PROBLEM 3.5 Determine the phase or phases in a system consisting of H2O at the following conditions and sketch the p-v and T-v diagrams showing the location of each state. (a) (b) (c) (d) (e) p = 100 lbf/in.2, T = 327.86oF p = 100 lbf/in.2, T = 240oF T = 212oF, p = 10 lbf/in.2 T = 70oF, p = 20 lbf/in.2 p = 14.7 lbf/in.2, T = 20oF (a) p = 100 lbf/in.2, T = 327.86oF 100 lbf/in.2 p Two-phase liquid-vapor mixture T 327.86oF 100 lbf/in.2 327.86oF (Table A-3E) v v (b) p = 100 lbf/in.2, T = 240oF p T<Tsat@p sub-cooled liquid 100 lbf/in.2 T 327.86oF . 100 lbf/in.2 327.86oF (Table A-3E) 240oF v . 240oF v Problem 3.5 (Continued) (c) T = 212oF, p = 10 lbf/in.2 p<psat@T superheated vapor p T 14.7 lbf/in.2 10 lbf/in.2 . 14.7 lbf/in.2 . o 212oF (Table A-3E) 10 lbf/in.2 212 F v v (d) T = 70oF, p = 20 lbf/in.2 p>psat@T sub-cooled liquid p . T 20 lbf/in.2 0.3632 lbf/in.2 (Table A-2E) 20 lbf/in.2 0.3632 lbf/in. 70oF . 2 v 2 70oF v o (e) p = 14.7 lbf/in. , T = 20 F p>psat@T solid (T is below the triple point temperature) p . 14.7 lbf/in. T 14.7 lbf/in.2 0.0505 lbf/in.2 (Table A-5E) 2 0.0505 lbf/in.2 20oF v . 20oF v PROBLEM 3.9 COMMENT: As the pressure increases, the difference in specific volume between saturated vapor and saturated liquid decreases. At the critical pressure, the two states coincide and the difference is zero. PROBLEM 3.20 PROBLEM 3.94 PROBLEM 3.102 PROBLEM 3.102 PROBLEM 3.111 As shown in Fig. 3.111, a piston-cylinder assembly fitted with a paddle wheel contains air, initially at p1 = 30 lbf/in.2, T1 = 540oF, and V1 = 4 ft3. The air undergoes a process to a final state where p2 = 20 lbf/in.2, V2 = 4.5 ft3. During the process, the paddle wheel transfers energy to the air by work in the amount 1 Btu, and there is energy transfer to the air by heat in the amount of 12 Btu. Assuming ideal gas behavior, and neglecting kinetic and potential energy effects, determine for the air (a) the temperature at state 2, in oR, and (b) the energy transfer by work from the air to the piston, in Btu. KNOWN: Data are provided for air contained in a piston-cylinder assembly fitted with a paddle wheel. FIND: For the process of the air, find the temperature at the final state and the energy transfer by work to the piston. SCHEMATIC AND GIVEN DATA: Q = - 12 Btu Wpw = - 1 Btu Wpist = ? ENGINEERING MODEL: 1. The air is the closed system. 2. Kinetic and potential energy effects are negligible. 3. The ideal gas model applies for the air. ANALYSIS: (a) Using the ideal gas equation of state m= = = 0.324 lb T2 = = = 750oR and (b) Noting that W = Wpw + Wpist and ΔU = m(u2 – u1) the energy balance reduces as follows. ΔKE + ΔPE + ΔU = Q – (Wpw + Wpist) Wpist = Q – Wpw – m(u2 – u1) From Table A-22E: u1 = 172.43 Btu/lb and u2 = 128.25 Btu/lb. Thus Wpist = ( 12 Btu) – ( 1 Btu) – (0.324 lb)(128.25 – 172.43)Btu/lb = 3.31 Btu (out) PROBLEM 3.117 As shown in Fig. P3.117, 20 ft3 of air at T1 = 600 oR, 100 lbf/in.2 undergoes a polytropic expansion to a final pressure of 51.4 lbf/in.2 The process follows pV1.2 = constant. The work is W = 194.34 Btu. Assuming ideal gas behavior for the air, and neglecting kinetic and potential energy effects, determine (a) the mass of air, in lb, and the final temperature, in oR. (b) the heat transfer, in Btu. KNOWN: Air undergoes a polytropic process in a piston-cylinder assembly. The work is known. FIND: Determine the mass of air, the final temperature, and the heat transfer. SCHEMATIC AND GIVEN DATA: T1 = 600oR p1 = 100 lbf/in.2 V1 = 20 ft3 P2 = 51.4 lbf/in.2 Q Air W = 194.34 Btu pV1.2 = constant p 100 ENGINEERING MODEL: 1. The air is a closed system. 2. Volume change is the only work mode. 3. The process is polytropic, with pV1.2 = constant and W = 194.34 Btu. 4. Kinetic and potential energy effects can be neglected. pv1.2 = constant .1 T1 51.4 ANALYSIS: (a) The mass is determined using the ideal gas equation of state. m= = = 9.00 lb To get the final temperature, we use the polytropic process, pV1.2 = constant, to evaluate V2 as follows. V2 = Now = (20 ft3) = 34.83 ft3 .2 T2 v PROBLEM 3.117 (CONTINUED) T2 = = 537oR = Alternative solution for T2 The work for the polytropic process can be evaluated using W = constant, and incorporating the ideal gas equation of state, we get W= . For the process pV1.2 = = Solving for T2 and inserting values T2 = + T1 = + (600oR) = 537oR (b) Applying the energy balance; ΔKE + ΔPE + ΔU = Q – W. With ΔU = m(u2 – u1), we get Q = m(u2 – u1) + W From Table A-22E: u(600oR) = 102.34 Btu/lb and u(537oR) = 91.53 Btu/lb. Thus, Q = (9.00 lb)(91.53 – 102.34)Btu/lb + (194.34 Btu) = 97.05 Btu (in) PROBLEM 3.132
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