMS Containing No dimethylsiloxane Chemistry of NHC-‐stabilized Disilicon(0) Paul Zelisko Kirill Zaitsev Chemoenzymatic Syntheses of Compounds of Group 14 Elements with Siloxane-‐oligoester Structures Element-‐element Bonds Alyssa Schneider William Leigh Controlling arylene density in the PDMS Photochemical Generation and Characterization backbone of network structures of Di-‐tert-‐Butylsilylene in Solution. Evening of Food, Wine and Music in Good Life Gardens (registration required) Tours of vineyard, brewery and gardens Thank you to the sponsors of the 46th Silicon Symposium!