Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ Unit 5 Test Review Wavelength and Frequency Formula C = λν C = 3.0 x 108 (m∙Hz) or (m∙sec-1) λ = Wavelength (m) ν = Frequency (Hz) or (sec-1) Answer the following questions by using the formula above: 1. What is the speed of light? 2. What is the wavelength of a wave having a frequency of 4.76 x 1014 Hz? Is this wave visible? 3. What is the frequency of a 6.9 x 10-7 m wave? Is this wave visible? 4. What is the frequency of a 3,410 km wave? Is this wave visible? 5. What is the frequency of a 5.6 x 102 nm wave? Is this wave visible? 6. What is the wavelength of 10.1 KHz wave? Is this wave visible? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ Energy of a Quantum Equantum = hv Energy of a Photon Equantum = Represents Energy h = Planck’s constant v = Frequency Ephoton = hv Ephoton = Represents Energy h = Planck’s constant v = Frequency Planck’s Constant h = 6.626 x 10-34 J•s Answer the following questions by using the formula above: 7. What is Plank’s Constant? 8. What is the energy of a 7.66 x 1014 Hz wave? 9. What is the frequency of a photon carrying 1.78 x 10-15 J of energy? 10. What is the Quantum energy of a 2.61 x 1019 Hz wave? 11. What is the frequency of a photon carrying 4.31x 10-22 J of energy? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ In the calculations below you will need to determine the wavelength of the given sample. [Hint: Use the Equantum or Ephoton equations to determine the frequency and then use c= λν] 12. What is the wavelength of a 1.32 x 10-6 J wave? 13. What is the wavelength of a 7.65 x 10-17 J wave? 14. What is the wavelength of a 1.528 x 10-13 J wave? Think about it: 15. What modification did Einstein make to Planck’s work? 16. Which has the largest wavelength, Ultraviolet Rays or X-Rays? 17. While and FM radio station broadcasts at a frequency of 94.7 MHz, an AM station broadcasts at a frequency of 820kHz. What are the wavelengths of the two broadcasts? 18. Objects get their colors from reflecting only certain wavelengths when hit with white light. Light reflected from a green leaf is found to have a wavelength of 4.90 x 10-7 m. What is the frequency of the light? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 19. Who is J. W. Dobereiner and what was his contribution to the organization of all of the known elements? 20. Who is J.A.R. Newlands and what was his contribution to the organization of all of the known elements? 21. Who is Dmitri Mendeleev and what was his contribution to the organization of all of the known elements? 22. Who is Henry Moseley and what was his contribution to the organization of all of the known elements? 23. What is the Periodic Law? 24. Who is Neils Bohr and what did he suggest? 25. Draw the Bohr’s Model for Lithium 26. What makes Bohr’s model fundamentally incorrect and how can it be fixed? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 27. Write the ground state electron configuration for each neutral atom. Remember ground state means that all of the lowest possible energy levels (up to the proper number of electrons for the element) are filled. a) Na b) Pb c) Sr d) U e) N 28. Write the ground state electron configuration for each neutral atom in Nobel Gas Notation. Remember ground state means that all of the lowest possible energy levels (up to the proper number of electrons for the element) are filled. a) Na b) Pb c) Sr d) U e) N Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 29. Write the ground state electron configuration for the following ions. Remember ions have a change in total number of electrons (positive ions, cations, have lost an electron and negative ions, anions, have gained an ion). [Example: N-3 is 1s22s23p6 and has 3 extra electrons] a) O-2 b) Fe+2 c) B+3 d) Cl-1 e) K+ 30. An excited atom has an electron or electrons which are not in the lowest energy state. Excited atoms are unstable energetically. The electrons eventually fall to a lower level. An excited state electron is denoted with the symbol (*). [Example: *Li is 1s22p1 whereas Li is 1s22s1] Write an excited state electron configuration for each of the following: a) *Al b) *Br c) *F d) *K e) *Sr Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 31. Use the Pauli Exclusion Principle and Hund’s Rule to identify how many unpaired electrons are present in the following atomic structures : The Pauli Exclusion Principle states that a maximum of two electrons can occupy a single atomic orbital to form paired electrons, but only if the two electrons have opposite spins. Hund’s Rule states that single electrons with the same spin must occupy each equal-energy orbital before additional electrons with opposite spins can occupy the same orbital. a) Si b) N c) Cl d) Mn e) Ru 32. Fill out the information below? s-orbital p-orbital d-orbital f-orbital Draw the shape of the orbital How many electrons can it hold? What is the lowest energy level in which it can exist? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 33. Write out all possible energy levels with the corresponding sublevels. 34. Why is the 4s orbital filled with electrons before the 3d orbital? 35. Why does it take more energy to take an electron from Al+ than from Al? 36. What is the difference between an atom in its ground stave vs. its excited state? 37. What are the three rules that we need to use when writing the electron configuration in orbital notation? 38. Draw the Orbital Configuration for Ru. Energy Level s-orbitals p-orbitals d-orbitals f-orbitals n=5 ____ 5s ____ ____ ____ 5p ____ ____ ____ ____ ____ 5d ____ ____ ____ ____ ____ ____ ____ 5f n=4 ____ 4s ____ ____ ____ 4p ____ ____ ____ ____ ____ 4d ____ ____ ____ ____ ____ ____ ____ 4f n=3 ____ 3s ____ ____ ____ 3p ____ ____ ____ ____ ____ 3d n=2 ____ 2s ____ ____ ____ 2p n=1 ____ 1s Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 39. Fill out the chart below: Element Atomic Number Na 11 S 16 Number of electrons in each level 1st 2nd 3rd 2 8 1 1st 3rd 2nd 4th 4th Electron Configuration Number of ethat can be lost or gained Number of electrons left after ionization Charge on the ion 1s22s22p63s1 Lose 1 10 +1 1s22s22p63s23p4 Gain 2 18 -2 5th 5th 2 8 6 1st 2nd 3rd 4th 5th 1st 2nd 3rd 4th 5th 1st 2nd 3rd 4th 5th 1st 2nd 3rd 4th 5th 1st 2nd 3rd 4th 5th K Al Cl Xe Ca 40. What are valence electrons and where can find them? 41. What do valence electrons help us determine? 42. Why do the d orbitals not factor in to the valence electron number? 43. How many valence electrons are present for the transition metals? 44. The Lewis Dot Structure is a short hand expression that shows the number of valence electrons surrounding the elemental symbol. Draw the Lewis Dot Structure for the following: Al Coach Kenney Ca Te I Kr Si Rb 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 45. Describe the Alkali Metals. 46. Describe the Alkaline Earth Metals. 47. Describe the Halogens. 48. Describe the Noble Gases. 49. Describe the Transition Metals. 50. Describe the Inner Transition Metals. Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 51. Describe the key differences between Metals and Non-Metals. Characteristics of Metals Characteristics of Nonmetals 52. Describe the chemical families below: Family Location Reactivity Outer Shell Electrons Alkali Metals Alkaline Earth Metals Halogens Noble Gasses Transition Metals Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 53. What is the Trend for Atomic Size and why does that occur? 54. What is the Trend for Ionic Size and why does that occur? 55. What is the Trend for Ionization Energy and why does that occur? 56. What is the Trend for electronegativity and why does that occur? 57. What is the difference between Electronegativity and Ionization Energy? Coach Kenney 3113 Name: ____________________________ When is this due? ___________________ Date: __________ Period: __________ 58. A photon of ultraviolet (UV) light possesses enough energy to mutate a strand of human DNA. What is the energy of a single UV photon having a wavelength of 257 nm? a) 7.74 x 10-37 J b) 5.68 x 10-31 J c) 7.74 x 10-19 J d) 1.29 x 1036 J 59. The elements silicon, gallium, arsenic, germanium, aluminum, cadmium, sulfur, and selenium are all used in the manufacture of various semiconductor devises. Which of the following electron configurations is the ground state electron configuration for germanium? a) b) c) d) 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p1 1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p2 1s2 2s2 2p6 3s2 3p6 4s2 3d12 1s2 2s2 2p6 3s2 3p6 4s2 3d6 4p6 60. Identify which element would have the following electron configuration as a ground state atom? [Ne]3s2 3p3 a) b) c) d) Al P S Sc 61. As one moves from the ultraviolet to X-ray regions of the electromagnetic spectrum, the frequency of light waves increases. What is the effect on the wavelength and energy of the waves? a) b) c) d) the wavelength increases and the energy increases the wavelength decreases and the energy increases the wavelength increases and the energy decreases the wavelength decreases and the energy decreases 62. Nickel, copper, and zinc are sometime known as the coinage metals. How many unpaired electrons are in a ground state nickel atom? Bubble your answer below. + - . . . . . . . 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 0 1 2 3 4 5 6 7 8 9 63. Order the following atoms from smallest to largest radius: C, Al, F, Si a) b) c) d) Coach Kenney C < F < Al < Si Al < Si < F < C C < Si < F < Al F < C < Si < Al 3113
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