Secondary Dust Explosions: How to Prevent them or Mitigate their Effects? Je´roˆme Taveau Institut de Radioprotection et de Suˆrete´ Nucle´aire, IRSN/DSU/SERIC/BEXI, 31, avenue de la Division Leclerc, 92 260 FONTENAY AUX ROSES cedex, France; [email protected] (for correspondence) Published online 8 August 2011 in Wiley Online Library (wileyonlinelibrary.com). DOI 10.1002/prs.10478 Dust explosions are frequent and particularly devastating in the process industries. Secondary dust explosions are the most severe ones, and occur when the blast wave from a primary explosion entrains dust layers already present in the plant, creating a large dust-air flammable mixture ignited by the first explosion. As the blast wave propagates through the plant, dust fuels the emerging flame, leading to extensive damage owing to the large quantity of dusts involved and the consequent strong pressure wave. Several cases of secondary dust explosions have been analyzed by Eckhoff. Major accidents have also occurred in the US in recent years, causing the Chemical Safety Board (CSB) to produce a specific report highlighting the increasing number of dust explosions. An illustration of this point is the massive explosion that occurred on 7 February 2008 at the Imperial Sugar Company in Port Wentworth (Georgia), causing 14 fatalities and injuring 36 people. The consequences of secondary dust explosions can be disastrous. However, only a minor initiating ‘‘primary’’ explosion can quickly develop into a major secondary explosion if appropriate measures have not been taken in advance. This article describes several secondary dust explosion accidents that occurred in France and in the US and present some practical solutions to prevent or mitigate these accidents. Ó 2011 American Institute of Chemical Engineers Process Saf Prog 31: 36–50, 2012 Keywords: dust; explosion; secondary; Imperial Sugar; prevention; protection; best practices INTRODUCTION Dust explosions are frequent in the process industries, if we compare to other major accidents, and particularly devastating. Various authors [1,2] have listed many cases in developed countries. In 2006, the Chemical Safety Board [3] produced a specific report that highlighted the increasing number of dust explosions in US facilities. Indeed, Chemical Safety Board (CSB) identified an average of 10 dust explosion incidents per year from 1980 to 2005, corresponding to five fatalities and 29 injuries per year (Figure 1). Year 2003 was particularly catastrophic since three massive dust explosions occurred (West Pharmaceutical [4], CTA Acoustics [5], and Hayes Lemmerz [6]), resulting in a total of 14 deaths and 81 injuries. Many dusts are combustible and therefore represent a potential explosion hazard if they are both airborne and Ó 2011 American Institute of Chemical Engineers 36 March 2012 exposed to an ignition source. A damaging dust explosion can occur if the following conditions are fulfilled (Figure 2): • An oxidant (oxygen of the air) must be present; • The dust must be combustible and airborne, and its concentration in the air must be within the explosible range; • An ignition source must be present (ignition source must be efficient, i.e., of sufficient energy and duration to ignite a dust cloud); • Finally, the environment must be sufficiently confined (or congested) to produce significant explosion overpressures. According to Zalosh et al. [8], secondary dust explosions are the most severe ones: ‘‘Perhaps the most devastating dust explosion scenario is the generation of a secondary dust explosion in the building surrounding the equipment in which a primary explosion takes place. The secondary explosion occurs when the blast wave emanating from the ruptured equipment or conveyor lifts the accumulated dust into suspension, and the flame from the primary explosion subsequently ignites the suspended dust cloud. The resulting devastation and casualties are associated both with the burning of building occupants and with the structural damage to the building.’’ Figure 3 from Eckhoff [1] shows the main mechanisms involved in a secondary dust explosion. Numerous secondary dust explosions have occurred over more than 150 years. This article reviews selected cases which occurred in France and USA in recent years and attempts to focus on the recurring factors. Also, a review of practical prevention and mitigation solutions is given, based on recognized and generally accepted good engineering practices, coming from standards and professional guidelines. FOCUS ON TWO FRENCH PAST ACCIDENTS INVOLVING SECONDARY DUST EXPLOSIONS Metz, France, 1982 (12 Killed, two Injured) Site Description The malt house silo was located on the Moselle River, near Metz (east of France). Built in 1973–1974, this facility was dedicated to the reception of barley shipments by rail, road, and boat. This process was designed to transform barley into malt for breweries. Built in reinforced concrete, the silo was composed of 14 vertical cylinders (7 m in diameter, 43 m in height) clustered into three rows and supplied by conveyor belts from a 62-m high handling tower. The handling tower contained cleaning machines, scales, presses, vacuum pumps, and bucket elevators. Only a portion of the installation had been set up with a Process Safety Progress (Vol.31, No.1) Figure 1. Dust incidents, injuries, and fatalities in the USA (1980–2005) [3]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 2. Dust explosion pentagon [7]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] dust removal system leading to a single plenum chamber. The facility did not have proper explosion venting to release excess pressure in the event of an explosion. The Accident The explosion occurred on October 18, 1982 at 2:15 pm. At this moment, several employees and subcontractors were working in the facility: seven operators in the handling tower (four operators installing dust removal ducts and three operators repairing slabs), two employees in the elevator pit (cleaning), one employee in the control room and three drivers [9]. Witnesses reported two successive explosions a ‘‘few seconds’’ apart, the second more powerful than the first. Given the type of operations in progress just before the accident, the investigation concluded that an initial explosion occurred in the handling tower, generated by the combination of an ignition source introduced during the works, or a smoker, with an explosive atmosphere. This primary event caused dust to spread inside the facility, leading to the second explosion throughout the tower, the upper gallery and spaces between cells. Process Safety Progress (Vol.31, No.1) Figure 3. Mechanisms involved in a secondary dust explosion [1]. Figure 4. View of the damage caused by the Metz explosion [9]. Consequences Twelve people were killed by the blast and the resulting projectiles. Two other people were slightly injured: one in an adjacent workshop and the other inside the malt house enclosure. Damage was bordered on the facility and its surroundings. The tower fell on top of the rail spur leading to the malt house, and eight of the 14 cells were completely destroyed (Figures 4 and 5). An estimate of damage caused by the accident amounted to 16 million dollars. Lessons Learned Beyond the inadequacy of technical devices (insufficient dust removal system and lack of explosion venting), this disaster highlights the fundamental importance of human and organizational factors relative to the execution of hot works. Hot work is a dangerous operation and needs to be performed safely according to written procedures, especially in facilities handling powders and bulk solids. Communication and coordination between operators is crucial when working in hazardous processes. Published on behalf of the AIChE DOI 10.1002/prs March 2012 37 Figure 5. View of the malt house silo before and after the explosion [9]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 6. Schematic depiction of the supposed explosion path [10]. The lack of written safety procedures, hot work permits, and, more generally, the absence of a risk analysis and subsequent prevention/monitoring measures all constitute anomalies that induced this accident. This accident led to the first revision of the silo regulation in France in 1983. Figure 7. View of the damage caused by the Blaye explosion [10]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] conveyor to provide a connection between the vertical silo and an adjoining hangar. The aboveground under-cell space contained 10 chain reclaim conveyors and an air-blowing unit. Silo dust removal was performed by a centralized air suction network set up at several points along the cereal circuit, using a fan positioned in the upper part of the northern handling tower. Blaye, France, 1997 (11 Killed, one Injured) Site Description The Accident The cereal silo was located at the Blaye port complex, on the right bank of the Gironde Estuary, near Bordeaux (south-west of France). It offered a total capacity of 130,000 tons of cereals. The facility was dedicated to handling and storing cereals for maritime export. The silo, built in two segments in 1970 and 1974, was composed of 44 circular reinforced concrete cells, arranged in three rows for a total capacity of 47,240 m3. Two handling towers, one containing bucket elevators and a centralized dust removal circuit (northern tower), and another housing a grading machine and two grain cleaners-separators (southern tower), were connected by an 80-m long, concrete-walled gallery running over the cells and housing conveyor belts. The northern tower was connected directly to both the over-cell gallery and the under-cell space. The over-cell gallery primarily contained three conveyor belts and a material-handling The explosion occurred on August 20, 1997 around 10:15 am, while a dumper truck was unloading corn into a delivery pit. Witnesses reported that the first explosion occurred in the northern handling tower before propagating into the over-cell gallery up to the southern end of this gallery. As no component parts of the centralized dust removal system were found, it is plausible that the explosion began inside. The investigation also led to point out sources internal to the dust removal circuit (mechanical impacts, friction in the fan, or fire caused by self-heating in the dust chamber) as plausible ignition sources. The break downstream of the dust suction fan could have been responsible for the spreading of a large quantity of dust in the northern handling tower. Then the explosion spread to the under-cell part (Figure 6), most likely via the hoppers positioned at the intersection of the two building seg- 38 DOI 10.1002/prs March 2012 Published on behalf of the AIChE Process Safety Progress (Vol.31, No.1) Figure 8. Propagation of the explosion in the DeBruce grain elevator [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] ments, causing a more violent explosion because of their elongated shape. Consequences Eleven people were killed by the explosion (seven employees, three subcontractors, and a fisherman) and one was seriously injured. Ten of the victims were found in the administrative and technical premises, apparently unable to react. The eleventh victim, the fisherman, was found buried underneath rubble on the Gironde riverbank side [10,11]. The vertical silo collapsed over its central and northern parts. Only 16 of the 44 cells were still intact after the accident (Figure 7). The northern handling tower, as well as the immediately adjacent cells, was almost entirely destroyed. The over-cell gallery was totally destroyed; an air extraction fan was found 30 m farther away from the silo. Many projectiles hit nearby storage tanks. Damage to residences was noticed within a 500 m radius away from the silo. Large projectiles (metal, concrete, or glass) were observed at distances of up to a hundred meters farther away from the silo. Lessons Learned This accident shows how much large concrete silos without explosion venting and separation walls represent a serious hazard in case of a dust explosion, as excess of pressure cannot be released in the environment and the resulting secondary dust explosion can easily propagate through the entire plant, causing widespread damage and also fatalities and injuries outside the facility. For this type of old confined facilities, strong prevention measures must be taken (see Best practices section): in particular, an effective housekeeping program is absolutely crucial in order not to fuel the ‘‘primary’’ explosion and lead to a disastrous secondary explosion. The Blaye accident also emphases hazards posed by dust removal systems: as dusts are concentrated at one location, the risk of dust explosion is high and strong safety measures Process Safety Progress (Vol.31, No.1) must be taken, such as prevention of ignition sources (e.g., grounding and bonding to avoid build-up of electrostatic charges) and explosion mitigation (isolation, suppression, and/or venting). This accident resulted in the updating of the regulations dating from 1983 (after the Metz accident) and the proposal of many safety improvements [11], among them the reinforced monitoring of centralized dust removal systems, and also the increase of separation distances between silos and administrative premises. Evolution of the French Regulatory Framework for Facilities Handling Powders and Bulk Solids A new prescriptive regulation framework was set up in France just after the Blaye accident [12]. Nevertheless, these new safety prescriptions were quite strict and often inapplicable to small and medium-scale agricultural facilities. Regarding the difficulties encountered for the application of this regulation framework, a working group was set up by the French Ministry of the Environment, with the strong involvement of companies and technical experts. It led to a new decree asking for a performance-based approach1 [15] and a best practices guide [16]. The best practices guide was designed to give practical advice to deal with fire and explosion hazards in facilities handling powders and bulk solids (such as: design of buildings and equipments, layout, prevention of explosive dust clouds and ignition sources, housekeeping, detection of abnormal conditions, means of protection, and safety organization). This guide is continuously updated by the working group regarding the state of the art. Also high-risk facilities handling powders and bulk solids are regularly inspected and safety reports may be peerreviewed by independent bodies to ensure that the level of protection is appropriate. 1 This decree was slightly modified in February 2007 [13] to take into account the changes introduced by the new approaches of land-use planning and risk analysis in safety reports after the Toulouse accident [14]. Published on behalf of the AIChE DOI 10.1002/prs March 2012 39 Figure 9. Postulated ignition source of the DeBruce grain elevator explosion [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] east side, and used to store maintenance equipment and supplies. Eight warehouse structures were located on the east side of the northern portion of the structure. Dust collection in the facility consisted of two cyclone-type collectors at ground level and a bag-type collector located on top of the truck trailer loading station. A collection bin was located adjacent to the bag collector near the truck station. A dust collector was located on the roof of the headhouse. The Accident Figure 10. Dust accumulation in the DeBruce grain elevator [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] FOCUS ON SOME US PAST ACCIDENTS INVOLVING SECONDARY DUST EXPLOSIONS Haysville, United States of America, 1998 (seven Killed, 10 Injured) Site Description Reported in Guinness Book of Records as the world’s largest grain elevator, the DeBruce Grain elevator was located at Haysville, 4 miles southwest of Wichita, Kansas. It was constructed in 1953 and consisted of a total of 246 concrete silos, each measuring 9.1 m in diameter and 36.6 m in height, for a capacity of 2,464 m3 of grain. The total capacity of the facility was 739,200 m3, for a total length of 823 m. The reinforced concrete headhouse structure located in the center of the facility stood 65.2 m high, and contained four bucket elevators for transporting product to the upper levels of the facility. The conveyor system at this facility consisted of four independent belts (two north and two south). The loading areas consisted of a rail siding on the west side of the facility and a truck loading area on the east side. A building was located alongside the southern half of the facility on the 40 March 2012 Published on behalf of the AIChE The explosion occurred on June 8, 1998, at approximately 9:20 a.m. At the time of the incident, 27 employees, contractors, and drivers were on-site. Witnesses reported hearing several small explosions and then the large blast that seemed to come from the headhouse. The investigation concluded that the initial explosion occurred when dust was ignited in the east tunnel of the south array of silos. Figure 8 shows the propagation of the initial explosion to the overall facility. The most probable ignition source was created when a concentrator roller bearing, which had seized due to no lubrication, caused the roller to lock into a static position as the conveyor belt continued to roll over it, wearing it, and leading to a high temperature rise (Figure 9). Dust accumulation was also pointed out (Figure 10) [17–19]. Consequences Three employees and four subcontractors were killed, whereas three other employees, five contractors and two visitors were injured [19] (Figure 11). The headhouse suffered severe structural damage on all levels (Figure 12). Bucket elevators suffered extensive damage. Several silos suffered major structural damage but did not collapse. Six silos in the north section of the facility had large portions blown out in the blasts, causing the contents of the silos to spill outside the structure. Many silo tops were blown off or displaced during the blast (Figure 13). Lessons Learned This accident is again an example of potential hazards posed by large concrete silos, particularly with underground galleries that cannot be equipped with venting panels: when a dust explosion propagates inside this kind of elongated enclosure, resulting overpressures are quite severe and may lead to extensive damage both inside and outside the facility. In this DOI 10.1002/prs Process Safety Progress (Vol.31, No.1) Figure 11. View of the DeBruce grain elevator after the explosion [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 13. View of the northern gallery after the explosion [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] ards were not sufficiently taken into account by the management of the DeBruce elevator, whereas the facility was daily invaded by dust leaking from the process conveyors2. Port Wentworth, United States of America, 2008 (14 Killed, 36 Injured) A short description of the facility and the accident is given here [20]. More details are available in a recent article published in the Process Safety Progress journal [21]. Figure 12. View of the damage on East side of headhouse [17]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] case, the use of blast proof walls could be advised to avoid explosion propagation to the overall facility, especially between handling towers and galleries. There were also ineffective housekeeping and no detection of conveyor malfunction (hot bearings). The investigation performed by the Grain Elevator Explosion Investigation Team showed that the dust explosion hazProcess Safety Progress (Vol.31, No.1) Site Description The Imperial Sugar Port Wentworth facility was built in the early 1900’s. At the beginning, the facility produced granulated sugar; over the years, the facility added refining and packaging capacity, raw sugar, and product warehouses. It was one of the largest sugar refining and packaging facilities in the United States. Refined sugar was stored in three concrete silos (12 m in diameter, 30 m in height) fed by two belt conveyors and then transferred from silos 1 and 2 by a steel conveyor belt (enclosed by a stainless steel frame but not equipped with dust removal system or explosion vents) to different process areas: 2 ‘‘Some workers testified that on some occasions you could not see your hand in front of your face at arm length’’ [17]. Published on behalf of the AIChE DOI 10.1002/prs March 2012 41 Figure 14. Dust accumulation in Imperial Sugar Port Wentworth facility before the accident [20]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] The explosion was fueled by massive accumulations of combustible sugar dust throughout the packaging building (Figure 14). Consequences This accident caused 14 deaths and injured 38 others, including 14 with serious burns. Buildings were heavily damaged (Figure 15). Lessons Learned Figure 15. View of the damage to the Imperial Sugar Port Wentworth facility [20]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] bulk sugar truck and train loading area, south packing and ‘‘Bosch’’ buildings, and powdered sugar production equipment. A complex system of screw conveyors, bucket elevators, and horizontal conveyor belts transported granulated sugar throughout the packing buildings. Packaged products were palletized and transferred to a warehouse for distribution to customers. The Accident Shortly before 7:15 p.m. on February 7, 2008, a massive explosion shattered the packing buildings and silos. The explosion propagated through packing and palletizer buildings and ignited fires in the refinery and bulk sugar building, tens of meters from the packing buildings where the incident begun. Fireballs erupted from the facility for more than 15 min [20]. CSB concluded that the primary dust explosion most likely occurred in the middle of the silo tunnel: a failure caused the granulated sugar to block the outlet under silos 1 and 2, and then to spill off the moving steel conveyor. The sugar dust accumulated above the minimum explosible concentration and was ignited, probably by a hot bearing inside the enclosed steel belt conveyor. 42 March 2012 Published on behalf of the AIChE Comparing to the other accidents, this one did not involve a large concrete silo. Nevertheless, strong secondary dust explosion still occurred, leading to the death of 14 people and also to widespread damage. The enclosure installed on the steel conveyor created a hazardous confined area and led to this disaster. This accident points out the need of an effective operating feedback and hazards awareness: indeed, although the facility experienced several small fires and explosions in the past and managers were aware of sugar dust explosion hazards, no action was taken to minimize and control these hazards; operators worked in unsafe conditions but did realize, as it was the case for years: it underlines the issue of a very high tolerance to the risks or so-called ‘‘normalization of deviance’’: when you work in a dangerous environment everyday, you may loose your ability to detect hazardous conditions and hence take actions to mitigate the risks. This accident also addresses the difficulties associated with the management of change, as the installation of an enclosure on the steel conveyor belt was not identified as a potential hazard that could lead to an explosion. Once again, housekeeping was not done properly: CSB found that the explosion would likely not have occurred if routine housekeeping was enforced. Other US Accidents Involving Secondary Dust Explosions Plenty of other cases are unfortunately available in the open literature: they show that secondary dust explosions do not only occur in the grain and sugar industries, as could be deducted from the examples developed in this article. As DOI 10.1002/prs Process Safety Progress (Vol.31, No.1) Figure 16. West Pharmaceutical facility destroyed by polyethylene dust explosion [3]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 17. CTA Acoustics’ production area after resin dust explosions [3]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] reported by CSB [3] and Frank [22], many cases were also noticed in the manufacturing (paper, plastic, rubber, textile, and metal), energy (coal, peat, and wood), and chemical (acetate, pharmaceuticals, dyes, and pesticides) industries: • Malden Mills Industries, Methuen, Massachusetts, Decem- • • • • ber 11, 1995 (37 injured): the initial event was likely a dust explosion involving nylon flock fibers. Managers and employees did not understand that the fibers were an explosion hazard before the disaster. This accident shows that dust explosion hazards identification is a critical step, as you cannot protect your facility from a risk you do not know. It is the starting point of a risk analysis that enables to define appropriate prevention and mitigation measures to reduce the risk; Ford Motor Company, Dearborn, Michigan, February 1, 1999 (six killed, 36 injured): although the initial event was a natural gas explosion, strong evidence was found of a secondary coal dust explosion, as coal dust accumulated on horizontal surfaces in the powerhouse. Facility design (presence of flat surfaces) and housekeeping program were found to be inadequate by the Michigan Occupational Safety and Health Administration (MIOSHA); Jahn Foundry, Springfield, Massachusetts, February 25, 1999 (three killed, nine injured): the incident likely involved a resin dust explosion in the shell mold area, spreading through the building due to heavy resin deposits. The underlying causes of the explosion included inadequate design and maintenance of the gas burner system and inadequate housekeeping again; Rouse Polymerics International, Vicksburg, Mississippi, May 16, 2002 (five killed, seven injured): investigation found that hot rubber entrained in the exhaust from product dryers fell onto the building roof, igniting a fire that was pulled into a product bagging bin. A primary fire occurred inside the bagging bin and spread to a screw conveyer, igniting a secondary dust explosion. Occupational Safety and Health Administration (OSHA) pointed out the inadequacy of gas-fired dryers and dust collector design and procedures, housekeeping, the lack of awareness of dust explosion hazards and the ineffective management of change; West Pharmaceuticals (Figure 16), Kinston, North Carolina, January 29, 2003 (six killed, dozens injured): polyethylene dust above a suspended ceiling was suspended in air and ignited, causing a severe secondary dust explosion. CSB pointed out that dust explosion hazard was not addressed during the reviews and electrical equipment was inad- Process Safety Progress (Vol.31, No.1) Figure 18. Fire following aluminum dust explosion at Hayes Lemmerz International [3]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] equate. Once again, this accident highlights the lack of dust explosion hazards recognition and the lack of proper risk analysis, as operators and managers were not aware that fine polyethylene dust could be formed as the rubber dried. Also, it points out the practical difficulties to perform an efficient housekeeping, as the dust accumulated above a drop ceiling, so it was hidden from view. New facilities should be designed for easy effective cleaning and avoidance of elevated flat surfaces (see NFPA 654), where it is difficult for operators to capture dust or even see it; • CTA Acoustics (Figure 17), Corbin, Kentucky, February 20, 2003 (7 killed, 37 injured): curing oven left open likely caused ignition of combustible resin dust stirred up by workers cleaning the area near the oven, causing multiple explosions. This accident hightlights the lack of communication and coordination between operators working at the same hazardous place. Facility design was not adequate (presence of flat surfaces, no firewalls between process units), housekeeping was not sufficient and inadequately done using compressed air; Published on behalf of the AIChE DOI 10.1002/prs March 2012 43 Table 1. Measures for the prevention of explosive dust clouds. Functional Requirements Measures Minimize dust cloud formation Minimize dust explosibility Minimize dust layers formation Grain cleaning before storage Oil adding systems Use of lower mass flow rates [16] Prevention of process leakages: sealing and dust removal (NFPA 654) Reduction of dust emission at chutes (Holbrow et al. [26], Wheeler et al. [27]) Collect of dust leaks (capture hoods, ‘‘elephant trunks’’) Use of bigger particle size Control that dust concentration is below the Minimum Explosive Concentration (NFPA 654 [24]) Inerting (NFPA 654, EN 15281 [25]) Avoidance of elevated flat surfaces (NFPA 654, [16]) Implementation of a good housekeeping program (NFPA 654) Figure 19. Enclosed conveyor [28]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] • Hayes Lemmerz International (Figure 18), Huntington, Indiana, October 29, 2003 (one killed, several injured): CSB found that explosion likely originated in a dust collector and spread through ducting, causing a large fireball to emerge from the furnace. Dust collector was not adequately vented or isolated from other parts of the process. Also housekeeping was not implemented and no lessons were learned from previous accidents. BEST PRACTICES TO PREVENT SECONDARY DUST EXPLOSIONS OR MITIGATE THEIR EFFECTS Safety measures can be classified in three main classes [23]: • prevention of explosive dust cloud; • prevention of ignition sources; • explosion mitigation. Figure 20. Dust removal system [28]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Prevention of Explosive Dust Clouds Table 1 presents some practical solutions to prevent explosive dust clouds; as examples: reduction of mass flow rates of conveyor systems and use of special devices at chutes can greatly minimize dust cloud formation; use of bigger particle size can sharply minimize dust explosibility and explosion strength (also big particles are less easily airbone and remain a shorter time in the air than small ones). Decrease of oxygen concentration (i.e. inerting) is effective as well theoretically, but remains difficult to achieve practically (only for particular processes and small volumes). The following paragraphs give an overview of current prevention and protection techniques that could be used against dust explosions, based on recognized and generally accepted good engineering practices, coming from standards and professional guidelines, and develop those which were particularly highlighted by the reviewed accidents. Also, as secondary dust explosions cannot develop if there is no fuel (i.e., dust layers), important prevention measures consist of prevention of leakages and a good housekeeping program. Equipments should be dust-tight (Figure 19) and equipped with a dust removal system (Figure 20) when an explosive dust cloud can form inside (it is particularly true for bucket elevators, conveyor systems and at transfer/discharge points), 44 DOI 10.1002/prs March 2012 Published on behalf of the AIChE Process Safety Progress (Vol.31, No.1) Figure 21. The potential hazards of thin dust layers [1]. Figure 23. When disappearing, white crosses indicates significant dust accumulation. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 22. Large-scale gallery used by Tamanini [29]. • to limit the extent of dust migration, and hence the size of the room that must be cleaned; to avoid a dust explosion inside the equipment, like what occurred in the steel conveyor belt of the Imperial Sugar Port Wentworth facility. Also, operators must check as frequently as possible if there are no fugitive sources in the facility and take actions to avoid them. As leakages cannot be completely eradicated, housekeeping is very important. According to Eckhoff [1], even a 1-mm layer of a dust of bulk density 500 kg/m3 on the floor of a 5-m high room may generate a cloud of average concentration 100 g/m3 if dispersed all over the room, or a cloud of average concentration 500 g/m3 if partially dispersed up to 1 m above the floor (Figure 21). Moreover, Tamanini [29] carried out a series of cornstarch explosion tests in a full-scale gallery (2.4 m height, 2.4 m width, and 24.4 m long) and showed that a flame only needs a very small amount of dust (77 g/m3 for a smooth, unobstructed gallery, corresponding to a layer of cornstarch 1/100 inch thick) to propagate, as the dust can be dispersed only in the lower part of a volume and therefore gives higher explosive dust concentrations (Figure 22). These experiments highlight the need of good housekeeping practices. Frank and Holcomb [30] provided some general guidance to deal with dust leakages and dust accumulation, which are reproduced here: • to design, maintenance, and operate equipments to minimize dust emissions; • to capture dust at the release point; Process Safety Progress (Vol.31, No.1) • to design facilities for easy effective cleaning (no flat elevated surfaces, see for example Ford Motor Company, West Pharmaceutical and lastly CTA Acoustics accidents); • to establish and enforce housekeeping (see the Imperial Sugar Port Wentworth example), by defining schedules and responsibilities; • to ensure that housekeeping programs comprehensively address all areas where combustible dust may accumulate; • to ensure that housekeeping is safely conducted. Very simple indicators, such as white crosses on the floor (Figure 23), can be used to detect dust accumulation. Also if you can write your name in the accumulated dust, a combustible dust hazard is likely to be present. Prevention of Ignition Sources Table 2 presents some practical solutions to prevent ignition sources. PR EN 1127-1 [38] distinguishes 13 different types of ignition sources. According to Figure 24, mechanically generated sparks (25%), smoldering fires (11%), mechanical heating and friction (9%), and electrostatic charges (9%) are the most likely in the process industries. By reviewing the four major accidents presented in the first sections, conveyors (hot bearings, i.e. mechanical heating) were implied in two of them (DeBruce grain elevator and Imperial Sugar Port Wentworth facility explosions), whereas dust removal systems (mechanically generated sparks) were involved in the two others (Metz and Blaye explosions). This Published on behalf of the AIChE DOI 10.1002/prs March 2012 45 Table 2. Measures for the prevention of ignition sources. Functional Requirements Avoid/control ignition sources Measures Mechanical and electrical equipments adapted to hazardous locations (NFPA 499 [31], NFPA 70 [32], ATEX European Directives [33,34]) Limitation of the use of low resistivity materials; bonding and grounding (NFPA 77 [35]) Maintenance of equipments to avoid friction, hot surfaces (NFPA 654, [16]) Detection of conveying equipments and dust removal systems malfunction [16] Control of hot surfaces (engine protection, thermal insulation) [16] Delivery pits covered with grates with small openings [16] Use of magnetic separators [16] Detection of hot particles [16] Lightning protection (NFPA 780 [36]) Fire prevention and protection (fireproof belts, fire detectors, extinguishers) [16] Hot work permit for welding, cutting, hot tapping (NFPA 654, NFPA 51B [37]) No smoking [16] Figure 24. Type of ignition sources involved in dust explosions in the Federal Republic of Germany (1965-1985, 426 dust explosions in total) [1]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 25. Type of plant/equipment involved in dust explosions in the Federal Republic of Germany (1965-1985, 426 dust explosions in total) [1]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] tendency is also well illustrated by Figure 25, which shows that dust collecting systems are involved in 17% of dust explosions (10% for conveying systems). It emphasizes the need to correctly monitor the operation of critical equipments (Figures 26 and 27 give examples of control devices that can be used for a belt con- 46 DOI 10.1002/prs March 2012 Published on behalf of the AIChE Process Safety Progress (Vol.31, No.1) Figure 26. Belt displacement control device [27]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Figure 27. Rotation control device [27]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Table 3. Measures for explosion mitigation. Functional Requirements Limit the consequences of a primary explosion Avoid the propagation of the primary explosion Limit the consequences of a secondary explosion Measures Venting (NFPA 68 [39], EN 14491 [40], EN 14797 [41]): bursting disks, venting panels, vent ducts, explosion doors, light construction [16] Explosion extinguishing systems: powder, water (NFPA 69 [42], EN 14373 [43]) Explosion resistant equipment (NFPA 69, EN 14460 [44]) Explosion isolation between vessels (NFPA 69, EN 15089 [45]): acting valve (PR EN 16009 [46]), diverter (PR EN 16020 [47]), rotary lock (Siwek [48]), screw conveyor, triggered barriers (Lebecki et al. [49]) Flame arresters (PR EN ISO 16852 [50]) Layout/unit segregation (NFPA 654, [16]) Explosion isolation between parts of a building (blast proof walls) [16] Venting [28] veyor). Process interlock should be used to forbid running operations when safety devices are not operational. Also attention must be paid to preventative maintenance (lubrification, infrared thermography) and hot work permit. Explosion Mitigation Table 3 presents some practical solutions to mitigate explosions, such as: using venting techniques (release of the excess of pressure in the environment), extinguishing systems or explosion resistant equipments to limit the consequences of a primary explosion; installing explosion isolation systems (valves, rotary locks. . .) and flame arresters to avoid the propagation of the primary explosion. Also, since severe dust explosions are often characterized by flame propagation through elongated volumes, the use of blast proof walls could be advised to avoid explosion propagation to the overall facility, especially between handling towers and galleries (see Metz, Blaye, and DeBruce explosion cases), as shown on Figure 28. Process Safety Progress (Vol.31, No.1) The use of open or light constructions (i.e. the avoidance of reinforced concrete and underground structures), as well as the siting of equipments outside the buildings (particularly for bucket elevators), can limit the resulting damage in case of explosion. Also, Tamanini [28] showed that venting a primary explosion in a gallery could be effective at reducing explosion overpressure and sometimes preventing flame propagation. Nevertheless, as it is not always true, this technique must be associated with blast proof walls or triggered barriers to be effective. Finally, it is indispensable to move away administrative and technical premises from hazardous locations: indeed, in the Blaye accident, most of the victims were in the administrative premises. Example of Prevention and Mitigation Principles Applied to a Dust Collector Review of accidents, and also statistical data (Figure 25), showed that dust collectors are among the most hazardous equipments in a facility handling powders or bulk solids. So strong prevention and protection measures must be taken to avoid a primary dust explosion in this kind of equiment, and/ or to avoid its propagation to the overall plant. Published on behalf of the AIChE DOI 10.1002/prs March 2012 47 Bonding and grounding should be considered to reduce the hazards of static electricity accumulation. Also IR detectors (1) should be installed so that hot particles cannot be sucked up by the dust collector and then provoke a fire and/or an explosion. Regarding explosion protection, several measures could be applied to a dust collector inside a building (Table 4, Figure 29): venting panel(s) (2) and/or extinguishing system(s) (3) should be installed to limit the maximum pressure inside the equipment in case of explosion; also, dust collector must be isolated from other process equipments in order to avoid propagation of a primary dust explosion. This could be achieved by installing a rotary lock (4) on ducting between the collector and the associated dust storage chamber, and an acting valve (5) on ducting between the collector and the process equipment (activated by pressure sensors for example). Figure 28. Blast proof walls between a gallery and a handling tower [27]. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] Dust collector should also be put in an area apart from the rest of the facility or separated by fire/blast walls to avoid escalation events in case of an accident. After that attention must be paid on the protection of the dust collector itself with an extinguishing system and a venting panel. Of course, prevention is also highly important and all prevention measures that are applicable must be considered: the most important are detection of hot particles by IR detectors (1), bonding and grounding. CONCLUSIONS Secondary dust explosions can have dramatic consequences, as shown from past accidents reviewed in this article. Numerous techniques exist to prevent secondary dust explosions or mitigate their effects; the most critical ones have been presented which are, from the author’s point of view: prevention of leakages, housekeeping, design and monitoring of equipments, separation of large volumes using blast proof walls, venting, and appropriate layout. Nevertheless, technical measures are not sufficient as major accidents are always a combination of technical and organizational failures. As a proof, reviewed accidents showed the preponderant rule of operators and managers in dust explosion occurrence. The development of a company’s safety culture is a key issue: operators must understand the risks related to the handling of powders and bulk solids to adapt their behavior at workplace and be involved in early detection of process deviances. They must as well be trained to properly react in case of an incident (see Imperial Sugar example). The reviewed accidents also emphasize the crucial importance of a serious involvement of the management to take action. When working in a hazardous plant, maybe the highest risk is the ‘‘normalization of deviance’’: when you work in a dangerous environment everyday, you may loose your ability to detect hazardous conditions and hence take actions to mitigate the risks. Dust explosions that occured in the past remind us that disasters can quickly occur if companies do not pay enough attention and accept abnormal and unsafe work conditions. As an example, in France, a performance-based regulation framework has been set up after the Blaye accident in 1997, to give more flexibility to companies to adapt safety measures to their own type of activities. This framework was accompanied by a best practices guide written with the help of technical experts to provide practical advice to deal with fire and explosion hazards in facilities handling powders and bulk solids. Also high-risk facilities handling powders and bulk solids are regularly inspected and safety reports may be peerreviewed by independent bodies to ensure that the level of protection is appropriate. This process seems to give fruitful results, as from this time, the number of serious incidents has significantly decreased. Table 4. Example of main prevention and mitigation measures for a dust collector Prevention Measures Mitigation Measures Bonding Grounding Preventive maintenance Detection of hot particles by IR detectors (1) 48 March 2012 Published on behalf of the AIChE Venting panel with a venting duct and a flame arrester (2) Extinguishing system with water or chemical powder (3) Isolation with a rotary lock (4) Isolation with an acting valve (5) Unit segregation from other process area DOI 10.1002/prs Process Safety Progress (Vol.31, No.1) Figure 29. Illustration of prevention and mitigation measures for a dust collector. [Color figure can be viewed in the online issue, which is available at wileyonlinelibrary.com.] LITERATURE CITED 1. R.K. Eckhoff, Dust explosions in the process industries, Gulf Professional Publishing, 2003, Elsevier Science, USA. 2. T. Abbasi and S.A. Abbasi, Dust explosions: cases, causes, consequences, and control, J Hazard Mater 140 ( 2007), 7–44. 3. Chemical Safety Board, Combustible dust hazard study, Report n82006-H-1, 2006. 4. Chemical Safety Board, Dust explosion (6 killed, 38 injured), West Pharmaceutical Services, Inc., Kinston, North Carolina, January 29, 2003, Report No. 2003–07-INC, 2004. 5. Chemical Safety Board, Combustible dust fire and explosions (7 killed, 37 injured), CTA Acoustics, Inc., Corbin, Kentucky, February 20, 2003, Report No. 2003–09-I-KY, 2005. 6. Chemical Safety Board, Aluminium dust explosion and fire (1 killed, 6 injured), Hayes Lemmerz International, Inc., Huntington, Indiana, October 29, 2003, Report No. 2004–03-I-IN, 2005. 7. V. Ebadat, Managing dust explosion hazards, Chem Eng Prog 105 (2009), 35–39. 8. R. Zalosh, S.S. Grossel, R. Kahn, and D.E. Sliva, Safely handle powdered solids, Chem Eng Prog 101 (2005), 23–30. 9. Analyse, Recherche, et Information sur les Accidents (ARIA), Explosion dans un silo d’une malterie, le 18 Octobre 1982, Metz (Moselle), France, Ministe`re charge´ de l’environnement—DPPR/SEI/BARPI, fiche n88781, Available at: http://www.aria.developpement-durable. gouv.fr, 2009. Accessed on March 2011. 10. Analyse, Recherche, et Information sur les Accidents (ARIA), Explosion d’un silo de ce´re´ales, le 20 Aouˆt 1997, Blaye (Gironde), France, Ministe`re charge´ de l’environnement—DPPR/SEI/BARPI, fiche n811657, Available at: http://www.aria.developpement-durable.gouv.fr, 2008. Accessed on March 2011. 11. F. Masson, Explosion d’un silo de ce´re´ales, Blaye (33)— Rapport de synthe`se, INERIS, 1998. 12. Arreˆte´ du 29 juillet 1998 relatif aux silos et aux installations de stockage de ce´re´ales, de graines, de produits alimentaires ou de tous autres produits organiques de´gageant des poussie`res inflammables. Process Safety Progress (Vol.31, No.1) 13. Arreˆte´ du 23 fe´vrier 2007 modifiant l’arreˆte´ du 29 mars 2004 relatif a` la pre´vention des risques pre´sente´s par les silos de ce´re´ales, de grains, de produits alimentaires ou de tous autres produits organiques de´gageant des poussie`res inflammables. 14. J. Taveau, Risk assessment and land-use planning regulations in France following the AZF disaster, J Loss Prev Process Ind 23 (2010), 813–823. 15. Arreˆte´ du 29 mars 2004 relatif a` la pre´vention des risques pre´sente´s par les silos de ce´re´ales, de grains, de produits alimentaires ou de tout autre produit organique de´gageant des poussie`res inflammables. 16. Ministe`re de l’Ecologie, de l’Energie, du De´veloppement Durable et de l’Ame´nagement du Territoire, Guide de l’e´tat de l’art sur les silos pour l’application de l’arreˆte´ ministe´riel relatif aux risques pre´sente´s par les silos et les installations de stockage de ce´re´ales, de grains, de produits alimentaires ou de tout autre produit organique de´gageant des poussie`res inflammables, Version 3, 2008. 17. V.L. Grose, Report on explosion of DeBruce grain elevator, Wichita, Kansas, 8 June 1998, Grain Elevator Explosion Investigation Team (GEEIT), 1999. 18. Fire investigation summary—Grain elevator explosion— Haysville, Kansas, June 8, 1998, National Fire Protection Association (NFPA), Fire Investigations Department, 1999. 19. C.W. Kauffman, The DeBruce grain elevator explosion, 7th International Symposium on Hazards, Prevention and Mitigation of Industrial Explosions (ISHPMIE) Proceedings, Vol. 3, pp. 3–26, Saint-Petersburg, Russia, July 7–11, 2008 1999. 20. Chemical Safety Board, Sugar dust explosion and fire (14 killed, 36 injured), Imperial Sugar Company, Port Wentworth, Georgia, February 7, 2008, Report No. 2008–05-IGA, 2009. 21. J.B. Vorderbrueggen, Imperial Sugar refinery combustible dust explosion investigation, Process Safety Prog 30 (2011), 66–81. 22. W.L. Frank, Dust explosion prevention and the critical importance of housekeeping, Process Safety Prog 23 (2004), 175–184. 23. R.K. Eckhoff, Dust explosion prevention and mitigation, Status and developments in basic knowledge and in practical application, Int J Chem Eng 2009 (2009), 12. 24. NFPA 654, Standard for the prevention of fire and dust explosions from the manufacturing, processing, and handling of combustible particulate solids, 2006. 25. FC CEN/TR 15281, Explosives atmospheres—Inerting guide for explosion prevention, 2006. 26. P. Holbrow and A. Tyldesley, Simple devices to prevent dust explosion propagation in charge chutes and pipes, J Loss Prev Process Ind 16 (2003), 333–340. 27. C. Wheeler, T. Krull, A. Roberts, and S. Wiche, Design of ship loading chutes to reduce dust emissions, Process Safety Prog 26 (2007), 229–234. 28. Syndicat National des Fabricants de Sucre (SNFS), Guide professionnel de l’e´tat de l’art sur la se´curite´ dans les silos a` sucre, 2008. 29. F. Tamanini, Dust explosion propagation in simulated grain conveyor galleries, Technical Report FMRC J.I. OFIR2.RK. National Grain and Feed Association, Washington, D.C., 1983. 30. W.L. Frank and M.L. Holcomb, Housekeeping solutions, Dust explosion hazard recognition and control: new strategies, Kansas City, MO, October 20–21, 2010. 31. NFPA 499, Recommended practice for the classification of combustible dusts and hazardous (classified) locations for electrical installations in chemical process areas, 2008. 32. NFPA 70, National electrical code, 2011. 33. Directive 1999/92/EC of the European Parliament and of the Council of 16 December 1999 on minimum requirements for improving the safety and health protection of Published on behalf of the AIChE DOI 10.1002/prs March 2012 49 34. 35. 36. 37. 38. 39. 50 workers potentially at risk from explosive atmospheres, Official Journal of European Community. Directive 94/9/EC of the European Parliament and the Council of 23 March 1994 on the approximation of the laws of the Member States concerning equipment and protective systems intended for use in potentially explosive atmospheres, Official Journal of European Community. NFPA 77, Recommended practice on static electricity, 2007. NFPA 780, Standard for the installation of lightning protection systems, 2011. NFPA 51B, Standard for fire prevention during welding, cutting, and other hot work, 1999. PR EN 1127–1, Explosives atmospheres—Explosion prevention and protection—Part 1: basic concepts and methodology, 2011. NFPA 68, Standard on explosion protection by deflagration venting, 2007. 40. EN 14491, Dust explosion venting protective systems, 2006. 41. EN 14797, Explosion venting devices, 2007. 42. NFPA 69, Standard on explosion protection systems, 2009. 43. EN 14373, Explosion suppression systems, 2006. 44. EN 14460, Explosion resistant equipment, 2006. 45. EN 15089, Explosion isolation systems, 2009. 46. PR EN 16009, Flameless explosion venting devices, 2011. 47. PR EN 16020, Explosion diverters, 2011. 48. R. Siwek, New knowledge about rotary air locks in preventing dust ignition breakthrough, Plant/Oper Prog 8 (1989), 165–176. 49. K. Lebecki, J. Sliz, K. Cybulski, and Z. Dyduch, Efficiency of triggered barriers in dust explosion suppression in galleries, J Loss Prev Process Ind 14 (2001), 489–494. 50. PR EN ISO 16852, Flame arresters—Performance requirements, test methods and limits for use, 2010. March 2012 DOI 10.1002/prs Published on behalf of the AIChE Process Safety Progress (Vol.31, No.1)
© Copyright 2024