Material Safety Data Sheet
WHMIS
Protective Clothing
Section I - Product Identification and Uses
Common/Trade Name ELECTROLYTIC TIN SLUDGE
Synonyms
E-Line Sludge
Chemical Name
Not applicable
Chemical Formula
Not applicable
Chemical Family
Not available
Supplier
ARCELORMITTAL DOFASCO INC.
P.O. BOX 2460
HAMILTON, ON.
CANADA L8N 3J5
(905) 548-7200 EXT. 4051 (By-Product Sales)
Material Uses
Internally generated by-product material.
TDG Road/Rail
MSDS #
9945
Section IA - First Aid Measures
Eye Contact
Immediately flush with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Seek medical attention.
Skin Contact
Immediately wash with soap and water for at least 15 minutes. Seek medical attention if irritation
persists. Launder contaminated clothing before reuse.
Inhalation
Remove person to fresh air. Seek medical attention.
Ingestion
DO NOT induce vomiting. Seek immediate medical attention. Never give anything by mouth to
an unconscious person.
Electrolytic Tin Sludge (MSDS 9945))
Page 2
Section II - Composition and Information on Ingredients
Name
CAS#
% by Weight
1. TIN
7440-31-5
58.8
2. COPPER
7740-50-8
0.1
TLV/PEL
3
TWA: 2 (mg/m ) from Ont.
MOL, ACGIH
ORAL (LD50): Acute: 3.5
mg/kg [Mouse]. 0.12 mg/kg
[Human/30min]
Not available.
Not available.
3
7440-69-9
0.08
4. ARSENIC (ELEMENTAL)
7440-38-2
0-0.02
TWA: 0.01 (mg/m ), STEL:
3
0.05 (mg/m )from Ont. MOL
3
TWA: 0.01 (mg/m ) from
ACGIH
5. CADMIUM
7440-43-9
0.002
6.
N.A.
7732-18-5
7. WATER
Not available.
TWA: 0.2 (mg/m ) from Ont.
MOL, ACGIH
3. BISMUTH
Plating Solution 0.6% ethoxylated
nathpthol sulphonic acid, 1.1%
sulphuric acid, 5% phenol
sulphonic acid and water.
LC50/LD50
3
ORAL (LD50): Acute: 763
mg/kg [Rat]. 145 gm/kg
[Mouse].
TWA: 0.01 (mg/m ) from
Ont. MOL, ACGIH
3
ORAL (LD50): Acute: 225
mg/kg [Rat]. 2330 mg/kg
[Rat]. GAS (LC50): Acute:
5 ppm 4 hours [Rat].
Approx.
10%
Not available
Not available
0-30%
Not available
Oral (LD50) >90 mL/kg
[Rat]
Section III - Toxicological Properties
Routes of entry
Eye contact. Inhalation. Skin contact.
TLV
Permissible exposure limits have not been determined for this product.
Toxicity for animals
LD50: Not available.
LC50: Not available.
CARCINOGENIC EFFECTS: Classified as A4 (Not classifiable for human or animal) by
ACGIH.
Chronic effects on humans
No chronic effects expected.
Acute effects on humans
Inhalation of dust will produce irritation to respiratory tract, characterized by burning,
sneezing and coughing. Moderate irritation to skin or eyes on contact. Prolonged skin or eye
contact may cause chemical burns.
Electrolytic Tin Sludge (MSDS 9945))
Page 3
Section IV - Physical Data
Physical State and Appearance
pH
Odor Threshold
Volatility
Melting/Sublimation Point
Boiling/Condensation Point
Specific Gravity
Vapor Density
Dispersion Properties
Solid (paste or slurry).
< 2 (Acidic).
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
Vapor Pressure
Evaporation Rate
Viscosity
Water/Oil Dist. Coeff.
Critical temperature
Instability temperature
Conditions of instability
Solubility
Odor
Color
Not available.
Not available.
Not available.
Not available.
Not available.
Not available.
No additional remark.
Not available.
Not available.
Brown.
Section V – Fire and Explosion Data
The product is
Does not burn and will not support combustion.
Auto-ignition temperature
Not applicable.
Fire degradation products
Sulfur compounds. Sulfur oxides (SO2, SO3…) Hydrogen gas. Oxides of parent
material.
Flash Points
Not applicable.
Flammable Limits
Not applicable.
Fire Extinguishing Procedures
Use DRY chemicals, CO2, foam. Use SCBA during fire fighting.
Flammability
Non combustible material.
Risks of explosion
Risks of explosion of the product in presence of mechanical impact: Not applicable
Risks of explosion of the product in presence of static discharge: Not applicable.
Section VI – Reactivity Data
Stability
The product is stable.
Hazardous Decomp. Products
Oxides of parent materials. Hydrogen gas. Sulfur compounds and oxides.
Degradability
Not available.
Products of Degradation
Not available.
Corrosivity
No specific information is available in our database regarding the corrosivity of this
product in presence of various materials.
Reactivity
No specific information is available in our database regarding the reactivity of this
material in presence of various other materials.
Electrolytic Tin Sludge (MSDS 9945))
Page 4
Section VII – Preventive Measures
Waste Information
Store waste material for return to reprocessing company. Dispose of in accordance with
local, provincial and federal regulations.
Storage
Keep away from incompatibles such as acids, oxidizers.
Precaution
Keep container dry. DO NOT breathe dust. Avoid contact with skin and eyes. Keep
away from incompatibles such as oxidizing agents, acids.
Small spill and leak
Contain spill. Reclaim spilled material to suitable container. Use appropriate personal
protective equipment during clean-up.
Large spill and leak
Refer to procedures in small spill and leak.
Section VIII – Protective Measures
Protective Clothing
Chemical goggles: Mono-goggle. Neoprene gloves. Use
MSHA/NIOSH approved respiratory protection if mist/dust is
generated.
Engineering Controls
Use general ventilation under normal conditions. Use mechanical ventilation if dust or fume
is generated. Water should be available to flush skin and eyes.
Section IX – Classification
TDG Road/Rail
Maritime Transportation
WHMIS
Federal and Provincial
Regulations
Shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC,
N.O.S. (Phenol Sulphonic Acid)
TDG Pin: UN3264 Class: 8 Packing Group: III
Not available.
WHMIS CLASS E: Corrosive solid.
WHMIS CLASS D1B: Materials causing immediate and serious
toxic effects (Toxic)
CEPA DSL; TIN; ARSENIC (ELEMENTAL)
MOE Provincial Code: 112C
Section X – Other Information
References
Dofasco’s Material Safety Data Sheet
If the use of this material is other than that specified by the supplier, additional precautions may be required.
Effective Date: April 1, 2015
24-HOUR EMERGENCY CONTACT (3E COMPANY): 1-760-476-3962
3E COMPANY CODE: 333211
To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability
whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the
user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are
the only hazards that exist.