THE FOLLOWING IS AN AMALGAM OF SEVERAL REPORTS AND IS FOR ILLUSTRATION ONLY XXXXXXXXX xxxxshire A Report on the Decoration Following an Examination of the Painted Surfaces in Several Areas A BRIEF SYNOPSIS Although sampling has been limited, the majority of the surfaces examined have either been stripped of their paint, or are recent insertions / replacements. A couple of samples retained a full sequence of coatings and others are likely to date from the ca.1830s. No complete decorative schemes for any of the four interior areas examined have been revealed. Earlier paint can be found on some of the external surfaces. Interior Fire is likely to be the main reason for the extensive paint removal and for the newer surfaces encountered during the analysis. Smoke damage has apparently been found in the attic and an incendiary bomb dropped during the Second World War might have caused this. The Entrance Hall seems to have been re-arranged in the early years of the twentieth century. Several years later, evidence of smoke damage can be seen in that area. The Kitchen Passage retains elements of earlier decorative schemes. The Drawing Room seems to have been severely damaged by the bomb explosion of 197x and little can be found from before that date. The Stairs have been stripped almost completely of paint; however various doors and door architraves survive from the eighteenth century. The use of a particular type of primer on certain elements suggests either that the original decoration was somewhat old-fashioned for the 1760s, or that parts of the house are older than is presently thought. This might bear further documentary investigations. Exterior The exterior railings seem to date from after ca.1830. A summary of the initial scheme on the other surfaces can be seen below: New Stables (1868-1869) Doors = Brunswick green Windows = grained 1 Ironwork = off-white Walled Garden (1815-1816) a) Potting Shed (1815-1816) Early stone-coloured paint survives on the timber panelling in the passage to the Vinery. The external doors seem to date from the second half of the nineteenth century. b) Ornamental Gates (1786) Stripped. Red-brown paint from late nineteenth / early twentieth century survives. c) Gardener’s House Appears to have been restored and stripped of early paint in 1970s. The door set in the wall to the East of the Gardener’s House probably dates from the second half of the nineteenth century. It was originally Brunswick green 2 XXXXXXXXX xxxxshire A Report on the Decoration Following an Examination of the Painted Surfaces in Several Areas Introduction I was asked by Mr xxx xxx to carry out an investigation of the decorative schemes applied in various rooms of the house and on selected external surfaces. The aim was to learn as much as possible of the original decoration. Historical Background1 The house lies to the South of xxxx. It was built for xx by xxx in the 1780s. The Estate was developed in the 1860s and then fell into a long period of decline. During the 1920s the house was the childhood home of xxxx. After the Second World War the xxx family owned the house. In 1958 xxx xxx bought xxx at auction for £xxx. The sales literature describe it as having been “modernised with care and knowledge” whilst preserving such period features as graceful bow sash windows and Georgian painted panelled walls. In 19xx the main house was subject to an attack by a terrorist organisation. Two bombs exploded, one destroying the kitchen and the second apparently demolished the front door and blew in the Drawing Room window. The house is listed Grade II* as a building of historical and architectural interest. Areas Examined A number of samples were taken from the following areas: Interior a) Entrance Hall; b) Kitchen Passage; c) Drawing Room; d) Stairs. 1 This has been taken from the Conservation Plan prepared by xxx Architects. See also Works Referred to at the end of this report for sources of other references. 3 Exterior a) The New Stables; b) Walled Garden & Gardener’s House; For the purposes of this report the front of the main house is regarded as facing East. Scope of Report The extent of sampling has been limited by the budget, which allowed for about 80 samples. In the event a few more samples were taken. However, in spite of these limitations, a picture has emerged of a number of the events that have taken place, and a few of the decorative treatments applied within the house and on some external elements. In some areas it is only possible to raise questions and not answer them. Indeed the small number of samples has inevitably led to a number of hypotheses that might have to be re-thought in the light of further evidence. Investigation of Samples A total of 84 samples were taken by Patrick Baty during two visits made in June and September 200x. Methods of analysis are dealt with in Appendix Nine.2 Dating of Individual Schemes Although there is no documentary information to assist with the dating of individual schemes it has been possible to estimate when certain of them were applied. This has either been possible through knowledge of the pigments employed or the relative position of schemes in the stratigraphy. Detailed Analysis of Samples INTERIOR General Most unusually in a house of this age many of the surfaces examined have either been stripped of their paint, or are recent insertions / replacements. In fact, approximately 75% of the surfaces sampled displayed paint from the middle of the twentieth century alone. While, of the remainder, only eight samples retained a full sequence of coatings that was likely to date from the period 1815-30. When compared to numerous other buildings of this age that have been sampled it is clear that the house was not decorated very often.3 With the exception of the front 2 The full process is described in (Baty 1995:1, 27-37). 4 railings, twelve schemes are the most that can be found. It is very unlikely that the paint build-up has ever been such to necessitate removal and no sign of paint stripping can be seen on the second floor door and door lining, for example.4 Fire is likely to be the main reason for the extensive paint removal seen throughout the house and for the newer surfaces encountered during the analysis. A number of samples suggest that the Entrance Hall was re-arranged in the early years of the twentieth century. This is not thought to have been prompted by an earlier fire because the Kitchen Passage, the likely route of flame and smoke, shows no sign of such damage. Some years later, evidence of smoke damage can be seen in the Entrance Hall, and that room together with the Stairs were either refurbished or stripped almost completely of paint The fire was not serious enough to destroy the door to the Master Bedroom (FF2) or to the bedroom (SF2) directly above it. However, as part of the post-fire work the door architraves on the Hall side of the Ground Floor rooms and the Master Bedroom were replaced. Entrance Hall (GF9) General Most surfaces display five decorative schemes. However the cornice in the South West corner has retained further evidence. Significantly, there are particles of wood smoke visible on this element and this may relate to wartime damage. If the theory concerning incendiary bombs is correct it appears that the room was substantially refurbished and redecorated following the period 1940-44. This would seem to have been before the sale of the house in 1958, when it was proclaimed as having “Georgian painted panelled walls”.5 Information provided by the paint seems to support this. Plaster Cornice A small length of the cornice above the window in the South West corner may display the full sequence of coatings applied to it (see photomicrographs of XX/26 in Appendix Two). Some sixteen or seventeen schemes can be seen, compared to the five or six found on most other surfaces in this area. The first four schemes were carried out in off-white soft distemper.6 A thin layer of lead white7 can next be seen. This was not likely to be a decorative scheme in its own right as it is too thin, but is probably what was known as “sharp 3 An abbreviated list of projects carried out over the last twenty years can be seen at www.colourman.com. 4 Two surfaces that appear to have retained their full sequence of coatings. 5 (xxxx 2002). 6 See Appendix Seven for details on this medium 7 Until the second half of the twentieth century, the main constituent of most 5 colour” or “sharp stuff” - a coat of oil paint applied over a series of earlier distempers with the aim of sealing the preceding layers.8 Almost to confirm this two further schemes of soft distemper were next employed. The following, the seventh, scheme is of note because it is the first to contain a pigment with a known date of introduction. This was an oil paint made up of lead white tinted with French ultramarine.9 From information provided by the reused shutter (XX/31) in the Kitchen Passage it is possible that this scheme dates from the ca.1840s. Two schemes of blue soft distemper, also tinted with French ultramarine, were next applied. These are thought to have been applied during the second half of the nineteenth century. A dark green scheme, made up in three coats, can be seen to follow the blue (see enlarged photomicrograph of XX/26 in Appendix Two). The colour was one of the variants of Brunswick Green, (composed of Prussian blue, chrome yellow and black) which saw great use during the period ca.1830-ca.1960.10 An approximation to this colour can be seen in Appendix Five. This colour could also be seen on the cornice of the Rear Hall (GF3) at the base of the stairs. Darker variants can be seen on the exterior railings (see photomicrograph of XX/76 in Appendix Two). The eleventh scheme looks like a grained one and is probably contemporary with the graining found elsewhere. Significantly, there are particles of wood smoke on top of it.11 The style of decoration and both the preceding and succeeding layers suggest that this scheme could have been visible during the early years of the War. The decorative scheme that follows the layer of smoke was a blue-green, and the last in the sequence of coatings to have been based on lead white (see SEM print out of XX/11 (layer A) in Appendix Two). It is this distinctive colour, which was made up of Prussian blue and yellow iron oxide,12 that can be found as the first, or second scheme, on most of the elements in the Entrance Hall, on the Stairs and on the first floor landing. In the Entrance Hall, to complete the decoration, the cornice and mouldings were then painted with a bronze paint. architectural paints was lead carbonate, a white compound derived from metallic lead. Throughout this report it is referred to as "lead white". See Appendix Four for more details. 8 (Hasluck 1913, 163). 9 See Appendix Four for more details on these pigments. 10 Three variants can be seen in the Dulux Heritage paint range. Chrome yellow first appeared in the second decade of the 19th century. Dr Ian Bristow notes that it saw early use in the Royal Pavilion at Brighton in 1818 (Bristow 1996, 37). See Appendix Four for a brief account of the pigments mentioned. 11 The characteristic globular particles of wood smoke have been encountered by the author in the South Hall at xx (Baty 2000:3, 15), and at Uppark, following that fire. See Appendix Six for some details on graining. 12 See Appendix Four for more details on these pigments. 6 A paler, yellower, green was next applied. This was based on lithopone13 (see SEM print out of XX/11 (layer B) in Appendix Two) and this colour appears throughout the three areas mentioned above. Three schemes of off-white paint, each based on titanium dioxide14 (see SEM print out of XX/11 (layer C) in Appendix Two) complete the sequence of coating identified on the cornice. Although this pigment was introduced before the War, its first appearance in a domestic paint stratigraphy usually indicates ca.1960. It is known that the front of the house was damaged during a bomb attack by the xxx in 19xx, and it is probable that the second of these schemes relates to the consequent repair work (see below). Skirting; Door and Architrave to Cloakroom; Chair Rail Samples taken from the skirting and skirting moulding, the chair rail and the door and architrave to the Cloakroom (GF10) display only the last five schemes identified on the cornice above (see SEM print outs and photomicrographs of XX/11 in Appendix Two). The door architraves to the cloakroom (DGF15) and to the Kitchen Passage (DGF14) are the same and date from the formation of the existing Entrance Hall. Presumably the other areas that display this architrave were altered at the same time. Presumably, also, the bolection moulding applied to the Entrance Hall relates to that used elsewhere – for example in the Master Bedroom (FF2). Walls Although sampling has been limited, the walls display the same sequence of coatings that have been found on the skirting. However, lining paper had been stuck to the wall initially. In common with several elements, a sample taken from the upper wall in the South West corner displays one scheme prior to the blue-green (see photomicrograph of XX/16 in Appendix Two). The plaster had been painted with lead white in oil before two coats of a paint based on lithopone and chalk. This appears to have been a waterpaint (oil-bound distemper)15 which suggests that it was applied at some time after 1874. A coat of varnish was applied over the blue-green on the upper wall. Panel Mouldings As mentioned above, while most surfaces were painted blue-green the mouldings and cornice were given a coat of bronze paint (see photomicrograph of XX/14 in Appendix Two). It looks as though a slightly darker green was applied to the mouldings when the yellower green lithopone paint was applied. 13 See Appendix Four for more details on these pigments. See Appendix Four for more details on this pigment. 15 See Appendix Seven for details on this medium and information on dating. 14 7 Front Door and Architrave The front door (DGF16) and its architrave were found to display an identical sequence to that on the skirting – the blue-green (followed by a layer of varnish), the yellower green and three off-whites. At the bottom of the sequence on the door, however, is a black undercoat that has not been found elsewhere in the house. It is puzzling to read that the Daily xxx reported that the front door was “demolished” during the bomb attack in 19xx16 as the paint indicates otherwise – perhaps it was merely damaged. The report would suggest that the Drawing Room window and the front door should display paint from that period alone. However, the window only displays two schemes of titanium dioxide-based paint, whilst the door has a lead scheme, one based on lithopone and three on titanium dioxide. It is likely that the first titanium scheme dates from the 1960s, the second from 19xx and the existing one from a date since then. Cupboard The external face of the cupboard door (DGF06) displays the same sequence of five schemes as found on the front door (including the layer of varnish) (see photomicrograph of XX/23 in Appendix Two). However, at the bottom of the sequence, on the wood substrate, is a mid-buff scheme based on lithopone. This is curious because it predates the blue-green scheme that was, arguably, introduced following a major fire. If the fire was serious enough to warrant a major refurbishment in this area how did the cupboard survive? Perhaps more damage was caused by smoke rather than flame. But would smoke alone have lead to the wholesale paint stripping and the large number of newly introduced elements seen throughout the house? The inner face of the cupboard door displays the first three schemes alone – i.e. the mid-buff in lithopone, the blue-green in lead, and the yellower green in lithopone, the last of which is still visible. The tongue and groove panelling at the rear of the cupboard displays the yellower green, and below this is one grained scheme that has also been found on the cupboard in the Kitchen Passage (see photomicrographs of XX/25 in Appendix Two). Electrical wiring was introduced in this area between these two schemes. Radiator Four decorative schemes can be identified on the radiator. On top of a black, which is thought to have been a factory finish, is the yellower green lithopone paint, followed by three off-whites based on titanium dioxide. Ceiling The bed of the ceiling displays approximately four schemes of twentieth century white paint, and appears to date from the post-fire work. 16 (ibid. 20 July 2000 reported in xx Conservation Plan. 8 Kitchen Passage (GF6) Joinery It was noticed during the initial visit that the cupboard doors in the Kitchen Passage appear to have been made from re-used shutters. When sampled, one of these shutters was found to display the same number of schemes as the framework to that cupboard (compare photomicrographs of XX/31 with XX/30 in Appendix Two). However, the first four schemes on the two elements are completely different. Clearly the shutter was originally fixed to a window in another room. Having only examined four rooms in the house it is difficult to be conclusive, but it has been noticed that a very similar early sequence has been found in the Entrance Hall. Is it possible that the shutter was originally in that room? The coatings on the shutter are particularly revealing and several are date-indicative (see XX/31). The first scheme was a pale blue consisting of lead white in oil tinted with French ultramarine. This pigment was introduced in the early nineteenth century and it is unlikely for this scheme to have been applied before ca.1830. The second scheme was a green one, tinted with the (optically) distinctive pigment Emerald green. Although comparatively recently introduced this pigment saw much use in the period ca.1840-1860.17 The third scheme was a very pale blue, once again, tinted with French ultramarine. It was noticed in the Entrance Hall that the sample taken from the cornice in the South West corner (XX/26) displayed a sequence of three schemes all based on this pigment. The position of these three schemes in the respective stratigraphies is very similar - is it possible that they are contemporary? The fourth scheme on the re-used shutter was an off-white based on zinc oxide (see SEM print out of XX/31 (A) in Appendix Two).18 This is also important, because the first occurrence of this pigment in a domestic stratigraphy usually indicates the period ca.1890-1920.19 At this stage it is believed that the shutters were removed from their original location and installed in the Kitchen Passage. The shutters / doors were grained in imitation of oak as was the framework to the cupboard (XX/30).20 The same grained scheme has also been found on the tongue and groove panelling at the rear of the Entrance Hall cupboard. The sixth scheme was a stone-coloured paint based on lead white. This was the first scheme applied on the architrave of the door to the Entrance Hall (see SEM print out and photomicrograph of XX/29 in Appendix Two) and also to the wooden framework to the partition wall to the Cloakroom. This confirms what has been found on the 17 See Appendix Four for details. The Sixth Duke of Devonshire had the Dining Room of his house in Brighton painted with this arsenical green on five or so occasions in the 1840s and 1850s (Baty 2000:1, 3). 18 See Appendix Four for more details on this pigment. 19 This comment is based on the evidence provided by a large number of analyses. 20 From this stage the schemes applied to both surfaces were identical. 9 samples taken from the wall between the Entrance Hall and the Cloakroom– that the partition was put up, and the Cloakroom formed, as part of the major refurbishment that may have taken place after the War and before 1952. It is, of course, possible that the Cloakroom replaced a similar space and analysis might reveal something in that area. The seventh and eighth schemes were both based on zinc oxide. The last three schemes, as in the Entrance Hall, were based on titanium dioxide. As mentioned above, the final seven schemes were also found on the framework of the cupboard in the Kitchen Passage (see photomicrograph of XX/30 in Appendix Two). However, the first four on this surface were very different, being off-whites / pale stone colours (as perhaps one might expect on a utilitarian surface in such an area). The door to the Entrance Hall (DGF14) was found to display just one scheme of a paint based on titanium dioxide. At this stage it is not known which of the three such schemes in the Entrance Hall it relates to (see photomicrograph of XX/28 in Appendix Two). The architrave to the side door lobby displays just two schemes of modern paint. This seems to reflect what has been found in the Drawing Room – that the area was decorated after bomb damage in 19xx and once since then. The wall displays eleven schemes, as does the cupboard in this area. The first seven were in pale stone colours, which ties in with some of those found on the framework of the cupboard. The eighth and ninth were in mid-blue, and the last two were in offwhite based on titanium dioxide. The radiator displays five schemes and appears to be of the same date as the others. Drawing Room (GF1) The Drawing Room is a puzzle. Nothing has been found of the early decoration, most surfaces displaying what appear to be just two schemes. It must have been very badly damaged by the bomb explosion of 19xx. The first scheme on the window shutter was based on titanium dioxide and seems to have been applied over a modern pink primer based on red lead and zinc oxide (see photomicrograph and SEM print out of XX/39 in Appendix Two). The rough surface of the wood suggests that it has been stripped. The skirting board in the Drawing Room is the same as that on the North wall of the Dining Room (but different to that on the East wall of that room - which appears to be earlier). It has been stripped and traces of lead white can be seen in the wood fibres (see photomicrograph of XX/41 in Appendix Two). It is worth remarking that the 10 early traces of primer were white, as perhaps one might expect on the inner surfaces of a bay window, rather than the earlier red.21 The inner face of the door to the Entrance Hall (DGF01) was sampled. This was found to display four decorative schemes (see SEM print out and photomicrographs of XX/42 in Appendix Two). The first comprised a layer of wood stain followed by a coat of clear varnish. The second was based on lead white and lithopone, and the last two were modern white ones. The panel moulding, however, displayed two, possibly three, schemes of titanium dioxide-based paint. Could it have been applied later? The chimneypiece displays just two schemes of modern white paint and is thought to date from 19xx. The modern coved cornice and ceiling display only two schemes of modern paint. The radiator had a dark brown scheme on top of the black factory finish, and this was followed by two modern whites (see photomicrograph of XX/46 in Appendix Two). Stairs Very little evidence of the decoration applied before the major refurbishment survives in this area. Five schemes of a similar nature to those in the Entrance Hall can be seen – the blue-green; the yellower green, and the three based on titanium dioxide. Fragments of earlier layers can be found on the cornice of the Rear Hall, on the window reveal at the top of the first flight and on the upper walls. The door and door lining to the North East bedroom (SF2) on the second floor appear to be complete. The radiator on the first floor landing displays two earlier schemes than any of the other radiators that were sampled although it is presumed to have been installed at the same time. Doors and Door Architraves The door (DSF01) and door lining of the North East bedroom (SF2) on the second floor appears to be original (see photomicrographs of XX/68 in Appendix Two). The wood was primed with a coat of red oxide ground in oil22 and the finish coat was an off-white lead paint. The second scheme was an off-white of a pinkish hue. The third scheme was a grained one, and is thought to date from the second quarter of the nineteenth century or later.23 21 See Appendix Eight for more details on priming. Stylistically the window clearly post-dates those original surfaces displaying red primer. 22 See Appendix Eight for details on priming. 23 See Appendix Six for details on graining. 11 Two successive schemes of a very similar olive green can next be seen. The second of these broadly resembles one found on the cornice in the South West corner of the Entrance Hall (XX/26). A lighter green follows. The seventh scheme was a grained one that was also found as the first scheme on the radiator on the first floor (XX/64). It can also be seen on the re-used shutter (XX/31) and cupboard framework (XX/30) in the Kitchen Passage and the rear wall of the Entrance Hall cupboard (XX/25). The blue-green post-war scheme seems not to have been applied, suggesting that the door and its lining had not been damaged or affected by fire. This is curious, because if an incendiary bomb had been responsible for much damage one might have expected the door’s proximity to the attic to have necessitated its replacement. The final four schemes are the same as found throughout the Entrance Hall and Stairs – the yellower green followed by three based on titanium dioxide. On the first floor, the sample taken from the door (DFF08) architrave to the front bedroom (FF10) reveals that it, too, is original (see photomicrographs of XX/63 in Appendix Two). The wood was primed with red oxide in oil, but the overlying layers have been stripped and the first complete scheme is the blue-green lead-based one believed to have been applied after the war. The final four schemes are identical to the ones found elsewhere. The door (DFF02) to the Master Bedroom (FF2) was also found to be original (see photomicrograph of XX/60 in Appendix Two). Once again, a red primer can be seen followed by the remains of a dark brown black. Evidence of paint stripping can be seen and this is followed by the blue-green post-war lead paint with a coat of varnish on top. Comparison of the above samples with photomicrographs of those from the ornate door architrave (DGF05) to the Dining Room (XX/53) and the less ornate one around the door (DFF02) to the Master Bedroom (XX/61) show that these two are clearly not original. Both display just five schemes starting with the post-war blue-green. The same ornate door architrave can be found on the ground floor on the Hall side of the Drawing Room (GF1); the TV Room (GF2) and the back door. This suggests that they were all installed at the same time, as part of the major work. It was noticed that the door architrave to the first floor passage (FF5) is the same type as on the door to the Master Bedroom (FF2) and therefore is probably of the same date. Other Joinery The skirting at the base of the stairs is original (see photomicrographs of XX/49 in Appendix Two). The wood was primed with red oxide in oil and painted with a dark 12 brown black. A sample taken from the margin of the stairs displayed exactly the same sequence. The window reveal on the first floor landing was found to have been primed with lead white rather than red oxide (see photomicrographs of XX/56 in Appendix Two). The overlying paints have been stripped as indicated by the disturbed lower levels and the first complete scheme is the blue-green post-war one. The usual final sequence of four schemes can also be seen. The suggestion is that this element is not original. Could it date from the phase of work that seems to have taken place after ca.1830? Walls Samples taken from the upper walls on the first flight and the on first and second floor landings were identical. That from the first flight, however, displayed one early scheme (see photomicrograph of XX/54 in Appendix Two). The wall was first given a coat of soft distemper. This has been almost completely washed off before a layer of “sharp colour” was applied at a later stage. Probably at the same time a thick layer of filler was used, and this was followed by two coats of lead white in oil. This may all have been a preparatory sequence prior to the wallpaper(?) which seems to have been hung as part of the post-war refurbishment. It seems that the yellower green lithopone paint that has been found elsewhere was next employed. What appears to be a layer of lining paper followed by wallpaper was then hung. This would seem to equate to the first of the titanium dioxide paints thought to date from the 1960s. One or two schemes of titanium dioxide paint complete the sequence. Radiator The radiator on the first floor landing was sampled, and found to display six decorative schemes (see photomicrograph of XX/64 in Appendix Two). The first layer was a dense black which is thought to have been a factory finish. A scheme of graining was next applied. This seems to relate to the grained scheme found at this level in a few of the stratigraphies elsewhere in the house (in the Kitchen Passage and the rear of Hall cupboard). The blue-green scheme found throughout the house was next used. A thin coat of varnish was applied to this. The remaining four schemes have also been seen in other areas. Dining Room (GF4) Although not within the scope of this report, the chimneybreast and inner face of a window shutter were sampled. 13 Two schemes of modern paint were found on the chimneybreast and four lead-based off-whites were found on the shutter. The shutter may date from the ca.1830s phase of work and, presumably, is of the same date as the Drawing Room window. EXTERIOR Front Railings Once again, these fall outside of the scope of the project. However, knowing that useful dating information is often displayed by railings, one sample was taken (see photomicrograph of XX/76 in Appendix Two). Approximately twenty-three schemes have been identified. Although unconfirmed, the first scheme appears to have been a Brunswick Green, which would give it a date of application of not before 1830. Certainly the second scheme contained Chrome yellow and could not have seen use before that date. By the simple expedient of dividing the period ca.1830-ca.1995 by the number of schemes found one is given an approximate average repainting cycle of just over seven years. Whilst not particularly frequent this figure is feasible and has been encountered before.24 If, from the single sample taken, the complete surviving sequence has been identified it would suggest that greens of various hues have been used until the first quarter of the twentieth century. Black has been used since. The stratigraphy is a very typical one seen on nineteenth century railings. The New Stables The New Stables were erected in 1868-1869. From the evidence of the paint layers one can see that Brunswick green was in use on the Estate from, at least, the ca.1860s to the mid 1960s when a bright green was employed. Comprehensive repairs were carried out to the interior and exterior during 1996-1997, when it was last repainted. It is possible however that the shop and toolstore doors were repainted again in 1999 when further conversion was carried out to this building. It is thought that little maintenance would have been carried out during the war and in the years immediately following. It also seems unlikely that xx would have been in a strong financial position to spend very much on the Estate during the 1930s. The paint layers suggest that redecoration was carried out at irregular intervals until the 1930s and that it started again ca.1953-1954. 24 The front railings of 1 Lewes Crescent, Kemptown, Brighton, were painted 26 times between 1828/9 and ca.1998 - approximately once every 6.75 years (Baty 2000:1, 1). Those in front of Nos. 26-31 Charlotte Square, Edinburgh (constructed between 1805 and 1820) were painted on average once every 8 to 11 years (Baty 2000:2, 9). 14 Coal Shed Door Most of the samples that were taken show signs of paint loss or of stripping. However the door to the coal shed of the lower flat at the East of the building has retained what appears to be a full sequence of coatings (see photomicrograph of xxx/6 in Appendix Two). The first two schemes were in dark Brunswick green. Black was used on the third occasion. A very distinctive mid Brunswick green with particles of red iron oxide was next employed. In the photomicrograph it can be seen that this has soaked down through a crack in the black layer and traces can be seen below the black. Three darker Brunswick greens were next applied and these were followed by a very distinctive scheme, which has been found on other surfaces. This consisted of a lithopone-based grey undercoat25 on top of which was a dark Brunswick green. A further Brunswick green followed this. The last of the greens was a bright green, which has also been seen on the xx Building. This is thought to date from the mid 1960s. The remaining schemes were all based on titanium dioxide and were in buffs and fawns. Door in Internal Corner The door set in the internal corner of the North side of the building has been stripped. Traces of a lead-based grey undercoat can be seen, however the first full scheme is the bright green mentioned above, and thought to date from the 1960s. The remaining ones were as the coal shed door that has been described above. Stair Balustrade The iron balustrade to the upper flat at the East end of the building was originally painted with an off-white lead-based paint. A stone-coloured one can next be seen. It is possible that rust was responsible for the loss of the next five (?) schemes because the third visible scheme is the dark Brunswick green on the grey lithopone-based undercoat.26 Following the bright green described elsewhere black has been employed on the stair balustrade. Tool Store Window The window of the Tool Store, in the SE corner of the building, was also sampled. The window was originally grained – probably in imitation of dark oak. Graining was repeated once more before a number of schemes of off-white in lead white-based paint were applied. Probably at the same time that the bright green was used on the doors and balustrade an off-white based on a mix of lithopone and lead was employed. The last seven or eight schemes have been in off-white paint based on titanium dioxide. 25 This seems to be the same as that used as part of the first (1959) scheme on the xx Building. 26 This seems to date from 1959. 15 The soil pipe adjacent to the front door of the lower flat in the North of the building displayed very few decorative schemes. A coat of black can be seen on top of a thick layer of rust. This seems to have been a scheme in its own right rather than a rustproofing coat. Two or three schemes of white paint followed by the same number of pinkish-brown complete the sequence. Walled Garden & Gardener’s House The Walled Garden was laid out between 1775 and 1786, but there are records indicating that the outer walls were rebuilt (in a new location) in 1816. The tool sheds and fruit stores (potting sheds) were built in 1815, most of the joinery looks as though it has been renewed since then. Some potting shed doors were renewed in 1996 and all exterior woodwork and metalwork in the Walled Garden was repainted in 1996. The timber gates were repainted in 2002. The 1786 ornamental gates are likely to have been moved to this position from somewhere else. There is evidence that there have been timber gates hung in this opening at some time. The Gardener’s House is likely to date from 1815-1816 and the old gateway to the East appears to have been formed with the construction of the wall. Ornamental Gates The ornamental iron gates set in the East wall of the Walled Garden were found to display very few decorative schemes (see photomicrograph of xxx/67 in Appendix Two). It is possible that further sampling would reveal more evidence of earlier coatings, but care was taken with the selection of this sample. Over a thick coating of rust can be seen three schemes of red iron oxide in oil. Each of these was varnished. There is nothing to suggest a date but similar coatings have been seen on late nineteenth and early twentieth century gates and railings.27 On top of the three red-brown schemes can be seen six of black. The penultimate scheme seems very similar to the one below the existing Antelope colour on the xx. Potting Shed: Interior a) The passage side of the six panel door to the Seed Store was found to display five decorative schemes. The first was grained in imitation of wood – probably dark oak. The ground coat was based on lead white and appears to be equivalent to the ninth scheme on the neighbouring passage lining. It is possible that this dates from the early twentieth century. The subsequent scheme was a dull green compounded of yellow iron oxide and black. No white pigment could be found to help with the dating of this. Two schemes of buff-coloured paint based on titanium dioxide can next be seen, placing these in the post 1960 era. The existing green is similarly based 27 (Baty 1995:2 passim). It is possible that the earliest paint is of the ca.1880s. 16 b) The beaded lining in the passage to the Vinery has similarities with the Seed Room door and it probably retains original paint (see photomicrograph of xxx/65 in Appendix Two). A sequence of eight schemes of stone colour in lead-based paint can be seen at the bottom of the stratigraphy. It is very noticeable that the paints are very second grade and display lots of adulterants – principally chalk and barytes. It is quite possible that the earliest of these dates from ca.1815. The ninth scheme is a grained one and identical to the first on the Seed Room door (see above). The tenth (dull green) scheme and the following buff-coloured paint were also found on the neighbouring door. The twelfth and the final (existing) schemes are both based on titanium dioxide. c) The inside face of the Western-most double doors of the Potting Shed displayed four schemes of off-white paint. Potting Shed: Exterior a) Slightly different numbers of decorative schemes can be seen on the samples taken from the external doors. The impression given, however, is that most date from the second half of the twentieth century. The double doors of the Potting Shed second from the West end displayed the greatest number of schemes (see photomicrograph of xxx/66 in Appendix Two). The wood was primed with an aluminium wood primer, given a green undercoat and then a top coat of Brunswick green in a paint based on titanium dioxide. Four further schemes in Brunswick green follow this. An olive green can then be seen and then the final (existing) Brunswick green. It seems likely that this particular door dates from ca.1960. Gardener’s House The top sash of the West window on the rear of the building was thought to display more paint than the other surfaces, but only modern paint can be found. The wood has been primed with an aluminium primer and four schemes of white paint based on titanium dioxide can be found on top. It seems likely that the window was stripped in the 1970s. A sample taken from the West window on the front of the building shows that this window was stripped at the same time. A sample taken from the central fanlight on the South front was unclear and an indeterminate number of schemes in limewash could be seen. 17 Door The old door set in the wall to the East of the Gardener’s House appears not to have been painted for many years (see photomicrograph of xxx/70 in Appendix Two). Underneath a faded red can be seen what appears to be a blue paint. A sample taken from this door shows the red to have been composed of red iron oxide. The “blue” however was shown to be a weathered Brunswick green. When such a colour is exposed to UV light for a long time the Prussian blue component of the mix migrates towards the surface of the film making the colour bluer. This is shown very clearly in the photomicrograph, where a thin layer of dark blue can be seen directly under the weathered red scheme. This phenomenon is well known as indicated by the following quote: Faded Colours It is well to remember that only genuine effects are permanent. A short time ago the artistic world discovered that on garden gates, farm fences, etc., there was a most lovely blue-green colour to be seen sometimes. This was Brunswick green in a state of dilapidation, and was showing that it needed repainting. However, the colour was so lovely that many attempts were made to copy it in new paint. They all failed hopelessly. One cannot with paint fake the work of time. An excellent example of this is seen inside houses where people have had their panelling painted to imitate dirt in the mouldings. It always looks wrong.28 Approximately six earlier schemes in Brunswick green can be seen as well as one in a very dark grey / almost black colour. This door displays approximately the same number of pre-titanium schemes as the stop to the Herb Garden gate. This suggests that they are of the same age, but that for reasons not known the door has not been painted since the xx have owned the Estate. Perhaps the doorway has been blocked since shortly before the war and it was felt that there was no need to paint a non-functioning door.29 Recommendations / Conclusions The limited number of paint samples, together with the almost meticulous paint stripping has led to far less information being obtained than is usual from buildings of this age. It is very unlikely that complete early schemes would be revealed by further analysis. More sampling might help with the dating of layers, and could shed light on the extent of replaced elements. This in turn might help reveal the course of the fire – if indeed that is what led to the major refurbishment. 28 29 (Ionides 1934, 18). This door will pose very interesting conservation issues. 18 It has been suggested from the scorch marks found in the attic that the house might have been hit by incendiary bombs during the Second World War. It is odd that, if the fire started at the top of the house and worked down, the door architrave to the North East bedroom on the second floor has retained so much of its early paint and that original fabric survives on the first floor. It would be interesting to learn more about xxx in the first half of the twentieth century. It is possible that some of the questions concerning post 1920s decoration in the house can be answered by xxx xxx who, although in her eighties, may respond to a letter. Perhaps if xxx xxx or her daughter are still alive, they may be able to answer general questions about their occupancy from 1958. It is known that there were restrictions on building materials in the years after the War. One wonders how long it was before ornate architraves and wallpaper became available again. Is it possible that the house was uninhabited for some time after the war before being put up for sale in 1958? Do the scorch marks in the attic and the wood smoke in the Entrance Hall indicate two separate outbreaks of fire or the extent of a single outbreak? The use of a red primer on certain elements suggests either that the original decoration was somewhat old-fashioned for the 1760s, or that parts of the house are older than is presently thought. This might bear further documentary investigations. The re-used shutter in the Kitchen Passage has given a hint to the colours used in the room that originally housed it. It is possible that other re-used shutters might be sampled to see if they were all from the same room. If the window shutters are freed and the inner faces sampled one should be able to learn a lot more about the earlier joinery colours in various parts of the house. The information gained would still be partial however and it is not felt that further analysis would help with redecorating the house. From early in the nineteenth century until the 1960s Brunswick green was applied to external doors, fasciae, and sometimes windows. A pinkish-brown / warm stone colour that was similar to the present BS 08B21 (Antelope) seems to have been introduced in the 1870s. This has only been found on certain elements of a secondary nature. Patrick Baty BA (Hons) FSA Scot FRSA 26th November 20xx Papers and Paints Ltd. 4 Park Walk London SW10 0AD www.colourman.com 19 APPENDIX ONE LOCATION OF SAMPLES 46 12 41 13, 14 & 15 30 & 32 37 45 43 42 38 North 35 36 40 44 44 33 27 & 28 2, 6 & 7 39 34 26 25 11 16, 17, 18, 20, 21 & 22 10 9 4 & 29 3 24 5 1 20 19 8& 23 31 /4 /3 /5 NW Corner - Door 21 /2 /6 /5 /7 NW Corner - Pilaster 22 /22 /21 /15 /14 /16 /20 /13 Column (diagrammatic) 23 APPENDIX TWO PHOTOMICROGRAPHS AND SEM PRINT OUTS Lead and Zinc ] ] ] ] 7 x lead schemes ] ] Plaster ] ] ] ] Ochre and black ] ] ] ] Black particle Distemper Plaster Photomicrographs of xxx/102 (x200 & x500) Staircase. Top Floor. NW wall between dining room + N lobby 24 3x [ modern [ schemes [ Zinc white + lead ] 7x lead ] schemes ] ] ] ] ] ] Paint has flaked off plaster – no distemper Photomicrographs of xxx/117 (x200 & x500) Staircase. First Floor. Wall RH of door to Picture Room 25 Energy-dispersive X-ray analysis (EDX), using the scanning electron microscope, was carried out on the greyish layer applied over the last pink scheme on the NW wall of the second floor of the Staircase. The reading was taken from sample xxx/102. It shows a peak from Lead (Pb) and smaller ones from Calcium (Ca), Barium (Ba) and Zinc (Zn). The indications are that the paint was based on lead and zinc with a quantity of chalk and barytes added as an extender. 26 { Lots of late { 20th century { schemes { { { { { { 3 x pink { schemes { 3 x earliest } schemes } } } } Mix of black, yellow / red and brown iron oxide Photomicrographs of xxx/114 (x200 & x500) Staircase. First landing. Skirting moulding above 2nd tread. 27 { 3 x pink { schemes White 3 x dark } greyish } schemes } Photomicrograph of xxx/113 (x200) Staircase. First landing. First pilaster on E side { late 20th { century { schemes 7 x lead schemes Photomicrograph of xxx/104 (x200) Staircase. Top floor. Column shaft nearest dining room {3 x late 20th {century {schemes { zinc on lead { scheme { 2 x varnished {pink {schemes 7 x lead } schemes } { 4 x whites Photomicrograph of xxx/115 (x200) Staircase. Edge of pencheck stair below baluster 28 Gold 2 Gold 1 Copper flakes Gold 1 Copper flakes Lithopone based scheme Photomicrographs of xxx/105 (x200 & x500) Staircase. Top floor. Gilded torus moulding of same column shaft 29 Brown – lithopone based Grained 7 x lead schemes Photomicrograph of xxx/96 (x200) Servants’ stair. Baluster, ground floor 30 4 – 5 x late 20th century schemes { 3 x red { oxide { schemes Dark Brunswick green { 4 x black { schemes { { { { { 4 x black { schemes { { { { Photomicrographs of xxx/91 (x200 & x500) Servants’ Corridor. Baluster of wine cellar stair 31 5 x whites in TiO2 Dark green 2 x greyish greens Buff lithopone based scheme Varnished browns 6 x offwhite Original off-white Photomicrographs of xxx/94 (x200 & x500) Servants’ Corridor. Door to kitchen lobby. External face LH stop 32 { { { 6 x schemes { in TiO2 { { { 3x lithopone based schemes { { 5 x pinkish { brown { schemes in { lead { Red iron oxide particles Photomicrographs of xxx/25 (x200 & x500) West wing. Cellar entrance door. S elevation 33 2x schemes in TiO2 Dirt layer { 2 x zinc { based schemes { { { 22 x lead { based { schemes { { { { { Original scheme Photomicrographs of xxx/28 (x100 & x500) West wing. Cellar window on Tower. LH lining 34 Schemes based on TiO2 Titanated lead scheme { { { { Schemes { based on { lead { { { { { Zinc based scheme Wood Original scheme Wood Photomicrographs of xxx/5 (x100, x200 & x500) Clock Tower Court. S side x room window upper sash 35 Late 20th century schemes Titanated lead Zinc based scheme 18 x leadbased schemes Photomicrograph of xxx/10 (x200) Clock Tower. W elevation 1st floor above arch. Window – outer sash N side 36 Energy-dispersive X-ray analysis (EDX), using the scanning electron microscope, was carried out on the twentieth scheme applied to the window above the arch of the Clock Tower. The reading was taken from sample xxx/10. It shows a peak from Lead (Pb) and smaller ones from Titanium (Ti). The indications are that the paint was based on lead with a small amount of titanium dioxide added. 37 5–6x schemes based on TiO2 Lithopone based schemes Wood Bright green also found on Stables Lithopone based schemes Wood Photomicrograph of CUL/124 (x200) x Building. S elevation. Coal hatch to LH of door. Lining of hatch 38 Bright green also found on x Building Lithopone based paint Lithopone based paint { { {4x { Brunswick { greens { { { { { { Black Brunswick green Photomicrographs of xxx/80 (x200 & x500) New Stables. Lower N flat. Coalshed door under stair 39 5 x modern paints Wood Particles of aluminium Remains of 2nd scheme Original pale pinkish brown White undercoat Photomicrographs of xxx/65 (x200 & x500) x House. Corner Post. NW corner. Above bench 40 Existing black First black 3 x red iron oxide Varnish Red iron oxide Rust Photomicrograph of xxx/77 (x200) Walled Garden. East wall. Iron gate 41 APPENDIX THREE CROSS SECTIONS MADE Cross sections in bold have been photographed and appear in Appendix Two. ENTRANCE HALL XX/1 Lower Wall SW corner – panel moulding XX/2 Fragments from upper wall XX/10 Skirting Fascia SW Corner XX/11 Skirting Moulding SW Corner XX/12 Lower Wall SW Corner XX/13 Lower Wall R/H Chimneypiece (S) XX/14 Lower Wall R/H Chimneypiece (S) – Panel Moulding XX/15 Chair Rail SW Corner XX/16 Upper Wall SW Corner XX/17 Upper Wall R/H Chimneypiece (S) XX/18 Upper Wall R/H Chimneypiece (S) – Panel Moulding XX/19 Front Door (Inside Face) – Centre Rail 5ft up XX/20 Front Door Architrave – Bottom R/H XX/21 Door to Lavatory – Hanging Stile XX/22 Door to Lavatory – Architrave: Bottom R/H XX/23 Cupboard Door (Outer) R/H Door XX/24 Cupboard Door (Inner) R/H Door XX/25 Cupboard – Rear Wall (tongue and groove panelling) E Wall XX/26 Cornice SW corner old plaster XX/27 Ceiling Bed XX/71 Radiator KITCHEN PASSAGE XX/28 XX/29 XX/30 XX/31 XX/32 XX/33 XX/34 XX/35 XX/36 XX/37 XX/38 XX/72 Door to Hall (Inner Face) Muntin Door to Hall - Architrave Framework of Cupboard Reused Shutter / cupboard Door Muntin Rear Wall of Cupboard (Tongue and Groove) R/H Side Wooden Framework to Partition Wall to Lavatory (W) Bottom L/H Curved (W) Plaster Wall Architrave to Side Door Lobby E Wall Top L/H of radiator (R/H of Cupboard) Blue Flakes below window to kitchen S Wall at base of Back Stairs Radiator DRAWING ROOM XX/39 Window Shutters (nailed shut) Bottom L/H (SW) 42 APPENDIX THREE (continued) XX/40 XX/41 XX/42 XX/43 XX/44 XX/45 XX/46 XX/47 XX/48 Skirting Fascia (SW) Skirting Moulding (SW) Door (Hanging Stile Bottom R/H) Door Panel moulding Chimneypiece Bottom L/H Plinth Wall Opposite Chimneybreast Radiator Cornice Opposite Chimneybreast Ceiling (above /47) STAIR COMPARTMENT XX/49 XX/50 XX/51 XX/52 XX/53 XX/54 XX/55 XX/56 XX/57 XX/58 XX/59 XX/60 XX/61 XX/62 XX/63 XX/64 XX/65 XX/66 XX/67 XX/68 XX/69 XX/70 Skirting at base Baluster Lower Wall – Level with 2nd Stair Chair Rail Door Architrave to Dining Room (ornate type) Upper Wall – Level with 3rd Stair Cornice to Hall – above 1st Step 1st Landing Window Reveal – Bottom L/H Stair Margin – Riser to 5th Step Ceiling Bed – Rear Hall 1st Landing – Lower Sash 1st Floor – Door to Master Bedroom: Bottom of Muntin 1st Floor – Door architrave to Master Bedroom – R/H Side 1st Floor – Door to front Bedroom 1st Floor – Door Architrave to Front Bedroom 1st Floor – Radiator 1st Floor – Landing Upper Wall (W) NW Corner 1st Floor – Upper Wall above Top Step (N) 2nd Floor – Landing Upper Wall (N) 2nd floor – Landing Door to NE Bedroom – Bottom of Muntin 2nd floor – Landing Door to NE Bedroom – Lining (Lower LH) 2nd Floor – Cornice (modern) DINING ROOM XX/73 XX/74 Shutter – Lower L/H Inside Face: Bottom L/H Wall – Chimneybreast Return: R/H above Bell FRONT RAILINGS XX/3 Railing Upright 43 APPENDIX THREE (continued) NEW STABLES XXX/4 XXX/5 XXX/6 XXX/7 XXX/8 XXX/9 New Stables. NE side. Diagonal entrance door. Stop LHS New Stables. Shop door. Stop to LHS fanlight New Stables. Lower N flat. Coalshed door under stair New Stables. Lower N flat. Soil pipe adjacent to front door New Stables. Upper N flat. Stair baluster New Stables. E elevation. Lower window of toolstore. LH rail upper sash WALLED GARDEN XXX/75 XXX/76 XXX/77 XXX/78 XXX/79 XXX/80 Walled Garden. Potting Shed. Eastern double doors. Top facing Walled Garden. Potting Shed. Interior 6 panel door into Seed Store. Hinge stile. Walled Garden. Potting Shed. Interior beaded lining in passage to Vinery. 122cm up beside office door Walled Garden. Potting Shed. Double doors 2nd from W end. RH leaf 91cm up Walled Garden. Potting Shed. Westernmost double doors. N face Walled Garden. Potting Shed. Western most double doors. N face. Flake from decayed lining LH leaf GARDENER’S HOUSE XXX/81 XXX/82 XXX/83 XXX/84 Gardener’s House. S face. Central fanlight. Middle of bottom rail Gardener’s House. S face. Top sash of W window Gardener’s House. N face. Door through wall to LHS of house Gardener’s House. N face. Window to RH of entrance. Top sash LHS 44 APPENDIX FOUR SOME PIGMENTS FOUND AT XXX White Lead "White may be said to be the basic colour in all painting practice, for few pigments are used without the incorporation of some white to give body (opacity) or to reduce colour strength. Until some fifty years ago [about 1900] white lead was the only white pigment produced in any great quantity, but since then other whites have been introduced which have practically superseded white lead for some purposes, notably interior painting. In spite of certain drawbacks, however, white lead remains unsurpassed for exterior painting. The other principal basic whites used in this country are zinc oxide, lithopone, antimony and titanium".30 Zinc Oxide Zinc oxide is a bright white pigment that is non-poisonous, and is not discoloured by sulphurous fumes. These properties led to its consideration as a replacement for white lead towards the end of the nineteenth century. One of the earliest references to it appears in a book of specifications published in 1859.31 In this instance it was recommended in rooms with gaslights where the "clearness and brilliancy" of the white was to be preserved. Its chief disadvantage is the hardening effect it has on oil, which causes it to produce a hard non-elastic and brittle paint film. This may lead to premature breakdown of the paint on external surfaces by cracking or chalking unless corrected. In mixture with white lead it produces a very good paint. The zinc hardens the lead and helps it to maintain colour in a smoky atmosphere, while the lead moderates any hardening action of the zinc and so prevents brittleness. Paints containing such a blend of lead white and zinc oxide were used in the first quarter of the twentieth century. The use of zinc oxide appears to have reached its peak in the second decade of the twentieth century. It was at this time that Arthur Jennings, the prolific writer on paint, wrote: Before 1914 nearly the whole quantity of zinc oxide used in this country was imported from France, Belgium, Holland, and the United States of America, but since that time several factories have been started in England, and the present produce has already reached an output almost sufficient to fill all home requirements.32 Its appearance in paint stratigraphy usually indicates the period ca.1890-1960. 30 (Hurst 1949, 61). (Donaldson 1859, xxi). 32 (Jennings 1921, 1:184-185). 31 45 APPENDIX FOUR (continued) Titanium Dioxide Titanium dioxide seems to have been first developed as a pigment simultaneously in Norway and the United States. This took place in 1916, and full-scale production was under way by 1919.33 Initially the pigment was composed of 25% anatase titanium dioxide and 75% barium sulphate, and this was known as titanium white. It was not introduced into Britain until 1921, and it met with a slow take up.34 A composite pigment using precipitated calcium carbonate was tried experimentally, but was abandoned because it was too expensive to produce. The first "pure" anatase grades of titanium dioxide were produced in 1923 in France, and began in England in 1934. Although the anatase variety compared favourably with other available white pigments, it had the tendency to "chalk" when exposed to the weather. Development and production of the more stable rutile variety were delayed by the Second World War, and the first manufacturing plant only appeared in England in 1948. The outstanding qualities of this were soon recognised, and by the late 1940s it had largely superseded the original type of pigment for many purposes, although the composite pigment was still manufactured and used for a while. Because of its brilliant whiteness and intense opacity it has been the prime white pigment in house paints for the last thirty years. The following figures show how the production of the pigment increased sharply after the last war: Estimated UK Production of TiO2 in Thousands of Tons35 1935 1937 1945 1948 1950 4 6 9 16 30 Barytes / Barium Sulphate The pulverized natural form of barium sulphate is traditionally called barytes in English-speaking countries; the synthetic product, blanc fixe. The natural product was first suggested as an artists' pigment in about 1782, but the major introduction of both natural and synthetic materials into commerce probably took place in the period 1810 to 1820. 33 (Blakey and Hall 1988, 4). Its earliest known use in a paint in this country was in 1924 (Baty 1999, 1). 35 (Chatfield 1955, 248). 34 46 APPENDIX FOUR (continued) The earliest use that has so far been encountered by this author is 1811, when it was used in the first scheme on the external railings at the front of the Bristol Commercial Rooms.36 By the 1820s the widespread practice of adulterating lead white with barytes was common, although this was generally legitimately done, and not a dishonest practice. Lead white thus adulterated was called Venice white at 1/1 barytes/lead white, Hamburg white at 2/1, and Dutch white at 3/1.37 A few years later, Tingry describes it as being good for undercoats or primers, but points out that it is not superior to any of the "simple earths", as it does not combine with oil in the same way that lead does.38 Shortly after, David Hay expressed concern at the way that lead white was adulterated with barytes, and gave tips on how to identify its presence. He acknowledges how difficult this is when the paint is ready-prepared,39 and suggests paying a high price in order to avoid buying it accidentally.40 One hundred years later, the use of barytes in cheaper grades of lead white was still recognised, but again with the caveat that such paint be marked as "reduced white lead", and not to be confused with "genuine white lead".41 Lithopone The Frenchman G.F. de Douhet must be considered the pioneer of the lithopone industry. In two French patents, granted to him in 1847, de Douhet described the concept of preparing a new white pigment from zinc sulphide and barium sulphate.42 Lithopone was first produced in England in 1874, and was found having been used soon afterwards on St Pancras. Early use has also been found at Chastleton, and at Chatham Dockyard.43 It saw much use in interior paints, particularly in oil-bound water paints. It had great advantages compared with the two principal white pigments in use at the end of the nineteenth century. Unlike white lead, which tends to discolour in the presence of sulphurous gases, it is inert. Compared with zinc white, its chief advantage is its greater opacity and elasticity. On the other hand lithopone has the drawback of blackening when exposed 36 (Baty 1995:2). (Leuchs 1825) in (Feller 1986, 47-64). 38 (Tingry 1830, 59-60). 39 Confirmation that ready-mixed paint has been available for many years. 40 (Hay 1847, 105). 41 (Heaton 1948, 65). 42 H. Clausen, "Zinc-Based Pigments" in Pigment Handbook, vol. 1. New York. John Wiley & Sons. 1988, 48 43 I am grateful to Catherine Hassall for this information. 37 47 APPENDIX FOUR (continued) to the sun before it has become thoroughly dry. Patents were taken out in 1923 and 1925 for methods of increasing its light fastness. It was, however, generally regarded as unsuitable for the preparation of external paints, which disintegrate rapidly owing to the combined effect of sulphonation of the oil and conversion of the lithopone to soluble salts. Lithopone frequently found use in the flat wall finishes manufactured at this time… A few years since an entirely new class of flat paints for walls was produced. They have been so exceedingly successful that it is not too much to say that every paint manufacturer to-day either makes such goods or contemplates doing so in the near future. ...Perhaps the quality of these materials which is the most appealing is that the body is so good (the base is lithopone) that a single coat almost always suffices, even on bare wood. A final coat of a good varnish completes a job which will be found to be durable, economical, and altogether satisfactory.44 Vermilion The pigment known as Vermilion, is a bright scarlet pigment produced by combining sulphur and mercury, the result being red mercuric sulphide. Cinnabar is the natural form, which was less common, but often preferred, because of the tendency of the early colour-shops to adulterate the artificial variety with red lead. There were two methods of producing this pigment, the one known as Dry-Process, and the other as Wet-Process. The Chinese are believed to have invented the dryprocess, although Amsterdam became the principal centre for its manufacture in Europe in the early seventeenth century. It is still available in mainland China, and the author has recently obtained a quantity from Guangdong province. When viewed under the microscope, the particles of dry-process vermilion are irregular, and clearly made by pulverising lumps. The larger particles tend to be elongated, reflecting its columnar structure. By the end of the seventeenth century, Gottfried Schulz, a German, had discovered an easier, and less expensive method of manufacturing the pigment. This was done by heating the black mercuric sulphide in a solution of ammonium or potassium sulphide. It soon became the favourite method of production in the West, being known as English or German vermilion. The particles of wet-process vermilion are fine and uniform in size, which is a characteristic of a chemically precipitated product.45 44 45 (Jennings and Rothery 1921 1:135). (Gettens et al 1993, 159-165). 48 APPENDIX FOUR (continued) Its price in the late 1840s varied from three shillings to six shillings per pound.46 As a benchmark, the ubiquitous yellow ochre varied from 1d. to one shilling per pound.47 Red Lead John Smith described very clearly the manufacture of red lead: this colour is made out of common lead, by first reducing it to a litharge; and that litharge being afterward ground to a powder in a mill is afterward conveyed into a hot furnace, for that purpose, where 'tis continually kept stirring with an iron rake, till it has attained to the colour of a fine, pale red.48 This pigment had a very mixed reputation, and was often used more for its drying properties, than its orange-red colour, which was liable to turn black in oil. Whittock said, however, that it kept its colour in water-based media, and was consequently, sometimes, used in distemper.49 Vanherman found little use for its colour in housepainting, except as a ground for mahogany graining.50 As well as being used in the manufacture of drying oils, this pigment came to replace Spanish brown or red oxide as a priming colour. Its quick drying nature was of considerable use at a time when a coat of oil paint could take several days to dry, and the decoration of a room, perhaps, a week. The addition of red lead to the undercoats would ensure that these would be ready to receive the finish coat as soon as possible. One consequence of this characteristic was that it was somewhat difficult to work with, hardening into an unmanageable mass51 and adhering: so strong to the bottom of the paint-pot, that it proves a troublesome task to liberate it and bring it into a working condition again.52 The pigment was often mixed with size and used to kill knots, prior to painting. Emerald Green Emerald, or Schweinfurt green was a later development among the arsenical greens, being discovered by F.V. Rusz and G. Vilhelm Sattler at Schweinfurt in 1814. It appears to have first been put on the market in 1816.53 Emerald green was regarded, in the 1830s, as a: 46 (Hay 1847, 110-12). (ibid. 108). 48 (Smith 1687, 21). 49 (Whittock 1827, 10). 50 (Vanherman 1829, 29). 51 (Tingry 1830, 106), 52 (Vanherman 1829, 29). 53 (Bristow 1996, 28). 47 49 APPENDIX FOUR (continued) …green which has recently obtained great reputation on the continent, and which is said to surpass Scheele's, both in beauty and splendour.54 The colourman, George Field, writing in 1850, described it as being a new copper green, the "most vivid of this tribe of colours", rather opaque, and more durable than the others. He added that it worked well in water, but with difficulty in oil, and dried badly in that medium.55 It was used in both oil and distemper, and as a colour in the manufacture of wallpaper. Chrome Yellow Chrome yellow was the yellow pigment that the artist and the house-painter had been waiting for. It was the first bright yellow that was reasonably durable, and yet worked in both oil- and water-based media. A Frenchman, Louis Vauquelin, is credited with the discovery, in 1797,56 though it was not until some years later that sufficient supplies of the mineral, lead chromate,57 were available to enable production in any capacity. Rosamund Harley says that it was a German, called Bollman, in his factory at Battersea, on the Thames, who first manufactured the pigment commercially in England, in the second decade of the nineteenth century.58 Vanherman, writing in 1829, said that it: surpasses every other yellow, for brilliance, beauty, and intensity of colour, either as a full, or in its gradations when lowered with white. There are two sorts manufactured, the orange and the lemon: the first is a rich warm tint; the latter is cool, and elegantly delicate. They are both standing articles, when properly prepared...those specimens which are light are to be rejected.59 Tingry indicated the up-to-date nature of his third edition, when he mentioned that "for some time past, it has been prepared artificially in this country",60 and claimed that it had superseded the use of patent yellow among coach-painters and housepainters. Its great advantage besides the "extreme richness and beauty of its colour" was that it possessed so much body: 54 (Gilder's ca.1827, 44). (Field 1850, 73). 56 (Tingry 1830, 107) 57 PbCrO4. 58 (Harley 1982, 100-102). 59 (Vanherman 1829, 28-29). 60 (Tingry 1830, 107) 55 50 APPENDIX FOUR (continued) that one pound of it will go as far as four pounds of patent yellow. It is so fine that it requires no laborious grinding, but will spread readily under the brush, and may be laid on with varnish; it is not poisonous like King's yellow;61 it will stand better than most other pigments; sulphuretted hydrogen-gas only impairing its beauty; against which, however, it may be protected by varnish. It makes also a beautiful green with Prussian blue. Care should be taken to obtain it pure, as it is apt to be adulterated with white lead or patent yellow, from both which it cannot be distinguished by the eye.62 Hay described it as "almost the only bright yellow now in use", commending the painter to purchase it from a manufacturer of high repute, and to pay as much as he could afford. He said that it came from the manufacturer in the form of "dry lumps".63 Prussian Blue The discovery of Prussian blue was announced in the memoirs of the Berlin Academy in 1710, but no directions were given for its preparation. A Dr Woodward published a recipe for making the pigment in the English Philosophical Transactions in 1724, explaining that he had received the formula from a friend in Germany. Late in the eighteenth century, it was learned that Prussian blue was a compound composed of "iron oxide with a peculiar acid." The composition of this acid - prussic acid - was finally made known by the Swedish chemist, Carl Scheele, in two essays published in 1782 and 1783.64 T.H. Vanherman, writing in 1829, stated that it "is the most general and useful blue we have, either for inside or out-door painting." He went on to say that combined with some of the reds, and most of the yellows, it "produces purples and greens, of numberless tints and gradations, but does not harmonise with patent yellow".65 Prussian blue was also used to correct the yellowing tendency of white paint. Tingry's later editor was very clear on this point: Besides the addition of the drier and oil of turpentine to white lead paint, it will be sometimes found very useful to add to it a small quantity of ground Prussian blue, to impart to it a very slight blue tinge, which in crowded and smoky towns, London in particular, without such addition, soon becomes of a dingy yellow.66 61 It may not have been quite as poisonous as king's yellow, but it is classified as a toxic pigment. 62 (ibid., 107-8). 63 (Hay 1847, 108). 64 (Penn 1966, 38). 65 (Vanherman 1829, 28). 66 (Tingry 1830, 270-71). 51 APPENDIX FOUR (continued) It is surprising that little mention was made of the tendency of Prussian blue to be destroyed by alkali,67 indeed Whittock referred to it being suitable for distemper, adding that in this case it was mixed with whiting and kept ready ground by the colourmen, under the name of "damp blue".68 Even after the introduction of an artificial ultramarine, Prussian blue was described as one of the most important pigments to the house-painter, being of: a deep and powerful colour, mixing well with white paint in the production of all tints of which blue is an element, and is at the same time decidedly transparent. It is, like most other manufactured pigments of various qualities.69 Ultramarine / French Ultramarine Ultramarine has been prized for many years for its beautiful blue colour, and since ancient times has been produced from the precious stone, lapis lazuli. Although mentioned by name in the majority of the early works on house-painting, there is no evidence of it having been in general use. John Smith, writing at the end of the seventeenth century, referred to it being "so vastly dear, that 'tis not to be used except in pieces of great price",70 and the author of the Pocket Manual, nearly one hundred and fifty years later, said its price "prevents its being introduced, unless very rarely indeed, into house painting".71 Pierre Tingry described it as being brought from Asia, particularly Persia, and the kingdom of Golconda.72 Other sources were listed as Siberia, Prussia, and Spain, although the stone produced from these countries was considered inferior. The price of ultramarine was recorded as being nearly as high, or even higher, than that of gold in the early nineteenth century.73 A couple of sources describe it being a preparation of "calcined lapis-lazuli",74 which is perhaps a confusion, in that the stone was heated in order to cause it to shatter when immersed in cold water, thus making it easier to grind, rather than in order to effect a change in appearance of the material. Except for its high price, ultramarine possessed several of the ideal properties of a pigment; it was suitable for use in both oil and water media, reasonably resistant to 67 Harley refers to the warning in Edward Dayes, The Works of the Late Edward Dayes, 1805 (Harley 1982, 73). The Painter's, Gilder's, and Varnisher's Manual is the only work examined to mention this (ibid., 38). 68 (Whittock 1827, 11). 69 (Hay 1847, 114). 70 (Smith 1687, 25). 71 (Pocket 1825, 100). 72 The old name for Hyderabad. SOED 1986, s.v. "Golconda." 73 (Tingry 1804, 303; Pocket 1825, 100). 74 (Nicholson 1823, 414; Whittock 1827, 11), 52 APPENDIX FOUR (continued) acids and alkalis, non-fading, and unaffected by moisture. It was also of a clean, slightly purple hue, unlike the darker greenish tints produced by the other blues used for house-painting. It is hardly surprising that a great effort was made to synthesize the pigment, and by the early years of the nineteenth century it was understood that sulphur was one of the chief components.75 The third edition of P.F. Tingry's Painter's and Colourman's Complete Guide recorded the successful production of artificial ultramarine by Guimet and Gmelin in 1828,76 and this pigment rapidly passed into general use. As with the natural product, there were different grades of the new pigment, and in the 1840s it was available at various prices, from five shillings to forty shillings a pound; the sort made by Guimet being decidedly the best.77 Charcoal / Blue Black Black, particularly Charcoal black was often added to white paint with the aim of removing the yellowish hue. Its slight blueness was also used to dull down a colour, especially a blue, without imparting any yellow / brown-ness, which would produce a greenish tinge. Willow was the standard source, but other products were burnt and crushed such as… Black from burnt vine twigs. Vine twigs reduced to charcoal gives a bluish black, which goes a great way. When mixed with white it produces a silver white, which is not produced by other blacks: it has a pretty near resemblance to the black of peach stones; but to bring this colour to the utmost degree of perfection, it must be carefully ground on porphyry.78 Yellow Ochre In common with the umbers, the earth pigments designated ochres (or oxides) saw constant use in house-painting, not only were they readily obtainable, but they encompassed a large range of hues, both in their natural and their calcined state. Tingry explained how readily they were obtained: Ochres are easily purified by simple washing. They mix readily with water, and the sand and stones which they contain being heavier than themselves, subside. The water, turbid with the ochre, is decanted, by making it pass into a trough lower than the vessel in which it was washed; when the ochre has 75 (Tingry 1804, 309). (Tingry 1830, 68). 77 (Hay 1847, 115). 78 (Tingry 1804, 350). 76 53 APPENDIX FOUR (continued) subsided the clear water is drawn off. The ochre is then taken out, and being dried is divided into small masses.79 John Smith mentioned the two basic types: Yellow Oaker, Is of two sorts; the one gotten in England, the other brought from beyond the Seas: the one is light Yellow, much like the colour of Wheat straw; the other is somewhat of a deeper colour.80 The second edition clarified this, by referring to the first as "Plain-Oaker" most of which was found in the Shotover Hills near Oxford,81 and the other as "SpruceOaker".82 The former displayed many of the best properties for a house-painting pigment, being described as a "Colour, that with pains, will grind very fine, it bears an excellent body, and resists the weather well".83 A darker ochre called "Common Brown or Bristol Oker" by Pincot was recommended for filling imperfections in the body work of carriages, presumably a greater capacity for drying rendered it useful for this purpose.84 This facility for drying could relate to the confusion mentioned earlier under Umber, where Tingry recorded the use of the name Brown ochre as a synonym for umber. Dossie pointed out that its colour was as a result of calcination "either by subterranean fires or artificially".85 As well as various sorts of yellow and brown, Tingry told us that: Many of the yellow ochres when burnt become of a red colour, and are then occasionally used for more delicate processes.86 In this state the pigment was generally known as light red. Hay accounted for the wide variety of colours, and told us that its price varied with the shade: They are a native earthy mixture of silica and alumina, coloured by oxide of iron, with occasionally a little calcareous matter and magnesia, and are found between strata of rock and sand. Ochre varies in...price from 1d. to 1s. per lb.87 79 (Tingry 1830, 74). (Smith 1676, 22). 81 A very detailed account of where to obtain this Oxford ochre is given in (Plot 1677, 55). 82 Dr. Harley suggests that spruce was an old form of Prussia or Prussian (Harley 1982, 89). 83 (Smith 1687, 22). 84 (Pincot ca.1811, 31). 85 (Dossie 1796, 1:104). 86 (Tingry 1830, 73). 87 (Hay 1847, 108). 80 54 APPENDIX FIVE BRUNSWICK GREEN An approximation to the colour employed on the cornice of the Rear Hall (GF3) can be found below. Approximate Munsell Reference: .38G 3.17/1.51 Approximate NCS88 Reference: 7412 G09Y L* 32.51 a* -6.66 b* 4.60 Observer conditions: CIE 10 (1964) Standard Observer. Illuminant: CIE A Standard Illuminant. Colour system: L*a*b*. 88 The NCS, or Natural Colour System, is a system of colour notation developed by the Scandinavian Colour Institute. The system had been licensed to ICI (Dulux) for the UK market and the colours can be seen in the Dulux Colour Dimensions Colour Atlas. The inclusion of this form of notation is purely for convenience and there is no suggestion that Dulux paints are being recommended for any redecoration carried out. [Dulux is a trademark of ICI.] 55 APPENDIX SIX GRAINING The imitation in paint of materials usually more expensive, or exotic, is thought to have been carried out since ancient times. As a means of decoration in interiors, Wyatt Papworth believed that: The processes of graining and marbling may be traced back as far as the time of James VI of Scotland, (1567-1603).89 The growing use of softwood for the building and internal cladding of houses in the late seventeenth century, led to an increased demand for the painted imitation of woods in this country. In his second edition, Smith referred to the imitation of "Olive Wood" and "Walnut Tree", and described them being veined over with a darker pigment.90 Ian Bristow's commentary on the seventeenth century decoration at Dyrham Park, in Gloucestershire, lists a number of painted woods, referred to in the accounts for the house; amongst them cedar colour, walnut colour, wainscot colour, and princes-wood colour.91 At first sight, such names might be understood to imply merely the colour and tone of these woods, but in this early period, either the colour or the imitation of a wood could be indicated,92 and it is usually context or recorded price that makes clear what had been carried out. A clue to some of the conventions of the day can be obtained from a letter of 1700 that accompanied three samples of graining prepared for a client: B, ye properest for a Bedchamber, if well performed (withe the pencil), and not tou mucht withe a brushe as is the common way, it will requier moor skill to paynes & will coste the moor, it represents a Light wall-nut tree color as I have seen some cabinets, and is proper for Antirooms & Bedchambers, the other A is a dark wallnut tree & will require a glossey varnishe and is very proper in Light chambers - C is a wainscot color muche in voge (since wright 89 (Papworth 1857-58, 9). (Smith 1687, 52). 91 (Bristow 1979, 141) Prince wood, or prince's wood, is a dark-coloured and lightveined timber produced by two West Indian trees, Cordia gerascanthoides and Hamelia ventricosa; also called Spanish elm. SOED 1986. S.v. "Prince-wood." Sir Roger Pratt, writing in the 1660s in his capacity as architect of Kingston Lacy Hall, Dorset, listed three of these four woods, making no mention, however, of wainscot (Gunther 1928, 282). 92 Smith, in dealing with umber, said that "it resembles the colour of new oaken wainscot the nearest of any colour in the world" (Smith 1687, 27). The earliest use of the word "graining", encountered by the author in a published text, is in a list of painting prices of 1786 (Pain 1786, 14). 90 56 APPENDIX SIX (continued) wainscot is subject to (since wright wainscot is subject to groe dark and in spots,) and generally speaking ye use at present is a flate color that of torteschall93 [italics mine].94 Not only could wood be represented in light and dark forms, but the finish could also vary in levels of sheen, some combinations being more appropriate than others. Olive wood and Walnut appear in the 1788 edition of Smith,95 yet by this time, the use of both of these woods was probably rather old-fashioned, being replaced by wainscot (or oak), and mahogany, which began to feature in price books of the period.96 No mention of graining is found in the first English edition of Tingry, of 1804, which is no doubt a reflection of both the book's continental origins, and the fact that the process had not yet become fashionable again. In England, however, during the next ten years, a rekindled interest in the technique of imitating woods in paint developed. Papworth recalled a friend saying that: …the doors of the Chapel in Conduit Street, Bond Street, attracted much attention from the novelty of their being grained to imitate wainscot, done perhaps, about the year 1810 when a new front was given to the building. From some letters in my possession I find that mahogany was imitated in 1815, and maple wood in 1817.97 Price books of the time reflect this growing interest in fancy woods, and Laxton's The Improved Builders' Price Book of 1818, contains an early and wide range, amongst them: new wainscot, white oak, old or dark oak, air wood, satin wood, Hispaniola mahogany, coromandel wood, amboyna wood, yew tree and black rose wood.98 By the 1820s the interest was such that even Butcher had changed the original list of woods mentioned by Smith, deleting olive wood, and adding mahogany and wainscot99 to the walnut already listed. Smeaton, reflected this, and added satin wood and two varieties of rose wood.100 Whittock confirmed the approximate date of this renewed enthusiasm, in his work of 1827: The very great improvement that has been made within the last ten years [italics mine] in the art of imitating the grain and colour of various fancy 93 "Flate color" probably refers to the low sheen on tortoiseshell. (Winde 1700, quoted in Beard 1981, 60). 95 (ibid., 5). 96 (Pain 1786, 14; Taylor 1813, 125). 97 (Papworth 1857-58, 9). 98 (Laxton 1818, 99). 99 (Butcher 1821, 3). 100 (Pocket 1825, 105, 109, 160-62; Gilder's ca.1827, 49, 51-52, 189-90). 94 57 APPENDIX SIX (continued) woods and marbles, and the facility and consequent cheapness of this formerly expensive work, has brought it into general use; and there are few respectable houses erected, where the talent of the decorative painter is not called into action, in graining doors, shutters, wainscots, &c..101 He went on to tell us that: Much has certainly been done by modern decorative painters, within the last fifteen years.102 One of the features of this new trend was the extent to which some house-painters developed the art of imitating the natural product. Whereas the late seventeenth century representations of woodgrain are almost theatrical in their handling, in that they only read as wood from a distance,103 the early nineteenth century grainer was encouraged to observe nature, for the "foundation of his future proficiency",104 and to produce realistic specimens. Whittock, as well as producing actual coloured examples of many of the popular wood effects in his The Decorative Painters' and Glaziers' Guide, gave an indication of where such woods might be used. Writing some twenty years later, Hay showed how this had changed by the end of the period: [Of Oak, or Wainscot] 1827 Oak is the wood that is commonly preferred to any other for outside work...preferred to any other wood for doors and shutters where strength is required. The decorative painter, therefore, who considers propriety, will generally recommend the imitation of oak for street doors, shutters, &c..105 1847 Imitation oak has been greatly used in halls, staircases, libraries, and diningrooms, and it will be observed, from the description of the process, that it must be very durable.106 It appears that the fashion for a wide variety of fancy woods began to wane within a few years, and Vanherman told us that, having "formed a considerable part of the 101 (Whittock 1827, 20). (ibid., 46). 103 See the walnut graining, carried out by Sergeant Painter Robert Streater, on the panelling of Apartment 7 at Hampton Court Palace, and recently exposed by Catherine Hassall. 104 (Whittock 1827, 20) 105 (Whittock 1827, 20). 106 (Hay 1847, 140). 102 58 APPENDIX SIX (continued) decorative system", graining and marbling are "now giving place to the plain and simple".107 The two reasons given for this change being, the: additional expense to the painter's bill, and the short-lived beauty they exhibit; for being generally executed in water colours, and then varnished, should this covering crack and chip, the work will consequently look shabby, ragged, and mean.108 He added that: Graining, like diamonds in portrait painting, should be sparingly employed for its scarcity constitutes in a great measure its value.109 The process of graining was, inevitably, labour intensive. Papworth, relying heavily on Hay's description,110 said that: in the first instance [it is] the same as for ordinary painted work, but it requires more care in obliterating the marks of the brush. The last coat, instead of being flatted, is composed of equal portions of oil and spirits of turpentine, and is brought up to the colo[u]r characteristic of the wood to be imitated.111 When this ground-work was quite dry, a thick layer of a semi-transparent paint was prepared, in the colour of the wood to be imitated. This was laid smoothly over the ground-work, after which a graining comb,112 made of steel, ivory, horn, or wood, was: drawn through this composition, by which it is separated upon the groundwork into minute portions, representing the grain of the wood.113 The heart grain and flowers would then be wiped out using a thumb nail, or a piece of horn, covered with a cloth. This was left to dry before being overgrained with a transparent layer of oil or water colour. Two or three coats of an oil varnish based on a resin such as copal would then be applied. 107 (Vanherman 1829, 40). (ibid.). 109 (ibid., 41). 110 (Hay 1847, 137). 111 (Papworth 1857-58, 9). 112 These combs were made in a range of sizes, a number being illustrated on plate II, facing page 22 of Whittock's The Decorative Painters', and Glaziers' Guide. Tingry tells us that they were obtained at the comb-makers in London (Tingry 1830, 282). 113 (Hay 1847, 138). 108 59 APPENDIX SEVEN DISTEMPER An inexpensive matt finish that was widely used on plaster walls and ceilings was known as distemper, or size colour. This was made with whiting, or ground chalk, bound with a glue size made from animal bones, horns or skin, and tinted with a suitable pigment. It had many advantages: cheapness, the wide range of tints achievable in it, the ease with which it could be made and applied, and the speed of its application. It was also used when the colour of the intended scheme could only be obtained using pigments that were liable to change in an oil medium. Being loosely bound, it could be washed off for renewal, but it was not particularly durable, and was neither washable nor suitable for areas of heavy traffic, hence the modern name of soft distemper. This mode of beautifying rooms is cheap and the appearance very agreeable; properly managed is within any capacity, and in my opinion is preferable to paper, as vermin will not harbour as they do behind the chassims of papered rooms...The proper consistence for use is rather thicker than cream, and always used in a chilled state...and, in all walls intended to be coloured it is necessary first to have them a good white with common White-wash,114 with nothing but size and whiting; the colours you should buy in a damp soft state...and these again you should thin and work smooth with a little water previous to mixing with the size, and observe to make a trial on a piece of card or paper, and dry it before the fire before you colour your wall as you will see the effect, and prevent being disappointed...Old papered rooms where the paper is in a firm and good state, may be coloured in this way...The convenience of colouring rooms in this way is so ready and attended with so little dirt or inconvenience, that a room may be compleated [sic] and dry in a day...in all cases have your colours smooth and well mixed before you lay them on, be as quick as you can in using them, laying them as even as you possibly can, and observing to leave them lay'd off one way, as the marks off the brush will not then be so much observed.115 As well as being cheap and relatively easy to apply, it had one great advantage over an oil-based paint, and that was its permeability to moisture. When one considers that new brickwork has been estimated to contain about thirty gallons of water per cubic yard, and lime plaster contains nearly half a gallon in each of its three coats per square 114 Tingry gave an account for the preparation of this: If plain distemper is to be applied to a wall or partition covered with plaster, some Spanish white or white of Troyes is thrown into water, where it may be easily broken and diluted if allowed sufficient time to soak. A little charcoal black, diluted separately in some water, is then added, to correct the too great whiteness, and to prevent it from becoming yellow. To the water mixed with white one half of a solution of strong glue in water is added, exceedingly hot, but not boiling, and it is then applied with a brush. The coatings are repeated till the tint has become uniform (Tingry 1830, 247). 115 (Pincot ca.1811, 19-21). 60 APPENDIX SEVEN (continued) yard,116 a new building would have a large amount of water present in it. Some of this would be permanently bound chemically, but many tons would slowly evaporate during the first few years, and not all of the water vapour would travel outwards. If obstructed by an impermeable layer of paint, the pressure built up underneath would cause the paint to be pushed off the wall. In view of this potential problem, it is perhaps surprising that only one author draws attention to it. Peter Nicholson, in his An Architectural Dictionary spoke of distemper as a stop-gap measure: Painting in distemper, or water-colours mixed with size, stucco, or plaster, which is intended to be painted in oil when finished [italics mine]; but not being sufficiently dry to receive the oil, may have a coating in water-colours, of any given tint required, in order to give a more finished appearance to that part of the building.117 He continued: It will not require less than two coats of any of the foregoing colours in order to cover the plaster, and bear out with an uniform appearance. It must be recollected, that when the stucco is sufficiently dry, and it is desirable to have it painted in oil, the whole of the water colour ought to be removed; which may be easily done by washing; and, when quite dry, proceed with it after the directions given in oil painting on stucco.118 Nicholson was also aware of the implications of this long drying-out time, and in a comment on speculative building said: Perhaps, in general cases, where persons are building on their own estate, or for themselves, two or three years are not too long to suffer the stucco to remain unpainted; though frequently, in speculative works, as many weeks are scarcely allowed.119 Dr Ian Bristow refers to the common practice, until quite recently, of decorating the plasterwork in newly finished interiors first in a porous water-based paint, pending final decoration in oil a year or two later. He cites the accounts for Henry Pelham's house in Arlington Street, London, which show that the whole of the staircase had been painted in this way by January 1746 and was not decorated in oil until about two years later.120 Thomas Cubitt, the builder, advised his clients to live "under builder's finish" for two years to prevent expensive decoration from being spoiled.121 116 Source: The Paint, Oil and Chemical Review, Chicago. 101, No.23, 15-16, November 1939; quoted in (Hess 1951, 334). 117 (Nicholson 1819, II:416). 118 (ibid.). 119 (ibid.). 120 (Bristow 1996, 111). 121 (Hobhouse 1971, 385) quoted in (Wilson and Mackley 2000, 196-97). 61 APPENDIX SEVEN (continued) It would seem that, in a new house, two to three years was also about the life of a coat of distemper on walls, as Hay warned that it lasted only as long as the size withstood the action of the atmosphere, "unless when the surface of the plaster has been rendered impervious to absorption by one or two coats of paint"122 Ceilings, throughout the nineteenth century, were generally treated with a water-based coating such as a size-bound distemper. A repaint would entail complete removal and washing down of the previous coat. As a precaution against incomplete removal, Pincot recommended the use of a size binder to stick "fast all the dirt left after washing".123 Oil Bound Water Paints / Washable Distempers Although "improved" recipes for water-based paints appeared throughout the nineteenth century, it was in the early 1870s that a significant breakthrough was made. The introduction of Charlton white, or Orr's white (lithopone - which was a co-precipitate of zinc sulphide and barium sulphate), gave the industry a pigment that was a very pure white with a high degree of opacity. This marked a significant stage in the development of what might be called emulsion paints, or oil-bound water paints. These products were often called "washable" distempers, and saw great use on plaster surfaces until recent years, when they have all but been replaced by the modern vinyl matt emulsions. By "oil-bound", it is meant that the paint was an oil-water-emulsion, in much the same way that milk is. Water and oil were combined with a solution of soap or a caustic alkali (such as lime) which saponified the oil, and the mixture was agitated until the oil broke down into tiny globules which remained in suspension as an emulsion. The pigment part of the paint usually consisted of lithopone, with extenders such as barytes or Paris white (chalk), and the vehicle largely of linseed oil or a long-oil varnish. Oil-bound water paints, such as the well known Walpamur, dried first by evaporation of the water content, and then by oxidation of the oil. Evaporation took place rapidly; however, oxidation is a slower process, sometimes taking several months to reach a maximum degree of hardness. As the ability of the coating to withstand water was related to its hardness, it needed to be protected for the first few months after application. 122 123 Meaning an oil paint. (Hay 1847, 154). (Pincot ca.1811, 14). 62 APPENDIX SEVEN (continued) Oil-bound water paints were available in a paste form, and could be thinned either with water or with petrifying liquid. This latter was generally a dilute solution of the emulsion used as a binder for the water paint itself, and the effect of adding it was to increase the oil content of the coating. Water paints could be used outside, in sheltered locations, but only when thinned with petrifying liquid. These early emulsion paints were generally supplied in a stiff paste, which was thinned in water to a brushable consistency for application. On evaporation of the water, the paint dried to a porous film, with the glue - often in the form of casein acting as a temporary binder during the drying of the oil, which finally hardened the film so that it became moderately wipeable. Unfortunately, these early form of emulsions - known variously as oil-bound waterpaints, oil-bound distempers, or washable distempers, had a number of weaknesses. a) The first problem became evident when a number of decorative schemes were applied on top of them. The strength of the bond of water paint was less than that of oil paint and, although the coating had some resistance to water, it was absorbent, and the liquid in a new coat would soften it to some extent and cause it to swell. Water paint, moreover, was applied in thicker and heavier coatings than oil paint; in drying, it contracted strongly and, in doing so, exerted a considerable pull on the underlying film, weakening the grip of any parts which were not firmly attached to the surface. A substantial strain was placed on the bond of the old coating. Two, three, or even more coats could be safely applied on occasion, but there came a time when the weight and stress were too great and cracking and flaking took place at the weakest points in the system. b) Unlike a soft distemper, which had to be removed when repainting, an oil-bound water-paint was fairly well adherent, and would often fool the decorator into leaving it in place. The presence of an early scheme of oil-bound water paint in a sequence of coatings should not necessarily be a cause for alarm, but care must be exercised in the redecoration. 63 APPENDIX SEVEN (continued) Sample specification for the application of an oil-bound water-paint on new plaster From: Jenson and Nicholson Ltd. Paint and its Part in Architecture. London, 1930. p.387 WALLS, NEW, INTERIOR To be finished any colour not Affected by Lime CONDITION: Finished with Portland Cement, Parian, Sirapite, Keene's, Medina, or other Patent Cements. Type of finish required: Good: Washable Water Paint or Washable Distemper The surface to be freed from dirt, grease or other foreign material incidental to building operations. All defects to be made good with material similar in composition to that of the main surface. The surface to receive one coat of sharp stuff [italics mine] composed of white lead with a vehicle of 90 per cent American turpentine and 10 per cent linseed oil, to be applied immediately the plasterer has completed trowelling and prior to the setting of the plaster. The surface is to receive two coats of washable distemper of approved shade, applied strictly in accordance with the manufacturers' printed instructions. 64 APPENDIX EIGHT PRIMING AND PAINTING WOOD The priming of the wooden elements in an early eighteenth century building can often assist with their dating. Unfortunately, too few areas of unstripped early woodwork survive in the building to demonstrate this. However, it is interesting to see that the certain elements had been primed with a red rather than a white primer. The use of white lead in the priming coat on timber usually suggests a date from the mid-eighteenth century, prior to that it was more usual to apply Spanish brown, a natural red earth (red oxide) pigment, "well ground and mix'd very thin with Linseed Oyl".124 As Ian Bristow has pointed out, this change to a paler primer probably reflected the change in taste that took place in the first half of the eighteenth century, when white became the almost universal colour for joinery in fine interiors.125 The use of a red primer at xxxx reflects a somewhat old-fashioned practice, and suggests that the general decoration was likely to have been darker than the more typical light schemes being introduced some twenty years before the house was built. Once the primer had been applied and allowed to dry, the nail holes and other superficial irregularities were filled in. This was done with putty, which was made out of whiting and linseed oil, the boiled version, as recommended by Field, probably drying more quickly.126 The practice of filling surface imperfections before priming, as opposed to after, seems only to have been advocated by Smith,127 no doubt it was soon discovered that the substrate tended to absorb the linseed oil from the putty, causing it to shrink and fall out. David Hay, writing in the 1840s, provided the clearest description of the process of painting once the primer had been applied, saying that the "second coat should be made thicker than the first", but that this: will depend upon the degree of absorption that has taken place in the application of the first coat. Sometimes a great proportion of it bears out - that is, drys with a gloss; in which case the second coat ought to have a good body of white lead in it. At other times, it is found that no part of the first coat bears out, and that even some portions of it have had the oil so completely absorbed as to leave nothing on the surface but a dry powder. When this is the case, it is a sure sign that the plaster is of such a nature as to receive the full benefit of the oil; and, that it may be properly saturated, the paint for the second coat is kept rather thin. Before applying this coat, the work should be rubbed with fine sand-paper. If the second coat bears out properly when dry, the third coat will form the groundwork for the finishing process; but should it not bear out 124 (Smith 1723, 43). The recipes for primers given in two works of the latter half of the eighteenth century form the basis for this statement (Watin 1778, 87; Secrets 1780, 93). 125 (Bristow 1994, 48). 126 (Field 1850, 152). 127 (Smith 1723, 43). 65 APPENDIX EIGHT (continued) properly, the work will be understood to require five coats; and, therefore, another coat of plain oil-paint is applied.128 The third coat that formed the base for the "finishing process" referred to was composed of white lead, diluted with an equal proportion of linseed oil and turpentine. The latter was added because of its ability to hold a large amount of solids in suspension, thus increasing the density of the coat. If the final colour was to be other than white, it was usually at this stage that pigment was added, the tint being darker than that of the finish coat. Both Pincot and Hay referred to the use of a cheap undercoat which was known as clearcole. This was generally chalk mixed with size, although sometimes lead white, ground in water, was included. The former explained that it: is a cheap mode of painting well calculated for servant's rooms, attics, and kitchens, old houses, small tenements, or ship's cabins, where dispatch is necessary, or where it is necessary to paint often.129 Whilst unquestionably a cheap process, it tended to cause later problems, and subsequent layers of paint could chip off, necessitating the complete removal of the old paint.130 128 (Hay 1847, 124-25). (Pincot ca.1811, 18). 130 (Hay 1847, 127-28). 129 66 APPENDIX NINE SAMPLE ANALYSIS TECHNIQUES Sample Preparation Procedures Pigments Samples of pigments from specific paint layers were permanently cast in Cargille Meltmount (with a refractive index of 1.66) onto microscope slides. The pigment samples were examined at 500x and 1000x magnifications under both transmitted, and plane polarized light. The pigments were identified using polarized light microscopy (PLM) techniques which allows identification of different pigment particles based on the characteristics of particle shape, colour, refractive index, and optical properties. In certain instances, where further confirmation was required, energy-dispersive X-ray analysis (EDX), using the scanning electron microscope, was carried out. Cross Sections Samples of finish coatings and substrates were removed from representative surfaces in the rooms being examined with a scalpel, craft knife or dental drill. Depending on the material, the samples varied in size from 5mm to 10mm. The samples were divided before casting, leaving a portion of the sample available for future testing. Samples were cast in small cubes in silicon rubber moulds using clear casting polyester resin (Alec Tiranti Ltd, Reading, Berks.). The resin was allowed to cure for 24 hours at room temperature and under ambient light. The cubes were then cut in half to expose the cross sections, and wet polished with 240, 400, 600 and 1200 grade wet-and-dry papers. The cross section samples were examined under visible light using a Brunel metallurgical microscope at 200x and 500x magnifications. Those that appeared to have the full sequence of layers, i.e. that displayed an intact sequence from the substrate through to the final scheme, were examined particularly closely. These intact samples were compared with those samples that were distorted or unclear, and with those that were incomplete. The combined information has provided the details in this report. The cross sections were photographed with Kodacolor Gold Plus ASA 200 colour print film, and the resulting photographs were labelled and laid out in sequence to allow direct visual comparisons. The best photomicrographs for each area have been included with this report. Most photographs were taken at 200x, and 500x, although other magnifications have been used. Many of the photographs have been digitally enlarged in order to fit the page and show more details. 67 WORKS REFERRED TO All works that were published appeared first in London, unless otherwise indicated [Anon.] Valuable Secrets Concerning Arts and Trades. 2nd (?) edn. 1780. Baty, Patrick. "The Role of Paint Analysis in the Historic Interior," The Journal of Architectural Conservation, March 1995 (1). Beard, Geoffrey. Craftsmen & Interior Decoration in England, 1660-1820. John Bartholomew, 1981. Blakey, R.R., and J.E. Hall. "Titanium Dioxide" in Pigment Handbook. Vol 1 (ed. Peter A. Lewis). New York, John Wiley. 1988. Bristow, Ian C.. "The Balcony Room at Dyrham" in National Trust Studies 1980 (1979). ________. "House Painting in Britain: Sources for American Paints, 1615 to 1830." Paint in America - The Colors of Historic Buildings, ed. Roger W. Moss. The National Trust for Historic Preservation, Washington, D.C. 1994, 43-53. ________. Interior House-Painting Colours and Technology 1615-1840. Yale University Press, 1996. Chatfield, H.W. Paint and Varnish Manufacture. Charles Griffin. 1955. Clausen, H.. "Zinc-Based Pigments" in Pigment Handbook, vol. 1. New York. John Wiley & Sons. 1988. Donaldson, Thomas Leverton. Handbook of Specifications. 1859. Dossie, Robert. The Handmaid to the Arts. 2 vols. Rev. ed. 1796. Feller, Robert L.. "Barium Sulfate - Natural and Synthetic." Artists' Pigments. A Handbook of Their History and Characteristics (Vol. 1), (ed.) Robert L. Feller, 47-64. New York, Cambridge University Press. 1986. Gettens, Rutherford J., Robert L. Feller, and W.T. Chase. "Vermilion and Cinnabar" in Artists' Pigments: A Handbook of Their History and Characteristics. Vol. 2. (ed. Ashok Roy). Oxford, OUP. 1993. Gunther, R.T.. The Architecture of Sir Roger Pratt. Oxford, Clarendon Press. 1928. Harley, Rosamund. Artists' Pigments c.1600-1835. 2nd edn. Butterworths. 1982. Hasluck, Paul N. (ed.). Cassell's House Decoration. A Practical guide to Painters' and Decorators' Work. Cassell and Co. 1913. 68 Hay, D.R.. The Laws of Harmonious Colouring Adapted to Interior Decorations, with Observations on the Practice of House Painting. 6th edn. Edinburgh and London. William Blackwood and Sons, 1847. Heaton, Noel. Outlines of Paint Technology. Charles Griffin & Company Ltd. 3rd edn. 1948. Hess, Manfred. Paint Film Defects their Causes and Cure. 1st English edn. Chapman & Hall. 1951. Hobhouse, Hermione. Thomas Cubitt; Master Builder. 1971. Hurst, A.E.. Painting and Decorating. Charles Griffin & Company Ltd. 1949. Ionides, Basil. Colour in Everyday Rooms. Country Life. 1934. Jennings, Arthur Seymour, and Guy Cadogan Rothery. The Modern Painter and Decorator. Caxton Publishing Company. 1921. Laxton, W.R.. The Improved Builder's Price Book. 2nd edn. 1818. 1869. Leuchs, J.C.. Anleitung zur Bereitung aller Farben und Flüssigkeiten. Nuremberg. 1825. Lewis, Peter A.. Pigment Handbook, vol. 1. New York. John Wiley & Sons. 1988. Nicholson, Peter. An Architectural Dictionary. Vol II, 1819. ________. The New Practical Builder. Appended is The Practical Builder's Perpetual Price Book. 1823. Pain, William, & James. British Palladio. 1786. Papworth, Wyatt. "An Attempt to Determine the Periods in England, when Fir, Deal & House Painting were First Introduced." Transactions of the RIBA. 1st series, vol. viii: 1-13. 1857-8. Pincot, John. Pincot's Treatise on the Practical Part of Coach and House Painting. ca.1811. Plot, Robert. Natural History of Oxfordshire. Oxford and London, 1677. [Smeaton, G.A.]. The Painter's and Varnisher's Pocket Manual. 1825. ________. The Painter's, Gilder's, and Varnisher's Manual. ca.1827. Smith, John. The Art of Painting. (The Art of Painting in Oyl.) 1676. 2nd edn. 1687. 9th edn. 1788. 69 [SOED] The Shorter Oxford English Dictionary. 3rd edn., rev., Oxford. Clarendon Press. 1986. Taylor, I. Builder's Price Book. 1813. Tingry, P.F.. The Painter's and Varnisher's Guide. 1804. ________. Painter's and Colourman's Complete Guide. 1830. Vanherman, T.H.. Every Man his own House-Painter and Colourman. 1829. (Originally published as: The Painter's Cabinet, and Colourman's Repository. 1828.) Watin, Jean Felix, L'art du peintre, doreur, vernisseur. Liege, nouvelle edition, 1778. Whittock, Nathaniel. The Decorative Painters', and Glaziers' Guide. 1827. Wilson, Richard and Alan Mackley. Creating Paradise. Hambledon. 2000. Assorted Unpublished Documents Patrick Baty. "The Commercial Rooms, Corn Street, Bristol. A Report on an Examination of the Original Paint in the Trading Areas of the Building". 26th April 1995 (2). A report produced for xx Plc. ________. "Civil Service Rifles War Memorial: Somerset House, London WC1. A Report Following an Examination of the Painted Surfaces". 4th September 1999. ________. "1 Lewes Crescent, Kemptown, Brighton. A Brief Report on Observations Following an Initial Examination of the Paint in Several Areas". 26th March 2000 (1). ________. "An Analysis of the Paint on the Exteriors of 26-31 Charlotte Square, Edinburgh". 3rd June 2000 (2). ________. "xx House, xx xx, Wiltshire. A Report on the Decoration Following an Examination of the Painted Surfaces in Various Areas". 26th Dec 2000 (3). xxx.. xxx Conservation Plan. January 2000. 70
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