SCIENTIFIC MEASUREMENT Ch 2 Chemistry is a lot of math! Warm-ups 8/22/13 Name Per, Row 1. 2. 8/26/13 Saving paper is always good! WARM UP 1.Name 3 tools used for measurement. 2.What is a unit? 3.Give an example of a unit. 4.Why are units important. MAKING MEASUREMENTS Ch 2.2 Qualitative measurements: Give results in a descriptive and non-numerical form Example: Cookie Monster is Blue Quantitative measurements: Give results in a definite form – usually as numbers and units Example: Cookie Monster ate 1 kg of cookies QUALITATIVE OR QUANTITATIVE? The Big Mac is $2.29. The Pop Rocks are blue. The coffee is hot. The slurpee is 0 degrees Celsius. Measurement—a quantity that has both a number and a unit. For example… I weigh 90! I make 1000 an hour! There are 72 in this class. Numbers with NO units mean NOTHING…and will be marked WRONG on HW/Tests, etc. Measurements are fundamental to the experimental science. INTERNATIONAL SYSTEM OF UNITS SI UNITS (SYSTEME INTERNATIONALE) Meter (m) for length Use a Second (s) for time meterstick to measure Use a stopwatch to measure Kilogram (kg) for mass (1 kg = 2.2 lbs) Mole for the amount of substance Weight is NOT the same thing as mass! Use a scale to measure We will talk about mole later Kelvin (K) for temperature K = oC + 273 0 K = absolute zero Use a thermometer to measure oC is another option, but not Fahrenheit (in the metric Liter (L) or m3 for volume Use a graduated cylinder to measure 1L = 1m3 joule or calorie for energy We don’t discuss this much in this class… MASS VS WEIGHT Mass: amount of matter - Gravity does not affect mass Weight: measure of gravitational pull DERIVED UNITS: IT IS A COMBINATION OF UNITS Volume: cm3 Density: D= m/v amount of space Ratio of mass to occupied by an volume object Speed: meters/ second WARM-UP A scientist wants to conduct an experiment measuring the effect of temperature on the density of nitrogen gas. 1. What is the independent variable in this experiment? 2. The dependent variable? 3. What could be used as a control group? 4. What would be some constants? 5. What units should be used for temperature and density? 6. What tools should be used to measure temperature and density? METRIC PREFIXES Adding prefixes, gives us a range of size measurements. Based on a system of 10’s (decimal system) NOTE that the bigger number goes with the smaller unit. 100 cm = 1 m Prefixes you need to memorize… milli- (1/1000), centi-(1/100), kilo(1000x) METRIC PREFIXES: The metric system utilizes prefixes based on powers of 10. Prefixes you need to memorize… milli(1/1000x), centi-(1/100x), kilo-(1000x) ALL METRIC UNITS INCREASE OR DECREASE BY A POWER OF 10. Conversion factors: a ratio of equal proportions Values can often be expressed in more than one form $1 = 4 quarters = 10 dimes = 20 nickels = 100 pennies 1 meter = 100cm = 1000mm = 0.001km equal values can be shown as a ratio equal to 1; such ratios are called conversion factors… $1 1000m 1km 60min 10 dim es 1hr 1km 1000m conversion factors are useful for solving problems in which given measurements must be expressed in some other unit. Example 1: conversions a. convert 20 meters to to millimeters 1. which is smaller? 1000 mm in 1m 2. how many of the smaller are in the larger? 20,000mm 3. create a conversion Example 2: conversions b. Convert 20 meters to kilometers 0.02 km Date SI Unit Practice Convert each of the following: Example: 3.68kg * 1000g 1. 3.68 kg = __________ g 1 kg 2. 568 cm = __________ m 3.68kg * 103 3. 8700 ml = __________ l 4. 25 mg = __________g 5. 0.101 cm = __________ mm 6. 250 ml = __________ l 7. 600 g = __________ kg 8. 8900 mm = __________ m 9. 0.000004 m = __________ mm 10. 0.250 kg = __________ mg = 3680g Use table 2 on pg35! However you won’t get the table for your quiz next class Date: SI Unit Practice What SI unit would you use to measure…. 1. The length of a football field? 2. The WIDTH of a strand of hair? 3. The mass of an elephant? 4. The mass of an ant? 5. The distance from school to Sears? 6. The height of your desk? 7. The volume of water in a pool? 8. The volume of water in a spoon? 9. The temperature of this room? 1. 3.68 kg = __3680____ g 2. 568 cm = ___5.68___ m 3. 8700 ml = ___8.7____ l 4. 25 mg = __0.025___ g 5. 0.101 cm = ___1.01___ mm 6. 250 ml = __0.25_____ l 7. 600 g = ___0.6____ kg 8. 8900 mm = ___8.9____ m 9. 0.000004 m = __0.004___ mm 10. 0.250 kg = __250000__ mg What SI unit would you use to measure…. 5. The distance from school 1. The length of a to union station? football field? Meters Kilometers 2. The WIDTH of a strand of hair? Mm, um 3. The mass of an km elephant? 4. The mass of an ant? Mg (grams) 6. The height of your desk? cm 7. The volume of water in a pool? kL or km3 8. The volume of water in a spoon? mL or cm3 9. The temperature of this room? Kelvin (Celsius) SCIENTIFIC NOTATION: move decimal point the number of times ex: 1*105 indicated by the power of 10. + means larger number - means smaller number Convert the following out of or into scientific notation 1) 6.5*104 = 65000. 2) 6.5*10-4 = .00065 3) .00035 = 3.5*10-4 4) 35000 = 3.5*104 DERIVED UNITS: IT IS A COMBINATION OF UNITS Volume: cm3 amount of space occupied by an object Density: D= m/v Ratio of mass to volume mL=cm3 Speed: meters/ second DENSITY add the symbols <, >, or =to compare the blocks < < = DENSITY: D= M/V Ex: A rock has a mass of 10 grams and a volume of 5 cm3. Calculate its density. 10g / 5cm3 = 2 g/cm3 mass Density volume Units: g 3 cm g mL or D= m/v How can you find density from a graph? Density is the slope of the line of mass vs volume. y2- - y1 rise D= m/v=slope = = X –x 2 1 run Ex: 11-3 g = 1 g/mL 11-3mL g mL 1. What mineral is more dense? A, B, or C? - A: it has greatest slope 2. If you put equal volumes of A and B on a balance, which would have a larger mass? -A http://www.youtube.com/watch?v=-CDkJuo_LYs DENSITY CALCULATIONS Water displacement is used to find the volume of unusual shape: 1. measure volume of water 50mL 2. Add an object and measure volume again 60ml 3. Subtract the volume of object+water from volume of just water 60-50=10mL Ex 2. The mass of 10 copper coins is 30 grams. The initial volume of water is 50mL and the volume with the coins if 55mL. Calculate the density of the copper coins. Ex: 3. The density of silver is 10.0 g/cm3. If you have a sample size of 17.235 grams, what is the volume of the silver? HOW WOULD TEMP AFFECT DENSITY?? As temperature increases, what happens to density? If density deals with mass and volume… Does temperature affect mass? Or volume? HOMEWORK HW: ch. 2 section 2 pg 42 answer questions 1-6 Pg 881 #1, 2, 7 Quiz! Next class Use pg 42 #1,2 And 881 # 1, 2, 7, 9 to study Table on pg 35 1. The density of silver is 10.0 g/cm3. If you have a sample size of 17.235 grams, what is the volume of the silver? 2. If you have equal volumes of B(blue line) and C (red line). Which one has a larger mass? CH 2.3 Accuracy: the closeness of measurements to the actual value Precision: The closeness of a set of measurements to each other 2 technicians measure the density of a new substance: A: 2.000, 1.999, and 2.001 g/mL B: 2.5, 2.9, and 2.7 g/mL The correct value is 2.480 g/mL Who is more accurate and who is more precise? PERCENT ERROR: MEASURE OF HOW DIFFERENT YOUR VALUE IS FORM THE REAL VALUE Percent error = Value experimental – Value accepted *100% Value accepted Example: The density of water at 4 oC is known to be 1.00 g/mL. Kayla experimentally found the density of water to be 1.075 g/mL. What is her percent error? SIGNIFICANT FIGURES Ch 2.3 When we make quantitative measurements, we care about how good our data is. How we do this? Significant figures Slide 1 of 6 Significant Figures (Sig. Figs) in Measurements… Significant Figures: all the digits in a measurement that are known with certainty plus one estimated digit Rules for Significant Figures: 1. Zeros b/t nonzero digits are significant 2. Zeros appearing in front of all nonzero are not significant 3. Zeros at the end of a number and the right of a decimal point are significant 4. Zeros at the end of a number but to the left of a decimal point, if a decimal point is there, are significant. (NOT necessarily significant if no decimal) Examples: 3 40.7 L 87009 km 5 .00958 m 3 1 0.09 kg 85.00g 9.00000 2000 m 2000. m 4 6 1 4 WHEN GIVEN A NUMBER, YOU MUST BE ABLE TO D E T E R M I N E T H E N U M B E R O F S I G . F I G S . I N I T. a) 12,389 = _____ e) 6.700 x 107 = _____ All non-zero #’s are significant All numbers in the coefficient of a # in scientific notation are significant b) 0.452 = _____ Zeros before a decimal are not imp unless it is part of a whole number c) 10.26 = _____ zeros in between #’s are significant d) 23.000 = _____ Zeros after a decimal are significant IF THERE IS A WHOLE # f) 24,000,000 = _____ zeros w/out a decimal are NOT significant Perfect example of why sci.not. is so great…gets rid of insig 0’s g) 0.00000670 = _____ zeros after a decimal but with no whole # are NEVER significant. Again, use sci.not. MATH WITH SIG FIGS Conversions with Sig Figs: use same number of sig figs in the original measurement - the conversion factor is considered exact and does not count 4.608 m * 100cm m =460.8cm Addition and Subtraction with Sig Figs: answer must have same # of sig figs as the number with the fewest digits to right of the decimal 25.1g + 2.03g = 27.1g Multiplication and Division with Sig Figs: answer must use same # sig figs as the # with the fewest sig figs 3.05g / 8.47mL = 0.360g 80.0g/ 5mL = 16mL = 20mL 80.0g/ 5.0mL = 16mL SCIENTIFIC NOTATION: move decimal point the number of times ex: 1*105 indicated by the power of 10. + means move to the right - means move to the left 6.5*104 = 65000. 6.5*10-4 = .00065 .00035 = 3.5*10-4 35000 = 3.5*104 Significant Figures A. State the number of significant digits in each measurement. 1) 2) 3) 4) 5) 6) 2804 m 2.84 km 5.029 m 0.003068 m 4.6 x 105 m 4.06 x 10-5 m 7) 750 m 8) 75 m 9) 75,000 m 10) 75.00 m 11) 75,000.0 m 12) 10 cm Significant Figures Practice A. State the number of significant digits in each measurement. 1) 2) 3) 4) 5) 6) 2804 m 4 2.84 km 3 5.029 m 4 0.003068 m 4 4.6 x 105 m 2 4.06 x 10-5 m 3 8) 75 m 2 9) 75,000 m 2 10) 75.00 m 4 11) 75,000.0 m 6 12) 10 cm 1 or 2 7) 750 m 2 or 3 B. Solve the following problems and report answers with appropriate number of significant digits. 1) 6.201 cm + 7.4 cm + 0.68 cm +12.0 cm = 2) 1.6 km + 1.62 m +1200 cm = 3) 8.264 g - 7.8 g = 4) 10.4168 m - 6.0 m = 5) 12.00 m+15.001 kg= 6) 1.31 cm x 2.3 cm = 7) 5.7621 m x 6.201 m = 8) 20.2 cm / 7.41 s = 9) 40.002 g / 13.000005 g = 1) 6.201 cm + 7.4 cm + 0.68 cm +12.0 cm = 26.3 cm 2) 1.6 km + 1.62 m +1200 cm = 1.2 x 103 or 1.20 x 103 or 1203 m 3) 8.264 g - 7.8 g = 0.5 g 4) 10.4168 m - 6.0 m = 4.4 m 5) 12.00 m+15.001 kg= can’t add m and kg 6) 1.31 cm x 2.3 cm = 3.0 cm2 7) 5.7621 m x 6.201 m = 35.73 m2 8) 20.2 cm : 7.41 s = 2.73 cm/s 9) 40.002 g : 13.000005 g = 3.0771 WARM UP 1. 2. 3. 4. What tool would you use to measure mass? What unit would you use to measure mass? What tool would you use to measure volume? What unit(s) would you use to measure length? 1. LINEAR MEASUREMENTS The length, width, or height of something Tool? ruler, meter stick, etc. Units? Meter (m) Centimeters (cm) Millimeters (mm) PRACTICE: 2. VOLUME The space matter takes up Tool? Graduated cylinder, beaker, etc. Units? Liter (L) Milliliters (mL) cm3 MUST BE EYELEVEL TO MEASURE CORRECTLY! PRACTICE: 3. MASS The quantity of matter Tool? balance, scale, etc. Units? Kilograms (kg) Grams (g) We use digital scales (usually)…so just record what the scale says Mass continued… Scale must read zero before you place anything on it! If you want to measure the mass of something inside a container…you must measure the empty container first. How much mass does the water have? 462.3 g 450.0 g 4. TEMPERATURE The amount of heat present Tool? thermometer Units? Degrees Celsius (°C) 5. DENSITY? The amount of matter in a space Units? g/cm3 or g/mL Tool? scale and ruler or graduated cylinder
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