MATERIAL SAFETY DATA SHEET
SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations. SECTION 1: IDENTIFICATION 1.1 PRODUCT IDENTIFIER: ITEM NUMBER: PRODUCT NAME: 410072, 410074, 410175 Mean Green All-Purpose Degreaser o 5 GL: 410072 o 1 GL: 410074 o 55 GL: 410075 1.2 RELEVANT IDENTIFIED USES OF THE MIXTURE OR USES ADVISED AGAINST IDENTIFIED USE: IDENTIFIED USERS: Cleaning and degreasing. For sale to, use and storage by service persons only. 1.3 DETAILS OF THE SUPPLIER OF THE SAFETY DATA SHEET MANUFACTURER/ SUPPLIER: ADDRESS BUSINESS PHONE: EMERGENCY PHONE: WAXIE Sanitary Supply 9353 Waxie Way; San Diego, CA 92123-1036 1-800-995-4466 1-800-255-3924 (CHEMTEL; 24 hours) 1.4 OTHER PERTINENT INFORMATION This SDS has been developed to address safety concerns affecting small volume handling situations and those involving warehouses and other workplaces where large numbers of these items are stored or distributed. This product is intended to be used only after dilution. The relevant hazard and safety data sheet are specified for both the Product as SOLD and Product at USE DILUTION, where appropriate. SECTION 2: HAZARDS IDENTIFICATION 2.1 CLASSIFICATION OF THE SUBSTANCE OR MIXTURE: OSHA/HCS Status Product as SOLD Product at USE DILUTION (< 10%) Classification of the Substance or Mixture Acute toxicity, Oral (Category 4); Acute toxicity, Inhalation (Category 4); Acute toxicity, Dermal (Category 4); Skin corrosion (Category 1B); Serious eye damage (Category 1) Skin corrosion (Category 2); Serious eye damage (Category 2A) Product as SOLD Product at USE DILUTION (<10%) DANGER. Harmful if inhaled, swallowed, or in contact with skin. Causes severe skin burns and eye damage. WARNING. 2.2 LABEL ELEMENTS: ELEMENT Hazard Pictograms Signal Word Hazard Statements Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 1 of 11 Causes skin and serious eye irritation. SAFETY DATA SHEET April 27, 2015 SECTION 2: HAZARDS IDENTIFICATION (Continued) 2.2 LABEL ELEMENTS (Continued): ELEMENT Product as SOLD Product at USE DILUTION (<10%) Keep out of reach of children. Avoid breathing mist/ vapors/ spray. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a Poison Center/doctor if you feel unwell. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do so. Continue rinsing. Immediately call a POISON CENTER. Take off contaminated clothes and wash it before reuse. Keep out of reach of children. Wash hands thoroughly after use. Wear eye protection/face protection/protective clothing/protective gloves. Store locked up. Store in a well-ventilated place. Keep in tightly closed container. Dispose of contents/container in accordance with local/regional/ national/ international regulations. Not established; follow guidelines in section 7. Precautionary Statements Prevention Response Storage Disposal IF SWALLOWED: Rinse mouth, Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing. If eye irritation persists, see a physician. IF ON SKIN: Wash with plenty of water. If skin irritation occurs, get medical advice/attention. Take off contaminated clothing and wash it before reuse. Dispose of contents/container in accordance with local/regional/ national/ international regulations. 2.3 OTHER PERTINENT DATA ON CHEMICAL AND PHYSICAL HAZARDS: May cause severe irritation of the respiratory tract if mists/sprays are inhaled. Ingestion of large quantities may cause irritation, ulceration, nausea, vomiting and can be fatal Due to the potential corrosive nature of the Product as Sold, additional personal protection (e.g., rubber apron) should be worn when in the process of diluting product. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS 3.1 SUBSTANCES/MIXTURES COMPONENT CAS NUMBER Silicic acid (H2SiO3), Disodium salt 6834-92-0 Eye irritation (Category 2A); Acute Toxicity – Oral (Category 5) GHS HAZARD CLASSIFICATION FOR COMPONENT Proprietary1 % (w/w) 1-Amino-2-Propanol 78-96-6 Proprietary 2-Butoxyethanol 111-76-2 Flammable liquids (Category 4); Acute toxicity, Oral (Category 4); Acute toxicity, Dermal (Category 4); Skin corrosion (Category 1B; Serious eye damage (Category 1) Flammable liquids (Category 4); Acute toxicity, Oral (Category 4); Acute toxicity, Inhalation (Category 4); Acute toxicity, Dermal (Category 4); Skin irritation (Category 2); Eye irritation (Category 2A) Balance SECTION 4: FIRST AID MEASURES 1 The exact percentage of composition has been withheld as a trade secret. All relevant physical and health hazards have been declared, in accordance with regulatory requirements. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 2 of 11 SAFETY DATA SHEET April 27, 2015 4.1 DESCRIPTION OF FIRST AID MEASURES AREA EXPOSED Product as SOLD Product at USE DILUTION (<10%) Eye Contact Flush with copious amounts of water for 15 minutes. “Roll” eyes during flush. Seek medical attention immediately. Flush with copious amounts of water for 15 minutes. “Roll” eyes during flush. Seek medical attention if irritation persists. Skin Contact Flush area with warm, running water for several minutes. Seek medical attention if irritation persists. Flush area with warm, running water for several minutes. Seek medical attention if irritation persists. Inhalation Obtain fresh air. Obtain fresh air. Ingestion If conscious only: Rinse mouth with water. Drink several cups of water. Do not induce vomiting. Contact a Poison Control Center or physician for instructions. If conscious only: Rinse mouth with water. Drink several cups of water. Do not induce vomiting. Contact a Poison Control Center or physician for instructions. Other Recommendations Wash clothing before reuse. 4.2 MOST IMPORTANT ACUTE AND CHRONIC EXPOSURE SYMPTOMS ACUTE HEALTH EFFECTS: AREA EXPOSED Product as SOLD Product at USE DILUTION (<10%) Eye Contact Corrosive to eye tissue; contact will cause pain, redness, and tissue damage. Chemical burns and blindness may occur. Corrosive to skin tissue; contact will cause pain, redness, and tissue damage. Chemical burns may occur. Inhalation of sprays, mists may cause Causes serious eye irritation. Skin Contact Inhalation Ingestion Causes mild to moderate skin irritation, depending on duration of contact coughing, nasal congestion and sore throat. May causes respiratory tract irritation; symptoms may include coughing and sneezing depending on volume of mist/spray inhaled. Corrosive and may cause severe and permanent damage to mouth, throat, and stomach. May be fatal if swallowed. Causes gastrointestinal system irritation; symptoms may include pain, sore throat, nausea and vomiting if large volumes are ingested. CHRONIC HEALTH EFFECTS: Product as SOLD Product at USE DILUTION (<10%) Prolonged or repeated eye contact may cause conjunctivitis. Prolonged or repeated skin contact may cause dermatitis. Due to the presence of 2Butoxyethanol, prolonged or repeated inhalation or ingestion may affect the liver, blood (potentially causing anemia), kidneys, metabolism and endocrine system (spleen, thymus, pancreas). None reported. Product as SOLD Product at USE DILUTION (<10%) Eyes, Skin, Respiratory System, Central Nervous System, Kidneys, Liver, Blood, Endocrine System. Skin, eyes. TARGET ORGANS: SECTION 4: FIRST AID MEASURES (Continued) 4.3 INDICATION OF IMMEDIATE MEDICAL ATTENTION AND SPECIAL TREATMENT NEEDED Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 3 of 11 SAFETY DATA SHEET April 27, 2015 The following information is for both Product AS SOLD and Product at USE DILUTION. GENERAL INFORMATION: For all exposures: In case of accident, or if you feel unwell, seek medical advice immediately. Take this document and a copy of the label to the healthcare professional. RECOMMENDATIONS TO PHYSICIANS: Treat symptomatically. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: None reported. SECTION 5: FIREFIGHTING MEASURES Unless stated, information in this section is for both Product as SOLD and Product at USE DILUTION. 5.1 EXTINGUISHING MEDIA RECOMMENDED FIRE EXTINGUISHING MEDIA: Water Spray, Water Jet, Dry Powder, Foam, Carbon Dioxide, Halon, or any other. UNSUITABLE FIRE EXTINGUISHING MEDIA: None known. 5.2 SPECIAL HAZARDS ARISING FROM THE SUBSTANCE OR MIXTURE NFPA FLAMMABILITY CLASSIFICATION: Classification Product as SOLD Product at USE DILUTION (<10%) NFPA Rating UNUSUAL HAZARDS IN FIRE SITUATIONS: Product as SOLD Product at USE DILUTION (<10% Decomposition Generates caustic vapors and oxides of potassium and nitrogen, carbon monoxide and carbon dioxide. Generates caustic vapors and oxides of potassium, carbon monoxide and carbon dioxide. Explosion Sensitivity to Mechanical Impact Not applicable. Not applicable. Explosion Sensitivity to Static Discharge Not applicable. Not applicable. 5.3 ADVICE FOR FIREFIGHTERS Self-Contained Breathing Apparatus and full protective equipment for fire response should be worn in any situation. Move containers from fire area if it can be done without risk to personnel. Otherwise, use water spray to keep fire-exposed containers cool. Because of the nature of this product, any equipment that comes in contact with this solution can be rinsed thoroughly with water and then returned to service. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 4 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 6: ACCIDENTAL RELEASE MEASURES Unless stated, information in this section is for both Product as SOLD and Product at USE DILUTION. 6.1 PERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT, AND EMERGENCY PROCEDURES RESPONSE TO INCIDENTAL RELEASES: Personnel who have received basic chemical safety training can generally handle small-scale releases. Gloves and safety glasses must be worn when cleaning-up spills. Use caution during clean-up; contaminated floors and items may be slippery. RESPONSE TO NON-INCIDENTAL RELEASES: Generally, releases of this product will be no larger than the loss of one shipment of material. Subsequently, personnel can follow the instructions for incidental releases. As needed, respond to non-incidental chemical releases of this product (such as the simultaneous destruction of several pallets of this product) by clearing the impacted area and contacting appropriate emergency personnel. In the unlikely event of a 55-gallon or multi-container release of the PRODUCT AS SOLD, and there is no other hazardous condition in the area, the use of an air-purifying respirator with high-efficiency particulate fileter cartridge, face-shield, safety glasses, and double gloves (e.g. nitrile over latex gloves), and body protection is recommended if splashes/sprays/mists can be generated during clean-up or the concentration of vapors is high. Use Self-Contained Breathing Apparatus if concentration of oxygen is less than 19.5% or is unknown. RESPONSE PROCEDURES FOR ANY RELEASE: Absorb spilled liquid with polypads or other suitable absorbent materials. If appropriate, neutralize contaminated area and equipment with base neutralizing agent. Rinse contaminated items and area thoroughly. Confirm that neutralization/decontamination is complete by testing with pH paper. ENVIORNMENTAL PRECAUTIONS Avoid response actions that can cause a release of a significant amount of the substance (more than one, 5-gallon container) into the environment. Avoid accidental dispersal of spilled material into soil, waterways and sewers. 6.2 6.3 METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING UP 6.4 SPILL RESPONSE EQUIPMENT: Polypad or other absorbent material; base neutralizing agent; pH paper. REFERENCES TO OTHER SECTIONS SECTION 8: For exposure levels and detailed personal protective equipment recommendations. SECTION 13: For waste handling guidelines. SECTION 7: HANDLING AND STORAGE 7.1 PRECAUTIONS FOR SAFE HANDLING Product as SOLD Product at USE DILUTION (<10%) Hygiene Practices Keep out of reach of children. Follow good chemical hygiene practices. Do not smoke, drink, eat, or apply cosmetics in the chemical use area. Avoid inhalation of mists and sprays. Use in well-ventilated area. Avoid contact with skin or eyes. Remove contaminated clothing promptly. Clean up spilled product immediately. Keep out of reach of children. Follow good chemical hygiene practices. Do not smoke, drink, eat, or apply cosmetics in the chemical use area. Avoid inhalation of mists and sprays. Use in well-ventilated area. Avoid contact with skin or eyes. Remove contaminated clothing promptly. Clean up spilled product immediately. Handling Practices Employees must be appropriately trained to use this product safely as needed. Keep containers closed when not in use. Employees must be appropriately trained to use this product safely as needed. Keep containers closed when not in use. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 5 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 7: HANDLING AND STORAGE (Continued) 7.2 CONDITIONS FOR SAFE STORAGE, INCLUDING ANY INCOMPATIBILITIES Storage Practices Incompatibilities Product as SOLD Ensure all containers are correctly labeled. Store containers away from direct sunlight, sources of intense heat, or where freezing is possible. Store this product away from incompatible chemicals Inspect all incoming containers before storage, to ensure containers are properly labeled and not damaged. Empty containers may contain residual liquid; therefore, empty containers should be handled with care. See Section 10 (Stability and Reactivity). Product at USE DILUTION (<10%) Ensure all containers are correctly labeled. Store containers away from direct sunlight, sources of intense heat, or where freezing is possible. Store this product away from incompatible chemicals. See Section Reactivity). 10 (Stability and SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 CONTROL PARAMETERS U.S. NATIONAL EXPOSURE LIMITS: COMPONENT 2-Butoxyethanol NIOSH REL (ppm) OTHER TWA = 20 ppm (Skin) TWA = 50 ppm (Skin) TWA = 5 ppm (Skin) NE 2-BUTOXYETHANOL: Butoxyacetic Acid (BAA) in Urine; End of Shift; 200 mg/g creatinine EXPOSURE CONTROLS Engineering Controls Respiratory Protection Hand Protection Eye Protection Body Protection 8.3 OSHA PEL (ppm) BIOLOGICAL OCCUPATIONAL EXPOSURE LIMITS: The following BEIs have been established for components of this product. o 8.2 ACGIH TLV Product as SOLD Use in well-ventilated environment. None needed in normal circumstances of use. Neoprene or nitrile gloves are recommended. Ensure gloves are intact prior to use. Safety glasses. Face-shields are recommended when splash, sprays, or mists can be generated. Standard protection used in janitorial service. If splashes or sprays can occur, a rubber apron should be used. Product at USE DILUTION (<10%) Use in well-ventilated environment. None needed in normal circumstances of use. Standard chemical-resistant gloves used in janitorial work are recommended. Safety glasses. Standard protection used in janitorial service. If splashes or sprays can occur, a rubber apron should be used. PERSONAL PROTECTION SYMBOLS Product as SOLD Product at USE DILUTION (<10%) Hand Protection Eye/Face Protection Body Protection SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 6 of 11 SAFETY DATA SHEET April 27, 2015 9.1 INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES 9.2 Product as SOLD Product at USE DILUTION (<10%) Appearance Odor Odor Threshold pH Melting Point/Freezing Point Initial Boiling Point/Boiling Range Flash Point Evaporation Rate (Water = 1) Flammability Upper/Lower Explosive Limits Vapor Pressure Vapor Density Relative Density (Density) Solubility Turquoise liquid. Citrus. Not determined. < 12.5 Not determined. >99C (210 F). Not applicable. Approx. 1.0. Not applicable. Not applicable. Not determined. Not determined. 1.09 (9.10 lbs/gal) Completely soluble in water. Colorless to yellow. Slight solvent Not determined. < 11.5 Approx. 0C (32 F). Approximately100C (212F). Not applicable. Approx. 1.0. Not applicable. Not applicable. Not determined. Not determined. Approx. 1.0. (8.34 .b/gal) Completely soluble in water. Partition Coefficient/noctanol/water Not determined. Not determined. Autoignition Temperature Not applicable. Not applicable. Decomposition Temperature Not determined. Not determined. Viscosity Not determined. Not determined. OTHER INFORMATION VOC (less water & exempt): 19 G/L WEIGHT% VOC: 1.9% SECTION 10: STABILITY AND REACTIVITY Unless stated, information in this section is for both Product as SOLD and Product at USE DILUTION. 10.1 10.2 REACTIVITY Not reactive under typical conditions of use or handling. CHEMICAL STABILITY Normally stable under standard temperatures and pressures. 10.3 POSSIBILITY OF HAZARDOUS REACTIONS This product is not self-reactive, water-reactive, or air-reactive. This product will not undergo hazardous polymerization. 10.4 CONDITIONS TO AVOID 10.5 10.6 Avoid contact with incompatible chemicals. INCOMPATIBLE MATERIALS Strong oxidizing agents, strong acids, water reactive material, aluminum and soft metals; lead; tin and tin oxides. HAZARDOUS DECOMPOSITION PRODUCTS Products of thermal decomposition of this product include caustic vapors, carbon monoxide, carbon dioxide, and oxides of potassium and nitrogen. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 7 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 11: TOXICOLOGICAL INFORMATION Unless stated, information in this section is for both Product as SOLD and Product at USE DILUTION. 11.1 INFORMATION ON TOXICOLOGICAL EFFECTS ACUTE TOXICITY: o TOXICOLOGY DATA: The following data are available for the hazardous components in this product listed in Section 3 (Composition/Information on Ingredients). 1-AMINO-2-PROPANOL LD50 (Oral, Rat) = 1715 mg/kg LD50 (Skin, Rabbit) = 1573 mg/kg 2-BUTOXYETHANOL LD50 (Oral, Rat) = 470 mg/kg LC50 (Inhalation, Rat) = 4 hours/- 450 ppm. LD50 (Dermal, Rabbit) = 220 mg/kg LD50 (Intraperitoneal, Rat) = 220 mg/kg LD50 (Intravenous, Rat) = 307 mg/kg SILICIC ACID (H2SIO3), DISODIUM SALT LD50 (Oral, Rat) = 1,152-1,349 mg/kg TDLo (Oral, Man) = 1 mL/Kg o DEGREE OF IRRITATION: Causes severe skin burns and eye damage. The following data are available for components of this product. 1-AMINO-2-PROPANOL Skin, Rabbit; Mild skin irritation - 24 hours Eyes, Rabbit; Result: Severe eye irritation, 24 hours SILICIC ACID (H2SIO3), DISODIUM SALT Eyes, Rabbit = Corrosive/4 hours Skin, Rabbit – Mild Irritant o SENSITIZATION: The components of this product are not reported to have skin or respiratory sensitization effects. o REVIEW OF ACUTE SYMPTOMS AND EFFECTS BY ROUTE OF EXPOSURE: See Section 2 (Hazards Information) and Section 4 (First-Aid Measures) for additional details. See Section 4 (First-Aid Measures) for more details. Eyes Product as SOLD Skin May cause moderate to severe skin irritation, and chemical burns. Causes mild to severe irritation of membranes of nose, mouth, throat. Causes severe irritation and chemical burns of gastrointestinal system. May be fatal if swallowed. May cause moderate to severe eye irritation and chemical burns. Inhalation Ingestion Product at USE DILUTION <10%) May cause moderate to severe eye irritation and chemical burns, depending on duration of exposure. May cause moderate to severe skin irritation, and chemical burns. Causes mild to severe irritation of membranes of nose, mouth, throat. Causes severe irritation and chemical burns of gastrointestinal system. May be fatal if swallowed. CHRONIC TOXICITY: o CARCINOGENICITY STATUS: The following table summarizes the carcinogenicity listing for the components of this product. “NO” indicates that the substance is not considered to be, or suspected to be, a carcinogen by the listed agency. CHEMICAL 2-Butoxyethanol IARC NTP NIOSH OSHA OTHER NO NO NO NO IARC-3: Unclassifiable as to Carcinogenicity in Humans; TLV-4: Not Classifiable as a Human Carcinogen; EPA – NL: Not Likely to Be Carcinogenic to Humans; MAK-4: No Significant Contribution to Human Cancer Risk Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 8 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 11: TOXICOLOGICAL INFORMATION (Continued) o REPRODUCTIVE TOXICITY INFORMATION: The components of this product are not reported to cause reproductive effects under typical circumstances of exposure. The following reproductive toxicity data are available for components of this product: o o o o 2-BUTOXYETHANOL: Overexposure may cause reproductive disorder(s) based on tests with laboratory animals. May cause adverse reproductive effects (maternal and paternal fertility, fetoxicity) based on animal data. May cause birth defects (teratogenic) based on animal data. MUTAGENIC EFFECTS The components of this product are not reported to cause mutagenic effects under typical circumstances of exposure. SPECIFIC TARGET ORGAN TOXICITY – SINGLE EXPOSURE: Not applicable. SPECIFIC TARGET ORGAN TOXICITY – REPEATED EXPOSURE: Not applicable. ASPIRATION HAZARD: Not applicable. OTHER INFORMATION o TOXICOLOGICALLY SYNERGISTIC PRODUCTS: None known. o ADDITIONAL TOXICOLOGY: Not applicable. SECTION 12: ECOLOGICAL INFORMATION Unless stated, information in this section is for both Product as SOLD and Product at USE DILUTION. 12.1 TOXICITY Based on available data, this product is anticipated to be harmful or fatal to contaminated terrestrial plants or animals. The following aquatic toxicity data are available for components of this product: 2-BUTOXYETHANOL LC50 - other fish: 220 mg/L - 96 hours EC50 (Daphnia magna): 1,815 mg/L - 24 hours 1-AMINO-2-PROPANOL LC50 (Carassius auratus): 210 mg/l - 96 hours SILICIC ACID (H2SIO3), DISODIUM SALT LC50 ( Danio rerio) - 210 mg/L - 96 hours 12.2 12.3 12.4 12.5 PERSISTENCE AND DEGRADABILITY When released into the soil, the components of this product are expected to biodegrade, dissipate in soils via oxidation, or otherwise chemically degrade or photo-decompose via solar radiation. BIOACCUMULATIVE POTENTIAL This product is not anticipated to bioaccumulate significantly. MOBILITY IN SOIL It is expected this product will have small mobility in soil. Some of the components may get into the soil and, ultimately, the ground water. Product spreads on the water surface. OTHER ADVERSE EFFECTS None reported. SECTION 13: DISPOSAL CONSIDERATION 13.1 13.2 o WASTE TREATMENT METHODS Product as SOLD Product at USE DILUTION Dispose of in accordance with local, State and Federal regulations. Dispose of unused product in accordance with local, State and Federal regulations. DISPOSAL CONSIDERATIONS EPA RCRA WASTE CODE: Not applicable to wastes consisting only of this product. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 9 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 14: TRANSPORT INFORMATION 14.1: DANGEROUS GOODS BASIC DESCRIPTION AND OTHER TRANSPORT INFORMATION DEPARTMENT OF TRANSPORTATION HAZARDOUS MATERIALS SHIPPING REGULATIONS: UN/NA Number Proper Shipping Name Packing Group Hazard Class Label North American Emergency Response Guide # Marine Pollutant Status NOT APPLICABLE CANADIAN TRANSPORTATION INFORMATION: This product is regulated by Transport Canada as dangerous goods under Canadian transportation standards. Refer to above information. IATA DESIGNATION: This product is regulated as dangerous goods by the International Air Transport Association. Use the following information: UN/NA Number Proper Shipping Name Packing Group Hazard Class Label North American Emergency Response Guide # Marine Pollutant Status NOT APPLICABLE IMO DESIGNATION: This product is regulated as dangerous goods by the International Maritime Organization. Use the following information: UN/NA Number Proper Shipping Name Packing Group Hazard Class Label North American Emergency Response Guide # Marine Pollutant Status NOT APPLICABLE 14.2: ENVIRONMENTAL HAZARDS None described, as related to transportation. 14.3: SPECIAL PRECAUTIONS FOR USERS Not applicable. 14.4: TRANSPORT IN BULK Not applicable. SECTION 15: REGULATORY INFORMATION 15.1: SAFETY, HEALTH, AND ENVIRONMENTAL REGULATIONS SPECIFIC FOR THE PRODUCT OTHER IMPORTANT U.S. REGULATIONS o U .S. SARA THRESHOLD PLANNING QUANTITY: Not applicable. o U.S. SARA HAZARD CATEGORIES (SECTION 311/312, 40 CFR 370-21): ACUTE: Yes; CHRONIC: Yes; FIRE: No; REACTIVE: No; SUDDEN RELEASE: No o U.S. CERCLA REPORTABLE QUANTITY (RQ): Not applicable. o U.S. TSCA INVENTORY STATUS: All components of this product are listed on the TSCA Inventory. o CALIFORNIA SAFE DRINKING WATER ACT (PROPOSITION 65) STATUS: Not applicable. INTERNATIONAL REGULATIONS o CANADIAN REGULATORY STATUS: The PRODUCT as SOLD is classified as hazardous under Canadian Controlled Products regulations (SOR-88-66). It is classified as E –Corrosive Material. See symbol to right. This SDS contains all the information required by the CPR. o CANADIAN DSL/NDSL INVENTORY STATUS: The listed components of this product are on the DSL/NDSL Inventory. o CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: The components of this product are not on the CEPA Priorities Substances Lists. o GERMAN WATER HAZARD CLASSIFICATION: 1 (Low hazard to waters). Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION WAXIE Sanitary Supply Page 10 of 11 SAFETY DATA SHEET April 27, 2015 SECTION 16: OTHER INFORMATION 16.1: 16.2: INDICATION OF CHANGE DATE OF REVISION: April 27, 2015 SUPERCEDES: October 1, 2014 CHANGE INDICATED: Update of OSHA Hazard Communication Standard (29 CFR 1910.1200). KEY LITERATURE REFERENCES AND SOURCES FOR DATA SAX – Dangerous Properties of Industrial Materials TOXNET – http://toxnet.nlm.nih.gov/ European Chemicals Inventory Classification and Listing: http://echa.europa.eu/ 16.3 HAZARDOUS MATERIALS CLASSIFICATION SYSTEM Product as SOLD 16.4 Product at USE DILUTION Health Flammability 2 0 Physical Hazard 0 Protective Equipment C/D HMIS Personal Protective Equipment Rating: Occupational Use situations: C - Safety glasses and gloves and- body protection suitable to specific circumstances of use should be worn. D Face-shield should be added if splashes/sprays can occur. Health Flammability 1 0 Physical Hazard 0 Protective Equipment B/C HMIS Personal Protective Equipment Rating: Occupational Use situations: B - Safety glasses and gloves. C – Rubber apron should be added if splashes/sprays can occur. DISCLAIMER WAXIE Sanitary Supply makes no warranty, representation or guarantee as to the accuracy, sufficiency or completeness of the material set forth herein. It is the user’s responsibility to determine the safety, toxicity and suitability of their own use, handling and disposal of this product. Since actual use by others is beyond our control, no warranty, expressed or implied, is made by WAXIE Sanitary Supply as to the effects of such use, the results to be obtained or the safety and toxicity of this product, nor does WAXIE Sanitary Supply assume any liability arising out of the use by others of this product referred to herein. The data in this SDS relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. WAXIE Sanitary Supply does not recommend blending this product with any other chemicals. All information, recommendations and data contained herein concerning this product are based upon information available at the time of writing from recognized technical sources. 16.5: ABBREVIATIONS AND ACRONYMS ALL SECTIONS: OSHA: U.S. Federal Occupational Safety and Health Administration. WHMIS: Canadian Workplace Hazardous Materials Standard. GHS: Globally Harmonized System of Classification of Chemical Substances. REACH: European Union regulation, Registration, Evaluation, Authorization and Restriction of Chemical substances. SECTION 2: CAS Number: Chemical Abstract Service Number, which is used by the American chemical Society to uniquely identify a chemical. SECTION 5: NFPA: National Fire Protection Association. NFPA FLAMMABILITY CLASSIFICATION: The NFPA uses the flash point (Fl.P.) and boiling point (BP) to classify flammable or combustible liquids. Class IA: Fl.P. below 73F and BP below 100F. Class IB: Fl.P. below 73F and BP at or above 100F. Class IC: :Fl.P. at or above 73F and BP at or above 100F. Class II: : Fl.P. at or above 100F and below 140F. Class IIIA: Fl.P. at or above 140F and below 200F. Class IIIB: Fl.P. at or above 200F. NFPA HAZARDOUS MATERIALS RATING: This is a rating system used to summarize physical and health hazards to firefighters. 0 = No Significant Hazard. 1 = Slight Hazard. 2 = Moderate Hazard. 3 = Severe Hazard. 4 = Extreme Hazard. SECTION 8: NE: Not established. ACGIH: American Conference of Government Industrial Hygienists; TWA: Time-Weighted Average (over an 8-hour work day); STEL: Short-Term Exposure Limit (15 minute average, no more than 4-times daily and each exposure separated by one-hour minimally); C: Ceiling Limit (concentration not to be exceeded in a work environment). PEL: Permissible Exposure Limit. NIOSH: National Institute of Occupational Safety and Health; REL: Recommended Exposure Limit; IDLH: Immediately Dangerous to Life and Health Concentrations. Note: In July 1992, a court ruling vacated the more protective PELs set by OSHA in 1989. Because OSHA may enforce the more protective levels under the “general duty clause”, both the current and vacated levels are presented in this document. ppm: Parts per Million. mg/m3: Milligrams per cubic meter. mppcf: Millions of Particles per Cubic Foot. BEI: Biological Exposure Limit. SECTION 9: pH: Scale (0 to 14) used to rate the acidity or alkalinity of aqueous solutions. For example, a pH value of 0 indicates a strongly acidic solution, pH of 7 indicates a neutral solution, and a pH value of 14 indicates an extremely basic solution. FLASH POINT: Temperature at which a liquid generates enough flammable vapors so that ignition may occur. AUTOIGNITION TEMPERATURE: Temperature at which spontaneous ignition occurs. Mean Green All-Purpose Degreaser Product AS SOLD and IN USE DILUTION SECTION 9 (Continued): LOWER EXPLOSIVE LIMIT (LEL): The minimal concentration of flammable vapors in air which will sustain ignition. UPPER EXPLOSIVE LIMIT (UEL): The maximum concentration of flammable vapors in air which will sustain ignition.≈: Approximately symbol. VOC: Volatile Organic Compound. SECTION 11: CARCINOGENICITY STATUS: NTP: National Toxicology Program. IARC: International Agency for Research on Cancer. REPRODUCTIVE TOXICITY INFORMATION: Mutagen: Substance capable of causing chromosomal damage to cells. Embryotoxin: Substance capable of damaging the developing embryo in an overexposed female. Teratogen: Substance capable of damaging the developing fetus in an overexposed female. Reproductive toxin: Substance capable of adversely affecting male or female reproductive organs or functions. TOXICOLOGY DATA: LDxxor LCxx: The Lethal Dose or Lethal Concentration of a substance which will be fatal to a given percentage (xx) of exposed test animals by the designate route of administration. This value is used to access the toxicity of chemical substances to humans. TDxxor TCxx: The Toxic Dose or Toxic Concentration of a substance which will cause an adverse effect to a given percentage (xx) of exposed test animals by the designate route of administration. SECTION 12: EC50: Effect Concentration (on 50% of study group); BOD: Biological Oxygen Demand. SECTION 13: RCRA: Resource Conservation and Recovery Act. The regulations promulgated under this act under Act are found in 40 CFR, Sections 260 ff, and define the requirements of hazardous waste generation, transport, treatment, storage, and disposal. EPA RCRA Waste Codes: Defined in 40 CFR Section 261. SECTION 15: CERCLA: Comprehensive Environmental Response Compensation and Liability Act (a.k.a. “Superfund”) and SARA: (Superfund Amendment and Reauthorization Act). The regulations promulgated under this Act are located under 40 CFR 300 ff. and provide “community right-to-know” requirements. TSCA: Toxic Substances Control Act: Rules regulating the manufacture and sale of chemicals found in 40 CFR 700-766. DSL/NDSL: Canadian Domestic Substances and Non-Domestic Substances Lists. SECTION 16: HAZARDOUS MATERIALS IDENTIFICATION SYSTEM RATING: This is a rating system used by industry to summarize physical and health hazards to chemical users and was originally developed by the National Paint and Coating Association. 0 = No Significant Hazard. 1 = Slight Hazard. 2 = Moderate Hazard. 3 = Severe Hazard. 4 = Extreme Hazard. WAXIE Sanitary Supply Page 11 of 11 SAFETY DATA SHEET April 27, 2015
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