50th AIAA Aerospace Sciences Meeting including the New Horizons Forum and Aerospace Exposition 09 - 12 January 2012, Nashville, Tennessee AIAA 2012-1266 Numerical Study on Kerosene/LOx Supercritical Mixing Characteristics of a Swirl Injector Jun-Young Heo1, Kuk-Jin Kim2, Hong-Gye Sung3 Korea Aerospace University, Goyang Gyeonggi, 412-791, Republic of Korea Hwan-Seok Choi4 Korea Aerospace Research Institute, Daejeon, 305-333, Republic of Korea Vigor Yang5 Georgia Institute of Technology, Atlanta, GA 30332, USA The turbulent mixing of a kerosene/liquid oxygen coaxial swirl injector under supercritical pressure has been numerically investigated. Three kerosene models are proposed for the kerosene thermodynamic properties. N-dodecene used to replace the kerosene is considered as baseline property for modeling simplicity. Two types of surrogate kerosene are applied. Turbulent numerical model is based on Large Eddy Simulation (LES) with real-fluid transport and thermodynamics; Soave modification of Redlich-Kwong equation of state, Chung's model for viscosity/conductivity, and Fuller's theorem for diffusivity to take account Takahashi's compressible effect. The effect of operating pressure and surrogate kerosene model on thermodynamic properties and mixing dynamics inside an injector and combustion chamber are investigated. To quantify the mixing completeness, mixing efficiency is deliberated. Power spectral densities of pressure fluctuations under various chamber pressures are analyzed. Nomenclature D E f p q t u x Z = = = = = = = = = Diffusivity Specific total energy Mixture fraction Pressure Heat flux Time Velocity components Spatial coordinate Pseudo-time variable vector = = = = Kronecker delta Preconditioning matrix or circulation Density Viscous stress tensor Greek δ Γ ρ τ 1 Research assistant, School of Aerospace and Mechanical Engineering. Research assistant, School of Aerospace and Mechanical Engineering. 3 Professor, School of Aerospace and Mechanical Engineering, AIAA Associate Fellow, [email protected]. 4 Head, Combustion Chamber Department, AIAA Member. 5 William R.T. Professor and Chair, School of Aerospace Engineering, AIAA Fellow. 1 American Institute of Aeronautics and Astronautics 2 Copyright © 2012 by the American Institute of Aeronautics and Astronautics, Inc. All rights reserved. Superscripts % sgs = Resolved-scale = Favre-averaged resolved-scale = Subgrid-scale I. Introduction L IQUID rocket engine for the space launch vehicle is operating at high pressure in order to increase the thrust and combustion efficiency, and its propellants are exposed to supercritical conditions in the combustion chamber. The supercritical conditions are the state that arbitrary substance is enclosed by the environment over its critical point. In such conditions, the propellants experience the transition of thermophysical properties that is different from phase change process at subcritical conditions. After the liquid propellant is introduced into the injector and combustion chamber, its properties are varied continuously and the distinction between gas and liquid is ambiguous. At near the critical point, propellant properties exhibit gas-like diffusivities and liquid-like densities so that the engine performance can be achieved with high energy density. Hence, the study for the mixing and combustion process of the propellants at supercritical conditions is an essential subject. Because of the peculiarities of substances at supercritical conditions, the conventional methods for property analysis are inappropriate so that the applicable thermodynamic relationships for a wide range of pressure must be employed. For understanding of the atomization, mixing and combustion phenomena in liquid rocket engine, experimental studies are performed in the wide range of pressure and temperature including the supercritical conditions. The Raman scattering technique lately has become the standard diagnostic method for quantitative species detection. Oschwald and Schik (1999) studied the atomization and mixing mechanism of the liquid nitrogen jet and obtained radial density profiles by spontaneous Raman scattering.1 In a wide range of pressures, the acoustic effect on the nitrogen injection and mixing dynamics such as the velocity fluctuations in the chamber when the acoustic driver was on was studied by Davis and Chehroudi (2004, 2007), Leyva et al. (2007).2-4 Lubarsky et al. (2004) performed experiments about the combustion instability in a high pressure air breathing combustor. As the temperature of the fuel was increased, it attained a supercritical state. After that, the spray disappeared and the scattered signal could no longer be detected. Also, unstable modes were observed during the transition to supercritical fuel injection.5 Recently, the heat transfer effect of fuel was studied in a supercritical environment. Zhong et al. (2009) investigated the heat transfer characteristics of China no.3 kerosene at supercritical conditions.6 Locke et al. (2010) studied the mixing and combustion characteristics in an LRE shear coaxial injector. In the investigation of liquid oxygen/gaseous oxygen cold flow, the phase change for liquid oxygen is more continuous similar to gaseous mixing.7 In research of numerical analysis, the results of mixing and combustion process in shear coaxial injectors using propellants as liquid oxygen/gaseous methane and liquid oxygen/gaseous hydrogen at supercritical conditions were investigated. The thermophysical characteristics of liquid oxygen/gaseous hydrogen flame in a shear coaxial injector at supercritical pressure have been investigated by Oefelein (2005) using direct numerical simulation.8 Zong and Yang (2008) applied the large eddy simulation for the identification of cryogenic fluid dynamics in a swirl liquid oxygen injector operating at supercritical pressure.9 In addition, Huo and Yang (2011) observed the mixing and combustion of liquid oxygen/gaseous methane in a shear injector at supercritical conditions.10 Giorgi and Leuzzi (2009) performed the numerical analysis of mixing and combustion in liquid oxygen/gaseous methane shear coaxial injector at supercritical conditions.11 The kerosene fuels are quite unwieldy in CFD because of a large number of components, reaction step, and thermophysical parameter. Several researchers have suggested a variety of kerosene surrogate models. Wang (1996, 2001, 2010) proposed a one formula surrogate fuel and its quasi-global combustion kinetics model of RP-1. The emphasis of his work was on computational efficiency.12-14 Montgomery et al. (2002) developed the four components surrogate model of JP-8 and studied its reduced chemical kinetic mechanisms.15 Dagaut’s Jet A-1 surrogate model includes three hydrocarbons and the kinetic reaction mechanism consists of 1592 reversible reactions and 207 species (Dagaut, 2002).16 Huang et al. (2002) presented the model of JP-7 and JP-8 consisting of 6 and 11 component, respectively.17 In this study, the turbulent mixing of a kerosene/liquid oxygen coaxial swirl injector under supercritical pressures has been numerically investigated. Compared with a shear injector, the coaxial swirl injector could produce the finer spray, shorter atomization distance, and the swirl injector is not sensitive to instability in 2 American Institute of Aeronautics and Astronautics combustor. Kerosene surrogate models are considered for the abbreviation of real fuel components. The surrogate models of JP-8/Jet-A are proposed for the kerosene thermodynamic properties. Turbulent numerical model is based on LES with real-fluid transport and thermodynamics over the wide pressure range; Soave modification of RedlichKwong (SRK) equation of state, Chung’s model for viscosity/conductivity and Fuller’s theorem for diffusivity to take account Takahashi’s compressible effect. The effect of operating pressure on thermodynamic properties and mixing dynamics inside an injector and a combustion chamber are investigated. Power spectral densities of pressure fluctuations in the injector under various chamber pressures are analyzed. II. Numerical Method A. Filtered Transport Equations The theoretical formulation is based on the filtered Favre averaged mass, momentum, energy and mixture fraction conservation equations in Cartesian coordinates. Turbulent closure is achieved by means of a LES technique in which large scale turbulent structures are directly computed and the unresolved small scale structures are treated by using the analytic or empirical modeling. The governing equations can be written as: ∂ρ ∂ρ u% j + =0 ∂t ∂x j (1) sgs sgs ∂ρ u%i ∂ ( ρ u%i u% j + pδ ij ) ∂ (τ ij − τ ij + Dij ) + = ∂t ∂x j ∂x j (2) % ∂ρ E% ∂ ( ρ E + p )u%i ∂ + = ( qi + u% jτ ij − Qisgs − H isgs + σ ijsgs ) ∂t ∂xi ∂xi (3) ∂ρ f% ∂( ρ u%i f% ) ∂ % ∂f% + = + Φisgs ρD ∂t ∂xi ∂xi ∂xi (4) The unclosed sub-grid scale terms are defined τ ij sgs = ρ ( ui u j − u%i u% j ) (5) Dij sgs = (τ ij − τ%ijj ) (6) Qi sgs = ( qij − q%ijj ) (7) ( H i sgs = ρ ( Eui − Eu%i ) + pu i − pu%i ( ) (8) σ i sgs = u jτ ij − u% jτ%ijj ) (9) ( ) (10) Φ i sgs = ρ ui f − u%i f% τ ij sgs , Dij sgs , Qi sgs , H i sgs , σ i sgs and Φ i sgs are the sgs stress, nonlinearity of viscous stress term, heat flux, energy flux, viscous work and conserved scalar flux, respectively. The static Smagorinsky model is employed to close those sgs terms. 3 American Institute of Aeronautics and Astronautics B. General-Fluid Thermodynamics and Transport The SRK equation of state and Chung’s model are applied to obtain appropriate thermophysical properties for a wide variety of pressure and temperature. The SRK equation of state is one of the real gas equation of state which are defined as p= ρ Ru T ( M w − bρ ) − ρ2 aα M w ( M w + bρ ) (11) where a= 0.42748 Ru2Tc2 pc b= ( 0.08664 Ru Tc pc )( ) α = 1 + 0.48508 + 1.55171ω − 0.15613ω 2 1 − Tr0.5 2 Ru , Vm , pc , Tc , Tr , a and b are the universal gas constant, molar volume, critical pressure, critical temperature, reduced temperature, attractive parameter and repulsive term, respectively. The acentric factor, ω was developed as a measure of the structural difference between the molecule and a spherically symmetric gas for which the force-distance relation is uniform around the molecule. Transport properties such as viscosity and thermal conductivity are predicted by the Chung’s model. Mass diffusivity is evaluated using the Fuller’s theorem with Takahashi method. C. Numerical scheme The governing equations are numerically solved by means of a finite volume method. This method allows for the treatment of arbitrary geometry. The spatial discretization employs a fourth order, central differencing scheme in generalized coordinates. The temporal discretization is obtained by second order backward differencing scheme using a fourth order Runge-Kutta scheme for integration of the real time term. In regions of low Mach number flows, the energy and momentum equations are practically decoupled and the system of conservation equations becomes stiff. Pressure decomposition and preconditioning techniques with dual time stepping are applied to circumvent the round-off errors associated with the calculation of the pressure gradient and the convergence difficulties for the low Mach number flows in the momentum equation. First, a rescaled pressure term is used in the momentum equation to circumvent the singular behavior of pressure at low Mach numbers. Second, a preconditioning technique with dual time-stepping integration procedure is established. A unified treatment of general fluid thermodynamics is incorporated into a preconditioning scheme.18 The pseudo-time derivative may be chosen to optimize the convergence of the inner iterations through the use of an appropriate preconditioning matrix that is tuned to rescale the eigenvalues to render the same order of magnitude to maximize convergence. To unify the conserved flux variables, a pseudo-time derivative of the form Γ∂Z / ∂τ can be added to the conservation equation. Since the pseudo-time derivative term disappears as the solution is converged, a certain amount of liberty can be taken in choosing the variable Z. We take advantage of this by introducing a pressure p ′ as the pseudo-time derivative term in the continuity equation. The code is paralleled using an MPI library for more effective calculation. III. Model Description Figure 1 shows a coaxial swirl injector geometry and the swirl numbers of a liquid oxygen and a kerosene are 1.598 and 6.548 respectively. The injector includes three major parts: a tangential inlet, a vortex chamber and a discharge nozzle. The kerosene (outer) and oxygen (inner) injects into the swirl injector through the tangential passage. The radial and azimuthal velocities are determined from the tangential inlet port angle and these velocity components are factor to set the swirl strength and mass flow rate, respectively. 4 American Institute of Aeronautics and Astronautics LOx Fuel dt,f or dt,o Lr dn,o So = 4d s , o d n , o π nn ,o d t , o 2 = 1.598 , doo Sf = dn,f 4 ( d n , f − d o ,o ) d s , f π n f dt , f 2 ds,f or ds,o = 6.548 Figure 1. Injector geometry and swirl number Table 1. Operation conditions Injector Chamber Pressure Fuel Oxidizer Fuel Oxidizer Mass Flow Rate Coaxial Swirl 5.25, 8.0, 10.0 MPa Kerosene; 350 K Liquid Oxygen; 103 K 0.232 kg/s 0.084 kg/s Table 2. Components of surrogate models for kerosene Species(mole,%) n-dodecene n-decane n-dodecane n-tetradecane n-hexadecane Isooctane Methylcyclohexane Meta-xylene Butylbenzene 1-methylnaphthalene Model-1 100 · · · · · · · · · Kerosene Model-2 · 32.6 34.7 · · · 16.7 · 16 · Model-3 · 16.4 20.2 14.2 10.3 6.8 7.9 7.3 5.8 11.0 Operation conditions are listed in Table 1. The surrogate models of JP-8/Jet-A are applied to kerosene mixing simulation using the mixing and combining rules (see Table 2). For model 1, n-dodecene, which is used to replace the kerosene in a conventional view point as modeling simplicity, is considered as baseline property of kerosene while models 2 and 3 are surrogate kerosene applied for this study. The model 2 (Montgomery, 2002) was 5 American Institute of Aeronautics and Astronautics considered to check if the predictions using a smaller number of components are suitable. The determination of model 3 based on the similarity of volatility and the phase change behavior of JP-8/Jet-A and the well-known components for the detailed thermodynamic characteristics (Tucker, 2005). Figure 2. Computational domain Because of the enormous computational time for simulating of full three-dimensional region using the large eddy simulation, quasi three dimensional flow fields with periodic boundaries is treated herein. The tangential inlets which are circular ports connected to the injector are approximated with a thin slit. Figure 2 shows a computational domain which is divided into 45 blocks, with each calculated on a single processor of a distributed computing facility. The total grid points are about 765,000 nodes. The disturbances are generated by a Gaussian randomnumber generator with an intensity of 5% of the mean quantity. IV. Results and Discussion A. Flow structures Figure 3. Flow structure of coaxial swirl injector The swirl injector flow structures computed in this study are presented in Figure 3. Liquid oxygen and kerosene are introduced into the injector through slots. Since the inlet ports consist of the tangential slit, the strong radial pressure gradient is formed by centrifugal force. Because the chamber pressure is higher than the critical pressure, there is no obvious boundary between the injected fluid and the ambience. Near the LOx post, a slowly swirling gaseous region forms. The adverse pressure gradient in this region gives rise to recirculation flow and finally produces a central toroidal recirculation zone (CTRZ), resulting from vortex breakdown, which play an important role in determining the flame stabilization characteristics. The CTRZ accelerates the earlier burst of vortices near the fuel/oxygen mixing zone. In the CTRZ, these vortical structures move downstream and upstream, and are rapidly dissipated by the turbulent diffusion and viscous damping. B. Effect of chamber pressure Figure 4 represents the instantaneous density contours while Figure 5 shows the mean density contours. The chamber pressures were selected as 5.25 MPa, 8 MPa and 10 MPa for transcritical and supercritical calculation because the critical pressures of oxygen and kerosene are 5.04 MPa and 1.93 MPa, respectively. The temperature was fixed at 103 K and 350 K for LOx and kerosene, respectively. Similar structures of the liquid surface are 6 American Institute of Aeronautics and Astronautics observed as pressure increased from transcritical to supercritical conditions. As shown in the figures, the higher chamber pressure is, the faster fluid density decreases during the mixing and atomization process. The region of phase-change is widely formed because of the supercritical effect. (a) (b) (c) Figure 4. Instantaneous density contours at different chamber pressures; (a) 5.25 MPa, (b) 8 MPa, (c) 10 MPa (a) (b) (c) Figure 5. Mean density contours at different chamber pressures; (a) 5.25 MPa, (b) 8 MPa, (c) 10 MPa Figure 6. Radial distributions of mean density components at x=25t downstream from the LOx post tip Figure 6 represents density distribution at x = 25t downstream from the LOx post tip. The variable, t, means the LOx post thickness; t = 0.6 mm. At the supercritical condition, taking things by and large, density distribution is 7 American Institute of Aeronautics and Astronautics higher than that at the transcritical environment. Also, the region of phase-change is widely formed as the chamber pressure increase. The phase change at supercritical conditions differs significantly from the process at transcritical conditions. The process goes through “liquid core → vaporization” at supercritical pressure, whereas it undergoes “liquid core → break up → atomization → vaporization” at the lower pressure. During the process at supercritical conditions, the properties of propellants vary continuously and the distinction between the liquid and gas phase is ambiguous. Figure 7. Mixing efficiency at different chamber pressures; 5.25 MPa, 8 MPa, 10 MPa To quantify the level of mixing, mixing efficiency is considered using the following formula: η mix ∫ ρY ( x) = ∫ ρY Fuel uα dA Fuel udA 1 α = 1 φ /φ global local ( φlocal ≤ φglobal ) ( φlocal > φglobal ) (12) Where ρ and YFuel are density and mass fraction of kerosene, respectively. u is the velocity component normal to the area, dA . φlocal and φ global are local and global equivalence ratio, respectively. The parameter α is decided by local equivalence ratio. This parameter means that if the local equivalence ratio is equal or less than global equivalence ratio, the mixing is regarded as completed. On the other hand, local efficiency is less than 1 when local equivalence ratio is large. Therefore, the mixing efficiency represents how many fuel spread into combustion chamber, in other words, the efficiency becomes 1 when local equivalence ratio is equal to global equivalence ratio through whole cross sectional area. Figure 7 shows mixing efficiencies on the time averaged fields. The efficiency increases as moves to downstream after the LOx post where the mixing starts. As shown in Figure 7, the higher chamber pressure is, the earlier the mixing efficiency reaches 1, meaning that most regions become lean burn environment because the mixing completely takes place not much far from the LOx injector post. (a) (b) (c) Figure 8. Instantaneous Z-vorticity contours at different chamber pressures; (a) 5.25 MPa, (b) 8 MPa, (c) 10 MPa 8 American Institute of Aeronautics and Astronautics Figure 8 shows the instantaneous z-vorticity magnitude. As the pressure increases, the vortical structures generated in the shear layer rapidly break up into small scale eddies, result from the local vaporization at supercritical environment. As a result, the toroidal recirculation zone downstream of the injector post becomes downsized. Figure 9. Probe location (a) (b) Figure 10. Power spectral densities of pressure fluctuations; (a) 5.25 MPa, (b) 10 MPa Figures 9 shows the locations of pressure measurement: inner side of injector (probe 1, 2), near the LOx post (probe 3), phase-change region (probe 4), mixing layer (probe 5), front of the CTRZ (probe 6). Figure 10 represents the power spectral densities of the pressure fluctuations at the locations. The Fast Fourier Transform (FFT) technique was implemented for the spectral analysis. Taken as a whole, the two frequencies of 1.25-1.3 kHz and 3.33.35 kHz are dominantly estimated inside the oxygen injector filled with high density fluid while only 3.3-3.35 kHz is observed at other locations. At the transcritical condition of 5.25 MPa, a pressure oscillation at 1.3 kHz is observed inside the oxygen injector while 3.3 kHz is estimated both outside and inside the kerosene injector. The oscillation at 3.3 kHz is same as a cycle of the vortex shedding at the oxygen injector exit. Also, high amplitude of the pressure oscillation at 3.3 kHz is observed in kerosene injector due to the Doppler effects. At the supercritical condition of 10 MPa, the dominant frequency increases as compared with those of the transcritical condition. The increase in frequency might be caused by the faster wave propagation speed at supercritical condition and it expedites the energy diffusivity. Figure 11 represents the temporal evolution of pressure and temperature field over one cycle of the dominant pressure oscillation in oxygen injector. The initial turbulence flow at the tangential inlet generates a succession of 9 American Institute of Aeronautics and Astronautics wavy structures and is convected downstream through the dense liquid oxygen. In a swirl injector, those waves are generated by the presence of oscillations in the combustion chamber or propellant feed-line. As the propellants are discharged into the chamber, sinuous Kelvin-Helmholtz waves develop along the outer wall of the injector. As these waves move downstream, a hairpin vortice is generated and grows up. The oscillation at 3.3-3.35 kHz is same as a cycle of the vortex shedding caused by the hairpin vortices at the LOx post. θ=0˚ θ = 90 ˚ θ = 180 ˚ θ = 270 ˚ (a) Pressure (b) Temperature Figure 11. Temporal evolution of pressure and temperature field over one cycle of the dominant pressure oscillation in the oxygen injector; 10 MPa 10 American Institute of Aeronautics and Astronautics C. Effect of kerosene model Among the propellants, kerosene fuels are quite unwieldy in theoretical and numerical analysis because of a large number of hydrocarbons, reactions and thermophysical parameters. Therefore, kerosene surrogate models are considered for the abbreviation of real fuel components. The surrogate models must have very similar characteristics for their chemical kinetic behavior and thermochemical property data, such as flash and freeze point, critical pressure and temperature. The single-species model and surrogate models based on the number of species will have a significant effect on the computation time. To analyze the effect of the computing load and the difference between variant kerosene models, the thermodynamic properties and mixing characteristics of single-species model and surrogate models are compared. Thermodynamic properties for each kerosene model are listed in Table 3. Figure 12 shows that surrogate models 1 and 3 undergo a phase change in a relatively narrow range as compared with model 2. Also, in case of model 2, it is observed that the length scale of the CTRZ is larger than that of other cases. The overall trends of property distributions are similar in the results of all three models. However, as for the combustion condition, the mixing characteristics may be significantly different because of the faster vaporization and the variant reaction mechanisms. Table 3. Thermodynamic properties of the kerosene models Properties Model-1 Density (kg/m3) Oxidizer Viscosity Oxidizer (N·s/m2) Fuel Fuel Model-2 Model-3 1086.6 605.2 603.9 (0.21%) 604.2 (0.17%) 1.41×10-4 2.29×10-4 2.18×10-4 (4.8%) 2.21×10-4 (3.5%) (a) (b) (c) Figure 12. Density contours for the kerosene models; (a) Model 1, (b) Model 2, (c) Model 3 V. Conclusions The turbulent mixing of a kerosene/liquid oxygen coaxial swirl injector under supercritical pressure has been numerically investigated. The effect of variant operating pressure as 5.25, 8, 10 MPa and kerosene models which are based on a single-species and the number of species on thermodynamic properties and mixing dynamics inside an injector and a combustion chamber are investigated. Power spectral densities of pressure fluctuations in the injector under variant chamber pressures are analyzed. Taken as a whole, the two frequencies of 1.25-1.3 kHz and 3.3-3.35 kHz are dominant inside the oxygen injector filled with high density fluid while 3.3-3.35 kHz is observed in other 11 American Institute of Aeronautics and Astronautics locations. In comparison, high frequency is dominantly estimated inside the fuel injector since the sound speed of kerosene fluid is faster than that of liquid oxygen. At the supercritical condition, the high frequency increased by 50 Hz and the low frequency decreased by 50 Hz as compared with those of the transcritical condition. The overall trends of property distributions are similar for all three kerosene surrogate models. However, as for the combustion condition, the mixing characteristics will be significantly different because of the faster vaporization and variant reaction mechanisms. Acknowledgement This research was supported by National Space Laboratory (NSL) Program (No. 2008-2006287) through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology. References 1 Oschwald, M. and Schik, A., “Supercritical Nitrogen Free Jet Investigated by Spontaneous Raman Scattering”, Experiments in Fluids, Vol. 27, No. 6, pp. 497-506, 1999. 2 Davis, D. W. and Chehroudi, B., “The Effects of Pressure and Acoustic Field on a Cryogenic Coaxial Jet”, AIAA Paper No. 2004-1330, 42nd AIAA Aerospace Sciences Meeting and Exhibit, Reno, Nevada, 5-8 January, 2004. 3 Davis, D. W. and Chehroudi, B., “Measurements in an Acoustically Driven Coaxial Jet Under Sub-, Near, and Supercritical Conditions”, Journal of Propulsion and Power, Vol. 23, No. 2, pp. 364-374, 2007. 4 Leyva, I. A., Chehroudi, B., and Talley, D., “Dark Core Analysis of Coaxial Injectors at Sub-, Near-, and Supercritical Pressures in a Transverse Acoustic Field”, AIAA Paper No. 2007-5456, 43th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Cincinnati, Ohio, 8-11 July, 2007. 5 Lubarsky, E., Shcherbik, D., Scarborough, D., Bibik, A., and Zinn, B. T., “Onset of Severe Combustion Instabilities During Transition to Supercritical Liquid Fuel Injection in High Pressure Combustions”, AIAA Paper No. 2004-4031, 40th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Fort Lauderdale, Florida, 11-14 July, 2004. 6 Zhong, F. Q., Fan, X. J., Yu, G., Li, J. G., and Sung, C. J., “Heat Transfer of Aviation Kerosene at Supercritical Conditions”, Journal of Thermophysics and Heat Transfer, Vol. 23, No. 3, pp. 543-550, 2009. 7 Locke, J. M., Pal, S., Woodward, R. D., and Santoro, R. 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S., “Thermo-Kinetics Characterization of Kerosene/RP-1 Combustion”, AIAA Paper No. 1996-2887, 32nd AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Lake Buena Vista, Florida, 1-13 July, 1996. 13 Wang, T. S., “Thermophysics Characterization of Kerosene Combustion”, Journal of Thermophysics and Heat Transfer, Vol. 15, No. 2, pp. 140-147, 2001. 14 Wang, Y. Z., Hua, Y. X., and Meng, H., “Numerical Studies of Supercritical Turbulent Convective Heat Transfer of Cryogenic Propellant Methane”, Journal of Thermophysics and Heat Transfer, Vol. 24, No. 3, pp. 490500, 2010. 15 Montgomery, C. J., Cannon, S. M., Mawid, M. A., and Sekar, B., “Reduced Chemical Kinetic Mechanisms for JP-8 Combustion”, AIAA Paper No. 2002-0336, 40th AIAA Aerospace Sciences Meeting and Exhibit, Reno, Nevada, 14-17 January, 2002. 16 Dagaut, P., “On the Kinetics of Hydrocarbons Oxidation from Natural Gas to Kerosene and Diesel Fuel”, Physical Chemistry Chemical Physics, Vol. 4, Issue 11, pp. 2079-2094, 2002. 12 American Institute of Aeronautics and Astronautics 17 Huang, H., Sobel, D. R., and Spadaccini, L. J., “Endothermic Heat-Sink of Hydrocarbon Fuels for Scramjet Cooling”, AIAA Paper No. 2002-3871, 38th AIAA/ASME/SAE/ASEE Joint Propulsion Conference and Exhibit, Indianapolis, Indiana, 7-10 July, 2002. 18 Meng, H. and Yang, V., “A Unified Treatment of General Fluid Thermodynamics and Its Application to a Preconditioning Scheme”, Journal of Computational Physics, Vol. 189, Issue 1, pp. 277-304, 2003. 13 American Institute of Aeronautics and Astronautics
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