CH-GATE-2015 PAPER| www.gateforum.com General Aptitude Questions Q.No-1-5 Carry One Mark Each 1. Choose the word most similar in meaning to the given word: Educe (A) Exert Answer: 2. (B) Educate (D) Extend (C) -25/49 (D) -49/25 (C) If logx (5/7) = -1/3, then the value of x is (A) 343/125 (B) 12/343 Answer: (C) Extract (A) 3 Exp: 5 7 7 = x −1 3 ⇒ = x1 3 ⇒ ⇒ x = 2.74 7 5 5 3. Operators , ◊ and → are defined by : a b = ( 66 6) , ( 66 ◊6) . (A) -2 Answer: Exp: (C) 1 (D) 2 (C) 666 = 66 (B) -1 a−b a+b ;a ◊ b = ;a → b = ab. Find the value a+b a−b 66 − 6 60 5 = = 66 + 6 72 6 6= 66 + 6 72 6 = = 66 − 6 60 5 5 6 (66 6)→(66 6) = × = 1 6 5 4. Choose the most appropriate word from the options given below to complete the following sentence. The principal presented the chief guest with a ____________, as token of appreciation. (A) momento Answer: (B) memento (C) momentum (D) moment (B) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 1 CH-GATE-2015 PAPER| 5. www.gateforum.com Choose the appropriate word/phrase, out of the four options given below, to complete the following sentence: Frogs ____________________. (A) Croak Answer: (B) Roar (C) Hiss (D) Patter (A) Exp: Frogs make ‘croak’ sound. 6. A cube of side 3 units is formed using a set of smaller cubes of side 1 unit. Find the proportion of the number of faces of the smaller cubes visible to those which are NOT visible. (A) 1 : 4 Answer: (B) 1 : 3 (C) 1 : 2 (D) 2 : 3 (C) Exp: 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 Number of faces per cube = 6 Total number of cubes = 9×3 = 27 ∴ Total number of faces = 27×6 = 162 ∴ Total number of non visible faces = 162-54 = 108 ∴ 7. Number of visible faces 54 1 = = Number of non visible faces 108 2 Fill in the missing value 1 6 5 4 7 4 7 2 9 2 8 1 4 1 5 2 3 1 2 1 3 3 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 2 CH-GATE-2015 PAPER| Answer: Exp: www.gateforum.com (3) Middle number is the average of the numbers on both sides. Average of 6 and 4 is 5 Average of (7+4) and (2+1) is 7 Average of (1+9+2) and (1+2+1) is 8 Average of (4+1) and (2+3) is 5 Therefore, Average of (3) and (3) is 3 8. Humpty Dumpty sits on a wall every day while having lunch. The wall sometimes breaks. A person sitting on the wall falls if the wall breaks. Which one of the statements below is logically valid and can be inferred from the above sentences? (A) Humpty Dumpty always falls having lunch (B) Humpty Dumpty does not fall sometimes while having lunch (C) Humpty Dumpty never falls during dinner (D) When Humpty Dumpty does not sit on the wall, the wall does not break Answer: (B) 9. The following question presents a sentence, part of which is underlined. Beneath the sentence you find four ways of phrasing the underlined part. Following the requirements of the standard written English, select the answer that produces the most effective sentence. Tuberculosis, together with its effects, ranks one of the leading causes of death in India. (A) ranks as one of the leading causes of death (B) rank as one of the leading causes of death (C) has the rank of one of the leading causes of death (D) are one of the leading causes of death Answer: (A) 10. Read the following paragraph and choose the correct statement. Climate change has reduced human security and threatened human well being. An ignored reality of human progress is that human security largely depends upon environmental security. But on the contrary, human progress seems contradictory to environmental security. To keep up both at the required level is a challenge to be addressed by one and all. One of the ways to curb the climate change may be suitable scientific innovations, while the other may be the Gandhian perspective on small scale progress with focus on sustainability. (A) Human progress and security are positively associated with environmental security. (B) Human progress is contradictory to environmental security. (C) Human security is contradictory to environmental security. (D) Human progress depends upon environmental security. Answer: (D) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 3 CH-GATE-2015 PAPER| www.gateforum.com Section Name: Chemical Engineering Q.No-1-25 Carry One Mark Each 1. Benzene is removed from air by absorbing it in a non-volatile wash-oil at 100kPa in a countercurrent gas absorber. Gas flow rate is 100 mol/min, which includes 2 mol/min of benzene. The flow rate of wash-oil is 50 mol/min.Vapour pressure of benzene at the column conditions is 50 kPa. Benzene forms an ideal solution with the wash-oil and the column is operating at steady state. Gas phase can be assumed to follow ideal gas law. Neglect the change in molar flow rates of liquid and gas phases inside the column.’ For this process, the value of the absorption factor (upto two decimal places) is _________. Answer: 1.02 Exp: Absorption factor A= liquid LS Ls mG S ( 50 mol min ) Given Raoult’s law is applicable for gas phase yP = xpsat ⇒ y × 100 = x × 50 ⇒ y = 0.5 x So, m = 0.5 A= Gas ( 100mol min ) 50 = 1.02 0.5 × 98 GS = 98mol min Benzene = 2mol min 2. The following set of three vectors 1 2, 1 x 3 6 and 4 x 2 is linearly dependent when x is equal to (A) 0 (B) 1 (C) 2 (D) 3 Answer: (D) Exp: For linearly dependent vectors A = 0 1 x 3 2 6 4 =0 1 x 2 ⇒ (12 − 4x ) − x ( 4 − 4 ) + 3 ( 2x − 6 ) = 0 ⇒ 2x = 6 ⇒ x =3 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 4 CH-GATE-2015 PAPER| 3. For which reaction order, the half-life of the reactant is half of the full lifetime (time for 100% conversion) of the reactant? (A) Zero order Answer: Exp: www.gateforum.com (B) Half order (C) First order (D) Second order (A) For zero order reaction − dC A = k C OA = k dt Where k = rate constant CAO − C A = kt For, full life time CA = 0 t = C AO K and for half life C A = C AO 2, So t1/ 2 = C AO 2k So, t = 2t1/2 4. Match the output signals as obtained from four measuring devices in response to a unit step I change in the input signal. Output signal time II P: Gas chromatograph, with a long capillary tube III Q : Venturi tube IV R : Thermocouple with first order dynamics S : Pressure transducer with second order dynamics (A) P-IV, Q-III, R-II, S-I (B) P-III, Q-I, R-II, S-IV (C) P-IV, Q-I, R-II, S-III (D) P-II, Q-IV, R-III, S-I Answer: Exp: (C) If y(t) = output (response) y(t) ( I ) Gas chromatograph ( II ) 1st order ( IV) Venturytube ( III ) 2nd order Gas chromatograph – IV time Ventury tube - I Thermocouple – II Pressure transducer with second order dynamics - III India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 5 CH-GATE-2015 PAPER| 5. Match the chemicals written on the left with the raw materials required to produce them mentioned on the right. (I) Single Superphosphate (SSP) (P) (II) Triple Superphosphate (TSP) (Q) Brine (III) Diammonium phosphate (DAP) (R) Rock Phosphate + Sulfuric Acid (IV) Caustic soda (S) Rock phosphate + phosphoric Acid Rock phosphate + Sulfuric Acid + Ammonia (A) I − Q, II − R, III − S, IV − P (B) I − S, II − P, III − Q, IV − R (C) I − R, II − S, III − P, IV − Q (D) I − S, II − R, III − P, IV − Qa Answer: Exp: www.gateforum.com (C) Single super phosphate (SSP) → Phosphate rock + H 2SO4 Triple super phosphate ( TSP ) → phosphate rock + H3 PO4 Diammonium phosphate (DAD) → Rock phosphate + H 2SO 4 + NH 3 Caustic soda → Brine 6. 4 3 For the matrix , if 3 4 Answer: Exp: 1 is an eigenvector, the corresponding eigenvalue is _______. 1 7 4 3 1 Let A = and x = 3 4 1 Let eigen value is λ So Ax = λx 1 0 or [ A − Iλ ][ x ] = 0, where I = 0 1 λ 0 So Ix = 0 λ 3 4 − λ ⇒ 4 − λ 3 4 − λ + 3 ⇒ =0 3 + 4 − λ 1 1 = 0 ⇒ λ=7 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 6 CH-GATE-2015 PAPER| 7. www.gateforum.com The transfer function for the disturbance response in an open-loop process is given by G open (s) . d The corresponding transfer function for the disturbance response in closed-loop feedback control system with proportional controller is given by G closed ( s ) . Select the option that is Always correct d {O G (S) represents order of transfer function G ( s )}: (A) O G open ( s ) = O G dclosed ( s ) d (B) O G open ( s ) ≠ O G dclosed ( s ) d (C) O G open ( s ) ≥ O G dclosed ( s ) d (D) O G open ( s ) ≤ O G dclosed ( s ) d Answer: (A) Exp: Open loop transfer function G OL = GH = G open (s) d x and closed loop transfer function G G CL = = G dclosed ( s ) 1 + GH Order of transfer function is order of denominator Order of GH and 1 + GH are same G y H so, O G open ( s ) = O G d closed ( s ) d 8. If v,u, s and g represent respectively the molar volume, molar internal energy, molar entropy and molar Gibbs free energy, then match the entries in the left and right columns below and choose the correct option. (P) − ( ∂u ∂v ) s ( Q ) ( ∂g ∂P ) T ( R ) − ( ∂g ( S ) ( ∂u ∂T ) P ∂s ) V ( I) Temperature ( II ) Pr essure ( III ) V ( IV ) S (A) P − II, Q − III, R − IV, S − I (B) P − II, Q − IV, R − III, S − I (C) P − I, Q − IV, R − II, S − III (D) P − III, Q − II, R − IV, S − I Answer: (A) Exp: We have du = Tds − pdv and dg = vdp − sdT So, ∂u ∂u = −P ⇒ − =P ∂v S ∂v S ∂u ∂s =T V ∂g ∂g = V and − =S ∂p T ∂T P India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 7 CH-GATE-2015 PAPER| www.gateforum.com 9. Two different liquids are flowing through different pipes of the same diameter. In the first pipe, the flow is laminar with centerline velocity, Vmax .1 , Whereas in the second pipe, the flow is turbulent. For turbulent flow, the average velocity is 0.82 times the centerline velocity, Vmax .2 . For equal volumetric flow rates in both the pipes, the ratio Vmax .1 Vmax .2 (up to two decimal places) is ______. Answer: 1.64 Exp: For laminar flow Vavg.1 = 0.5Vmax.1 For Turbulent flow Vavg.2 = 0.82 Vmax .2 ( given ) Since volumetric flow rate is some Q1 = Q 2 A1Vavg.1 = A 2 Vavg.2 Given A 1 = A 2 So, Vavg.1 = Vavg.2 ⇒ 0.5 Vmax .1 = 0.82 Vmax .2 ⇒ Vmax .1 = 1.64 Vmax .2 dy + p ( x ) y = r ( x ) . Functions p ( x ) and r ( x ) are dx defined and have a continuous first derivative. The integrating factor of this equation is non-zero. Multiplying this equation by its integrating factor converts this into a: (A) Homogeneous differential equation (B) Non-linear differential equation (C) Second order differential equation (D) Exact differential equation Answer: (D) Exp: Linear differential equation 10. Consider linear ordinary differential equation y1 + p ( x ) y = r ( x ) Multiplying above equation by integrating factor e ∫ p ( x ) dx makes the equation exact A spherical naphthalene ball of 2mm diameter is subliming very slowly in stagnant air at 25OC. The change in the size of the ball during the sublimation can be neglected. The diffusivity of naphthalene in air at 25o C is 1.1×10-6 m2/s. The value of mass transfer coefficient is B × 10-3 m/s, where B (up to one decimal place) is _______. Answer: 1.1 Exp: For spherical ball Dimensionless sherwood number = 2 kCL =2 D AB 11. India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 8 CH-GATE-2015 PAPER| www.gateforum.com Where L = characteristic length = diameter of Spherical ball = d = 2 mm = 2 × 10−3 m 2 × D AB 2 × 1.1 × 10−6 = d 2 × 10−3 K C = 1.1 × 10−3 m s KC = So, B = 1.1 12. An irreversible, homogeneous reaction A → products, has the rate expression: Rate = 2C2A + 0.1CA , where CA is the concentration of A. 1 + 50CA CA varies in the range 0.5 – 50 mol/m3. For very high concentration of A, the reaction order tends to: (A) 0 Answer: Exp: (B) 1 (C) 1.5 (D) 2 (B) Rate = 2CA 2 + 0.1CA 1 + 50CA 0.5 < C A < 50 ( mol m3 ) For very high value of CA ( say 50 mol m 3 ) 0.1CA << 2C2A and 50C A >> 1 So, rate = 2C2A 1 = CA 50CA 25 So reaction order is one 13. A scalar function in the xy-plane is given by φ ( x, y ) = x 2 + y 2 . if ˆi amd ˆj are unit vectors in the x and y directions, the direction of maximum increase in the value of φ at (1,1) is along: (A) −2iˆ + 2jˆ Answer: Exp: (B) 2iˆ + 2jˆ (C) − 2iˆ − 2jˆ (D) 2iˆ − 2jˆ (B) Direction of maximum increase = ∇ φ at (1.1) ( ) = ( 2iˆ + 2ˆj) = 2x ˆi + 2yjˆ at (1.1) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 9 CH-GATE-2015 PAPER| 14. For a gas phase cracking reaction A → B + C at 300OC, the Gibbs free energy of the reaction at this temperature is ∆G O = − 2750J mol. The pressure is 1 bar and the gas phase can be assumed to be ideal. The universal gas constant R = 8.314J/mol. K. The fractional molar conversion of A at equilibrium is: (A) 0.44 Answer: Exp: www.gateforum.com (B) 0.50 (C) 0.64 (D) 0.80 (D) A →B+C at t = 0, ⊥ 0 0 at t = t 1 − α α α where, α = fraction converted Equilibrium constant KP = YB YC .P YA α α α2 α2 1 + α 1 + α = = .P = 1 − α2 1 − α2 1− α 1+ x Also ln k = −∆G O RT −∆G O K = exp : exp RT K = 1.78 2750 8.314 × 573 α2 = 1.78 1 − α2 α = 0.80 so, 15. Two infinitely large parallel plates (I and II) are held at temperatures TI and TII ( T1 > TII ) respectively, and placed at a distance 2d apart in vacuum. An infinitely large flat radiation shield (III) is placed in parallel in between I and II. The emissivities of all the plates are equal. The ratio of the steady state radiative heat fluxes with and without the shield is: I III T1 (A) 0.5 II TI1 (B) 0.75 (C) 0.25 (D) 0 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 10 CH-GATE-2015 PAPER| Answer: Exp: www.gateforum.com (A) 4 4 Q12 σ ( T1 − T2 ) = We have 1 1 A + −1 ε ε Where ε = emissivity 4 4 Q12 σ ( T1 − T2 ) = 2 A −1 ε (i ) ( iii ) T1 T3 ( ii ) T2 In presence of shield 4 4 4 4 Q13 Q 23 σ ( T1 − T3 ) σ ( T3 − T2 ) = = = 2 2 A A −1 −1 ε ε T 4 + T24 or T34 = 1 2 ( 4 4 T14 − ( T14 + T24 ) 2 Q13 σ ( T1 − T3 ) = =σ So, 2 2 A −1 −1 ε ε 1 Q12 = 2 A Q13 1 = So, Q12 2 16. A cylindrical packed bed of height 1 m is filled with equal sized spherical particles. The particles are nonporous and have a density of 1500 kg/m3. The void fraction of the bed is 0.45. The bed is fluidized using air (density 1kg/m3). If the acceleration due to gravity is 9.8m/s2, the pressure drop (in pa) across the bed at incipient fluidization (up to one decimal place ) is _________. Answer: Exp: ) 8079.61 For incipient fluidization ∆P = g (1 − ε )( ρ P − ρ ) L Where ε = 0.45 ρP =1500 kg m 3 ρ = 1kg m 3 And L = 1m (height of the bed) ∆P = 9.8 × (1 − 0.45 )(1500 − 1) × 1 = 8079.61Pa India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 11 CH-GATE-2015 PAPER| 17. For a pure liquid, the rate of change of vapour pressure with temperature is 0.1 bar/K in the temperature range of 300 to 350 K. if the boiling point of the liquid at 2 bar is 320 K, the temperature (in K) at which it will boil at 1 bar (up to one decimal place) is ___________. Answer: Exp: www.gateforum.com 310 Given dP = 0.1⇒ dp = 0.1dT dT ⇒ P = 0.1T + C........... (1) Given at T = 320K. P = 2bar 2 = 0.1× 320 + C ⇒ C = −30 Equation (1) becomes P = − 30 + 0.1T Putting P = 1 bar 1 = −30 + 0.1T ⇒ T = 310 K 18. For uniform laminar flow over a flat plate, the thickness of the boundary layer, δ, at a distance x from the leading edge of the plate follows the relation: (A) δ ( x ) α x −1 Answer: Exp: (B) δ ( x ) α x (C) δ ( x ) α x1 2 (D) δ ( x ) α x −1 2 (C) For laminar flow Boundary layer thickness 8( x ) = 4.99 x Re Or, δ ( x ) α x 19. 1 = 4.99x ρVx µ 2 Match the polymer mentioned on the left with the catalyst used for it manufacture given on the right. (I) Low density Polyethylene (P) Ziegler-Natta catalyst (II) High density Polyethylene (Q) Traces of Oxygen (III) Polyethylene Terephthalate (R) Butyl Lithium (IV) Polyvinyl Chloride (S) Antimony (A) I − Q, II − R, III − S, IV − P (B) I − S, II − P, III − Q, IV − R (C) I − Q, II − P, III − S, IV − R (D) I − S, II − R, III − P, IV − Q India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 12 CH-GATE-2015 PAPER| Answer: www.gateforum.com (C) Exp: 20. LDPE Traces of oxygen HDPE Zeigler – Natta catalyst PET Antimony PVC Butyl Lithium Three identical closed systems of a pure gas are taken from an initial temperature and pressure ( TL , P1 ) to a final state ( T2 , P2 ) , each by a different path. Which of the following in Always true for the three systems? ( ∆ represents the change between the initial and final states: U, S, G, Q and W are internal energy, entropy, Gibbs free energy, heat added and work done, respectively.) (A) ∆U, ∆S, Q are same (B) W, ∆U, ∆G are same (C) ∆S, W, Q are same (D) ∆G, ∆U, ∆S are same Answer: (D) Exp: U,S and G are state variables (point function) so, ∆U, ∆S and ∆G Remain same between two states 1 and 2. ( P1 . T1 ) P 1 2 ( P2 . T2 ) T 21. Identify the WRONG statement amongst the following: (A) Steam distillation is used for mixtures that re immiscible with water. (B) Vacuum distillation is used for mixtures that are miscible with water. (C) Steam distillation is used for mixtures that are miscible with water. (D) Vacuum distillation columns have larger diameters as compared to atmospheric columns for the same throughout. Answer: (C) Exp: Steam distillation is used for the mixture immiscible with water. Option (C) is the wrong statement India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 13 CH-GATE-2015 PAPER| 22. For a binary mixture of components A and B, NA and NB denote the total molar fluxes of components A and B, respectively. JA and JB are the corresponding molar diffusive fluxes. Which of the following is true for equimolar counter-diffusion in the binary mixture? (A) N A + N B = 0 and J A + J B ≠ 0 (B) N A + N B ≠ 0 and J A + J B = 0 (C) N A + N B ≠ 0 and J A + J B ≠ 0 (D) N A + N B = 0 and J A + J B = 0 Answer: 23. www.gateforum.com (A) A complex-valued function, f(z), given below is analytic domain D: f ( z ) = u ( x, y ) + iv ( x, y ) z = x + fy Which of the following is NOT correct? (A) df ∂v ∂u = +i dz ∂y ∂y (B) df ∂u ∂v = +i dz ∂x ∂x (C) df ∂v ∂u = −i dz ∂y ∂y (D) df ∂v ∂v = +i dz ∂y ∂x Answer: Exp: (A) f ( z ) = u ( x, y ) + iv ( x, y ) f '( z ) = df ∂u ∂v ∂v ∂u ∂v = +i = = +i dz ∂x ∂x ∂x ∂y ∂y - (i) For analytic function ∂u ∂ υ ∂u −∂v = and = ∂x ∂y ∂y ∂x So, equation ( i ) can be written as df ∂υ ∂v ∂v ∂u ∂u ∂v = +i = −i = +i dz ∂y ∂x ∂y ∂y ∂x ∂x Only option (A) can not be deduced 24. Which of the following can change if only the catalyst is changed for a reaction system? (A) Enthalpy of reaction (B) Activation energy (C) Free energy of the reaction (D) Equilibrium constant Answer: Exp: (B) Catalyst changes the activation energy of the reaction India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 14 CH-GATE-2015 PAPER| 25. www.gateforum.com Match the technologies in Group 1 with the entries in Group 2: Group – 1 Group 2 (P) Urea manufacture (I) Microencapsulation (Q) Coal gasification (II) Ultra-low sulphur diesel (R) Controlled release of chemicals (III) Shale oil (S) Deep hydrodesulphurization (IV) Prilling tower (V) Gas hydrates (VI) Gas – solid non-catalytic reaction (A) (C) Answer: Exp: P − I, Q − V, R − II, S − VI (B) P − IV, Q − I, R − III, S − II P − IV, Q − VI, R − I, S − II (D) P − V, Q − VI, R − IV, S − II (B) P : Urea manufacture → IV prilling tower Q : coal gasification → VI Gas solid non − catalytic reaction R : controlled release of chemical → I :micron capsulation. S : Deep hydrodesulphurization → II ultra low sulphur diesel. Q.No-26-55 Carry Two Marks Each 26. Consider a solid block of unit thickness for which the thermal conductivity decreases with an increase in temperature. The opposite faces of the block are maintained at constant but different temperatures: T(x = 0) > T(x = 1). Heat transfer is by steady state conduction in x-direction only. There is no source or sink of heat inside the block. In the figure below, identify the correct temperature profile in the block. T ( x = 0) I II T III T ( x = 1) 0 (A) I IV x (B) II 1 (C) III (D) IV India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 15 CH-GATE-2015 PAPER| Answer: Exp: www.gateforum.com (C) Let T ( x = 0 ) T1 and T ( x = 1) = T2 we have from Fourier’s law q dT =− k A dx At steady state conduction T1>T2 −k dT q = const = dx A ⇒ q dx = − kdT A ____(1) Here K is decreasing with temperature Let K = K O (1 − αT ) ⇒ T q x dx = − ∫ − k o (1 − αT ) dT ∫ T1 A 0 q α x = − k O ( T + T1 ) + ( T 2 − T12 ) A 2 ____(11) Similarly integrating equation (1) between x = 0 & x = 1 x =1 q A ∫ ⇒ q α (1) = − k o ( T2 − T1 ) + ( T22 − T12 ) − − − (iii) A 2 x =0 dx = ∫ − k O (1 − αT ) dT T2 T1 Dividing equation (ii) and (iii) α ( T 2 − T12 ) − 2k o ( T − T1 ) = x {αT22 − T12 } − 2k 0 ( T2 − T1 ) From the above expression for temperature profile it is clear that the temp passes through a minima India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 16 CH-GATE-2015 PAPER| 27. www.gateforum.com The schematic diagram of a steady state process is shown below. The fresh feed (F) to the reactor consists of 96 mol% reactant A and 4 mol% inert I. The stoichiometry of the reaction is A → C . A part of the reactor effluent is recycled. The molar flow rate of the recycle stream is 0.3F. The product stream P contains 50 mol% C. The percentage conversion of A in the reactor based on A entering the reactor at point 1 in the figure (up to one decimal place) is ________. 0.3F 1 F Answer: Exp: A C P 59.19 Basis: - 0.3F 100 mole of feed F A in feed = 96 mol Inert in feed = 4mol Recycle = 0.3F = 30 mole (1) F A→C Product (P) Contains 50%C ( 2) P At steady state F = P = 100 mole Product Contains 50 mole C Product must also contain 4% inert At point (2) total molar flow rate =100 + 30 = 130mole 50 mole C Product stream P is 46 mole A 4 mole C 15 mole C Recycle stream R is 13.8 mole A 1.2 mole I Conversion of A in the reactor = = A converted int o C at po int ( 2 ) A fed at point A 65 × 100 = 59.19% ( 96 + 13.8) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 17 CH-GATE-2015 PAPER| 28. www.gateforum.com The impulse response to a tracer pulse experiment for a flow reactor is given below: t ( min ) 6.0 C ( mol 1) 4.0 2.0 0.0 0.0 2.0 6.0 4.0 In the above figure, c is the exit tracer concentration. The corresponding E or E θ (normalized E) curve is correctly represented by which of the following choices? Here, θ is dimensionless time. (A) E 1 ( min −1 ) 0.30 (C) 2.0 4.0 t ( min ) θ (− ) 1.00 1.0 θ( −) 3.0 2.0 (D) 6.00 0.40 E 1 ( min 0.20 0.00 0.0 2.00 0.00 0.0 6.0 0.60 E 1 ( min −1 ) 29. E 0.10 0.00 0.0 Answer: (B) 0.30 2.0 4.0 t ( min ) 6.0 −1 ) 4.00 2.00 0.00 0.0 6.0 2.0 4.0 t ( min ) (C) Consider a steady state mass transfer process between well-mixed liquid and vapour phases of a binary mixture comprising of components A and B. The mole fractions of component A in the bulk liquid (xA) and bulk vapour ( y A ) phases are 0.36 and 0.16, respectively. The mass transfer coefficients for component A in liquid and vapour phases are 0.1 mol/(m2.s) and 0.05 mol/(m2.s), respectively. The vapour-liquid equilibrium can be approximated as y*A = 2x A for x A less than 0.4. The mole fraction of A in the liquid at the interface (up to two decimal places) is Answer: 0.08 Exp: Given x A = 0.36 y A = 0.16 k L = 0.1mol m 2 sec k g = 0.05mol m 2s y*A = 2x A for x A < 0.4 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 18 CH-GATE-2015 PAPER| www.gateforum.com So y Ai = 2x A ……….(i) At steady state, mass flux is constant k L ( x A − x Ai ) = k g ( y Ai − y A ) 0.1( 0.36 − x Ai ) = 0.05 ( 2x A − 0.16 ) 0.11( 0.36 − x Ai ) = 0.05 ( 2 × 0.36 − 0.16 ) ⇒ x Ai = 0.08 30. A heated solid copper sphere (of surface area A and volume V) is immersed in a large body of cold fluid. Assume the resistance to heat transfer inside the sphere to be negligible and heat transfer coefficient (h), density ( ρ ) , heat capacity (C), and thermal conductivity (k) to be constant. Then, at time t, the temperature difference between the sphere and the fluid is proportional to: h (A) exp − A t ρVC ρVC t (B) exp − hA 4πk (C) exp − t ρCA ρCA (D) exp − t 4πk Answer: Exp: (A) T = f(time) Let apply first law of thermodynamics. If at any instant of time T. if T is body temperature then. hA ( T∞ − T ) = ρ C P V dT dt Where CP = heat capacity of the body T t dT hA ∫T T∞ − T = ∫0 ρVCP dt 0 ⇒ ln T − T∞ hA =− t To − T∞ ρVC P −hA ⇒ T − T∞ = e t ρVC An ideal gas is initially at a pressure of 0.1 MPa and a total volume of 2m3. It is first compressed to 1MPa by a reversible adiabatic process and then cooled at constant pressure to a final volume of 0.2m3. The total work done (in kJ) on the gas for the entire process (up to one decimal place) is ____________ Data: R = 8.314 J/molK; heat capacity at constant pressure (CP) = 2.5R Answer: 750 Exp: 1 → 2 : Re versible adiabatic process 31. 2 → 3 : Re versible isobaric process India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 19 CH-GATE-2015 PAPER| www.gateforum.com Given P1 = 0.1MPa =105 Pa V1 = 2m3 3 P P2 = 10 Pa = P3 6 2 V3 = 0.2 m 3 CP = 2.5R So CV = 1.5R 2.5 =1.667 1.5 For process 1 – 2: P1V1γ = P2 V2γ γ = CP CV = 1 P γ 105 V2 = 1 .V1 = 2 × 6 10 P2 ⇒ V2 = 0.50 m 2 V 1 1.667 Work done on gas for process 1 – 2 W1− 2 = P1V1 − P2 V2 0.1 × 106 × 2 − 106 × 0.5 = γ −1 0.667 ⇒ W1− 2 = −450kJ Work done for process 2 – 3 W2− 3 = P∆V =106 × ( 0.2 − 0.5 ) = − 300kJ Net work done = 450 + 350 = 750kJ A centrifugal pump delivers water at the rate of 0.22 m3/s from a reservoir at ground level to another reservoir at a height H, through a vertical pipe of 0.2m diameter. Both the reservoirs are open to atmosphere. The power input to the pump is 90 kW and it operates with an efficiency of 75%. Data: Fanning friction factor for pipe flow is f = 0.004. Neglect other head losses Take gravitational acceleration, g = 9.8 m/s2 and density of water is 1000kg/m3. The height H, in meters, to which the water can be delivered (up to one decimal place) is _______. Answer: 36 Exp: Given Q = 0.22 m 2 sec 32. V2 = 0.22 π 2 × ( 0.2 ) 4 W = 90 kW = 7m sec W in head unit = 90 × 103 ρQg Applying Bernaulli’s equation between (1) and (2) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 20 CH-GATE-2015 PAPER| www.gateforum.com ρ1 v2 z1 + 1 + hf + ηw ρg 2g = ρ2 V2 + z 2 + 2 − − − (1) ρg 2g and Z2 = H hf = 4fHV 2 4 × 0.004 × H × 7 2 = = 0.2 H m 2gD 2 × 9.8 × 0.2 90 × 103 49 =H+ 0.22 × 1000 × 9.8 2 × 9.8 ⇒ 0.2H + 31.308 = H + 2.5 (1) ⇒ 0.2 H + 0.75 × ⇒ 0.8H = 28.808 H = 36.01m So, H = 36m 33. A multi-stage, counter-current liquid-liquid extractor is used to separate solute C from a binary mixture (F) of A and C using solvent B. Pure Solvent B is recovered from the raffinate R by distillation, as shown in the schematic diagram below: F R P extractor distillation E B B Locations of different mixtures for this process are indicated on the triangular diagram below. P is the solvent-free raffinate, E is the extract, F is the feed and ∆ is the difference point from which the mass balance lines originate. The line PB interects the binodal curve at U and T. The lines P∆ and FB intersect the bimodal at V and W respectively. C F E P V U ∆ A B The raffinate coming out of extractor is represented in the diagram by the point: (A) T Answer: (B) U (C) V (D) W (B) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 21 CH-GATE-2015 PAPER| 34. www.gateforum.com The solution of the non-linear equation x 3 − x = 0 is to be obtained using Newton-Raphson method. If the initial guess is x = 0.5, the method converges to which one of the following values: (A) -1 (B) 0 (C) 1 (D) 2 Answer: (A) Exp: f ( x ) = x 3 − x, f ' ( x ) = 3x 2 − 1 Initial guess = 0.5 = x0 First iteration x1 = x 0 − f ( x0 ) f '( x 0 ) ( 0.5) − 0.5 = 0.5 − ( −0.375) ⇒ x1 = 0.5 − 2 ( −0.25) 3 ( 0.5 ) − 1 3 ⇒ x1 = −1 Solution to above equations are 0.1, - 1 but after first iteration it is converging to – 1 35. An isothermal steady state mixed flow reactor (CSTR) of 1m3 volume is used to carry out the first order liquid-phase reaction A → products. Fresh feed at a volumetric flow rate of Q containing reactant A at a concentration CA0 mixes with the recycle steam at a volumetric flow rate RQ as shown in the figure below. Q = 0.5m 3 min C A0 = 1mol m 3 Q = 0.5m 3 min C X A A = C = X A f A f RQ It is observed that when the recycle ratio R = 0.5, the exit conversion X Af = 50% When the recycle ratio is increased to R = 2, the new exit conversion (in percent) will be: (A) 50.0 (B) 54.3 (C) 58.7 (D) 63.2 Answer: (A) Q Exp: Mole balance Input – Output disappearance = Accum. CA0 = 1mol m3 At steady state, Q ( QCA0 + RQCA ) − ( RQ + Q ) CA = kCA V ⇒ QC A 0 − QC A = kC A V RQ CA = CAf x A = x Af India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 22 CH-GATE-2015 PAPER| www.gateforum.com ⇒ CA 0 − C A = kC A τ or τ = C A0 − C A kC A0 (1 − x ) or τ = xA x ⇒ τk = A k (1 − x A ) 1− xA τk 1 + τk So, conversion xA is independent of Recycle ratio R So final conversion = 50% Or , x A = 36. A typical batch filtration cycle consists of filtration followed by washing, One such filtration unit operating at constant pressure difference first filters a slurry during which 5 liters of filtrate is collected in 100 s. This is followed by washing. Which is done for tw seconds and uses 1 liter of wash water. Assume the following relation to be applicable between the applied pressure drop ∆P , cake thickness L at time t, and volume of liquid V collected in time t. ∆P dv = k1 ; L = k 2 V, if L is changing L dt k1 and k 2 can be taken to be constant during filtration and washing. The wash time tw, in seconds (up to one decimal place) is __________ Answer: 40 ∆P dV Exp: Given = k1 and L = k 2 V L dt so dv 1 ∆P = dt k1 k 2 V 5 ⇒ ∫ vdv = 0 ∆P k1k 2 ∫ 100 0 ⇒ ∆P 25 = × 100 2 K1 K 2 or ∆P 1 = k1k 2 8 dt Also, Final rate of filtration dV ∆P 1 = =1 = 8 × 5 dt k1k 2 V 40 washing time t w = tw = volume of wash water used finalrate of filtration 1 = 40sec 1 40 ( ) India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 23 CH-GATE-2015 PAPER| www.gateforum.com 37. Which one of the following transfer functions, upon a unit step change in disturbance at t = 0, will show a stable time domain response with a negative initial slope (i.e., slope at t = 0): 1 2 1 2 (A) G ( s ) = (B) G ( s ) = − + s +1 s + 4 s +1 s + 4 1 2 1 2 (D) G ( s ) = (C) G ( s ) = + + s +1 s − 4 s −1 s − 4 Answer: (A) 1 2 Exp: From option (A) G ( s ) = − s +1 s + 4 so y ( s ) = 1 1 2 − s s +1 s + 4 d {sy ( s )} = dy = e − t − 2e −4t dt dy = −1 dt z = 0 So (A) has –ve initial slope 38. Given that molar residual Gibbs free energy, g R , and molar residual volume VR, are related as R p v gR R O =∫ dP, find g at T = 27 C and P = 0.2 MPa. The gas may be assumed to follow the 0 RT RT viral equation of state, Z=1+BP/RT,where B= -10-4 m3/mol at the given conditions (R = 8.314J/mol.K). The value of gR in J/mol is: (A) 0.08 (B) −2.4 (C) 20 (D) −20 Answer: Exp: (D) Given R PV gR =∫ dP Rt 0 RT We know, V R = V − V ig = or ZRT RT RT − = ( Z − 1) P P P V R ( Z − 1) = RT P And Z = 1 + So, ( Z − 1) = B BP ⇒ RT P RT P B gR =∫ dP 0 RT RT g R = B ( P − 0 ) = −10−4 m3 × 0.2 × 106 Pa mol g R = −20 J mol India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 24 CH-GATE-2015 PAPER| 39. www.gateforum.com A spherical solid particle of 1mm diameter is falling with a downward velocity of 1.7mm/s through a liquid (viscosity 0.04 Pa.s) at a low Reynolds number (Strokes regime). The liquid is flowing upward at a velocity of 1 mm/s. All velocities are with respect to a stationary reference frame. Neglecting the wall effects, the drag force per unit projected area of the particle, in Pa, (up to two decimal places) is _________ 1.7 mm s 1mm s 40. In the figure below, the temperature profiles of cold and hot fluids in counter current double pipe heat exchanges (in different mode of operation) are shown on the left. For each case, match the heat exchange process for the fluid represented by the bold curve with the options given on the right. ( I) (P) Heating of sub − cooled feed to sup er heated vapour Temperature Dis tan ce ( II ) (Q) Condensation of sup er heated vapour (R ) Boiling of sub − cooled liquid Temperature Dis tan ce ( III ) Temperature Dis tan ce ( IV ) ( S) Condensation of Saturated vapour followed by sub − cooling Temperature Dis tan ce India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 25 CH-GATE-2015 PAPER| (A) I − P, II − Q, III − R, IV − S (B) I − P, II − Q, III − S, IV − R (C) I − Q, II − P, III − S, IV − R (D) I − Q, II − S, III − P, IV − R Answer: Exp: www.gateforum.com (C) (P) Heating of sub cooled feed to super heated vapour ( 3) (1) ( 2) (1) Sub cooled to saturated (2) Saturated up to boiling point (3) Saturated to superheat (Q) Condensation of superheated vapour. (1) ( 2) (1) Cooling of superheated vapour to saturated vapour (2) Condensation of saturated vapour to liquid. (R) Boiling of sub-cooled liquid (1) ( 2) ( 2) (1) (1) Heating of sub cooled liquid to saturated liquid (2) Boiling of saturated liquid (S). Condensation of saturated vapour followed by sub-cooling (1) ( 2) (1) Condensation of saturated vapour to saturated liquid (2) Sub cooling of saturated liquid. India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 26 CH-GATE-2015 PAPER| 41. www.gateforum.com The block diagram for a process with feedback control for output deviation variable h is shown in the figure below. All transfer functions are given with pre-factor of s in minutes. A unit step change is made in the set-point at t = 0. The time required for h to reach 50% of its ultimate value, in minutes (up to two decimal places), is: _____________. 1 Gd (s ) = 0.5s h sp ( s ) G c ( s ) = 0.5s + Gf (s ) = 0.2 1.5s + 1 Gp (s) = h (s) 1 0.5s G m (s) = 1 Answer: Exp: 0.8664 We have by making G d ( s ) = 0 (no load disturbance) 0.2 0.2 = 1.5s + 1 = 0.2 h sp ( s ) + 1 1.2 + 1.5s 1.5s + 1 h (s) Given h sp ( s ) = 1 s 1 0.2 A B So, h sp ( s ) = . = + s 1.5s + 1.2 S 1.5S + 1.2 1 −1 A = . and B = 6 4 1 1 1 So, h(s) = − . 6s 4 1.5s + 1.2 Taking inverse laplace transformation h (t) = 1 1 −0.8t − e 6 6 Ultimate value = h (∞ ) = 1 6 Let t = time required to reach 50% of ultimate value 1 1 1 −0.8t −1 −1 −0.8t = − e ⇒ = e 12 6 6 12 6 0.693 ⇒ e −0.8t = + 1 ⇒ t = = 0.8664sec 2 0.8 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 27 CH-GATE-2015 PAPER| www.gateforum.com 42. Adsorption on activated carbon is to be used for reducing phenol concentration in wastewater from 0.04 mol/1 to 0.008mol/1. The adsorption isotherm at the operating temperature can be expressed as q = 0.025C1/3; where q is the phenol concentration in solid (mol/g solid) and C is the phenol concentration in water (mol/1). The minimum amount of solid (in grams) required per liter of wastewater (up to one decimal place) is ______________________ 43. Consider a control system with the open loop transfer function given by: K e e −0.3c 1.5s + 1 In the above function, pre-factor of s is in minutes and KC is the gain of proportional controller. G OL ( s ) = The frequency for phase margin of 30O is 40.04rad/min. The value of KC for a gain margin of 1.7 (up to one decimal place) is _______ Answer: 44. 5.019 For complex variable Z, the value of the contour integral 1 2πi e −2z ∫c z ( z − 3) dz along the clockwise contour C: z = 2 ( up to two decimal places ) is __________ Answer: Exp: 1 2πi -0.33 e −2z ∫c z ( z − 3) C: z = 2 − 2 < z < 2 Poles are z = 0.3 Z = 3 is outside the countour C R (o) = e −2×0 1 = − = −0.33 ( 0 − 3) 3 Value of integral = -0.33 45. A proposed chemical plant is estimated to have a fixed capital (FC) of Rs. 24 crores. Assuming other costs to be small, the total investment may be taken to be same as FC. After commissioning (at t = 0 years), the annual profit before tax is Rs.10 crores/year (at the end of each year) and the expected life of the plant is 10 years. The tax rate is 40% per year and a linear depreciation is allowed at 10% per year. The salvage value is zero. If the annual interest rate is 12% the NPV (net present value or worth) of the project in crores of rupees (up to one decimal place) is _______. India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 28 CH-GATE-2015 PAPER| 46. www.gateforum.com For fanning friction factor f (for flow in pipes) and drag coefficient CD(for flow over immersed bodies), which of the following statements are true? P: f accounts only for the skin friction Q: CD accounts only for the form friction R: CD accounts for both skin friction and form friction S: Both f and CD depend on the Reynolds number T: For laminar flow through a pipe, f doubles on doubling the volumetric flow rate. (A) R,S,T Answer: Exp: (B) P,Q,S (C) P,R,S (D) P,Q,S,T (C) Correct Statements are P : f accounts only for the skin friction R : CD accounts for both skin friction and form friction S : Both f and CD depends on the Reynolds number 47. A binary feed consisting of 25 mol% liquid and 75 mol% vapour is separated in a staged distillation column. The mole fraction of the more volatile component in the distillate product is 0.95. The molar flow rate of distillate is 50% of the feed flow rate and McCabe-Thiele method can be used to analyze the column . The q-line intersects the operating line of the enriching section at (0.35,0.5) on the x-y diagram. The slope of the stripping section operating line (up to one decimal place) is ________ Answer: Exp: 1.4 Given q = 0.25 X D = 0.95 Equation of operating line for rectifying section is y n +1 − x R xn + D R +1 R +1 V Since this line passes through (0.35, 0.5). 0.5 = R 0.95 0.35R + 0.95 × 0.35 + = R +1 R +1 R +1 ⇒ 0.5R + 0.5 = 0.35R + 0.95 ⇒ 0.15R = 0.45 ⇒R = 3 L Reflux ratio = O ⇒ L O = 3D D A (∞) F = D + w n.mm LO D F m m +1 W ⇒ 2D = D + W W = D and F = 2D India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 29 CH-GATE-2015 PAPER| www.gateforum.com For stripping section Wx w L y m +1 = m x m − Vm +1 Vm +1 In stripping section Lm = Ln + qF = 3D + 0.25 * 2D Lm = 3.5D and Vm +1 = Lm − W = 3D − 0.5D = 2.5D Slope of operating line in stripping Lm 3.5 Section = = = 1.4 Vm +1 2.5 48. A catalyst slab of half-thickness L (the width and length of the slab>> L) is used to conduct the first order reaction A → B . At 450 K, the Thiele modulus for this system is 0.5. The activation energy for the first order rate constant is 100kJ/mol. The effective diffusivity of the reactant in the slab can be assumed to be independent of temperature, and external mass transfer resistance can be neglected. If the temperature of the reaction is increased to 470 K, then the effectiveness factor at 470 K (up to two decimal place) will be _________. Value of universal gas constant = 8.314 J/mol.K Answer: 1.875 49. The diameter of sand particles in a sample range from 50 to 150 microns. The number of particles 1 of diameter x in the sample is proportional to . The average diameter, in microns, (up to 50 + x one decimal place) is ________________ 50. Consider two steady isothermal flow configuration shown schematically as Case I and Case II below. In case I, a CSTR of volume V1 is followed by a PFR of volume V2, while in Case II a PFR of volume V2 is followed by a CSTR of volume V1. In each case, a volumetric flow rate Q of liquid reactant is flowing through the two units in series. An irreversible reaction A → products (order n) takes place in both cases, with a reactant concentration CA0 being fed into the first unit. Q C A0 Q Q V1 Q Q C A0 I CAf V2 Q V2 V1 C Af II India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 30 CH-GATE-2015 PAPER| www.gateforum.com Choose the correct option: (A) (C) Answer: Exp: CIA C II Af CIA C > 1 for n = 1 f (B) < 1 for n = 1 f II Af (D) CIA C CIA C f II Af f II Af = 1 for n = 1 = 1 for n > 1 (B) We can solve problem by taking 1st order reaction. (n = 1) For Case I, Q C A0 Q V1 C A1 V2 Q C Af Consider V1 = V2 =1m , k = 1.sec−1 3 Q =1m 3 sec, and C AO = 1mol m 3 For CSTR, τk = 1×1 = C A0 − C A1 C A1 1 − C A1 C A1 ⇒ C A1 = 0.5 mol m3 For PFR. τ= ∫ C Af C A1 ⇒1 = ln dC A kC A C Af ⇒ C Af = 0.184 mol m 3 C A1 Case – II Q CA0 V2 Q CA1 V1 Q CAf India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 31 CH-GATE-2015 PAPER| www.gateforum.com With same data, For PFR τ = − ln C A1 =1 C A0 ⇒ C A1 = 0.3680 mol m 3 and for CSTR, τK = 1 = C A1 − C Af 0.3680 − C Af = C Af C Af CAf = 0.1840 mol m3 . Clearly for both the case CAf is equal i,e 51. C IAf = 1 for n = 1 CIIAf Select the wrong statement regarding water gas shift converters from the list below. (A) Inter-stage cooling is provided between the two stages of shift converters. (B) Usually high temperature shift (HTS) reactor has a iron-based catalyst and low temperature shift (LTS) reactor has a copper-based catalyst. (C) HTS reactor is followed by LTS reactor. (D) LTS reactor is followed by HTS reactor. Answer: Exp: (D) The correct sequence is High Temp Reactor Inter Low temp Cooler reactor Wrong statement is D 52. A vector u = - 2yi + 2xj, where i and j are unit vector in x and y directions, respectively. Evaluate the line integral I= ∫ u.dr c Where C is a closed loop formed by connecting points (1,1) , (3,1), (3,2) and (1,2) in the order. The value of I is ___________. India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 32 CH-GATE-2015 PAPER| Answer: Exp: www.gateforum.com 8 Given u = −2y ˆi + 2xjˆ dr = dxiˆ + dy ˆj So, ∫ u.dx = − ∫ 2y.dx + ∫ 2x.dy − (1) c c c Now, for A → B y = 1, dy = 0 x changes from 1 to 3 (1) ⇒ ∫ u.dr = − ∫1 2 × dx = −4 3 c For B → C, x = 3, dx = 0, y changes from 1 to 2 (1) ⇒ ∫ u.dr = ∫1 2 × 3dy = 6 2 c For C → D, y = 2, dy = 0, x changes from 3 to 1 (1) ⇒ ∫ u.dr = − ∫3 2 × 2dx = 8 1 C For D → A, x = 1, dx = 0, y changes from 2 to 1 (1) ⇒ ∫ u.dr = ∫ 2x1dy = −2 C For whole loop 2 ∫ u.dr = − 4 + 6 + 8 − 2 = 8 C 53. A binary mixture of components (1) and (2) forms an azeotrope at 130OC and x1 = 0.3. The liquid phase non-ideality is described by ln γ1 = Ax 22 and ln γ 2 = Ax12 , where γ1 , γ 2 are the activity coefficients, and x1 , x 2 are the liquid phase mole fractions. For both components, the fugacity coefficients are 0.9 at the azeotropic composition. Saturated vapor pressures at 130OC are P1sat = 70 bar P2sat = 30 bar. The total pressure in bars for the above azeotopic system (up to two decimal places) is Answer: Exp: 27.54 Given x1az = 0.3 = y1az ( At a zeotrope x az = y1az ) P1sat = 70 bar, P2sat = 30 bar ln γ1 = Ax 22 and l n γ 2 = Ax12 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 33 CH-GATE-2015 PAPER| So ln γ1 = A ( x 2 2 − x12 ) = A(x 2 − x1 ) ( x 2 + x1 ) γ2 γ1 = A (1 − 2x1az ) γ2 ln www.gateforum.com _____(1) Also y1az φ1P = x1az γ1P1sat ______(2) y az2 φ 2 P = x az2 γ 2 P2sat ______(3) We know x1az = y1az and yaz2 = x az2 So, (2)/(3) ⇒ φ1 γ Psat = 1 = 1 1sat φ2 γ 2s 2 ⇒ γ1 P2sat 30 3 = = = γ 2 P1sat 70 7 From (1) ln 3 = A (1 − 2 × 0.3) 7 A = − 2.1182 So ln γ1 = Ax 22 = −2.1182 × ( 0.7 ) 2 γ1 = 0.3542 and ln γ 2 = Ax12 = −2.1182 × ( 0.3) 2 γ 2 = 0.8264 Adding equation (2) and (3) ( φ1 = φ2 ≠ φ ( say ) ) φ2 p + φ1p = γ1p1sat + γ 2 psat 2 2φp = 0.3542 × 70 + 0.8264 × 30 P = 27.54 bar 54. Air is flowing at a velocity of 3m/s perpendicular to a long pipe as shown in the figure below. The outer diameter of the pipe is d = 6 cm and temperature at the outside surface of the pipe is maintained at 100o C. The temperature of the air far from the tube is 30OC. Data for air Kinematic Viscosity, V = 18 × 10−6 m 2 s; Thermal conductivity, k = 0.3 W/(m.K) Using the Nusselt number correlation : Nu = hd = 0.024 × Re 0.8 , the rate of heat loss per unit k India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 34 CH-GATE-2015 PAPER| www.gateforum.com Length ( W m ) from the pipe to air (up to one decimal place) is ____________________ Surface temperature 100O C 6cm Air velocity 3m s, Temperature 30O C Answer: 250.945 Exp: Given v = 3m s d = 6 × 10−2 m υ = 18 × 10−6 m 2 sec k = 0.03 w mk Given Nu = hd = 0.024 R 0.8 e k Re = ρVd Vd 3 × 6 × 10−2 = = = 10,000 µ υ 18 × 10−6 hd 0.8 = 0.024 × (10,000 ) = 38.037 k 0.03 × 38.037 ⇒h= =19.0187 w m 2 k 6 × 10−2 So, Rate of heat loss/length = h.( πd )( TS − Ta ) = 19.0187 × π × 6 × 10−2 × (100 − 30 ) = 250.945 w m India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 35 CH-GATE-2015 PAPER| 55. www.gateforum.com The cost of two independent process variable f1 and f2 affects the total cost CT (in lakhs of rupees) of the process as per the following function: CT = 100f1 + 1000 + 20f 22 + 50 f1f 2 The lowest total cost CT, in lakhs of rupees (up to one decimal place), is ________. Answer: Exp: 572.8 Given CT =100f1 + 1000 20f 22 + 50 f1f 2 ∂CT 1000 = P =100 = ∂f1 f 2 f12 and ∂CT −1000 =q= 2 + 40f 2 ∂f 2 f 2 f1 For maxima of minima P = 0, q = 0 100 = 1000 1000 and = 40f 2 2 f 2 f1 f1f 22 ⇒ f12 f 2 = 10............. (1) ⇒ f1 f 23 = 25............(II) Dividing equation (ii) by equation (1) ( ii ) ( i ) ⇒ f1f 23 = 2.5 f12 f 2 ⇒ f 22 f2 = 2.5 ⇒ f1 = 2 f1 2.5 From (1) ⇒ f 24 ( 2.5) 2 f 2 = 10 ⇒ f 25 = 62.5 ⇒ f 2 = 2.2865 so, f1 = ( 2.2865) 2 = 2.091 2.5 f1 = 2.091, f 2 = 2.2865 India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 36 CH-GATE-2015 PAPER| Now, www.gateforum.com ∂ 2 CT +1000 × 2 2000 = = 3 =r ∂f12 f 2 f13 f1 f 2 S= ∂ 2 CT 1000 =+ 2 2 f1 f 2 ∂f1∂f 2 t= 2000 ∂ 2 CT = 40 + 3 2 f 2 f1 ∂f 2 rt − s 2 > 0 and r > 0 So, ( f1 , f 2 ) is point of minima Lowest cost C T = 100 × 2.091 + 1000 + 20 × 2.8652 + 50 2.091 × 2.2865 CT = 572.82lakhs India’s No.1 institute for GATE Training 1 Lakh+ Students trained till date 65+ Centers across India 37
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