Teachers' resource Pack Heinemann Science Scheme Book 1 Unit E Sample pages Please note: There is additional material to be added to this unit, for example, teachers' notes and answers; charts showing Science 1 opportunities etc. There may still be some uncorrected errors in these pages. 1 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme 2 E1 What are acids and alkalis? Learning objectives (from QCA Scheme of Work) Pupils should learn: l l l l E2 How can we identify acids and alkalis? l l l E3 How strong are acids and alkalis? l l l E4 Acids and alkalis in everyday situations l l l Teaching activities that many household materials and acids are not hazardous to recognise and interpret common hazard signs how to deal with acids or alkalis . . . that adding water to an acid or alkali dilutes it and makes it less hazardous Learning outcomes (from QCA Scheme of Work) Pupils: l l l l that acids and alkalis can change the colours of some dyes the names of some common laboratory acids and alkalis to classify solutions as acidic, alkaline or neutral l l E3 Core Measuring the pH of different solutions that acids and alkalis are used in a range of everyday situations that when an acid is added to an alkali, it lowers the pH that a neutral solution can be obtained by adding an acid to an alkali E4 Core Acids and alkalis cancel out E4a Extension How does pH change as alkali is added to acid? E4b Extension Does the temperature change when an acid is added to an alkali? l l l l l l Specials (learning support) identify some acids and everyday uses of acids identify hazard symbols describe how to work safely with acids and alkalis explain that if water is added to an acid or alkali, it dilutes the solution E1 Hazards E1 What are acids and alkalis? (Cloze and matching activities) recognise that solutions of dyes that show one colour in acids and another colour in alkalis are called indicators recall the names of some acids and alkalis E2 Indicators E2 How can we identify acids and alkalis? (Cloze and colouring activities) identify the pH of a given solution from a colour chart classify the solution as strongly or weakly acidic or alkaline, or neutral relate the classification to the use and associated hazards E3 Weak or strong E3 How strong are acids and alkalis? (Cloze and labelling activities) identify uses of acids and alkalis describe that when an acid is added to an alkali, the pH falls explain how to produce a neutral solution E4 Using pH E4 Acids and alkalis in everyday situations (Cloze passage) Extension resources Scheme of Work that universal indicator gives a range of colours in acidic and alkaline solutions that pH numbers indicate how acidic or alkaline a solution is that neutral solutions are pH 7, acidic solutions below 7 and alkaline solutions above 7 Homework resources Unit E Acids and alkalis q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Book spread E5 What happens when acids react with alkalis? Learning objectives (from QCA Scheme of Work) Pupils should learn: l l l l how to frame a question that can be investigated to choose appropriate techniques and equipment to compare investigative techniques and evidence to summarise and evaluate Teaching activities E5 Core How good is an antacid? E5 Extension Are acids and alkalis used up during neutralisation? Learning outcomes (from QCA Scheme of Work) Pupils: l l l suggest how to investigate a question about antacids summarise what they have found out use the evidence collected to evaluate an indigestion remedy Homework resources E5 Testing remedies Specials Extension resources E5 What happens when acids react with alkalis? (Cloze passage) E5 Are acids and alkalis used up during neutralisation? (Paper alternative to Activity E5 extension) (learning support) Unit E Acids and alkalis Book spread 3 Scheme of Work q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Teacher and technician notes Measuring the pH of different solutions Resources available Core sheet Measuring the pH of different solutions CD-ROM Results table blank: customise with names of solutions you want to use Printable UI comparison charts for pH 1±14 and also pH 1±11 E3 Core clean and dry the tiles when all twelve dimples have been used. If there is a wide spread of attitude or ability, vary the number of solutions to be tested or suggest that quicker workers check results or start questions. Watch out for people swapping droppers between beakers! Materials required Per group Links with: Book 1 SoW Sc 1 E3 7E page 2 2 f, g, h, k Safety Eye protection is needed. The main hazard here is that a pupil could deliberately or accidentally squirt one of the solutions from a dropper. If this is likely to be an issue then replace the dropper with a glass tube (dip the tube in the solution, finger over the end, transfer to tile and remove finger). Do NOT use finely drawn out glass tubes fitted with large teats. Activity procedure 1 Demonstrate test procedure. Emphasise one OR two drops ± more than this causes dilution effects and likely overflow into other dimples causing contamination. 2 Set up the room while class prepare results tables. 3 Small groups (individuals if you have enough tiles) go to each station to test the solution there, record their results then move on. Order of stations is unimportant. 4 Recap results with group. l One dimple tile l Access to UI solution (preferably tiny bottle & dropper) or paper strips cut into squares l UI comparison chart Access to Dropper and labelled beaker of 50 ml each solution. Suggested solutions (all max 0.4 M with pH given in brackets): hydrochloric acid (1), sulphuric acid (1), nitric acid (1), lemon juice (citric acid) (2), white vinegar (acetic acid) (3), boric acid (5), distilled water (7*), sodium bicarbonate solution (8), calcium hydroxide solution (limewater) (10), ammonia solution (11), sodium hydroxide solution (14). Also milk (6), apple juice (3), white wine (4), rhubarb (3), lemonade (4) (most foods are acidic). In the absence of solutions to a desired pH value, refer to The CLEAPSS Laboratory Handbook or similar publication, and make up buffer solutions. *check pH is 7 before the lesson Sample results See numbers in brackets for a guide to pH numbers only. Test your own samples before use. Answers 5 Group complete appropriate questions. 1 From practical. Running the activity 2 Extremes of pH tend to give rise to hazard warnings. Suggested organisation: put beakers with one dropper already in the solution around the room, and send small groups (preferably 2's) around with their dimple tiles to each station. If you have 12-dimple tiles, either limit the number of solutions to twelve or explain how to 3 The colour of the indicator changes slowly over a few minutes. 4 (i) dilution of the colour gives false reading, (ii) if the dimple is overfilled the liquid will flow into other dimples contaminating them and changing other readings. 4 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Teacher and technician notes Acids and alkalis cancel out E4 Core out with a pH probe and/or with a temperature probe (see Activity E4 a/b). Resources available Core sheet Acids and alkalis cancel out Extension sheet How does the pH/ temperature change as acid is added to an alkali Materials required l Universal Indicator comparison chart Sample datalogger/ spreadsheet files of extension material results l Universal Indicator solution l 2 100 cm3 beakers l 2 25 cm3 measuring cylinders l 2 droppers l stirring rod l Reactants (100 cm3 of each) 0.4 mol/dm3 hydrochloric acid (aq) 0.4 mol/dm3 sodium hydroxide (aq) CD-ROM Links with Book 1 SoW Sc 1 E4 7E page 3 2 f, g, h, k, p Safety Eye protection is needed. The concentrations used here are not rated higher than `irritant'. Be aware of droppers being used to squirt liquid. Per group Notes on materials preparation Refer to The CLEAPSS Laboratory Handbook, HazCards, or similar publications for information on making up solutions. Sample results Activity procedure 1 Students measure out an excess of acid and 20 ml of alkali. Watch for contamination ± there is a separate measuring cylinder and dropper for each solution. 2 Put the indicator in the alkali (so it goes blue ± easy to check as you go round) and add acid with a dropper in quantities of 0.5 cm3 to 1 cm3 until the mixture is neutral or beyond. At this point students should measure the remaining acid and subtract from the original volume to find out how much has been used. Running the activity If the HCl and NaOH are the same concentration, the same amount (20 cm3 ) of each should be required to give a neutral solution. If you change the acid to sulphuric, half the volume of the alkali would be needed. Answers 1 Less (less alkali to neutralise). 2 Not very. Inaccuracies may be present in measuring, end point, remeasuring or calculation, not to mention contamination! 3 Open, but there is no reason to expect that a different substance would behave in the same way or to the same degree. Demonstrate the procedure first. Have some strips of UI paper in your pocket for testing the contents of containers as you go round ± students love to add sodium hydroxide to itself in the hope that it will be neutralised . . . There is plenty of room to extend this activity, by repeating to improve technique at the end point (improves accuracy) and to check results (reliability of results). If you wish to do this with smaller or larger quantities, change the worksheet to suit. The activity could be carried 5 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Teacher and technician notes The changes in temperature and/or pH during neutralisation Resources available Extension sheets CD-ROM E4a/b Extension Materials required How does pH or temperature change as acid is added to an alkali Sample datalogger/ spreadsheet files of extension material results Links with Book 1 SoW Sc 1 E4 7E page 3 2 f, g, h, i, k, m Safety Eye protection is needed. The concentrations used here are not rated higher than `irritant'. Be aware of droppers being used to squirt liquid. Activity procedure Students measure out 75 cm3 (an excess) of acid and 50 cm3 of alkali. Watch for contamination ± use a separate measuring cylinder and dropper for each solution. Put the acid into a dropping funnel then arrange the apparatus. Check the logger is operating. Per group l 250cm3 beaker l 100cm3 beaker l 1 100 cm3 measuring cylinder l 1 50 cm3 measuring cylinder l 2 droppers l dropping funnel l magnetic stirrer l datalogger l pH or temperature (or both) sensor(s) for logger l Reactants (100 cm3 of each): 0.4 mol/dm3 hydrochloric acid 0.4 mol/dm3 sodium hydroxide soln Sample results The pH does not change steadily as students might expect, but within a very narrow band. The temperature effects can vary depending on the environment and how much (if any) insulation the beaker has, but will tend to lag behind the pH (if both are logged) due to the time taken for the heat to spread through the mixture. Answers Running the activity This activity can be used as small-group extension work or could be done as a demonstration to give wider access. The activity could be carried out with a pH probe and logger to get a graphical output of pH change against time or with a temperature probe to measure the energy change during neutralisation (HCl NaOH is exothermic). You might try temperature and pH at the same time if you are sure that the students can sort out the multiple lines on the graph. By default you will log against time, but if you can log against mass (with an electronic balance) then that would provide a measure of the amount of acid added. Clearly this is a procedure that needs trialling. These are derived from the students' graphs. A suitable answer to question 1 might be of the form ``the pH of the sodium hydroxide solution was 14 and that remained the same for x seconds and then rapidly changed during the next y seconds until it stopped changing at pH1 showing that there was an excess of hydrochloric acid.'' 6 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Teacher and technician notes How good is an antacid? Resources available E5 Core Materials required Per group Core sheet How good is an antacid? Extension sheet Are acids and alkalis used up during neutralisation? Links with: Book 1 SoW Sc 1 E5 7E page 3 2 f, g, h, k, o, p Safety Eye protection is needed. The concentrations used here are not rated higher than `irritant'. Activity procedure 1 Demonstrate how to make a paper dish for the antacid, and revisit tareing the balance if necessary. 2 Students measure 40 cm3 of dilute hydrochloric acid and add a few drops of indicator. 3 Students add one spatulaful of antacid at a time and check to see if the acid has been neutralised. When it has, they reweigh the antacid and subtract this from the original mass of antacid to find the amount used. The procedure is repeated for each antacid. Running the activity Remind students that when the right amounts of acid and alkali are mixed together they make a neutral solution. A good way to find out if anything has been `used up' is to weigh before and after a change. It is preferable to have more than one balance if possible, to avoid students having to wait. UI paper can be used instead of the UI solution by dropping one strip into the acid ± the colour leaches into the liquid. If all the antacids are carbonate (or bicarbonate) based the experiment can be done just by looking for fizzing, although this will then miss a valuable opportunity for reinforcement of neutralisation. l 100 cm3 beaker l 50 cm3 measuring cylinder l dropper (for measuring acid) l spatula l stirring rod. l UI solution Access to l top-pan balance l 0.4 mol/dm3 hydrochloric acid l various antacids (made by mixing different proportions of sodium hydrogen carbonate and salt, labelled with letters.) Notes on materials preparation Refer to The CLEAPSS Laboratory Handbook, HazCards, or similar publications for information on making up solutions. Sample results If you use 0.4 M hydrochloric acid, 40 cm3 of the acid should react with 3.36 g of sodium hydrogen carbonate or 6.72 g of 50:50 mix, so you can work out the expected answers for each of your own mixes. Answers 1 See above. 2 Which needed the smallest amount of antacid to use up the acid. 3 Because that is what you want the antacid to do to cure the indigestion. 4 Add the masses found during this experiment all at once, and see which stops fizzing first ± which reacts the fastest. You could add an exercise on which is the cheapest, by allocating each antacid a cost and asking students to work out the cost of the `dose'. The results can be pre-ordained by the mix used for each ``antacid''. If the beaker is stood on white paper or a tile, the indicator colour is easier to see. 7 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity Measuring the pH of different solutions E3 Core Aim To measure and record the pH of solutions Take care when using acids and alkalis! Equipment: l l Universal Indicator (UI) paper comparison chart l l dimple tile different solutions What to do 1 Cut each strip of UI paper up into squares ± you should get five or six from each strip. 2 Make sure your results table is UI Solution ready to record your results. 3 Put one square of UI paper into dropper of test solution each dimple of the tile. 4 Put one (or at most two) drops of UI solution the first solution you want to test on to one piece of the UI paper squares of UI paper with the dropper. HAZARD: some of the solutions you will test are hazardous. Treat them all with care. 5 Immediately compare the colour that the UI paper turns with the UI comparison chart. 6 Write down the colour of the UI paper in your results table. 7 Write down the pH number that corresponds to the colour of the UI paper in your results table. 8 Repeat this test with the other test solutions. Results Name of solution Colour of UI paper pH of solution Hydrochloric acid red pH 1 Questions 1 For each substance, classify it as a strong acid, weak acid, neutral, weak alkali or strong alkali. 2 How does the pH relate to the hazard warning symbols found on the substances? 3 Why is it important to compare the colour of the paper to the comparison chart straight away? 4 Give two reasons why you shouldn't add too many drops of the test solution to the UI paper. 8 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity Acids and alkalis cancel out E4 Core Aim To find out how much hydrochloric acid is needed to use up 20 cm3 of sodium hydroxide solution. Equipment l Universal Indicator (UI) comparison chart 3 l 2 100 cm beakers l 2 droppers l hydrochloric acid l l l l Take care when using acids and alkalis! UI solution 2 25 cm3 measuring cylinders stirring rod sodium hydroxide solution What to do 3 3 1 Measure 40 cm of hydrochloric acid. Put it in a 100 cm beaker. 2 Measure 20 cm3 of sodium hydroxide solution. Put it in a 100 cm3 beaker. 3 Add five drops of UI solution to the sodium hydroxide solution in the beaker. The indicator should turn dark blue or purple. 4 5 Use a dropper to add the hydrochloric acid to the sodium hydroxide solution, a little at a time and stir gently to make sure they are mixed. stirring rod dropper of hydrochloric acid dilute hydrochloric acid Check the colour of the indicator. If the blue colour has changed to light green the solution is neutral and you should stop. If the indicator has turned yellow or orange you have added a little too much acid, but you should still stop. 6 Measure the amount of hydrochloric acid you have got left by carefully pouring it into the correct measuring cylinder. 7 Repeat the experiment to check your result. ;;; ;;; ;;; sodium hydroxide solution with UI solution left-over hydrochloric acid measuring cylinder for hydrochloric acid Results Write down the amount of hydrochloric acid that you needed to use up all the sodium hydroxide solution. Questions 1 If the sodium hydroxide was diluted with water, do you think it would need more or less acid to use it up? Explain why you think this. 2 How accurate do you think your answer is? Explain why you think this. 3 Do you think that you would need the same amount of a different acid to use up 20 cm3 of sodium hydroxide solution? Explain why you think this. 9 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity How does the pH change as an acid is added to an alkali? E4a Extension Aim To find out how much hydrochloric acid is needed to use up 50 cm3 of sodium hydroxide solution. Take care when using acids and alkalis! Equipment l l l l 250 and 100 cm3 beakers 100 and 50 cm3 measuring cylinders 2 droppers magnetic stirrer l l l l datalogger pH sensor for logger hydrochloric acid sodium hydroxide solution ;; ; ; ; What to do 3 1 Measure 75 cm of hydrochloric 75 cm3 dilute acid. Put it in to a dropping hydrochloric acid in dropping funnel funnel. 3 2 Measure 50 cm of sodium hydroxide solution. Put it in a 250 cm3 tall-form beaker. 50 cm3 sodium hydroxide 3 Stand the beaker on a magnetic solution stirring plate and put the stirrer in the beaker. Start the stirrer. 4 Clamp the pH probe so that it is in the liquid. 5 Arrange the dropping funnel so that it can drip into the liquid. 6 Start the datalogger. 7 Open the funnel tap slightly so that the hydrochloric acid drips in to the sodium hydroxide solution, approximately one drop every second. Count the drops in 30 seconds. 8 Continue adding the acid until the pH stops changing (about pH 1 or 2). 9 Stop adding the acid, turn off the stirrer and logger. ; DATALOGGER pH sensor magnetic stirrer Results Print the graph of the data collected by the logger. Questions 1 On your graph, mark the point where the mixture was exactly neutral. 2 How long did it take for the mixture to go from pH 14 to pH 1? 3 How many drops of hydrochloric acid dripped into the sodium hydroxide solution in thirty seconds? 4 How many drops of hydrochloric acid dripped into the sodium hydroxide solution to change it from pH 14 to pH 1? 5 Write a paragraph to describe how the pH of the mixture changes as the acid runs into the alkali. 10 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity How does the temperature change as an acid is added to an alkali? E4b Extension Aim To find out how much hydrochloric acid is needed to use up 50 cm3 of sodium hydroxide solution. Take care when using acids and alkalis! Equipment l l l l 250 and 100 cm3 beaker 50 and 100 cm3 measuring cylinder 2 droppers magnetic stirrer l l l l datalogger temperature sensor for logger hydrochloric acid sodium hydroxide solution ;; ; ;; What to do 3 1 Measure 75 cm of hydrochloric 75 cm3 dilute acid. Put it in to a dropping funnel. hydrochloric acid 3 in dropping funnel 2 Measure 50 cm of sodium hydroxide solution. Put it in a 250 cm3 tall-form beaker. 3 Stand the beaker on a magnetic 50 cm3 stirring plate and put the stirrer in sodium hydroxide solution the beaker. Start the stirrer. 4 Clamp the temperature sensor so that it is in the liquid. 5 Arrange the dropping funnel so that it can drip into the liquid. 6 Start the datalogger. 7 Open the funnel tap slightly so that the hydrochloric acid drips in to the sodium hydroxide solution, approximately one drop every second. Count the drops in 30 seconds 8 Continue adding the acid until the temperature stops changing. 9 Stop adding the acid, turn off the stirrer and logger. ; temperature sensor magnetic stirrer Results Print the graph of the data collected by the logger. Questions 1 On your graph, mark the point where the temperature started to change and the point where the temperature stopped changing. 2 How many drops of hydrochloric acid dripped into the sodium hydroxide solution in thirty seconds? 3 Write a paragraph to describe how the temperature of the mixture changes as the acid runs into the alkali. 11 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity How good is an antacid? E5 Core Aim To compare different stomach remedies. The main question to answer when deciding which is the `best' antacid is `how much acid does the antacid remove?' This experiment allows you to answer that question. Take care when using acids and alkalis! Equipment l l l l 100 cm3 beaker hydrochloric acid samples of antacids spatula l l l l 50 cm3 measuring cylinder Universal Indicator solution balance stirring rod What to do 3 1 Measure 40 cm of spatula full of antacid hydrochloric acid. 2 Put the acid in a 100 cm3 beaker with a few drops of Universal Indicator solution. 3 Measure out 10 g of one of the antacids on a piece of paper. sample of antacid 4 Add one spatulaful of antacid to the acid and stir. 5 If the mixture fizzes and the indicator stays red, orange or yellow, repeat step 4. If it goes green, and stays green, go on to step 6 . 6 Measure the amount of antacid you have left, and work out how much you have used. Don't forget to allow for the weight of the paper! 7 Repeat the experiment using different antacids. stirring rod 40 cm3 of hydrochloric acid with a few drops of UI solution Results Write down the amount of each antacid that was needed to use up 40 cm3 of the acid. Questions 1 Which antacid was best at using up the acid? 2 How did you decide which the best antacid was? 3 Why is the amount of acid the antacid removes important? 4 How could you find out which antacid works the most quickly? 12 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Activity Are acids and alkalis used up during neutralisation? E5 Extension Aim To find out if acids and alkalis are used up during neutralisation. Take care when using acids and alkalis! Equipment l l l 2 250 cm3 beakers 2 100 cm3 measuring cylinder 2 droppers l l l hydrochloric acid sodium hydroxide solution top-pan balance What to do 3 1 Measure 100 cm of hydrochloric acid. Put it in to the 250 cm3 beaker. 2 Put the beaker carefully on the balance and write down the mass. 3 Measure 100 cm3 of sodium hydroxide solution. Put it in to the other 250 cm3 beaker. 4 Put the beaker carefully on the balance and write down the mass. 5 Check your readings by putting both beakers on the balance together and make sure that the total mass of the two beakers and their contents is the same as the sum of the individual masses. 6 Take the beakers off the balance and carefully mix the acid and the alkali together. 7 Put both beakers carefully back on the balance (make sure no acid or alkali touches the balance) and record the total mass again. Results Present your measurements in a clear format. You could use a table if you like. Questions 1 What is the difference between the total mass of the beakers and the chemicals before and after the acid and alkali were mixed? 2 Do you think the acid was used up? beaker containing 100 cm3 of hydrochloric acid top pan balance beaker containing 100 cm3 of sodium hydroxide solution top pan balance ;; ;; beaker containing mixture empty beaker top pan balance 3 Do you think the alkali was used up? 4 What do you think we mean when we say that the acid and alkali are ``used up'' during neutralisation? 13 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Homework Hazards E1 Design your own hazard warning symbol to show that a substance is explosive. Remember that your symbol can only be black on orange. Look around your house for containers with chemicals in. Some of these containers will have hazard warnings and some won't. List all the chemicals you find in the table below, and when they have a hazard warning sign, tick the correct column to show the hazard. Name of chemical No hazard warning Harmful Irritant Corrosive Use the information you found to answer these questions 1 Which was the most common hazard warning symbol in your house? 2 In which room were the largest number of hazardous chemicals kept? 3 Write a few sentences about how and where the chemicals were stored. For example, were they kept out of reach of young children? 4 Write a safety report for the chemicals in your house, mentioning good things (when chemicals are stored properly) and bad things (when they aren't). " ......................................................................................... Homework Indicators 1 Copy out the statements below so that they are in the correct order to extract an indicator from some red cabbage leaves. l Cut up the cabbage leaves. l Filter the mixture. l Put the cabbage leaves in a mortar with some sand and a little water. l Pick the cabbage leaves. l Grind the leaves with a pestle to release the dye from the leaf cells. E2 3 Raw beetroot can be used to make an indicator. Why shouldn't pickled beetroot be used? 4 Litmus solution turns pink in acids and blue in alkalis. Copy and complete the box showing the colour that the litmus would turn in that solution. The first two have been done for you. 2 Collect advertisements for products which are either acids or alkalis, or are made from them. Make a display of your advertisements to show the range of products that can be made from acids and alkalis. 14 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Solution hydrochloric acid pink sodium hydroxide blue citric acid potassium hydroxide phosphoric acid water Homework Weak or strong? E3 1 Copy the pH number and match each number to the meaning pH 1 pH 5 pH 7 pH 9 pH 13 weak alkali neutral strong alkali weak acid strong acid 2 Copy and complete the table using the pH numbers and colours from the list below. Use each number or colour once only. Solution Type hydrochloric acid strong acid boric acid weak acid sodium hydroxide strong alkali sodium bicarbonate weak alkali distilled water neutral pH number Colour of UI paper pH numbers: 1, 5, 7, 9, 14 Colours: purple, red, yellow, light green, dark green 15 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Homework Using pH 1 Which of these statements are true and which are false? a All acids have pH numbers less than 3. b All alkalis turn pH paper blue. c Neutral solutions have a pH of 7. d pH 5 means neutral e Stronger acids have low pH numbers. f High pH numbers mean strong alkalis. 2 Bee stings and wasp stings are very different to each other. Wasp stings can be treated with vinegar and bee stings with bicarbonate of soda solution. Explain why each treatment works. E4 3 You find an unlabelled bottle on the bench. When you test the liquid in the bottle with Universal Indicator, you find that the liquid has a pH number of 4. Which of the following statements are true? a b c d e The liquid is salt solution The liquid is an acid The liquid is an alkali The liquid is a weak acid The liquid is sodium hydroxide solution f The liquid is hazardous " ......................................................................................... Homework Testing remedies Razak wants to know which indigestion remedy works the most quickly. He has three remedies he wants to test, remedy A is a powder, remedy B is a tablet that has to be dissolved in water before drinking it and remedy C is a liquid that is taken from a teaspoon. Write a plan for one or more tests that will answer Razak's question. You can make use of any laboratory equipment or chemicals you normally use. 16 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme E5 Specials What are acids and alkalis? E1 1 Use the words below to fill the gaps in these sentences. You may need to use a word more than once. chemicals acids stomach alkalis burn corrode Acids and alkalis are two important groups of soap . often have a sharp or sour taste. Strong can wear away or metals but many are weak and harmless. Many strong are described as caustic, which means they can living tissue. We can find acids and alkalis all over the place, in foods, shampoo and even in your , . 2 Below are chemical hazard symbols and descriptions of what they mean. Match the symbols to the correct description. Attacks and destroys living tissue, including eyes and skin h Can make you ill if swallowed, breathed in or absorbed through the skin May cause reddening or blistering of the skin i 17 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Specials How can we identify acids and alkalis? E2 1 Use the words below to fill the gaps in these sentences. You may need to use a word more than once. colourless litmus Universal Indicator hydrochloric hydroxide colour indicator petals leaves a Many acids and alkalis are liquids, so you can't tell them apart just by looking. We can use an to tell whether a substance is an acid or an alkali. in acids and alkalis. They can be b Indicators change made from plant material such as and . Two indicators that are often used in schools are and c acid is an acid, and sodium is an alkali. 2 The drawings show litmus paper in a beaker of acid and a beaker of alkali. Show what colour it would turn in each one by colouring it in or writing the colour. litmus paper ACID ALKALI 18 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Specials How strong are acids and alkalis? E3 1 Use the words below to fill the gaps in these sentences. You may need to use a word more than once. strong Universal Indicator Sulphuric acid is a weak higher pH scale acid, but cows' milk is a acid. acids and alkalis tend to react more quickly than weak acids and alkalis. We use to tell us how strong acids and alkalis are. The shows the range of strengths of acids and alkalis. Alkalis have pH numbers than acids. 2 On the pH scale, pH 7 means neutral and pH 1 means a strong acid. On the pH line below label the three arrows to show where a weak acid, a weak alkali and a strong alkali would appear. 0 1 strong acid 2 3 4 5 6 7 8 9 10 11 12 13 14 neutral 19 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Specials Acids and alkalis in everyday situations E4 1 Use the words below to fill the gaps in these sentences. You may need to use a word more than once. vinegar fertilisers acidic lime skin plastics neutralise Acids and alkalis are used to make chemicals such as soaps, , , paints and drugs. Some foods can be pickled by soaking them in which is an acid. pH 5.5 is the best value for your . Ant bites and bee stings are , so they can be treated with a weak alkali. Acidic soil is made better for growing crops by spreading onit.Acidsandalkaliscancanceleachotherout.Wesaythatacids can alkalis. " ......................................................................................... Specials What happens when acids react with alkalis? E5 1 Use the words below to fill the gaps in these sentences. You may need to use a word more than once. neutral antacids acid A common cause of stomach ache is green indigestion. Indigestion remedies contain which use up the excess acid. To find out which antacid uses up the most acid, we would have to add the to a mixture of antacid and Universal Indicator, to see how much acid was used up before the UI turned show it was . 20 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme to Extension Are acids and alkalis used up during neutralisation? Aim To find out if acids and alkalis are used up during neutralisation. When the right amounts of an acid and an alkali are mixed together, they make a neutral solution. We say that the acid and alkali have cancelled each other out. Could this mean that the acid has ``used up'' the alkali? Or has the alkali ``used up'' the acid? A good way to find out if something has been used up is to weigh it before and after a change: if the mass goes down, something may have been used up. Xavier and Jeannette carried out the experiment below to find out if anything had been used up during neutralisation. 3 l They measured 100 cm of hydrochloric acid and put it in to the 250 cm3 beaker. l They put the beaker carefully on the balance and wrote down the mass. 3 l They measured 100 cm of sodium hydroxide solution and put it in to the other 250 cm3 beaker. l They also wrote down the mass of this beaker. l They carefully mixed the acid and the alkali together. l They put both beakers carefully back on the balance and recorded the total mass again. Results E5 beaker containing 100 cm3 of hydrochloric acid top pan balance beaker containing 100 cm3 of sodium hydroxide solution top pan balance ;; ;; beaker containing mixture empty beaker top pan balance Mass of hydrochloric acid + beaker = 179 g oxide Mass of sodium hydr + beaker = 185 g ts = 364 g Both beakers + conten Mass of mixture + 2 beakers = 364 g Questions 1 What is the difference between the total mass of the beakers and the chemicals before and after the acid and alkali were mixed? 2 Do you think the acid was used up? 3 Do you think the alkali was used up? 4 What do you think we mean when we say that the acid and alkali are ``used up'' during neutralisation? 21 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Test yourself Acids and alkalis Unit E 1 Match each hazard warning symbol to its meaning. Can make you ill if swallowed, breathed in or absorbed through the skin i May cause reddening or blistering of the skin h Attacks and destroys living tissue including eyes and skin 2 Litmus solution turns pink in acids and blue in alkalis. Complete the table below by writing in the colour that the litmus would turn in that solution. The first one has been done for you. Solution Colour of litmus hydrochloric acid pink sodium hydroxide citric acid potassium hydroxide phosphoric acid water 3 Put the following words in the correct places in the table: neutral pH1 strong alkali light green weak acid Substance Strength & type hydrochloric acid strong acid pH pH 5 sodium hydroxide pH 14 distilled water purple Colour of UI red boric acid sodium bicarbonate pH 9 weak alkali yellow dark green pH 7 4 Which of these statements are true and which are false? l l l l l l Acids have pH numbers less than 7 Some alkalis have pH numbers greater than 9 A neutral solution has a pH anywhere between 5 and 9 pH 7 means neutral The lower the number, the stronger the acid The lower the number, the stronger the alkali 22 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme True/False True/False True/False True/False True/False True/False Test yourself Acids and alkalis continued Unit E 5 You find an unlabelled bottle on the bench. When you test the liquid in the bottle with universal indicator, you find that the liquid has a pH number of 5. Which of the following statements are true? l l l l The liquid is an alkali The liquid is a weak acid The liquid is sodium hydroxide solution The liquid is hazardous 6 Choose the right words to complete the sentences by crossing out the wrong words: Acids turn Universal Indicator red/green/blue, and have a sharp/sweet/blunt taste. Some alkalis are described as acidic/caustic/alkaline because they can burn living tissue. Alkalis turn Universal Indicator red/green/dark green if they are weak/strong/neutral. When acids and alkalis are mixed together, they add up/cancel out/disappear. The word scientists use to describe this is evaporation/condensation/neutralisation. 7 Complete the crossword. If you get stuck, the answers are all written below, but try not to use them! 1 Across 1 To cancel out an acid and alkali 4 Substance with a sharp taste 6 These fruit are acidic 8 A laboratory acid Down 1 Not an acid or an alkali ± pH 7! 2 These can be caustic! 3 Shows what is an acid and what is an alkali 5 Another name for calcium oxide 7 Solid form of a common, neutral substance! 8 Is hydrochloric acid an alkali? 2 3 4 5 6 7 8 8 Which group of pH numbers would ALL indicate the presence of acids? A 1 3 5 B 1 5 7 C 7 9 11 D 9 11 13 Answers: Acid, alkalis, ice, indicator, lemons, lime, neutral, neutralise, nitric, no 23 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme End of unit test Acids and alkalis Unit E Tier 3±6 1 a Which of these substances could have this sign? (1 mark) A weak acid A strong acid A weak alkali A strong alkali i b Put these substances in order, most hazardous first. (2 marks) ;; ;; ;; A B C h i c Explain why should you add water to an acid if the acid spills on your skin. (1 mark) 2 Shaheen has three colourless liquids labelled A, B and C. a When she puts Universal Indicator into solution A it turns red. When she puts it into solution B it turns purple. Copy out the correct statement. (1 mark) l A and B are both strong acids l A is a strong acid, B is a strong alkali l A is a weak acid, B is a weak alkali l A and B are both weak alkalis b Shaheen now puts Universal Indicator into solution C and it turns green. What does this tell her about the liquid? (1 mark) c Suggest what substance C might be. (1 mark) d Below is a pH scale with some values marked in. Copy the scale and mark Shaheen's 3 substances where you think they would be on the scale. (3 marks) pH 0 1 4 7 Letter of substance 24 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme 9 13 End of unit test Acids and alkalis continued Unit E Tier 3±6 3 If you have a stomach ache this is often caused by `acid indigestion'. a What causes acid indigestion? (1 mark) b You can buy indigestion remedies to cure this. What do many of them contain? (1 mark) c Explain how an indigestion remedy can cure acid indigestion. (1 mark) d Nettle stings are caused by formic acid. Many people say that rubbing a dock leaf on a nettle sting will cure it. What test would you carry out on the dock leaf to see if this could be true? (1 mark) 4 The graph shows how the pH of sodium hydroxide solution changes as hydrochloric acid is added slowly to it. 14 13 12 11 10 9 8 7 6 5 4 3 2 1 0 pH of mixture a How much hydrochloric acid has been added when the solution becomes neutral? (1 mark) b Explain why the pH of the mixture above changes as it does. (1 mark) 10 0 20 30 40 50 60 cm3 of hydrochloric acid added 70 80 5 Two students carried out an experiment to investigate temperature changes during neutralisation. They added acid slowly to an alkali and recorded the temperature after each 5 cm3 of acid added. Here are their results: amount of acid added (cm3 ) 5 10 15 20 25 30 temperature (8C) 15 15 18 22 30 24 a Draw a line graph of the students' results. (2 marks) b Describe what happens to the temperature during the experiment. (1 mark) c Mark on your graph the point where you think the neutralisation had finished. (1 mark) 25 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme End of unit test Acids and alkalis Unit E Tier 2±5 1 Find one acid and one alkali in the following passage: Peter got up one morning and had a wash with soap and water. For breakfast he had orange juice and cereal with extra iron in it ± but no milk! On his way to school he ate a chocolate bar. a Which is the acid? (1 mark) b Which is the alkali? (1 mark) 2 a Look at the list below and pick out one acid and one alkali which you might find in the school lab. (2 marks) Hydrochloric acid, sodium hydroxide solution, copper sulphate solution b Name one other acid (1 mark) 3 a Copy the sentence below that describes what this symbol means? (1 mark) l Can make you ill if swallowed, breathed in or absorbed through the skin l May cause reddening or blistering of the skin l Attacks and destroys living tissue including eyes and skin b Name one of these substances which could have this sign. (1 mark) l A weak acid l A strong acid l A weak alkali l A strong alkali c Put these substances in order, most hazardous first. (2 marks) ;; ;; ;; A B C d Explain why you should add water to an acid if you spill acid on your skin. (1 mark) 26 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme h i End of unit test Acids and alkalis continued Unit E Tier 2±5 4 Shaheen has three colourless liquids labelled A, B and C. a When she puts Universal Indicator into solution A it turns red. When she puts it into solution B it turns purple. Copy out the correct statement. (1 mark) l A and B are both strong acids l A is a strong acid, B is a strong alkali l A is a weak acid, B is a weak alkali l A and B are both weak alkalis b Shaheen now puts Universal Indicator into solution C and it turns light green. What does this tell her about the liquid? (1 mark) c Suggest what substance C might be. (1 mark) d Below is a pH scale with some values marked in. Copy the scale and mark Shaheen's 3 substances where you think they would be on the scale. (3 marks) pH 0 1 4 7 9 13 Letter of substance 5 If you have a stomach ache this is often caused by `acid indigestion'. a What causes acid indigestion? (1 mark) b You can buy indigestion remedies to cure this. What do many of them contain? (1 mark) c Explain how an indigestion remedy can cure acid indigestion. (1 mark) d Nettle stings are caused by formic acid. Many people say that rubbing a dock leaf on a nettle sting will cure it. What test would you carry out on the dock leaf to see if this could be true? (1 mark) 27 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Mark scheme Acids and alkalis Unit E Tier 2±5 Question Part Answer Mark Level 1 a Orange juice 1 2 b soap 1 2 a Acid hydrochloric acid, alkali sodium hydroxide solution 1 1 3 b Any other acid 1 3 a Attacks and destroys living tissue 1 3 b A strong acid or a strong alkali 1 4 c A then C then B: 1 mark for A, then 1 mark for C 2 3 d It stops the acid doing so much damage by washing some away/by diluting it (credit either). Credit ``it makes the acid weaker'' 1 5 a A is a strong acid, B is a strong alkali 1 4 b Neutral 1 4 c Any neutral liquid eg water, salt solution 1 4 d A linked to pH 1 B linked to pH 13 C linked to pH 7 1 1 1 4 4 4 a Too much stomach acid 1 4 b Antacid, allow ``alkali'' or ``carbonate'' 1 4 c Neutralises/cancels out/uses up excess acid 1 5 d Something to the effect of: extract the juice from a dock leaf and test it to see if it is an alkali or if it neutralises an acid. Accept ``pH test'' 1 4 2 3 4 5 Scores in the range of: Level 3±5 2 6±10 3 11±14 4 15±20 5 28 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Mark scheme Acids and alkalis Unit E Tier 3±6 Question Part Answer Mark Level 1 a A weak acid or a weak alkali 1 4 b C then B then A: 1 mark for C, then 1 mark for B 2 3 c It stops the acid doing so much damage by washing some away/by diluting it (credit either). Credit ``it makes the acid weaker'' 1 5 a A is a strong acid, B is a strong alkali 1 4 b Neutral 1 4 c Any neutral liquid eg water, salt solution 1 4 d A linked to pH 1 B linked to pH 13 C linked to pH 7 1 1 1 4 4 4 a Too much stomach acid 1 4 b Antacid, allow ``alkali'' or ``carbonate'' 1 4 c Neutralises/cancels out/uses up excess acid 1 5 d Something to the effect of: extract the juice from a dock leaf and test it to see if it is an alkali or if it neutralises an acid. Accept ``pH test'' 1 4 a 42 cm3 accept answers in range 40±45, with units 1 5 b pH stays at 14 while there is excess alkali, then falls quickly to 7 as the alkali is neutralised and then to 1 as the excess of acid is established. 1 5 a Appropriate scales (0±30 cm3 on x axis, 0±308C on y axis) 1 6 Points and line correct (make an acetate overlay) 1 6 2 3 4 5 30 25 20 °C 15 10 5 0 0 5 10 15 20 cm3 acid 25 30 29 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Mark scheme Acids and alkalis Unit E Tier 3±6 b Temperature increases as you add more acid until about 25 cm3 of acid has been added, then the temperature falls as you add more acid. 1 5 c Credit mark at highest temperature (although neutralisation will have occurred before the highest temperature is reached). 1 5 Scores in the range of: Level 4±7 3 8±11 4 12±14 5 15±20 6 30 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Student record sheet Acids and alkalis I can do this very well I can do this quite well I need to do more work on this I can identify some acids and describe how they are used in everyday life I can identify some alkalis and describe how they are used in everyday life I know the hazard symbols for harmful, irritant and corrosive substances I can describe how to work safely with acids and alkalis I know what happens when water is added to an acid or alkali I know what an indicator is I can describe the effect of acids and alkalis on indicators I know the names of some acids and alkalis we can find in the school lab I can use a colour chart to find the pH of a substance I can use the pH value of a substance to identify it as acid, alkali or neutral I can use the pH value to describe how weak or strong an acid or alkali is I can describe what happens to the pH when an acid is added to an alkali I can describe what happens to the pH when an alkali is added to an acid I know what neutralisation means I can explain how to get a neutral solution What I enjoyed most in this unit was The most useful thing I have learned in this unit was I need to do more work on 31 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Key words Unit E Acids and alkalis Key word list acid alkali antacid caustic corrode harmful hazardous indicator lichen lime neutral neutralise neutralisation pH paper ph scale pH values symbol universal indicator " ......................................................................................... Glossary Unit E Acids and alkalis Glossary acids substances that react with alkalis and sometimes have a sour taste alkalis substances that react with acids antacid substance that uses up or cancels out an acid caustic substance that can burn living tissue corrode to eat away a substance harmful can make you ill if swallowed, breathed in or absorbed through the skin hazardous has some risk connected with it indicator a chemical that changes colour in acids and alkalis lichen kind of plant lime everyday name for calcium oxide neutral neither acid nor alkali neutralised made neutral neutralisation using up or cancelling out an acid or alkali to make it neutral pH paper universal indicator on filter paper to make it easy to use ph scale range of strength of acids and alkalis, from 1 to 14 pH values numbers that mean how acid or alkaline something is symbol sign that means something universal indicator mixture of dyes that show the strength of an acid or alkali 32 q I Bradley, C Tear, M Winterbottom, S Young, 2001, The Heinemann Science Scheme Help with navigation Use the bookmarks on the left of the screen to look at the different activities and teacher’s notes – click on a title to view the first page of that section; click on the plus sign (+) to the left of a title to view a list of activities (or other pages) in that section; then click on any of these subtitles to view that page (or part of a page). 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