pointer Magazine specialising in metrology published by Measurepolis Development Ltd 01/2015 theme issue: water Mr. Jussi Mäkinen, CEO The Times They Are a-Changin... sang Bob Dylan in 1964 and this certainly has happened ever since! The change has been faster and faster every year, and nowadays it affects both our business and personal life. from Croatia, Hungary, Italy, Slovakia, Spain, Sweden and U.K. But getting funded by EU is not an easy task! At Measurepolis Development Plc, in our work concentrating on developing the measurement and monitoring technology and business areas, we have seen the change continuously. Looking at the bright side, the technological development offers us new opportunities to help our customers and partners gaining new market areas. On the other hand, we need to run faster to even keep ourselves a little bit ahead of the status quo. With globally growing need for energy, new ecological forms of energy production comprise not only sun and wind power, but also the bioeconomy. By further refining sustainable annual forest growth in our region, to produce for instance biofuel, it would be possible to increase our countrys energy self-sufficiency and reach several EU environmental targets more easily than before. The recent financial crisis has shaken our businesses as well as the global economy, too. This has forced us to set our focus more clearly on the international cooperation, according to the company strategy set by the Board of Directors. One successful example in this respect is ITEA 2 project Water-M, where our role is to act as the Country Coordinator of Finland. Our partners are from Finland, France, Turkey and Romania. Mrs. Outi Laatikainen describes this project better in her article in page 6-7. Through our several trips to Brussels we have widened our international network of both research institutes and companies working in the same fields of interest. We have been preparing quite many project applications, mainly for Horizon 2020, the biggest EU Research and Innovation programme ever. Among others, we have been working together with partners MEASUREPOLIS DEVELOPMENT LTD CEO Jussi Mäkinen gsm +358 400 995 466 [email protected] ---------------------------------------------------------------------------VP Outi Laatikainen gsm +358 44 7101 662 [email protected] ---------------------------------------------------------------------------CTO Jouni Tornberg gsm +358 40 5550 756 [email protected] ---------------------------------------------------------------------------communications manager Marko Lipponen gsm +358 44 7100 102 [email protected] ---------------------------------------------------------------------------- Wastewater sludge or sewage sludge has become an increasing challenge all over the world. Even though the technology for producing energy and fertilizers from sludge is well known today, making this profitable business needs new innovations, and we are willing and capable to cooperate in developing those ones. With our domestic and international partners we are for instance aiming at combining municipal, agricultural and industrial waste and turning them into new, environmentally friendly products, and thus also promoting the Finnish companies success worldwide. These sustainable products will provide environmental, social and economic benefits while protecting and over their whole life cycle, from the extraction of until the final disposal. Because the environmental monitoring has a growing demand, this offers us new needs for RDI projects and potential for business applications. Kehräämöntie 7 | 87400 Kajaani | Suomi, Finland www.measurepolis.fi | [email protected] secretary Irma Oikarinen gsm +358 44 7500 778 [email protected] ---------------------------------------------------------------------------technology expert Merja Rautiainen gsm +358 40 8333 783 [email protected] ---------------------------------------------------------------------------technology expert Petri Österberg gsm +358 44 7500 779 [email protected] ---------------------------------------------------------------------------- WssTP working group on Emerging Compounds works on European agenda 4-5 WATER-M Paving the way for unified intelligent water management 6-7 Water balance analysis reliability and the use of its results in mine water management 8-9 Online metal analyzer developed in CEMIS-OULU 10 Evolution energie 11 Qualitative and quantitative water management measurement data on the map quickly for more effective use 12-13 On-line measurement with laboratory accuracy 14-15 Wastewater sludge analysis with an on-line optical monitoring device (MOFI) 16-18 Solution to remove soluble metals from process waters and effluents 19 Finnish Water Forum - Your link to international projects and collaboration 20-21 Magazine specialising in metrology published by Measurepolis Development Ltd ISSN 1797-1578 Editor in chief & Layout: Marko Lipponen Translate: www.kainuunkielikeskus.fi Circulation: 1000 Print: Painotalo Seiska, Iisalmi since 2004 Marko Lipponen Measurepolis Development Oys POINTER magazine is a specialist publication that has appeared since 2004, its main target group being Measurepolis customers and stakeholders. POINTER is a specialist magazine that offers versatile, unbiased and up-to-date information about metrology nationally. POINTER has a significant role in Measurepolis communication in that it reveals wider customer bases. It not only enables us to provide our readers with a comprehensive, concrete selection of current issues in the field, but also the companys operations, expertise and solutions. More detailed information about our operation is also available from our website www.measurepolis.fi. Pointer wants to be part of change and as a result of a readers survey the magazine has gained new content, e.g. articles written by experts. These articles are supplied by companies and therefore real experts are responsible for their content. In this issue we will focus on smart water management and related measurements. WssTP working group on Emerging Compounds works on European agenda Emerging compounds comprise a wide range of new anthropogenic chemical substances in the aquatic environment, including pharmaceuticals, biocides, industrial products, micro plastics, nano-particles and ingredients of personal care products (PPCP). The number of substances is increasinges every day, emerging compounds are more often detected in the environment and may threaten water quality and living organisms. This leads to a public and scientific concern about the risks of these new chemicals entering the environment. There are 2 main approaches to address emerging pollutants in water: End-of-pipe approach in which substances that have entered the water cycle are removed with the help of different technological solutions. Upstream approach in which preventive measures are taken to avoid dangerous substances entering the water cycle. The upstream approach has been proven to be much more environmentally friendly and requiring lesser investment costs. There is strong need for science- based innovative technologies and strategies to tackle the problem of emerging compounds. Research and innovation is on-going, but fragmented: FP7 projects, the JPI-water water quality call on emerging compounds in 2013, and National 4 programs. Because of the public and scientific concern and the large number of fragmented activities, WssTP started a working group that tries to keep an overview of ongoing activities in Europe and extracts the new topics out of the large amount of information. The aims of the working group are: To exchange information between scientists, practitioners, policy makers, SMEs and industries and NGOs on scientific and technological developments in helping to tackle the challenges of emerging compounds To provide an comprehensive overview of past and on-going R&D activities in the area of emerging compounds and deduce knowledge gaps to be addressed by future activities on the European level To develop a research and innovation agenda and to provide input in national and European research and innovation programmes (including JPIwater, Horizon2020). To support upcoming policy and regulation efforts by the EU and/or Member States by underpinning the process with reliable scientific proof. To facilitate joint research and innovation activities through linking national projects and collaborating in international consortia. The WG on Emerging Compounds will focus its activities on emerging chemical substances in the urban water cycle, aquatic environment and ground water resources. Topics that will be addressed within the WG are: identification, emissions and monitoring of emerging compounds, methods for treatment and removal, fate and transport in the aquatic environment and urban water cycle, impacts on ecosystems and human health, modelling and information systems, policy strategies for control and mitigation, social aspects related to PPCPs. The WG will identify the knowledge gaps for the different topics, discuss the level of priority with stakeholders and will formulate recommendations for future research. The WG will facilitate collaborative research between the WG partners: through existing national research projects: submitting proposals for COST Actions on specific topics (funding of meetings) within the framework of JPI-water: submitting proposals for specific calls on emerging compounds (national funding), led by the WG members that can receive funding within the framework of research and innovation via HORIZON2020 work programmes: submitting proposals for specific calls on emerging compounds (EU funding) Next activity of the working group is to present an update of current activities on emerging compounds in European countries. Furthermore, the WG aims to organise workshops twice a year on specific topics. WssTP is the European Technology Platform for Water and currently counts 130 members. WssTP is unique at the European level as it membership represents the full diversity of the water value chain including industry, research, utilities, technology providers, and water users. WssTP also closely collaborates with European Technology Platforms for other industrial sectors as water is an important component of the production value chains in a number of waterdependent industries (such as textile, chemical, food production, mining, etc). Through its Member States Mirror Group and its collaboration with the European Regions Research and Innovation Network (ERRIN) WssTP also reaches out to national and regional authorities. WssTP represents a key mechanism to increase coordination and collaboration on research, technology development and innovation with regard to water, increase the competitiveness of the European in the water sectors and allied fields, and contribute to solving Europes water-related societal challenges. The WssTP WG structure is essential to the WssTP strategy and for achieving its objectives. And last but not least, the WG contributes to the WssTP vision on the European water sector and gives input to the European research agenda. For more information on the WG Emerging compounds, please contact: Leonard Osté ([email protected]). For more information about WssTP, please contact: Durk Krol ([email protected]) 5 WATER-M Paving the Way for Unified Intelligent Water Management Water is a finite resource that should be carefully managed. However, more than 50% of the world population is living on areas with a water sustainability problem. Europe, despite of relatively sufficient water resources, is facing challenges with water safety and contamination issues and supply operation system efficiency. The Water-M project is geared to enable the creation of new products and services to build a unified water business model . The core of the project includes subjects like providing early warning tools, novel monitoring solutions, real time acquisition and processing platforms and new services for both water suppliers and water consumers. Water-M project deals with interoperability issues, real-time, big data and heterogeneous data challenges and aimes to find solutions towards a Unified Smart Water Network. One of the main objectives of the project is defining a unified smart operation for water supply. This is achieved via development and demonstration actions in collaboration of several water supply stakeholders; water utilities, research institutes, technology solution providers and responsible authorities. The solutions, which are not nowadays widely used in enhancing water safety and supply efficiency, include adding distributed intelligence via real-time platforms, XTPP and large storage and data processing technologies. The provision and validation of novel monitoring and sensing solutions for detecting possible harmful compounds and residues form a remarkable part in enhancing water safety and quality. Providing new added value services and information for smart water networks to both suppliers and customers pave the way for new business and operation model. This allows citizens and different kind of interest groups to understand and participate on enhancing a highquality water supply system. The Business Value of the project is based on following topics: 1) Implementing a smart monitoring and early warning tools for failure detection, diagnosis, water outages and harmful compound detection. 2) Providing a unified Water Information Model for exploiting data from the water grids and support decision making to increase reliability of operations. 3) Achieving high levels of water supply efficiency employing more efficient leak detection and network monitoring The Water-M project is carried out as a part of European ITEA2-programme and EUREKA! cluster. It includes industry-leaded consortiums from Finland, France, Turkey and Romania and is carried out by selections of companies, research institutes and a governmental authority. The project is running until DEC 2016. Outi Laatikainen, Measurepolis Development Ltd: I find the availability of safe and high-qualified fresh water as a very remarkable benefit and possibility for European Well-being in Future. We have wonderful excellence to develop the European way to ensure and enhance water supply system further to a totally new level. The awareness for possibility of harmful compound contamination has been rising as a remarkable issue in EU agenda - and active citizens have been adapting the crowdsourcing idea and want to participate in ensuring their water quality. Its great to be at the frontline of a renewing European excellence area with such and interesting expert group! Jérôme Meloni: Nowadays it appears as an evidence that fresh water is becoming a scarce resource and so more and more precious one. This project is the opportunity to use new technologies allowing better water management policies in the way to avoid waste and water stress problems. Beyond economic benefits considered by targeted results, the environmental aspect is really important for us and this project can help us to take care about fresh water for a sustainable future. 6 Water-M consortium was presenting the idea for novel water management systems at ITEA & ARTEMIS Co-Summit 2015 (Outi Laatikainen, Serge Deydestere, Jerome Meloni & Golnaz Garbashi) Unified Intelligent Water Management Project summary Water is a finite resource that should be carefully managed. However, more than 50% of the world population is living on areas with a water sustainability problem. The Water-M project is geared to enable the creation of new products and services to build a unified water business model with the core of early warning tools, real time acquisition and processing platforms and services for water suppliers and water consumers. Water-M project deals with the interoperability, real-time, big data and heterogeneous data challenges to find solutions towards a Smart Water Network. Objectives - Defining a unified smart operation for water supply - Distributed intelligence via real-time platforms, XTPP and large storage and processing technologies - Providing new added value services and information for smart water networks to both suppliers and customers Unique selling Points / Business value - Implementing a smart monitoring and early warning tools for failure detection, diagnosis and water outages - Providing a unified Water Information Model for exploiting data from the water grids and support decision making to increase reliability operation - - Achieving high levels of water efficiency and the reduction of water consumption Results - A robust secured distributed data platform supporting realtime data acquisition and control mechanisms - A unified Water information model for exploiting data from the water grids to increase reliability operation - Proposing and implementing an open standard architecture based on the most advanced and flexible IT architectures - A framework to support the intelligent management of smart water networks itea3.org/project/water-m.html 7 analysis reliability Wandaterthebalance use of its results in mine water management Mine water management is the storage, transfer and processing of water of various qualities within the boundaries of the mining area so that it does not cause problems in production and beyond the mining area. By reliably calculating the water balance, it is possible to get process technology and recycling solutions right and to calculate waste water amounts. Mine water balance analysis requires raw data not only on ore body, prevailing weather conditions, and the ore extraction and recovery process but also on gangue and by-product storage. For example, at the start of a project there are typically several ore treatment alternatives to choose from and the method of storing by-products is not finalised, causing a uncertainty in the raw data used for analysis at this stage. It is possible to predict weather conditions to a fairly high degree of accuracy by considering different scenarios the water balance for both exceptionally wet years and annual average rainfall can be calculated. Statistics provide reliable data on the melting period and autumn flooding, for which mines can prepare. For example, it is possible to prepare M 8 8 Annika Hämäläinen | Managing Director | Teollisuustaito Oy for a high or low water balance by building adjacent water pipelines and treatment plants or by using buffer pools. The obligations set out in environmental permits should also take seasonal variation into account. On the other hand, there is no easy or cheap way of measuring ground water flow rates in mining at least not before the mine is in operation. Even after mining has begun, it can be difficult to determine how much rain water, runoff or ground water is present even though the total volume of pumped off water can be measured. Ore body mineralogy, the structure of the ore deposit and the gangue/ore ratio all affect the volumes and composition of waters present in the mine. Although the mineralogy of valuable minerals is often known, it is possible that acidifying and even neutralising minerals are analysed less thoroughly during feasibility studies. An understanding of the ore extraction and recovery process and ore body chemical reactions and phenomena are crucial to process mass and water balance. Data for the ore treatment plant can be acquired using pilot runs, for example. Before mining begins, solubility testing can be used to estimate the solution rate of minerals. Nevertheless, estimates based on test results always include some degree of uncertainty. This is due to complex composition, the effect of chemicals and extremely slow rates of reaction, among other reasons. Although water and particularly mass balance analysis requires extensive and high-quality raw data, in most cases it is possible to plan mine water management so that unwelcome surprises can be avoided. In addition to the design of the system and the quality of raw data, good planning procedures should also be followed to guarantee the operational reliability of the process. It is also important to allow for updating and adjusting the water balance model and altering water management systems, when further data is available after mining has begun. Mine water management planning tools and methods Mine water management is the storage, transfer and processing of water of various qualities within the mining area so that it does not cause problems in production and beyond the mining area. It requires reliable planning in many technical sectors, of which process design produces the raw data for many other types planning as a basis for environmental impact assessment and cost analysis. The most important tool in water management process design is water balance analysis. Water balance is the volume of water that enters and exits a given area. In order to plan a mine water management system, knowledge of the internal connections, flow rates and water qualities of the various parts of the water balance area is needed to extend the analysis to include other elements. Mass balance analysis is also linked to the ore extraction and recovery process. Combining water and mass balance in one model is a good solution from a water management perspective because the concentrations and amounts of components, such as chemicals, from the process that affect water composition, can be analysed as part of the water balance. Finlands natural waterways make the water balance positive more water flows in unless directed into nearby waterways or used in the process. For this reason, it is crucial to know the energy balance of the process, its water-consuming reactions and water adsorbing materials when determining water flow volume in the mining area. In addition to weather, surface and ground water conditions, mine location data also includes ore body properties. Mining waters contain sulphide minerals causing acidification and also neutralising minerals, which have a considerable impact on water quality. The proportion of gangue also affects the water balance. For example, the size of the waste rock dumping area affects the amount of rainwater to be purified. Therefore, mine water management process planning requires comprehensive raw data concerning the deposit, the areas water and weather conditions as well as the ore extraction and recovery process. A part of this data is based on actual measurements and the remaining data must be estimated using, for example, statistics. However, a degree of accuracy and reliability is always associated with measurements. Additionally, pilot runs can be used when planning the ore treatment process. The quality of the raw data is a core issue in mine water balance modelling since it determines how reliably the development of water flow volumes and quality can be estimated. Since water balance analysis results are used for device, pipeline, instrument and storage pool sizing, the impact of the quality of the raw planning data extends well into the operational stage of the plant. It is typical of the initial stages of planning that scenario analysis or so called sensitivity analyses are used to determine the impact of changes in the numerical value of various factors on the end result. The raw data of factors with greater impact can then be adjusted further and confidence coefficients can also be used for support. Analyses and plans are often adjusted after the plant is up and running. In this case actual numerical values can be used to verify assumptions made during the planning stage. As is generally the case in mining, the geographical location of the plant, amongst other factors, affects water management. Conditions in Finland and teollisuustaito.fi 9 Introduction There is clear need for continuous on-line monitoring of trace metal concentrations in water streams of industrial activities. Currently available automated trace metal analyzers are not suitable for field use due to large size and high power consumption of the instrumentation, while the portable analysis kits require manual procedures by skilled technicians. Furthermore, most electrochemical measurement techniques currently used involve highly toxic elemental mercury in the measurement process, which is unacceptable especially in environmental applications. The market potential for monitoring trace metals has been predicted to increase strongly in the future on global scale. Dr. Jarkko Räty & project researcher Mika Mahosenaho, Cemis-Oulu metal analyzer O nlinedeveloped in CEMIS-Oulu Mika Mahosenaho | Cemis-Oulu University of Oulu, measurement technology unit CEMIS-Oulu in Kajaani has carried out a lot of research in development of electrochemical measurement of heavy metals in water solutions during recent years. The measurement system developed in Tekes-funded MEAN project is based on a sophisticated electrochemical detection method, where the use of mercury is avoided. A fully integrated measurement system consists of all the components needed for sampling, sample pre-treatment, analysis, data processing and transfer. The instrument can be operated and controlled remotely via network connection, requiring only little amount of maintenance procedures. An automated measurement instrument is designed to operate with low running and maintenance costs. Continuous monitoring of trace metal levels remotely on-site enables fast reaction to possible hazardous incidents like leakages or process failures, unlike the traditional method involving manual sample collecting and transportation followed by laboratory-based offline analysis. Moreover, compared to less-frequent offline analysis, the developed online monitoring system provides more accurate evaluation of longterm environmental impact. Measurement principle The metal analysis method is based on a voltammetric technique, in which electrochemically active metal ions present in the sample are reduced on the working electrode, and then oxidised during anodic potential scanning step. Each metal is determined according to the intensity of electric current at its specific oxidation peak potential. At present, measurement 10 10 of selected metals (e.g. copper, lead, zinc and mercury) has been optimized and after further studies more metals important for industrial sector will be added to the list of possible analytes. Variety of the analytes can be extended within certain limits by adjusting properties of the electrochemical cell by using different working electrode materials and/or changing electrolyte composition. When interpreting the measurement results it should be noted that this measurement technique can detect only the electrolabile fraction, not the total concentration of the metal. However, the ratio between the measured and total concentration in a water system is usually stable enough to be used as a base for total emission calculations. Towards commercialization Extensive field tests with the device are now running to evaluate the reliability of the field compatibility and maintenance interval of the device in the demanding year-round weather conditions. The results obtained with the online analyzer are being compared to laboratory-based analysis of the reference sample collected at the same time. A market study has been performed to recognize potential customers in industrial sector and to identify their individual needs related to metal monitoring. According to the results obtained from this study, different business models have been evaluated. Ultimate aim is to create business value in a form or other, like spin-off company established by CEMISOulu personnel. Stephanie Grehl | Evolution Energie evolution Only 2.5% of the worlds water supply is fresh water. This makes it an invaluable resource for the next generations. The European project WATER-M is geared to enable the creation of new products and services to build a unified water business model that will benefit European water stakeholders. As a member of the WATER-M Project, Evolution Energie focuses on finding solutions that will be an enabler for the operation and control of smart water grids, supported by data exploitation mechanism and management subsystems. Evolution Energie is a French software company that created an exhaustive software solution for energy data integration and processing across Europe and worldwide. Currently, Evolution Energie software solution covers over 6% of the EUs energy consumption, based on data integration and processing of resources such as Natural Gas, Power, Industrial Gases and Water for major industries. With the use of this complete software solution, clients can save up to 20% of their energy consumption and increase the efficiency and transparency of their resource usage. Resource management, especially for Energy production and consumption is becoming more and more important ecologically and politically across the world. With most resources such as oil, gas, coal or water being non-renewable or finite, efficient usage of resources is vital to respond to the demands of increasing population numbers. The worlds fresh water supply, used as a basic consumption and energy generating resource, is becoming increasingly scarce in regards to continuously rising population demands and has to be managed carefully. In this light, efficient usage of water resources is imperative energie and to achieve this aim a comprehensive water management system is needed. In response to this, the WATER-M is aiming to enable the creation of new products and services to build a unified water management model that will benefit water stakeholders across the European Union. To manage resources successfully, the full resource usage cycle has to be monitored. In regards to water usage management this starts at the origin of the water and ends when the water is returned to the environment after being used. This requires new technologies to accurately measure water production, treatment, transportation and consumption in realtime followed by digital integration and processing of the acquired data to continuously increase efficient use of the full water cycle. Evolution Energie concept is based on extensive background knowledge and research of the commodity industry and state of the art technology. It offers a wide range of research capabilities and industrial experience, with particular expertise in big data management and analytics, metering data collection, modeling, software development and data-visualization. Using know-how of several IT fields Evolution Energie establishes metering data gateways, creates market evaluation models and incorporates compatibilities with SAP + Microsoft technologies. Evolution Energie will apply these skills to the WaterM project to facilitate the creation of a complete smart water management system. Ultimately, this will be a leading step forward to increase usage efficiency and save limited fresh water resources. evolutionenergie.com 11 Network location information Measurement technology data collection Open interfaces Network modelling Data extraction, analysis ualitative and quantitative Qwater management measurement data on the map quickly for more effective use The international Water-M initiative is aiming to make an impact: not only by combining distance water consumption and pressure measurements and information, it intends to stimulate a revolutionary change in operational models by combining different forms of data via open interfaces enabling safer and more predictable water management. Water-M is an international research and development initiative consisting of cooperation projects based in Finland, France, Turkey and Romania. The members of the Finnish consortium are Econet Oy, Keypro Oy, remoteMX Oy, Measurepolis Oy and EHPTekniikka Oy. Measurepolis is the acting Coordinator for Finland. In addition to the aforementioned companies, the initiative includes Finlands leading research institutes in the field of water management: Savonia University of Applied Sciences provides expertise in network modelling while the National Institute for Health and Welfare (THL), in studying risks and health related factors. However, Oulu University will provide the largest contribution to research with six different department´s representing expertise in quantitative and qualitative measurement 12 methods, water management process and risk modelling, algorithm development and wireless data transfer and security. What then, is the initiative all about? In brief, primarily smart water management technology ideas will be developed to resemble saleable products and, on a secondary level, the initiative will enable practitioners to create new networks in Finland and in international markets. The objective is to increase the competitiveness of European water management technology. One of the core ideas supporting the whole purpose of the initiative is the use of open standards and interfaces, as set out in figure above. Moreover, these open interfaces will support companies specialising in various areas of smart water management as effectively as possible. Lets take a practical example: A company focusing on the online or real-time measurement of a specific bacterium does not need to know anything about a specific networks place data solution or about a specific data extraction solution to be of benefit, but the innovative measurement data produced by the company in question will travel smoothly from one subsystem to another. This concept will open up the water technology sector to competition which will, in turn, speed up innovation: how small, specialised practitioners can be compatible with a smart water management solution if they all use the same shared interfaces. In terms of geographical and network data, WaterM will create long overdue transparency and competition. Web solutions based on open source code and open standards will play an increasingly important role in the near future. For instance, one such solution is Key Aqua, a network data solution developed by Keypro Oy, a member of Finlands consortium. In addition to geographical position and features data management, Key aqua offers a variety of features for using open measurement data and conducting map-based analyses as set out in the aims of the Water-M initiative. KeyAqua is also acknowledged for its SMS messaging features and a mobile user interface, making field work more productive. For example, leak and pressure measurements are transferred directly to the pipeline supervisors tablet device in the field and are displayed in the correct location on a real map. KeyAqua is already used for water management purposes by more than 60 network owners. In the Water-M initiative, Keypro Oy is cooperating with partners to make the current solution even more innovative. An example of this is a pilot scheme with the Kymen Vesi water company in which Keypro together with two other Finnish consortium members, Econet Oy and remoteMX Oy, are developing a unique cloud based measurement solution. The data produced by this pilot scheme will in turn be refined and studied by Oulu University. Interested water management practitioners, both public and private, please note that the business and research members of the Finnish consortium are still looking for interesting pilot schemes. Interested companies should contact Outi Laatikainen (Measurepolis Development Ltd), the coordinator of the Finnish consortium: www.measurepolis.fi www.keypro.fi 13 Fig 1. Inkeroinen Boards production capacity is 245 000 tons and the Anjala paper mill, 435,000 tons per year. They share a joint effluent treatment plant, seen to the right of the picture. n-line O measurement with laboratory accuracy The Anjalankoski Mill area is home to two of Stora Enso's production units, the Anjala Paper Mill, as well as the Inkeroinen Board Mill seen here in the background. Cooperative efforts between the mills cover raw materials, energy and power generation, as well as waste water treatment and resultant sludge drying and firing. The Anjala paper mill together with the wastewater treatment plant has a long history of equipment supplied by Valmet *) measuring sludge prior to drying and solids content of reject water. Earlier, the only possible reliable measurements were tedious laboratory tests unsuitable for real-time process control. Environmental values are the priority For all industrial production, protection of the environment currently functions as the guideline to operating conditions with compliance to permitted values. The pulp and paper industry is one of the most closely regulated and controlled industries in the world. The allowable limits generally require best available technology (BAT) for process measuring and control technology as well as for manufacturing processes. For water protection, effective waste water treatment and the recovery of harmful substances is of paramount importance. The large volumes of water (for Anjalankoski around 30,000 m3 per day), low solids content and contamination of measuring devices create special challenges for reliable realtime measurements. Traditionally, the only way to manage this process was by laboratory analysis which made rapid corrective control actions impossible. Valmet *) has developed a measurement technology to address these challenges. These measurements now provide real-time process values in the extreme conditions of the effluent treatment plant. Measuring solutions in Anjalas waste water treatment The specific need of the Anjalankoski mills was to get real-time information on flows from clarifiers 14 and to sludge dewatering, as well reject water solids content from the belt press filter. Valmet TS (Total Solids) *) transmitters have been measuring the dry matter content of clarifier sludge in Anjalankoski since 2010. The transmitter measures the time of flight of a microwave signal through the sludge. Time of flight is dependent on the permittivity of the slurry which for organic substances is practically constant, whereas the permittivity of water is considerably different. The measured change in permittivity allows an accurate calculation of the total solids content in the slurry. The measured slurry consistency varies normally from 2 to 3 per cent. The measuring device in the picture is installed on the sludge mixture to the belt filter press. Fig. 2 Fig. 3 The Valmet LS (Low Solids) *) - measuring system is designed to measure very low, 0 - 5000 mg/liter, solids content. The Anjalankoski system was installed in 2011 to measure the solids content of the reject water leaving the belt press filter, which had normally varied between 2000 to 5000 mg/liter. The device utilizes two light sources in a sample measurement cell where absorption, scattering and depolarization signals are measured.. The system also deaerates and filters the sample as well as self-cleaning the measurement optics at regular intervals. Fig.2 Simplified diagram of the sludge drying at the Anjala paper mill wastewater treatment plant. Fig.3 Comparison to laboratory results Anjalankoski mill experience Pertti Rongas, Department Manager, is particularly pleased with Valmet TS-measuring devices *) capability to provide accurate measurement data. "The results have been compared to laboratory tests and match them perfectly. The transmitters are reliable and do not require much maintenance. I wonder how, for example the primary clarifier could be run efficiently without such a measurement?" The improved measurements should make it possible to control the process automatically, but experienced operators are needed to follow the values in order to take appropriate action. If, for example, the sludge from the clarifier has a downward consistency trend, it could be the sign of a sludge dam forming at the bottom of the clarifier requiring sludge removal. The LS-system helps avoid excessive solids content in the belt press reject water which would normally circulate unnecessarily over and over again through the plant. The online measurement allows accurate monitoring and the current target is to keep the solids content to less than 350 mg/liter, whereas earlier it was much higher. Improved polymer dosage and plant operation The operators can now optimize the sludge intended for combustion by adjusting polymer addition and belt press speed. Polymer dosage depends on the amount of slurry mixture and solids volume. A higher relative proportion of primary sludge reduces the need for polymer. Sludge is removed from the press at about 30-35 per cent prior to thermal drying and firing. With reliable measurement technology, plant operation has improved even though dried sludge volume has increased by about 15 percent since 2011. Real-time measurement results have significantly improved both the polymer dosage control and plant operation. *) product and company names changed from Metso to Valmet. Valmet acquired Metsos Process Automation System business and products on April 1st 2015. 15 sludge analysis Wastewater with an on-line optical monitoring device (MOFI) a a ba b Terhi Suopajärvi , Elisa Koivuranta , Jani Tomperi Fibre and Particle Engineering, University of Oulu Control Engineering, University of Oulu The morphology analyzer MOFI has been developed in a MMEA - Measurement, Monitoring and Environmental Assessment Project, which is a SHOK program of Energy and Environment Cluster, CLEEN. (MOFI) is the on-line optical monitoring device, which has been used in the analysis of wastewater flocs morphology. MOFI has been used in the flocculation performances studies in the laboratory scale with different chemicals, wastewaters and sludges. With MOFI differences in floc morphologies with different chemicals have been compared and studied how different flocs are breaking during the pumping of the sample . MOFI consists of an imaging unit, a sample handling unit and a control PC and electronics unit (Fig. 1). The imaging unit is equipped with a CCD camera, LED light source and a cuvette. The cuvette is planar with the special design, which makes the flow of the sample laminar . The sample can be recirculated back to the sample handling unit, like in the case of floc strength tests or it can be led to disposal after imaging. MOFI has been placed in the wastewater treatment plant (Viikinmäki, Helsinki) as in situ sludge floc analyzer at the end of May 2013 (Fig. 1), and since then image analysis from the flocs of the biosludge has been done approximately four times per day. The CCD camera was changed to one with better resolution at February 2014, which has improved the results of image analysis by giving more accurate data of the morphology of the flocs. Fig. 1. Schematic illustration of floc measurement environment (MOFI) and MOFI at Viikinmäki waste water treatment plant. The automated image analysis program is used to calculate the different size and shape parameters; equivalent diameter, amount of filaments, roundness, aspect ratio and the amount of small particles (< 25µm), which are not settling down easily, in each image. One image contains about 150 particles and the amount of images per analysis is around 1000, which makes the amount of analyzed particles 16 approximately 150 000 per sampling . MOFI analyses have shown that mainly temperature of the wastewater effects in the growth of filaments and other morphological parameter (Fig. 2) and by that also to the purification results. Also sludge age and the amount of the sludge have effect on the growth of filaments. Fig. 2. The effect of temperature on the growth of filaments and on the equivalent diameter of flocs. It has been seen that extensive filaments growth affects the morphology of the flocs. High filament content decreases the roundness and the size of the flocs and increases the amount of small (<25 µm) particles. On that account, the amount of suspended solid and nutrients increases in the purified water by decreasing the purification result (Fig. 3). Fig. 3. The effect of floc morphology on the amount of suspended solids (SS) and nutrients on biologically treated wastewater. a) The content of filaments versus SS, b) the equivalent diameter of flocs versus biological oxygen demand (BOD), c) the roundness of flocs and d) the amount of small particles versus total phosphor content. Analyzing the floc data from a long period of time has offered an opportunity to follow different parameters and their effect on purification result in different situations and find correlations between floc parameters, online measurements and results from laboratory analysis. 17 Suspended solids content in biologically treated wastewater, which is one parameter to assess the treatment process efficiency, can be predicted with a simple model (Fig.4) developed using the on-line optical analysis parameters and process measurements from the early stage of the process . Since the optical monitoring is performed in the aeration tank, proactive information about the quality of effluent is received over ten hours in advance. Fig. 4. Modelled versus measured suspended solids content in biologically treated wastewater. MOFI is a useful analyzer device in the laboratory scale as well as an on-line analyzer in a plant scale. It gives accurate information about flocs morphology and current situation in a purification performance in the aeration tank. References Koivuranta E, Keskitalo J, Haapala A, Stoor T, Sarén M & Niinimäki J (2013): Optical monitoring of activated sludge flocs in bulking and non-bulking conditions. Environ Technol 34: 679686. Koivuranta E, Keskitalo J, Stoor T, Hattuniemi J, Sarén M & Niinimäki J (2014): A comparison between floc morphology and the effluent clarity at a full-scale activated sludge plant using optical monitoring. Environ Technol 16. Koivuranta E, Stoor T, Hattuniemi J & Niinimäki J (2015): On-line optical monitoring of activated sludge floc morphology. J Water Process Eng 5: 2834. Suopajärvi T, Koivuranta E, Liimatainen H & Niinimäki J (2014): Flocculation of municipal wastewaters with anionic nanocelluloses: Influence of nanocellulose characteristics on floc morphology and strength. J Environ Chem Eng 2: 20052012. Tomperi J, Koivuranta E, Kuokkanen A, Juuso E & Leiviskä K (2015): Real-time optical monitoring of wastewater treatment process. Environ Technol Submitted. 18 olution to remove soluble metals sfrom process waters and effluents Aquaminerals Finland Ltd is a privately owned Finnish company specializing in production of heavy metal and metalloid sorbents. Company is registered to Paltamo, close to a city of Kajaani in Finland. Products of Aquaminerals are used in waste water treatment, both in industrial and domestic facilities. The products are powerful in removing potentially toxic elements (e.g. heavy metals) from waste water. Activity of the company is based on scientific research carried out at the University of Oulu between 20052012. Patented products are derived from modified natural minerals. Products of Aquaminerals have proved to be both cost-efficient and high in performance in terms of adsorbing e.g. chrome, phosphorus, arsenic, uranium, nickel, copper, lead, zinc, manganese and cadmium. Their effect is based on simultaneous adsorption and neutralization. Adsorbents take the form of fine powder which can be tailored for specific aqueous environments. aquaminerals.fi Aquaminerals manufactures also modified mineral powder which can be used for intensification of settling and pH regulation (incl. detoxification). Main applications of Aquaminerals products include the following: o Treating waste water of flue gas scrubbers o Treating diluted effluent water of mining companies o Waste water treatment of a surface treatment or coating plants Besides, products can be used with mine drainage-, road bank-, as well as contaminated soil management. In connection to mineral deliveries portable dosing system is delivered. One unit can treat 50-300 m3 waste water per hour. Installation at the site takes only a few days. Partners wanted Aquaminerals is currently searching partners to execute pilot projects at overseas markets. Please do not hesitate to contact Marketing and Sales Director Mr. Tuomo Pikkarainen (+358 40 551 9994 or e-mail tuomo.pikkarainen(at)aquaminerals.fi). 19 Finnish Water Forum Your link to international projects and collaboration Katri Mehtonen, Markus Tuukkanen, Timo Koski, Aura Salmivaara As a joint network of private and public water sectors, Finnish Water Forum (FWF) serves as a platform through which enterprises, scientific institutions, government and nongovernment organizations can create partnerships and link their knowledge to find solutions for global water challenges. FWF was established in 2009 to promote Finnish water sectors knowhow in international forums and projects. With more than 100 member organizations, members range of skills covers sustainable solutions for a complete range of needs. Ministry of Economy and Employment is looking for growth sectors to be funded for joint business promotion actions. FWF together with its members and Finpro have made a proposal for a water sectors growth programme to support Finnish water sector companies growth internationally (http://www.finnishwaterforum.fi/binary/file/-/fid/1953/). The Finnish strongholds lie in: · · · · · Long traditions in Integrated Water Resources Management, transboundary water resources management and water governance give the Finnish knowhow solid foundation. Water issues together with Millennium Development Goals and water security are also high on Finlands development agenda. FWF leverages private and public sector co-operation in generation of new projects, which involves activities ranging from marketing and communication, development of business models and service concepts, mapping out concrete business export opportunities, and collaboration among other export promoters such as Finpro. Figure 1 describes the activities and role of FWF in more detail. The estimated value of global water market is 375 billion USD and currently Finnish water business activities reach 4 billion euros. Growing trends and opportunities can be found in blue bioeconomy, circulating economy and also in the fields of ecosystem services and smart water. · Water efficiency & Clean Tech Smart Water Arctic water knowhow Waste water and sludge treatment Industrial water and waste water treatment FWF with its members offer services to all water challenges individual and comprehensive solutions: Design, engineering, monitoring, measurement, equipment, chemicals, policy, governance, research, education FWF member benefits include: · · · · Links and match-making to partners, international opportunities and projects FWF to represent and market members in international events FWF to lobby member views, e.g. for instruments enhancing export activities Possibility to join various working groups chaired by member organizations for joint activities benefitting all participants Fig 1. The role of FWF in promoting the export of Finnish knowhow. BENCHMARKING FINNISH SMART WATER KNOWHOW Finnish Water Forum conducted an assessment of the current state of Smart Water in Finland and globally. Finnish companies in water sectors were interviewed and the Finnish knowhow in smart water technology was assessed and the export opportunities were mapped. This study and more recent experiences show that Finnish Smart Water knowledge is among the best in the world. Smart water technology is about utilizing and analyzing various data sources, which enhances making water treatment, distribution and use more efficient and automatic (Fig 2 & 3). The benefits of using ICT need to be clearly measurable and show economically sound influences. Globally main applications are optimization of water use in water scarce regions and identification and reduction of leakages in the water distribution network. Concepts of Smart City in city planning and Smart Grid in power distribution network share the visions and goals with Smart Water. The fast development and increased accessibility both technically and financially of ICT and measurement and modeling systems have enabled new possibilities to integrate data from different sources in such way that management systems can be developed and new systems can be built without big investments. The results of the FWF Smart Water assessment indicate that there is export potential in Finnish Smart Water knowhow. There are Finnish companies working on practically all Smart Water sectors though only few have yet become international. Some of the big global water sector companies have their Smart Water knowledge turned into products making it tougher for SME´s to thrive. Therefore co-operation with a larger company is practically a must for many of the companies for international success. Technology development especially in data transfer and measurement technologies may also quickly open new opportunities. The assessment is available here to FWF members send request to [email protected] CONTACT INFORMATION FOR FWF: Managing Director, Katri Mehtonen, tel. +358 40 5722 468 Deputy Managing Director, Markus Tuukkanen, tel. +358 40 865 3175 GOAL FOR SMART WATER NETWORK Fully integrated multi-sourced compilation of products, solutions and systems enabling automatic round-the-clock remote on-line monitoring, operation and problem preventative management (Andrew Burrows, SAWN 2013) Fig 2. Remote on-line monitoring & forecasting, (Figure by Kemira & Vaisala) Fig 3. Technology layers making systems smart (Figure by SWAN network) corporate cooperation bioenergy research wood innovation technology environment information technology consulting Research&Development mine management water marketing development programmes green energy communications business information system wireless www.measurepolis.fi ISSN 1797-1578 measurement vehicle
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