XC13T0016
Date
September 21,2013
Certificate of UN test for Lithium ion Battery
Model
SSL-JVC50
IDX Company, Ltd.
Products Division
H.Kawamura, General Manager
Technical Development
Manual of Tests and Criteria (38.3 Lithium Batteries)
No.
Test Item
Note
Test Results
T1
Altitude Simulation
Pass
T2
Thermal Test
Pass
T3
Vibration
Pass
T4
Shock
Pass
T5
External Short Circuit
Pass
T6
Impact
Pass
T7
Overcharge
Pass
For Battery Only
T8
Forced Discharge
Pass
For Cell Only
Lithium ion battery Specification
Item
Value
Nominal Voltage
7.4V
Capacity(mAh)
4900mAh
Capacity(Wh)
37Wh
Lithium equivalent content
2.94g
Note
We declare that the above-mentioned test is the result of being checked according to UN test.
(UN Manual of Tests and Criteria, ST/SG/AC.10/11/Rev5 Amendment 1, Part III, sub-section 38.3)
IDX Company, Ltd.
6-28-11 Shukugawara, Tama-ku, Kawasaki-shi, Kanagawa-ken, 214-0021, Japan
Tel: +81-(0)44-850-8801 Fax: +81-(0)44-850-8838
URL: http://www.idx.tv
E-mail: [email protected]
XC13T0016
Date
January 11,2013
Certificate of Package Drop test for Lithium ion Battery
Model
SSL-JVC50
IDX Company, Ltd.
Products Division
H.Kawamura, General Manager
Technical Development
Test Item
Note
Test Results
Package Drop Test
Pass
The package shall be dropped from 1.2meter
high on to a concrete surface (flat and horizontal)
with five orientations
(1)flat on the bottom, (2)flat on the top, (3)flat on the long side,
(4)flat on the short side, (5)on a corner
Packing Instruction 965 SectionⅡ
Lithium ion battery Specification
Item
Value
Nominal Voltage
7.4V
Capacity(mAh)
4900mAh
Capacity(Wh)
37Wh
Lithium equivalent content
2.94g
Note
We declare that above-mentioned test is passed.
IDX Company, Ltd.
6-28-11 Shukugawara, Tama-ku, Kawasaki-shi, Kanagawa-ken, 214-0021, Japan
Tel: +81-(0)44-850-8801 Fax: +81-(0)44-850-8838
URL: http://www.idx.tv
E-mail: [email protected]
Issued: January 19 2015
No. XC11T0278-9
SAFETY DATA SHEET FOR PRODUCT
1. PRODUCT AND COMPANY IDENTIFICATION
- Product Name
- Product code
: Lithium Ion Rechargeable Battery Pack
SSL-JVC50, SSL-JVC75
DUO-150, DUO-95, CUE-D150, CUE-D95, CUE-D75
E-HL10DS
- Company Name
: IDX Company, Ltd.
- Address
: 6-28-11 Shukugawara, Tama-ku, Kawasaki-shi,
Kanagawa-ken, 214-0021 Japan
- TEL
: +81-44-850-8801
- FAX
: +81-44-850-8838
- Emergency Telephone Number
: +81-44-850-8831 (Products Div. Direct)
Page 1
2. COMPOSITION / INFORMATION ON INGREDIENTS
For cell
- Substance or preparation:
Preparation
- Information about the chemical nature of product:*1
Portion
Material name
CSA No.
Concentration
range (wt %)
Positive electrode
Lithium transition metal oxidate
(Li[M]m[O]n *2)
Positive electrode’s base
Aluminum
Negative electrode
Carbon
Negative electrode’s base
Copper
Organic electrolyte principally
involves ester carbonate
Iron
Electrolyte
Outer case
12190-79-3
12057-17-9
182442-95-1
7429-90-5
7782-42-5
7440-44-0
7440-50-8
7439-89-6
20~60
1~10
10~30
1~15
5~25
1~30
*1 Not every product includes all of these materials.
*2 The letter M means transition metal and candidates of M are Co, Mn, Ni and Al. One compound
includes one or more of these metals and one product includes one or more of the compounds.
The letter m and n means the number of atoms.
For molding case
- Chemical Name :
Polycarbonate based on bisphenol A
- Composition :
Polycarbonate
more than 81 wt%(CAS No.25971-63-5)
Flame Retardant less than 12 wt%
Elastomer less than 7 wt%
- Chemical Formula :
[-0-C6H4-C(CH3)2-C6H4-0-CO-]n-
- CAS Registry No. :
25971-63-5
3. HAZARDS IDENTIFICATION
For cell
For the battery cell, chemical materials are stored in a hermetically sealed metal or metal laminated
plastic case, designed to withstand temperatures and pressures encountered during normal use.
As a result, during normal use, there is no physical danger of ignition or explosion and chemical
danger of hazardous materials' leakage.
However, if exposed to a fire, added mechanical shocks, decomposed, added electric stress by
miss-use, the gas release vent will be operated. The battery cell case will be breached at the
extreme, hazardous materials may be released.
Moreover, if heated strongly by the surrounding fire, acrid gas may be emitted.
Page 2
- Most important hazard and effects
Human health effects
- Inhalation :
The steam of the electrolyte has an anesthesia action and stimulates a
respiratory tract.
- Skin contact :
The steam of the electrolyte stimulates a skin. The electrolyte skin
contact causes a sore and stimulation on the skin.
- Eye contact :
The steam of the electrolyte stimulates eyes. The electrolyte eye
contact causes a sore and stimulation on the eye. Especially, substance
that causes a strong inflammation of the eyes is contained.
- Environmental effects :
Since a battery pack remains in the environment, do not throw out it into
the environment.
Specific hazards
If the electrolyte contacts with water, it will generate detrimental hydrogen fluoride.
Since the leaked electrolyte is inflammable liquid, do not bring close to fire.
For molding case
According to GHS Classification
- Classification :
Not Classification
- Possible hazards :
No specific dangers known
4. FIRST-AID MEASURES
For cell
Spilled internal cell materials
- Inhalation :
Make the victim blow his/her nose, gargle. Seek medical attention if
necessary.
- Skin contact :
Remove contaminated clothes and shoes immediately. Wash
extraneous matter or contact region with soap and plenty of water
immediately.
- Eye contact :
Do not rub eyes. Immediately flush eyes with water continuously for at
least 15 minutes. Seek medical attention immediately.
A battery cell and spilled internal cell materials
- Ingestion :
Make the victim vomit. When it is impossible or the feeling is not well
after vomiting, seek medical attention.
For molding case
- Inhalation :
If fumes are inhaled, remove person to fresh air. If breathing is difficult,
get medical attention.
Page 3
- Ingestion :
This product does not show significant acute toxicity. Get medical
attention if considerable amounts of this product are ingested.
- Skin contact :
Wash contaminated skin with soap and water after contact with
processing vapors and fumes. Immediately cool contaminated skin with
water and get medical attention after contact with molten resin.
- Eye contact :
Flush the eyes with plenty of water without rubbing the eyes with hands.
Get medical attention if irritation persists.
5. FIRE-FIGHTING MEASURE
For cell
- Suitable extinguishing media :
Plenty of water, carbon dioxide gas, nitrogen gas, chemical
powder fire extinguishing medium, and fire foam.
- Specific hazards :
Corrosive gas may be emitted during fire.
- Specific methods of fire-fighting :
When the battery burns with other combustibles simultaneously,
take fire-extinguishing method which corresponds to the
combustibles. Extinguish a fire from the windward as much as
possible.
- Special protective equipment for firefighters
- Respiratory protection :
Respiratory equipment of a gas cylinder style or protection –
against - dust mask.
- Hand protection :
Protective gloves.
- Eye protection :
Goggle or protective glasses designed to protect against liquid
splashes.
- Skin and body protection :
Protective cloth.
For molding case
- Special firefighting procedures
This product is a combustible thermoplastic material which will melt and drip when ignited and
gives off combustion product mainly consisting of carbon dioxide carbon monoxide. Formation of
traces of aliphatic and aromatic hydrocarbons, aldehydes, acids, phenol and phenol derivatives
may occur. Fire-men have to wear self-containing breathing apparatus.
- Extinguishing media :
Water spray or other Class A extinguishing agent.
Page 4
6. ACCIDENTAL RELEASE MEASURES
Spilled internal cell materials, such as electrolyte leaked from a battery cell, are carefully dealt
with according to the followings.
- Precautions for human body :
Remove spilled materials with protective equipment (protective
glasses and protective gloves). Do not inhale the gas as much
as possible. Moreover, avoid touching with as much as possible.
- Environmental precautions :
Do not throw out into the environment.
- Method of cleaning up :
The spilled solids are put into a container. The leaked place is
wiped off with dry cloth.
- Prevention of secondary hazards : Avoid re-scattering. Do not bring the collected materials close to
fire.
In general for molding case
Sweep or gather up product and place in proper container for disposal or recovery. Do not discard in
sewers or waterways because fish may eat pallets, resulting in the obstruction of their digestive
tracts.
7. HANDLING AND STORAGE
- Handling suggestions
For cell
- Do not connect the positive terminal to the negative terminal with electrical wire or chain.
- Avoid polarity reverse connection when installing the battery to an instrument.
- Do not wet the battery with water, seawater, drink or acid; or expose to strong oxidizer.
- Do not damage or remove the battery case.
- Keep the battery away from heat and fire.
- Do not disassemble or reconstruct the battery; or solder the battery directly.
- Do not give a mechanical shock or deform.
- Do not use unauthorized charger or other charging method. Terminate charging when the charging
process doesn’t end within specified time.
- In the case of charging, use only dedicated charger or charge according to the conditions specified
by IDX.
For molding case
Avoid breathing processing fumes and vapors. Processing fumes and vapors may cause eye, skin
and respiratory tract irritation, and in case of overexposure, nausea and headache. Clean dust form
cutting and sanding operation to prevent its accumulation, since it may cause spark due to statics
electricity or dust explosion. Properly ground air transportation lines including hoppers, bad filters to
prevent accumulation of static electricity.
Page 5
- Storage
For cell
- Do not store the battery with metalware, water, seawater, strong acid or strong oxidizer.
- Make the charge amount 30~50% then store at room temperature or less (temperature= -20~35
degree C) in a dry (humidity: 45~85%) place. Avoid direct sunlight, high temperature, and high
humidity.
- Use insulative and adequately strong packaging material to prevent short circuit between positive
and negative terminal when the packaging breaks during normal handling. Do not use conductive or
easy to break packaging material.
For molding case
Store this product in place not subject to direct sunlight or elevated temperatures or where there are
no ignition sources. Take measures to prevent an accident due to static electricity from occurring.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION (WHEN THE ELECTROLYTE LEAKS)
For cell
- Control parameters
ACGIH has not been mentioned control parameter of electrolyte.
- Personal protective equipment
- Respiratory protection :
Respirator with air cylinder, dust mask
- Hand protection :
Protective gloves
- Eye protection :
Goggle or protective glasses designed to protect against liquid
splashes
- Skin and body protection :
Working clothes with long sleeve and long trousers
For molding case
- Personal protections
- respiratory protection :
Avoid breathing dust, vapors or fumes.
Use NIOSH/OSHA approved respiratory protection equipment(full
facepiece recommended) when airborne exposure limits are exceeded.
- Eye protection :
Does not cause significant eye irritation or eye toxicity requiring special
protection, except when in molten state. Use good industrial practice to
avoid eye contact. Processing of this product releases vapors or fumes
which may cause eye irritation. Where there is significant potential for eye
contact, wear appropriate eye protection and have eye flushing
equipment available.
- Skin protection :
Does not present a significant skin concern requiring special protection at
room temperature. Minimize skin contamination by following good
industrial hygiene practice. Processing of this product releases vapors or
Page 6
fumes which may cause skin irritation. Wash hands and contaminated
skin thoroughly after contact with processing vapors or fumes. Wear
rubber glove when handling molten resin.
ACGIH :
American Conference of Governmental Industrial Hygienists, Inc.
NIOSH :
National Institute for Occupational Safety and Health
OSHA :
Occupational Safety & Health Administration
9. PHYSICAL AND CHEMICAL PROPERTIES
For cell
- Appearance
- Physical stat :
Solid
- Form :
Cylindrical
- Color :
Metallic color(without tube if it has tube)
- Odor :
No odor
For molding case
- Appearance :
Pellet
- Boiling point :
Not applicable
- flash point :
> 520℃
- Ignition point :
> 550℃
- Vapor pressure :
Not applicable
- Melting point :
Not applicable
- Specific gravity :
1.2
- Oxidizibility
:
None under nomal handling conditions
- Flammability
:
combustible
- Explosion Limit :
Not applicable
- Solubility in water :
Unsoluble
- Odor :
None
10. STABILITY AND REACTIVITY
For cell
- Stability :
Stable under recommended conditions of storage and handling.
- Hazardous reactions occurring under specific conditions
- Conditions to avoid :
When a battery cell is exposed to an external short-circuit, crushes,
deformation, high temperature above 100 degrees Celsius, it will be the
cause of heat generation and ignition. Direct sunlight and high humidity.
- Materials to avoid :
Conductive materials, water, seawater, strong oxidizers and strong acids.
- Hazardous decomposition products : Acrid or harmful gas is emitted during fire.
Page 7
For molding case
- Thermal decomposition :
Decomposition begins at 380℃
- Reactivity with water :
none
- Self-reactivity :
none
- Hazardous decomposition products :
Smoldering or incomplete combustion leads to the formation of
toxic gas mixture such as carbon dioxide, carbon monoxide and
traces of aliphatic and aromatic hydrocarbons, aldehydes, acids,
phenol and phenol derivatives.
- Hazardous reaction :
No hazardous reaction observed.
11. TOXICOLOGICAL INFORMATION
For cell
- Organic Electrolyte
- Acute toxicity :
LD50, oral - Rat 2,000mg/kg or more
- Irritating nature :
Irritative to skin and eye
For molding case
- Skin corrosivity, Irritation :
None
- Acute Toxicity, Sub-acute toxicity, Chronic Toxicity, Mutagenic effects : Not known
- Carcinogenic effects :
IARC group 3 (not classifiable as to its carcinogenicity to
humans)
12. ECOLOGICAL INFORMATION
- Persistence / degradability :
Since a battery cell and the internal materials remain in the
nvironment, do not bury or throw out into the environment.
For molding case
Relevant information is not available.
13. DISPOSAL CONSIDERATIONS
- Recommended methods for safe and environmentally preferred disposal :
Product (waste from residues)
Specified collection or disposal of lithium ion battery is required by the law like as "battery control law"
in several nations. Collection or recycle of the battery is mainly imposed on battery's manufacturer or
importer in the nations recycle is required.
Page 8
Contaminated packaging
Neither a container nor packing is contaminated during normal use. When internal materials leaked
from a battery cells contaminates, dispose as industrial wastes subject to special control.
- Waste disposal : Efforts to recycle material should be made. If unable to use recycle, material
should be buried in approved landfill or incinerated in accordance all applicable
with federal, state and local regulations.
14. TRANSPORT INFORMATION
In the case of transportation, avoid exposure to high temperature and prevent the formation of any
condensation. Take in a cargo of them without falling, dropping and breakage. Prevent collapse of
cargo piles and wet by rain. The container must be handled carefully. Do not give shocks that result in
a mark of hitting on a batteries. Please refer to Section 7 – HANDLING AND STORAGE also.
UN classification
- UN Number and proper shipping name :
UN3480 “Lithium ion batteries ” [ or UN3481 “Lithium ion batteries packed
with equipment ” or UN3481 “Lithium ion batteries contained in
equipment”].
DUO-150/CUE-D150 : Class9 Dangerous Goods (PI965 section 1A)
Packing group 2
DUO-95,SSL-JVC50,SSL-JVC75,CUE-D95,CUE-D75,E-HL10DS :
Class9 Dangerous Goods (PI965 section 1B)
Exempted Dangerous Goods (PI965 section 2) is 2 batteries per one
packaging.
UN Specification packaging is not required. Packaging must be test for
1.2m drop test.
* However this product is defined as above, it is not recognized as "DANGEROUS GOODS" or is
treated as almost non-DANGEROUS GOODS when its transport condition accords with instructions
or provisions depend on region and transportation mode.
About the instructions or provisions, please see descriptions in box brackets of following
regulations.
Regulation depends on region and transportation mode
- Worldwide, air transportation :
IATA-DGR [As non-DANGEROUS GOODS : "packing instruction 965 section II" /
Almost as above however displayed as DANGEROUS GOODS : "packing instruction 965 section
IB"] (When batteries are packaged with equipments or contained in equipments, refer packing
instruction 966 or 967 instead of 965.)
Page 9
- Worldwide, sea transportation :
IMO-IMDG Code [special provision 188]
- Europe, road transportation :
ADR [special provision 188]
15. REGULATORY INFORMATION
- Regulations specifically applicable to the product:
IATA-DGR (air transportation)
IMO-IMDG Code (sea transportation)
US Department of Transportation 49 Code of Federal Regulations [USA]
Wastes Disposal and Public Cleaning Law [Japan]
Law for Promotion of Effective Utilization of resources [Japan]
16. OTHER INFORMATION
- The information contained in this Safety data sheet is based on the present sate of knowledge and
current legislation.
- This safety data sheet provides guidance on health, safety and environmental aspects of the product
and should not be construed as any guarantee of technical performance or suitability for particular
applications.
- IDX makes no warranty, expressed or implied regarding the accuracy of these data or the results to
be obtained from the use thereof. IDX assumes no responsibility for injury from the use to the product
described herein.
- Reference
Dangerous Goods Regulations – 56th Edition Effective from 1 January 2015: International Air
Transport Association (IATA)
MSDS of raw materials prepared by the manufactures
9th
edition:January 19, 2015
Prepared and approved by
Products Division Technical Development
IDX Company, Ltd.
Page 10