MSDS SHEETS FOR CHANCE HOTLINE TOOL & BOOM CLEANING KIT – C400-2365 CONSISTS OF: Moisture Eater II – 1 Gallon Hot Stick Wiping Cloth Gloss Restorer - Part A Gloss Restorer - Part B Abrasive Cleaning Pads C400-2364 M1904 C400-1520 C400-1520 C400-1166 HUBBELL CANADA LP MATERIAL SAFETY DATA SHEET Date of Preparation/Revision: February 01, 2005 1. PRODUCT INFORMATION FOR: USE: CLEANER HOT LINE TOOL & BOOM CLEANER (MOISTURE EATER II) C400-2364, C400-2538 & C400-2551 WHMIS CLASS(ES): B3, D2B Manufacturer's Name: A. B. Chance Company Supplier's Name: Hubbell Canada LP Street Address: 210 North Allen Street Street Address: 870 Brock Road South City or Town: Centralia City or Town: Pickering Province or State: Missouri, USA Province or State: Ontario, Canada Postal/Zip Code: 65240 Postal/Zip Code: L1W 1Z8 Telephone Number: 573-682-5521 Telephone Number: 905-839-1138 1-800-263-4622 Emergency Telephone Number: Chemical Emergency Only Telephone Number: CANUTEC call collect 24 hours (613) 996-6666 573-682-8465 2. HAZARDOUS INGREDIENTS Hazardous Ingredient % CAS Number LD50 LC50 TLV1 Diacetone alcohol 40-70 123-42-2 n.av. 50 ppm d-Limonene 15-40 58-27-5 2520 mg/kg (oral rat) 500 mg/kg n.av. (oral, rat) n.av. 1 Consult local authorities for acceptable limits. Page 1 of 6 3. PHYSICAL DATA Physical State: Odor and Appearance: liquid mild pleasant orange odour, colourless liquid Odor Threshold: n.av. Specific Gravity: approximately 0.8973 ( at 20°C) Vapor Pressure: approximately 7.1 mm Hg at 154 °C Vapor Density: >1 Evaporation Rate: 1.6 (n butyl acetate = 1) Boiling Point [°C]: 136.7°C Freezing Point [°C]: < - 40 °C pH: n.av Coefficient of Water/Oil Distribution: n.av 4. FIRE AND EXPLOSION HAZARD Flammability: combustible liquid Means of Extinction: “alcohol” foam, carbon dioxide, dry chemical, water spray Flash Point and Method: 43.9 TCC Upper Flammable Limit [% by volume]: Diacetone alcohol d-Limonene 6.9 n.av Lower Flammable Limit [% by volume]: Diacetone alcohol d-Limonene 1.8 n.av Auto ignition Temperature [°C]: Diacetone alcohol d-Limonene 643 (acetone free) n.av Hazardous Combustion Products: Carbon dioxide, carbon monoxide Page 2 of 6 Explosion data: a. Sensitivity to impact: b. Sensitivity to static discharge: No no - NB Diacetone alcohol at temperatures above 50°C in the presence of catalytic amounts of alkaline substances reverts to acetone, which is a flammable liquid. 5. REACTIVITY DATA Chemically Stable: Under normal conditions material is stable. Please note comments under sensitivity static discharge Incompatibility With Other Substances: This material can react dangerously with amines, strong oxidizers (eg. Hydrogen peroxide, nitric acid), pyridines, ammonia, isocyanates, inorganic acids, and caustics. Will react explosively with iodine pentafluoride and tetrafluoroethylene. Avoid polymerization catalysts such as aluminium chloride. Hazardous Decomposition Products: Thermal oxidation degradation of this product can produce toxic gases such as carbon monoxide, mesityl oxide, and partial oxidation products. Hazardous Polymerization: Does not occur. 6. TOXICOLOGICAL PROPERTIES Route of Entry: Skin Contact: May cause temporary local reddening and itching. Prolonged contact may cause defatting the tissue, which can subsequently lead to dermatitis. Skin Absorption: No evidence of adverse effects from the literature available. Eye Contact: Immediate stinging and pain with reddening and possible swelling of the conjunctiva. Excess tear formation and blinking. Page 3 of 6 Inhalation: High vapour concentrations are irritating to the upper respiratory tract, which can be experienced as nasal discomfort and discharge. Coughing and chest discomfort can result (similar to symptoms as described in ingestion). Ingestion: Product is moderately toxic. May cause abdominal discomfort, nausea, diarrhea, dizziness, drowsiness, fainting, lack of coordination, kidney damage secondary to red blood cell breakdown and liver damage may occur. Irritancy of Product: Primary irritant - refer to the above information. Sensitization of product: Refer to the above information. Carcinogenicity of product: This product is not known to be (NTP, IARC or OSHA). Teratogenicity of product: Not known to be a teratogen. Mutagenicity of product: RTECS report mutagenicity data on d limonene Reproductive toxicity: Not known to have reproductive toxicity. Synergistic products: None known. Effects of acute exposure: Irritation of eyes, nose and throat. Either prolonged or repeated skin contact with product can cause defatting of the skin, which can lead to dermatitis. Effects of chronic exposure: Based on animal data, may lead to kidney damage. 7. PREVENTIVE MEASURES: Personal Protective Equipment: Gloves: Butyl rubber or Neoprene. Respirator: In high concentrations use NIOSH or self contained breathing apparatus. Eye: Chemical safety goggles. Footwear: Impervious boots. Page 4 of 6 Clothing: Wear butyl rubber or Neoprene apron and/or overall. Other: Eye bath and safety shower should be close at hand. Engineering Controls: All mechanical and electrical equipment should be explosion proof. Adequate ventilation should be used to keep air concentrations below TLV. Leak and Spill Procedures: Evacuate unnecessary personnel. Eliminate all possible sources of ignition. Provide good ventilation of the area. Personnel dealing with spill should immediately don the proper protective equipment. Dike with absorbent to prevent entry into sewers, storm ditches and waterways. Sweep up absorbent with spark proof equipment and place in a proper disposal drum. Waste Disposal: Dispose of in accordance with all municipal, provincial and federal regulations. Handling Procedures and Equipment: Refer also to Engineering Controls. Do not apply to hot surfaces or live electrical equipment. Do not pressure containers. Do not cut, heat or weld empty containers. Keep containers closed when not being used. Storage Requirements: Store closed containers in a cool, dry, wellventilated area away from all sources of ignition. Do not store in direct sunlight. Specific Shipping Information: Flammable Liquid, N.O.S. (Diacetone alcohol) UN 1993 – Class 3 PG III 8. FIRST AID MEASURES Eye Contact: Page 5 of 6 Holding eyelids well apart, flush with running water for at least 15 minutes. Seek medical attention. Skin Contact: Remove any contaminated clothing. Flush with running water for at least 15 minutes. Wash with soap and water. If any aeration persists get medical attention. Inhalation: Remove to fresh air. If breathing has stopped apply artificial respiration. Seek medical attention. Ingestion: Have victim drink two glasses of water. Do not induce vomiting. Get immediate medical attention. 9. PREPARATION OF THE MATERIAL SAFETY DATA SHEET Prepared By: John R. Turner, Chemical Safety Consultant for Hubbell Power Systems. Telephone Number: Fax Number: 905-884-3869 905-770-9014 Date of Preparation: February 01, 2005 10. SOURCES USED • • • • • • • Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 2004, ACGIH. Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, ACGIH. Dangerous Properties of Industrial Materials, Sax, Ninth Edition Registry of the Toxic Effects of Chemical Substances, (RTECS), U.S. Department of Health & Human Services [NIOSH] [CD-ROM]. Hawley’s Condensed Chemical Dictionary, Eleventh Edition. OSHA Chemical Safety Database NTP 10th Report on Carcinogens (2002) 11. WHMIS SYMBOL(S) THAT SHOULD APPEAR ON THE WARNING LABEL FOR THIS PRODUCT. Page 6 of 6 HUBBELL CANADA LP MATERIAL SAFETY DATA SHEET Date of Preparation: February 01, 2005 1. PRODUCT INFORMATION FOR: USE: WIPING CLOTH HOT STICK WIPING CLOTH – M1904 WHMIS CLASS(ES): THIS IS NOT A CONTROLLED PRODUCT. Manufacturer's Name: A. B. Chance Company Supplier's Name: Hubbell Canada LP Street Address: 210 North Allen Street Street Address: 870 Brock Road South City or Town: Centralia City or Town: Pickering Province or State: Missouri, USA Province or State: Ontario, Canada Postal/Zip Code: 65240 Postal/Zip Code: L1W 1Z8 Telephone Number: 573-682-5521 Telephone Number: 905-839-1138 1-800-263-4622 Emergency Telephone Number: 573-682-8465 Chemical Emergency Telephone Number: CANUTEC call collect 24 hours (613) 996-6666 2. HAZARDOUS INGREDIENTS This product does not contain any hazardous ingredients as defined by the Controlled Products Regulations. 3. PHYSICAL DATA Physical State: Solid Odor and Appearance: brownish, wet looking cloth, no odour Odor Threshold: n.ap. Specific Gravity: 1.289 Vapor Pressure: >5 mm Hg @ 25°C Vapor Density: n.ap. Page 1 of 5 Evaporation Rate: < 1( ether =1) Boiling Point [°C]: >149° Freezing Point [°C]: n.ap. pH: n.ap. Coefficient of Water/Oil Distribution: n.av. % Volatile by Volume: <0.5% 4. FIRE AND EXPLOSION HAZARD Flammability: no Flash Point [°C] and Method: n.ap. Upper Flammable Limit [% by volume]: n.ap. Lower Flammable Limit [% by volume]: n.ap. Auto ignition Temperature [°C]: >500°C (cloud) Hazardous Combustion Products: Though low in combustibility, the product will burn at high temperature, producing SiO2 smoke in addition to oxides of carbon. When heated in air (without burning), for example at 200-300°C, it slowly evolves formaldehyde. Explosion data: a. Sensitivity to impact: No b. Sensitivity to static discharge: No 5. REACTIVITY DATA Chemically Stable: Yes Incompatibility With Other Substances: Strong oxidizing agents. Hazardous Decomposition Products: Silicon dioxide, carbon dioxide, incompletely burned carbon products. Hazardous Polymerization: Will not occur. Page 2 of 5 6. TOXICOLOGICAL PROPERTIES Summary of Risks: This material is considered to be non-toxic. Ingestion of large amounts of silicone would be expected to have a laxative effect. This is unlikely, however, very small amounts may be ingested if user failed to wash hands before eating. The fluid and cotton thread can be irritating in the eye until removed. When heated at high temperature, fumes and oxidation products can be irritating and toxic. Route of Entry: Skin Contact: No evidence of adverse effects from available information. Skin Absorption: No evidence of adverse effects from available information. Eye Contact: May cause mild irritation in some people. Inhalation: No evidence of adverse effects from available information. Fluid can act as a laxative. Ingestion: Irritancy of Product: Mild eye irritant. Sensitization of product: Not know to be a sensitizer. Carcinogenicity of product: Not known to be. Teratogenicity of product Not known to be teratogen. Mutagenicity of product: Not known to be a mutagen. Reproductive toxicity: Not known to have reproductive toxicity. Synergistic products: None known. Effects of acute exposure: May cause mild irritation of eyes in some people. Effects of chronic exposure: Not known. 7. PREVENTIVE MEASURES: Personal Protective Equipment: Gloves: Plastic. Respirator: Not required. Eye: Use of safety glasses/goggles recommended to prevent eye irritation. Page 3 of 5 is Footwear: As required in work area. Clothing: As required in work area. Other: Eyewash stations and washing facilities should be available. Engineering Controls: No special controls are required. Leak and Spill Procedures: Dispose of used cloths in flame resistant container. Waste Disposal: In accordance to all government regulations. Handling Procedures and Equipment: No special procedures - use good industrial hygienic practices Storage Requirements: No special storage requirements. Specific Shipping Information: This product is not classified under Transportation of Dangerous Goods Regulations, or under the US Title 49 CFR. 8. FIRST AID MEASURES Eye Contact: Holding eyelids well apart flush eye with large amounts of water for 15 minutes. Get medical attention if irritation persists. Skin Contact: Wash well with soap and water. If any irritation persists, get medical attention. Inhalation: Remove to fresh air. Apply artificial respiration if necessary. If there is any discomfort, seek medical attention. Ingestion: If laxative symptoms persist, consult a physician. Not known adverse chronic health effects, but unnecessary exposure to any chemical should be avoided. This product, as with any chemical, may enhance allergic conditions with certain people. 9. PREPARATION OF THE MATERIAL SAFETY DATA SHEET Prepared By: John R. Turner, Chemical Safety Consultant for Hubbell Canada Inc. Telephone Number: Fax Number: 905-884-3869 905-770-9014 Date of Preparation: February 01, 2005 Page 4 of 5 10. SOURCES USED • • • • • • • Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 2004, ACGIH. Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, ACGIH. Dangerous Properties of Industrial Materials, Sax, Ninth Edition Registry of the Toxic Effects of Chemical Substances (RTECS), U.S. Department of Health & Human Services [NIOSH] Hawley’s Condensed Chemical Dictionary, Eleventh Edition. OSHA Chemical Safety Database NTP 10th Report on Carcinogens (2002) 11. WHMIS SYMBOL(S) THAT SHOULD APPEAR ON THE WARNING LABEL FOR THIS PRODUCT None required for this product. Page 5 of 5 HUBBELL CANADA LP MATERIAL SAFETY DATA SHEET Date of Preparation: February 01, 2005 1. PRODUCT INFORMATION FOR: CHANCE GLOSS RESTORER – PART A C400-1520 USE: GLOSS RESTORER WHMIS CLASS(ES): B2, D2B Manufacturer's Name: A. B. Chance Company Supplier's Name: Hubbell Canada LP Street Address: 210 North Allen Street Street Address: 870 Brock Road South City or Town: Centralia City or Town: Pickering Province or State: Missouri, USA Province or State: Ontario, Canada Postal/Zip Code: 65240 Postal/Zip Code: L1W 1Z8 Telephone Number: 573-682-5521 Telephone Number: 905-839-1138 1-800-263-4622 Emergency Telephone Number: 573-682-8465 Emergency Telephone Number: CANUTEC call collect 24 hours (613) 996-6666 2. HAZARDOUS INGREDIENTS Hazardous Ingredient % CAS Number LD50 LC50 TLV1 Xylene 43 - 47 1330-20-7 4.3 g/kg (oral, rat) 6350 ppm (4 hr. rat) 100 ppm Light aromatic naphtha 16 - 20 64742-95-6 8.4 g/kg n.av. n.av. >6000 ppm (6 hr. rat) 20 ppm (oral,rat) Ethylene glycol propyl ether 1 23 - 27 2807-30-9 3.1 g/kg (oral, rat) Consult local authorities for acceptable limits. 3. PHYSICAL DATA Physical State: Page 1 of 6 liquid Odor and Appearance: typical aromatic odour, yellow viscous liquid Odor Threshold: n.av. Specific Gravity: 0.996 Vapor Pressure: n.av. Vapor Density: n.av. Evaporation Rate: n.av. Boiling Point [°C]: 66 - 173 Freezing Point [°C]: n.ap. pH: n.ap. Coefficient of Water/Oil Distribution: n.av. 4. FIRE AND EXPLOSION HAZARD Flammability: Flammable liquid - WHMIS Class B2 Means of Extinction: Foam, carbon dioxide, dry chemical, water, fog Flash Point (oC) and Method: 27 (Seta flash, closed) Upper Flammable Limit [% by volume]: 7.0 Lower Flammable Limit [% by volume]: 1.0 Auto ignition Temperature [°C]: n.av. Hazardous Combustion Products: Carbon dioxide, carbon monoxide, organic acids, soot and smoke. Explosion data: a. Sensitivity to impact: No b. Sensitivity to static discharge: Yes 5. REACTIVITY DATA Chemically Stable: Product is stable. Incompatibility With Other Substances: Strong acids and strong oxidizers. Hazardous Decomposition Products: See “Hazardous Combustion Products”. Page 2 of 6 Hazardous Polymerization: Does not occur. 6. TOXICOLOGICAL PROPERTIES Route of Entry: Skin Contact: Irritation. Can cause defatting of skin, which may lead to dermatitis. Skin Absorption: Ethylene glycol propyl ether can be absorbed through the skin and is moderately toxic. Eye Contact: May cause severe eye irritation, experienced as discomfort, excess redness and swelling of the conjunctiva – possible corneal damage. Inhalation: Vapours may produce irritation of the respiratory tract as experienced by nasal discomfort and discharge, chest discomfort, cough and difficulty with breathing. Extended or repeated exposure above recommended concentrations may cause nervous depression. Ingestion: May cause mouth, throat, esophagus and stomach irritation, nausea, vomiting, and diarrhea. Signs of intoxication may also result of ingestion. Irritancy of Product: See information in “Route of Entry”. Sensitisation of product: See information in “Route of Entry”. Carcinogenicity of product: None known to be a carcinogen Teratogenicity of product: None known to be a teratogen Mutagenicity of product: None known to be a mutagen. Reproductive toxicity: Ethylene glycol propyl ether is reported to be fetotoxic in animals. Synergistic products: None known. Effects of acute exposure: See “Route of Entry”. Effects of chronic exposure: See “Route of Entry”. 7. PREVENTIVE MEASURES: Personal Protective Equipment: Gloves: Page 3 of 6 Impervious - nitrile - Neoprene Respirator: If exposure exceeds recommended values wear a NIOSH approved respirator for organic vapors, or self-contained breathing equipment. Eye: Chemical safety goggles. Footwear: Safety work boots. Clothing: Wear impervious clothing. Other: Eye bath and safety shower. Engineering Controls: Flammable material - grounding/bonding must be used when pouring this product. All equipment, such as bung wrenches, must be spark proof. All electrical equipment should be spark proof. Adequate ventilation should be employed where this product is used. Leak and Spill Procedures: Eliminate all sources of ignition. In the event of a large spill evacuate all non-essential personnel. Clean up staff should wear appropriate personal protective equipment. Dike with absorbent material to prevent entry into sewers and waterways. Use only spark proof equipment to clean up spill. Place absorbent and spilled material in a proper waste disposal drum. Waste Disposal: Dispose of in accordance to all government regulations for a hazardous waste. Handling Procedures and Equipment: Flammable material - avoid all source of ignition such as open flames, red-hot surfaces. No smoking. All equipment used during the use of this product must be spark proof. All electrical equipment must be spark proof. Close drums tightly when not in use. Storage Requirements: Store in a cool dry, well ventilated area away from incompatible materials. Avoid storage in direct sunlight. Do not store near open flames and other sources of ignition. Specific Shipping Information: Flammable Liquid N.O.S. (Xylene) UN 1993 Class 3 Packing Group III Page 4 of 6 8. FIRST AID MEASURES Eye Contact: Flush with a copious amount of water for at least 15 minutes while holding eyelids well apart. Get medical attention. Skin Contact: Start rinsing and removing contaminated clothing. Clothes should be thoroughly wetted with water to prevent static discharge. Wash with soap and water. If any irritation persists, seek medical attention. Inhalation: Remove victim to fresh air. If breathing has stopped, apply artificial respiration. Seek medical attention. Ingestion: Do not induce vomiting. Get immediate medical attention. 9. PREPARATION OF THE MATERIAL SAFETY DATA SHEET Prepared By: John R. Turner, Chemical Safety Consultant for Hubbell Power Systems. Telephone Number: Fax Number: 905-884-3869 905-770-9014 Date of Preparation: February 01, 2005 10. SOURCES USED • • • • • • • Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 2004, ACGIH. Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, ACGIH. Dangerous Properties of Industrial Materials, Sax, Ninth Edition Registry of the Toxic Effects of Chemical Substances (RTECS), U.S. Department of Health & Human Services [NIOSH] Hawley’s Condensed Chemical Dictionary, Eleventh Edition. OSHA Chemical Safety Database NTP 10th Report on Carcinogens (2002) Page 5 of 6 11. WHMIS SYMBOL(S) THAT SHOULD APPEAR ON THE WARNING LABEL FOR THIS PRODUCT Page 6 of 6 HUBBELL CANADA LP MATERIAL SAFETY DATA SHEET Date of Preparation: February 01, 2005 1. PRODUCT INFORMATION FOR: CHANCE GLOSS RESTORER - PART B C400-1520 USE: GLOSS RESTORER WHMIS CLASS(ES): B2, D2B Manufacturer's Name: A. B. Chance Company Supplier's Name: Hubbell Canada LP Street Address: 210 North Allen Street Street Address: 870 Brock Road South City or Town: Centralia City or Town: Pickering Province or State: Missouri, USA Province or State: Ontario, Canada Postal/Zip Code: 65240 Postal/Zip Code: L1W 1Z8 Telephone Number: 573-682-5521 Telephone Number: 905-839-1138 1-800-263-4622 Emergency Telephone Number: 573-682-8465 Emergency Telephone Number: CANUTEC call collect 24 hours (613) 996-6666 2. HAZARDOUS INGREDIENTS Hazardous Ingredient % CAS Number LD50 LC50 TLV1 Xylene 61 - 67 1330-20-7 4.3 g/kg (oral, rat) 6350 ppm (4 hr. rat) 100 ppm 3.1 g/kg (oral, rat) >6000 ppm (6 hr. rat) n.av. Ethylene glycol 11 - 15 2807-30-9 propyl ether 1 Consult local authorities for acceptable limits. Page 1 of 6 3. PHYSICAL DATA Physical State: liquid Odor and Appearance: typical aromatic odour, viscous liquid Odor Threshold: n.av. Specific Gravity: 0.90 Vapor Pressure: n.av. Vapor Density: n.av. Evaporation Rate: n.av. Boiling Point [°C]: 66 – 140 Freezing Point [°C]: n.ap. pH: n.ap. Coefficient of Water/Oil Distribution: n.av. 4. FIRE AND EXPLOSION HAZARD Flammability: Flammable liquid - WHMIS Class B2. Means of Extinction: Foam, carbon dioxide, dry chemical, water fog. Flash Point (oC) and Method: 27 (Setaflash, closed) Upper Flammable Limit [% by volume]: 7.0 Lower Flammable Limit [% by volume]: 1.0 Auto ignition Temperature [°C]: n.av. Hazardous Combustion Products: Carbon dioxide, carbon monoxide, organic acids, soot and smoke. Explosion data: a. Sensitivity to impact: No b. Sensitivity to static discharge: Page 2 of 6 Yes 5. REACTIVITY DATA Chemically Stable: Product is stable. Incompatibility With Other Substances: Strong acids and strong oxidizers. Hazardous Decomposition Products: See “Hazardous Combustion Products”. Hazardous Polymerization: Does not occur. 6. TOXICOLOGICAL PROPERTIES Route of Entry: Skin Contact: Irritation. Can cause defatting of skin, which may lead to dermatitis. Skin Absorption: Ethylene glycol propyl ether can be absorbed through the skin and is moderately toxic. Eye Contact: May cause severe eye irritation, experienced as discomfort, excess redness and swelling of the conjunctiva - possible corneal damage. Inhalation: Vapours may produce irritation of the respiratory tract as experienced by nasal discomfort and discharge, chest discomfort, cough and difficulty with breathing. Extended or repeated exposure above recommended concentrations may cause nervous depression. Ingestion: May cause mouth, throat, esophagus and stomach irritation, nausea, vomiting, and diarrhea. Signs of intoxication may also result of ingestion. Irritancy of Product: Primary irritant - see information in ”Route of Entry”. Sensitization of product: See information in “Route of Entry” Carcinogenicity of product: None known to be a carcinogen Teratogenicity of product: None known to be a teratogen Mutagenicity of product: None known to be a mutagen Reproductive toxicity: Ethylene glycol propyl ether is reported to be fetotoxic in animals. Synergistic products: None known. Page 3 of 6 Effects of acute exposure: See “Route of Entry”. Effects of chronic exposure: See “Route of Entry”. 7. PREVENTIVE MEASURES: Personal Protective Equipment: Gloves: Impervious - nitrile – Neoprene. Respirator: If exposure exceeds recommended values wear a NIOSH approved respirator for organic vapors, or self-contained breathing equipment. Eye: Chemical safety goggles. Footwear: Safety work boots. Clothing: Wear impervious clothing. Other: Eye bath and safety shower. Engineering Controls: Flammable material - grounding/bonding must be used when pouring this product. All equipment, such as bung wrenches, must be spark proof. All electrical equipment should be spark proof. Adequate ventilation should be employed where this product is used. Leak and Spill Procedures: Eliminate all sources of ignition. In the event of a large spill evacuate all non-essential personnel. Clean up staff should wear appropriate personal protective equipment. Dike with absorbent material to prevent entry into sewers and waterways. Use only spark proof equipment to clean up spill. Place absorbent and spilled material in a proper waste disposal drum. Waste Disposal: Dispose of in accordance to all government regulations for a hazardous waste. Handling Procedures and Equipment: Flammable material - avoid all source of ignition such as open flames, red hot surfaces. No smoking. All equipment used during the use of this product must be spark proof. All electrical equipment must be spark proof. Close drums tightly when not in use. Page 4 of 6 Storage Requirements: Store in a cool, dry, well-ventilated area, away from incompatible materials. Avoid storage in direct sunlight. Do not store near open flames and other sources of ignition. Specific Shipping Information: Flammable Liquid N.O.S. (Xylene) UN 1993 Class 3 Packing Group III 8. FIRST AID MEASURES Eye Contact: Flush with a copious amount of water for at least 15 minutes while holding eyelids well apart. Get medical attention. Skin Contact: Start rinsing and removing contaminated clothing. Clothes should be thoroughly wetted with water to prevent static discharge. Wash with soap and water. If any irritation persists seek medical attention. Inhalation: Remove victim to fresh air. If breathing has stopped apply artificial respiration. Seek immediate medical attention Ingestion: Do not induce vomiting. medical attention. Get immediate 9. PREPARATION OF THE MATERIAL SAFETY DATA SHEET Prepared By: John R. Turner, Chemical Safety Consultant for Hubbell Power Systems. Telephone Number: Fax Number: 905-884-3869 905-770-9014 Date of Preparation: February 01, 2005 Page 5 of 6 10. SOURCES USED • • • • • • • Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 2004, ACGIH. Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, ACGIH. Dangerous Properties of Industrial Materials, Sax, Ninth Registry of the Toxic Effects of Chemical Substances (RTECS), U.S. Department of Health & Human Services [NIOSH] Hawley’s Condensed Chemical Dictionary, Eleventh Edition. OSHA Chemical Safety Database NTP 10th Report on Carcinogens (2002) 11. WHMIS SYMBOL(S) THAT SHOULD APPEAR ON THE WARNING LABEL FOR THIS PRODUCT Page 6 of 6 HUBBELL CANADA LP MATERIAL SAFETY DATA SHEET Date of Preparation: February 01, 2005 1. PRODUCT INFORMATION FOR: ABRASIVE CLEANING PADS C400-1166 USE: CLEANING COMPONENTS WHMIS CLASS(ES): THIS IS NOT A CONTROLLED PRODUCT Manufacturer's Name: A. B. Chance Company Supplier's Name: Hubbell Canada LP Street Address: 210 North Allen Street Street Address: 870 Brock Road South City or Town: Centralia City or Town: Pickering Province or State: Missouri, USA Province or State: Ontario, Canada Postal/Zip Code: 65240 Postal/Zip Code: L1W 1Z8 Telephone Number: 573-682-5521 Telephone Number: 905-839-1138 1-800-263-4622 Emergency Telephone Number: 573-682-8465 Emergency Telephone Number: CANUTEC call collect 24 hours (613) 996-6666 2. HAZARDOUS INGREDIENTS Hazardous Ingredient % CAS Number LD50 LC50 TLV1 Pads consist of Nylon fibres, cured phenol-formaldehyde resin, cured polyurethane resin, cured epoxy resin with abrasive particles of aluminium oxide and silicon carbide. The Controlled Products Regulations Disclosure List requires disclosure of aluminium oxide of over 1%*. Aluminium oxide 10-65 1344-28-1 n.av. n.av. 10 mg/m3 (respirable) *Refer to Section 15 Cheminfo Record Number 86, Canadian Centre for Occupational Health & Safety does not meet criteria for Disclosure List. Page 1 of 5 WHMIS Classes; A, B, C, D, E, and F. “Proposed Deletion” re: Ingredient 3. PHYSICAL DATA Physical State: solid Odor and Appearance: No odour, non-woven fibrous articles with abrasive particles, which are bonded together with cured resin binders. Odor Threshold: n.ap. Specific Gravity: n.av. Vapor Pressure: n.ap. Vapor Density: n.ap. Evaporation Rate: n.ap. Boiling Point [°C]: n.ap. Freezing Point [°C]: n.ap. pH: n.ap. Coefficient of Water/Oil Distribution: n.ap. 4. FIRE AND EXPLOSION HAZARD Flammability: Not flammable by WHMIS criteria. Means of Extinction: Carbon dioxide, dry chemical, foam, water. Flash Point [°C] and Method: n.ap. Upper Flammable Limit [% by volume]: n.ap. Lower Flammable Limit [% by volume]: n.ap. Auto ignition Temperature [°C]: n.av. Hazardous Combustion Products: Carbon dioxide, carbon monoxide, oxides of nitrogen, cyanides. Explosion data: a. Sensitivity to impact: Not sensitive. b. Sensitivity to static discharge: Not sensitive. 5. REACTIVITY DATA Chemically Stable: Page 2 of 5 Product is stable Incompatibility With Other Substances: Strong dehydrating acids. Hazardous Decomposition Products: Refer to “Hazardous Combustion Products”. Hazardous Polymerization: Does not occur. 6. TOXICOLOGICAL PROPERTIES Route of Entry: Skin Contact: Possible mechanical abrasion if rubbed. Skin Absorption: n.ap. Eye Contact: Mechanical abrasion if rubbed. Inhalation: Possible dust from use may irritate respiratory tract. Ingestion: Not an anticipated route of entry. Irritancy of Product: Refer to “Route of Entry” information. Sensitization of product: n.av. Carcinogenicity of product: Not known to be a carcinogen. Teratogenicity of product: Not known to be a teratogen Mutagenicity of product: Not known to be a mutagen Reproductive toxicity: Not known to have reproductive toxicity. Synergistic products: None known. Effects of acute exposure: Refer to “Route of Entry” information. Effects of chronic exposure: n.av. 7. PREVENTIVE MEASURES: Personal Protective Equipment: Gloves: Work gloves. Respirator: Approved dust mask if there is nuisance dust. Eye: Safety goggles. Footwear: As required by the work conditions. Page 3 of 5 Clothing: No special requirements - usual good condition work clothes. Other: Eye bath. Engineering Controls: Good, adequate industrial ventilation as generally required. Leak and Spill Procedures: n.ap. Waste Disposal: Used material can be disposed of in landfill sites. Handling Procedures and Equipment: No special requirements. Storage Requirements: No special requirements. Specific Shipping Information: Not regulated under TDG or US Title 49 CFR. 8. FIRST AID MEASURES Eye Contact: For any nuisance dust, holding eyelids well apart, flush with running water for at least 15 minutes. Get medical attention or possible abrasion. Skin Contact: Wash with soap and water. Get medical attention if any irritation persists. Inhalation: n.ap. 9. PREPARATION OF THE MATERIAL SAFETY DATA SHEET Prepared By: John R. Turner, Chemical Safety Consultant for Hubbell Power Systems. Telephone Number: Fax Number: 905-884-3869 905-770-9014 Date of Preparation: February 01, 2005 Page 4 of 5 10. SOURCES USED • • • • • • • Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices, 2004, ACGIH. Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, ACGIH. Dangerous Properties of Industrial Materials, Sax, Ninth Edition Registry of the Toxic Effects of Chemical Substances (RTECS), U.S. Department of Health & Human Services [NIOSH] Hawley’s Condensed Chemical Dictionary, Eleventh Edition. OSHA Chemical Safety Database NTP 10th Report on Carcinogens (2002) 11. WHMIS SYMBOL(S) THAT SHOULD APPEAR ON THE WARNING LABEL FOR THIS PRODUCT Not required. Page 5 of 5
© Copyright 2024