Safety Data Sheet according to Regulation (EC) No1907/2006
Page 1 of 13
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394
PART B 25G E-Z PAK
SDS No. : 234781
V004.4
Revision: 05.03.2014
printing date: 20.10.2014
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1. Product identifier
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART B 25G E-Z PAK
Contains:
3,6,9-Triazaundecamethylenediamine
Amines, polyethylenepoly3,6,9,12-tetraazatetradecamethylenediamine
Triethylenetetramine
1.2. Relevant identified uses of the substance or mixture and uses advised against
Intended use:
Part B of 2-Component Epoxy Adhesive.
1.3. Details of the supplier of the safety data sheet
Henkel Ireland
Operations and Research Limited
Tallaght Business Park
Dublin 24
Ireland
Phone:
Fax-no.:
+353 (14046444)
+353 (14519926)
[email protected]
1.4. Emergency telephone number
24 Hours Emergency Tel: +44 (0)1442 278497
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Classification (CLP):
Acute toxicity
H302 Harmful if swallowed.
Route of Exposure: Oral
Skin corrosion
H314 Causes severe skin burns and eye damage.
Skin sensitizer
H317 May cause an allergic skin reaction.
Chronic hazards to the aquatic environment
H411 Toxic to aquatic life with long lasting effects.
Category 4
Category 1B
Category 1
Category 2
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 2 of 13
Classification (DPD):
C - Corrosive
R34 Causes burns.
Xn - Harmful
R21/22 Harmful in contact with skin and if swallowed.
Sensitizing
R43 May cause sensitisation by skin contact.
Dangerous for the environment
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
2.2. Label elements
Label elements (CLP):
Hazard pictogram:
Signal word:
Danger
Hazard statement:
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H411 Toxic to aquatic life with long lasting effects.
Precautionary statement:
Prevention
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statement:
Response
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/ shower.
P333+P313 If skin irritation or rash occurs: Get medical advice/attention.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER or doctor.
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 3 of 13
Label elements (DPD):
C - Corrosive
N - Dangerous for the
environment
Risk phrases:
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases:
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
S57 Use appropriate container to avoid environmental contamination.
S60 This material and its container must be disposed of as hazardous waste.
Additional labeling:
For consumer use only: S2 Keep out of the reach of children.
S46 If swallowed, seek medical advice immediately and show this container or label.
Contains:
3,6,9-Triazaundecamethylenediamine,
Amines, polyethylenepoly-,
3,6,9,12-tetraazatetradecamethylenediamine,
Triethylenetetramine
2.3. Other hazards
None if used properly.
SECTION 3: Composition/information on ingredients
General chemical description:
Accelerator for epoxy systems
Base substances of preparation:
organic amine
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 4 of 13
Declaration of the ingredients according to CLP (EC) No 1272/2008:
Hazardous components
CAS-No.
3,6,9-Triazaundecamethylenediamine
112-57-2
EC Number
REACH-Reg No.
203-986-2
content
Classification
>= 25- < 50 %
Acute toxicity 4; Dermal
H312
Acute toxicity 4; Oral
H302
Skin sensitizer 1
H317
Chronic hazards to the aquatic environment 2
H411
Skin corrosion 1B
H314
Bis(aminopropyl)piperazine
7209-38-3
230-589-1
>= 25- < 50 %
Skin corrosion 1B
H314
Amines, polyethylenepoly68131-73-7
268-626-9
>= 5- < 10 %
Acute toxicity 4; Dermal
H312
Skin corrosion 1B
H314
Skin sensitizer 1
H317
Acute hazards to the aquatic environment 1
H400
Chronic hazards to the aquatic environment 1
H410
Acute toxicity 4; Oral
H302
3,6,9,12-tetraazatetradecamethylenediamine
4067-16-7
223-775-9
>= 5- < 10 %
Skin corrosion 1B
H314
Skin sensitizer 1
H317
Acute hazards to the aquatic environment 1
H400
Chronic hazards to the aquatic environment 1
H410
Triethylenetetramine
112-24-3
203-950-6
01-2119487919-13
>= 1- < 2,5 %
Acute toxicity 3; Dermal
H311
Skin corrosion 1B
H314
Skin sensitizer 1
H317
Chronic hazards to the aquatic environment 3
H412
For full text of the H - statements and other abbreviations see section 16 "Other information".
Substances without classification may have community workplace exposure limits available.
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 5 of 13
Declaration of ingredients according to DPD (EC) No 1999/45:
Hazardous components
CAS-No.
3,6,9-Triazaundecamethylenediamine
112-57-2
EC Number
REACH-Reg No.
203-986-2
content
Classification
>= 25 - < 50 %
Bis(aminopropyl)piperazine
7209-38-3
Amines, polyethylenepoly68131-73-7
230-589-1
>= 25 - < 50 %
Xn - Harmful; R21/22
R43
C - Corrosive; R34
N - Dangerous for the environment; R51/53
C - Corrosive; R34
268-626-9
>= 5 - < 10 %
3,6,9,12tetraazatetradecamethylenediamine
4067-16-7
Triethylenetetramine
112-24-3
223-775-9
>= 5 - < 10 %
203-950-6
01-2119487919-13
>= 1 - < 5 %
N - Dangerous for the environment; R50/53
Xn - Harmful; R21/22
R43
C - Corrosive; R34
C - Corrosive; R34
R43
N - Dangerous for the environment; R50/53
Xn - Harmful; R21
C - Corrosive; R34
R43
R52/53
For full text of the R-Phrases indicated by codes see section 16 'Other Information'.
Substances without classification may have community workplace exposure limits available.
SECTION 4: First aid measures
4.1. Description of first aid measures
Inhalation:
Move to fresh air, consult doctor if complaint persists.
Skin contact:
Rinse with running water and soap. Apply replenishing cream. Change all contaminated clothing. If necessary, see a
dermatologist.
Eye contact:
Wash with plenty of water immediately and continue for several minutes, holding eyelid open. Consult a doctor.
Ingestion:
Rinse out mouth, drink 1-2 glasses of water, do not induce vomiting.
Immediate medical treatment necessary.
4.2. Most important symptoms and effects, both acute and delayed
Causes burns.
SKIN: Rash, Urticaria.
INGESTION: Nausea, vomiting, diarrhoea, abdominal pain.
4.3. Indication of any immediate medical attention and special treatment needed
See section: Description of first aid measures
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
Foam, extinguishing powder, carbon dioxide.
Fine water spray
5.2. Special hazards arising from the substance or mixture
Danger of decomposition if exposed to heat.
See section 10.
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 6 of 13
5.3. Advice for firefighters
Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.
In case of fire, keep containers cool with water spray.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Avoid contact with skin and eyes.
Wear protective equipment.
Ensure adequate ventilation.
6.2. Environmental precautions
Do not let product enter drains.
6.3. Methods and material for containment and cleaning up
Remove mechanically.
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust).
Dispose of contaminated material as waste according to Section 13.
6.4. Reference to other sections
See advice in section 8
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Ensure good ventilation/suction at the workplace.
See advice in section 8
Do not spray against flames or glowing bodies. Keep away from sources of ignition - no smoking.
Hygiene measures:
Wash hands before work breaks and after finishing work.
Do not eat, drink or smoke while working.
Extractors are required on all machines used for thermal or for cutting and grinding processes.
7.2. Conditions for safe storage, including any incompatibilities
Store in sealed original container.
Store in a cool, dry place.
Ensure that storage and workrooms are adequately ventilated.
Must be stored in a room with spill collection facilities.
Keep away from heat and direct sunlight.
7.3. Specific end use(s)
Part B of 2-Component Epoxy Adhesive.
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Occupational Exposure Limits
Valid for
Great Britain
Ingredient
SILICA, AMORPHOUS, INHALABLE
DUST
112945-52-5
SILICA, AMORPHOUS, RESPIRABLE
DUST
112945-52-5
ppm
mg/m3
6
Type
Time Weighted Average
(TWA):
2,4
Time Weighted Average
(TWA):
Category
Remarks
EH40 WEL
EH40 WEL
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V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 7 of 13
Biological Exposure Indices:
None
8.2. Exposure controls:
Respiratory protection:
Suitable breathing mask when there is inadequate ventilation.
Suitable respiratory protection:
Filter type: A
Hand protection:
Chemical-resistant protective gloves (EN 374).
Suitable materials for short-term contact or splashes (recommended: at least protection index 2, corresponding to > 30
minutes permeation time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
Suitable materials for longer, direct contact (recommended: protection index 6, corresponding to > 480 minutes permeation
time as per EN 374):
nitrile rubber (NBR; >= 0.4 mm thickness)
This information is based on literature references and on information provided by glove manufacturers, or is derived by
analogy with similar substances. Please note that in practice the working life of chemical-resistant protective gloves may be
considerably shorter than the permeation time determined in accordance with EN 374 as a result of the many influencing
factors (e.g. temperature). If signs of wear and tear are noticed then the gloves should be replaced.
Eye protection:
Goggles which can be tightly sealed.
and/or
facial protection
Skin protection:
Wear protective equipment.
Protective clothing that covers arms and legs.
apron
Advices to personal protection equipment:
Wash off any dirt that gets onto the skin with lots of soap and water, skin care.
Do not breathe dust and vapors.
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance
paste
paste, solid
brown
Odor
of amine
Odour threshold
No data available / Not applicable
pH
(20 °C (68 °F); Solvent: Water)
Initial boiling point
(1.013 hPa)
Flash point
Decomposition temperature
Vapour pressure
Density
(20 °C (68 °F))
Bulk density
Viscosity
Viscosity (kinematic)
Explosive properties
Solubility (qualitative)
(20 °C (68 °F); Solvent: Water)
Solidification temperature
Melting point
>7
> 93 °C (> 199.4 °F)
> 93 °C (> 199.4 °F)
No data available / Not applicable
No data available / Not applicable
1,0 g/cm3
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
Soluble
No data available / Not applicable
No data available / Not applicable
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Flammability
Auto-ignition temperature
Explosive limits
Partition coefficient: n-octanol/water
Evaporation rate
Vapor density
Oxidising properties
Page 8 of 13
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
No data available / Not applicable
9.2. Other information
No data available / Not applicable
SECTION 10: Stability and reactivity
10.1. Reactivity
Reaction with strong oxidants.
Reacts with acids.
Will cause some corrosion to copper alloys and aluminum.
Reaction with some curing agents may produce an exothermic reaction which in large masses could cause runaway
polymerization.
10.2. Chemical stability
Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
See section reactivity
10.4. Conditions to avoid
Avoid mixing resin (Part A) and curing agent (Part B) unless you plan to use immediately.
Failure to observe these precautions may result in excessive heat build-up causing an exotherm.
Danger of decomposition if exposed to heat.
10.5. Incompatible materials
None if used properly.
10.6. Hazardous decomposition products
Hydrocarbons
At higher temperature ammonia or amine derivatives may be generated.
At higher temperature carbon oxides and nitrogen oxides may be generated.
May produce fumes when heated to decomposition. Fumes may contain carbon monoxide and other toxic fumes.
See section 5.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
General toxicological information:
The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant
available health/ecological information for the substances listed under Section 3 is provided in the following.
Oral toxicity:
Harmful if swallowed.
Dermal toxicity:
Harmful in contact with skin.
Skin irritation:
Causes burns.
Eye irritation:
Corrosive
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V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 9 of 13
Sensitizing:
May cause sensitization by skin contact.
Acute oral toxicity:
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
Triethylenetetramine
112-24-3
Value
type
LD50
Value
2.500 mg/kg
LD50
2.780 mg/kg
Route of
application
oral
Exposure
time
Species
Method
rat
rat
Acute inhalative toxicity:
Hazardous components
CAS-No.
Value
type
Value
Route of
application
Exposure
time
Species
Method
Value
type
LD50
Value
Route of
application
dermal
Exposure
time
Species
Method
Acute dermal toxicity:
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
850 mg/kg
rabbit
Skin corrosion/irritation:
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
Triethylenetetramine
112-24-3
Result
Exposure
time
Species
corrosive
rabbit
corrosive
rabbit
Method
Respiratory or skin sensitization:
Hazardous components
CAS-No.
3,6,9Triazaundecamethylenedi
amine
112-57-2
Triethylenetetramine
112-24-3
Result
Test type
Species
sensitising
Guinea pig guinea pig
maximisat
ion test
sensitising
Guinea pig guinea pig
maximisat
ion test
Method
Germ cell mutagenicity:
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
Result
positive
Type of study /
Route of
administration
bacterial reverse
mutation assay (e.g
Ames test)
Metabolic
activation /
Exposure time
with and without
Species
Method
SECTION 12: Ecological information
General ecological information:
The preparation is classified based on the conventional method outlined in Article 6(1)(a) of Directive 1999/45/EC. Relevant
available health/ecological information for the substances listed under Section 3 is provided in the following.
If used properly the product does not enter the drains.
In the cured state contribution of this product to Environmental Hazards is insignificant in comparison to articles in which it
is used.
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V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 10 of 13
12.1. Toxicity
Ecotoxicity:
Toxic to aquatic organisms
May cause long-term adverse effects in the aquatic environment.
Do not empty into drains / surface water / ground water.
Hazardous components
CAS-No.
Value
type
Value
Exposure
time
Species
Method
420 mg/l
Acute
Toxicity
Study
Fish
3,6,9Triazaundecamethylenediamin
e
112-57-2
3,6,9,12tetraazatetradecamethylenedia
mine
4067-16-7
LC50
96 h
Poecilia reticulata
OECD Guideline
203 (Fish, Acute
Toxicity Test)
LC50
> 100 mg/l
Fish
96 h
Brachydanio rerio (new name:
Danio rerio)
OECD Guideline
203 (Fish, Acute
Toxicity Test)
LC50
> 100 mg/l
Fish
96 h
Brachydanio rerio (new name:
Danio rerio)
LC50
570 mg/l
Fish
96 h
LC50
570 mg/l
Fish
96 h
Triethylenetetramine
112-24-3
EC50
31 mg/l
Daphnia
48 h
Triethylenetetramine
112-24-3
EC10
< 2,5 mg/l
Algae
72 h
EC50
20 mg/l
Algae
72 h
Triethylenetetramine
112-24-3
OECD Guideline
203 (Fish, Acute
Toxicity Test)
Poecilia reticulata
OECD Guideline
203 (Fish, Acute
Toxicity Test)
Poecilia reticulata
OECD Guideline
203 (Fish, Acute
Toxicity Test)
Daphnia magna
OECD Guideline
202 (Daphnia sp.
Acute
Immobilisation
Test)
Selenastrum capricornutum
OECD Guideline
(new name: Pseudokirchnerella 201 (Alga, Growth
subcapitata)
Inhibition Test)
Selenastrum capricornutum
OECD Guideline
(new name: Pseudokirchnerella 201 (Alga, Growth
subcapitata)
Inhibition Test)
12.2. Persistence and degradability
Persistence and Biodegradability:
The product is not biodegradable.
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
Result
Route of
application
aerobic
Degradability
Method
0%
OECD Guideline 301 D (Ready
Biodegradability: Closed Bottle
Test)
12.3. Bioaccumulative potential / 12.4. Mobility in soil
Mobility:
Cured adhesives are immobile.
Bioaccumulative potential:
No data available.
Hazardous components
LogKow Bioconcentration Exposure
CAS-No.
factor (BCF)
time
3,6,9,12-3,67
tetraazatetradecamethylenedia
mine
4067-16-7
Triethylenetetramine
-2,65
112-24-3
12.5. Results of PBT and vPvB assessment
Species
Temperature
Method
OECD Guideline 107
(Partition Coefficient (noctanol / water), Shake
Flask Method)
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Hazardous components
CAS-No.
Triethylenetetramine
112-24-3
Page 11 of 13
PBT/vPvB
Not fulfilling Persistent, Bioaccumulative and Toxic (PBT), very Persistent and very
Bioaccumulative (vPvB) criteria.
12.6. Other adverse effects
No data available.
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product disposal:
Special waste incineration with the approval of the responsible local authority.
Disposal of uncleaned packages:
Disposal must be made according to official regulations.
Use packages for recycling only when totally empty.
Packaging that cannot be cleaned are to be disposed of in the same manner as the product.
Waste code
08 04 09 waste adhesives and sealants containing organic solvents and other dangerous substances
The valid EWC waste code numbers are source-related. The manufacturer is therefore unable to specify EWC waste codes
for the articles or products used in the various sectors. The EWC codes listed are intended as a recommendation for users. We
will be happy to advise you.
MSDS-No.: 234781
V004.4
LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 12 of 13
SECTION 14: Transport information
14.1.
UN number
ADR
RID
ADNR
IMDG
IATA
14.2.
UN proper shipping name
ADR
RID
ADNR
IMDG
IATA
14.3.
Environmentally Hazardous
Environmentally Hazardous
Environmentally Hazardous
Environmentally Hazardous
not applicable
Special precautions for user
ADR
RID
ADNR
IMDG
IATA
14.7.
III
III
III
III
III
Environmental hazards
ADR
RID
ADNR
IMDG
IATA
14.6.
8
8
8
8
8
Packaging group
ADR
RID
ADNR
IMDG
IATA
14.5.
AMINES, SOLID, CORROSIVE, N.O.S. (Tetraethylene pentamine,Substituted
piperazine)
AMINES, SOLID, CORROSIVE, N.O.S. (Tetraethylene pentamine,Substituted
piperazine)
AMINES, SOLID, CORROSIVE, N.O.S. (Tetraethylene pentamine,Substituted
piperazine)
AMINES, SOLID, CORROSIVE, N.O.S. (Tetraethylene pentamine,Substituted
piperazine)
Amines, solid, corrosive, n.o.s. (Tetraethylene pentamine,Substituted piperazine)
Transport hazard class(es)
ADR
RID
ADNR
IMDG
IATA
14.4.
3259
3259
3259
3259
3259
not applicable
Tunnelcode: (E)
not applicable
not applicable
not applicable
not applicable
Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code
not applicable
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
VOC content
0%
MSDS-No.: 234781
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LOCTITE EA 9394 AERO PART B 25GR KIT known as EA 9394 PART
B 25G E-Z PAK
Page 13 of 13
(1999/13/EC)
15.2. Chemical safety assessment
A chemical safety assessment has not been carried out.
SECTION 16: Other information
The labelling of the product is indicated in Section 2. The full text
of all abbreviations indicated by codes in this safety data sheet are as follows:
R21 Harmful in contact with skin.
R21/22 Harmful in contact with skin and if swallowed.
R34 Causes burns.
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
H302 Harmful if swallowed.
H311 Toxic in contact with skin.
H312 Harmful in contact with skin.
H314 Causes severe skin burns and eye damage.
H317 May cause an allergic skin reaction.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H411 Toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
Further information:
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any
particular properties.