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PROF. GUIDO PAMPALONI
Elenco pubblicazioni dal 2007
F. Marchetti, F. Marchetti, B. Melai, G. Pampaloni , S. Zacchini, Synthesis and Reactivity of
Haloacetato Derivatives of Iron(II) Including the Crystal and the Molecular Structure of
[Fe(CF3COOH)2(-CF3COO)2] n, Inorg. Chem., 46, 3378 (2007).
U. Englert, G. Pampaloni, F. Puccini, M. Volpe, One-Electron Redox Reactions Involving
Chromium(0) and Molybdenum(0) Bis-1,3,5-Trimethylbenzene Derivatives, J. Organomet. Chem., 692,
3144 (2007).
A. Albinati, F. Calderazzo, F. Marchetti, S. A. Mason, B. Melai, G. Pampaloni, S. Rizzato, A trinuclear
trifluoroacetato anion of iron(II) containing a central O(–I) ligand, Inorg. Chem. Commun., 10, 902
(2007).
G. Pampaloni, R. Peloso, D. Belletti, C. Graiff and A. Tiripicchio, Trifluoromethyl-substituted
Bis(Pyrazolyl)Methanes as Ligands for Copper and Silver: Synthesis and Spectroscopic and Structural
Characterization, Organometallics, 26, 4278 (2007).
F. Marchetti, G. Pampaloni and S. Zacchini, Reactivity of Niobium(V) and Tantalum(V) Halides with
Carbonyl Compounds: Synthesis of Simple Coordination Adducts, C–H bond Activation, C=O
Protonation, and Halide Transfer, Dalton Trans., 4343 (2007).
F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Niobium and Tantalum Pentahalides with
Cyclic Ethers and the Isolation and the Characterization of Intermediates in the Polymerization of
Tetrahydrofuran, Inorg. Chem., 47, 365 (2008).
F. Marchetti, G. Pampaloni, S. Zacchini, Complexes of Niobium(V) and Tantalum(V) Halides with
Ligands containing N–C=O and P=O Functionalities: a Synthetic and Structural Study, Eur. J. Inorg.
Chem., 453 (2008).
F. Marchetti, G. Pampaloni, T. Repo, On the Polymerization of Tetrahydrofuran Initiated by
Niobium(V) and Tantalum(V) Halides, Eur. J. Inorg. Chem., 2107 (2008).
E. K. Brechin L. Calucci, U. Englert, L. Margheriti, G. Pampaloni, C. Pinzino, A. Prescimone, 1,10Phenanthroline-5,6-dione Complexes of Middle Transition Elements: Mono- and Dinuclear
Derivatives, Inorg. Chim. Acta, 361, 2375 (2008).
F. Marchetti, G. Pampaloni, S. Zacchini, The Chemistry of Niobium and Tantalum Halides, MX5, with
Haloacetic Acids and their Related Anhydrides. Anhydride C–H Bond Activation Promoted by MF5,
Polyhedron, 27, 1969 (2008).
D. Belli Dell’Amico, F. Calderazzo, G. Pampaloni, Heavier halides of transition metals by halide
exchange, Inorg. Chim. Acta, 361, 2997 (2008).
F. Marchetti, G. Pampaloni, S. Zacchini, From 1,2-Dialkoxyalkanes to 1,4-Dioxanes. A Transformation
Mediated by NbCl5 via Multiple C–O Bond Cleavage at Room Temperature, Chem. Commun, 3651
(2008).
F. Marchetti, G. Pampaloni and S. Zacchini, Unusual Room Temperature Activation of 1,2Dialkoxyalkanes by Niobium and Tantalum Pentachlorides: Multiple Cleavage of C–O bonds and
Formation of Oxychloride Complexes, Dalton Trans., 7026 (2008).
G. Pampaloni, Inorganic Synthesis in Inorganic and Bio-Inorganic Chemistry, V. Bertini Ed., in
Encyclopedia of Life Support Systems (EOLSS), Developed under the auspices of the UNESCO,
EOLSS Publishers, Oxford, UK, 2008. [http:www.eolss.net].
F. Marchetti, F. Marchetti, F. Masi, G. Pampaloni, V. Passarelli, A. Sommazzi, S. Spera, Synthesis,
variable temperature NMR investigations and solid state characterization of novel octafluorofluorene
compounds, J. Fluorine Chem., 130, 341 (2009).
F. Marchetti, G. Pampaloni, S. Zacchini, Epoxide Ring Opening and Insertion into the M–X Bond of
Niobium and Tantalum Pentahalides: Synthesis of Dihalide-tris(2-haloalcoholato) Complexes,
Polyhedron, 28, 1235 (2009).
G. Pampaloni, P. Zanello, Redox Chemistry and Electrochemistry of Metal Enolates in The Chemistry
of Metal Enolates, J. Zabicky, Ed., J. Wiley, Chichester, England, 2009, pp. 461-550.
F. Calderazzo, F. Masi, G. Pampaloni, Homonuclear and heteronuclear transition metal complexed by
syn-proportionation reactions, Inorg. Chim. Acta, 362, 4291 (2009).
F. Marchetti, G. Pampaloni, S. Zacchini, Fragmentations of Oxygen-containing Molecules via C–O
Bonds Cleavage Promoted by Coordination to Niobium and Tantalum Pentahalides, Dalton Trans.,
6759 (2009).
F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of 1,1-Dialkoxyalkanes with Niobium and
Tantalum Pentahalides. Formation of Coordination Compounds, C–H and C–C Bonds Activation and
the X-Ray Structure of the Stable Carboxonium Species [Me2C=CHC(=OMe)Me][NbCl5(OMe)],
Dalton Trans., 8096-8106 (2009).
A. M. Raspolli Galletti, G. Pampaloni, A. D’Alessio, Y. Patil, F. Renili, S. Giaiacopi, Novel highly
active niobium catalysts for ring opening metathesis polymerization of norbornene, Macromol. Rapid
Commun., 30, 1762-1768 (2009).
L. Calucci, C. Forte, G. Pampaloni, C. Pinzino, F. Renili, Chemical Implantation of Group 4 Cations
on Silica via Cyclopentadienyl- and N,N-Dialkylcarbamato Derivatives, Inorg. Chim. Acta, 363, 33
(2010).
F. Marchetti, G. Pampaloni, S. Zacchini, 19F NMR Spectroscopy as Useful Tool for Determining the
Structure in Solution of Coordination Compounds of MF5 (M = Nb, Ta), J. Fluorine Chem., 131, 21
(2010).
G. Pampaloni, Coord. Chem. Rev., 254, 387 (2010).
G. Pampaloni, Aromatic Hydrocarbons as Ligands. Recent Advances in the Synthesis, the Reactivity
and the Applications of bis(6-Arene) Complexes, Coord. Chem. Rev., 254, 402 (2010).
A. M. Raspolli Galletti, G. Pampaloni, Niobium Complexes as Catalytic Precursors for the
Polymerization of Olefins, Coord. Chem. Rev., 254, 525 (2010).
R. Bini, C. Chiappe, F. Marchetti, S. Zacchini, G. Pampaloni, The Structures and the Unusual
Rearrangements of Coordination Adducts of MX5 (M = Nb, Ta; X = F, Cl) with Simple Diethers. A
Crystallographic, Spectroscopic and Computational Study, Inorg. Chem., 49, 339 (2010).
F. Marchetti, G. Pampaloni, S. Zacchini, Preparation and Reactivity of Mono- and Dinuclear
Derivatives of Niobium and Tantalum Pentahalides with Alkyl-Aryl-Ethers, Eur. J. Inorg. Chem., 767774 (2010).
S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini A Systematic Study on the Activation of Simple
Polyethers by MoCl5 and WCl6, Dalton Trans., 39, 5367-5376 (2010).
F. Marchetti, C. Pinzino, S. Zacchini, G. Pampaloni, Long-Lived Radical Cations of Monocyclic Arenes
at Room-Temperature Obtained by NbF5 Acting as Oxidising Agent and Counterion Precursor,
Angew. Chem. Int. Ed., 49, 5268 (2010)
P. Biagini, L. Bonoldi, F. Marchetti, G. Pampaloni, Halo-complexes of Titanium(III): the
Thermochromic Behaviour of [NBu4][TiCl4(THF)2], Inorg. Chim. Acta, 363, 3637-3639 (2010).
F. Marchetti, G. Pampaloni, Characterization and Thermal Activation of Adducts of Group 4
Tetrahalides with 1,2-Dialkoxyalkanes, Inorg. Chim. Acta, 363, 3670-3673 (2010).
A. Boni, F. Marchetti, G. Pampaloni, S. Zacchini, Cationic Diiron and Diruthenium -Allenyl
Complexes: Synthesis, X-Ray Structures and Cyclization Reactions with Ethyldiazoacetate/Amine
Affording Unprecedented Butenolide- and Furaniminium-Substituted Bridging Carbene Ligands,
Dalton Trans., 39 108666-10875 (2010).
C. Forte, G. Pampaloni, C. Pinzino, F. Renili, N,N-Dialkylcarbamato Derivatives of Niobium and
Tantalum as Precursors to Metal-Functionalized Silica Surfaces, Inorg. Chim. Acta, 365, 251-255
(2011).
F. Marchetti, G. Pampaloni, C. Pinzino, Room-temperature long-lived [Nb2F11] − salts of radical
cations of simple arenes: EPR, UV–Vis and DFT results, J. Organomet. Chem., 696, 1294-1300
(2011).
F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, S. Zacchini, Easily Available Niobium(V)
Mixed Chloro-Alkoxide Complexes as Catalytic Precursors for Ethylene Polymerization, J. Polym.
Sci., Part A: Polymer Chem., 49, 1664-1670 (2011).
F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Ethylene
Polymerization by Niobium(V) N,N-dialkylcarbamates Activated with Aluminum Co-catalysts,
Organometallics, 30, 1682-1688 (2011).
R. Bini, F. Marchetti, G. Pampaloni, S. Zacchini, Further Insights into the Chemistry of Niobium and
Tantalum Pentahalides with 1,2-Dialkoxyalkanes: Synthesis of Bromo- and Iodoalkoxides,
Spectroscopic and Computational Studies, Polyhedron., 30, 1412-1419 (2011).
S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, C Bond Forming Self-Condensation of Amide
Promoted by MoCl5 at Room Temperature, Inorg. Chem., 50, 3846-3848 (2011).
C. Forte, M. Hayatifar, G. Pampaloni, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Ethylene
Polymerization Using Novel Titanium Catalytic Precursors Bearing N,N-dialkylcarbamato Ligands, J.
Polym. Sci., Part A: Polymer Chem., 49, 3338-3345 (2011).
A. Boni, T. Funaioli, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Reversible Reductive
Dimerization of Diiron -Vinyl Complex via CC Coupling: Characterization and Reactivity of the
Intermediate Radical Species, Organometallics, 30, 4115-4122 (2011).
F. Marchetti, G. Pampaloni, The Reactivity of NbX5 (X = F, Cl) with Lactons and Lactams, and the
Synthesis of the First Nucleobase-Containing Niobium Complex, Inorg. Chim. Acta, 376, 123-128
(2011).
A. Boni, T. Funaioli, F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Electrochemical, EPR and
computational results on [Fe2Cp2(CO)2]-based complexes with a bridging hydrocarbyl ligand, J.
Organomet. Chem., 696, 3551-3556 (2011).
F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, M. Hayatifar, Easily-Available OxygenContaining Derivatives of Niobium Pentachloride as Catalytic Precursors for Ethylene Polymerization,
Polym. Intern., 60, 1722-1727 (2011).
M. Hayatifar, F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, Room-temperature
polymerization of -pinene by niobium and tantalum halides, Catal. Today, 192, 177-182 (2012).
F. Marchetti, G. Pampaloni, Interaction of Niobium and Tantalum Pentahalides with O-donors:
Coordination Chemistry and Activation Reactions, Chem. Commun., 48, 635-653 (2012).
F. Marchetti, G. Pampaloni, L. Biancalana, Activation Reactions of 1,1-Dialkoxoalkanes and
Unsaturated O-Donors by Titanium Tetrafluoride, Inorg. Chim. Acta, 385 135-139 (2012).
M. Bortoluzzi, N. Guazzelli, F. Marchetti, G. Pampaloni, S. Zacchini, Convenient synthesis of fluoridealkoxides of Nb(V) and Ta(V): a spectroscopic, crystallographic and computational study, Dalton
Trans., 41 12898-12906 (2012).
S. Dolci, V. Ierardi, M. Remskar, Z. Jagličic, F. Pineider, A. Boni, G. Pampaloni C. A. Veracini, V.
Domenici, Chemical–physical properties, morphology, and magnetic investigations on new cystine
functionalized ultra-small super-paramagnetic iron-oxide nanoparticles, J. Mat. Sci., 48 1283-1291
(2013).
F. Marchetti, G. Pampaloni, S. Zacchini, The Interaction of MoCl5 with Carbonyl Compounds, Dalton
Trans., 42, 2477-2487 (2013).
F. Marchetti, G. Pampaloni, C. Pinzino, F. Renili, T. Repo, S. Vuorinen, Ring Opening Polymerization
of rac-Lactide by Group 4 Tetracarbamato Complexes: Activation, Propagation and Role of The
Metal, Dalton Trans., 42, 2792-2802 (2013).
S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Molybdenum Pentachloride with
Ester Molecules: Ester Activation, Metal Reduction and Synthesis of 1D Coordination Polymers, Eur.
J. Inorg. Chem., 1371-1380 (2013).
S. Dolci, F. Marchetti, G. Pampaloni, S. Zacchini, Coordination Chemistry of WCl6: a
Crystallographic and Spectroscopic Study on the Reactions with Carbonyl Compounds, Dalton Trans.,
42, 5635-5648 (2013)
S. Dolci, V. Ierardi, A. Gradišek, Z. Jagličić, M. Remskard, T. Apihd, M. Cifelli, G. Pampaloni, C. A.
Veracini, V. Domenici, Precursors of Magnetic Resonance Imaging Contrast Agents Based on Cystinecoated Iron-oxide Nanoparticles, Curr. Phys. Chem., 3, 493-500 (2013).
M. Hayatifar, F. Marchetti, G. Pampaloni, Y. Patil, A. M. Raspolli Galletti, Fluoride adducts of
Niobium(V): Activation Reactions and Alkene Polymerizations, Inorg. Chim. Acta, 399, 214-218
(2013).
G. Agonigi, M. Bortoluzzi, T. Funaioli, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis of Diiron Allenyl Complexes by Electrophilic Addition to Propen-2-yl-Dimetallacyclopentenone Species: a Joint
Experimental and DFT Study, J. Organomet. Chem., 731, 61-66 (2013).
M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis, X-Ray Characterization and
Reactivity of -Aminoacidato Ethoxide Complexes of Niobium(V) and Tantalum(V), Inorg. Chem., 52,
4017-4025 (2013)
M. Bortoluzzi, F. Ghini, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Oxo- and Sulfido N,NDiethylcarbamates of Niobium(V): Synthesis, Characterization and DFT Study, Eur. J. Inorg. Chem.,
3112-3118 (2013).
F. Marchetti, G. Pampaloni, S. Zacchini, Lactam/MoCl5 Interaction in CH2Cl2: synthesis and X-ray
Characterization of Protonated -Valerolactam Salts, RSC Advances, 3, 10007-10013 (2013).
M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Reactions of Molybdenum Pentachloride with
Oxygen and Nitrogen Donor Ligands, Polyhedron, 61, 188-194 (2013).
M. Bortoluzzi, F. Marchetti, G. Pampaloni, M. Pucino, S. Zacchini, Coordination Complexes of NbX5
(X = F, Cl) with (O,N)- and (O,O)-Donor Ligands and the First X-Ray Characterization of a
Mononuclear NbF5 Adduct, Dalton Trans, 42, 13054-13064 (2013)
T. Funaioli, F. Marchetti, G. Pampaloni, S. Zacchini, Ligand-Interchange Reactions Between M(IV) (M
= Ti, V) Oxide Bis-Acetylacetonates and Halides of High Valent Groups 4 and 5 Metals. A Synthetic
and Electrochemical Study, Dalton Trans, 42, 14168 - 14177 (2013).
F. Marchetti, G. Pampaloni, C. Pinzino Long-Lived Radical Cation Salts Obtained by Interaction of
Monocyclic Arenes with Niobium and Tantalum Pentahalides at Room Temperature: EPR and DFT
Studies, Chem. Eur. J., 19, 12962-13969 (2013).
C. Forte M. Hayatifar, G. Pampaloni, A. M. Raspolli Galletti, F. Renili, S. Zacchini, Titanium
Complexes Bearing Carbamato Ligands as Catalytic Precursors for Propylene Polymerization
Reactions, J. Polym. Sci., Part A: Polymer Chem.,51, 4095-4102 (2013).
F. Marchetti, G. Pampaloni, C. Pinzino, S. Zacchini, Stable [M2F11] – (M = Nb, Ta) Salts of Protonated
1,3-Dimethoxybenzene, Eur. J. Inorg. Chem., 5755-5761 (2013).
F. Marchetti, G. Pampaloni, S. Zacchini, The Reactivity of Molybdenum Pentachloride with Ethers:
Routes to the Synthesis of MoIVCl4 Adducts, Mo(V) Chlorido-Alkoxides and Mo(V) Oxydo-Chlorides,
Dalton Trans., 42, 15226-15234 (2013).
S. Dolci, V. Ierardi, A. Gradišek, Z. Jagličić, M. Remskar, T. Apih, M. Cifelli, G. Pampaloni, C. A.
Veracini and V. Domenici, Precursors of Magnetic Resonance Imaging Contrast Agents Based on
Cystine-coated Iron-oxide Nanoparticles, Curr Phys Chem, 3 493-500 (2013).
L. Favero, F. Marchetti, G. Pampaloni, S. Zacchini, The Interaction of Molybdenum Pentachloride with
O- and S-Heterocycles, Dalton Trans., 43, 495-504 (2014).
M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Reactions of TaF5 with Activated Arenes.
Synthesis of [4-(OH)-3-(OCH3)C6H3CH(=O-H)][4-(OH)-3-(OCH3)C6H3CHO][TaF6], a Rare Example
of Protonated Aldehyde, Polyhedron, 70, 6-10 (2014).
M. Hayatifar, G. Pampaloni, L. Bernazzani, C. Capacchione, A. M. Raspolli Galletti, Y. Kissin, A new
type of post-metallocene catalyst for alkene polymerization. Copolymerization of ethylene and 1-hexene
with titanium complexes bearing N,N-dialkylcarbamato ligands, Polym. Int., 63, 560-567 (2014).
M. Bortoluzzi, E. Ferretti, F. Marchetti, G. Pampaloni, S. Zacchini, A Structurally-Characterized
NbCl5-NHC Adduct, Chem. Commun, 50, 4472-4474 (2014).
M. Bortoluzzi, F. Marchetti, G. Pampaloni, S. Zacchini, Tribenzylamine CH Activation and
Intermolecular Hydrogen Transfer Promoted by WCl6, Inorg. Chem., 53, 3832-3838.
M. Bortoluzzi, M. Hayatifar, F. Marchetti, G. Pampaloni, S. Zacchini, Synthesis of di- and tetranuclear
oxidomolybdenum(V) complexes containing p-toluenesulfonates as ligands: a joint spectroscopic,
crystallographic and computational study, Dalton Trans., 43, 10157-10163 (2014).
Sara Dolci, Valentina Domenici, Celia Duce, Maria Rosaria Tiné, Vincenzo Ierardi, U Valbusa, Z
Jaglicic, Adriano Boni, M Gemmi, Guido Pampaloni, Ultrasmall superparamagnetic iron oxide
nanoparticles with titanium-N,N-dialkylcarbamato coating, Mat. Res. Express, 1, 035401-035420
(2014)