ユミコア社・ソルビアス社製 触媒 Catalyst of Umicore・Solvias この度、弊社では下記Umicore社・Solvias社製の触媒の販売を開始いたしました。 ご愛顧賜りますよう宜しくお願い申し上げます。 【Umicore社】 CXシリーズ(クロスカップリング用パラジウム触媒) ・触媒調製用の配位子フリーPd触媒。 ・鈴木-宮浦カップリングやBuchwald-Hartwigアミノ化反応、Heck反応、熊田反応、ケトンのアリル化 反応など、Pd触媒を利用するカップリング反応に有用。 特徴 Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene]palladium(II) 49023-20 500 mg ¥14,600 Chlorophenylallyl[1,3-bis(2,6-diisopropylphenyl)2-imidazolidinylidene]palladium(II) 49023-22 500 mg [884879-23-6] [884879-24-7] Umicore No. 68 1844 4716 Umicore No. 30000 34527 CX32 CX31 Allylchloro[1,3-bis(2,6-diisopropylphenyl)imidazol2-ylidene]palladium(II) 49022-06 500 mg ¥14,600 Allylchloro[1,3-bis-(2,6-diisopropylphenyl)imidazol2-idinylidene]palladium(II) 49022-08 500 mg [478980-01-7] Umicore No. 68 1844 4018 Umicore No. 30000 34526 Dichloro(di-μ-chloro)bis[1,3-bis(2,6-diisopropylphenyl) imidazol-2-ylidene]dipalladium(II) 49022-76 Cl N Cl Pd Cl Pd Cl ¥14,600 [478980-03-9] CX21 N ¥14,600 500 mg ¥14,600 CX23 Allylchloro[1,3-bis-(2,4,6-trimethylphenyl)imidazol2-ylidene]palladium(II) 49022-10 500 mg ¥14,800 [444910-17-2] [478980-04-0] Umicore No. 68 1844 3519 Umicore No. 68 1844 4022 N N CX41 CX22 Bis(1,4-naphthoquinone)bis[1,3-bis(2,6-diisopropylphenyl) imidazole-2-ylidene]dipalladium(0) Bis(1,4-naphthoquinone)bis[1,3-bis(2,4,6-trimethylphenyl) imidazol-2-ylidene]dipalladium(0) 49023-14 500 mg ¥14,600 49023-16 500 mg ¥14,600 [649736-75-4] [467220-49-1] Umicore No. 68 1844 4016 Umicore No. 68 1844 4019 CX11 CX12 その他Umicore社製 化合物 Bis(η5-2,4-dimethylpentadienyl)ruthenium(II) 49022-44 500 mg (1,5-Cyclooctadiene)bis(2-methylallyl)ruthenium(II) ¥58,400 49022-56 500 mg ¥29,200 [85908-78-7] [12289-94-0] Umicore No. 68 1874 3834 Umicore No. 68 1874 2432 Ru Bis(1,5-cyclooctadiene)tetra[μ-trifluoroacetato] diruthenium(II) hydrate 49022-70 500 mg Di(μ-chloro)dichlorobis(benzene)diruthenium(II) ¥78,300 Umicore No. 68 1874 2423 Umicore No. 68 1874 3540 500 mg Di(μ-iodo)diiodobis(p-cymene)diruthenium(II) ¥3,600 BF4 500 mg ¥19,400 [90614-07-6] Umicore No. 68 1874 1310 Umicore No. 68 1874 2621 49023-56 N 49022-96 [15529-49-4] Trisacetonitrile(η5-2,4-dimethylpentadienyl) ruthenium(II) tetrafluoroborate N ¥15,600 [37366-09-9] 49022-94 N 500 mg [93582-31-1] Dichlorotris(triphenylphosphine)ruthenium(II) Ru 49022-74 500 mg Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate ¥71,400 49022-36 500 mg ¥28,200 [145271-55-2] [35138-22-8] Umicore No. 68 1874 3325 Umicore No. 68 1864 3025 Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate 49022-38 Bisnorbornadienerhodium(I) tetrafluoroborate 500 mg ¥18,400 49022-58 500 mg ¥26,400 [99326-34-8] [36620-11-8] Umicore No. 68 1864 3822 Umicore No. 68 1864 3627 Di(μ-chloro)dichlorobis(pentamethylcyclopentadiene) dirhodium(III) Di(μ-chloro)bis(norbornadiene)dirhodium(I) 49022-66 500 mg ¥13,200 49022-90 Cl [12257-42-0] Rh Umicore No. 30000 34546 Dichlorobis[di-tert-butyl(4-dimethylaminophenyl) phosphine]palladium(II) 49022-40 500 mg Cl 500 mg ¥18,000 [12354-85-7 ] Cl Rh Cl Umicore No. 68 1864 3033 Dichloro[1,1’-bis(di-tert-butylphosphino)ferrocene] palladium(II) ¥15,400 49022-42 500 mg ¥14,200 [887919-35-9] [95408-45-0] Umicore No. 68 1844 5415 Umicore No. 30000 34532 Dichloro[1,1’-bis(diphenylphosphino)ferrocene] palladium(II) 49022-78 500 mg Dichloro[1,1’-Bis(diphenylphosphino)ferrocene] palladium(II) acetone adduct ¥3,000 49022-80 500 mg ¥3,000 [72287-26-4] [851232-71-8] Umicore No. 68 1844 4114 Umicore No. 30000 36045 Dichloro[1,1’-Bis(diphenylphosphino)ferrocene] palladium(II) dichloromethane adduct 49022-82 500 mg Bis(tri-tert-butylphosphine)palladium(0) ¥3,000 49023-04 [95464-05-4] 500 mg ¥15,600 [53199-31-8] P Pd P Umicore No. 68 1844 4213 Dichlorobis[(di-tert-butyl)phenylphosphine] palladium(II) 49023-64 500 mg Umicore No. 30000 34529 Dichlorobis[(di-tert-butyl)(n-butyl)phosphine] palladium(II) ¥15,400 49023-65 500 mg ¥15,400 [34409-44-4] [1444507-24-7] Umicore No. 68 1844 5517 Umicore No. 30000 36046 Tris(dibenzylideneacetone)dipalladium(0) 49023-62 Bis(1,5-cyclooctadiene)iridium(I) tetrafluoroborate 500 mg ¥4,600 Umicore No. 30000 34523 Umicore No. 30000 34535 500 mg Di(μ-chloro)bis(1,5-cyclooctadiene)diiridium(I) ¥49,000 49022-64 ¥6,600 [12112-67-3] Umicore No. 68 1854 2015 Umicore No. 30000 34536 49023-06 500 mg Di(μ-iodo)diiodobis(pentamethylcyclopentadienyl) diiridium(III) ¥10,000 49023-08 I Cl Ir Ir Umicore No. 68 1854 3449 Cl 500 mg [666826-16-0] Di(μ-chloro)dichlorobis(pentamethylcyclopentadienyl) diiridium(III) Cl ¥50,600 [35138-23-9] 49022-34 Ir 500 mg [51364-51-3] Bis(1,5-cyclooctadiene)iridium(I) tetrakis[3,5-bis(trifluoromethyl)phenyl]borate Cl 49022-32 I I 500 mg ¥17,000 [33040-12-9 ] Ir I Umicore No. 68 1854 3533 Platinum(IV) oxide hydrate 49023-24 500 mg ¥24,600 [52785-06-5]/[1314-15-4] PtO2 Umicore No. 68 1832 2281 ※本リーフレットに記載されている製品以外にも弊社ではUmicore社製品(121品目)、Solvias社製品 (192品目)を取り扱っております。 詳細は、弊社営業所・支店までお問合わせ下さい。 【Solvias社】 化合物 (αR,αR)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(S,S)1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino] ferrocene 49019-26 O O ¥22,000 H O N H Fe Fe H N Solvias No. SL-M004-1 P 49019-30 O [494227-37-1] N P 100 mg (αS,αS)-2,2'-Bis(α-N,N-dimethylaminophenylmethyl)-(R,R)1,1'-bis[di(3,5-dimethyl-4-methoxyphenyl)phosphino] ferrocene Solvias No. SL-M004-2 (R,S) (S,R) O O O O 1,5-Cyclooctadiene{[dibenzyl((4R,5R)-5-methyl-2-phenyl-4,5dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite KN:KP} iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate 49019-60 100 mg 1,5-Cyclooctadiene{[dibenzyl((4S,5S)-5-methyl-2-phenyl-4,5dihydro-4-oxazolyl)methyl]dicyclohexylphosphinite KN:KP} iridium(I) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate ¥22,000 49019-62 [880262-14-6] O N (R,R) N 49019-82 100 mg Solvias No. SK-X001-2a P (S,S) (R)-1-[(S)-2-Di-tert-butylphosphino)ferrocenyl] ethyldi(2-methylphenyl)phosphine Ir(COD)(BARF) (S)-1-[(R)-2-Di-tert-butylphosphino)ferrocenyl] ethyldi(2-methylphenyl)phosphine ¥22,000 49019-84 [849924-76-1] Fe Solvias No. SL-J505-1 H CH3 ¥22,000 Solvias No. SL-J505-2 (S,R) (R,S) (R)-1-Dicyclohexylphosphino-2-[(R)-α-(N,N-dimethylamino)o-dicyclohexylphosphinophenyl)methyl]ferrocene 49019-94 100 mg (S)-1-Dicyclohexylphosphino-2-[(S)-α-(N,N-dimethylamino)o-dicyclohexylphosphinophenyl)methyl]ferrocene ¥22,000 49019-96 [1016985-24-2] 100 mg ¥22,000 [914089-00-2] P P Solvias No. SL-T002-1 H 100 mg [849924-77-2] P P Fe H3C H P P ¥22,000 O Solvias No. SK-X001-1a Ir(COD)(BARF) 100 mg [583844-38-6] O O P N ¥22,000 [849925-12-8] P N H P 100 mg Fe Solvias No. SL-T002-2 P P (R,R) 49020-16 CF3 H N (S,S) (R)-1-[(R)-2-(2'-Dicyclohexylphosphinophenyl)ferrocenyl] ethyldi(bis-(3,5-trifluoromethyl)phenyl)-phosphine F3C Fe 100 mg (S)-1-[(S)-2-(2'-Dicyclohexylphosphinophenyl)ferrocenyl] ethyldi(bis-(3,5-trifluoromethyl)phenyl)-phosphine ¥22,000 49020-18 F3C CF3 [494227-32-6] 100 mg ¥22,000 CF3 [849925-22-0] F3C P P Fe P CH3 H CF3 (R,R) Solvias No. SL-W008-1 P H3C F3C H (S,S) Fe Solvias No. SL-W008-2 (R)-1-[(S)-2-(Di-2-furylphosphino)-ferrocenyl] ethyldi-tert-butylphosphine 49020-24 P CH3 Fe ¥22,000 Solvias No. SL-J212-1 H O (R,S) 49020-42 H3CO P H3C Fe H 100 mg ¥22,000 P Solvias No. SL-J212-2 O (S)-(-)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) ¥22,000 P [133545-16-1] P Solvias No. SL-A101-1 49020-44 H3CO H3CO 100 mg ¥22,000 P [133545-17-2] P Solvias No. SL-A101-2 (S) (R) (R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl] ethyldicyclohexylphosphine ethanol adduct 49020-80 100 mg (S)-1-[(R)-2-(Diphenylphosphino)ferrocenyl] ethyldicyclohexylphosphine ethanol adduct ¥22,000 49020-82 [155806-35-2] P H H3C C2H5OH C2H5OH (R,S) (S,R) (R)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl] ethyldi(bis-3,5-trifluoromethylphenyl)phosphine 49020-88 CF3 CF3 F3C 100 mg Fe H ¥22,000 [387868-06-6] 49020-90 F3C CF3 F3C CH3 CF3 Solvias No. SL-W001-1 Chloro(di-2-norbornylphosphino) (2-dimethylaminomethylferrocen-1-yl)palladium (II) 49019-58 P F3C H3C Fe H Cl [849925-17-3] Solvias No. SL-W001-2 250 mg 2'-(Dimethylamino)-2-biphenylpalladium(II) chloride dinorbornylphosphine ¥12,100 49020-62 [614753-51-4] Pd ¥22,000 (S,S) (R,R) N 100 mg P P H Solvias No. SL-J001-2 P (S)-1-[(S)-2-(2'-Diphenylphosphinophenyl)ferrocenyl] ethyldi(bis-3,5-trifluoromethylphenyl)phosphine P Fe ¥22,000 [162291-02-3] Solvias No. SL-J001-1 CH3 Fe 100 mg P P Fe 100 mg [849924-42-1] O (S,R) (R)-(+)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis(diphenylphosphine) H3CO 49020-26 [849924-41-0] P O 100 mg (S)-1-[(R)-2-(Di-2-furylphosphino)-ferrocenyl] ethyldi-tert-butylphosphine 250 mg ¥12,100 [359803-53-5] PH PH Solvias No. SK-CC02-A Pd N Cl Solvias No. SK-CC01-A ※本リーフレットに記載されている製品以外にも弊社ではUmicore社製品(121品目)、Solvias社製品 (192品目)を取り扱っております。 詳細は、弊社営業所・支店までお問合わせ下さい。 【関連製品】 Buchwald 配位子 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl MeO 2-Dicyclohexylphosphino-2',4',6'-triisopropylbiphenyl 11049-55 5g ¥35,000 11051-55 5g ¥33,000 11049-65 1g ¥11,000 11051-65 1g ¥13,000 PCy2 OMe [564483-18-7] [657408-07-6] XPhos SPhos 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl 2-Dicyclohexylphosphino-2'-methylbiphenyl 11054-55 5g ¥74,000 11055-55 5g ¥52,000 11054-65 1g ¥16,000 11055-65 1g ¥12,000 [251320-86-2] [564483-19-8] tBuXPhos MePhos 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl 11057-55 5g ¥28,000 11057-65 1g ¥11,000 2-Dicyclohexylphosphino-3,6-dimethoxy-2',4',6'triisopropylbiphenyl MeO OMe 11058-65 1g ¥32,000 PCy2 11058-68 100 mg ¥8,500 [787618-22-8] [1070663-78-3] RuPhos BrettPhos 近日発売 2-(Di-tert-butylphosphino)biphenyl 2-Di-tert-butylphosphino-2'-(N,N-dimethylamino) biphenyl 11059-55 5g ¥48,000 11061-55 5g ¥65,000 11059-65 1g ¥11,000 11061-65 1g ¥17,000 [224311-49-3] [224311-51-7] JohnPhos tBuDavePhos 2-Di-tert-butylphosphino-3,4,5,6-tetramethyl-2',4',6'triisopropylbiphenyl 2-Di-tert-butylphosphino-2'-methylbiphenyl 11062-65 1g ¥19,000 11062-68 100 mg ¥8,000 [255837-19-5] tBuMePhos P(tBu)2 11063-65 1g ¥60,000 11063-68 100 mg ¥14,000 [857356-94-6] Me4tBuXPhos 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino) biphenyl 2-(Dicylohexylphosphino)biphenyl 11070-55 5g ¥41,000 11071-55 5g ¥60,000 11070-65 1g ¥11,000 11071-65 1g ¥16,000 PCy2 [213697-53-1] [247940-06-3] CyJohnPhos 2-Diphenylphosphino-2'-(N,N-dimethylamino)biphenyl DavePhos Sodium 2'-dicyclohexylphosphino-2,6-dimethoxybiphenyl-3-sulfonate hydrate 11075-55 5g ¥44,000 38010-65 1g ¥48,000 11075-65 1g ¥15,000 38010-68 100 mg ¥11,000 [240417-00-9] [1049726-96-6] SPhos-SO3Na PhDavePhos 製造元:日本化学工業株式会社 ◆MITの対象特許 当該製品に関しましては、下記の通り日本国内にて出願されております。 特願2000-559117, 特願2002-583366, 特願2005-508499, 特願2007-550475, 特願2008-276608 2015.01
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