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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 20.11.2014
*
Version number 4
Revision: 20.11.2014
SECTION 1: Identification of the substance/mixture and of the
company/undertaking
· 1.1 Product identifier
· Trade name: OBSH Blähmittel
· CAS Number:
80-51-3
· EC number:
201-286-1
· 1.2 Relevant identified uses of the substance or mixture and uses advised against
No further relevant information available.
· Application of the substance / the mixture Organic intermediates
· 1.3 Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Polytrade GmbH
Borsigallee 12
D-60388 Frankfurt/M.
Tel. +49 69 94 20 72-33
Fax +49 69 41 03 60
www.polytrade.de
· Informing department:
Tel. +49 69 94 20 72 - 34
[email protected]
· 1.4 Emergency telephone number:
Tel. +49 69 94 20 72 - 33
Bürozeiten / Office hours 9:00 - 17:00
*
SECTION 2: Hazards identification
· 2.1 Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Self-react. CD
H242 Heating may cause a fire.
GHS08 health hazard
Muta. 2
H341 Suspected of causing genetic defects.
GHS09 environment
Aquatic Chronic 2 H411 Toxic to aquatic life with long lasting effects.
GHS07
Acute Tox. 4
Skin Irrit. 2
Eye Irrit. 2
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
(Contd. on page 2)
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Printing date 20.11.2014
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Trade name: OBSH Blähmittel
(Contd. from page 1)
Skin Sens. 1
H317 May cause an allergic skin reaction.
· Classification according to Directive 67/548/EEC or Directive 1999/45/EC
Xn; Harmful
R22-68:
Harmful if swallowed. Possible risk of irreversible effects.
Xi; Irritant
R36/38:
Irritating to eyes and skin.
Xi; Sensitising
R43:
May cause sensitisation by skin contact.
E; Explosive
R2:
Risk of explosion by shock, friction, fire or other sources of ignition.
N; Dangerous for the environment
R51/53:
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
· 2.2 Label elements
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07 GHS08 GHS09
· Signal word Danger
· Hazard-determining components of labelling:
4,4'-oxydi(benzenesulphonohydrazide)
· Hazard statements
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261
Avoid breathing dust.
P280
Wear protective gloves / eye protection / face protection.
P273
Avoid release to the environment.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P301+P312
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P302+P352
IF ON SKIN: Wash with plenty of water.
P337+P313
If eye irritation persists: Get medical advice/attention.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
(Contd. on page 3)
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Trade name: OBSH Blähmittel
(Contd. from page 2)
P403+P235
P501
Store in a well-ventilated place. Keep cool.
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· 2.3 Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
*
SECTION 3: Composition/information on ingredients
· 3.1 Chemical characterisation: Substances
· CAS No. Designation:
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
· Identification number(s):
· EC number: 201-286-1
*
SECTION 4: First aid measures
· 4.1 Description of first aid measures
· General information Instantly remove any clothing soiled by the product.
· After inhalation
Supply fresh air; consult doctor in case of symptoms.
In case of unconsciousness bring patient into stable side position for transport.
· After skin contact
Instantly wash with water and soap and rinse thoroughly.
In case of skin irritations or sensitizing effects, consult doctor.
· After eye contact
Rinse opened eye for several minutes under running water.
Call a doctor immediately.
· After swallowing
Rinse out mouth and then drink plenty of water.
Instantly call for doctor.
· 4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
· 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
*
SECTION 5: Firefighting measures
· 5.1 Extinguishing media
· Suitable extinguishing agents
Immediately evacuate area!
Extinguishing powder, foam or water jet. Fight larger fires with water jet or alcohol-resistant foam.
· For safety reasons unsuitable extinguishing agents Water with a full water jet.
· 5.2 Special hazards arising from the substance or mixture
Danger of explosion when heated under confinement.
Inhalation of combustion gases may cause serious health hazards.
During incomplete combustion carbon monoxide can be formed.
Can be released in case of fire:
Nitrogen oxides (NOx)
(Contd. on page 4)
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Trade name: OBSH Blähmittel
(Contd. from page 3)
Sulphur oxides (SOx)
· 5.3 Advice for firefighters
· Protective equipment: Wear self-contained breathing apparatus.
· Additional information
Remove fill mass from incendiary zone, if possible.
Cool closed containers near by fire source with water.
Provide for sufficient reservoirs for water for fire fighting.
*
SECTION 6: Accidental release measures
· 6.1 Personal precautions, protective equipment and emergency procedures
Avoid causing dust.
Keep away from ignition sources
Bring persons out of danger.
· 6.2 Environmental precautions: Do not allow to enter drainage system, surface or ground water.
· 6.3 Methods and material for containment and cleaning up:
Collect mechanically.
Avoid dust generation.
Send for recovery or disposal in suitable containers.
Dispose of contaminated material as waste according to item 13.
· 6.4 Reference to other sections
See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
*
SECTION 7: Handling and storage
· 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
Any deposit of dust which cannot be avoided must be removed regularly.
Use appropriate industrial vacuum cleaners or central vacuum systems for dust removal.
· Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Prevent impact and friction.
Protect from heat.
· 7.2 Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Store only in the original container.
Store in a cool, dry and light-protected place.
Store < 50 °C.
· Information about storage in one common storage facility:
Do not store together with oxidising and acidic materials as well as heavy-metal compounds.
Store away from foodstuffs.
· Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed containers.
Protect from heat and direct sunlight.
Protect from humidity and keep away from water.
(Contd. on page 5)
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Trade name: OBSH Blähmittel
(Contd. from page 4)
· 7.3 Specific end use(s) No further relevant information available.
*
SECTION 8: Exposure controls/personal protection
· 8.1 Control parameters
· Components with limit values that require monitoring at the workplace: Not required.
· DNELs
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
Dermal
DNEL (worker, long-term, systemic) 0.015 mg/kg bw/day (human)
Inhalative DNEL (worker, long-term, local)
0.1 mg/m³ (human)
DNEL (worker, long-term, systemic) 0.1 mg/m³ (human)
· PNECs
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
PNEC aqua (freshwater)
0.014 mg/L (.)
PNEC aqua (intermittent releases) 0.03 mg/L (.)
PNEC aqua (marine water)
0.0014 mg/L (.)
PNEC sediment (freshwater)
0.03 mg/kg sedim. dw (.)
PNEC sediment (marine water)
0.003 mg/kg sedim. dw (.)
PNEC soil
0.002 mg/kg soil dw (.)
· Additional information: The lists that were valid during the compilation were used as basis.
· 8.2 Exposure controls
· Personal protective equipment
· General protective and hygienic measures
Do not eat, drink or smoke while working.
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or
longer exposure use breathing apparatus that is independent of circulating air.
Filter P3.
· Protection of hands: Synthetic gloves
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further
marks of quality and varies from manufacturer to manufacturer.
· Penetration time of glove material
With solid dry substances permeation is not to be expected. Therefore the breakthrough-time
for this protective glove has not been measured.
The exact break through time has to be found out by the manufacturer of the protective gloves
and has to be observed.
· For the permanent contact gloves made of the following materials are suitable:
Nitrile rubber, NBR
· Eye protection: Tightly sealed safety glasses.
GB
(Contd. on page 6)
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(Contd. from page 5)
SECTION 9: Physical and chemical properties
· 9.1 Information on basic physical and chemical properties
· General Information
· Appearance:
· Form:
Powder
· Colour:
White
· Odour:
Characteristic
· Odour threshold:
Not determined.
· pH-value:
· Change in condition
· Melting point/Melting range:
· Boiling point/Boiling range:
Not applicable.
155 °C
Decomposition at heating.
· Flash point:
Not applicable
· Inflammability (solid, gaseous)
Substance is inflammable.
· Ignition temperature:
530 °C
· Decomposition temperature:
Not determined.
· Self-inflammability:
Not determined.
· Danger of explosion:
Risk of explosion by shock, friction, fire or other
sources of ignition.
· Critical values for explosion:
· Lower:
· Upper:
Not determined.
Not determined.
· Vapour pressure:
Not applicable.
· Density
Not determined
· Solubility in / Miscibility with
· Water:
Insoluble
· Partition coefficient (n-octanol/water): Not determined.
· Viscosity:
· dynamic:
· 9.2 Other information
Not applicable.
No further relevant information available.
SECTION 10: Stability and reactivity
· 10.1 Reactivity
· 10.2 Chemical stability
· Thermal decomposition / conditions to be avoided:
To avoid thermal decomposition do not overheat.
Thermal decomposition > 70 °C.
Exothermic thermal decomposition
· 10.3 Possibility of hazardous reactions Explosive
· 10.4 Conditions to avoid No further relevant information available.
· 10.5 Incompatible materials: No further relevant information available.
· 10.6 Hazardous decomposition products:
Carbon monoxide and carbon dioxide
(Contd. on page 7)
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(Contd. from page 6)
Nitrogen oxides (NOx)
Sulphur oxides (SOx)
*
SECTION 11: Toxicological information
· 11.1 Information on toxicological effects
· Acute toxicity:
· LD/LC50 values that are relevant for classification:
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
Oral
LD50 > 2000 mg/kg (rat) (OECD 401)
Dermal LD50 >200 mg/kg (rabbit)
· Primary irritant effect:
· on the skin: Irritant to skin and mucous membranes.
· on the eye: Irritant effect.
· Sensitisation: Sensitization possible by skin contact.
· Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC
Classification Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
· Repeated dose toxicity
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
Oral NOAEL (28d) 10 mg/kg bw/day (rat) (OECD 407)
· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Muta. 2
*
SECTION 12: Ecological information
· 12.1 Toxicity
· Aquatic toxicity:
80-51-3 4,4'-oxydi(benzenesulphonohydrazide)
EC50 (static) 6.7 mg/l/72h (Pseudokirchneriella subcapitata) (OECD 201)
0.16 mg/l/48h (Daphnia pulex) (OECD 202)
2.9 mg/l/48h (Daphnia magna) (OECD 202)
LC50
75 mg/l/96h (Oryzias latipes) (OECD 203)
NOEC (static) 0.9 mg/l/72h (Pseudokirchneriella subcapitata) (OECD 201)
· 12.2 Persistence and degradability No further relevant information available.
· Other information: There are no data available about the preparation.
· 12.3 Bioaccumulative potential No further relevant information available.
· 12.4 Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Water danger class 3 (German Regulation) (Assessment by list): extremely hazardous for
water.
Do not allow product to reach ground water, water bodies or sewage system, even in small
quantities.
Danger to drinking water if even extremely small quantities leak into soil.
(Contd. on page 8)
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Trade name: OBSH Blähmittel
(Contd. from page 7)
· 12.5 Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· 12.6 Other adverse effects No further relevant information available.
SECTION 13: Disposal considerations
· 13.1 Waste treatment methods
· Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage
system.
The waste code numbers mentioned are recommendations based on the probable use of the
product.
· European waste catalogue
07 00 00 WASTES FROM ORGANIC CHEMICAL PROCESSES
07 01 00 wastes from the manufacture, formulation, supply and use (MFSU) of basic organic
chemicals
07 01 08* other still bottoms and reaction residues
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations.
*
SECTION 14: Transport information
· 14.1 UN-Number
· ADR, IMDG, IATA
· 14.2 UN proper shipping name
· ADR
· IMDG, IATA
UN3226
3226 SELF-REACTIVE SOLID TYPE D (4,4'oxydi(benzenesulphonohydrazide))
SELF-REACTIVE SOLID TYPE D (4,4'oxydi(benzenesulphonohydrazide))
· 14.3 Transport hazard class(es)
· ADR
· Class
· Label
4.1 (SR1) Flammable solids, self-reactive
substances and solid desensitised explosives.
4.1
· IMDG, IATA
· Class
4.1 Flammable solids, self-reactive substances
and solid desensitised explosives.
(Contd. on page 9)
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(Contd. from page 8)
· Label
4.1
· 14.4 Packing group
· ADR, IMDG, IATA
Void
· 14.5 Environmental hazards:
· Marine pollutant:
· Special marking (ADR):
No
Symbol (fish and tree)
· 14.6 Special precautions for user
· EMS Number:
Warning: Flammable solids, self-reactive
substances and solid desensitised explosives.
F-J,S-G
· 14.7 Transport in bulk according to Annex II
of MARPOL73/78 and the IBC Code
Not applicable.
· Transport/Additional information:
Prohibited in air transportation.
· ADR
· Limited quantities (LQ)
· Excepted quantities (EQ)
500 g
Code: E0
Not permitted as Excepted Quantity
2
D
· Transport category
· Tunnel restriction code
· IMDG
· Limited quantities (LQ)
· Excepted quantities (EQ)
· UN "Model Regulation":
*
500 g
Code: E0
Not permitted as Excepted Quantity
UN3226, SELF-REACTIVE SOLID TYPE D, 4.1
SECTION 15: Regulatory information
· 15.1 Safety, health and environmental regulations/legislation specific for the substance or
mixture
· Labelling according to Regulation (EC) No 1272/2008
The substance is classified and labelled according to the CLP regulation.
· Hazard pictograms
GHS02 GHS07 GHS08 GHS09
· Signal word Danger
· Hazard-determining components of labelling:
4,4'-oxydi(benzenesulphonohydrazide)
· Hazard statements
H242 Heating may cause a fire.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
(Contd. on page 10)
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(Contd. from page 9)
H411 Toxic to aquatic life with long lasting effects.
· Precautionary statements
P210
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
P261
Avoid breathing dust.
P280
Wear protective gloves / eye protection / face protection.
P273
Avoid release to the environment.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P301+P312
IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.
P302+P352
IF ON SKIN: Wash with plenty of water.
P337+P313
If eye irritation persists: Get medical advice/attention.
P333+P313
If skin irritation or rash occurs: Get medical advice/attention.
P403+P235
Store in a well-ventilated place. Keep cool.
P501
Dispose of contents/container in accordance with local/regional/national/
international regulations.
· National regulations
· Water hazard class:
Water danger class 3 (Assessment by list): extremely hazardous for water.
· Substances of very high concern (SVHC) according to REACH, Article 57
Substance is not listed.
· 15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
· Department issuing data specification sheet:
This Material Safety Data Sheet has been drawn up in cooperation with:
DEKRA Consulting GmbH, Hanomagstr. 12, D-30449 Hanover, Germany,
tel.: (+49) 511 42079 311, [email protected].
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations
Concerning the International Transport of Dangerous Goods by Rail)
ICAO: International Civil Aviation Organisation
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning
the International Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Self-react. CD: Self-Reactive Substances and Mixtures, Types C, D
Acute Tox. 4: Acute toxicity, Hazard Category 4
Skin Irrit. 2: Skin corrosion/irritation, Hazard Category 2
Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2
Skin Sens. 1: Sensitisation - Skin, Hazard Category 1
Muta. 2: Germ cell mutagenicity, Hazard Category 2
Aquatic Chronic 2: Hazardous to the aquatic environment - Chronic Hazard, Category 2
· * Data compared to the previous version altered.
GB