Invincible. The next generation of thermoset matrix resins CALIDUR® polyetheramide resins CALIDUR® is a new class of thermoset matrix resins that combines the high flame retardancy of phenolic resins with the mechanical properties of high TG epoxy resins. Benefits CALIDUR® provides much greater design flexibility for carbon fiber and glass fiber composite structures in aircraft and other transportation interior applications. Properties • Intrinsic FST performance • High TG • Excellent surface quality Processing • Rapid processing and curing • Formaldehyde-free • Thermoformable • Storage-stable at 8°C CALIDUR® is supplied as a resin solution or in powder form. Prepregs with various fiber reinforcements are available via our partner c-m-p GmbH. Prepreg production Drying Dry fabric Resin solution Impregnated fabric Dry prepreg Parts production Autoclave Compression molding press Our Partner 2 In addition to enabling short production cycles, CALIDUR® does not require binders while providing greater flexibility across a wide range of curing temperatures. With a very low shrinkage of < 0.5 % and superior characteristics compared to stateof-the-art phenolic compounds, CALIDUR® also demonstrates very good mechanical properties. Prepreg characteristics Tackiness No tack Storage stability Stable for at least 6 months at 8°C Curing cycle Wide range of curing conditions possible TG after curing (30 mins at 150°C)* DSC 152°C TG after curing (10 mins at 180°C) DSC 163°C * TG after curing (45 mins at 180°C) * * DSC 187°C 1 layer glass fiber prepreg (300gsm, E-Glass HexForce 07781, 8H satin) 3 CALIDUR® meets both Airbus FST (ABD0031) and FAA requirements, and is competitive with phenolic resin. Vertical Bunsen burner test (AITM 2.0002 A) Burn length [mm] After flame time [s] 0 0 0 0 0 0 After flame time of drips [s] 1 CALIDUR® 100 10 Phenolic resin Epoxy resin Airbus & FAA limits Heat release rate, heat release (AITM 2.0006) HRR max * [kW/sqm] HR ** [kW min/sqm] 0 CALIDUR® *** 5 10 15 Phenolic resin 20 25 Epoxy resin * Max heat release rate within 5 minutes; ** Total heat release at 2 minutes; *** Values are measured with 1 h 160 °C post curing 4 30 35 40 45 50 55 Airbus & FAA limits 60 65 70 Specific optical density of smoke (AITM 2.0007A; flaming model) Max. specific optical density 0 CALIDUR® *** 20 40 Phenolic resin 60 80 Epoxy resin 100 120 140 160 Airbus & FAA limit *** Values are measured with 1 h 160 °C post curing Epoxy resin fulfills the requirements of FAR25.853; phenolic resin fulfills the requirements of DAN 407-08. Fiber: 300gsm, E-Glass HexForce 07781, 8H satin; two prepreg plies 5 CALIDUR® shows superior composite properties compared to phenolic resin and is competitive with epoxy resin. CALIDUR® vs. state-of-the-art prepreg resins for aerospace interior applications Tensile strength* EN 2747 Tensile modulus* EN 2747 In-plane shear strength* AITM 1-0002 In-plane shear modulus* AITM 1-0002 Compression strength* EN 2850 Compression modulus* EN 2850 Compression strength after 30 J impact 0 20 40 60 80 100 Data normalized [%] CALIDUR® Epoxy resin Phenolic resin Epoxy resin fulfills the requirements of FAR25.8533; phenolic resin fulfills the requirements of DAN 407-08. Fiber: 300 gsm, E-Glass HexForce 07781, 8 H satin. * Data normalized on 50 % fiber volume content. 6 The exceptional properties of CALIDUR® make it ideal for applications that require both superior resistance to flammability, especially smoke density, and outstanding mechanical strength. 7 Technical contact: Dr. Silke Witzel Evonik Industries AG Paul-Baumann-Straße 1 45772 Marl Germany +49 2365 49-84878 +49 2365 49-8084878 [email protected] Marketing: Kirsten Alting Evonik Industries AG Paul-Baumann-Straße 1 45772 Marl Germany +49 2365 49-2259 +49 2365 49-802259 [email protected] Prepreg inquiries: This information and all further technical advice is based on our present knowledge and experience. However, it implies no liability or other legal responsibility on our part, including with regard to existing third party intellectual property rights, especially patent rights. In particular, no warranty, whether express or implied, or guarantee of product properties in the legal sense is intended or implied. We reserve the right to make any changes according to technological progress or further developments. The customer is not released from the obligation to conduct careful inspection and testing of incoming goods. Performance of the product described herein should be verified by testing, which should be carried out only by qualified experts in the sole responsibility of a customer. Reference to trade names used by other companies is neither a recommendation, nor does it imply that similar products could not be used. CALIDUR® is a registered trademark of Evonik Industries or its subsidiaries. c-m-p gmbh Industrieparkstraße 15 52525 Heinsberg Germany +49 2452 15721–0 +49 2452 15721–44 [email protected] 300-09.14 Evonik Industries AG Agrochemicals & Polymer Additives Paul-Baumann-Straße 1 45764 Marl Germany www.evonik.com/composites
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