BEST Research Institute Dr Ed Loffill CIWEM/IEMA University Innovations event Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Overview • • • • • • LJMU-Generic Information BEST Microwave Assisted Chemistry Renewable Energy from Waste Microwave Renewable Energy Projects Sensing – Water/Wastewater – Healthcare/Food Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Liverpool John Moores University - a major civic university Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Some Facts about LJMU • Founded in 1825, LJMU has grown into one of the UK’s most dynamic and progressive universities. • The University is organised into 5 Faculties comprising 26 Academic Schools. • LJMU is the 15th largest university in the UK with over 24,000 students in Liverpool/internationally plus 2,500 staff. • LJMU has annual turnover of more than £110m per year. • External research funding, from sources such as our industrial partners, the Welcome Foundation and research councils, EU, Government fund and Industry, has increased by 86 per cent since 2011-12 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 BEST-Research Institute 68 PhD 14 Post Docs Since 2008-Present • 42 PhD completion • >$20M Research income generated • >500 publications • > 10 Patents http://www.ljmu.ac.uk/BLT/BEST/index.htm Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 BEST Research Landscape • applied research – closely linked to industrial requirements • highly theoretical blue-skies research • successful portfolio of KTP(Knowledge Transfer Partnerships). With key elements of • Excellence & Innovation • Niche and Uniqueness • Sustainability Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Research-Impact Social Economics Quality Of Life Public Policy services IMPACT Health Cultural Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Environment Riken, 15th May 2013 Research-Impact http://www.telegraph.co.uk/technology/news/ 10312326/UK-researchers-win-patent-forwearable-smart-sensors.html Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 BEST Research Profile RAE-2008 • 50% of our research activity was judged to be “World Leading” in terms or originality, significance and rigour (outputs, Environment, Impact). • This has placed us within the top 5 UK Universities. • The Time Higher Education Table of Excellence, in respect of the Post 1992 “New Universities” ranked Liverpool John Moores University 1st for Architecture and the Built Environment. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 RAE 2008 • Outcome Virtually all outputs were assessed as at least internationally recognised with nearly 70% in the 3* and 4* categories 50% of the submitted department showed evidence of good impact and recognition and the remainder was considered excellent or outstanding Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 R&D, Enterprise Funds • • • • • • • • EU Research Councils Technology Strategy Board (TSB) MoD Directly from Industry Royal Academy of Engineering Royal Society Carbon Trust Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 What we do… • • • • • • • • Microwave assisted chemistry Niche renewable energy systems Process optimisation “Traditional” research studies Radar and underwater radio communications Wireless sensor networks Sensor applications Bespoke research… wide staff expertise! Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwaves and Their Industrial Applications Professor Ahmed Al-Shamma’a Dr Alex Mason and Dr Olga Korostynska Riken, Japan 15 May 2013 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska th Riken, 15th May 2013 Electromagnetic Wave Spectrum • Non-ionising, Good penetration, Selectivity, Relatively inexpensive, Good versatility, Designs to suit application, Instantaneous measurements Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwaves - ra y s WG4 X - ra y s 896 MHz 124mm U ltra v oi el t V si bi el 248mm In fra re d M ci row a v e s 1 GHz to 300 GHz R a d oi 2 g g 1 co Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska c f WG9A 2.45 GHz 86mm 43mm Riken, 15th May 2013 Microwaves Basics Electric field Magnetic field TE10 Standing Waveform Electric Field Magnetic Field Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Cavity Resonators Modes Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 EM wave modes E010 H111 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska H011 Riken, 15th May 2013 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Dielectric Properties of Water Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwave chemistry H ig h in te n sity E -F ie ld M icro w a v e p ro p a g a tio n Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwave chemical reactors Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 2 2 2 2 3 3 3 3 2 2 2 2 Tube Inlet 3 3 3 3 Outlet Tube Fig 1: Schematic diagram of experimental Setup Copper Mesh 2 2 2 3 3 3 FigOlga 2: Image of the MW Mesh Cavity Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Korostynska PTFE coils Riken, 15th May 2013 Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwave cw chemical reactor Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Complete Multipurpose Microwave Biofuel System from Waste oil/fat, Biomass Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Biofuels: classification Biomass Direct Indirect Use by combustion Use requires processing first Wood, straw, rice husks Hydrolysis Anaerobic digestion -> methane Extraction -> oils and fats Modification , (chemical reaction) -> Biodiesel Extraction -> sugars SVO Modification (fermentation) -> Ethanol Butanol etc) Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Biomass Resource Pathways Feedstock Processing Hydrolysis Acids, enzymes Gasification Feedstock collection, handling, and preparation High heat, low oxygen Digestion Intermediates Outputs Sugars and Lignin Syngas Biobased chemicals Biogas Biobased materials Biocrude Liquid biofuels Carbon Rich Chains Electricity Bacteria Pyrolysis Catalysis, heat, pressure Extraction Mechanical, chemical Separation Heat Plant Products Mechanical, chemical Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Oils Used • Catering Waste Solutions: – Good Commercial Waste Oil – Good Domestic Waste Oil – Poor Overused Waste Oil • New Vegetable Oil Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Conventional vs. Microwave system Methanol Pump Mixer Oil + FFA Decanter Pump “Clean” Oil Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 The future; Technology overview • Physical – • optimise milling process • Chemical – • Microbial inert system • No or little inhibitor formation • New, developing and emerging technologies • Biological – • Development of fermentation methods and organisms Steam explosion Ammonia fibre explosion Liquid hot water Supercritical carbon dioxide Ozonolysis Microwave plasma Acid assisted steam explosion Alkali assisted steam explosion Hydrogen peroxide • Product recover – • Consolidate into upstream unit operation Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Delignification reactor control Microwave power Temperature (media bulk) 0 Reactor vessel pressure temperature&pressure pH Agitation Gas phase input Foam Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska FP7-SME-2008-1-232080 Riken, 15th May 2013 Novel Bio ethanol Production from Brownfield waste Microwave plasma frequency tuner (Frequency will be chosen in function of type of material, weight and temperature to achieve in terms of yield of sugars) Energy crops or/and Cellulose waste + Alkali for higher yield if necessary Multi sensors, real time interfacing and control the process Microwave plasma source Microwave plasma reactor On Line real time monitoring and control the process. After Treatment: Sugar solution for production of ethanol Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Process integration Raw materials Distillation 0 0 Enzymatic saccharification Fermentation 0 Pre-soak De-lignification and remediation Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Biomass Resource Pathways Feedstock Processing Hydrolysis Acids, enzymes Gasification Feedstock collection, handling, and preparation High heat, low oxygen Digestion Intermediates Outputs Sugars and Lignin Syngas Biobased chemicals Biogas Biobased materials Biocrude Liquid biofuels Carbon Rich Chains Electricity Bacteria Pyrolysis Catalysis, heat, pressure Extraction Mechanical, chemical Separation Heat Plant Products Mechanical, chemical Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwave Plasma Setup Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Syngas Analysis Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Novel Gasification Recycling of Waste into SynGas SynGas (CO, H2) Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwaves for sensing • • • • Non-ionising Good penetration Relatively inexpensive Good versatility – Designs to suit application • We have developed many different types of sensor to suit different usage. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Industrial opportunities Healthcare Food industry Wearable sensors APPLICATIONS Structural monitoring Biofuels Built environment Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Water industry Riken, 15th May 2013 Microwave sensors Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Measurement process Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Theory A change in sample εr results in shift of resonant frequency f nml c 2 r r 2 p nm l a d 2 Sample S11 (reflected power) Port 1 1 Port Input power Port 2 Pozar, D. M. 1998. Microwave Engineering 2nd Edition, John Wiley & Sons, ISBN 0471170968. S21 (transmitted power) Microwave Cavity Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Field interaction TM010 TM210 TM310 TM220 Increasing frequency Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Measurement process Sample (0.6 ml) in quartz NMR tube Port 2 (S21) Microwave cavity Port 1 (S11) Vector Network Analyser (VNA) Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Healthcare application Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Experimental setup Sample (0.6 ml) in quartz NMR tube Microwave cavity Vector Network Analyser (VNA) Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Microwave spectrum Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Spinal fluid analysis J. H. Goh, A. Mason, A. I. Al-Shamma’a, M. Field, and P. Browning, "Lactate Detection Using Microwave Spectroscopy for In-Situ Medical Applications," International Journal on Smart Sensing and Intelligent Systems, vol. 4, pp. 338-352, September 2011. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Cow blood Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Blood measurements Physiological Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Supraphysiological Riken, 15th May 2013 Novel sensors In-line measurement, no cavity and good sensitivity. A. Mason, A. Shaw, and A. Al-Shamma’a, "A Co-Planar Microwave Sensor for Biomedical Applications," Sensors and Actuators: A Physical, DOI: 10.1016/j.sna.2013.04.015, 2013. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Wearable sensors On-going work: Textile microwave sensors. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Development… Testing analyte in basic background media; prove principle. Testing analyte in blood and “insitu” pushing proof of principle further. Consideration of how to make “non-invasive” a reality. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Structural Monitoring Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Crack monitoring Holder Jaws VNA Aluminium test plate Sensor Wooden holder Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Corrosion monitoring Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Food quality Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Demonstration Transmitter Receiver Analyser Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Real-time Water Contamination Monitoring Dr Olga Korostynska EU Research Fellow [email protected] Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Need for real-time water quality monitoring Acid rain Industrial water pollution discharged into river Cows leeching phosphate into ground water Polluted water source Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Daiwa Anglo-Japanese Foundation Project: 9050/9942 Real-time monitoring of nuclear contamination of water through sensors fusion In collaboration with Associate Professor Satoshi Ikezawa (Waseda University) Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Need for real-time water quality monitoring Assessment: source waters, industrial waste and sewage treatment plants, storm waters and runoff from urban and agricultural lands. ~70,000 known and emerging chemicals present in water resources. Environmental water monitoring includes measurements of: physical characteristics (e.g. pH, temperature, conductivity) chemical parameters (e.g. oxygen, alkalinity, nitrogen and phosphorus compounds) assays of biological activity (alkaline phosphatase) tests for toxins (microcystins) direct measurements of pollutants (heavy metals or hydrocarbons). Real time detection by a continuous online water quality monitoring platform is essential for preserving potable water resources. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Phosphate and Nitrate The Nitrogen cycle in nature Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 UV-Vis Optical Methods Conceptual diagram of standard UV-Vis optical methods: a) Molybdenum blue method, b) Vanadate / molydate yellow method Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Potentiometric detection methods Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Fibre optic sensors Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 MEMs and Microelectrode arrays Micro-Electro Mechanical (MEMs) Microelectrode Array Sensors: the major advantages of these systems include the ability to penetrate samples to perform measurements, small tip size for in situ measurements, array structure for higher robustness, and possibility of multi-analyte detection. Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Biosensors Recording and Display Signal processing Amplifier Transducer Bioreceptor Impurities Target Analyte Schematic diagram of a biosensor Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Multi-sensor real-time water monitoring system Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Measuring water volume, in µl 0 -2 -4 10 20 30 40 50 60 70 80 90 100 S11, dBm -6 -8 -10 -12 -14 -16 -18 -20 1.50x109 1.75x109 2.00x109 2.25x109 2.50x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Measuring water volume, in µl 0 -2 -4 50 100 150 200 250 300 350 S11, dBm -6 -8 -10 -12 -14 -16 -18 2.00x109 2.25x109 2.50x109 2.75x109 3.00x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Novel Microwave sensors Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Comparing average values for pH 4, pH7 and pH10 in 10 MHz – 1.5 GHz region Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Detecting NaCl DIW NaCl_0.01M NaCl_0.1M 0 S11, dBm -10 -20 -30 -40 0.0 5.0x108 1.0x109 1.5x109 2.0x109 2.5x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Detecting NaCl Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Detecting MnCl 2 0 -2 -4 DIW MnCl_0.1M MnCl_1M -6 S11, dBm -8 -10 -12 -14 -16 -18 -20 -22 -24 0 1x109 2x109 3x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Detecting CuCl DIW CuCl_0.1M CuCl_1M 2 0 -2 -4 S11, dBm -6 -8 -10 -12 -14 -16 -18 -20 0.0 5.0x108 1.0x109 1.5x109 2.0x109 2.5x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Unique Signature Spectra for each composition and concentration Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Change in microwave spectra with COD concentration, in µl 0.0 COD_24.6 COD_26.1 COD_54.7 S11, dBm -0.5 -1.0 -1.5 -2.0 -2.5 1x109 2x109 3x109 4x109 5x109 6x109 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Change in microwave spectra with NO3 concentration, in µl 0 -5 S11, dBm -10 NO3_31.8 NO3_32.4 NO3_56.6 NO3_72.5 -15 -20 -25 -30 7.0x109 8.0x109 9.0x109 1.0x1010 1.1x1010 Frequency, Hz Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Concept of water source management based on real-time measurements of water parameters Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Co-planar sensor built into main water supply system for continuous water quality control and source management Main metal pipe water Test plastic pipe with water Co-planar sensor SMA connector N-type cable ZVA PC for sensor data processing and water management Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Handheld real-time water monitoring system water sample to be tested General concept of handheld real-time water monitoring system Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013 Conclusions • Microwave technique has a huge flexibility for application in many areas. • In terms of sensing, many advantages; – Inexpensive, good penetration depth, non-ionising, sensor structure flexible to suit application. • Only touched the surface of what is possible today however; – Chemical processing – Renewable energy Professor Ahmed Al-Shamma’a, Dr Alex Mason and Dr Olga Korostynska Riken, 15th May 2013
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