META-PEGMATITES IN THE PRIJAKTPOLINIK COMPLEX (EASTERN ALPS) Thomas REPOLUST 1) Ralf SCHUSTER 2) Georg HOINKES 1) Christoph A. HAUZENBERGER 1) 1) 2) Geological Survey (Geologische Bundesanstalt), Neulinggasse 38, A-1030 Vienna, Austria email: Ralf Schuster <[email protected]> Geologische Bundesanstalt 100 km Munich Linz section 2 1 03R37 Grt41 A 1.0 0.9 0.9 0.8 0.8 0.7 0.7 0.6 0.6 0.5 0.4 0.9 XFe/(XFe+XMg) 0.8 XFe 0.7 XMn XMg XCa 0.0 0 200 400 600 800 1000 1200 1400 distance [µm] 03R37 Grt82 Innsbruck 1.0 1.0 0.9 0.9 0.8 0.8 0.7 0.7 0.6 0.6 0.6 0.6 0.5 0.5 0.5 0.5 0.5 0.4 0.4 0.4 0.4 0.4 Bozen Verona Enns SEMP TriestMur XFe 0.3 0.2 0.2 0.1 0.1 0.0 0.0 200 D 400 600 distance [µm] 03R37 Grt42 0.8 XFe 0.7 0.3 0.3 0.2 0.2 0.2 0.1 0.1 0.0 1000 0.0 800 E XMg XCa 0.1 0.0 0 200 400 03R37 Grt41 600 800 1000 1200 1400 distance [µm] F 1 1000 µm 1000 µm Villacher Alpe S Zagreb Nockberge 0.9 0.3 XMg XCa 0 XFe/(XFe+XMg) XMn XMn 0.3 A Traun XFe/(XFe+XMg) 1.0 Fig. 3: Characterisation of garnet from sample 03R37 A) cut hand specimen of mylonitic pegmatite, B) thin section, C) BSE-image with section lines, D-F) element distribution of selected garnet crystalls. Explanation see text. Graz Niedere Tauern C 1000 µm 1.0 1.0 0.1 Sopron B 2 cm 0.2 Salzburg 03R37 Grt42 1 0.3 Vienna Nördliche Kalkalpen 2 1mm µm 1000 The northeastern part of the Kreuzeck Mountains (Carinthia, Austria) is built up by the Prijakt-Polinik Complex, which is part of the Koralpe-Wölz nappe system (Austroalpine unit) according to SCHMID et al. (2004) (Fig. 1A, 1B). This Complex experienced preAlpine metamorphic imprints and an up to eclogite-facies eo-Alpine (Cretaceous) metamorphic overprint. It consists of paragneisses and micaschists with intercalations of retrogressed eclogites, amphibolites and minor orthogneisses. As in other Austroalpine units deformed and partly mylonitised meta-pegmatites occur. According to Rb-Sr data by HOKE (1990) they are Permian in age. In this study, two mylonitised meta-pegmatites from the crests north of Mt. Polinik (2784 m) (Fig. 1C, Fig. 2) were investigated. The aim of the study is to get information on the magmatic age of the rocks and the effects of the structural and metamorphic overprint. GRAZ Institut für Erdwissenschaften, Karl-Franzens-Universität Graz, Universitätsplatz 2, 8010 Graz, Austria INTRODUCTION N UNI Drau Gail PAL Venedig ADRIA Geologische Bundesanstalt C 03R36 Grt32a1 2 03R36 Grt32a2 B Obervellach Gmünd Stall Möllbrücke Spittal a.d. Drau Oberdrauburg Greifenburg Apulian plate Southalpine unit Austroalpine unit Upper Austroalpine subunit Drauzug-Gurktal nappe system Ötztal-Bundschuh nappe system Juvavic nappe system Tirolic nappe system Noric Nappe Wölz-Koralpe nappe system Bajuvaric nappe system Silvretta-Seckau nappe system GWZ exclusively Noric nappe Lower Austroalpine subunit Meliata-Hallstatt zone 1 2 A 1000 µm 1.0 1.0 0.9 0.9 0.8 0.8 0.8 0.8 0.7 0.7 0.7 0.7 0.6 0.6 0.5 0.5 0.4 0.4 0.4 0.3 0.3 0.3 0.3 0.2 0.2 0.2 0.2 0.1 0.1 0.0 0.0 1.0 XFe/(XFe+XMg) 0.9 0.6 XFe 0.5 XCa XMg Mauthern 0.0 0 200 400 03R36 Grt32a2 25km Hermagor SAMPLE LOCALITY The samples were collected from the crests north of Mt. Polinik in the area of the 2nd and the 3rd Mörningkopf (Fig. 2). Sample 03R36 is an 0.5 m thick mylonitised pegmatite directly from the crest at 2265m altitude (WGS83 E 13°10'23'', N 46°54'23''). The second sample 03R37 is a loose-block from below the rock walls west of the crest in 2130 m altitude (WGS83 E 13°10'07'', N 46°54'24''). In the wall an about 1 m thick mylonitic pegmatite layer is situated. (WGS83 E 13°10'07'', N 46°54'24'') 600 800 distance [µm] D 0.9 0.6 XFe 0.5 XMn 0.4 Fig. 4: Characterisation of Garnet from sample 03R36 A) thin section, B-C) BSEimage with section lines, DE) element distribution of selected garnet crystalls. Explanation see text. 0.1 XCa XMg 0.0 200 0 400 03R36 Grt32a1 600 800 distance [µm] 1000 E Sm-Nd GEOCHRONOLOGY For dating with the Sm-Nd method a whole rock powder and three garnet fractions of sample 03R37 were analysed. Except of fraction Grt1 (Fig.5A), which was represented by chips from the central part of crystals without rims, the two other fractions (Grt2, Grt2b) were represented by idiomorphic garnet crystals of 0.2-0.3 mm in size (Fig. 5B). From sample 03R36 also idiomorphic garnet crystals of 0.2-0.3 mm in diameter and feldspar were used. With respect to the chemical zoning pattern of the garnet fraction, Grt1 contains large percentages of core composition, whereas the other fractions contain large amounts of the rims with XCa>XMg. The core shows lower Sm and Nd contents and a higher 147Sm/144Nd ratio with respect to the rims (core = 5.32; rim = 0.38-1.23) (Table 1). Garnet-whole rock isochrons yielded a Permian age of 267±3 Ma for Grt1 and 239±18 Ma for Grt2+Grt2b from sample 03R37 (Fig. 5C). For feldspar and garnet of sample 03R36 an age of 248±3 Ma was calculated (Fig. 5D). Fig. 2: A) Orthophoto and DHM showing the sample localities along the crest between Mt. Polinik and Polinik hut. 03R36 (WGS83 E 13°10'23'', N 46°54'23'') Nd Sm [ppm] [ppm] 03R36 Fsp 0,14 0,03 03R36 Grt 0,41 0,82 03R37 WR 0,48 0,15 03R37 Grt1 0,13 1,12 03R37 Grt2 0,41 0,61 03R37 Grt2b 1,66 1,05 147 144 Sm/ Nd 143 144 Nd/ Nd 2Sd(m) 0.522 03R37 0.520 mylonitic pegmatite, Prijakt-Polinik Complex Kreuzeck Mountains Carinthia a 0.518 0.516 143 sample 2 67 Grt1 ± 3 M 23 1 ± 9 a M 8 0.514 0,139 1,231 0,191 5,323 0,910 0,385 0,512017 0,513786 0,512201 0,521167 0,513332 0,512484 1,20E-05 5,75E-06 5,37E-06 9,96E-06 8,88E-05 7,17E-05 Grt2b Grt2b 0.512 Io 0.51187 ± 1 Io 0.51190 ± 2 WR 0.510 A 1.0 2.0 Sm/ The meta-pegmatites are characterised by a mylonitic foliation (Fig. 3A). They consist of quartz, albite-rich alkalifeldspar (Ab98), muscovite, tourmaline and almandine-rich garnet. Quartz forms rods consisting of grains with a crystal preferred orientation and grain boundary migration. The alkalifeldspar is present as fine-grained, totally recrystallised layers and patches. Partly it is transformed into metamorphic white mica with a grain size of about 1mm. These micas exhibit a significant paragonite component (Ms80, Pa20). Mica fishes of up to 2 cm in diameter represent relics of the magmatic muscovite. Garnet is present as idiomorphic crystals. They formed porphyroclasts during the mylonitic deformation. In sample 03R37 (Fig. 3A, 3B, 3C) it is 0.2-3.0 mm in diameter and shows a chemical zoning with cores characterised by homogeneous chemical composition (Alm66, Sps31, Grs2, Prp1) and rims with increasing Fe and decreasing Mn contents (Alm71, Sps22, Grs5, Prp3) (Fig. 3D, 3E, 3F). Fe and Mn show more or less continuous opposite trends in the outermost 0.1-0.4 mm. In some of the measured profiles (e.g. Fig 3E 03R37 Grt42) the Ca-content shows an abrupt increase in the outermost 0.1 mm. In these rims the XCa is higher than XMg. In sample 03R36 (Fig. 4A-E) garnet is up to 1.5 mm in diameter and exhibits homogeneous chemical composition throughout the whole crystals (Fig. 4D, 4E). With respect to the other sample the Mn content is somewhat higher and the Fe-content is lower (Alm55, Sps42, Grs2, Prp1). The XCa is always higher than Xmg. Nd 0.5136 mylonitic pegmatite, Prijakt-Polinik Complex Kreuzeck Mountains Carinthia 0.5132 24 8 ± 4 Fsp 0.2 6.0 C Grt 0.5128 0.5116 0.0 5.0 4.0 03R36 0.5120 B 144 0.5140 0.5124 PETROLOGY 3.0 147 Nd/ 144Nd Table 1: Sm-Nd data of analysed whole rock, feldspar and garnet from samples 03R36 and 03R37. 0.0 143 Mt. Polinik (2784 m) 1000 Nd/ 144Nd 03R37 XFe/(XFe+XMg) European plate (southern margin) Fig. 1: A) Tectonic map of the Eastern Alps according to SCHMID et al. (2004). The red square shows the area of Fig. 1B. B) Tectonic map showing the sample locality in the PrijaktPolinik Complex marked by the arrow. C) Eastern slopes of Mt. Polinik (2784 m). Polinik hut 1.0 XMn 0.1 Penninic nappes C B a M Fig. 5: Mineral seperates and Sm-Nd isochron ages of mylonitic pegmatites: A) 0.2-0.3 mm sized garnet fragments of sample 03R37 (Grt1), B) 0.2-0.3 mm sized idiomorphic garnet of sample 03R37 (Grt2a), C) mineral isochrons of sample 03R37, D) mineral isochron of sample 03R36. Explanation see text. Io 0.51179 ± 2 0.4 0.6 147 Sm/ 0.8 144 Nd 1.0 1.2 1.4 D DISCUSSION AND CONCLUSION With respect to the best defined age measured form the chips representing the core of the garnet from sample 03R37 the pegmatites formed in Permian times at 267±3 Ma. This age is in agreement with those published by HOKE (1990). The age values measured on the idiomorphic garnets represent the age information of the more Ca-rich rim composition. Their Early to Middle Triassic ages (239±18 Ma, 248±3) are significantly lower than the formation age of the magmatic rock. Based on the chemical zoning pattern the rims are influenced by postmagmatic processes. Most likely these processes include overgrowth and diffusion which occurred in Permo-Triassic and/or Cretaceous times. REFERENCES HOKE, L. (1990): The Altkristallin of the Kreuzeck Mountains, SE-Tauern Window, Eastern Alps - Basement Crust in a convergent plate Boundary Zone. - Jb. Geol. B.-A., 133: 5-87, Wien. SCHMID, S.M., FÜGENSCHUH, B., KISSLING, E. & SCHUSTER, R. (2004): Tectonic map and overall architecture of the Alpine orogen. - Eclogae Geol. Helv., 97/1, 93-117.
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