Name: _____________________________________ Prd: _____ Score: ______ Calculations Involving Phase Changes 1. What does the specific heat tell you about a substance? 2. The specific heat of water is 4.18kJ/g °C. What does this number mean? The specific heat of several liquids are listed in the table to the right. Beakers containing 100mL of each of these liquids were Specific Heat Liquid placed into an oven at the same time. All the (J/g °C) liquids were removed a few minutes later, before Acetone 2.15 any of the liquids started to boil. Water 4.18 Methanol 2.51 Olive Oil 1.97 3. The temperature of the liquids after they were removed from the oven were measured. Rank the liquids from lowest to highest temperature. Lowest Highest Temp ________ ________ ________ ________ Temp a. Explain your reasoning for your rankings above in terms of the specific heat of the liquid. 4. Rank the liquids above from weakest intermolecular forces to strongest. Weakest Strongest IMF ________ ________ ________ ________ IMF a. Explain your reasoning for your rankings above in terms of the specific heat of the liquid. 5. A polar bond forms between atoms that have ( very similar / very different ) electronegativities these atoms share electrons ( evenly / unevenly ) resulting in one atom having a slight ________________ charge and the other atom have a slight ______________ charge. This type of molecule tend to have ( weak / strong ) intermolecular forces. Explain your reasoning below. 6. Rank the liquids above from least polar to most polar. Least Most polar ________ ________ ________ ________ polar 7. Dietrich has 56.0g of methanol and wants to heat it from 23.0°C to a temperature of 65.0°C. How many joules of energy will this require? 8. Laina heats 265g of water over a campfire, heating the water from 20.0°C to 90.0°C. How much heat did the water absorb? 9. If Jordan has 25.5g of olive oil that is at room temperature, 22.0°C. He adds 156kJ of heat to the olive oil. What is the new temperature of the olive oil? Enthalpies of Fusion and Vaporization The table to the right has enthalpy of vaporization and fusion for three substances. Substances Water Methanol Acetone Enthalpy of Vaporization (kJ/mol) 40.7 35.1 31.3 Enthalpy of Fusion (kJ/mol) 6.0 3.1 5.7 10. What does the Enthalpy of Fusion tell you? 11. What does the Enthalpy of Vaporization tell you? 12. How many joules of heat are required to melt 65.0g of ice that is at a temperature of 0°C? (Hint: Don’t forget to calculate the number of moles first!) 13. How much heat has to be released released when 98.7g of steam at 100°C condenses? 14. The Enthalpy of Vaporization is ( less than / similar to / greater than ) the Enthalpy of Fusion. Explain this trend at the molecular level. 15. Below is a heating curve for Acetone. The melting point of acetone is 95.0°C and the boiling point is 56°C. Temperature (°C) 150 100 50 0 -50 0 50 100 150 200 -100 -150 Time Calculate the amount of energy that would be required to heat a frozen block of acetone from -150.0°C to gaseous acetone at 150°C. The calculation should take 5 distinct steps. Clearly show your work below.
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