Name: Mass Relationship in a Chemical Reaction Purpose: To determine the mass of copper produced and the % yield of copper when copper (II) chloride dihydrate is reacted with aluminum metal. Materials: Copper (II) chloride dihydrate (CuCl2 ● 2H2O ) and aluminum foil, beaker, stir stick, Bunsen burner, watch glass, lighter, tweezers, scale Method: 1. Determine the mass of a clean, dry 150 mL beaker. Add exactly 2 grams of copper (II) chloride dihydrate to the beaker. 2. Add 50 mL of water to the beaker and stir with a glass rod until the crystals have dissolved. (Note the colour of the solution.) 3. Fold a piece of 6 cm x 10 cm aluminum foil into a strip and bend it into a circle and put it into the solution in the beaker. 4. Heat the solution and let it boil gently for 5 minutes. There may be foaming in the first minutes. Don’t heat too strongly. Let the solution cool. (Note the colour of the solution and the solid product.) 5. Using tweezers, carefully remove as much aluminum foil as possible. Try not to take too much copper with it. 6. Decant the liquid into the drain as demonstrated by the teacher. Add 30 mL of water to the beaker. Stir well with the glass rod and decant the water into the drain. Repeat with another 30 mL of water. 7. Heat the beaker gently to dry the product. If the product starts to turn black, you are heating too strongly. 8. Let the beaker cool and mass the beaker and its contents. Record the mass. Data Table: Mass of empty Beaker Mass of beaker and CuCl2 ● 2H2O Exact mass of CuCl2 ● 2H2O added Mass of beaker and copper after heating Mass of just the copper I ) What two observations indicate that your reaction is complete? ________________________________________________________________________ II) Based on what you visually see, what reactant is in excess (left over)? ____________ Calculations: 1. Below is the reaction that you carried out. If you removed the H2O portions of the reaction, what type of reaction did you carry out? _____________________________________________ 3CuCl2 ● 2H2O + 2Al 3Cu + 2AlCl3 + 6H2O 2. i)What is the mole ratio of copper (II) chloride dihydrate to Copper? _______ ii) What is the mole ratio of copper (II) chloride dihydrate to aluminum? _______ 3. Determine the molar mass of CuCl2 ● 2H2O _________________ This dot means add 2 water molecules onto this compound as it is a hydrated compound 4. Using the 4 step mass-mass calculation taught in class, determine how many grams of copper you should have made when 2 g of copper (II) chloride dihydrate reacts with excess aluminum. 3CuCl2 ● 2H2O + 2Al 3Cu + 2AlCl3 + 6H2O 5. Looking at your actual yield of copper obtained from the lab, calculate your percent yield. 6. List 2 specific reasons as to why your percent yield is not 100%. 7. How many grams of aluminum would be required to react with 2.0 g of copper (II) chloride dihydrate? [ mass –mass problem] 8. How would the results of the experiment been affected if you had not used an excess of aluminum? 9. How would the results have been affected if you had heated the copper so strongly that it turned black? 10. Would a chemical reaction take place if a piece of copper was placed in a solution of Aluminum sulphate? Explain [hint: look at activity series]
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