SAMPLE PAGES FROM UNIT E Heinemann Science Scheme Teacher Resource Pack 3 ISBN: 0 435 58249 6 D E T C E R R O UNC OOFS PR This sample contains most of Unit E from Heinemann Science Scheme Teacher Resource Pack 3 in a PDF format. Because this advance material has not yet been through all checking stages, it may still contain minor errors. The following pages are not included in this sample material but will be in the Pack: test-yourself answers; keywords lists and glossary lists. © D. Lees, 2002, The Heinemann Science Scheme This material may be freely copied for institutional use prior to the publication of the book from which it is taken. However, this material is copyright and under no circumstances may copies be offered for sale. that metals are good conductors of heat and electricity that most non-metallic elements are poor conductors of heat and electricity about the range of metals, their uses and where they are found to use and combine data from a variety of information sources to organise facts/ideas/ information into an appropriate sequence that some metals react with dilute acids to form salts and release hydrogen to carry out a test for hydrogen to represent the reactions of metals with dilute acids by word equations to identify patterns in reactions between metals and dilute acids to use patterns in reactions to make predictions about other reactions E2 How do metals react with acids? (from QCA Scheme of Work) Pupils should learn: Learning objectives E1 Why are metals useful? Book spread E2 Core: Reacting metals with acids E1a Core: Looking at metals and non-metals E1b Core: Properties of metals and non-metals Teaching activities identify the gas produced in the reaction between metals and acids as hydrogen write word equations for the reactions and explain the similarities between them use the formulae of the reactants and products to explain how atoms join in different ways as a result of the reaction predict that hydrogen and the appropriate salt will be made as a result of the reaction contrast the conductivity of metals and non-metals identify graphite as a nonmetallic conductor produce an information sheet that is correct and well sequenced and contains appropriate information make some generalisations about the properties of metals which make them useful, eg they are hard, they can be flexible (from QCA Scheme of Work) Pupils: Learning outcomes E2 Which metals react with acids? E1 Why are metals useful? Homework resources E2 How do metals react with acids? E1 Why are metals useful? (learning support) Specials Extension resources Unit E Reactions of metals and metal compounds Scheme of Work 1 C D Lees, 2002, The Heinemann Science Scheme C that acids react with metal carbonates, producing carbon dioxide and a salt that production of new materials and energy changes are evidence of chemical reactions that acids react with metal oxides, producing a salt and water that production of the salt is evidence of a chemical reaction to represent reactions of acids with metal oxides by word equations to use preliminary work to find out if a possible approach is practicable to use common laboratory equipment safely and effectively to evaluate the methods used in terms of the quality of the salt made to organise content into a piece of writing, with the relationship between paragraphs clearly signalled E4 How do metal oxides react with acids? Learning objectives (from QCA Scheme of Work) Pupils should learn: E3 How do metal carbonates react with acids? Book spread 2 D Lees, 2002, The Heinemann Science Scheme E4 Core: Reacting metal oxides with acids E3 Core: Reacting carbonates with acids Teaching activities identify evidence for a chemical reaction, eg crystals are made, which are a different colour from what we started with represent reactions by word equations identify the patterns in word equations and produce a general equation decide whether they need to modify their plan obtain a satisfactory sample of the salt identify where they found problems and the effect these had on their product produce an account of their work which identifies problems and corrects these, with clear explanations of how they were dealt with write, using evidence, in paragraphs that develop points decide whether they need to modify their plan identify the gas produced as carbon dioxide identify evidence for a chemical reaction, eg a gas is produced, the test tube is getting hot represent reactions by word equations identify the pattern in word equations and produce a general equation (from QCA Scheme of Work) Pupils: Learning outcomes E4 How do metal oxides react with acids? (Note: this homework is preparation for Activity E4) E3 Naming salts Homework resources E4 How do metal oxides react with acids? E3 How do metal carbonates react with acids? (learning support) Specials E3 Chemical translation Extension resources Unit E Reactions of metals and metal compounds Scheme of Work that when an alkali is added to an acid, neutralisation takes place how to obtain a neutral solution from an acid and an alkali the hazards associated with alkalis to identify key points about the reactions of metals and acids to identify patterns in the chemical reactions that there are many different salts that many salts are useful compounds to summarise how acids react with metals, metal carbonates and metal oxides to represent the reactions of metals with dilute acids by word equations to represent reactions of acids with metal oxides by word equations E6 Balanced symbol equations Learning objectives (from QCA Scheme of Work) Pupils should learn: E5 How do alkalis react with acids? Book spread E6a Core: Writing equations E6a Resource: Writing equations E6b Extension: Balanced symbol equations E5a Core: Neutralising an acid with an alkali E5b Extension: Uses of salts Teaching activities represent reactions by word equations identify that a solution of pH7 is neutral explain the safety precautions that need to be taken when using alkalis use the technique adopted to obtain a neutral solution from which sodium chloride can be isolated represent reactions by word equations identify the pattern in word equations and produce a general equation, eg acid 1 alkali salt 1 water name a variety of salts give the uses of a variety of salts make generalisations about reactions of acids and metals, using chemical names for products and reactants (from QCA Scheme of Work) Pupils: Learning outcomes E6 Writing word equations E5 How do alkalis react with acids? Homework resources E6 (Note: there is no Specials sheet as balanced symbol equations is considered unsuitable) E5 How do alkalis react with acids? (learning support) Specials E6 Writing balanced symbol equations Extension resources Unit E Reactions of metals and metal compounds Scheme of Work 3 C D Lees, 2002, The Heinemann Science Scheme Teacher and technician notes Looking at metals and non-metals Resources available Core sheet Looking at metals and non-metals CD-ROM All resources customisable Links with Book 3 SoW Sc1 E1 9E page 1 2fgijkm Safety Instruct students in the safe use of a scalpel. Scalpel guards can be made from a short piece of rubber tubing. E1a When hitting samples with a hammer to test for brittleness, a wooden board will prevent damage to bench tops. Safety screens must be used for this test. Materials required Per group samples of metals and non-metals (see below), labelled with the element name scalpel with guard For the teacher demonstration samples of mercury, lithium, white phosphorus, chlorine white tile Use safety screens for the teacher demonstration. scalpel Care should be taken by the teacher in the use of mercury, lithium, chlorine and phosphorus. wooden board Activity procedure 1 Students look at the appearance of samples of metals and non-metals 2 They test the samples for flexibility and hardness. hammer safety screens Notes on materials preparation Suitable elements for the students' experiment include: copper, iron, magnesium, zinc, roll sulphur, carbon (graphite rods). The metals should ideally be in the form of rods, but thin strips may be used. 4 The teacher tests some elements that the For the teacher demonstration samples of mercury (under water), white phosphorus (under water) and chlorine should be provided in sealed containers, which should not be opened. Running the activity Lithium should be provided stored in oil with a scalpel and white tile for cutting. 3 As a teacher demonstration, students are shown some elements that are more difficult to handle. students have looked at for brittleness. Samples of elements can be shared between groups in the class on a rota basis. Tell the students not to break samples when testing them for flexibility. Point out to them that flexibility will be affected by the thickness of the samples used. For the teacher demonstration, mercury should be kept under a layer of water in a sealed sample bottle. Take lithium out of its storage oil and cut it so that students can see the shiny, silver surface. Keep gaseous non-metals such as chlorine in sealed gas jars. Samples of the elements for the students' experiment will be needed for testing for brittleness by hitting with a hammer. Answers 1 Metals are shiny, usually silvery, flexible and hard. 2 Non-metals are usually dull, inflexible and soft. Some are gases. 3 Mercury is a liquid metal. Lithium is soft. 4 Conduction of heat and electricity 1 C D Lees, 2002, The Heinemann Science Scheme Teacher and technician notes Properties of metals and non-metals Resources available Materials required Core sheet Properties of metals and non-metals CD-ROM All resources customisable Per group battery lamp switch four connecting leads Links with Book 3 SoW Sc1 E1 9E page 1 2fgijkm Safety Safety screens should be used to separate the beaker of boiling water and rods from the rest of the class. two crocodile clips rods of metals and non-metals (see below), labelled with the element name where appropriate For the teacher demonstration beaker of water Bunsen burner Care should be taken that the beaker of boiling water is not tipped over during the demonstration. tripod and gauze Eye protection must be worn when observing the demonstration. safety screens Activity procedure 1 Students set up an electrical circuit containing a battery, a lamp, a switch and leads ending with crocodile clips. 2 They use the circuit to test samples of metals and non-metals for electrical conductivity. 3 As a teacher demonstration, students are shown long rods of metals and non-metals, each with one end standing in a beaker of boiling water for at least 10 minutes. 4 Students feel how hot the other end of each rod has become. Running the activity Some students may need help in connecting up their circuit. Set up the demonstration behind safety screens. Students should visit this demonstration one group at a time to feel the ends of the rods. 2 C E1b D Lees, 2002, The Heinemann Science Scheme heatproof mat long rods of metals and non-metals (see below) Notes on materials preparation For the student activity small pieces, rods or strips of copper, iron, magnesium, zinc, roll sulphur, carbon (graphite rods) may be used. In addition plastic, glass and wood may be used. Long rods of the same materials may be used for the teacher demonstration. Answers 1 Copper, iron, magnesium, zinc 2 Metals are good conductors of heat and electricity; non-metals are poor conductors of heat and electricity. 3 Carbon (graphite) conducted electricity. 4 For example, copper is used for electrical wiring, plastic is used as insulation for wiring, copper is used to make saucepans, wood is used for saucepan handles. 5 Plastic, wood and glass Teacher and technician notes Reacting metals with acids Resources available Core sheet Reacting metals with acids CD-ROM All resources customisable E2 Warn students not to heat the metal and acid mixtures using Bunsen burners. If a faster reaction is desired for zinc, the mixture should be heated in a beaker of hot water. This could be demonstrated. Materials required Links with Book 3 SoW Sc1 E2 9E page 2 2fgijkm Safety Eye protection must be worn. Care should be taken when handling both hydrochloric acid and sulphuric acid as they are corrosive. Students should take care not to burn their fingers when using lighted splints for the hydrogen test. Take care when washing apparatus in case acid is splashed. Activity procedure 1 Students place samples of metals in turn into hydrochloric acid and sulphuric acid. 2 They test any gas evolved with a lighted splint. They also see if the test tube gets hot. Running the activity Students should be warned of the corrosive nature of the two acids. Zinc reacts slowly at room temperature so there may not be enough gas evolved to produce a `pop' with a lighted splint. Some of the zinc and the copper will be left unreacted at the end of the experiment. Students should empty test tubes into a large beaker before washing them to prevent blockage of sinks. Per group six test tubes and rack hydrochloric acid, 0.4 mol/dm3 sulphuric acid, 0.4 mol/dm3 wooden splints Bunsen burner heatproof mat pieces of magnesium, zinc and copper foil Notes on materials preparation 0.4 mol/dm3 hydrochloric acid should be prepared in a fume cupboard by making up 35 cm3 of concentrated hydrochloric acid to 1000 cm3 with distilled water. 0.4 mol/dm3 sulphuric acid can be prepared by slowly adding 22 cm3 of concentrated sulphuric acid to 800 cm3 of cold water and diluting the solution to 1000 cm3. Small pieces of metal foil, approximately 0.5 cm square, are ideal for the metal samples. Answers 1 Magnesium and zinc 2 Yes, hydrogen was produced with both magnesium and zinc for both acids. 3 Magnesium 1 hydrochloric acid magnesium chloride 1 hydrogen 4 With copper no bubbles of hydrogen were seen, and the test tube did not get hot. 3 C D Lees, 2002, The Heinemann Science Scheme Teacher and technician notes Reacting carbonates with acids Resources available Core sheet Reacting carbonates with acids CD-ROM All resources customisable Links with Book 3 SoW Sc1 E3 9E page 3 2fgijkm Safety Delivery tubes are fragile. Warn students that they are easily broken. Materials required Per group hydrochloric acid, 0.4 mol/dm3 sodium carbonate copper(II) carbonate four test tubes Eye protection must be worn. delivery tube and bung Care should be taken when handling hydrochloric acid as it is corrosive. limewater spatula Take care when washing apparatus in case acid is splashed. clamp stand When powdered carbonate is added to acid, the reaction is vigorous. Warn students to take care that the mixture does not fizz out of the tube over their hands. Delivery tubes are easily broken. If this happens, care should be taken not to cut hands on the sharp edges. Activity procedure 1 Students add sodium carbonate and copper(II) carbonate in turn to hydrochloric acid in a test tube. 2 A delivery tube is used to pass the gas produced through limewater in a second test tube. Running the activity Students should be warned of the corrosive nature of the acid, and of the danger of the mixture `frothing over' when carbonate is added to acid. 4 C Warn students not to use more than the quantities of materials stated in the instructions. D Lees, 2002, The Heinemann Science Scheme Notes on materials preparation 0.4 mol/dm3 hydrochloric acid should be prepared in a fume cupboard by making up 35 cm3 of concentrated hydrochloric acid to 1000 cm3 with distilled water. Powdered anhydrous samples of the carbonates should be used. Answers 1 A gas was given off; the test tube became warm. 2 Carbon dioxide 3 Water 4 A green colour in the liquid 5 Copper carbonate 1 hydrochloric acid copper chloride 1 carbon dioxide 1 water E3 Teacher and technician notes Reacting metal oxides with acids Resources available Core sheet Reacting metal oxides with acids CD-ROM All resources customisable Links with Book 3 SoW Sc1 E4a 9E page 4 2afgijkm Safety Eye protection must be worn. E4 Remind students to take care not to evaporate the solution to dryness. The final reducedvolume solution may need to be left overnight for crystals to form. The students may be given stock crystals to compare with the ones they have made. One crystal of good shape may be selected and suspended by a fine wire in the collected remaining solution to grow a larger crystal. Materials required Per group 400 cm3 beaker Care should be taken when handling sulphuric acid as it is corrosive. Bunsen burner The beaker of hot water should be set up carefully so that it will not be knocked over. heatproof mat Hot tripods should not be handled and should be left to cool. boiling tube Activity procedure 1 Students heat a mixture of copper(II) oxide and dilute sulphuric acid in a water bath. 2 They filter the mixture. 3 They partially evaporate the filtrate. 4 They leave the solution to form crystals. Running the activity Homework E4 may be used to plan all or part of this activity prior to the practical. Care must be taken that students set up the water bath safely. If all of the copper(II) oxide reacts, more must be added. It is essential that all of the acid has reacted so that acid is not evaporated, so the copper(II) oxide must be in excess. tripod and gauze sulphuric acid, 0.4 mol/dm3 copper(II) oxide spatula filter funnel filter paper evaporating basin Notes on materials preparation 0.4 mol/dm3 sulphuric acid can be prepared by slowly adding 22 cm3 of concentrated sulphuric acid to 800 cm3 of cold water and diluting the solution to 1000 cm3. Answers 1 To speed up the reaction 2 To remove excess (unreacted) copper oxide 3 Crystals of copper sulphate 4 Copper oxide 1 sulphuric acid copper sulphate 1 water 5 No gas was produced. 5 C D Lees, 2002, The Heinemann Science Scheme Teacher and technician notes Neutralising an acid with an alkali Resources available Core sheet Neutralising an acid with an alkali CD-ROM All resources customisable Links with Book 3 SoW Sc1 E5 9E page 5 2fgijkm Safety The titration should be demonstrated by the teacher behind safety screens. A safety pipette filler should be used to measure out the acid. Activity procedure 1 As a teacher demonstration, a pipette is used to measure 25 cm3 of acid into a beaker. To this is added approximately 25 cm3 of distilled water, or more if necessary to cover the end of the pH probe. A stopwatch is started and 2 cm3 of alkali are added from the burette every minute. Although the students plot pH against volume, the computer printout will feature pH against time. Since the alkali is added every two minutes the computer plot is valid. Materials required Per class potassium hydroxide solution, 0.1 mol/dm3 hydrochloric acid, 0.1 mol/dm3 distilled water 25 cm3 pipette safety pipette filler 50 cm3 burette and stand 400 cm3 beaker stirrer (magnetic if available) pH probe temperature sensor data logger computer, preferably with printer stopwatch 2 The pH of the mixture is monitored using a Notes on materials preparation The computer, data logger and probes should be set up in advance and tested to make sure that the system is working prior to the lesson. 3 Students plot a graph of pH (on the vertical Acid/Base Titrations is a piece of simulations software available from Newbyte Educational Software, PO Box 16710, Glasgow, G12 9WS, www.newbyte.com. data logger and computer. A temperature sensor is used to follow temperature changes in the mixture. axis) against volume of alkali added. A graph printed from the computer may also be provided for students. Running the activity Tell the students that distilled water is added to the acid in the beaker to allow enough depth for the probes to work. Explain that the addition of distilled water will not affect the results. Students should note the results each minute. Most software will allow a large display of the pH and temperature on the computer screen. 6 C D Lees, 2002, The Heinemann Science Scheme Answers 1 So that the probes had enough depth of liquid to work 2 Started low and rose. It changed little at first, then it changed very rapidly near the neutralisation point. After this the pH again changed very little. 3 Correct result read from graph 4 It gives out heat. 5 Potassium chloride E5a Teacher and technician notes Uses of salts E5b Resources available Answers Extension sheet Uses of salts CD-ROM All resources customisable Students are expected to expand on the brief details given below. The students' accounts should be checked for accuracy and marked for communication skills. Ammonium nitrate ± fertiliser Links with Book 3 SoW Sc1 E5 9E page 5 2bk Activity procedure 1 Students are given a list of salts and asked to find out what they are used for, using secondary sources such as text books and the internet. 2 They use rough notes to write an account of how salts are used in the twenty-first century. Running the activity Careful selection of text books will allow much of the required information to be gained from them. Students may be given access to a wider range of books in the school library. If possible students should be given access to the internet. Ammonium sulphate ± fertiliser Calcium carbonate ± indigestion remedy Calcium chloride ± drying agent Calcium nitrate ± fireworks Calcium phosphate ± washing powder Calcium sulphate ± plaster casts Copper sulphate ± fungicide Iron(II) nitrate ± animal feeds, catalyst Iron sulphide ± making hydrogen sulphide gas (in small quantities) Magnesium sulphate ± tanning, dyeing Potassium nitrate ± gunpowder Silver chloride ± photography Silver nitrate ± testing for the presence of chloride in water, as an antiseptic for treating cuts and burns Sodium carbonate ± glass-making Sodium chloride ± salting roads, making acids Zinc sulphate ± pesticides and fungicides Materials required Per student or group selection of science text books access to school library access to computer connected to the internet 7 C D Lees, 2002, The Heinemann Science Scheme Teacher and technician notes Writing equations E6a Core sheet Writing equations For some of the reactions in the questions, students may need help to rearrange the reactants into products. Resource sheet Writing equations The cards may be kept for re-use in Activity E6b. CD-ROM All resources customisable Resources available Links with Book 3 SoW Sc1 E6 9E pages 2±6 2ijk Safety Blunt-ended scissors should be used. Activity procedure 1 Students cut out cards from the resource sheet. Materials required Per group Resource sheet E6a scissors Notes on materials preparation The resource sheet should be photocopied on thin card if possible, though paper may be used. Answers 1 Nitric acid 1 potassium hydroxide potassium nitrate 1 water 2 They use the cards to put together the names 2 Magnesium 1 hydrochloric acid magnesium chloride 1 hydrogen 3 They rearrange the cards to make the 3 Copper oxide 1 sulphuric acid copper sulphate 1 water of reactants. products of the reaction. Running the activity At this stage the different sizes of the boxes is not important. If students ask about this they should be told to ignore it. Some students may need help with the idea of eg hydrogen sulphate being sulphuric acid. 8 C D Lees, 2002, The Heinemann Science Scheme 4 Zinc carbonate 1 hydrochloric acid zinc chloride 1 carbon dioxide 1 water 5 Zinc 1 sulphuric acid zinc sulphate 1 hydrogen 6 Nitric acid 1 magnesium hydroxide magnesium nitrate 1 water Teacher and technician notes Balanced symbol equations Resources available E6b Running the activity Extension sheet Balanced symbol equations Resource sheet Writing equations CD-ROM All resources customisable Links with Book 3 SoW Sc1 E6 9E pages 2±6 2ijk Safety Blunt-ended scissors should be used. Activity procedure 1 Students cut out cards from the resource sheet, or re-use them from Activity E6a. 2 They use the cards to put together the formulae of reactants. 3 They rearrange the cards to make the formulae of the products of the reaction. 4 They use this information to write a balanced Some students may require help in putting together the correct number of cards for each formula. Materials required Per group: Resource sheet E6a scissors Notes on materials preparation The resource sheet should be photocopied on thin card if possible, though paper may be used. Alternatively, cards made during Activity E6a may be re-used for this activity. Answers 1 HNO3 1 KOH 2 Mg 1 2HCl KNO3 1 H2O MgCl2 1 H2 3 CuO 1 H2SO4 CuSO4 1 H2O 4 ZnCO3 1 2HCl 5 Zn 1 H2SO4 ZnCl2 1 CO2 1 H2O ZnSO4 1 H2 6 2HNO3 1 Mg(OH)2 Mg(NO3)2 1 2H2O symbol equation for the reaction. 9 C D Lees, 2002, The Heinemann Science Scheme Activity Looking at metals and non-metals E1a Core Aim To look at the different properties of metals and non-metals. Equipment samples of metal and non-metal elements scalpel with guard scalpel metal or non-metal What to do 1 Draw a table like the one below ready to record your results. 2 Collect a sample of one element. 3 Look carefully at the appearance of the element. 4 Try to bend the sample to find out how flexible it is. Make sure that you do not break it. 5 Try to scratch the sample using a scalpel, to find out how hard it is. 6 Record your results in your table. 7 Repeat steps 2 to 6 with each element. Your teacher will demonstrate the next part of the experiment. Take care using a scalpel. Replace the guard between use. 8 Your teacher will show you some more elements. 9 Some samples of elements will be hit with a hammer, to find out how brittle they are. 10 Record the results of these experiments in your table. Results Element Is it a metal or a non-metal? What does it look like? How flexible is it? How hard is it? How brittle is it? Questions 1 List the properties of the metal elements you studied. 2 List the properties of the non-metal elements you studied. 3 What exceptions to these general rules did you see? 4 What other properties of metals and non-metals could be tested? 1 C D Lees, 2002, The Heinemann Science Scheme Activity Properties of metals and non-metals E1b Core Aim To investigate the conduction of electricity and heat by metals and non-metals. Equipment battery lamp switch four connecting leads two crocodile clips samples of metals and non-metals What to do 1 Draw a table like the one below ready to record your results. 2 Put together the apparatus as shown in the diagram. 3 Place a metal or non-metal sample between the two crocodile clips. 4 Press the switch for a few seconds. 5 Record in your table whether or not the lamp lights. 6 Repeat steps 3 to 5 ⴙ ⴚ crocodile clips with each sample. Your teacher will demonstrate the next part of the experiment. 7 Your teacher will set up a beaker of boiling water. 8 Rods of metals and non-metals will be placed with one end in the boiling water. They will be left for at least 10 minutes. 9 The teacher or students will feel the other end of each rod to see how hot it is. 10 Record the results in your table. Wear eye protection. Results Element Is it a metal or non-metal? Did the lamp light? How hot was the end of the rod? Questions 1 Which of the samples conducted electricity and heat well? 2 What is the pattern in the results for metals and non-metals? 3 What exceptions are there to this pattern? 4 Give two examples of how these properties determine how we use metals and non-metals. 5 Which of the samples used are not elements? 2 C D Lees, 2002, The Heinemann Science Scheme Activity Reacting metals with acids E2 Core Aim To find out how metals react with acids. Equipment six test tubes and rack dilute hydrochloric acid dilute sulphuric acid wooden splints Bunsen burner heatproof mat pieces of magnesium, zinc and copper foil burning splint ;;;; dilute acid metal What to do 1 Draw a table like the one below ready to record your results. Wear eye protection. Take care not to get acid on your skin or clothes. 2 Pour about 2 cm depth of dilute hydrochloric acid into a test tube in a rack. 3 Add a small piece of magnesium to the acid in the test tube. Immediately put your finger or thumb over the end of the test tube. 4 After about one minute, bring a lighted splint to the end of the test tube as you take your finger or thumb away. 5 Feel the bottom of the tube to see if it is hot. 6 Record the results in your table. 7 Repeat steps 8 Repeat steps 2 to 6 using zinc instead of magnesium. You may not be able to collect enough gas to test with a lighted splint this time. 9 Repeat steps 2 to 6 using copper instead of magnesium. Do not carry out the test with a lighted splint this time. 2 to 6 using sulphuric acid instead of hydrochloric acid. Continued 3 C D Lees, 2002, The Heinemann Science Scheme Activity Reacting metals with acids continued E2 Core Results Metal Acid Observations Results of test with lighted splint Questions 1 Which metals reacted with the two acids? 2 Was the same gas produced in each reaction? 3 Write a word equation for the reaction between magnesium and hydrochloric acid. 4 Copper did not react with the acids. How do you know that a reaction did not take place? 4 C D Lees, 2002, The Heinemann Science Scheme Activity Reacting carbonates with acids E3 Core Aim To find out how metal carbonates react with acids. Equipment dilute hydrochloric acid sodium carbonate copper carbonate four test tubes delivery tube and bung limewater spatula clamp stand delivery tube Wear eye protection. Take care not to get acid on your skin or clothes. dilute acid limewater metal carbonate What to do 1 Draw a table like the one below ready to record your results. 2 Pour about 2 cm depth of dilute hydrochloric acid into a test tube. 3 Pour some limewater into another test tube so that it is about half full. 4 Get a delivery tube ready with the delivery end in the limewater. 5 Add a spatula measure of sodium carbonate to the test tube containing hydrochloric acid. Immediately fit the delivery tube to this test tube to bubble gas through the limewater. 6 Feel the bottom of the tube containing acid and carbonate to see if it is hot. 7 Record your observations in your table. 8 Repeat steps 2 to 7 using a few small pieces of copper carbonate instead of sodium carbonate. Results Metal carbonate Observations in acid test tube Observations in limewater test tube Continued 5 C D Lees, 2002, The Heinemann Science Scheme Activity Reacting carbonates with acids continued Questions 1 What observations showed you that a reaction takes place between sodium carbonate and hydrochloric acid? 2 Which gas was produced in both of the reactions you carried out? 3 What additional substance is produced, other than a salt and carbon dioxide, in these reactions? 4 What observation showed you that a salt was produced when copper carbonate reacted with hydrochloric acid? 5 Write a word equation for the reaction of copper carbonate with hydrochloric acid. 6 C D Lees, 2002, The Heinemann Science Scheme E3 Core Activity Reacting metal oxides with acids E4 Core Aim To find what happens when metal oxides react with acids. Equipment beaker Bunsen burner tripod and gauze heatproof mat filter funnel filter paper evaporating basin dilute sulphuric acid boiling tube copper oxide spatula What to do 1 Draw a table like the one on the next page ready to record your results. Record your observations at each stage. 2 Set up a beaker half filled with water on a tripod and gauze. Heat the water to boiling using a Bunsen burner. Turn off the Bunsen burner when the water is boiling. 3 Pour about 3 cm depth of dilute sulphuric acid into a boiling tube. 4 Add two spatula measures of copper oxide to the sulphuric acid. 5 Place the boiling tube in the beaker of hot water for a few minutes. Every minute remove the boiling tube to shake the contents of the tube. hot water If all of the copper oxide disappears, add another spatula measure. sulphuric acid and copper oxide ;y;y;y ;y;y ;y;y ;y;y;y ;y;y;y ;y;y;y;y ;y;y ;y;y ;y;y;y ;y;y;y;y When no more copper oxide will disappear, filter the contents of the tube, collecting the filtrate in an evaporating basin. 7 Place the evaporating basin on the tripod and gauze. Boil the filtrate until only about a third of the original volume is left. filtrate evaporating basin y;y; y;y; y;y; y;y;y; y;y;y; y;y;y;y; y;y; y;y; y;y;y; y;y;y;y; 6 8 ;; Wear eye protection. Take care not to get acid on your skin or clothes. Leave your evaporating basin and remaining liquid to cool. Then look at them and record the appearance of the final product. Continued 7 C D Lees, 2002, The Heinemann Science Scheme Activity Reacting metal oxides with acids continued E4 Core Results Appearance of acid and oxide before heating Appearance of acid and oxide after heating Appearance of filtrate Appearance of final product Questions 1 Why were the of copper oxide and sulphuric acid heated? 2 Why were the contents of the test tube filtered? 3 What was formed at the end of the experiment? 4 Write a word equation for the reaction between copper oxide and sulphuric acid. 5 Why were no bubbles seen as the copper oxide and sulphuric acid reacted? 8 C D Lees, 2002, The Heinemann Science Scheme Activity Neutralising an acid with an alkali E5a Core Aim To find out what happens when an alkali is added to an acid. Equipment For the demonstration: dilute potassium hydroxide solution dilute hydrochloric acid distilled water 25 cm3 pipette safety pipette filler 50 cm3 burette and stand 400 cm3 beaker stirrer What to do Your teacher will demonstrate this experiment. 1 Draw a table like the one below ready to record your results. 2 Your teacher will set up the apparatus shown in the diagram. pH probe temperature sensor data logger computer stopwatch potassium hydroxide solution temperature sensor 3 A pipette is used to measure 25 cm3 of acid into the beaker. About 25 cm3 of distilled water are added. 4 2 cm3 of alkali are added from the burette every minute while the mixture is stirred. to data logger and computer 5 The pH of the mixture is monitored using a data logger. hydrochloric acid 6 A temperature sensor is used to follow the temperature change in the mixture. 7 Use your results to plot a graph of pH (on the vertical axis) against volume of alkali added. Your teacher may give you a graph printed from the computer. pH probe stirrer Results Volume of alkali added (cm3) pH of mixture Temperature of mixture (8C) Questions 1 Why was distilled water added to the acid in the beaker? 2 Describe what happened to the pH of the mixture during the experiment. 3 What volume of alkali exactly neutralises 25 cm3 of acid? Use your graph to find the answer. 4 Does the neutralisation reaction give out heat or take in heat? 5 What is the name of the salt produced in this reaction? 9 C D Lees, 2002, The Heinemann Science Scheme Activity Uses of salts Aim To find the uses of some salts using secondary sources. Equipment selection of science text books access to school library access to computer connected to the internet What to do You will be given access to a range of books. You may be given access to the internet to help you to find information. 1 Use the resources available to find out what some or all of the salts in the list below are used for. 2 During your research make notes that you can use later. 3 Use your notes to write an account of the use of salts in the twenty-first century. Salts ammonium nitrate ammonium sulphate calcium carbonate calcium chloride calcium nitrate calcium phosphate calcium sulphate copper sulphate iron(II) nitrate iron sulphide magnesium sulphate potassium nitrate silver chloride silver nitrate sodium carbonate sodium chloride zinc sulphate 10 C D Lees, 2002, The Heinemann Science Scheme E5b Extension Activity Writing equations E6a Core Aim To write word equations for reactions. Equipment Resource sheet E6 scissors What to do 1 Cut out the cards on the resource sheet. 2 Arrange the cards for hydrogen and chloride side by side: H hydrogen Cl chloride This represents hydrochloric acid. All acids have hydrogen as part of the formula. Sulphuric acid is hydrogen sulphate and nitric acid is hydrogen nitrate. 3 Now arrange the cards for sodium and hydroxide side by side: Na sodium OH hydroxide This represents the alkali sodium hydroxide. All alkalis have hydroxide as part of the formula. 4 You are going to write the word equation for the neutralisation reaction between hydrochloric acid and sodium hydroxide. First write the reactants on the left of the equation: hydrochloric acid 1 sodium hydroxide 5 6 Now rearrange the cards to show the products: Na sodium Cl chloride H hydrogen OH hydroxide Now complete the word equation: hydrochloric acid 1 sodium hydroxide sodium chloride 1 water Note that hydrogen hydroxide is water, H2O. Continued 11 C D Lees, 2002, The Heinemann Science Scheme Activity Writing equations continued Questions Use the same method to write a word equation for each of the following reactions. 1 Nitric acid 1 potassium hydroxide 2 Magnesium 1 hydrochloric acid 3 Copper oxide 1 sulphuric acid 4 Zinc carbonate 1 hydrochloric acid 5 Zinc 1 sulphuric acid 6 Nitric acid 1 magnesium hydroxide 12 C D Lees, 2002, The Heinemann Science Scheme E6a Core Activity Writing equations E6a Resource NO3 nitrate NO3 nitrate C carbon Na sodium Na sodium K potassium Cu copper Mg magnesium SO4 sulphate CO3 carbonate K potassium H hydrogen Zn zinc H hydrogen OH hydroxide O oxide OH hydroxide Cl chloride Cl chloride 13 C D Lees, 2002, The Heinemann Science Scheme Activity Balanced symbol equations E6b Extension Aim To write balanced symbol equations for reactions. Equipment Resource sheet E6 scissors What to do 1 Cut out the cards on the resource sheet. 2 Arrange cards for hydrogen and chloride side by side: H hydrogen Cl chloride To match the cards you need one hydrogen card and one chloride card. This represents the formula for hydrochloric acid, which is HCl. (Note: All acids have hydrogen as part of the formula. Sulphuric acid is hydrogen sulphate and nitric acid is hydrogen nitrate.) 3 Now arrange the cards to show the formula for magnesium hydroxide: OH hydroxide Mg magnesium OH hydroxide Note that two hydroxide cards are needed to match up to one magnesium card, so the formula for magnesium hydroxide is Mg(OH)2. The set of brackets around OH shows that we have two lots of OH. If we wrote MgOH2 it would look like one oxygen and two hydrogens. 4 Next, you are going to write a balanced symbol equation for the reaction between magnesium hydroxide and hydrochloric acid. Write the formulae of the reactants: Mg(OH)2 1 HCl Continued 14 C D Lees, 2002, The Heinemann Science Scheme Activity Balanced symbol equations continued 5 E6b Extension Now rearrange the cards to make the formulae of the products: Mg magnesium Cl chloride Cl chloride H hydrogen OH hydroxide H hydrogen OH hydroxide Note that you need an extra Cl because the formula for magnesium chloride is MgCl2. To get this extra Cl you will need an extra molecule of hydrochloric acid. Using the extra H, two molecules of water, H2O, can be formed. 6 Now use the cards to help you complete the symbol equation: Mg(OH)2 1 2HCl MgCl2 1 2H2O Note how the number 2 has been placed in front of the formulae for hydrochloric acid and for water, to show that two molecules of each are in the equation. Questions Use the same method to write a balanced symbol equation for each of the following reactions. 1 Nitric acid 1 potassium hydroxide 2 Magnesium 1 hydrochloric acid 3 Copper oxide 1 sulphuric acid 4 Zinc carbonate 1 hydrochloric acid 5 Zinc 1 sulphuric acid 6 Nitric acid 1 magnesium hydroxide 15 C D Lees, 2002, The Heinemann Science Scheme Homework Why are metals useful? E1 Metals and non-metals in the home Look in and around your home. You will find many articles that are made of metals and many others that are made of materials that are not metals. You may find that some articles in your home are made from a mixture of two or more metals. A mixture of metals is called an alloy. An example of an alloy is brass, which is a mixture of copper and zinc. You will also find some compounds and mixtures in your home that are not metals. For example, glass is a mixture made from the compounds silicon dioxide and sodium carbonate. 1 Draw a table showing the names of some metals in your home, the job that each one is used for, and the properties of the metal that make it useful for that job. 2 Draw a second table showing the names of some materials that are not metals in your home, the job that each one is used for, and the properties that make it useful for that job. 3 For one of the metals you have listed, try to find out more information: When was the metal discovered? Where do we get it from? What are its properties? What else is it used for? Use books, the library and the internet if possible to find the information. Write up your findings as a set of notes. ........................................................................................ Homework Which metals react with acids? E2 Not all metals react with dilute acids. Amongst those that do not react are silver, gold and platinum. Some metals, such as iron and zinc, react slowly with dilute acids. Sodium and potassium react so quickly and violently with dilute acids that these reactions are too dangerous to be carried out in the laboratory. 1 Look at the names of the metals that do not react with dilute acids. How could you show that these metals do not react with dilute acids? 2 Sweat contains dilute acids. Explain why it is better to make jewellery from gold rather than zinc. 3 What might happen if you tried to show the reaction of sodium with dilute hydrochloric acid in the laboratory? 1 C D Lees, 2002, The Heinemann Science Scheme Homework Naming salts E3 Below are some reactions used to make salts. For each one, name the salt that is produced. 1 Sulphuric acid 1 potassium hydroxide 2 Magnesium 1 nitric acid 3 Zinc oxide 1 hydrochloric acid 4 Copper carbonate 1 nitric acid 5 Zinc1 hydrochloric acid 6 Sulphuric acid + magnesium hydroxide ........................................................................................ Homework How do metal oxides react with acids? Making copper sulphate crystals Rather than asking questions about work you have done in class, this homework is to prepare for your next science lesson. Your science class is going to make crystals of copper sulphate from copper oxide powder and a dilute solution of sulphuric acid. Plan how you will carry out this experiment. Include details of the apparatus you will use and full instructions for each step of the experiment. Draw diagrams of the apparatus you will use. 2 C D Lees, 2002, The Heinemann Science Scheme E4 Homework How do alkalis react with acids? E5 Neutralisation at home Many of the products that we use at home contain acids or alkalis. Look in and around your home to find products that contain acids or alkalis. You will probably find the contents listed on the label of each product. Remember that acids are usually called `something' acid, eg sulphuric acid, and alkalis are usually called `something' hydroxide, eg sodium hydroxide. Also look for substances that will neutralise acids, for example carbonates and hydrogencarbonates (often called bicarbonates). Good places to look are amongst cleaning products and in the medicine cupboard. You must ask your parents or other adults for permission to look in these places. Your medicine cupboard may be locked. You may need to be supervised when you look at some of the products. Make a table listing each product, the acid, alkali or neutralising substance it contains, and what the product is used for. ........................................................................................ Homework Writing word equations E6 In Homework E3 Naming salts you worked out the names of the salts formed in some reactions. For each one you can now write a word equation. You may find it useful to look back at the work you did in Activity E6a Writing equations. 1 Sulphuric acid 1 potassium hydroxide 2 Magnesium 1 nitric acid 3 Zinc oxide 1 hydrochloric acid 4 Copper carbonate 1 nitric acid 5 Zinc 1 hydrochloric acid 6 Sulphuric acid 1 magnesium hydroxide 3 C D Lees, 2002, The Heinemann Science Scheme Specials Why are metals useful? E1 1 Complete these sentences. Use the words below to fill the gaps. You must use each word once only. aluminium copper dense electricity shiny is an excellent conductor of . For this reason is used to make wires and cables to carry electricity in our homes. is also a good conductor of electricity. It is used for overhead power cables carried on pylons because it is less than copper. Copper overhead cables would be too heavy. Gold is used for making jewellery. It does not react with acid and so will stay and not corrode. 2 Choose which of the statements in the table are descriptions of metals and which are descriptions of non-metals. Put a tick in the correct box for each one. Statement Metals Nonmetals They have a shiny surface. They do not conduct electricity. They are good conductors of heat. They are flexible. They are strong. 1 C D Lees, 2002, The Heinemann Science Scheme Specials How do metals react with acids? E2 1 Complete these sentences. Use the words below to fill the gaps. You must use each word once only. burns gold heat hydrogen splint zinc Not all metals react with dilute acids in the same way. does not react at all, but reacts steadily. When a metal does react with a dilute acid, a salt and gas are always made. The reaction also gives out . You can test for hydrogen gas using a lighted . The gas with a popping noise. 2 Complete the word equations. Use the words below to fill the gaps. You must use each word once only. calcium hydrochloric hydrogen a Magnesium 1 iron nitrate sulphate acid magnesium chloride 1 b 1 sulphuric acid calcium 1 hydrogen c Iron 1 nitric acid 1 hydrogen 2 C D Lees, 2002, The Heinemann Science Scheme Specials How do metal carbonates react with acids? E3 1 The apparatus shown can be used to react calcium carbonate with hydrochloric acid and test the gas given off. a Write these labels in the correct boxes on the diagram. calcium carbonate dilute hydrochloric acid limewater delivery tube b The limewater goes milky white as the gas passes through it. Which gas does this test prove has been produced in the reaction? Choose from this list and write your answer on the line below. carbon dioxide hydrogen oxygen 2 Complete these sentences. Use the words below to fill the gaps. You must use each word once only. calcium nitrate sulphate zinc Calcium carbonate and hydrochloric acid react to make the salt chloride. Copper carbonate and sulphuric acid react to make the salt copper . Zinc carbonate and nitric acid react to make the salt . 3 C D Lees, 2002, The Heinemann Science Scheme Specials How do metal oxides react with acids? E4 1 The sentences below describe how crystals of copper sulphate can be made from copper oxide and dilute sulphuric acid, but they are in the wrong order. A B C D E F Filter the mixture and collect the filtrate in an evaporating basin. Leave the hot solution to cool. Add copper oxide to dilute sulphuric acid in a test tube. Filter again to collect crystals of copper sulphate. Warm the mixture in a beaker of hot water. Heat the solution to evaporate off about two-thirds of the water. Write the letters to show the correct order of the sentences. The correct order is 2 Complete the word equations. Use the words below to fill the gaps. You must use each word once only. nitrate a Magnesium oxide 1 sulphuric water zinc acid magnesium sulphate 1 water b oxide 1 hydrochloric acid c Iron oxide 1 nitric acid iron 4 C D Lees, 2002, The Heinemann Science Scheme 1 zinc chloride 1 water Specials How do alkalis react with acids? E5 1 The apparatus shown can be used to react potassium hydroxide with hydrochloric acid and measure the change in pH and temperature. dilute potassium hydroxide stirrer pH probe Write these labels in the correct boxes on the diagram. burette to data logger and computer dilute hydrochloric acid temperature sensor 2 The pH scale is shown here. Acid is added to alkali until the solution is neutral. 1 2 3 4 5 6 7 8 9 more acidic 10 11 12 13 14 more alkaline neutral How does the pH of the solution change during this neutralisation reaction? Circle the correct answer. from pH 14 to pH 7 from pH 7 to pH 14 from pH 1 to pH 7 3 Complete the word equations. Use the words below to fill the gaps. You must use each word once only. calcium a hydroxide potassium sulphate water hydroxide 1 hydrochloric acid potassium chloride 1 water b Sodium + sulphuric acid sodium + water c Calcium hydroxide 1 nitric acid nitrate 1 5 C D Lees, 2002, The Heinemann Science Scheme Extension Chemical translation E3 The language of chemical symbols, formulae and equations is the same all over the world. Chemists from all countries can understand symbol equations, whatever language they speak. The passage below is about some chemical reactions that you have studied, but it is written in German. Look carefully at the equations included in the passage. Wenn Kalziumcarbonat hinzugefuÈgt wird, um die SalzsaÈure zu verduÈnnen, wird das Salz Kalziumchlorid gebildet. Wasser und Kohlendioxid werden auch gebildet. CaCO3 1 2HCl CaCl2 1 H2O 1 CO2 FuÈr den Nachweis von Kohlendioxid, wird das Gas durch eine Kalziumhydroxid LoÈsung geleitet. Die waÈssrige, klare LoÈsung wird zu einer truÈben weiûen Mischung. CO2 1 Ca(OH)2 CaCO3 1 H2O 1 What do you think this passage is about? 2 What helped you answer question 1? 3 Try to write a `translation' of the passage. ........................................................................................ Extension Writing balanced symbol equations E6 In Homework E6 Writing word equations, you wrote word equations for some reactions involving acids. For each one you can now write a balanced symbol equation. You may find it useful to look back at the work you did in Activity E6b Balanced symbol equations. 1 Sulphuric acid 1 potassium hydroxide 2 Magnesium 1 nitric acid 3 Zinc oxide 1 hydrochloric acid 4 Copper carbonate 1 nitric acid 5 Zinc 1 hydrochloric acid 6 Sulphuric acid 1 magnesium hydroxide 1 C D Lees, 2002, The Heinemann Science Scheme Test yourself Reactions of metals and metal compounds Unit E 1 Tick the statements that are true. A metal is: a good conductor of heat brittle a solid shiny strong living an electrical insulator 2 Complete the passage. Choose from the words below to fill the gaps. Use each word once only. high liquids low metals Most of the elements are non-metals solids . These are all at room temperature except mercury. Most metals have melting points. 3 Complete this table about metals by filling in the empty boxes. Metal Use of metal copper aluminium conducts electricity saucepans drills gold Property related to this use very hard jewellery 4 When a metal reacts with an acid, two products are formed. What are these two products? 1 a 2 Continued 1 C D Lees, 2002, The Heinemann Science Scheme Test yourself Reactions of metals and metal compounds continued Unit E 5 Look at this list of metals. potassium sodium zinc iron copper gold Choose from the list a metal that: a reacts violently with dilute hydrochloric acid b reacts steadily with dilute hydrochloric acid c does not react with dilute hydrochloric acid. 6 Complete this word equation. magnesium 1 acid sulphate 1 7 When metal carbonates react with acids, the gas carbon dioxide is produced. Describe a test for carbon dioxide. Test: Result: 8 Complete this word equation. copper carbonate 1 acid copper nitrate 1 1 Continued 2 C D Lees, 2002, The Heinemann Science Scheme Test yourself Reactions of metals and metal compounds continued Unit E 9 a These sentences describe how you could make crystals of zinc sulphate, but some instructions have been missed out. Fill in the missing instructions. Add some zinc oxide to dilute sulphuric acid in a test tube. Warm the mixture in a beaker of hot water. Evaporate some of the water by boiling the solution. Filter to get the crystals of zinc sulphate. b Write a word equation for the reaction between zinc oxide and sulphuric acid. 10 15 cm3 of sodium hydroxide solution are measured into a beaker. 30 cm3 of the same concentration of hydrochloric acid are added 1 cm3 at a time. The pH of the solution is measured after each addition. a What is the pH: i when no acid has been added? pH ii when 15 cm3 of acid have been added? pH iii when 30 cm3 of acid have been added? pH b What is this type of reaction called? c What is the name of the salt formed during this reaction? Continued 3 C D Lees, 2002, The Heinemann Science Scheme Test yourself Reactions of metals and metal compounds continued Unit E 11 The table gives the names of salts and substances that can be reacted to form these salts. Fill in the empty boxes to complete the table. Salt Substances reacted together to make the salt hydrochloric acid sodium hydroxide copper sulphate copper oxide magnesium nitrate magnesium carbonate potassium sulphate sulphuric acid 12 Complete these word equations. aluminium oxide + acid aluminium sulphate + water lithium hydroxide + nitric acid + water calcium + hydrochloric acid calcium + potassium carbonate + hydrochloric acid 1 4 C D Lees, 2002, The Heinemann Science Scheme 1 water End of unit test Reactions of metals and metal compounds Unit E Tier 3±6 1 Which of the following changes are chemical reactions? A When magnesium is heated, it changes from shiny silver to a white powder. B When chocolate is heated, it goes liquid and then solid. C hen salt is added to water, a clear liqiud is produced. D When a marble chip is added to an acid, bubbles are produced (2 marks) 2 a When calcium carbonate is added to hydrochloric acid, carbon dioxide gas is produced. How could you prove that the gas is carbon dioxide? (2 marks) b When zinc is added to sulphuric acid, hydrogen gas is produced. How could you prove that the gas is hydrogen? (2 marks) 3 When dilute hydrochloric acid is added to copper carbonate, a salt is produced. Copy and complete this word equation for the reaction. copper carbonate 1 hydrochloric acid (2 marks) copper 1 1 water 4 A piece of zinc is added to some dilute sulphuric acid in a test tube. A chemical reaction takes place. a i Describe two observations that show a chemical reaction is taking place. (2 marks) ii Name the salt made in this reaction. (1 mark) iii Name the gas produced (1 mark) b A piece of magnesium is added to some more dilute sulphuric acid in another test tube. The metal reacts with the acid. Describe one way in which this reaction is similar to that of zinc and dilute sulphuric acid. c Zinc oxide reacts with sulphuric acid as shown in the word equation below. zinc oxide 1 sulphuric acid (1 mark) zinc sulphate 1 water i Using this information, copy and complete the general equation below to show how metal oxides react with acids. (1 mark) metal oxide 1 acid 1 water ii When iron oxide reacts with sulphuric acid, what else is produced apart from water? (1 mark) Continued 1 C D Lees, 2002, The Heinemann Science Scheme End of unit test Reactions of metals and metal compounds continued Unit E Tier 3±6 5 10 cm3 of a dilute solution of potassium hydroxide are placed in a beaker. Dilute nitric acid is then added a few drops at a time and the solution tested with Universal Indicator paper after each addition. When the alkali has been neutralised no more acid is added. a What colour does Universal Indicator change to to show neutralisation has taken place? b Write a word equation for this neutralisation reaction. c How could crystals of the salt from this reaction be obtained from the neutral solution? 2 C D Lees, 2002, The Heinemann Science Scheme (1 mark) (2 marks) (2 marks) End of unit test Reactions of metals and metal compounds Unit E Tier 5±8 1 A piece of zinc is added to some dilute sulphuric acid in a test tube. A chemical reaction takes place. a i Describe two observations that show a chemical reaction is taking place. (2 marks) ii Name the salt made in this reaction. (1 mark) b A piece of magnesium is added to some more dilute sulphuric acid in another test tube. The metal reacts with the acid. Describe one way in which this reaction is similar to that of zinc and dilute sulphuric acid. (1 mark) c Zinc oxide reacts with sulphuric acid as shown in the word equation below. zinc oxide 1 sulphuric acid zinc sulphate 1 water Using this information, copy and complete the general equation below to show how metal oxides react with acids. metal oxide 1 (2 marks) 1 water 2 10 cm3 of a dilute solution of potassium hydroxide are placed in a beaker. Dilute nitric acid is then added a few drops at a time and the solution tested with Universal Indicator paper after each addition. When the alkali has been neutralised no more acid is added. a What colour does Universal Indicator change to to show neutralisation has taken place? b Write a word equation for this neutralisation reaction. (1 mark) (2 marks) 3 Jo wants to make some copper sulphate. She reacts copper carbonate with dilute sulphuric acid to make the salt. a Copy and complete this word equation for the reaction. copper carbonate 1 sulphuric acid (2 marks) copper sulphate 1 1 b How could Jo make sure that all of the sulphuric acid is used up during the reaction to leave a clear, neutral solution? (2 marks) Continued 3 C D Lees, 2002, The Heinemann Science Scheme End of unit test Reactions of metals and metal compounds continued Unit E Tier 5±8 4 a The table shows some substances that are reacted together, and the products from these reactions. Write answers for A, B and C to complete this table. (3 marks) Substances reacted together Products of the reaction tin nitric acid A hydrogen lead oxide hydrochloric acid B water C sulphuric acid calcium sulphate water b Copy and complete this symbol equation for the reaction between tin and nitric acid. Sn 1 (2 marks) Sn(NO3)2 1 c This word equation shows the reaction between magnesium hydroxide Mg(OH)2 and hydrochloric acid. magnesium hydroxide 1 hydrochloric acid Write a symbol equation for the reaction. 4 C D Lees, 2002, The Heinemann Science Scheme magnesium chloride 1 water (2 marks) Mark scheme Reactions of metals and metal compounds Question Part Answer Mark Level A and D 1, 1 3 a Bubble the gas through limewater The limewater goes milky or cloudy or forms a white precipitate 1 1 4 4 b Hold a lighted splint to the mouth of a test tube of the gas You will hear a squeaky pop when the gas ignites 1 4 1 4 Copper carbonate 1 hydrochloric acid copper chloride 1 carbon dioxide 1 water (L4 mark for chloride in correct space, L5 mark for carbon dioxide in correct space) 1 4 1 5 Bubbles are seen Heat is given out Zinc sulphate Hydrogen 1 1 1 1 5 5 6 5 b One from: Bubbles are seen Heat is given out Hydrogen is produced A salt or a sulphate is produced 1 5 ci Metal oxide 1 acid salt 1 water (one mark for salt in correct space) iron sulphate 1 6 1 5 a Colour changes to yellow/green 1 5 b Potassium hydroxide 1 nitric acid potassium nitrate 1 water (one mark for each product) 2 6 c Evaporate (most of) the water Leave the (saturated) solution to cool 1 1 5 6 1 2 3 3 ai ii iii ii 4 Unit E Tier 3±6 Scores in the range of: Level x±x x±x x±x x±x 1 C D Lees, 2002, The Heinemann Science Scheme Mark scheme Reactions of metals and metal compounds Question Part Answer Mark Level 1 ai Bubbles are seen Heat is given out Zinc sulphate 1 1 1 5 5 6 b One from: Bubbles are seen Heat is given out Hydrogen is produced A salt or a sulphate is produced 1 5 c Metal oxide 1 acid salt 1 water (one mark for acid in correct space, one mark for salt in correct space) 1 5 a Colour changes to yellow/green 1 6 b Potassium hydroxide 1 nitric acid potassium nitrate 1 water (one mark for each product) 2 6 a Copper carbonate 1 sulphuric acid copper sulphate 1 water 1 carbon dioxide (one mark for water, one mark for carbon dioxide in any order as products) 2 6 b Add excess copper carbonate or add copper carbonate until some is left unreacted Filter off the excess solid Accept for two marks: Keep adding copper carbonate until the mixture is neutral when tested with Universal Indicator paper 1 7 1 7 a A Tin nitrate B Lead chloride C Calcium hydroxide 1 1 1 6 6 7 b Sn 1 2HNO3 Sn(NO3)2 1 H2 (one mark for each formulae, one mark for balancing) 2 7 c Mg(OH)2 1 2HCl MgCl2 1 2H2O (one mark for formulae, one mark for balancing) 2 8 ii 2 3 4 Scores in the range of: Level x±x x±x x±x x±x 2 C Unit E Tier 5±8 D Lees, 2002, The Heinemann Science Scheme Student record sheet Reactions of metals and metal compounds Unit E I can do this quite well I can do this very well I need to do more work on this I know some uses for metals and non-metals I know that metals are good conductors of heat and electricity I know that non-metals are poor conductors of heat and electricity I know the things that show a chemical reaction has taken place I know that a new substance is made when a chemical reaction takes place I know that hydrogen is produced when many metals react with acids I know that carbon dioxide is produced when acids react with metal carbonates I can describe tests for hydrogen and carbon dioxide I can describe how metals react with acids I can describe how acids react with metal carbonates, metal oxides and alkalis I know how to extract a salt by filtering and evaporation I can represent reactions by word equations I can find patterns in reactions and write general word equations I can name a variety of salts I can describe the uses of some salts I can represent chemical compounds by formulae I can use formulae to write symbol equations I can use my knowledge of reactions to make predictions about other reactions What I enjoyed most in this unit was The most useful thing I have learned in this unit was I need to do more work on 1 C D Lees, 2002, The Heinemann Science Scheme
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