Copper and Copper Alloys Compositions, Applications and Properties Copper and Copper Alloys Compositions, Applications and Properties Copper Development Association Publication No 120 April 1998, Revised and reprinted December 2004 MEMBERS, as at December 2004 BrazeTec Codelco Services Ltd Ecosea Ltd IBP Conex Mueller Europe Copper Tube & Fittings Noranda Islandi ehf Outokumpu Copper Metal Supplies Ltd Rio Tinto London Ltd Southern Peru Copper Corporation The British Non-Ferrous Metals Federation WMC Resources Ltd Yorkshire Copper Tube Ltd Yorkshire Fittings Ltd COPPER DEVELOPMENT ASSOCIATION is a non-trading organisation sponsored by the copper producers and fabricators to encourage the use of copper and copper alloys and to promote their correct and efficient application. Its services, which include the provision of technical advice and information, are available to those interested in the utilisation of copper in all its aspects. The Association also provides a link between research and the user industries and maintains close contact with other copper development organisations throughout the world. Acknowledgements CDA is glad to acknowledge with thanks the compilation of the data for this publication by Eur Ing John Westlake and the helpful comments made on this revision by David Parker. Disclaimer Whilst this document has been prepared with care, we can give no warranty regarding the contents and shall not be liable for any direct, incidental or consequential damage arising out of its use. For complete information on any material the appropriate standard should be consulted. Copper Development Association 5 Grovelands Business Centre Boundary Way Hemel Hempstead Hertfordshire HP2 7TE Tel: +44 (0)1442 275700 Fax: +44 (0)1442 275716 Email: [email protected] Websites: www.cda.org.uk www.brass.org (Revision of CDA Publication TN10, 1986) Copper and Copper Alloys Compositions, Applications and Properties • The Introduction explains the rationale of the EN series of standards • Section 1 (page 5) shows, where possible, the equivalents to the old • Section 2 (page 8) lists the ranges of compositions and properties of for coppers and copper alloys. British Standard materials. coppers and copper alloys included in the EN standards that replaced the old British Standards for these materials. For most materials it is easy to obtain near-equivalents to those included in previous standards. Full details of compositions and other requirements are included in the standards, obtainable from The British Standards Institution. • Section 3 (page 19) includes a selection of tables giving near-equivalents for the brasses previously included in the British Standards in order to simplify selection from the very wide range of materials now available. • The CDA Technical Helpline offers free advice on the selection and use of coppers and copper alloys. Telephone: 01442 275700 Fax: 01442 275716 Email: [email protected] Websites: www.cda.org.uk & www.brass.org i Copper and Copper Alloys Introduction to Standards CONTENTS Introduction to Standards 1 The EN Standards 1 Withdrawal of Old Standards 1 Numbers and Titles of Standards 1 Product Forms 1 Material Designations 1 Numbering System 1 Symbol Designations 2 Material Condition (Temper) Designations 2 Castings 2 Examples 2 Ordering Information 2 Typical Properties 2 Declarations of Conformity 2 Table 1 EN Standards for Copper and Copper Alloys 3 Table 2 Listing of Old BS Standards replaced by EN Standards 4 Symbols for Chemical Elements used as Alloying Additions or found as Impurities 4 Conversion Factors 4 Section 1: Conversion of old BS into EN Material Designations 5 Table 3 Unwrought and Wrought Coppers – Conversion of Old BS into EN Material Designations 5 Table 4 Wrought Copper Alloys – Conversion of Old BS into EN Material Designations 6 Table 5 Copper and Copper Alloy Ingots and Castings – Comparison of BS 1400 and EN 1982 7 Section 2: EN Coppers and Copper Alloys 8 Table 6a Unwrought and Wrought Coppers – Compositions, Uses and Typical Properties 8 Table 6b Unwrought and Wrought Coppers – Relevant Standards 9 Table 7 EN 1982 Copper and Copper Alloy Ingots and Castings – Compositions, Uses, and Typical Properties Table 8 Table 9 Table 10 Table 11 10/11 Wrought Low-Alloyed Copper Alloys – Compositions, Uses, Typical Mechanical Properties, Relevant Standards and Approximate Electrical Conductivity 12 Wrought Copper-aluminium, Copper-nickel and Copper-nickel-zinc Alloys – Compositions, Uses, Typical Properties, Relevant Standards and Machinability 13 Wrought Copper-zinc and Copper-tin Binary Alloys – Compositions, Uses and Typical Properties 14 Wrought Copper-zinc-lead Alloys (Leaded Brasses) – Compositions, Uses, Typical Properties, Relevant Standards and Machinability 15 Table 12a Wrought, Complex, Copper-zinc Alloys (Special Brasses) – Compositions, Uses and Typical Properties 16 Table 12b Wrought, Complex, Copper-zinc Alloys (Special Brasses) – Relevant Standards 17 Table 13 Copper and Copper Alloys for Welding and Braze Welding – Composition and Melting Ranges (EN 13347) Section 3: Brass Semi-Finished Products 18 19 Table 14 Brass Rods and Sections – Compositions, Uses and Typical Properties 19 Table 15 Brass Forgings, Stampings and Hot Pressings – Compositions, Uses and Typical Properties 20 Table 16 Brass Sheet, Strip and Plate – Compositions, Uses and Typical Properties 21 Table 17 Brass Tubes – Compositions, Uses and Typical Properties 22 Table 18 Brass Wire – Compositions, Uses and Typical Properties 23 ii Copper and Copper Alloys Compositions, Introduction Applications to Standards and Properties Introduction The EN Standards Product Forms The EN series of standards for copper and copper alloys offers As part of the standardisation process, uniform definitions have now been adopted for all product forms. This will result in some products having new terminology. As an example, the term ‘wire’ now includes all material made in coil form. a selection of materials to suit a very wide variety of end uses. They represent a consensus agreement on those most frequently ordered by consumers. Commencing in the late 1980s, drafting of European Material Designations Standards for Copper and Copper Alloys became a major Material designations (individual copper and copper alloy identifications) are in two forms, symbol and number. As with many other existing European national standards, symbols are based on the ISO compositional system (e.g. CuZn37 is 63/37 brass). ISO and EN symbols may be identical but the detailed compositional limits are not always identical and cannot be assumed to refer to unique materials. activity for national standards’ organisations and their industrial partners. Because a large number of national preferences have needed to be taken into account against the background of a panEuropean agreement to develop tight product standards, the EN standards are more complex than the old BS standards. Furthermore, the EN standards tend to cover narrower fields Numbering System than BS standards; hence there are more alloys in the EN A new numbering system has therefore been developed to offer a more user- and computer-friendly alternative. The system is a 6-character, alpha-numeric series, beginning C for copper based material; the second letter indicates the product form as follows:- series than in the old BS standards. This publication summarises the main compositions and the range of properties. For full details refer to the standards documents obtainable from: The British Standards B – Materials in ingot form for re-melting to produce cast products C – Materials in the form of cast products F – Filler materials for brazing and welding M – Master alloys conflict with the old British Standards. These were R – Refined unwrought copper withdrawn, as were those of other European countries, S – Materials in the form of scrap W– Materials in the form of wrought products X – Non-standardised materials Institution, 398 Chiswick High Road, London W4 4AL. Tel: 020 8996 9001 Fax: 020 8996 7001 www: bsi-global.com Withdrawal of Old Standards As the new standards have been published they were in leaving Europe with one harmonised series of standards published in each country but applicable across all. The majority of the new standards, published or due A three-digit number series in the 3rd, 4th and 5th places is used to designate each material and can range from 001 to 999. Numbers are allocated in preferred groups, each series being shown below. The sixth character, a letter, indicates the copper or alloy grouping as follows:Number series Letters Materials during the period 1996-2003, caused withdrawal of conflicting national standards such as BS 1400 for castings, the BS 287x series for wrought materials and the BS 143x series covering coppers for electrical purposes. Materials popularly used from the old BS standards continue to be available but the new designations should be used. Numbers and Titles of Standards Table 1 shows EN standards’ titles, categorised by product 000-099 A or B Copper 100-199 C or D Copper alloys, low alloyed (less than 5% alloying elements) 200-299 E or F Miscellaneous copper alloys (5% or more alloying elements) 300-349 G Copper–aluminium alloys type, and the BS standards that have been replaced. During the standardisation process, at the stage of draft for public comment, an EN number is allocated. At this stage drafts are identified with the prefix ‘pr’. After successful formal vote, when the draft is approved for publication throughout Europe, the EN implementation uses the same number. 350-399 H Copper–nickel alloys 400-449 J Copper–nickel–zinc alloys 450-499 K Copper–tin alloys 500-599 L or M Copper–zinc alloys, binary Table 2 shows old BS standard numbers in numerical order 600-699 N or P Copper–zinc–lead alloys and their replacement EN standards. 700-799 R or S Copper–zinc alloys, complex 1 Copper and Copper Alloys Introduction to Standards Symbol Designations Examples ● The symbols used are based on the ISO designation system (ISO 1191 Pt1). CW614N – R420 refers to wrought CuZn39Pb3 copper-zinc-lead alloy to be supplied to a minimum tensile strength of 420 N/mm2 CC750S-GS refers to sand cast CuZn33Pb2 copper-zinc duplex alloy ● The principal element, copper, is first. ● Other alloying elements are included in decreasing order of percentage content. ● Where contents are similar, alphabetical order may be used. Ordering Information ● The numbers after elements represent nominal compositions. Each product standard gives examples of the full ordering information required including quantity, product form, standard number, designation, condition, tolerances and packaging. ● No number is normally used if the nominal composition is less than 1%. Material Condition (Temper) Designations Typical Properties Material condition (alternative term – temper) designations are defined in EN 1173. In most product standards, materials are available in a choice of material conditions. Depending on the product standard there may be one or more mandatory properties associated with the particular material condition. For designation purposes the principal mandatory property for each material condition is identified by a letter, as follows:A – B – D – G – H – M – R – Y – In Tables 6 to 12, typical properties are usually shown as ranges. For materials available in both ‘soft’ condition, for example as forging stock, and ‘very hard’, for example as spring wire, then the ranges are very wide. Tables 14 to 18 show typical properties for ranges of brasses similar to those previously included in British Standards in order to give a closer idea of the range of properties available in each product form. Elongation Spring bending limit As drawn, without specified mechanical properties Grain size Hardness (Brinell or Vickers) As manufactured, without specified mechanical properties Tensile strength 0.2% proof strength It is vital that designers and purchasers consult with suppliers to clarify what property values and combinations are available to be best fit for purpose in the desired product form. Declarations of Conformity Where the full quality systems standardised in EN ISO 9001 series of standards are not required, a declaration of conformity may still be needed to confirm compliance with order requirements: In EN 1655 ‘Copper and Copper Alloys – Declarations of Conformity’, four levels of declaration of conformity are available: Products can only be ordered to one material condition and not a combination. However, besides the designating property, other properties may be mandatory; check the standard document for full details. Type A for suppliers who do not have a certified quality assurance scheme. Normally three digits, but in a few instances four digits, follow the material condition designating letter, where appropriate, to indicate the value of the mandatory property with the possibility of a final character, ‘S’, for the stress relieved condition. Normally the value refers to a minimum for the property. Sometimes, as with grain size, it refers to a nominal mid-range value. Type B for suppliers who do not have a certified quality assurance scheme but have access to an accredited laboratory. Tables 6 to 12 show not only the existence of copper or copper alloys in particular standards but also the material conditions available as mandatory properties within those standards. Type D for suppliers who have both a certified quality assurance scheme and access to an assessed laboratory. Type C for suppliers who have a certified quality assurance scheme but do not have access to an accredited laboratory. These declarations are more specific than those based on systems used for steels included in EN 10204 ‘Metallic Products – Types of Inspection Documents’. Castings For castings, properties are dependent on the casting process used. This is designated according to the system: GS sand casting GM permanent mould casting GZ centrifugal casting GC continuous casting GP pressure diecasting 2 Copper and Copper Alloys Introduction to Standards Table 1: EN Standards for Copper and Copper Alloys EN Number Unwrought Products 1976 1977 1978 1981 1982 Rolled Flat Products 1172 1652 1653 1654 1758 13148 14436 Tubes 1057 12449 12450 12451 12452 12735 13348 13349 Rod/Bar, Wire, Profiles 12163 12164 12165 12166 12167 12168 13347 Electrical Purposes 13599 13600 13601 13602 13604 13605 60317-0-1 Forgings and Fittings 1254 Pt 1-5 prEN1254 Pt 6-7 12420 prEN14905 Test Methods 723 1971 12384 12893 13147 13603 ISO 196 ISO 2624 ISO 2626 ISO 6509 Miscellaneous 1173 1412 1655 10204 12861 CR13388 Title Nearest Old BS Equivalent Cast unwrought copper products Copper drawing stock (wire rod) Copper cathodes Master alloys Ingots and castings 6017 6926 6017 1400 Sheet and strip for building purposes Plate, sheet, strip and circles for general purposes Plate, sheet and circles for boilers, pressure vessels and hot water storage units Strip for springs and connectors Strip for lead frames Hot dip tinned strip Electrolytically tinned strip 2870 2870, 2875 2870, 2875 2870 - Seamless, round tubes for water and gas in sanitary and heating applications Seamless, round tubes for general purposes Seamless, round capillary tubes Seamless, round tubes for heat exchangers Rolled, finned, seamless tubes for heat exchangers Seamless round tubes for air conditioning and refrigeration Part 1: Tubes for piping systems Part 2: Tubes for equipment Seamless, round copper tubes for medical gases Pre-insulated copper tubes with solid covering 2871 Pt 1 2871 Pt 2 2871 Pt 3 - Rod for general purposes Rod for free machining purposes Wrought and unwrought forging stock Wire for general purposes Profiles and rectangular bar for general purposes Hollow rod for free machining purposes Rod and wire for welding and braze welding 2874 2874 2872 2873 2874 1453, 1845, 2901 Copper plate, sheet and strip for electrical purposes Seamless copper tubes for electrical purposes Copper rod, bar and wire for general electrical purposes Drawn round copper wire for the manufacture of electrical conductors Products of high conductivity copper for electronic tubes, semiconductor devices and vacuum applications Copper profiles for electrical purposes Enamelled copper wire 4608 1977 1433, 1432, 4109 4109 3839 6811 Plumbing fittings Plumbing fittings 864 - Forgings Recommended practice for the installation of plumbing fittings 2872 - Combustion method for determination of carbon on the inner surface of copper tubes or fittings Eddy current test for tubes Determination of spring bending limit on strip Determination of spiral elongation number Determination of residual stresses in the border area of strip Test methods for assessing protective tin coatings on drawn round copper wire for electrical purposes Detection of residual stress - mercury(l) nitrate test Estimation of average grain size Hydrogen embrittlement test Determination of dezincification resistance of brass DD79 5899 - Material condition or temper designation European numbering system Declarations of conformity Metallic products - types of inspection documents Scrap Copper and copper alloys - Compendium of compositions and products - 3 Copper and Copper Alloys Introduction to Standards Table 2: Listing of Old BS Standards replaced by EN Standards Old BS Standard Title (abbreviated) EN Standards 1400 Copper and copper alloy ingots and castings 1982 1432 Drawn copper strip for electrical purposes 13601 1433 Copper rod and bar for electrical purposes 13601 1434 Copper sections in bars, blanks and segments for commutators (electrical purposes) n/a 1453 Filler metals for gas welding 13347 1845 Filler metals for brazing 13347 1977 Copper tubes for electrical purposes 13600 2870 Sheet, strip and foil 1172, 1652, 1653, 1654 2871 Pt 1 Tubes for water, gas and sanitation 1057 2871 Pt 2 Tubes for general purposes 12449 2871 Pt 3 Tubes for heat exchangers 12451 2872 Forgings and forging stock 12165, 12420 2873 Wire 12166 2874 Rods and sections 12163, 12164, 12167 2875 Pt 3 Plate 1652, 1653 2901 Copper and copper alloy filler wires for gas shielded arc welding 13347 3839 Oxygen free high conductivity copper for electronic tubes and semiconductor devices 13604 4109 Copper wire for electrical purposes 13602 4577 Materials for resistance welding electrodes n/a 4608 Copper sheet, strip and foil for electrical purposes 13599 6017 Copper refinery shapes 1976, 1978 6811 Winding wires (part) 13602 6926 Copper wire rod for electrical purposes 1977 Symbols for chemical elements used as alloying additions or found as impurities Conversion factors Ag Al As Au B Be Bi Cd Co Cr Fe Mn Nb Ni O P Pb S Sb Si Sn Te Zn Zr The following conversions may be used for other units: 1N/mm2 = 1 MPa = 10-1 hbar = 6.4749 x 10-2 tonf/in2 = 145.038 lbf/in2 = 0.101972 kgf/mm2 All units quoted are those used in the relevant standards. Silver Aluminium Arsenic Gold Boron Beryllium Bismuth Cadmium Cobalt Chromium Iron Manganese Niobium Nickel Oxygen Phosphorus Lead Sulphur Antimony Silicon Tin Tellurium Zinc Zirconium 4 Copper and Copper Alloys Section 1: Conversion of Old BS into EN Material Designations Table 3: Unwrought and Wrought Coppers - Conversion of Old BS into EN Material Designations EN Material Designation Nearest Old BS Equivalent Number Main Table Number Symbol Wrought Unwrought Wrought Unwrought Copper Cathode 6a, 6b - Cu-CATH-1 Cu-CATH-1 - CR001A - Cu-CATH-2 Cu-CATH-2 - CR002A C100 - Cu-ETP1 CW003A CR003A - - Cu-OF1 CW007A CR007A Cu-OFE Cu-OFE CW009A CR009A - Cu-PHCE CW022A CR022A Coppers ex Cu-CATH-1 C110 - 6a, 6b Other Unalloyed Coppers 6a, 6b C101 Cu-ETP-2 Cu-ETP CW004A CR004A C102 Cu-FRHC Cu-FRHC CW005A CR005A C103 Cu-OF Cu-OF CW008A CR008A C104 Cu-FRTP Cu-FRTP CW006A CR006A C105 Cu-AS - - - Phosphorus - containing Coppers 6a, 6b - - Cu-PHC CW020A CR020A - - Cu-HCP CW021A CR021A - - Cu-DLP CW023A CR023A Cu-DHP Cu-DHP CW024A CR024A - Cu-DXP - CR025A Cu-AsP - - - C106 C107 Silver-bearing Coppers 6a, 6b Tough Pitch C101 Cu-Ag-2 CuAg0.04 CW011A CR011A C101 Cu-Ag-3 CuAg0.07 CW012A CR012A C101 Cu-Ag-4 CuAg0.10 CW013A CR013A - - CuAg0.04P CW014A CR014A - - CuAg0.07P CW015A CR015A - - CuAg0.10P CW016A CR016A Cu-Ag-OF2 CuAg0.04(OF) CW017A CR017A - CuAg0.07(OF) CW018A CR018A Cu-Ag-OF4 CuAg0.10(OF) CW019A CR019A Phosphorus Deoxidised Oxygen Free C103 C103 5 Copper and Copper Alloys Conversion of Old BS into EN Material Designations Table 4: Wrought Copper Alloys – Conversion of Old BS into EN Material Designations (These are arranged broadly in increasing order of alloying content) Nearest Old BS Equivalent EN Material Designation Symbol Number Heat-treatable Alloys CB101 CuBe1.7 CuBe2 CuBe2Pb CuCo1Ni1Be C112 CuCo2Be CuNi2Be CC101 CuCr1 CC102 CuCr1Zr C113 CuNi1P CuNi1Si CuNi2Si CuNi3Si1 CuZr Non Heat-treatable Alloys - Free Machining CuPb1P C109 CuTeP C111 CuSP Non Heat-treatable Alloys - Other CuFe2P CuSi1 CS101 CuSi3Mn CuSn0.15 CuZn0.5 C108 CuCd CuCd0.7 CuCd1.0 Copper-tin (Phosphor Bronze) PB101 CuSn4 PB102 CuSn5 PB103 CuSn6 PB104 CuSn8 CuSn8P CuSn4Pb2P CuSn4Te1P CuSn5Pb1 CuSn8PbP CuSn3Zn9 CuSn4Pb4Zn4 Copper-zinc (Brass) CZ125 CuZn5 CZ101 CuZn10 CZ102 CuZn15 CZ103 CuZn20 CuZn28 CZ106 CuZn30 CuZn33 CZ107 CuZn36 CZ108 CuZn37 CZ109 CuZn40 Copper-zinc-lead Alloys (Leaded Brasses) CZ104 CZ124 CuZn36Pb3 CZ121Pb4 CuZn38Pb4 CZ121Pb3 CuZn39Pb3 CZ122 CuZn40Pb2 CZ119 CuZn37Pb2 CZ131 CuZn37Pb2 CZ120 CuZn38Pb2 CZ128 CuZn38Pb2 CZ120 CuZn39Pb2 CZ128 CuZn39Pb2 CZ118 CuZn35Pb1 CZ119 CuZn35Pb2 CZ131 CuZn35Pb2 CuZn38Pb1 CZ123 CuZn39Pb0.5 CZ137 CuZn39Pb0.5 CZ129 CuZn39Pb1 CZ132 CuZn36Pb2As CuZn39Pb2Sn CuZn40Pb2Sn CuZn39Pb3Sn CuZn40Pb1Al CuZn40Pb2Al CuZn41Pb1Al EN Material Designation Symbol Number Copper-zinc-lead Alloys (Leaded Brasses) - continued CuZn42PbAl CW621N CuZn43Pb1Al CW622N CZ130 CuZn43Pb2Al CW624N CZ130 CuZn43Pb2 CW623N Table No Nearest Old BS Equivalent 8 CW100C CW101C CW102C CW103C CW104C CW110C CW105C CW106C CW108C CW109C CW111C CW112C CW120C - CuZn37Pb0.5 CW604N - CuZn37Pb1 CW605N Copper-zinc Alloys (Special Brasses) – (Corrosion Resistant Alloys) CZ127 CuZn13Al1Ni1Si1 CZ110 CuZn20Al2As CZ111 CuZn28Sn1As CZ126 CuZn30As CZ105 CuZn30As CuZn38AlFeNiPbSn CuZn38Sn1As CuZn32Pb2AsFeSi CZ134 CuZn36Pb2Sn1 CZ112 CuZn36Sn1Pb CZ113 CuZn37Pb1Sn1 CZ133 CuZn39Sn1 High Tensile Brasses CuZn23Al6Mn4Fe3Pb CZ116 CuZn25Al5Fe2Mn2Pb CuZn35Ni3Mn2AlPb CZ114 CuZn40Mn1Pb1AlFeSn CZ115 CuZn40Mn1Pb1FeSn CuZn31Si1 CZ135 CuZn37Mn3Al2PbSi CuZn39Mn1AlPbSi Other Brasses CuZn19Sn CuZn23Al3Co CuZn38Mn1Al CZ136 CuZn40Mn1Pb1 CuZn40Mn2Fe1 Copper-aluminium (Aluminium Bronze) CuAl5As CA101 CA107 CuAl6Si2Fe CuAl7Si2 CA106 CuAl8Fe3 CA102 CA105 CuAl9Ni3Fe2 CA103 CuAl10Fe1 CuAl10Fe3Mn2 CA104 CuAl10Ni5Fe4 CuAl11Fe6Ni6 Copper-nickel CN105 CuNi25 CN101 CuNi9Sn2 CN102 CuNi10Fe1Mn CN103 CN104 CN106 CN108 CuNi30Fe2Mn2 CN107 CuNi30Mn1Fe Copper-nickel-zinc (Nickel Silver) NS103 CuNi10Zn27 NS104 CuNi12Zn24 NS111 CuNi12Zn25Pb1 CuNi12Zn29 CuNi12Zn30Pb1 NS105 NS112 NS113 CuNi18Zn19Pb1 NS106 CuNi18Zn20 NS107 CuNi18Zn27 NS108 NS109 CuNi7Zn39Pb3Mn2 NS101 CuNi10Zn42Pb2 CuNi12Zn38Mn5Pb2 8 CW113C CW118C CW114C 8 CW107C CW115C CW116C CW117C CW119C CW130C CW131C 10 CW450K CW451K CW452K CW453K CW459K CW455K CW457K CW458K CW460K CW454K CW456K 10 CW500L CW501L CW502L CW503L CW504L CW505L CW506L CW507L CW508L CW509L 11 CW603N CW609N CW614N CW617N CW606N CW606N CW608N CW608N CW612N CW612N CW600N CW601N CW601N CW607N CW610N CW610N CW611N CW602N CW613N CW619N CW615N CW616N CW618N CW620N continued top right 6 Table No 11 12 CW700R CW702R CW706R CW707R CW707R CW715R CW717R CW709R CW711R CW712R CW714R CW719R 12 CW704R CW705R CW710R CW721R CW722R CW708R CW713R CW718R 12 CW701R CW703R CW716R CW720R CW723R 9 CW300G CW301G CW302G CW303G CW304G CW305G CW306G CW307G CW308G 9 CW350H CW351H CW352H CW353H CW354H 9 CW401J CW403J CW404J CW405J CW406J CW408J CW409J CW410J CW400J CW402J CW407J Copper and Copper Alloys Conversion of Old BS into EN Material Designations Table 5: Copper and Copper Alloy Ingots and Castings - Comparison of BS 1400 and EN 1982 Showing near equivalents where standardised in EN 1982 and original compositional symbols for guidance where no near equivalent is included. See Table 7 for full details of compositions and properties. EN Relevant Casting Processes and Designations (3) Nearest Equivalent in Old BS 1400 or BS 4577 EN or ISO Symbol for Castings (1) EN Material Designation Number for Castings (2) GM GS GZ GP GC Die Casting Sand Centrifugal Pressure Die Continuous Copper and Copper-chromium (High Conductivity Coppers) HCC1 Cu-C CC040A ✱ ✱ CC1-TF CuCr1-C CC140C ✱ ✱ A4/1 G-CuNiP – A3/2 G-CuNi2Si – A3/1 G-CuCo2Be – A4/2 G-CuBe – Copper-zinc (Brasses) ✱ ✱ DZR1 CuZn35Pb2Al-C CC752S DZR2 CuZn33Pb2Si-C CC751S - CuZn37Pb2Ni1AlFe-C CC753S PCB1 G-CuZn40Pb – DCB1 CuZn38Al-C CC767S DCB2 G-CuZn37Sn – DCB3 CuZn39Pb1Al-C CC754S ✱ - CuZn39Pb1AlB-C CC755S ✱ SCB1 G-CuZn25Pb3Sn2 – SCB2 G-CuZn30Pb3 – SCB3 CuZn33Pb2-C CC750S SCB4 G-CuZn36Sn – SCB5 G-CuZn10Sn – SCB6 CuZn15As-C CC760S - CuZn16Si4-C CC761S - CuZn32Al2Mn2Fe1-C CC763S - CuZn34Mn3Al2Fe1-C CC764S ✱ ✱ ✱ HTB1 CuZn35Mn2Al1Fe1-C CC765S ✱ ✱ ✱ ✱ HTB2 G-CuZn36Al4FeMn HTB3 CuZn25Al5Mn4Fe3-C CC762S ✱ ✱ ✱ ✱ - CuZn37Al1-C CC766S ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ – Copper-tin (Gunmetals and Phosphor Bronzes) CT1 CuSn10-C CC480K ✱ ✱ ✱ ✱ PB1 CuSn11P-C CC481K ✱ ✱ ✱ ✱ - CuSn11Pb2-C CC482K ✱ ✱ ✱ PB2 CuSn12-C CC483K ✱ ✱ ✱ CT2 CuSn12Ni2-C CC484K ✱ ✱ ✱ PB4 G-CuSn10PbP – LPB1 G-CuSn7PbP – ✱ Copper-tin-lead (Gunmetals and Leaded Bronzes) ✱ ✱ ✱ ✱ ✱ ✱ ✱ CC492K ✱ ✱ ✱ ✱ CC493K ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ LG1 CuSn3Zn8Pb5-C CC490K LG2 CuSn5Zn5Pb5-C CC491K LG3 G-CuSn7Pb4Zn2 – LG4 CuSn7Zn2Pb3-C - CuSn7Zn4Pb7-C LB1 CuSn7Pb15-C CC496K LB2 CuSn10Pb10-C CC495K LB3 G-CuSn10Pb5 – LB4 CuSn5Pb9-C CC494K LB5 CuSn5Pb20-C CC497K G1 G-CuSn10Zn2 – G2 G-CuSn8Zn4Pb – G3 G-CuSn7Ni5Zn3 – Copper-aluminium (Aluminium Bronzes) - CuAl9-C CC330G ✱ AB1 CuAl10Fe2-C CC331G ✱ ✱ ✱ ✱ ✱ - CuAl10Ni3Fe2-C CC332G ✱ ✱ ✱ ✱ AB2 CuAl10Fe5Ni5-C CC333G ✱ ✱ ✱ ✱ - CuAl11Fe6Ni6-C CC334G ✱ ✱ ✱ AB3 G-CuAl6Si2Fe – Copper-manganese-aluminium CMA1 CuMn11Al8Fe3Ni3-C CC212E CMA2 G-CuMn13Al9Fe3Ni3 – ✱ Copper-nickel (Cupro-nickels) - CuNi10Fe1Mn1-C CC380H ✱ ✱ - CuNi30Fe1Mn1-C CC381H ✱ ✱ CN1 CuNi30Cr2FeMnSi-C CC382H ✱ CN2 CuNi30Fe1Mn1NbSi-C CC383H ✱ Notes: (1) Symbol finishes with B for material in ingot form (2) Number begins CB for material in ingot form NB: Ingots are not specified for high conductivity coppers (3) GM - permanent mould casting GS - sand casting GZ - centrifugal GP - pressure die casting GC - continuous casting Method of casting affects properties significantly. 7 ✱ CR002A CR007A CR009A CR022A Cu-OF1 Cu-OFE Cu-PHCE CR005A CR008A CR006A Cu-FRHC Cu-OF Cu-FRTP 8 CR023A CR024A CR025A Cu-DLP Cu-DHP Cu-DXP CR012A CR013A Cu-Ag 0.04 Cu-Ag 0.10 CR015A CR016A Cu-Ag 0.07P Cu-Ag 0.10P CR018A CR019A Cu-Ag 0.07(OF) Cu-Ag 0.10(OF) Rem. CW019A CW018A CW017A CW016A CW015A CW014A CW013A CW012A CW011A – CW024A CW023A CW021A Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. 99.90 min. 99.90 min. 99.90 min. 99.95 min. 99.95 min. 99.90 min. CW006A CW020A 99.95 min. 99.90 min. 99.90 min. 99.99 min. 99.99 min. Rem. Rem. 99.90 min. CW008A CW005A CW004A CW022A CW009A CW007A CW003A – – Wrought Cu (incl. 0.015 max Ag) Cu-DHP – P 0.015-0.040 0.03 excl. Ag, Ni & P (P 0.04-0.06) Cu-Ag-OF2 Cu-Ag-OF4 0.0065 excl. Ag & O (Ag 0.08-0.12) - 0.03 excl. Ag & P (Ag 0.08-0.12) P 0.001-0.007 0.0065 excl. Ag & O (Ag 0.06-0.08) - 0.03 excl. Ag & P (Ag 0.06-0.08) P 0.001-0.007 0.0065 excl. Ag & O (Ag 0.03-0.05) - 0.03 excl. Ag & P (Ag 0.03-0.05) P 0.001-0.007 Cu-Ag-4 Cu-Ag-3 Cu-Ag-2 – 0.03 excl. Ag, Ni & P (P 0.005-0.013) 0.03 excl. Ag & O (Ag 0.03-0.05) 0.04 max 0.03 excl. Ag & O (Ag 0.06-0.08) 0.04 max 0.03 excl. Ag & O (Ag 0.08-0.012) 0.04 max – 0.03 excl. Ag & P (P 0.002-0.007) – Cu-FRTP 0.05 excl. Ag, Ni, O 0.03 excl. Ag & P (P 0.001-0.006) Cu-OF Cu-FRHC 0.04 excl. Ag, O 0.03 excl. Ag Cu-ETP-2 – P 0.001-0.006 plus 14 elements listed individually 0.03 excl. Ag, O Cu-OFE Cu-OF 0.0065 excl. O 15 elements listed individually Cu-ETP1 Cu-CATH-2 0.0065 excl. O 0.04 max O Cu-CATH-1 0.03 excl. Ag, O Unwrought (BS 6017) 0.0065 excl. O 0.04 max O Max of 19 listed elements (2), other than Cu C103 - C103 - - - C101 C101 C101 – C106 – – – C104 C103 C102 C101 – C110 C103 C100 – – Wrought Nearest Old BS Equivalent 0.15176 Good creep resistance to 250ºC (short times at 350ºC). Increasing additions of silver give increase in creep strength and resistance to softening in elevated service temperatures. 0.15328 0.15328 0.15328 0.15596 0.15596 0.15596 0.15328 0.15328 0.15328 – – – 0.15596 0.15328 – Phosphorus deoxidised coppers for general and chemical engineering applications, particularly when brazing or welding is involved. PHC & HCP are suited to electrical applications. Cu-DXP is used for anodes for electroplating. 0.15328 General engineering and building applications - not in reducing atmospheres. 0.15328 0.15328 Oxygen-free version of Cu-ETP for use in reducing atmospheres. Suitable for conductors and fabricated electrical components but not in reducing atmospheres. 0.15176 Oxygen-free and low phosphorus coppers, suitable for use in electronic vacuum devices. 0.15328 0.15176 Oxygen-free version of ETP1 for use in reducing atmospheres. 0.15328 0.15176 Max. Mass Resistivity (Ω g/m2) For re-draw to wire; suitable for high speed annealing and enamelling. Flat products for remelting made by electrolytic deposition. Characteristics and Uses 100.0 100.0 100.0 98.3 98.3 98.3 100.0 100.0 100.0 – – – 98.3 100.0 – 100.0 100.0 100.0 100.0 101.0 101.0 101.0 100.0 101.0 Nominal Min. Conductivity (% IACS) Electrical Properties at 20ºC (Annealed) Table 6a: Unwrought (1) and Wrought Coppers – Compositions, Uses and Typical Properties Composition, %, Range or Max (1) Unwrought coppers in EN 1976 – Cast Unwrought Copper Products and EN 1978 - Copper Cathodes (2) Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te, Zn Notes: CR017A Cu-Ag 0.04(OF) Oxygen Free CR014A Cu-Ag 0.04P Phosphorus Deoxidised CR011A Cu-Ag 0.04 Tough Pitch Silver–bearing Coppers CR021A CR020A Cu-HCP Cu-PHC Phosphorus–containing Coppers CR004A Cu-ETP Other Unalloyed Coppers CR003A Cu-ETP1 Coppers ex Cu-CATH-1 CR001A Cu-CATH-2 Unwrought Cu-CATH-1 Copper Cathode Symbol Number Material Designation 50-340 50-340 50 50-340 50-340 50-340 – – 0.2% Proof Strength (N/mm2) – – Elongation (%) 50-5 50-5 50-5 30 50-5 50-5 Properties similar to those for Cu-ETP at ambient temperatures Properties similar to those for Cu-DLP 200-400 200-400 200 Properties similar to those for Cu-DLP 200-400 200-400 Properties similar to those for Cu-ETP 200-400 Properties similar to those for Cu-ETP – – Tensile Strength (N/mm2) Typical Mechanical Properties 40-120 40-120 45 40-120 40-120 40-120 – – Hardness (HV) Copper and Copper Alloys Section 2: EN Coppers and Copper Alloys CW022A CR009A CR022A Cu-OFE Cu-PHCE CR006A 9 CR021A CR023A CR024A CR025A Cu-HCP Cu-DLP Cu-DHP Cu-DXP CW015A CW016A CR012A CR013A CR014A CR015A CR016A CR017A CR018A CR019A CuAg0.07 CuAg0.10 CuAg0.04P CuAg0.07P CuAg0.10P CuAg0.04(OF) CuAg0.07(OF) CuAg0.10(OF) RH RH RH RH R R Plate, Sheet, Circles (4) Plate, Strip, Sheet, Circles (3) RH 1653 1652 (2) A – mandatory elongation D – cold worked E – mandatory hydrogen embrittlement test G – mandatory grain size Notes: (1) Unwrought coppers in EN 1976 – Cast Unwrought Copper Products and EN 1978 – Copper Cathodes CW019A CW018A CW017A CW014A CW013A CW012A CR011A CW011A – CW024A CW023A CW021A CW020A CuAg0.04 Silver-bearing Coppers CR020A Cu-PHC Phosphorus-containing Coppers CW008A CR008A Cu-OF Cu-FRTP CW006A CW005A CR005A Cu-FRHC CW004A CR004A Cu-ETP Other Unalloyed Coppers CW009A CR007A Cu-OF1 CW007A CR003A Cu-ETP1 CW003A – CR002A Cu-CATH-2 Coppers ex Cu-CATH-1 – Wrought CR001A Unwrought Number Cu-CATH-1 Copper Cathode Symbol Material Designation (3) (4) RH Strip for Lead Frames 1758 MH MH MH MH Forging Stock 12165 MRHG Wire MRH MRH Profiles, Rectangular Bar 12167 MRH Tubes (3) 12449 RH Tubes for Heat Exchangers 12451 RH Copper Drawing Stock (Wire Rod) Finned Tubes for Heat Exchangers EV EV EV EV EV MRH MRH DRH DRH DRH DRH DRH DRH DRH DRH DRH EV DRH V DRH DRH DRH DRH DRH V DRH DRH DRH DRH DRH DRH DRH MRH MRH MRH Copper Rod, Bar, Wire 13601 (For Electrical Purposes) Seamless Copper Tubes 13600 V EV EV MRH MRH V EV MRH Copper Plate, Sheet, Strip 13599 V EV EV EV SV 1977 12452 Inclusion in the following EN Standards with Indicated Material Conditions (2) 12166 H – mandatory hardness M – as manufactured R – mandatory tensile strength S – spiral elongation test V – volume resistivity test For general purposes For boilers, pressure vessels and hot water storage units MRH MRH MRH Rod (3) 12163 Table 6b: Unwrought (1) and Wrought Coppers - Relevant Standards AR AR AR AR AR Drawn Round Copper Wire 13602 DRH DRH DRH DRH DRH DRH DRH DRH DRH DRH DRH DRH DRH DRH Copper Profiles 13605 Copper and Copper Alloys EN Coppers and Copper Alloys Number for Castings (2) Cu Al Fe CC140C CuCr1-C 10 CC751S CC752S CC753S CC754S CC755S CC760S CC761S CC762S CC763S CC764S CC765S CC766S CC767S CuZn33Pb2Si-C CuZn35Pb2Al-C CuZn37Pb2Ni1AlFe-C CuZn39Pb1Al-C CuZn39Pb1AlB-C CuZn15As-C CuZn16Si4-C CuZn25Al5Mn4Fe3-C CuZn32Al2Mn2Fe1-C CuZn34Mn3Al2Fe1-C CuZn35Mn2Al1Fe1-C CuZn37Al1-C CuZn38Al-C 59.0 - 64.0 60.0 - 64.0 57.0 - 65.0 55.0 - 66.0 59.0 - 67.0 60.0 - 67.0 78.0 - 83.0 83.0 - 88.0 59.5 - 61.0 58.0 - 63.0 58.0 - 61.0 0.1 - 0.8 0.3 - 1.8 0.5 - 2.5 1.0 - 3.0 1.0 - 2.5 3.0 - 7.0 CC481K 87.0 - 89.5 CC482K 83.5 - 87.0 CC483K 85.0 - 88.5 CC484K 84.5 - 87.5 CuSn11P-C CuSn11Pb2-C CuSn12-C CuSn12Ni2-C Mn Ni P Pb Composition, %, Range or Max Si Sn 0.60 0.40 0.5 - 1.0 0.2 1.5 - 2.5 0.05 - 0.40 2.0 2.0 2.0 1.0 2.0 6.0 3.0 2.5 3.0 1.0 1.0 0.5 - 1.2 0.8 0.7 1.0 - 2.5 1.0 1.5 0.8 1.2 - 1.7 0.5 - 2.5 1.8 - 2.5 1.5 - 2.5 1.0 3.0 - 5.0 1.3 - 2.2 0.065 - 1.1 1.0 - 3.0 (4) GM – permanent mould casting GS – sand casting GZ – centrifugal casting GP – pressure die casting GC – continuous casting 0.5 - 2.0 0.5 - 3.0 0.5 - 2.5 1.0 - 4.0 0.5 - 2.0 1.0 - 3.5 1.5 - 4.0 2.5 - 5.0 0.05 - 0.2 0.5 - 0.8 0.25 - 0.5 1.0 11.0 - 13.0 11.0 - 13.0 10.5 - 12.5 10.0 - 11.5 9.0 - 11.0 1.0 1.0 1.0 0.8 1.5 Castings shall be made from the copper grades Cu-CATH-2, Cu-ETP-2 and Cu-FRHC Notes: (1) Symbol finishes ‘B’ for material in ingot form (2) Number begins ‘CB’ for material in ingot form NB. Ingots are not specified for high conductivity coppers (3) Boron for grain refining CC480K 88.0 - 90.0 CuSn10-C 0.1 0.8 0.4 - 0.8 61.5 - 64.5 0.3 - 0.70 63.5 - 66.0 63.0 - 66.0 Rem. Copper-tin (Gunmetals and Phosphor-Bronzes) CC750S CuZn33Pb2-C Copper-zinc (Brasses) CC040A Cu-C Copper and Copper-chromium (High Conductivity Coppers) Symbol for Castings (1) Material Designation 2.0 Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zn 0.05 - 0.15 As (3) 0.15 As 0.4 - 1.2 Cr Others CT2 PB2 - PB1 CT1 DCB1 - HTB1 - - HTB3 - SCB6 - DCB3 - DZR1 DZR2 SCB3 CC1 - TF HCC1 Nearest Equivalent in Old BS 1400 300 For gears and general bearing applications offering higher corrosion/erosion resistance than gunmetals. The lead in CC482K gives improved machinability and the nickel in CC484K increases strength and hardness. General purpose, high quality engineering castings. 180 150 150 170 160 130 170 200 260 200 480 70 180 120 150 120 280 70 250 40 Silicon brass for valves and water fittings. High tensile brasses for engineering castings when good wear resistance is required and high loads encountered. Relevant Casting Processes and Designations (4) 300 270 280 310 270 380 450 480 600 430 750 500 160 350 280 300 280 400 180 350 150 10 5 5 4 10 30 25 18 12 8 5 8 20 10 10 15 10 5 12 10 25 95 85 90 85 80 75 105 110 140 110 190 130 45 90 70 90 70 110 45 95 40 ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ 0.2% GS GZ GP GC Tensile Elongation Hardness GM Proof Die Centri Pressure Strength Strength (%) (HB) 2 Sand Continuous Casting -fugal Die (N/mm2) (N/mm ) Brazable. Good corrosion resistance. General purposes, extensively for plumbing fittings. Boron in CC755S gives superior strength for thin sections. Fine grained, freely machinable. Dezincification resistant alloys for water fittings in areas with aggressive waters. General purpose applications Electrical and thermal applications. Additionally specified by minimum conductivity requirements. eg. 93-99% IACS Characteristics and Uses Typical Minimum Mechanical Properties (Properties vary significantly with method of casting) Table 7: EN 1982 Copper and Copper Alloy Ingots and Castings – Compositions, Uses and Typical Properties Copper and Copper Alloys EN Coppers and Copper Alloys Number for Castings (2) Cu CC491K CC492K CC493K CC494K CC495K CC496K CC497K CuSn5Zn5Pb5-C CuSn7Zn2Pb3-C CuSn7Zn4Pb7-C CuSn5Pb9-C CuSn10Pb10-C CuSn7Pb15-C CuSn5Pb20-C 70.0 - 78.0 74.0 - 80.0 78.0 - 82.0 80.0 - 87.0 81.0 - 85.0 85.0 - 89.0 83.0 - 87.0 81.0 - 86.0 11 CC331G CC332G CC333G CC334G CuAl10Fe2-C CuAl10Ni3Fe2-C CuAl10Fe5Ni5-C CuAl11Fe6Ni6-C CC381H CC382H CC383H CuNi30Fe1Mn1-C CuNi30Cr2FeMnSi-C CuNi30Fe1Mn1NbSi-C Rem. Rem. 64.5 84.5 68.0 - 77.0 72.0 - 78.0 76.0 - 83.0 80.0 - 86.0 83.0 - 89.5 88.0 - 92.0 7.0 - 9.0 10.0 - 12.0 8.5 - 10.5 8.5 - 10.5 8.5 - 10.5 8.0 - 10.5 Al Notes: (1) Symbol finishes ‘B’ for material in ingot form (2) Number begins ‘CB’ for material in ingot form NB: Ingots are not specified for high conductivity coppers (3) Boron for grain refining CC380H CC212E CuNi10Fe1Mn1-C Copper-nickel CuMn11Al8Fe3Ni3-C Copper-manganese-aluminium CC330G CuAl9-C Copper-aluminium (Aluminium Bronzes) CC490K CuSn3Zn8Pb5-C Copper-tin-lead (Gunmetals and Leaded Bronzes) Symbol for Castings (1) Material Designation 2.5 3.0 2.0 1.0 0.50 Mn 0.6 - 1.2 0.5 - 1.0 0.6 - 1.2 1.0 - 1.5 29.0 - 31.0 29.0 - 32.0 29.0 - 31.0 9.0 - 11.0 1.5 - 4.5 4.0 - 7.5 4.0 - 6.0 1.5 - 4.0 1.5 1.0 0.5 - 2.0 0.5 - 2.0 2.0 2.0 2.0 2.0 2.0 2.0 Ni 0.10 0.10 0.10 0.10 0.10 0.10 0.10 0.05 P Pb 18.0 - 23.0 13.0 - 17.0 8.0 - 11.0 8.0 - 10.0 5.0 - 8.0 2.5 - 3.5 4.0 - 6.0 3.0 - 6.0 (4) GM – permanent mould casting GS – sand casting GZ – centrifugal casting GP – pressure die casting GC – continuous casting 0.5 - 1.5 0.5 - 1.0 0.5 - 1.5 1.0 - 1.8 2.0 - 4.0 8.0 - 15.0 4.0 - 7.0 4.0 - 5.5 1.0 - 3.0 1.5 - 3.5 1.2 Fe Composition, %, Range or Max 0.3 - 0.7 0.15 - 0.50 Si 4.0 - 6.0 6.0 - 8.0 9.0 - 11.0 4.0 - 6.0 6.0 - 8.0 6.0 - 8.0 4.0 - 6.0 2.0 - 3.5 Sn 2.0 2.0 2.0 2.0 2.0 - 5.0 1.5 - 3.5 4.0 - 6.0 7.0 - 9.5 Zn 0.5 - 1.0 Nb 0.15 Zr 1.5 - 2.0 Cr 0.25 Ti 1.0 Nb Others CN2 CN1 - - CMA1 - AB2 - AB1 - LB5 LB1 LB2 LB4 - LG4 LG2 LG1 Nearest Equivalent in Old BS 1400 High strength and corrosion resistance for the most arduous marine applications. Pipe fittings and flanges in chemical engineering. Seawater handling components, propellers. For highly stressed components in corrosive environments where high wear and shock loads may be encountered. Pumps, bearings, tools, bushings, housings. Resists tarnishing. Building and decorative components. Leaded tin bronzes whose plasticity increases with lead content for bearings when some measure of plasticity is required and for when there is a risk of scoring mating materials. Leaded gunmetals giving good corrosion resistance with moderate strength and good castability. Applications include pumps, valves and bearings. Characteristics and Uses Relevant Casting Processes and Designations (4) 230 250 120 100 275 380 280 220 200 170 75 90 110 80 120 130 110 100 440 440 340 280 630 750 650 550 550 470 175 200 220 200 240 240 230 220 18 18 18 25 18 5 12 20 18 15 6 8 5 6 12 12 10 12 115 115 80 70 150 185 150 120 130 100 50 65 65 60 70 70 65 70 ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ ✱ GM GS GZ GP GC 0.2% Tensile Proof Strength Elongation Hardness Die Centri Pressure Strength (N/mm2 (%) (HB) ) Sand Continuous (N/mm2) Casting -fugal Die Typical Minimum Mechanical Properties (Properties vary significantly with method of casting) Table 7 (continued): EN 1982 Copper and Copper Alloy Ingots and Castings – Compositions, Uses and Typical Properties Copper and Copper Alloys EN Coppers and Copper Alloys Number Rem. Rem. Rem. CW101C CW102C CW110C CW105C CW106C CW108C CW109C CW111C CW112C CW120C CuBe2Pb CuCo1Ni1Be CW103C CW104C CuBe2 CuCo2Be CuNi2Be CuCr1 CuCr1Zr CuNiP CuNi1Si CuNi2Si CuNi3Si1 12 CuZr 0.2-0.6 0.4-0.7 0.4-0.7 1.8-2.0 1.8-2.1 1.6-1.8 Be 0.5-1.2 0.5-1.2 CW114C CW118C CuSP CuTeP Rem. Rem. Rem. CW115C CW116C CW117C CW119C CuSi1 CuSi3Mn CuSn0.15 CuZn0.5 Rem. Rem. Rem. Rem. Rem. Notes: (1) M - as manufactured R - mandatory tensile strength H - mandatory hardness G - mandatory grain size CW107C CuFe2P Non Heat-treatable Alloys - Other CW113C CuPb1P 2.6-4.5 1.6-2.5 1.0-1.6 0.8-1.2 1.4-2.4 0.8-1.3 Ni 0.005-0.015 0.003-0.012 0.003-0.012 0.003-0.012 0.15-0.25 P Si 2.7-3.2 0.8-2.0 0.8-1.3 0.4-0.8 0.4-0.7 Composition, %, Range or max Cr Non Heat-treatable Alloys - Free Machining Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. CW100C Rem. Cu CuBe1.7 Heat-treatable Alloys Symbol Material Designation C112 0.8-1.3 Co 0.5 2.0-2.8 Co 0.5 C109 0.4-0.7 Te 0.1 CS101 - 0.10-0.15 Sn 0.1 0.1-1.0 Zn 0.1 Strip for radiator fins. Strip for leadframes (see EN 1758) Good corrosion resistance and strength. Nails, marine fixings, welding wire. Special wire products. Special tube products and strip for lead frames (see EN 1758) Free machining high conductivity coppers with machinability index of about 80%. Special applications at elevated temperatures. As silicon is added and increased, strength and wear resistance increase and conductivity decreases. Electrode holders, seam welding wheel shafts, welding dies and bearing cages. Resistance welding electrode materials. Good conductivity and strength at elevated temperatures. Zr in CW106C raises softening temperature. Beryllium containing alloys with lower strength and better conductivity and ductility than beryllium copper, also suitable for higher temperature service. High strength beryllium coppers for springs and pressure sensitive devices. CW102C is the free machining version. Characteristics and Uses (2) For general purposes B - mandatory spring bending limit Y - mandatory 0.2% proof strength - 0.5 0.7-1.3 Mn 0.5 - C111 0.2-0.7 S 0.1 2.1-2.6 Fe 0.05-0.20 Zn 0.2 - - 0.7-1.5 Pb 0.1 - 0.5 - - 0.1-0.2 Zr 0.1 0.3 0.3 C113 CC102 0.1 CC101 0.2 0.03-0.3 Zr 0.2 - - 0.2-0.6 Pb 0.5 0.5 - CB101 0.5 0.5 Others & Total Impurities Nearest Old BS Equivalent Tensile ElongHardness Strength ation HV (N/mm2) (%) 30-5 35-5 30-5 30-5 35-5 30-8 25-3 25-3 80-230 80-220 80-220 80-240 55-175 70-185 90-230 90-230 25-3 100-230 140-320 220-480 250-490 200-890 380-900 300-400 510-760 240-550 350-600 200-320 250-360 200-320 250-360 90-110 90-110 90-110 42-6 9-2 50-3 40-115 60-140 90-220 15-6 145-200 13-5 100-180 7-2 7-2 7-2 180-350 30-14 40-135 200-320 250-360 40-350 120-780 320-800 100-620 300-700 100-570 300-590 140-730 250-800 100-440 220-540 100-440 220-500 135-900 240-800 135-900 240-800 135-760 250-800 200-1300 410-1400 20-4 100-210 200-1300 410-1400 20-2 100-420 200-1100 410-1300 35-3 100-400 0.2% Proof Strength (N/mm2) Typical Mechanical Properties 1654 RH RH RH RH RH RH RH RH RHY RHY RHYB RHYB Plate, Strip for Strip, Springs, Sheet, Connectors Circles (2) 1652 MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Rod (2) 12163 MR MR MR MR MH MH MH MH MH MH MH MH MH MH MRHG MRHG MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Wire 12165 12166 Rod for Forging Free Stock Machining 12164 12168 MRH MRH MRH MRH MRH MRH MRH MRH MRH MH MH Free Profiles, Machining Rectangular Hollow Bar Rod 12167 Inclusion in the following EN Standards with Indicated Material Conditions (1) Table 8: Wrought Low-Alloyed Copper Alloys – Compositions, Uses, Typical Mechanical Properties, Relevant Standards and Approximate Electrical Conductivity MRH MRH Tubes (2) 12449 80 88 90 93 75 85-90 40 50 75 80 45 45 30 30 % IACS Approx. Conductivity Copper and Copper Alloys EN Coppers and Copper Alloys Number Cu CW301G CW302G CW303G CW304G CW305G CW306G CW307G CW308G CuAl6Si2Fe CuAl7Si2 CuAl8Fe3 CuAl9Ni3Fe2 CuAl10Fe1 CuAl10Fe3Mn2 CuAl10Ni5Fe4 CuAl11Fe6Ni6 13 CW351H CW352H CW353H CW354H CuNi9Sn2 CuNi10Fe1Mn CuNi30Fe2Mn2 CuNi30Mn1Fe 1.0 - 3.0 1.5 - 3.5 0.5 - 0.7 Mn 8.5 - 10.5 24.0 - 26.0 5.0 - 7.0 4.0 - 6.0 2.0 - 4.0 Ni 4.5 - 6.0 11.0 - 13.0 1.0 - 2.5 CW406J 56.0 - 58.0 CW408J 59.5 - 62.5 CW409J 60.0 - 63.0 CW410J 53.0 - 56.0 CW400J 47.0 - 50.0 CW402J 45.0 - 48.0 CuNi12Zn30Pb1 CuNi18Zn19Pb1 CuNi18Zn20 CuNi18Zn27 CuNi7Zn39Pb3Mn2 CuNi10Zn42Pb2 CuNi12Zn38Mn5Pb2 CW407J 42.0 - 45.0 Notes: (1) M - as manufactured R - mandatory tensile strength H - mandatory hardness G - mandatory grain size B - mandatory spring bending limit 9.0 - 11.0 1.0 - 2.5 CW405J 57.0 - 60.0 CuNi12Zn29 1.5 - 3.0 CW404J 60.0 - 63.0 2.3 - 3.3 1.5 - 2.2 2.0 - 2.4 Si NS101 - Zn Rem. 0.2 - NS107 NS106 NS113 - - NS111 NS104 NS103 CN107 CN108 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 Zn Rem. 0.2 0.2 0.2 CN102 - 0.2 CN105 0.1 - CA104 - - CA105 CA106 - CA107 - 1.8 - 2.8 Sn 0.1 0.2 0.2 0.2 0.3 0.2 0.2 0.2 0.2 0.1 - 0.4 As 0.3 Others and Total Impurities Nearest Old BS Equivalent 1652 1653 1654 380 500 300 450 280-680 400-820 200-800 380-900 320-460 450-600 300-440 410-550 450-720 520-820 260-650 380-730 180-800 360-880 180-880 360-880 130-330 350-520 175 100-420 290-520 200-550 350-620 120 500-680 750-850 400-530 600-760 330-510 600-720 210-480 420-670 180 180-210 460-500 250-350 500-650 250-350 500-650 130 8 15-2 20-2 45-2 40-2 15-2 15-2 4-2 20-2 50-2 50-2 35-12 35 35-8 45-2 - 10-5 15-5 15-5 22-5 30 30 25-10 25-10 55 165-190 120-220 120-220 90-230 85-230 120-200 110-190 170-240 110-210 80-210 80-210 90-130 110 80-160 80-220 85 200-260 170-220 130-210 110-205 125 125-135 125-160 125-160 85 RH RHG RH RHG RHG RH RH RH RH RH R R R R R RH RHB RH RH RHB MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Rod (2) 12163 12167 MH MH MH MH MH MH MH MH MH MH MH MH MRH MRH MRHG MRH MRH MRHG MRHG MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Profiles, Forging Wire Rectangular Stock Bar 12165 12166 RH RH RH RH Tubes (2) 12449 12452 RH RH RH RH RH RH Tubes Finned for Tubes Heat for Heat Exchangers Exchangers 12451 Shows Inclusion In the following EN Standards with Indicated Material Conditions (1) Plate, Plate, 0.2% Tensile Strip for Proof Strength Elongation Hardness Strip, Sheet, Springs, Sheet, Circles (%) (HV) Strength (N/mm2) Circles Connectors 2 (N/mm ) (3) (2) Typical Mechanical Properties Two-phase, alpha-beta 250-620 460-720 alloys for similar applications to those above but for use when 250-500 460-660 hot formability is required for production of forgings or hot extruded 400-450 600-660 architectural profiles. Alpha phase alloys with good corrosion resistance. Colour becomes whiter as nickel content increases. Lead, when present, improves machinability. Applications include tableware, telecommunication components, decorative building features and general mechanical and food manufacturing equipment. Good elastic properties for electrical contacts. Excellent sea-water corrosion resistance. The alloys with 30% nickel have good resistance to erosion. UK "silver" coinage alloy. Medium strength alloys, readily hot worked and moderately cold workable. With machinability of 40-50%, the alloys are suitable for manufacture of items of chemical plant, machine parts, tools and instruments when good corrosion resistance is required. High strength alloys for use in aggressive media when wear resistance and good impact strength are required. An alpha phase alloy for tube manufacture. May be heavily cold worked. Characteristics and Uses (2) For general purposes (3) For boilers, pressure vessels and hot water storage units 6.0 - 8.0 17.0 - 19.0 17.0 - 19.0 17.0 - 19.0 0.5 - 1.5 11.0 - 13.0 0.5 - 1.5 11.0 - 13.5 11.0 - 13.0 0.5 - 1.5 11.0 - 13.0 CW403J 63.0 - 66.0 CuNi12Zn25Pb1 Pb CuNi12Zn24 9.0 - 11.0 0.4 - 1.0 0.5 - 1.5 30.0 - 32.0 1.5 - 2.5 1.5 - 2.5 29.0 - 32.0 1.0 - 2.0 0.5 - 1.0 9.0 - 11.0 10.5 - 12.5 5.0 - 7.0 8.5 - 11.0 3.0 - 5.0 9.0 - 11.0 2.0 - 4.0 1.5 - 3.5 9.0 - 10.0 0.5 - 1.5 8.0 - 9.5 6.5 - 8.5 7.3 - 7.6 6.0 - 6.4 4.0 - 6.5 Fe CW401J 61.0 - 64.0 Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Al Composition, %, Range or Max CuNi10Zn27 Copper-nickel-zinc (Nickel Silver) CW350H CuNi25 Copper-nickel CW300G CuAl5As Copper-aluminium (Aluminium Bronze) Symbol Material Designation Table 9: Wrought Copper-aluminium, Copper-nickel and Copper-nickel-zinc Alloys – Compositions, Uses, Typical Properties, Relevant Standards and Machinability 80 90 90 30 30 75 80 30 75 30 30 20 20 20 20 20 30 30 30 20 20 20 50 50 20 Machinability Index (%) Copper and Copper Alloys EN Coppers and Copper Alloys Number CW501L 89.0 - 91.0 CW502L 84.0 - 86.0 CW503L 79.0 - 81.0 CW504L 71.0 - 73.0 CW505L 69.0 - 71.0 CW506L 66.0 - 68.0 CW507L 63.5 - 65.5 CW508L 62.0 - 64.0 CW509L 59.5 - 61.5 CuZn10 CuZn15 CuZn20 CuZn28 CuZn30 CuZn33 CuZn36 CuZn37 CuZn40 14 Rem. Rem. CW452K CW453K CW459K CW455K CW457K CW458K CW460K CW454K CuSn6 CuSn8 CuSn8P CuSn4Pb2P CuSn4Te1P CuSn5Pb1 CuSn8PbP CuSn3Zn9 CuSn4Pb4Zn4 CW456K P 7.5 - 8.5 7.5 - 8.5 5.5 - 7.0 4.5 - 5.5 3.5 - 4.5 Sn 4.0 - 5.0 Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zn 3.5 - 4.5 0.2 0.2 0.2 (2) For general purposes - - - - - 0.2 - 0.2 - PB104 PB103 PB102 PB101 CZ109 CZ108 CZ107 - CZ106 - CZ103 CZ102 CZ101 CZ125 (0.5 - 1.0 Te) 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Others Nearest Old BS Equivalent G – mandatory grain size B – mandatory spring bending limit Y – mandatory 0.2% proof strength 0.01 - 0.4 3.5 - 4.5 3.5 - 4.5 1.5 - 3.5 7.5 - 10.0 0.2 - 0.4 0.1 - 0.5 7.5 - 9.0 0.01 - 0.4 0.5 - 1.5 3.5 - 4.5 0.1 - 0.4 0.2 - 0.4 1.5 - 2.5 3.5 - 4.5 0.2 - 0.4 0.01 - 0.4 0.01 - 0.4 0.01 - 0.4 Pb Composition, %, Range or Max 0.01 - 0.4 Notes: (1) M – as manufactured R – mandatory tensile strength H – mandatory hardness Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. CW451K CuSn5 Rem. CW450K CuSn4 Copper–tin (Phosphor Bronze) CW500L 94.0 - 96.0 Cu CuZn5 Copper–zinc (Brass) Symbol Material Designation 340-1000 320-950 320-950 340-500 280-820 280-820 300-500 300-830 310-500 260-630 260-630 240-600 240-420 200-620 350-680 Wrought version of a casting-type, bearing material composition. 280-550 350-680 300-400 400-500 260-550 450-750 320-700 460-650 450-750 380-480 480-550 390-650 15-2 40-2 40-5 15-2 15-2 10-5 50-2 60-1 60-1 60-1 60-1 45-2 50-1 50-1 30-2 55-1 30-2 50-2 50-2 45-2 45-4 150-210 80-210 125-180 150-210 140-160 150-210 95-200 85-270 80-250 75-230 75-230 90-150 65-190 65-190 65-160 65-200 90-160 65-170 65-170 60-165 50-125 RH RH RH RH RH RH RHG RHG RHG RHG RHG RHG RH RH RH RHYB RHYB RHY RHY RH RHY RHY 1652 1654 Tensile Elongation Hardness Plate, Strip, Strip for Strength (%) (HV) Sheet, Springs, (N/mm2) Circles (2) Connectors 170-1000 390-1100 140-950 140-850 140-850 200-420 130-800 130-800 120-420 130-810 120-420 120-590 120-590 120-560 60-420 0.2% Proof Strength (N/mm2) A dilute alloy with properties approaching those of the true bronzes. Free-machining versions of the above alloys. Strength increases as tin content increases. Good corrosion and corrosion fatigue properties lead to uses such as springs, instrument components, wire cloth, condenser tube-plates and vessels, and electronic components. Controlled resistivity wire for power applications. Muntz metal - good hot and cold working properties. The standard alloys for deep drawing, spinning, upsetting, thread rolling and bending. Good soldering properties. Very good cold working properties for extreme deep drawing and cold forging applications. Very good cold working properties for electrical engineering components. Flexible tubes and sleeves. Attractive range of colours for costume jewellery. Can easily be enamelled. Characteristics and Uses Typical Mechanical Properties Table 10: Wrought Copper–zinc and Copper–tin Binary Alloys – Compositions, Uses and Typical Properties MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MR MR MR MR MH MH MRHG MRHG MRHG MRHG MRHG MRHG MRHG MRHG MRHG MRHG Inclusion in the following EN Standards with Indicated Material Conditions (1) 12163 12164 12165 12166 Rod for Rod Forging Free Wire (2) Stock Machining MRH MRH MRH MRH MRH 12167 Profiles, Rectangular Bar MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Tubes (2) 12449 Copper and Copper Alloys EN Coppers and Copper Alloys 0.8 - 1.6 CW608N 60.0 - 61.0 CW612N 59.0 - 60.0 CW600N 62.5 - 64.0 CW601N 62.0 - 63.5 CW607N 60.0 - 61.0 CuZn38Pb2 CuZn39Pb2 CuZn35Pb1 CuZn35Pb2 CuZn38Pb1 CuZn39Pb0.5 CW610N 59.0 - 60.5 CuZn39Pb1 15 1.0 - 2.0 1.6 - 3.0 0.1 - 0.8 0.8 - 1.6 CW616N 57.0 - 59.0 0.05 - 0.30 CW618N 57.0 - 59.0 CW620N 57.0 - 59.0 CW621N 57.0 - 59.0 CW622N 55.0 - 57.0 CW624N 55.0 - 57.0 CW623N 55.0 - 57.0 CuZn40Pb1Al CuZn40Pb2Al CuZn41Pb1Al CuZn42PbAl CuZn43Pb1Al CuZn43Pb2Al CuZn43Pb2 CuZn37Pb0.5 CW604N 62.0 - 64.0 CuZn37Pb1 0.05 - 0.5 0.05 - 0.5 0.05 - 0.5 0.05 - 0.5 Notes: (1) M – as manufactured R – mandatory tensile strength H – mandatory hardness CW605N 61.0 - 62.0 2.5 - 3.5 CuZn39Pb3Sn CW615N 57.0 - 59.0 0.2 - 0.5 0.2 - 0.5 0.2 - 0.5 Sn (2) For general purposes 1.6 - 3.0 0.8 - 1.6 0.2 - 0.8 0.8 - 1.6 1.6 - 3.0 1.6 - 2.5 CuZn40Pb2Sn CW619N 57.0 - 59.0 0.05 - 0.5 1.6 - 2.5 1.7 - 2.8 1.6 - 2.5 0.8 - 1.6 1.6 - 2.5 1.6 - 2.5 1.6 - 2.5 1.6 - 2.5 CuZn39Pb2Sn CW613N 59.0 - 60.0 CuZn36Pb2As CW602N 61.0 - 63.0 0.02 - 0.15 0.2 - 0.8 CW606N 61.0 - 62.0 CuZn37Pb2 CW611N 59.0 - 60.0 0.8 - 1.6 CW617N 57.0 - 59.0 2.5 - 3.5 2.5 - 3.5 Pb CuZn40Pb2 As CW614N 57.0 - 59.0 Al CuZn39Pb3 Cu CW603N 60.0 - 62.0 Number Composition, %, Range or Max. CuZn36Pb3 Symbol Material Designation Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zn 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.2 0.2 0.2 0.2 0.2 0.2 Others Total – – CZ130 CZ130 – – – – – – – – CZ132 CZ129 CZ123, CZ137 – CZ119, CZ131 CZ118 CZ120, CZ128 CZ120, CZ128 CZ119, CZ131 CZ122 CZ121Pb3 CZ124 Nearest Old BS Equivalent 160-450 160-340 For manufacture of tube and hollow rod. 150-220 – – – – – 130-160 130-160 150-420 150-420 For manufacture of plate and tube. Aluminium imparts a golden lustre, avoiding need for further polishing. The alloys with more than 1.6% Pb have very good machinability. This group of alloys is used for production of profiles by hot extrusion. These alloys are designed for hot forging. These alloys have good machinability and limited cold workability. 340-440 300-580 350-420 – – – – – 340-380 340-380 360-580 360-580 280-450 Dezincification resistant brass with good machinability and 120-200 moderate hot and cold workability. 360-580 360-580 330-470 300-580 360-580 360-580 300-580 360-580 150-450 150-420 150-350 150-450 150-450 150-450 160-450 360-580 360-580 340-580 150-420 This group contains the standard alloys for bending, CW610N, and extreme riveting, CW601N. These alloys are machinable and have good to very good cold workability. These alloys have good machinability and some cold workability for limited bending and riveting. Inclusion in the following EN Standards with Indicated Material Conditions (1) 35-10 45-10 30-20 – – – – – 20-12 20-12 25-5 30-5 40-20 30-5 40-5 30-5 30-10 45-10 40-5 40-5 45-5 25-5 25-5 35-5 80-130 80-150 100-130 – – – – – 85-95 85-95 100-160 90-150 80-140 90-150 90-150 90-150 90-130 90-150 90-160 90-150 90-150 100-160 100-160 90-150 RH RH RH RH RH RH MR MR MR MR MR MR MR MR MR MR MR MR MH MH MH MH MH MH MH MH MH MH MH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH M M M M M MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH MH MH MH MH MH MH MH MH MH MH MH 1652 12164 12165 12166 12167 12168 0.2% Tensile Free Elongation Hardness Plate, Proof Free Profiles, Strength Strip, Machining Forging Machining (%) (HV) Strength Wire Rectangular Hollow (N/mm2) Sheet, Stock 2 (N/mm ) Rod Bar Circles(2) Rod These alloys have excellent 160-450 machinability but very limited cold workability. Alloy CW614N is rated as a standard against which 150-420 other materials are compared. Alloy CW617N is the standard hot 150-420 forging brass. Characteristics and Uses Typical Mechanical Properties Table 11: Wrought Copper-zinc-lead Alloys (Leaded Brasses) – Compositions, Uses, Typical Properties, Relevant Standards and Machinability MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Tubes (2) 12449 50 45 95 95 60 55 85 90 60 95 85 75 70 60 50 55 65 50 80 75 70 90 100 95 Machinability Index (%) Copper and Copper Alloys EN Coppers and Copper Alloys CW702R CW706R CW707R CW715R CW717R CW709R CW711R CW712R CW714R CW719R CuZn20Al2As CuZn28Sn1As CuZn30As CuZn38AlFeNiPbSn CuZn38Sn1As CuZn32Pb2AsFeSi CuZn36Pb2Sn1 CuZn36Sn1Pb CuZn37Pb1Sn1 CuZn39Sn1 16 CW705R CW710R CW721R CW722R CW708R CW713R CW718R CuZn25Al5Fe2Mn2Pb CuZn35Ni3Mn2AlPb CuZn40Mn1Pb1AlFeSn CuZn40Mn1Pb1FeSn CuZn31Si1 CuZn37Mn3Al2PbSi CuZn39Mn1AlPbSi CW701R CW703R CW716R CW720R CW723R CuZn19Sn CuZn23Al3Co CuZn38Mn1Al CuZn40Mn1Pb1 CuZn40Mn2Fe1 Other Brasses CW704R CuZn23Al6Mn4Fe3Pb High Tensile Brasses CW700R CuZn13Al1Ni1Si1 Corrosion Resistant Alloys 56.5 - 58.5 57.0 - 59.0 59.0 - 61.5 72.0 - 75.0 80.0 - 82.0 57.0 - 59.0 57.0 - 59.0 66.0 - 70.0 56.5 - 58.5 57.0 - 59.0 58.0 - 60.0 65.0 - 68.0 63.0 - 65.0 59.0 - 61.0 59.0 - 61.0 61.0 - 63.0 59.5 - 61.5 64.0 - 66.5 59.0 - 62.0 59.0 - 60.7 69.0 - 71.0 70.0 - 72.5 76.0 - 79.0 81.0 - 86.0 0.3 - 1.3 3.0 - 3.8 0.3 - 1.3 1.3 - 2.3 0.3 - 1.3 0.3 - 1.3 4.0 - 5.0 5.0 - 6.0 0.1 - 0.5 1.8 - 2.3 0.7 - 1.2 Al 0.5 - 1.5 0.2 - 1.2 0.2 - 1.2 0.5 - 3.0 2.0 - 3.5 0.1 - 0.2 0.1 - 0.4 Fe 1.0 - 2.0 0.5 - 1.5 0.6 - 1.8 0.8 - 1.8 1.5 - 3.0 0.8 - 1.8 0.8 - 1.8 1.5 - 2.5 0.5 - 3.0 3.5 - 5.0 1.0 - 2.0 0.2 - 0.8 0.2 - 0.8 0.8 - 1.6 0.8 - 1.6 0.2 - 0.8 0.2 - 0.8 0.2 - 0.8 0.4 - 1.0 0.2 - 0.6 1.3 - 2.2 1.5 - 2.2 0.3 - 0.7 Pb Si 0.2 - 0.8 0.3 - 1.3 0.7 - 1.3 0.45 - 0.8 0.8 - 1.3 Mn Cu Symbol Number Composition, %, Range or Max Material Designation 0.2 - 0.5 0.2 - 1.0 0.2 - 1.0 0.5 - 1.0 0.5 - 1.0 1.0 - 1.5 0.5 - 1.0 0.5 - 1.0 0.3 - 0.6 0.9 - 1.3 Sn 0.25 - 0.55 Co 2.0 - 3.0 Ni 0.03 - 0.08 As 0.02 - 0.06 As 0.2 - 0.5 Ni 0.02 - 0.06 As 0.02 - 0.06 As 0.02 - 0.06 As 0.8 - 1.4 Ni Others Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zn – CZ136 – – – – CZ135 – CZ115 CZ114 – CZ116 – CZ133 – CZ112 CZ134 – – – CZ126 CZ111 CZ110 CZ127 Nearest Old BS Equivalent Medium strength structural materials. Springs, connectors. Scouring pads. Bearings and sliding stress requirements, synchro rings. Machinability 40-50%. High strength structural materials. CW722R is aluminium-free and suitable for brazing and soldering. Machinability 50-80%. Naval brasses for sea-water environments; 60-70% machinability when lead is included. Complex DZR Brass Sea-water resistant alloys for condenser plates and tubes; heat exchangers. Special purpose tubes Characteristics and Uses Table 12a: Wrought, Complex, Copper–zinc Alloys (Special Brasses) – Composition, Uses and Typical Properties 160-320 160-350 200-350 600-800 – 250-350 300-450 250-350 200-380 200-380 250-350 300-400 500-540 160-360 200-400 160-360 200-400 200-300 130-230 160-220 110-410 110-410 140-380 120-350 0.2% Proof Strength (N/mm2) 350-550 350-550 450-570 660-880 350-900 440-540 550-650 460-560 450-580 450-580 450-550 550-650 700-800 340-480 360-540 340-480 360-540 380-450 320-430 400-460 320-460 320-460 340-540 400-580 Tensile Strength (N/mm2) 20-8 20-10 20-8 12-4 55-35 20-10 25-8 25-10 30-15 30-15 15 12 10 30-10 30-5 30-10 30-5 25-12 35-20 25 60-20 60-20 60-20 50-10 Elongation (%) Typical Mechanical Properties 100-160 100-170 130-160 200-250 70-180 120-170 170-210 120-160 130-170 130-170 120-150 150-200 190-210 190-210 110-160 90-150 110-160 115-145 80-120 115-130 80-160 80-160 80-160 70-180 Hardness (HV) Copper and Copper Alloys EN Coppers and Copper Alloys CW702R CW706R CW707R CW715R CW717R CW709R CW711R CW712R CW714R CW719R CuZn20Al2As CuZn28Sn1As CuZn30As CuZn38AlFeNiPbSn CuZn38Sn1As CuZn32Pb2AsFeSi CuZn36Pb2Sn1 CuZn36Sn1Pb CuZn37Pb1Sn1 CuZn39Sn1 17 CW705R CW710R CW721R CW722R CW708R CW713R CW718R CuZn25Al5Fe2Mn2Pb CuZn35Ni3Mn2AlPb CuZn40Mn1Pb1AlFeSn CuZn40Mn1Pb1FeSn CuZn31Si1 CuZn37Mn3Al2PbSi CuZn39Mn1AlPbSi CW703R CW716R CW720R CW723R CuZn23Al3Co CuZn38Mn1Al CuZn40Mn1Pb1 CuZn40Mn2Fe1 Notes: (1) M – as manufactured R – mandatory tensile strength H – mandatory hardness (HB) CW701R CuZn19Sn Other Brasses CW704R CuZn23Al6Mn4Fe3Pb High Tensile Brasses CW700R Number CuZn13Al1Ni1Si1 Corrosion Resistant Alloys Symbol Material Designation 1653 RH MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Rod (2) Strip for Springs, Connectors MR MR MR MR MR MR Rod for Free-machining 12164 MH MH MH MH MH MH MH MH MH MH MH MH Forging Stock 12165 MRH MRH MRH MRH Wire 12166 MRH MRH MRH MRH MRH MRH MRH MRH MRH MRH Profiles, Rectangular Bar (2) 12167 Inclusion in the following EN Standards with Indicated Material Conditions (1) 12163 1654 (3) For boilers, pressure vessels and hot water storage units R R R R Plate, Sheet, Circles (3) (2) For general purposes RH Plate, Sheet, Strip, Circles (2) 1652 Table 12b: Wrought, Complex, Copper-zinc Alloys (Special Brasses) – Relevant Standards 12168 MH MH MH MH MH MH Hollow Rod for Free-machining MRH MRH MRH MRH MRH MRH MRH MRH Tubes (2) 12449 RH RH RH Tubes for Heat Exchangers 12451 12452 RH RH Finned Tubes for Heat Exchangers Copper and Copper Alloys EN Coppers and Copper Alloys CF008A CF024A Cu-DHP CF116C CF239E CuSi3Mn1 CuMn13Al6Fe2Ni2 18 CF732R CF733R CF734R CuZn40Fe1Sn1MnSi CuZn39Fe1Sn1MnNiSi CuZn40FeSiSn CF452K CF453K CF461K CuSn6 CuSn8 CuSn12 CF301G CF310G CuAl6Si2Fe CuAl9Ni4Fe3Mn2 46.0-50.0 Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. 58.5-61.5 56.0-60.0 56.0-60.0 56.0-62.0 57.0-61.0 62.6-63.5 59.0-61.0 58.5-61.5 58.5-61.5 58.5-61.5 58.5-61.5 Rem. 72.0-78.0 Rem. Rem. Rem. 99.90 min 99.90 min 99.90 min Cu 0.01 8.5-9.5 6.0-6.4 9.0-10.0 7.0-9.0 0.005 0.02 0.01 0.01 0.01 0.02 0.02 0.05 0.01 0.01 0.01 0.01 0.01 5.5-6.5 0.05 0.03 0.03 Al 0.25 2.5-4.0 0.5-0.7 0.5-1.5 0.5 0.1 0.1 0.1 0.1-0.5 0.25-1.2 0.25-1.2 0.25 0.2 0.05 0.05 0.25 0.25 0.25 0.25 1.5-2.5 0.2 0.03 0.03 Fe (2) EN 1044 Brazing - filler metals 0.2 1.0-2.0 0.1 0.5 0.5 0.05-0.25 0.01-0.5 0.01-0.5 0.2-1.0 0.01 0.02 0.05-1.0 0.05-0.25 0.05-0.25 9.0-14.0 0.7-1.3 0.1-0.4 0.1-0.4 Mn 8.0-11.0 3.5-5.5 0.1 1.0 0.5 0.2 0.2 0.2 0.2-0.8 0.5-1.5 0.3 1.5-2.5 0.1 0.1 Ni Pb Si 0.01-0.4 0.01-0.4 0.01-0.4 0.01-0.4 7.5-8.1 0.05 0.015 0.015 0.015-0.040 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.02 0.03 0.05 0.05 0.02 0.05 0.05 0.02 0.02 0.02 0.02 0.02 0.025 0.02 0.05 0.01 0.01 0.15-0.4 0.1 2.0-4.0 0.2 0.2 0.15-0.3 0.04-0.15 0.04-0.15 0.1-0.5 0.2 0.1-0.2 0.15-0.40 0.15-0.4 0.15-0.4 0.2-0.4 0.2-0.4 0.2 2.7-3.2 0.1-0.4 0.1-0.4 0.0005 Bi, 0.005 Pb, Total 0.03 max excl. Ag, (1) 0.0005 Bi, 0.005 Pb, Total 0.03 max excl. Ag, O(1) P Composition, %, Range or Max 0.2 0.1 0.1 11.0-13.0 7.5-8.5 5.5-7.0 4.5-5.5 0.2-0.5 0.8-1.1 0.8-1.1 0.5-1.5 0.25-1.0 0.05 0.2-0.5 0.2-0.5 0.2 0.2-0.5 0.2 0.5-1.0 0.1 Sn Rem. 0.2 0.4 0.5 0.2 0.05 0.2 0.2 0.2 Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. 0.05 0.2 0.4 Zn 0.2 0.2 0.2 0.2 0.2 0.025 Cd 0.4 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.2 0.03 Bi 0.025 Cd 0.25 0.5 0.5 0.2 0.2 Others Total Table 13: Copper and Copper Alloys for Welding and Braze Welding - Composition and Melting Ranges (EN 13347) Notes: (1) Ag, As, Bi, Cd, Co, Cr, Fe, Mn, Ni, O, P, Pb, S, Sb, Se, Si, Sn, Te, Zn CuNi10Zn42 CF411J CF305G CuAl10Fe1 Copper-nickel-zinc CF309G CuAl8 Copper-aluminium CF451K CuSn5 Copper-tin CF731R CuZn40Sn1MnNiSi CF728R CuZn39Mn1SiSn CF730R CF727R CuZn40MnSiSn CF729R CF726R CuZn40MnSi CuZn40Sn1 CF725R CuZn40SiSn CuZn37Si CF724R CuZn40Si Copper-zinc CuP8 CF222E CF133C CuSn1MnSi Copper-phosphorus CF132C CuMnSi Miscellaneous Copper Alloys CF004A Cu-OF Number Cu-ETP Coppers Symbol Material Designation C4 C2B C2C C2 C2 1453 CZ7A CZ7 CZ6A CZ6 Cu6 Cu3 1845 C20 C23 C13 C11 C10 C9 C7 C7 2910 Nearest Old BS Equivalent Cu305 Cu202 Cu201 Cu306 Cu304 Cu303 Cu302 Cu301 CP201 Cu104 Cu102 Cu101 Equivalent in EN 1044 (2) 890-920 825-990 910-1040 870-890 870-900 870-900 875-895 875-895 710-770 1085 1085 1085 Melting Range ºC Copper and Copper Alloys EN Coppers and Copper Alloys CW603N CW608N and CW612N CuZn36Pb3 CuZn38Pb2 and CuZn39Pb2 CZ124 CZ128 19 CuZn36 CuZn20 CZ103 Ductile brasses 60/40 brasses Naval brass (uninhibited) Leaded naval brass Naval brass Arsenical brass Dezincification-resistant brass High tensile brass/ wear-resistant High tensile brasses Brasses for architectural sections Free cutting brasses with improved ductility Free cutting brasses High-speed machining brass Description 79.0-81.0 63.5-65.5 69.0-71.0 59.5-61.5 59.0-60.5 59.0-61.0 59.5-61.5 61.0-63.0 69.0-71.0 61.0-63.0 57.0-59.0 56.5-58.5 65.0-68.0 57.0-59.0 57.0-59.0 55.0-57.0 55.0-57.0 79.0-81.0 59.0-60.0 60.0-61.0 59.0-60.0 62.0-63.5 61.0-62.0 60.0-61.0 59.0-60.0 60.0-62.0 57.0-59.0 57.0-59.0 Cu 1.3-2.3 4.0-5.0 0.3-1.3 0.05-0.5 Al 0.2-1.2 0.5-3.0 0.2-1.2 Fe Compositions: Compositions given are the EN materials appropriate to designation number. Composition ranges may be outside those of previous BS specifications, therefore compliance should be checked before assuming suitability for applications. 1.5-3.0 0.8-1.8 0.5-3.0 0.8-1.8 0.5-1.5 Mn 0.3-1.3 Si 0.5-1.0 Sn 0.5-1.0 Sn 1.0-1.5 Sn 0.02-0.06 As 0.02-0.15 As 0.2-1.0 Sn 0.2-1.0 Sn Others Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem Rem. Rem. Rem. Zn 90-460 90-480 90-480 120-280 120-280 155-280 125-170 125-185 110-170 110-140 230-340 230-340 420-490 230-340 125-200 160-200 160-200 90-460 140-320 140-320 120-280 140-450 140-450 140-320 140-320 140-320 140-310 110-260 340-650 370-770 370-770 340-460 340-460 400-460 340-400 340-430 200-350 310-370 500-700 430-590 690-770 430-590 340-500 370-430 370-430 340-650 340-520 340-520 340-460 330-570 330-570 340-520 340-520 340-520 350-540 370-460 Tensile Strength (N/mm2) 50-5 55-3 55-3 45-25 45-25 30-20 40-20 40-20 55-20 45-35 20-12 30-20 20-15 30-20 40-30 35-25 35-25 50-5 40-15 40-15 45-20 45-5 45-5 40-15 40-15 40-5 40-15 35-15 70-170 70-190 70-190 90-150 90-150 100-145 100-150 100-160 70-90 70-80 150-200 110-175 170-220 110-175 80-115 90-120 90-120 70-170 90-160 90-160 90-140 70-160 70-160 90-160 90-160 70-160 90-160 90-160 Elongation Hardness % (HV) Typical Mechanical Properties (1) 0.2% Proof Strength (N/mm2) Can be deformed extensively by cold working. Will withstand limited amount of cold working and bending. The tin addition improves corrosion resistance, especially in sea water. The leaded version has improved machinability. Brass with good hot ductility which is then heat treated to give excellent resistance to dezincification (see CDA Information Sheet No. IS 36). The addition of arsenic to 70/30 brass improves resistance to corrosion. The alloying additions produce improved mechanical properties. The lead in CW721R improves machinability. Used for fasteners, valve parts, etc. Silicon addition gives added wear resistance. The aluminium containing alloy has a bright yellow colour on the surface of extruded sections, while the manganese containing alloy may be toned to a chocolate brown colour. This gives an accentuated uniform improvement to natural oxidation effects. The higher copper and lower lead contents of these alloys improves ductility, while retaining free machining characteristics. Can be used for cold heading, riveting, etc. CW601N is the standard material for extreme riveting. Excellent machinability combined with sufficient ductility for some cold work. CW617N is the standard hot forging brass. The most suitable materials for high speed machining, but have limited ability to be cold worked. The hardness of sections is typically 115 HV. Remarks Standards: This table includes materials previously included in BS 2874 'Specification for copper and copper alloy rods and sections (other than forging stock)'. These materials are now included in the following EN standards for individual product forms: EN 12163 'Copper and copper alloys - Rod for general purposes' EN 12164 'Copper and copper alloys - Rod for free machining purposes' EN 12167 'Copper and copper alloys - Profiles and rectangular bar for general purposes' EN 12168 'Copper and copper alloys - Hollow rod for free machining purposes' 0.2-0.8 1.3-2.2 0.2-0.6 1.7-2.8 0.2-0.8 0.8-1.6 0.2-0.8 0.8-1.6 1.0-2.0 1.6-3.0 1.6-3.0 0.1-1.0 1.6-2.5 1.6-2.5 0.8-1.6 1.6-2.5 1.6-2.5 1.6-2.5 1.6-2.5 2.5-3.5 1.6-2.5 2.5-3.5 Pb Composition, %, Range (Excluding Impurities) This table shows only the old BS alloys with their equivalent EN specifications. For alloys not included, see earlier tables. Notes: (1) Properties: The typical mechanical properties shown apply to rod for free machining and general purposes which can have significant cold drawing after extrusion. The values represent those typically required rather than the limits that are possible. Products such as hollows and profiles which are not normally significantly cold drawn will have the lower end of the range for proof stress, tensile strength and hardness and will have good elongation values. CW503L CW507L CW505L CuZn30 CW719R CZ107 CuZn39Sn1 CZ133 CW711R CW712R CZ106 CuZn36Pb2Sn1 CZ134 CW509L CuZn36Sn1Pb CZ112 CW707R CW602N CuZn40 CuZn30As CZ105 and CZ126 CZ109 CuZn36Pb2As CZ132 CW713R CW722R CW610N CuZn37Mn3Al2PbSi CW705R CZ137 CuZn39Pb0.5 (superseded CZ123) CuZn40Mn1Pb1FeSn CZ135 CZ114 CZ115 CuZn40Mn1Pb1AlFeSn CW721R CZ136 CuZn25Al5Fe2Mn2Pb CuZn40Mn1Pb1 CZ130 CZ116 CW623N CW624N CW720R None CW612N CuZn39Pb2 CuZn43Pb2 and CuZn43Pb2Al CW608N CuZn38Pb2 CZ120 (CuZn20Pb) CW611N CuZn39Pb1 CZ129 CZ104 CW601N CW606N CZ131 CuZn35Pb2 and (superseded CZ119) CuZn37Pb2 CW617N CuZn40Pb2 CZ122 CW614N Number CuZn39Pb3 Symbol EN CZ121-Pb3 Old BS Near Equivalent Designation Table 14: Brass Rods and Sections - Compositions, Uses and Typical Properties Copper and Copper Alloys Section 3: Brass Semi-Finished Products CW608N and 20 CuZn40Mn1Pb1AlFeSn CuZn25Al5Fe2Mn2Pb CuZn40Mn1Pb1FeSn CuZn37Mn3Al2PbSi CuZn36Pb2As CuZn40Mn1Pb1 CuZn36Sn1Pb (CuZn20Pb) CZ114 CZ116 CZ115 CZ135 CZ132 CZ136 CZ112 CZ104 None CW712R CW720R CW602N CW713R CW722R CW705R CW721R CW509L CW610N CW611N CW612N Naval brass Manganese brass Dezincification-resistant brass High tensile brass with silicon High tensile brass (soldering quality) High tensile brasses Lead free 60/40 brass 60/40 brasses Leaded brasses Description 61.0-63.0 57.0-59.0 61.0-63.0 57.0-59.0 56.5-58.5 65.0-68.0 57.0-59.0 59.5-61.5 59.0-60.5 59.0-60.0 59.0-60.0 60.0-61.0 57.0-59.0 57.0-59.0 57.0-59.0 Cu 1.3-2.3 4.0-5.0 0.3-1.3 Al 0.2-1.2 0.5-3.0 0.2-1.2 Fe 0.5-1.5 1.5-3.0 0.8-1.8 0.5-3.0 0.8-1.8 Mn 1.0-1.5 Sn 0.02-0.15 As 0.3-1.3 Si 0.2-1.0 Sn 0.2-1.0 Sn Others Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem Rem. Zn 150 125 130 230 min 195 min 295 min 195 min 140 140 180 180 180 180 200 170 390 340 350 500 min 460 min 540 min 460 min 370 370 380 380 380 380 420 400 35 40 40 12 min 15 min 12 min 15 min 40 40 40 40 40 40 32 35 110 90 75 150 110 160 110 100 100 100 100 100 100 100 100 0.2% Tensile Elongation Hardness Proof Strength % (HV) Strength 2) (N/mm (N/mm2) Typical Mechanical Properties (Except where Minimum Quoted) The tin addition improves corrosion resistance, especially in sea water. The higher melting temperature facilitates brazing with standard filler materials. Used for architectural purposes. Generally it is chemically toned to a decorative chocolate colour. Also used for valve spindles and nuts in contact with cast iron, having an excellent resistance to seizure. Brass with good hot ductility which is then heat treated to give excellent resistance to dezincification. Readily hot stamped. Possesses excellent wear resistance. Similar to CW721R, but the restriction in aluminium content avoids non-wetting problems during soft soldering operations. Used in applications where high strength is required, such as high pressure gas valves etc. The lead addition in CW721R improves machinability. These alloys are very plastic at the hot working temperature, therefore very intricate shapes, showing fine surface detail, can be produced. Components made from these alloys have limited cold working ability. The most popular alloy for hot stamping. The lead content ensures free-machining characteristics. Commonly used hot stamping brasses with a useful range of ductility and machinability. Remarks Standards: This table includes materials previously included in BS 2872 'Specification for copper and copper alloy forging stock and forgings'. These materials are now included in the following EN standards for individual product forms: EN 12420 'Copper and copper alloys - Forgings' EN 12165 'Copper and copper alloys - Wrought and unwrought forging stock' 0.2-0.6 1.0-2.0 1.7-2.8 0.2-0.8 0.8-1.6 0.2-0.8 0.8-1.6 0.2-0.8 0.8-1.6 1.6-2.5 1.6-2.5 3.5-4.2 2.5-3.5 1.6-2.5 Pb Composition, %, Range (Excluding Impurities) Compositions: Compositions given are the EN materials appropriate to designation number. Composition ranges may be outside those of previous BS specifications, therefore compliance should be checked before assuming suitability for applications. Notes: CuZn40 CuZn39Pb0.5 CZ137 (superseded CZ123) CZ109 CuZn39Pb1 CZ129 CuZn39Pb2 CuZn38Pb2 and CZ128 CW609N CuZn38Pb4 CZ121-Pb4 CW614N CuZn39Pb3 CZ121-Pb3 CW617N Number CuZn40Pb2 Symbol EN CZ122 Old BS Near Equivalent Designation This table shows only the old BS alloys with their equivalent EN specifications. For alloys not included, see earlier tables. Table 15: Brass Forgings, Stampings and Hot Pressings - Compositions, Uses and Typical Properties Copper and Copper Alloys Brass Semi-Finished Products Symbol CW702R 21 CuZn40 CuZn20Al2As CuZn36Sn1Pb CuZn30As CuZn30 CZ109 CZ110 CZ112 CZ105 CZ106 CW505L CW707R CW712R CW702R CW509L CW610N 69.0-71.0 69.0-71.0 70/30 brass (Cartridge brass) 61.0-63.0 76.0-79.0 59.5-61.5 59.0-60.5 62.5-64.0 62.0-63.5 60.0-61.0 59.0-60.0 61.0-63.0 76.0-79.0 59.5-61.5 70/30 arsenical brass Naval brass Aluminium brass Lead free 60/40 brass 60/40 brass Leaded clock brasses Naval brass Aluminium brass Lead free 60/40 brass 59.0-60.5 62.0-64.0 60/40 brass 63.5-65.5 Common brass (Basis brass) 69.0-71.0 79.0-81.0 84.0-86.0 89.0-91.0 94.0-96.0 Cu 1.8-2.3 1.8-2.3 Al 0.2-0.6 0.2-0.8 0.8-1.6 1.6-2.5 1.6-2.5 1.6-2.5 0.2-0.6 0.2-0.8 Pb 0.02-0.06 As 1.0-1.5 Sn 0.02-0.06 As 1.0-1.5 Sn 0.02-0.06 As Others Composition, %, Range (Excluding Impurities) 2/1 brass 70/30 brass (Cartridge brass) Gilding Metals Cap Copper Description Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zinc Compositions: Compositions given are the EN materials appropriate to designation number. Composition ranges may be outside those of previous BS specifications, therefore compliance should be checked before assuming suitability for applications. (1) Ranges of tempers are available between annealed and hard and, for some materials, up to extra hard and extra spring hard. (a) - annealed (h) - hard Notes: CuZn39Pb0.5 Hot Rolled Plate CZ137 (superseded CZ123) CW600N CW601N CuZn35Pb1 CuZn20Al2As CZ110 CW509L CZ118 CuZn40 CZ109 CW610N CuZn35Pb2 CuZn39Pb0.5 CZ137 (superseded CZ123) CW508L CZ131 (superseded CZ119) CuZn37 CZ108 CW507L CW608N and CW612N CuZn36 CZ107 CW505L CuZn38Pb2 and CuZn39Pb2 CuZn30 CZ106 CW503L CZ120 CuZn20 CZ103 CW502L CW712R CuZn15 CZ102 CW501L CW500L Number CuZn36Sn1Pb CuZn10 CZ101 EN CZ112 CuZn5 CZ125 Cold Rolled Sheet and Strip Old BS Near Equivalent Designation 110 110 120 170 170 170 325 465 495 495 350 550 450 450 450 400 385 370 (h) 325 340 420 420 370 340 355 355 355 325 325 310 290 265 250 (a) 325 325 340 400 385 385 525 540 590 590 525 390 465 465 585 540 540 540 465 450 420 (h) Tensile Strength (N/mm2) 50 50 30 30 45 60 45 45 55 65 70 65 60 55 50 (a) 55 55 55 35 40 40 7 7 5 5 20 50 25 25 7 10 15 12 10 8 4 (h) Elongation % 70 75 110 110 95 75 90 90 80 70 70 70 65 60 60 (a) 85 85 85 110 110 110 170 175 185 185 160 100 140 140 180 170 170 160 150 140 130 (h) Hardness (HV) These alloys are more resistant to corrosion (especially by sea water) than 60/40 brass. They are also used for the purposes outlined above. Used for tube plates of condensers and similar purposes. In the hard condition these alloys can be accurately punched to shape with a minimum of 'burr', hence their major use as pinions for clocks, watches and instruments. Also suitable for engraving. The addition of aluminium and tin produces enhanced corrosion resistance when compared with the unalloyed brass. Good hot working alloys which can also be cold worked to a limited extent. General purpose alloy suitable for simple forming etc. A good cold working alloy. Deep drawing brass having maximum ductility of the Cu-Zn alloys. Used for architectural metalwork, imitation jewellery etc. on account of golden colours and ability to be brazed and enamelled. Industrial use practically confined to caps for ammunition. Remarks Standards: This table includes materials previously included in BS 2870 'Specification for rolled copper and copper alloys: sheet, strip and foil' and BS 2875 'Specification of copper and copper alloys: plate'. These materials are now included in the following EN standards for individual product forms: EN 1652 'Copper and copper alloys - Plate, sheet, strip and circles for general purposes' EN 1653 'Copper and copper alloys - Plate, sheet and circles for boilers, pressure vessels and hot water storage units' EN 1654 'Copper and copper alloys - Strip for springs and connectors' EN 1172 'Copper and copper alloys - Sheet and strip for building purposes' 108 125 170 170 180 125 124 125 110 100 100 100 (a) 0.2% Proof Strength (N/mm2) Typical Mechanical Properties (1) This table shows only the old BS alloys with their equivalent EN specifications. For alloys not included, see earlier tables. Table 16: Brass Sheet, Strip and Plate - Compositions, Uses and Typical Properties Copper and Copper Alloys Brass Semi-Finished Products 22 CuZn13Al1Ni1Si1 CZ127 CW700R CW601N CW702R CW706R CW707R CW509L CW508L CW503L CW502L CW501L Number 62.0-63.5 81.0-86.0 Aluminium-nickelsilicon brass 76.0-79.0 Free cutting brass Aluminium brass 70.0-72.5 69.0-71.0 70/30 arsenical brass Admiralty brass 59.5-61.5 62.0-64.0 79.0-81.0 84.0-86.0 89.0-91.0 Cu 60/40 brass Common brass 80/20 brass 85/15 brass 90/10 brass Description 0.7-1.2 1.8-2.3 Al 1.6-2.5 Pb 0.8-1.3 Si 0.8-1.4 Ni 0.02-0.06 As 0.02-0.06 As 0.9-1.3 Sn 0.02-0.06 As Others Compositions: Compositions given are the EN materials appropriate to designation number. Composition ranges may be outside those of previous BS specifications, therefore compliance should be checked before assuming suitability for applications. Notes: (1) Ranges of tempers are available between annealed and hard. (a) - annealed (h) - hard. CuZn35Pb2 CuZn30As CZ126 CZ131 (superseded CZ119) CuZn40 CZ109 CuZn20Al2As CuZn37 CZ108 CZ110 CuZn20 CZ103 CuZn28Sn1As CuZn15 CZ102 EN CZ111 CuZn10 Symbol CZ101 Old BS Near Equivalent Composition, %, Range (Excluding Impurities) Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zinc 460 410 420 360 350 110 480 450 360 340 (h) n/a 340 360 320 310 360 315 280 260 (a) 465 560 460 465 495 370 540 380 430 420 (h) Tensile Strength (N/mm2) n/a 40 60 60 60 60 55 50 60 (a) 40 44 10 20 20 20 10 15 20 20 (h) Elongation % n/a 80 75 75 70 75 75 65 60 (a) 75 n/a 150 165 165 165 170 135 140 125 (h) Hardness (HV) Trade name ‘Tungum’. Used for hydraulic and pneumatic control and instrumentation circuits in aviation, offshore and marine applications. Used to transmit high pressure oxygen (non-sparking). The lead content gives good machinability but ductility is reduced. Possesses excellent corrosion resistance in clean seawater and is a favoured alloy for condenser tubes. Good corrosion resistance in brackish water. Standard compositions for condenser tubes. The arsenic is added to inhibit dezincification. Sanitary and decorative applications. Aerials. Architectural applications. Used for condenser and cooling units, gauges and instrument tubes. Decorative uses. Musical instruments. Used for driving bands for projectiles. Architectural - hand rails. Communication systems - wave guides. Bellows for fluid and steam systems. Remarks Standards: This table includes materials previously included in BS 2871 'Specification for copper and copper alloys. Tubes': Part 1 'Copper tubes for water, gas and sanitation' Part 2 'Tubes for general purposes' Part 3 'Tubes for heat exchangers' These materials are now included in the following EN standards for individual product forms: EN 12449 'Copper and copper alloys - Seamless, round tubes for general purposes' EN 12451 'Copper and copper alloys - Seamless, round tubes for heat exchangers' EN 12452 'Copper and copper alloys - Rolled, finned seamless tubes for heat exchangers'. n/a 90 115 110 110 120 115 85 90 (a) 0.2% Proof Strength (N/mm2) Typical Mechanical Properties (1) This table shows only the old BS alloys with their equivalent EN specifications. For alloys not included, see earlier tables. Table 17: Brass Tubes - Compositions, Uses and Typical Properties Copper and Copper Alloys Brass Semi-Finished Products 23 CuZn39Pb0.5 CuZn36Pb3 CuZn39Pb2 CuZn35Pb2 CuNi10Zn27 CZ123 CZ124 CZ128 CZ131 (superseded CZ119) NS103 CW401J CW601N CW612N CW603N CW610N CW617N CW614N CW606N CW509L CW508L CW507L CW505L CW707R CW503L CW502L CW501L Number Nickel Silver 61.0-64.0 62.0-63.5 59.0-60.0 60.0-62.0 59.0-60.5 57.0-59.0 57.0-59.0 Leaded brass 58% copper, 3% lead Free cutting brasses 61.0-62.0 59.5-61.5 62.0-64.0 63.5-65.5 69.0-71.0 69.0-71.0 79.0-81.0 84.0-86.0 89.0-91.0 Cu Leaded brass Lead-free 60/40 brass Common brass 2/1 brass 70/30 brass 70/30 arsenical brass 80/20 brass 85/15 brass 90/10 brass Description Notes: (1) Ranges of tempers are available between annealed and half hard. Hard and spring hard tempers are also available for most alloys. (a) - annealed (hh) - half hard CuZn40Pb2 CZ122 CuZn37 CZ108 CuZn39Pb3 CuZn36 CZ107 CZ121-Pb3 CuZn30 CZ106 CuZn37Pb2 CuZn30As CZ105 and CZ126 CZ119 CuZn20 CZ103 CuZn40 CuZn15 CZ102 CZ109 CuZn10 Symbol CZ101 Old BS Near Equivalent EN 1.6-2.5 1.6-2.5 2.5-3.5 0.2-0.8 1.6-2.5 2.5-3.5 1.6-2.5 Pb Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Rem. Zn 360 400 400 340 340 440 390 340 340 340 340 325 325 310 310 280 (a) 850 500 500 400 420 530 480 400 480 550 570 525 525 510 510 420 (hh) Tensile Strength (N/mm2) 40 25 25 40 40 25 35 50 55 60 65 70 70 65 55 50 (a) 6 12 12 25 18 8 15 25 15 10 10 12 12 15 10 10 (hh) Elongation % Typical Mechanical Properties (1) White colour. Good corrosion resistance. Jewellery, model making. A variety of copper and lead contents to give a choice of optimum combinations of ductility, formability and machinability to suit a very wide range of end-uses. Wire supplied as continuous feedstock for high speed machining operations. The lead content is added to impart good machining properties but should be low if the brass is to be cold headed. Alloys of the higher copper contents, within the range quoted, are the most ductile and suitable for severe cold forming such as heading. Alloys within this range have better corrosion resistance properties than the lower copper content alloys and are used for paper machine plant. They are also used for ornamental purposes because of their colour and ability to be brazed. The addition of arsenic improves corrosion resistance still further. Remarks Standards: This table includes materials previously included in BS 2873 'Copper and copper alloys. Wire' which are now included in EN 12166 'Wire for General Purposes'. Compositions: Compositions given are the EN materials appropriate to designation number. Composition ranges may be outside those of previous BS specifications, therefore compliance should be checked before assuming suitability for applications. 9.0-11.0 Ni 0.02-0.06 As Others Composition, %, Range This table shows only the old BS alloys with their equivalent EN specifications. For alloys not included, see earlier tables. Table 18: Brass Wire - Compositions, Uses and Typical Properties Copper and Copper Alloys Brass Semi-Finished Products Notes 24 Notes 25 Notes 26 Copper Development Association 5 Grovelands Business Centre Boundary Way Hemel Hempstead Hertfordshire HP2 7TE Tel: +44 (0)1442 275700 Fax: +44 (0)1442 275716 Email: [email protected] Websites: www.cda.org.uk www.brass.org
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