4/4 Appendix 1 Samples, measurands, concentration ranges and preservations Measurands Metals in synthetic water sample A1M Al, As, B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, Sn, Sr, Stot, Ti, U, V, Zn (22 measurands) Metals in domestic and natural water Al, As, B, Ba, Cd, Co, Cr, Cu, Fe, Mn, Mo, Ni, Pb, Sb, Se, Sn, Sr, Stot, Ti, U, V, Zn (22 measurands) Sample type (volume) and preservations Synthetic water sample (60 ml plastic bottle) Sample code 1) A1M As, Cd, Co, Ni, Pb, Se, U, V: 1 – 10 µg/l B, Ba, Cr, Cu, Mn, Mo, Sb, Sn, Sr, Ti, Zn: 10 – 100 µg/l Al, Fe: 50 – 500 µg/l Stot: > 10 mg/l D2M A1Hg As, Cd, Co, Ni: 0,1 – 1 µg/l Ba, Cr, Pb, Sb, Se, Sn, U, V: 1 – 10 µg/l Al, B, Mn, Mo, Sr, Ti, Zn: 10 – 50 µg/l Cu, Fe: > 100 µg/l Stot: > 5 mg/l As, Cd: 0,1 – 1 µg/l Co, Cr, Ni, Pb, Se, U, V: 1 – 10 µg/l B, Ba, Cu, Mo, Sb, Sn, Sr, Ti, Zn: 10 – 100 µg/l Al, Fe, Mn: > 100 µg/l Stot: > 5 mg/l 0,05 – 1 µg/l 12.5 ml conc. HCl/250 ml Domestic water (250 ml glass bottle) D2Hg 0,05 – 1 µg/l 12.5 ml conc. HCl/250 ml Natural water (250 ml glass bottle) N3Hg > 0,1 µg/l 0.3 ml conc. HNO3/60 ml Domestic water (125 ml plastic bottle) 0.625 ml conc. HNO3/125 ml Natural water (125 ml plastic bottle) N3M 0.625 ml conc. HNO3/125 ml Hg in waters 1) Sample codes / matrix: Concentration ranges Synthetic sample (250 ml glass bottle) 12.5 ml conc. HCl/250 ml A = Synthetic sample D = Domestic water N = Natural water (river) Proficiency test MET 04/2017 - Metals in natural water
© Copyright 2025