Current Projects

 The Field lab is part of the Hydrocarbon and Dispersant Chemistry Team of Ecosystem Impacts
of Oil & Gas Inputs to the Gulf (ECOGIG-II). (http://ecogig.org/hydrocarbon-dispersantchemistry). The laboratory developed methods for the surfactant components of Corexit, the oil
dispersant, used on the 2010 Gulf of Mexico oil spill. The methodology is now being applied to
determine the fate of Corexit surfactant components in microcosms containing microbial
consortia from shallow and deep Gulf water locations, marine sediments, and in marine snow.
Publications:
1. Barsamian, A., Perkins, M, Field, J., and Blakemore, P. 2014. Regioselective Syntheses of
[13C]4-Labelled Sodium 1-Carboxy-2-(2-ethylhexyloxycarbonyl)ethanesulfonate and
Sodium 2-Carboxy-1-(2-ethylhexyloxycarbonyl)ethanesulfonate from [13C]4-Maleic
Anhydride. 2014. Journal of Labelled Compounds and Radiopharmaceuticals, 57, 625625.
2. Place, B., Perkins, M. Sinclair, E., and Field, J.A. 2014. Trace Analysis of Anionic and
Nonionic Surfactants from Oil Dispersants in Gulf of Mexico Seawater Using Large Volume
Injection Liquid Chromatography with Tandem Mass Spectrometry. Special issue in Deep
Sea Research. DOI: 10.1016/j.dsr2.2014.01.015.
3. Place, B., Anderson, B., Mekebri, A., Furlong, E., Gray, J., Tjeerdema, R., Field, J. 2010. A
role for analytical chemistry in advancing our understanding of the occurrence, fate, and
effects of Corexit oil dispersants. Environmental Science and Technology, 44, 6016-6018.
The Field lab will also be working in collaboration with Dr. Mary
Beth Leigh (http://faculty.iab.uaf.edu/mary_beth_leigh), a
microbiologist with the Institute of Arctic Biology at the University
of Alaska, Fairbanks (on a project funded (2015-2017) by the
Coastal Marine Institute titled, “Fate and persistence of oil spill
response chemicals in arctic seawater.“
Collaborators
Drs. David Sedlak and Lisa Alvarez-Cohen, Dept. of Civil Engineering, UC Berkeley
Technical Objectives
It is our goal to fully delineate the fluorochemicals that persist in AFFF-contaminated groundwater,
sediment, and soil at military sites where fire-training activities occurred and to evaluate their impact
on priority pollutant transport and bioremediation.
Publications
1. Barzen-Hansen, K., Field, J.A. In Press. Discovery and implications of C2 and C3
perfluoroalkyl sulfonates in aqueous film forming foams (AFFF) and groundwater.
Environmental Science & Technology Letters, DOI: 10.1021/acs.estlett.5b00049
2. McGuire, M.E., Schaefer, C., Richards, T., Backe, W.J., Field, J.A., Houtz, E., Sedlak, D.S.,
Guelfo, J.L., Wunsch, A., Higgins, C.P. 2014. Evidence of Remediation-Induced Alteration
of Subsurface Poly- and Perfluoroalkyl Substance Distribution at a Former Firefighter
Training Area. Environmental Science & Technology, 48, 6644-6652
3. Houtz, E., Higgins, C., Field, J. and Sedlak, D. 2013. Persistence of perfluoroalkyl acid
precursors in AFFF-impacted groundwater and soil. Environmental Science and
Technology, 47, 9342-9349
4. Backe, W.J., Christensen, K.E., and Field, J.A. 2013. Newly-identified cationic, anionic, and
zwitterionic fluorinated chemicals in groundwater at US military bases by large volume
injection HPLC – MS/MS. Environmental Science and Technology, 47, 5226-5234.
5. Place, B., Field, JA. 2012. Identification of novel fluorochemicals in aqueous film-forming
foams (AFFF) used by the US military. Environmental Science and Technology, 46, 71207127