eODEm P2-15-1 PAPER-2 552701 Maximum Marks: 240 Time: 3 Hours READ THE INSTRUCTIONS CAREFULLY GENERAL: 1. This sealed booklet is your Question Paper. Do not break the seal till you are told to do so. 2. The question paper CODE is printed on the left hand top corner of this sheet and the right hand top corner of the back cover of this booklet. Use the Optical Response Sheet (ORS) provided separately for answering the questions. 3. 4. The ORS CODE is printed on its left part as well as the right part. Ensure that both these codes are identical and same as that on the question paper booklet. If not, contact the invigilator. 5. Blank spaces are provided within this booklet for rough work. 6. Write your name and roll number in the space provided on the back cover of this booklet. 7. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that all the 60 questions along with the options are legible. QUESTION PAPER FORMAT AND MARKING SCHEME: The question paper has three parts: Physics, Chemistry and Mathematics. Each part has three sections. 9. Carefully read the instructions given at the beginning of each section. 10. Section 1 contains 8 questions. The answer to each question is a single digit integer ranging from 0 to 9 (both inclusive). Marking scheme: +4 for correct answer and 0 in all other cases. 11. Section 2 contains 8 multiple choice questions with one or more than one correct option. Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases. 12. Section 3 contains 2 "paragraph" type questions. Each paragraph describes an experiment, a situation or a problem. Two multiple choice questions will be asked based on this paragraph. One or more than one option can be correct. Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases. OPTICAL RESPONSE SHEET: 13. The ORS consists of an original (top sheet) and its carbon-less copy (bottom sheet). 14. Darken the appropriate bubbles on the original by applying sufficient pressure. This will leave an impression at the corresponding place on the carbon-less copy. 15. The original is machine-gradable and will be collected by the invigilator at the end of the examination. 16. You will be allowed to take away the carbon-less copy at the end of the examination. 17. Do not tamper with or mutilate the ORS. 18. Write your name, roll number and the name of the examination center and sign with pen in the space provided for this purpose on the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll number. ~ 'Please see the last page of this booklet for rest of the instructio"ns ... ** 1 « ..J el :>z w :r: I- >lD o UI o o o Io 8. ~~ a:: o I- . [~~] W IU ::l a:: I- UI Z el Z W lD I- ::l o :r: I- ~ I w :r: I- ~ « w a:: lD I- o Z o o PART I :.PHYSICS SECTION 1 (Maximum Marks: 32) • • • o This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme: +4 If the bubble corresponding to the answer is darkened o In all other cases ,Q:('" A large spherical mass M is fIxed at one position and two identical point masses m are kept on a line passing through the centre of M (see figure). The point masses are connected by a rigid massless rod of length l and this assembly is free to move along the line connecting them. All three masses interact only through their mutual gravitational interaction. When the point mass nearer to M is at a distance r = 3l from M, the tension in the rod is zero for 1. m = k ( M ). The value of k is 288 The energy of a system as a function of time t is given as E(t)=A2exp(-at), a = 0.2 S-I. where The measurement of A has an error of 1.25%. If the error in the measurement of time is 1.50%, the percentage error in the value of E(t) at t = 5 s is ~ The densities of two solid spheres A and B of the same radii R vary with radial distance r as PA(r)=k(~) and PB(r)=k(~J, respectively, where k is a constant. The moments of inertia of the individual spheres about axes passing through their centres are IA and IB, respectively. If IB = ~, IA the value of n is 10 , Space for rough work t cLt --' L \0/ . it)/,\ .•. ~ ~ ' ,,\\ f .~ + 1. ciA -A .)11\ ** 1 C M I '" l ~ ~ /, j".J.:; + (c 2.) I \, ,,---, -it.X i' 5 3/32 PHYSICS Four harmonic waves of equal frequencies and equal intensities 10 have phase angles)/, 11/3, 211/3 and/When they are superposed, the intensity of the resulting wave is n1o. The value of nis ~ For a radioactive material, its activity A and rate of change of its activity R are defined as dN and R = - dA, where N(t) is the number of nuclei at time t. Two radioactive dt dt sources P (mean life ,) and Q (mean life 2,) have the same activity at t = O. Their rates of A =- p change of activities at t = 2, are Rp and RQ, respectively. If R RQ = n, e then the value of n is A monochromatic beam of light is incident at 60° on one face of an equilateral prism of refractive index n and emerges from the opposite face making an angle B(n) with the normal (see the figure). For n =.J3 the value of B is 60° and dB dn = m. The value of m is 2- ",(),(I .\ (,0 ( Q;(,\J "nO>' (; '':'' (; 9'0 - (; 00"'~~; , .l" -, Space for rough work '. J3/\, '1 3 v' 1:1 J, 'A ~;(i '\\ Cfl' 1- I -l ,. ' I (,1,1'\0 - hJ l ,1 J'\. ** 1 f (' 4/32 /" t. t'" :'\.. I " {1 .!,~ , } r~. IL' IE . _' Yl L X .:5J~vv'0 ~ \l~ -rr 1Q)7 / UI.,QZ,c. ~J' -;.. "1. \ ); x,,~ vv. ~ ( ,,\ -\~ < '; l /( PHYSICS In the following circuit, the current through the resistor R (= 2Q) is I Amperes, The value of! is 20 ii An electron in an excited state of Li2+ ion has angular momentum 3h/2Jr, The de Broglie wavelength of the electron in this state is pJrao (where Go is the Bohr radius), The value ofp is 2- r'V' . (' I , ,v \ 'i (1 Space for rough work 141 "6 18 ,( ~ 1 A. ~ ~ A~ -l-t-2 ~ --"MIJ 2 X't-1'f\Q 1'1J1. . 2.A''I'a..on ~ )( z: ::: .2 11. ',(.. ); - {'lef '(:2., Nu~ ? 't:) -Z. . _, i 01>( --< Ne~ ~ 'ft;" C\.t ::- (2)2-. ~X$ .~q-o ...2 ') . ...-r) )4f It f....?'.(3/ :: 1- xX 2% M-',~rfr. C -' 5/32 Yn7~. ._, '/ -----------------------PHYSICS SECTION 2 (Maximum Marks: • • • • 32) This section contains EIGHT questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme: +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened o If none of the bubbles is darkened -2 In all other cases Two spheres P and Q of equal radii have densities PI and P2' respectively. The spheres are connected by a massless string and placed in liquids L1 and L2 of densities 0"1 and 0"2 and viscosities 171 and 172 , respectively. They float in equilibrium with the sphere P in L1 and sphere Q in L2 and the string being taut (see figure). If sphere Palone in(LJhas terminal ~ _~__~-~-_. ~ ---,-.~~. velocity Vp and Q alone in L1 has terminal velocity VQ ' then .- .. .. -- ...~., - ,_.,,,.,'----'- - .."", \ If ~ (B) I Vp I --=- 172 (C) ~ IVQ I 171 In terms of potential difference V, electric current I, permittivity speed of light c, the dimensionally correct equation(s) is(are) ¥{ ",1' = So V' (B) sol = '" Vi'. (fl(' t = So' V &0' permeability J.10 and (D) Space for rough work V -;:. C - LT-\ • ! 1\' L "I 1\-( , 1,-1 A-; 6/32 ** 1 1\ I A~ ) -r-~~ M -\ C1. ;vi 'J., /..'1 ,r T ~ NI L i ~').. ~ PHYSICS Consider a uniform spherical charge distribution of radius ~ centred at the origin O. In this distribution, a spherical cavity of radius R2, centred at P with distance OP = a =~ - r R2 (see figure) is made. If the electric field inside the cavity at position is --'> --'> E (1') , then the correct statement(s) is(are) ' I '\ .\ .f ~"~"I, I, f,_.. ~\ '" V .... ~I ;V - '\l"-.. J"" ,!;' ~ /~ ~ ~/ '. J/t~ fit ) .f-.... '" ~ i;)1 /' (A) E is uniform, its magnitude is independent of R2 but its direction depends on (B) E is uniform, its magnitude depends on R2 and its direction depends on (C) E is uniform, its magnitude is independent of a but its direction depends on £p(' E is uniform and both its magnitude and direction depend on r r )<;, a )<7 a \" L1'-1 Vr -~ T -;: A V:: ML!-T-31). i \j I' V(. d VJld.+T~.\;! , ;Ub ("'. 'r f:' '. fV\ l VJ20 ~ V~ d o~~ 0- -r, .1 ~ qt ! ** 1 7/32 ~ ( PHYSICS 1 G Instrainplottingon thestressy-axisversusandstrain curves for two materials and a student by mistake puts stress on the x-axis as shown in the figure. Then the correct P Q, statement(s) is(are) - ---_._--_._--~ Stress y~ > ~ tf,) P has more tensile strength than Q \.E:E( P is more ductile than Q (C) P is more brittle than Q /:>.. (D) The Young's modulus of P is more than that of Q ~ --1 1 ytS5=U9hWO~ J-K- ' b \c ~ ** 1 I 3. ~ Q.13 Q.14 f PHYS::S ] . t f' fl 'd f d' dl. A sp h enca 1 b0 dy 0 f ra d'lUS R conSlS S 0 a Ul 0 constant enslty an IS m eqUl 1 rlUm under its own gravity. If per) is the pressure at r(r < R), then the correct option(s) is(are) (A) P(r=O)=O (C) P(r P(r = 3R/5) = 2R/5) _~ 21 (B) P(r P(r = 3R/4) 63 = 2R/3) = 80 (D) P(r P(r = R/2) 20 = R/3) = 27 li- A parallel plate capacitor having plates of area S and plate separation d, has capacitance Cl in air. When two dielectrics of different relative permittivities (£1 = 2 and £2 = 4) are introduced between the two plates as shown in the figure, the capacitance becomes C2• The C2 1) " ratio C is 1 X" "f :L :.:;;;- /f\. dl2 •......" 'l.o S ~ .• t;(¥-. ~ C(flY ~ A ',V I 7';{Y -! ~0 \ \ . G $05 ),~ '\ Y ~ ',. \ .•. ,- d 6/5 (A) (B) 5/3 (C) 7/5 V<D) Space for rough work 7/3 ,I' I i C\-.:: /) .-7 [' .1 I L1 --,..-...- .- .; . It; r 'X! r , J .\ ~ '" J I -.:;-+ c. .' I. l( '2 :i5-:3 I (~. ~- . J . .\: /p $ "-!-.- /1' Z.~ .,., !:Jd 9/32 7;;: A. ~ ._r- -11 . ~ " I PHYSICS Q.15 An ideal monoatomic gas is confined in a horizontal cylinder by a spring loaded piston (as shown in the figure). Initially the gas is at temperature TI, pressure PI and volume VI and the spring is in its relaxed state. The gas is then heated very slowly to temperature Tz, pressure Pz and volume Vz. During this process the piston moves out by a distance x. Ignoring the friction between the piston and the cylinder, the correct statement(s) is(are) ................. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. ... .. . .. .. . .. . . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. . . . .. . . .. . .... .. . . . . .. . .. . . . .. . . . . . . .. . ... ... .. .. .. .. .. . .. . .. .. . . . .. . . . ... .. . .. .~ ........................ '. .. . . . . . . . . . . . . . . . . . . . . . . ... . . . . ... . , ~\ (A) If Vz= 2VI and Tz = 3Tv then the energy stored in the spring is ~ PI VI ~ If Vz= 2VI and Tz = 3TI, then the change in internal energy is 3PI VI (C) If Vz= 3VI and Tz = 4TI, then the work done by the gas is 'i PI VI 3 )0 ". (D) If Vz= 3 VI and Tz = 4TI, then the heat supplied to the gas is .!2. PI VI 6 k'lt -1((~ _. .- PtA Space for rough work ,,~\' ) ;L ~i\l ~ 'LA ," 'f f, R ~ 11\ 11 X:? .• p~". "• .2- -- 2; "1 -- K PI VI 4 '2 ....•• r- kl( +r;' (t!'i 8 k- - j .-:; I X ~X '\' V J ~ 5. -, , . ! ** 1 P ~ ~~\ ~/ "1" I r f'~ If -+." ~ •• t)\ ?l {.~. ~ ,• PI 0,'\\ ~+ y' 'I X ~ K '1 """ ,. ~ K.. 11 \i• I F~ Ii"',,71)( ~-- "(1 \ c! 10/32 " PHYSICS A fission reaction is given by 2~~U~ l:~Xe + ~:Sr + x + y, where x and yare 1 two particles. Considering 2~~U to be at rest, the kinetic energies of the products are denoted by Kxe, Ksr, Kx (2 MeV) and Ky (2 MeV), respectively. Let the binding energies per nucleon of 2~~U, l:~Xe and ~~Sr be 7.5 MeV, 8.5 MeV and 8.5 MeV, respectively. Considering different conservation laws, the correct option(s) is(are) y1' x = n, y = n, KSr= 129 MeV, KXe = 86 MeV ..w) x = p, y = e-, KSr= 129 MeV, KXe = 86 MeV J" .JP5 x = p, y = n, KSr= 129 MeV, KXe = 86 MeV (D) x = n, y = n, KSr= 86 MeV, KXe = 129 MeV Space for rough work A "( -;: ;)V ~ ,..( (+ ~"." 3 -r(ei"l\- p\'4,'P 7i"~ I c( • Pf .~. VI ,II g + J. "i 3 2. t{- .., Q ... ** 1 11/32 PHYSICS SECTION 3 (Maximum Marks: • • • • • 16) This section contains TWO paragraphs Based on each paragraph, there will be TWO questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme: +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened o If none ofthe bubbles is darkened -2 In all other cases Space for rough work V,: L w p .. ct-£: v, ~ BIQ. -;: 13.:r , t III -,~ 'I 2> 11.;..... l ( 12/32 PHYSICS PARAGRAPH 1 In a thin rectangular metallic strip a constant current I flows along the positive x-direction, as shown in the figure. The length, width and thickness of the strip are l, wand d, respectively. -> A uniform magnetic field B is applied on the strip along the positive y-direction. Due to this, the charge carriers experience a net deflection along the z-direction. This results in accumulation of charge carriers on the surface PQRS and appearance of equal and opposite charges on the face opposite to PQRS. A potential difference along the z-direction is thus developed. Charge accumulation continues until the magnetic force is balanced by the electric force. The current is assumed to be uniformly distributed on the cross section of the strip and carried by electrons . --1. •••• 1-- I L_ Q.17 Q P z Consider two different metallic strips (1 and 2) of the same material. Their lengths are the same, widths are WI and W2 and thicknesses are dI and d2, respectively. Two points K and M are symmetrically located on the opposite faces parallel to the x-y plane (see figure). VI and V2 are the potential differences between K and M in strips 1 and 2, respectively. Then, for a given current I flowing through them in a given magnetic field strength B, the correct statement(s) is(are) (A) If WI = W2 and dI = 2d2, then V2 = 2VI ~..B(If WI = W2 and dI = 2d2, then V2 = VI (C) If WI = 2w2 and dI = d2, then V2 = 2VI (D) If WI = 2W2 and dI = d2, then V2 = VI Q.18 Consider two different metallic strips (1 and 2) of same dimensions (length l, width wand thickness d) with carrier densities nI and n2, respectively. Strip 1 is placed in magnetic field BI and strip 2 is placed in magnetic field B2, both along positive y-directions. Then VI and V2 are the potential differences developed between K and M in strips 1 and 2, respectively. Assuming that the current I is the same for both the strips, the correct option(s) is(are) (A) If BI = B2 and nI = 2n2, then V2 = 2VI (B) If BI = B2 and nI = 2n2' then V2 = VI (C) If BI = 2B2 and nI = n2, then V2 = O.5VI (D) If BI = 2B2 and nI = n2, then V2 = VI Space for rough work ** 1 13/32 \ . PHYSICS PARAGRAPH 2 Light guidance in an optical fiber can be understood by considering a structure comprising of thin solid glass cylinder of refractive index n] surrounded by a medium of lower refractive index n2. The light guidance in the structure takes place due to successive total internal reflections at the interface of the media n] and n2 as shown in the figure. All rays with the angle of incidence i less than a particular value im are confined in the medium of refractive index ~. The numerical aperture (NA) of the structure is defined as sin i",. d _ " l Air Cladding \ Q.19 For two structures namely 8] with ~ = fi5/4 and n2 = 3/2, and 82 with I~ = 8/5 and n2 = 7/5 and taking the refractive index of water to be 4/3 and that of air to be 1, the correct option(s) is(are) / JA) NA of 8] immersed in water is the same as that of 82 immersed in a liquid of refractive . d 16 ~ m ex ~ lIP' 3",15 ~~', ..t); (B) immersed in liquid of refractive index immersed in water (ci / ',. 6 .J15 ]s the same as that of 82 'r NA of 8] placed in air is the same as that of 82 immersed in liquid of refractive index 4 \ .J15 . .',', \' ' A (D) ", NA of 8] placed in air is the same as that of 82 placed in water "I " Q.20 If two structures of same cross-sectional area, but different numerical apertures NA1 and NA2 (NA2 < NA]) are joined longitudinally, the numerical aperture of the combined structure is 't I' ' " ". NA1NA2 (A) -.\~ ** 1 (B) NA] +NA2 8 '\4n ~fI • " , ~,J .... v " j: , "('''1 ," I '"' , y", - (C) NA1 +NA2 JlJ{ NA] NA2 ,t \' -:, ". ~,' h " \ j/ "~ {Fs ' i!' )/ ,v •.. ~r (I,' " 'I r r f y( END OF PART I : PHYSICS ~ , ~), \\J 14/32 i, - ' \ I , f , \ \ // , )\'J \/ {. pARTjI: . ._-,. .CHEMiSTRY 'I, r-~--------------------------~-------' \\1 . ...J.;,t' / . 'fi. \'",. ~ ...\ d \ SECTION 1 (Maximum Marks: 32) . vi • • This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORB • • Marking scheme: +4 If the bubble corresponding to the answer is darkened o In all other cases " Q.21 The number of hydroxyl group(s) in Q is H+ aqueous dilute KMn04 (excess) ----. p heat Q.22 • Q OOC Among the following, the number ofreaction(s) that produce(s) benzaldehyde is o CMO j CO, HCI ! J V Anhydrous AICI3/CuCI ! \lJ/ COCI I () H _2__ // (YC02Me V n ~ (." Pd-BaS04 DIBAL-H , -ro-lu-e-n-e,---7S-0-C--' H20 ,(3l ,~, "\ , "\ If 'o\"\ W .• / .- \\ l:; ..)', ' In the complex acetylbromidodicarbonylbis( triethy lphosphine )iron(II), the \ Fe-C bond(s) is "') .••.. ~ / ' (.J Space for rough work ""' number of \ I! o I' \' Fe. ~-C) ~ .' c- C" c' ~.~ 5 ,}. ** 1 15/32 '. t, ~\.\ ~1i' .'1 I'.' -If-' , "fC> 1~ong .;.',! : l ( CHEMISTRY ] eYt .:J. / V -le) / 3 tt? complex ions, [Co(NH2.CH2-CH2.NH2)2Cl~+, [CrC12(C2.0r.,4)21 [Fe(H20MO~92r,~ -, 3 [Fe(NH3MCN)4r, [Co(NH2-CH2.CH2-NH2MNH~9l12+and [CO(NH~20)Cl12+, the number of complex ion(s) that show(s) c~isomerism is -6 -+'3 Thre_~_moles of B2H6 are completely reacted with methanol. The number of moles of boron containing produCt formed is ~ ~ J26 The molar conductivity of a solution of a weak acid HX (0.01 M) is 10 times smaller than the molar conductivity of a solution of a weak acid HY (0.10 M). If A~_ '" A~_, the difference in II " their pKa values, pKa (HX) - pKa (HY), is (consider degree of ionization of both acids to be «1) fc{Y\ 9.-27 A closed vessel with rigid walls contains - \ / 1 mol of 2~~Uand 1 mol of air at 298 K. Considering complete decay of 2~~Uto 2~~Pb,the ratio of the final pressure to the initial pressure of the system at 298 K is ~ .~. ~ In dilute aqueous H2S04, the complex diaquodioxalatoferrate(II) is oxidized by MnO~. For this reaction, the ratio of the rate of change of [H+]to the rate of change of [MnO~] is 3 i,/ -- L1 -j r)( -. cJ. Space for rough work -.J iIT] 1Ll1 I Ij () (!c ~ QV\--------- C\ I ---~J L. r r' ~ l./I, C. vi, f.'O' t,\ Co' i - -I ,-' (F e (~t~):.((! r.\ .:; \ Yi=$5 --.---:., I. ,?;>f l ) 0f -Li ,~' , (Q." 4' , MIn 11 8 '20C ...--;:; ' . ',i {•. f' I I ., v;/ ~.. I), 16/32 ' [ CHEMISTRY] SECTION 2 (Maximum Marks: 32) • • • • \ I \ This section contains EIGHT questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme: +4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened o If none of the bubbles is darkened -2 In all other cases In the following reactions, the product S is i. 03 ---- Q.30 .•• R ----. S The major product ~Jg!1Q!\:iQg react0ns i!3 o CH2=CH-CH3, H+ --------... T -----~. U (A) \. ~CH3 . l 1 0 <£ H3C CH3 era,a'H 1 0 ~ 0-0 (C) (-(--c high pressure, heat ~ 0-0 (- ([) radical initiator, O2 ~CH2 I~ CH2 >a (D) ~a'a,H I 0 17/32 [ CHEMISTRY] In the following reactions, (Y NH V 2 NaN02, HCI (A) \..jJ?,{ (JJ( (D) Q.33 ~OH ~,NaOH w • V aOc The cor~tstatement(s) Q.32 the major product W is regarding, (i) HCIO, (ii) HCIOz, (iii) HCI03 and (iv) HCI04, is (are) The number of CI=O bonds in (ii) and (iii) together is two The number oflone pairs of electrons on CI in (ii) and(iii) The hybridization of CI in (iv) is Amongst (i) to (iv), the strongest ... ,'J B'3+ F 1 ,e together is three Sp3 acid is (i)~ The pair(s) of ions where BOTH the ions are precipitated of dilute HCI, ~s(are) (A) Baz+, ZnzX, (B) ~ 3+ }17 upon passing, HzS gas in presence (D'''' H g,Z+ B.13+ 'VI Space for rough work \ 1 () II f. , .. 'C' - ** 1 18/32 I J [ CHEMISTRY] Q.34 Under hydrolytic conditions, the compounds used for preparation of linear polymer and for chain termination, respectively, are './ .. (A) CHaSiCla and Si(CHa)4 YJ \.{B) (CHa)2SiC12and (CHa)aSiCl --_._._ (C) ' (D) SiC14 and (CHahSiCl f< (CHa)2SiC12and CHaSiCla ~' When O2 is adsorbed on a metallic surface, e~ t~n;;(~r occurs from the metal to O2,The • k TRUE stateme~t(s) regarding this adsorpti"is(are) . At& ::..\~</----.t.~:@) O2 IS physlsorbed;< ckv,V\,<. {d3) heat IS released . \~() v<.<S) occupancy of of O2 is increased ff;p Jd bond length of O2 is increased One mole of a monoatomic real gas satisfies the equation p(V - b) = RT where b is a constant. The relationship of interatomic potential V(r) and interatomic distance r for the gas is given by VCr) (A) VCr) (B) o o~---r r !...I', VCr) VCr) (C) (D) of---L---- o r r Space for rough work I .., _6'-)'(-'0 "- \ ,, \, t I!)' i' ., .1 r. , I:' ! v. " . It-I I '! C' {"'I' ".' I (I ** 1 19/32 [CHEMIST!YJ SECTION 3 (Maximum Marks: 16) • • • o • This section contains TWO paragraphs Based on each paragraph, there will be TWO questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is (are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS Marking scheme: +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened o -2 If none of the bubbles is darkened In all other cases PARAGRAPH 1 In the following reactions Pd-BaS04 ---~. CsHs -------. x I H20 ~ HgS04, H2S04 i. EtMgBr, H20 CsHsO • Y ii. H+, heat Q.37 ~-c::- Compound X is OH ° (A) ~CH' (B) d'CH, cd (J0H 1 0 (D) U ~ (B) (C) ~CH' 0 ~) \ C CHO (j'/I @J- ~CH3 . dCH' gI) 1: 1CH, \ C (:: a ( •••.c 0 oH C2:r.c \ Space for rough work o ** 1 CY\ \\ CH2 1 I c- Q.38. The major compound Y is (A) ~CH3 C 0-~b~C I C \ C Et 20/32 [ CHEMISTRY] PARAGRAPH 2 When 100 mL of 1.0 M HCI was mixed with 100 mL of 1.0 M NaOH in an insulated beaker at constant pressure, a temperature increase of 5.7 °C was measured for the beaker and its contents (Expt. 1). Because the enthalpy of neutralization of a strong acid with a strong base is a constant (-57.0 kJ morl), this experiment could be used to measure the calorimeter constant. In a second experiment (Expt. 2), 100 mL of 2.0 M acetic acid (Ka = 2.0 x 10-5) was mixed with 100 mL of 1.0 M NaOH (under identical conditions to Expt. 1) where a temperature rise of 5.6 °C was measured. (Consider heat capacity of all solutions as 4.2 J g-l K-l and density of all solutions as 1.0 g mL-I) Q.39 Enthalpy of dissociation (in kJ mol-I) of acetic acid obtained from the Expt. 2 is ci 1.0 (B) 10.0 . (C) 24.5 (D) 51.4 (C) 5.0 (D) The pH of the solution after Expt. 2 is QAO (A) rI 2.8 4.7 7.0 END OF PART II: CHEMISTRY ~XL{'2 A ~;4 --- ~ "J :5"'1 ~ (f'I) >( j 2ifVCj (; j - - 5-~jL b, !" .r " I~ I~J r~l; J ~ el- tJ.3 ~ '. f tl"" '; -I I L','" . •'.' 1 It, ). t -*,,' 2_ . --' ,- I U -I I ( .'- 2. y !r , 1" . V!. 1 l• / j ** 1 21/32 PART III : MATHE~ATICS SECTION 1 (Maximum Marks: 32) • • This section contains EIGHT questions The answer to each question is a SINGLE DIGIT INTEGER ranging from to 9, both inclusive For each question, darken the bubble corresponding to the correct integer in the ORS Marking scheme: +4 If the bubble corresponding to the answer is darkened o In all other cases ° • • , I I, e., Q.41 For any integer A. •.•",_. 1- k, let a = cos(k; ) + sin (k; lwhere i = ~ . The value of the expression i k V u ~ paM' -a,1 I/ a 4k-1 - "j. ,/ / Q.:43 ~ -.j.. .-tJ a4k-Z! k=l Q.42 ~ ~~ Suppose that ratio of the 6 : 11 and the A.P. is all the terms of an arithmetic progression (A.P.) are natural numbers. If the sum of the first seven terms to the sum of the first eleven terms is seventh term lies in between 130 and 140, then the common difference of this ~ The coefficient of x9 in the expansion of (1+ x)(l + xZ)(l + x3) (1+ x100) is ..• Space for rough work ~ ._---- .~if - GI,O l:f '7 i . (2-a. + :. . ~ f ( ~ j' llt, \ ~ !:) ('H 6J l2a. ,- ,1\ oj i dJ Jtfd 'f' ,. J 6 ') (I-Ix) C lb) (t.i'X/ :;'\/ (I~';(~) .~ ~,) I..'':( ) '.1:( / i.iCJ ( H •.;':)I If./ f) "/(0; ) ( .. ~1:.." X) ( ,I.r I . , 'f \-11( / -', H XI ) Cit " )-\ ( ,s '\ (~~+~r .. ** 1 1tbtflJ .' ( '4?: c'. C' \ ! ( I~ "I) 22/32 I ..• -I i (MATHEMATICS) . Q.44 i x2 Suppose that the foci of the ellipse - + - = 1 are (f1' 0) and (f2' 0) where ft > 0 and (2 < O. 9 5 Let ~ and P2 be two parabolas with a common vertex at (0, 0) and with foci at (ft, 0) and (2(2,0), respectively. Let T" be a tangent to ~ which passes through (2(2,0) and T2 be a tangent to P2 which passes through (ft, 0). If m1 is the slope of T" and m2 is the slope of T2, then the value of (~~ + m~J is Q.45 2- Let m and n be two positive integers greater than 1. If lim (_eCOs(a_n) -eJ= _(~) a.->O am 2 then the value of m is n 12_\ Q.46 If a (12+ 9x J dx 2 = J1(e9X+3tan-l X) 1+x2 o where tan -1 x takes only principal values, then the value of (lOgell + a . )- i- t ( ,.•.. rr (, (0,' ~l' \ /-j / j \,... - ~.•.- '] ..•. ~v. I , /" Q!\ n ), Y'2 / " -le ,./ , I ~ __ ,..... \ K .- j r 1- 3:) is -1-I,¥, _., --.-r' - -. c,.C.( ** 1 C~'J c< ( ..,' f\~) 'I . r ;(r\ J 23/32 (MATHEMA TI CS ) Let [: IR ~ IR be a continuous o!<!Junction, which vanishes exactly at one point and Qd7 1 x [(1)=2' Suppose that F(x) x = f[(t)dt for all xE[-1,2] and G(x)= ftl [(f(t»Idt -1 xE[-I,Z]. Q.48 If limF(X)=~,thenthevalUeOf[(!)iS x ..••1 G(x) 14 Suppose that vector ...• S p ", q :rd Tit are. three s along (-t-t-t -t-t--t are x, y and z, respectively, then the Space for rough work e'G, -; - tl ..~"; ~t'Fj • "';1f -t--t-t (-p-q+r) 0 --,' •. 3 non-coplanar vectors in 1R . Let the components of a and (p-q+r) value of 2x + y + z is •~ 1- 2 ~, ~ and' T be 4, 3 and 5, respectively. If the components of this vector along -p+q+r), ..,.,......, for all -1 .. t;;. :.;$1 ( , - F -i L , .-1 . t )" p I.~ Il n., ". .- ,, \.; 8.jb-2 -2 ._ " 5 .- 4~ 13j A f'\ -\ O~ f r I I . ,.( 7: (I. 1 / , \. .I, I,.. •. -,2-1--/0 q- - (P ** 1 '. 2 -I Lf~' 24/32 (MATHEMATICS 1 SECTION 2 (Maximum Marks: 32) • This section contains EIGHT questions • Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct • For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS • Marking scheme: +4 If only the bubble(s) corresponding If none of the bubbles is darkened o -2 Q.49 In all other cases Let S 2 ax - be the set of all non-zero real x + a = 0 has two distinct real roots Which of the following intervals (B) Q.50 to all the correct option(s) is(are) darkened and Xl satisfying X2 the quadratic equation I Xl the inequality x21 < 1. - S? a subset(s) of I (1J5' 2"1) where the in~erse trigonometric functions 35,0) (0') Yl C If a=3sin-I (- is(~ a such that numbers 6 1) and ,8=3COS-I(~). take only the principal values, then the correct option(s) is(are) (A) cos,8 > 0 (B) sin,8 < 0 cos(a + ,8) > 0 (C) cosa < 0 (D) Space for rough work . , I. :. i I "'. '). --I 't{!~~2 i. ;: ~. j ';I /...7 ''- ' J f,. 1 1:!- -I ,,':'. 3 <'. C( .f',' 1 S- <-. '\. I I , -J', , . '- ~ -l ** L ()\- ! ,lc!!J \6 . (,1 i.. .1 , ' I A ,) .- / ,/.- . ,I ~- .. ~, 25/32' [MATHEMATICS] Q.51 Let El and E2 be two ellipses whose centers are at the origin. The major axes of El and E2 2 lie along the x -axis and the y -axis, respectively. Let S be the circle x + (y _1)2 = 2. The straight line x + y = 3 touches the curves S, E1 and E2 at P, Q and R, respectively. Suppose that PQ = PR = 2.J2 . If el 3 then the correct expression(s) is(are) (A) Q.52 2 2 e1 +e2 43 =- and e2 are the eccentricities of El and E2, respectively, (D) (C) (B) 40 Consider the hyperbola H: x2 -l = 1 and a circle S with center N(xz,O). Suppose that Hand S touch each other at a point P(Xl'Yl) with Xl > 1 and Yl > O. The common tangent to Hand S at P intersects the x -axis at point M. If (1, m) is the centroid of the triangle !1PMN, then the correct expression(s) is(are) (A) . dl 1 = 1 - -2 for dXl 3xl Xl >1 (B) (C) dl 1 -=1+-2 for dX1 3xl Xl >1 (D) dm 1 dYl 3 -=- for Yl >0 Space for rough work • I • ~ \ n ",' , ,'\ • .\ '(vi /( -I I J .. ~) , '- .•..i, 1 oJ- ')'1(.\ ',)(1.,\,1' '-' 'l o I I..'. ~.I .~ 'I _i. -, ** 1 . 26/32 [MATHEMATICS) Q.53 The option(s) with the values of a and L that satisfy the following equation is (are) 4" f e (sin t 6 at+ cos4 at)dt = L? o " f e (sin t 6 at+ cos4 at)dt o e4" -1 a=2 L=-, e" -1 (B) e4" +1 a=2, L=-e" +1 e4" -1 (C) a=4, L=-e" -1 (D) e4" + 1 a=4, L=-e" +1 (A) Q.54 Let I, g: [-1, 2] --+ lR be continuous functions which are twice differentiable on the interval (-1, 2). Let the values of I and g at the points -1, 0 and 2 be as given in the following table: x=-1 x=O x=2 I(x) 3 6 0 g(x) 0 1 -1 In each of the intervals (-1, 0) and (0, 2) the function (f - 3g)" never vanishes. Then the correct statement(s) is(are) (A) {'(x) - 3g' (x) = 0 has exactly three solutions in (-1, 0) u (0, 2) (B) f'(x) -3g'(x) (C) ('(x) - 3g' (x) = 0 has exactly one solution in (0,2) (D) ('(x) - 3g' (x) =0 has exactly one solution in (-1,0) = 0 has exactly two solutions in (-1,0) and exactly two solutions in (0, 2) Space for rough work ** 1 27/32 [MATHEMATICS) Q.55 Let f(x)=7tan8x+7tan6x-3tan4x-3tan2x expression(s) 1 dx =-' 12 fo xf(x)dx=- K/4 (C) Q.56 Let f'(x) = all XE(_Jr, Jr). \ 2 2 Then the correct is (are) fo xf(x) K/4 (A) for K/4 (B) f f(x)dx =0 o 1 K/4 (D) 6 f f(x)dx =1 o 1 19~x43 for all x E JR with f(-2 ) = o. If 2+ sm 7lX II f(x)dx m =0; =0; M, then the possible 1/2 values of m and Mare (A) (C) m=13, M =24 m = -11, M =0 (B) (D) m=m 1 4' = 1, M=- M 1 2 = 12 Space for rough work \ ') \ I ./ (I)t) , ** 1 28/32 v\ [MATHEMATICS] SECTION 3 (Maximum Marks: • • • 16) This section contains TWO paragraphs Based on each paragraph, there will be TWO questions Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are) correct For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS • • Marking scheme: +4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened o If none of the bubbles is darkened -2 In all other cases \ PARAGRAPH 1 \ ~ ~~ ' Let n and nz be the number of red and black balls, respectively, in box I. Let n3 and n4 be the number of red and black balls, respectively, in box II. j Q.57 One of the two boxes, box I and box II, was selected at random and a ball was drawn randomly out of this box. The ball was found to be red. If the probability that this red ball was drawn from box II is .!, then the correct option(s) with the possible values of ~,nz,na . 3 is(are) (A) nj = 3, nz = 3, n3 = 5, n4 = 15 {<> = 3, nz = 6, n3 = 10, n4 = 50 and n4 $f ~ (C) nj = 8, nz = 6, n3 = 5, n4 = 20(0 (D) ~ = 6, nz = 12, n3 = 5, n4 = 20 A ball is drawn at random from box I and transferred to box II. If the probability of drawing Q.58 .!, then a red ball from box I, after this tr::sfer, values of nj and nz is(are) is (A) (B) nj = 2 and nz = 3 I5.P?' n = 3 and nz = 6 ~ = 4 and nz = 6 >c ~ = 10 and nz = 20 ,yc) the correct option(s) with the possible 3 i l' .. -- .~ + . .7 'r, I ~ --' 'i< G-W ! "7/ JE., -8 ~ j;.:'., 8 :Ie: -" ~ i~ 5 ---! -~ ;;0 tr '-;;l,z1 J- \-,/ _.:Ef. __ . /' -. .. ]'1 ":E.? \. ') 3C -;,,\ 2.( i ~ $;- 01,:; ** 1 /i J;-," .' ~~ 2 "t-{) 10' 6 - ;'" ":r ') ~:. ,-., Y , ~r'-" .' 2 j. 9 ~S '\ j ' __ .t \' ~ 2:--,:t. ~ iT' r 'f.. f) 10... Space for rough work < ("<J v 29/32 /J..(l"J 9(:) ,. :-.' Ii) <, / a I ft Ii'. t' J [MATHEMATICS 1 PARAGRAPH r- (/) 2 F: lR --* lR be a thrice differentiable function. Suppose F'(x) < 0 for all x E (112 ,3). Let f(x) = xF(x) for all x E lR. Let that F(I) J:.{ = 0, F(3) = -4 and ";( F' (-£i '/ Q.59 The correct statement(s) is (are) A \J...A1' ('(1) < 0 \j!65 ~ ('(x)"* 0 for any x E (1,3) 3 Q.60 r (I) {(2)<0 (D) ('(x) = 0 for some x E (1,3) 3 If f x2F'(x)dx=-I2 and fx3 F"(x)dx=40, 1 then the correct expression(s) is(are) 1 3 9('(3) + ('(1) - 32 = 0 (A) (B) f f(x)dx = 12 1 \.(9,( 9('(3) - ('(1) + 32 at =0 1 ff(X)dX=-I2 1 . t I C. ; , ,j .I ( 0, , I i I '. - it .J -" ! I \ ti / 'J '-' J 2'( r .( ! (f / I , [ --- -\2 i I '" _\ J- END OF THE QUESTION PAPER '.1 ", ,. " JJ 'I' j'l I' i I (..ih'.dl - -/2 r J " "', . I " , f" (':< ,:]" I J :»)(~ F (t) dl I I ** 1 30/32 ' eODEm .,' DARKENING THE BUBBLES ON THE ORS : 19. Use a BLACK BALL POINT PEN to darken the bubbles in the upper sheet. 20. Darken the bubble COMPLETELY. 21. Darken the bubbles ONLY if you are sure of the answer. 22. The correct way of darkening a bubble is as shown here: _ 23. There is NO way to erase or "un-darken" a darkened bubble. 24. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are evaluated. NAME OF THE CANDIDATE tS;ARA.N 5.1.M.'I ROLL NO .. Q.OjD.1~.i . . I HAVE READ ALL THE INSTRUCTIONS AND SHALL ABIDE BY THEM I have verified the identity, name and roll number of the candidate, and that question paper and ORS codes are the same Signature of the Invigilator Signature of the Candidate Space for rough work I ** 1 32/32 •
© Copyright 2024