XC13T0025-1
Date
September 21, 2013
Certificate of UN test for Lithium ion Battery
Model
E-7S
IDX Company, Ltd.
Products Division
H.Kawamura, General Manager
Technical Development
Manual of Tests and Criteria (38.3 Lithium Batteries)
No.
Test Item
Note
Test Results
T1
Altitude Simulation
Pass
T2
Thermal Test
Pass
T3
Vibration
Pass
T4
Shock
Pass
T5
External Short Circuit
Pass
T6
Crush
Pass
T7
Overcharge
Pass
For Battery Only
T8
Forced Discharge
Pass
For Cell Only
Lithium ion battery Specification
Item
Value
Nominal Voltage
14.8V
Capacity(mAh)
4600mAh
Capacity(Wh)
68Wh
Lithium equivalent content
5.52g
Note
We declare that the above-mentioned test is the result of being checked according to UN test.
(UN Manual of Tests and Criteria, ST/SG/AC.10/11/Rev5 Amendment 1, Part III, sub-section 38.3)
IDX Company, Ltd.
6-28-11 Shukugawara, Tama-ku, Kawasaki-shi, Kanagawa-ken, 214-0021, Japan
Tel: +81-(0)44-850-8801 Fax: +81-(0)44-850-8838
URL: http://www.idx.tv
E-mail: [email protected]
XC13T0025-1
Date
January 11,2013
Certificate of Package Drop test for Lithium ion Battery
Model
E-7S
IDX Company, Ltd.
Products Division
H.Kawamura, General Manager
Technical Development
Test Item
Note
Test Results
Package Drop Test
Pass
The package shall be dropped from 1.2meter
high on to a concrete surface (flat and horizontal)
with five orientations
(1)flat on the bottom, (2)flat on the top, (3)flat on the long side,
(4)flat on the short side, (5)on a corner
Packing Instruction 965 SectionⅡ
Lithium ion battery Specification
Item
Value
Nominal Voltage
14.8V
Capacity(mAh)
4600mAh
Capacity(Wh)
68Wh
Lithium equivalent content
5.52g
Note
We declare that above-mentioned test is passed.
IDX Company, Ltd.
6-28-11 Shukugawara, Tama-ku, Kawasaki-shi, Kanagawa-ken, 214-0021, Japan
Tel: +81-(0)44-850-8801 Fax: +81-(0)44-850-8838
URL: http://www.idx.tv
E-mail: [email protected]
Issued: Janualy 13. 2015
No. XC09T0233-9
MATERIAL SAFETY DATA SHEET
1. PRODUCT AND COMPANY IDENTIFICATION
- Product Name
- Product code
: Lithium Ion Rechargeable Battery Pack
E-7S(serial No.CX02001~CX03148)
SL-VBD50(serial No.1Axxxxxx)
- Company Name
: IDX Company,Ltd.
- Address
: 6-28-11 Shukugawara, Tama-ku, Kawasaki-shi,
Kanagawa-ken, 214-0021 Japan
- TEL
: +81-44-850-8801
- FAX
: +81-44-850-8838
- Emergency Telephone Number
: +81-44-850-8831 (Products Div. Direct)
Page 1
2. COMPOSITION / INFORMATION ON INGREDIENTS
- Information about the chemical nature of product:
Common chemical name /
CAS number
General name
Aluminum Foil
7429-90-5
Metal oxide (proprietary)
Polyvinylidene Fluoride
24937-79-9
(PBDF)
Styrene Butadiene Rubber
9003-55-8
(SBR)
Copper Foil
7440-50-8
Carbon (proprietary)
7740-44-0
Erectrolyte (proprietary)
Poly-(4,4’isopropyliden diphenyl
25971-63-5
carbonate)
4.4’isopropylidendiphenyl
carbonate
1,1,1-tris(4-hydroxyphenyl)
ethane copolymer
Proprietary ingredients
Concentration /
Concentration range
2-10%
20-50%
5>
Classification and
hazard labeling
-
5>
-
2-10%
10-30%
10-20%
95 % <
Inflammable liquid
5>
3. HAZARD IDENTIFICATION
- Primary routes of entry :
- Symptoms of exposure :
Skin contact, Skin absorption, Eye contact, Inhalation, and Ingestion
Skin contact, Skin absorption, Eye contact, Inhalation → No effect
under routine handling and use.
For the molding case
The materials do not all under category as dangerous/hazardous substances.
4. FIRST-AID MEASURES
A battery cell, spilled internal cell materials and molding case
If exposure to internal materials within cell due to damaged outer casing, the following actions are
recommended.
- Inhalation :
- Skin contact :
- Eye contact :
- Ingestion :
Leave area immediately and seek medical attention.
Wash area thoroughly with soap and water and seek medical attention.
If contact with molten product occurs, treat as for thermal burn. Do not
try to peel molten polymer from the skin. Seek medical attention.
Rinse eyes with water for 15 minutes and seek medical attention.
Drink milk/water and induce vomiting; seek medical attention.
Page 2
5. FIRE-FIGHTING MEASURE
- General hazard :
Cell is not flammable but internal organic material will burn if the cell is
incinerated. Combustion products include, but are not limited to
hydrogen fluoride, carbon monoxide and carbon dioxide.
- Extingushing media :
Use extinguishing media suitable for the materials that are burning.
Also, combustion products may include intense heat and high levels of
black smoke containing, carbon monoxide, carbon dioxide. Formation
of traces of aliphatic and aromatic hydrocarbons, aldehyde, acids,
phenol and phenol derivatives may occur.
- Special firefighting instructions :
If possible, remove cell(s) from fire fighting area. If heated above
125°C, cell(s) can explode/vent.
- Firefighting Equipment :
Use NIOSH/MSHA approved full-face self-contained breathing
apparatus (SCBA) with full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Spilled internal cell materials, such as electrolyte leaked from a battery cell, are carefully dealt
with according to the following.
- Precautions for human body :
Remove spilled materials with protective equipment (protective
glasses and protective gloves). Do not inhale the gas as much
as possible. Moreover, avoid touching as much as possible.
- Environmental precautions :
Do not throw out into the environment.
- Method of cleaning up :
The spilled solids are put into a container. The place that was
leaked on is wiped off with dry cloth.
- Prevention of secondary hazards : Avoid re-use. Do not bring the collected materials close to fire.
In general for molding case:
Sweep or gather up product and place in proper container for disposal or recovery.
Do not discard in sewers and waterways because fish may eat pallets, resulting in the obstruction of
their digestive tracts.
7. HANDLING AND STORAGE
- Handling :
- Storage :
No special protective clothing required for handling individual cells.
Store in a cool, dry place away from moisture, excessive heat and
sources of ignition.
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8. EXPOSURE CONTROL / PERSONAL PROTECTION
- Engineering Controls
Keep away from heat and open flame. Store in a cool dry place.
- Control parameters
- OSHA regulation 29CFR1910.1000 :
5 mg/m3(respirable dust), and 15mg/m3(total dust) based on OSHA
PEL for nuisance dust.
- ACGIH TLV :
A TWA of 10 mg/m3 (total dust) for nuisance dust.
- Personal Protection
- Respirator :
Not required during normal operations. SCBA required in the event of
a fire.
- Eye/face protection :
Not required beyond safety practices of employer.
- Gloves :
Not required for handling of cells.
- Foot protection :
Steel toed shoes recommended for large container handling.
- Ventilation :
A continuous supply of fresh air to the workplace together with removal
of processing fumes through exhaust systems is recommended.
Processing fumes may contain small amounts of carbon dioxide,
diphenyl-carbonate, phenol and substituted phenols. Ventilation
requirements must be locally determined to limit exposure to materials
at their point of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
For cell
- State :
- Odor :
- PH :
- Vapor pressure :
- Vapor density :
- Boiling point :
- Solubility in water :
- Specific gravity :
- Density :
Solid
N/A
N/A
N/A
N/A
N/A
Insoluble
N/A
N/A
For molding case
- Appearance
- Physical state :
Solid
- Odor and appearance :
Pellet
- Boiling point :
Not applicable
- Melting point :
220 – 230 ˚C <
- Vapor pressure (Torr) :
Negligible
- Vapor density (air=1) :
Not applicable
- Specific gravity (Water=1) :1.2
Page 4
- pH :
- Water solubility :
- Volatiles :
Not applicable
Insoluble
Negligible
10. STABILITY AND REACTIVITY
- Stability :
able under recommended conditions of storage and handling.
- Hazardous reactions occurring under specific conditions:
For cell
- Reactivity :
None
- Incompatibilities :
None (during normal operation). Avoid exposure to heat, open flame,
and corrosives.
- Hazardous decomposition products :
None (during normal operating conditions). If cells are opened,
hydrogen fluoride and carbon monoxide may be released.
- Conditions to avoid :
Avoid exposure to heat and open flame. Do not puncture, crush or
incinerate.
For molding case
Not reactive under recommended conditions of storage, handling, processing and use.
11. TOXICOLOGICAL INFORMATION
For internal cell materials:
- This product does not elicit toxicological properties during routine handling and use.
Sensitization
Teratogenicity
Reproductive toxicity
Acute toxicity
NO
NO
NO
NO
- This product does not contain any kinds of the following substances and halogen-type flame
retardants including Chlorine and Bromide type harmful flame retardants which are listed in
Appendix of TCO documents and relevant international ECO requirements:
Polybromated Biphenyls
Polybromated Biphenyl Ethers
Polybromated Biphenyl Oxides
Polybromated Diphenylethers
Polychlorinated Biphenyl
Polychloronated Diphenylethers
Tetrabromphisphenol A
Asbestos, Antimonytrioxide, Dioxine
(PBB)
(PBBE)
(PBBO)
(PBDE)
(PCB)
(PCDE)
(TBBPA)
Page 5
- None of the following substances will be exposed, leaked, or emitted during transportation,
storage or any operation and any temperature condition:
Chlorinated Fluorohydrocarbon
(FCKW)
Acrylonitride
Styrol
Phenol
Benzol
Mercury of greater than 0.0001 wt% for alkaline battery
Mercury of greater than 0.0005 wt% for other battery
Lithium content of greater than 0.5g/cell, 1.5g/battery
Cadmium, lead, and other harmful heavy metal
- This product does not contain mercury, cadmium and lithium-metal.
Mercury content: N/A
Lithium-metal: N/A
Cadmium content: N/A
- If the cells are opened through misuse or damage, discard immediately. Internal components of
cell are irritants and sensitizers.
For molding case
- ACUTE ORAL LD50 :
Not available
The components of this product are not hazardous under OSHA
Hazard communication. (29 CFR 1919. 1200)
12. ECOLOGICAL INFORMATION
Some materials within the cell are bioaccumulative. Under normal conditions, these materials are
contained and pose no risk to persons or the surrounding environment.
For molding case
Relevant information is not available.
13. DISPOSAL CONSIDERATIONS
- Recommended methods for safe and environmentally preferred disposal:
Product (waste from residues)
Do not throw out a used battery cell. Recycle it through the recycling company.
Contaminated packaging
Neither a container nor packing is contaminated during normal use. When internal materials
leaked from a battery cell contaminates, dispose as industrial wastes subject to special control.
- Waste disposal:
Efforts to recycle material should be made. If unable to use recycle, material should be buried in
approved landfill or incinerated in accordance all applicable with federal, state and local
regulations.
Page 6
14. TRANSPORT INFORMATION
In the case of transportation, avoid exposure to high temperature and prevent the formation of any
condensation. When being transported, avoid falls, drops, and breakage. Prevent collapse of cargo
piles. Prevent wetness due to rain. The container must be handled carefully. Do not give shocks that
result in a mark of hitting on a cell. Please refer to Section 7 – HANDLING AND STORAGE also.
- UN classification :
Although this product’s shipping name is “Lithium batteries” (or Lithium
Batteries packed with equipment” or “Lithium Batteries contained in
equipment”), it is not recognized as “DANGEROUS GOODS” when its
transport condition accords with “special provision PI965 of IATA-DGR” or
“special provision 188 of IMO-IMDG Code”.
15. REGULATORY INFORMATION
- Regulations specifically applicable to the product:
IATA-DGR (air transportation)
IMO-IMDG Code (sea transportation)
US Department of Transportation 49 Code of Federal Regulations [USA]
Wastes Disposal and Public Cleaning Law [Japan]
Law for Promotion of Effective Utilization of resources [Japan]
Chemical Substance Inventory requirements of the US EPA Toxic Substances Control Act
16. OTHER INFORMATION
- The information contained in this Safety data sheet is based on the present sate of knowledge and
current legislation.
- This safety data sheet provides guidance on health, safety and environmental aspects of the
product and should not be construed as any guarantee of technical performance or suitability for
particular applications.
- IDX makes no warranty, expressed or implied regarding the accuracy of these data or the results to
be obtained from the use thereof. IDX assumes no responsibility for injury from the use to the
product described herein.
- Reference
Dangerous Goods Regulations – 56th Edition Effective from 1 January 2015: International Air
Transport Association (IATA)
MSDS of raw materials prepared by the manufactures
8th edition: Janualy 13. 2015
Prepared and approved by
Engineering Dept., Products Div.
IDX Company, Ltd.
Page 7