SAFETY DATA SHEET Superset NC 1. Identification Material Name: Synonyms: Product Use: Supplier: Emergency: Superset NC Concrete admixture, non chloride accelerator. This product speeds the rate of hydration of cement, shortens the normal set time, or increases the rate of hardening of strength development. Eastern Admix, LLC 1250 Riverfront Center Amsterdam, NY 12010 http://easternadmix.com/ (518) 684-6069 2. Hazard Identification Danger! Causes serious eye damage. Harmful if swallowed. GHS Classification: Health Eye irritation, Category 1 - H318-causes serious eye damage Acute Category 4 (oral) - H302-harmful if swallowed Environmental Not Classified Physical Not Classified GHS Label: Symbols: Hazard Statements Danger! Causes serious eye damage Harmful if swallowed. Precautionary Statements Prevention: P264-Wash skin thoroughly after handling. P270-Do not eat, drink or smoke when using this product. P280-Wear eye protection/face protection. Response: P301+P312-If swallowed: seek medical attention if you do not feel well P305+P351+P338-If in eyes: Rinse gently for 15 minutesseek medical attention P310-seek medical attention immediately P330-rinse mouth Disposal: P501-dispose of contents to an approved waste disposal plant 3. Composition / Information on Ingredients Substance Water Calcium nitrate tetrahydrate Calcium nitrite Sodium thiocyanate 03/17/2015 CAS # 7732-18-5 13477-34-4 13780-06-8 540-72-7 Page 1 of 4 EINECS # 231-791-2 233-332-1 237-424-2 208-754-4 Wt.% 30 - 60 50 - 70 1-5 1-3 Superset NC SAFETY DATA SHEET Superset NC There are no additional ingredients present which within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. See Section 8 for exposure limits. 4. First Aid Measures Inhalation: IF INHALED: Remove person to fresh air and ensure comfortable breathing. Get medical attention if you feel unwell. Skin Contact: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice. Eye Contact: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Ingestion: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Note to physician: Treat symptomatically, monitor methemoglobinemia and hypercalcemia. 5. Fire Fighting Measures Suitable Extinguishing media: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Water fog should be used to cool fire-exposed containers, structures and to protect personnel. Unsuitable Extinguishing media: Not applicable. Special exposure hazards: Toxic nitrogen oxides may be generated at elevated temperature. Combustion products: Not combustible. Protection of firefighters: Fire fighters should wear full protective clothing including self-contained breathing apparatus. Keep personnel removed and upwind of fire. Do not inhale combustion gases. NFPA Hazard Classification: Health: 3 Flammability: 0 Instability: 1 Special: -This information is intended solely for the use of individuals trained in the NFPA system. 6. Accidental Release Measures Personal precautions: Use suitable protective equipment (see section 8) to prevent contamination of skin, eyes and personal clothing. Provide sufficient ventilation. Methods for cleanup: Keep out of sewers and waterways. Collect spilled material with inert absorbent into containers and dispose in accordance with applicable regulations and product characteristics at time of disposal (see also Section 13). 7. Handling and Storage Handling: When using do not eat, drink or smoke. Wear eye protection, gloves and wash hands thoroughly after handling. Remove contaminated clothing and protective equipment before entering eating areas. Storage: Store in a well-ventilated place. Store in the original container away from combustible materials and reducing agents. 8. Exposure Controls / Personal Protection Exposure Limits: Exposure limits are not established for this product. Engineering controls: Local exhaust ventilation is recommended. Personal protection: General: General hygiene considerations are appropriate when used as recommended. The following precautions are recognized as common good industrial hygiene practice. Emergency conditions may require additional precautions. Follow precautions listed and recommendations for personal protective equipment. Eye: Wear eye and face protection. Have eye-wash stations available where eye contact can occur. Skin: Avoid skin contact. Wear rubber gloves impervious to conditions of use. Additional protection may be necessary to prevent skin contact including use of apron, face shield, boots or full body protection. Wash hands thoroughly after handling. A safety shower should be located in the work area. 03/17/2015 Page 2 of 4 Superset NC SAFETY DATA SHEET Superset NC Respiratory: Do not breathe vapor. NIOSH approved respiratory protection should be worn if exposure limits are exceeded. NIOSH approved respiratory protection should be worn if exposure limits are exceeded. A NIOSH approved respirator is generally acceptable for concentrations up to 10 times the PEL. Use a NIOSH approved air-supplied respirator for higher concentrations, unknown concentrations and for oxygen deficient atmospheres. Use only outdoors or in a well-ventilated area. Engineering controls are the preferred means for controlling chemical exposures. In case of inadequate ventilation wear respiratory protection. Respiratory protection may be needed for non-routine or emergency situations. Respiratory protection must be provided in accordance with OSHA 29 CFR 1910.134. Thermal: Not normally required. 9. Physical and Chemical Properties Appearance: Odor: Odor threshold: pH: Melting/ Freezing point/ range: Initial Boiling point/ range: Flash Point: Evaporation rate: Flammability (solid, gas): Upper/ lower flammability or explosive limits: Vapor pressure, mm Hg: Vapor density: Relative density: Solubility in water: Solubility in fats/ oils: Partition Coefficient (n-octanol-water): Autoignition temperature: Decomposition temperature: Viscosity: Clear to yellowish liquid None Not available 8.0 – 9.5 < -23⁰C, 10⁰F 102⁰C, 215⁰F Not applicable Not available Not available Not available Not available Not available 1.31 Soluble Negligible Not available Not available 132⁰C Not available 10. Stability and Reactivity Chemical Stability: Hazardous Reactions: Conditions to Avoid: Incompatible Materials: Hazardous Decomposition Products Product is stable at ambient temperature and pressure. Will not occur at ambient temperature Avoid heat, acids, aluminum, evaporation to dryness Strong reducing agents, aluminum, ammonia, organic materials, combustible materials. Normally stable. Emits nitrogen oxides when heated to decomposition. 11. Toxicological Information Acute toxicity: Skin corrosion / irritation: Respiratory or skin sensitization: Germ cell mutagenicity: Carcinogenicity: Reproductive toxicity: STOT–single exposure: STOT-repeated 03/17/2015 Acute Toxicity Estimate, Rat, oral LD50 = 614 mg/Kg Skin and eye irritant. Not a sensitizer. Not available Not carcinogenic Not available Corrosive to eyes. Not available Page 3 of 4 Superset NC SAFETY DATA SHEET Superset NC exposure: Aspiration hazard: Other Information: None. Most likely exposure route is skin or eye contact. 12. Ecological Information Toxicity: Persistence and degradability: Bioaccumulative potential: Mobility in soil: Other adverse effects: Calcium nitrate: D. magna EC50 = 490 mg/L/48h; O. mykiss LC50 >89.9 mg/L/96h, NOEC= 98.9 mg/L/96h Not available Unlikely Not available Not available 13. Disposal Considerations Disposal methods: Reuse if possible. Dispose of contaminated materials to an approved waste disposal plant. 14. Transport Information Not regulated for transportation. Environmental Hazards: Not a DOT listed marine pollutant. 15. Regulatory Information No components are subject to Montreal Protocol, Stockholm Convention, or Rotterdam Convention. Region specific regulations SARA Title III: Section 302/304. Extremely Hazardous Substances - None. Section 311/312. (40CFR370) Hazardous Categories: Acute Section 313: Contains the following SARA 313 Toxic Release Chemicals: Chemical Name CAS Number Concentration Water dissociable nitrate compounds NA 40 – 50% The following product components are cited on the lists below: None TSCA (Toxic Substance Control Act): Listed. CA65: No components are known to the State of California to cause cancer or reproductive toxicity. 16. Other Information HMIS Hazard Classification: Health-3 Flammability-0 Physical Hazard-1 Personal Protection – X The information provided in this Safety Data Sheet is accurate to the best of our knowledge and belief. The information is given as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by use of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations. Revision History: Date Prepared: 03/17/2015. By: Charles Leonard, CIH, ASLAN Group LLC Supersedes: Initial Issue SDS ID: Superset NC 03/17/2015 Page 4 of 4 Superset NC
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