Energy harvesting by dielectric elastomer generators Project Number: IZERZO_142215/1; 10/RO-CH/RSRP/01.01.2013 Partners: EMPA- Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Functional Polymers, Dübendorf, Switzerland ICMPP- ”Petru Poni” Institute of Macromolecular Chemistry, Iasi, Romania PROJECT CO-FINANCED BY A GRANT FROM SWITZERLAND THROUGH THE SWISS CONTRIBUTION TO THE ENLARGED EUROPEAN UNION www.snf.ch www.uefiscdi.gov.ro Summary The search for new reliable green sources of energy increased significantly in the last years. Nature offers a number of sources of “unlimited” energy, ocean wave’s energy being one of them. Dielectric elastomer generators are a relatively new technology that can convert mechanical energy (e.g. wave energy) into more useful electrical energy. It is the aim of this project to develop new materials for Dielectric elastomer generators. New silicone based elastomeric materials with increased permittivity, low dielectric losses, low conductivity, and good mechanical properties will be prepared. In order to increase permittivity, polar groups will be attached to the silicone chains. Copolymers containing different amounts of dipoles at random position on the chain as well as copolymers where the position of the dipole is precisely controlled will be made. The newly prepared materials will be investigated regarding their mechanical and electrical properties as well as regarding their feasibility to convert mechanical energy into electrical energy. At the end of the project, not only should a good material for dielectric elastomer generators be achieved but also the understanding on structure property relationship would be greatly improved. www.snf.ch www.uefiscdi.gov.ro Keywords: permittivity, polar silicones synthesis, elastomers, actuators, dielectric elastomer generators Start/End: 01.01.2013 - 31.12.2015 Principal investigators: Dr. Dorina Maria Opris –EMPA Dr. Carmen Racles -ICMPP www.snf.ch www.uefiscdi.gov.ro Approved budget SNSF contribution www.snf.ch UEFISCDI contribution CH team RO team RO team Total 178516 141310 56440 376266 www.uefiscdi.gov.ro Publications: 1) „Synthesis and characterization of silicones containing cyanopropyl groups and their use in dielectric elastomer actuators”, Carmen Racles, Maria Cazacu, Beatrice Fischer, Dorina M Opris, Smart Mater. Struct,. 22 (2013) 104004, 2) „Chemical modification of polysiloxanes with polar pendant groups by co hydrosilylation”, Carmen Racles, Mihaela Alexandru, Adrian Bele, Valentina Musteata, Maria Cazacu, Dorina M. Opris, RSC Advances, 2014, 4(71), 37620 – 37628, 3) „Tailoring the dielectric properties of silicones by chemical modification”, Carmen Racles, Mihaela Alexandru, Adrian Bele, Valentina Musteata, Maria Cazacu, Dorina Opris, in: "Research Developments in Polymer Science" Volume 12(2014), Editor: S.G. Pandalai; ISBN: 978-81-7895-611-4, Research Signpost, Transworld Research Network, in press. www.snf.ch www.uefiscdi.gov.ro Communications and posters: 1. Dorina M. Opris, Sascha Grimm, Frank Nüesch, Martin Molberg, Gabor Kovacs, Carmen Racles, Maria Cazacu, Jose Quinsaat, Heinrich Hofmann, "Self-reparable Dielectric Elastomer Actuators"; Makromolekulares Kolloquium Freiburg, February 23 - 25, 2012, Freiburg, Germany. (oral) 2. D. M. Opris, S- Dünki, F. Nüesch, J. E. Q. Quinsaat, Y. Song Ko, S. Michel, C. Racles, M. Cazacu, "Dielectric elastomers put to work", SCS Fall Meeting 2013, September 6, 2013, Lausanne, Switzerland. (oral) 3. Dorina M. Opris, Jose Enrico Q. Quinsaat, Frank Nüesch, Heinrich Hofmann, Carmen Racles, Maria Cazacu, "Dielectric elastomer actuators", Makromolekulares Kolloquium Freiburg, 24-26 February, 2013, Freiburg, Germany. (poster) 4. Carmen Racles, Maria Cazacu, Dorina Opris- Silicone elastomers for actuationEuroEAP 2011: First international conference on Electromechanically Active Polymer (EAP) transducers & artificial muscles, Pisa, 8-9 June 2011. (poster) www.snf.ch www.uefiscdi.gov.ro 5. Carmen Racles, Maria Cazacu, Beatrice Fischer, Dorina M Opris -Synthesis and characterization of silicones containing cyanopropyl groups and their use in dielectric elastomer actuators; EuroEAP 2013: International conference on Electromechanically Active Polymer (EAP) transducers & artificial muscles, Dübendorf, 25-26 June 2013. (poster) 6. Carmen Racles, Maria Cazacu, Mihaela Alexandru, Adrian Bele, Valentina Musteata, Daniela Ionita, Stelian Vlad, Cristian Varganici, Florica Doroftei: Polimeri siliconici cu grupe polare pentru actuaţie, Zile Academice Iesene, 2-5 oct. 2013, Iasi. (poster) 7. Carmen Racles, Mihaela Alexandru, Valentina Musteata, Adrian Bele, Maria Cazacu: Tailoring the dielectric properties of silicones by chemical modification, The 13th International Balkan Workshop on Applied Physics, Constanta, 4-6 July 2013. (poster) 8. Carmen Racles, Mihaela Alexandru, Adrian Bele, Valentina Musteata, Maria Cazacu, Simon Dunki, Dorina M. Opris: New insights into tailoring dielectric properties of silicones by chemical modification –poster at EuroEAP 2014, Linköping, Sweden, 10-11 June 2014. (poster) www.snf.ch www.uefiscdi.gov.ro 9. Adrian Bele, Maria Cazacu, Mihaela Alexandru, Valentina Musteata, Dorina M. Opris, Carmen Racles: A dual strategy for improving the electromechanical properties of silicones, poster at EuroEAP 2014, Linköping, Sweden, 10-11 June 2014. (poster) 10. Carmen Racles, Maria Cazacu, Mihaela Alexandru, Adrian Bele, Valentina Musteata and Florica Doroftei: Composites from incompatible polymer pairs: silicone elastomers as disperse phase or matrix, ICCE-22, Malta, July 13-19, 2014. (oral) 11. Valentina E. Musteata, Carmen Racles, Maria Cazacu, Mihaela Alexandru, Adrian Bele, Dorina M. Opris: Polysiloxanes for dielectric actuators and their molecular dynamics, 8th International Symposium “Molecular Order and Mobility in Polymer Systems”, St. Petersburg, June 2-6, 2014. (poster) 12. Simon Dünki, Mihaela Alexandru, Adrian Bele, Maria Cazacu, Frank Nüesch, Dorina Opris, Carmen Racles: Influence of Polar Groups on the Dielectric Constant of Silicones, Macromolecular Colloquium, 26-28.02.2014, Freiburg, Germany. (poster) www.snf.ch www.uefiscdi.gov.ro 13. Carmen Racles, Mihaela Alexandru, Maria Cazacu, Adrian Bele, Simon Dünki, Dorina M. Opris: Polysiloxanes with γ-cyanopropyl groups: considerations on(co)hydrosilylation reactions and applications for dielectric elastomer transducers, PolyColl 2014 Annual Meeting of the Division of Polymers, Colloids and Interfaces, 20 June 2014, Dubendorf, Switzerland. (poster) www.snf.ch www.uefiscdi.gov.ro Useful links: http://www.swiss-contribution.admin.ch/romania/ http://p3.snf.ch/Project-142215 PROJECT CO-FINANCED BY A GRANT FROM SWITZERLAND THROUGH THE SWISS CONTRIBUTION TO THE ENLARGED EUROPEAN UNION www.snf.ch www.uefiscdi.gov.ro
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