كيمياء لغات مراجعة عامة (Write all the chemical equations balanced , mention the conditions of the reaction) Answer four questions only from the following Question (1) : First : Choose the correct answer for each of the following: 1- Benzene reacts with chlorine in direct sun light giving A- cyclio hexane B- normal hexane C- gamixane D- chlorobenzene 2 - The law which controls the relation between the velocity of the chemical reaction and the concentration of reactants is discovered by A- Le chatelier B- Avogadro C- Gay lussac D- Guldberg and waage 3 - The quantity of electricity needed to precipitate ( deposit ) one gram/atom of aluminum in the reaction : Al+3 + 3e Al0 A- 0.5 faraday C- 3 faraday 4 - The oxygen gas is equal to B- faraday D- 0.3 faraday B - 6.02 ×10 23 molecules A- 32 gram C- 2 (6.02 ×10 23 ) atoms D- occupies 22.4 litre E- all previous 5 - o.001 molar solution of hydrochloric acid has a PH value equals A- 3 B- 1 C- zero D- 11 Second : A) Compare between each of the following : 1 - Chemical equilibrium and ionic equilibrium . 2 - Addition polymerization and condensation polymerization . 3 - Avogadro ,s law and gay lussac law . 4 - Dry cell and mercury cell . B) write the names of the following compounds according to the IUPAC system 1- CH3 CH CH2 CH2 OH 2- CH3 CH CH2 CH3 CH3 C2H5 3- CH3 CH2 CH2 4- CH3 C C CH CH3 CH2 CH3 C = CH2 CH3 CH2 NO2 O 5- CH3 CH CH C OH 6- CH3 CH3 Cl 1 Third : A) Write the symbolic representation, the oxidizing agent , reducing agent and the electromotive force ( e.m.f. )of the following galvanic cell : H20 + Cu+2 2H+ + Cu0 Provided that the oxidation potential of copper is ( -0.34 ) volt B) Explain briefly the following : The rate of the chemical reaction and the factors affecting it . ــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــــ Model Answer QUESTION 1 : First : Choose the correct answer for the following : 1- Gamixane 2- Guldberg and waage 4- all previous 5- 3 3- 3 Faraday Second : A- Compare between each of the following : 1- Chemical Equilibrium Ionic Equilibrium It is a state of equilibrium in the reversible reaction at which the rate of forward reaction equals the rate of backward reaction. It is the equilibrium arising between molecules of a weak electrolyte and the ions resulting from it . Ex : CH3COOH +C2H5OH Ex : CH3COO + (H3O)+ CH3COOC2H5 + H2O CH3COOH + H2O 2- Addition Polymerization Condensation Polymerization It takes place by adding a huge number of unsaturated small molecules to each other to form a very large molecule . It takes place between two different monomers and accompanied by losing a simple molecule such as water to from copolymer which continues the polymerization process. Ex(1) H H n C=C H H Ex H H Cat. Pressure CC Temp. H H Ethylene H OH n H Poly ethylene n C=C H Cl Vinyl chloride Temp. H H2O O H H Cat. Pressure OH C || Ex(2) H H H OH CC H Cl OH CH2 Copolymer n Poly Vinyl chloride P.V.C Bakelite 3- Avogadro's law Gay Lussac's law The Volumes of gases involved in a reaction Equal volumes of gases under the same pressure and temperature cantain equal numbers and the gases produced are exist in fixed ratios of molecules. P.O.C 1-The cell type: 2-Anode 3-Cathode 4-electrolyte 5-E.M.F 6- The Total reaetion 4- Dry cell Primary cell Zinc Graphite rod Ammonium chloride 1.5 volt Zn + 2MnO2 + 2NH4+ Zn+2 + 2 MnO (OH) + 2NH3 Mercury Cell Primary Zinc Mercury oxide Potassium hydroxide 1.35 volt Zn + HgO ZnO + Hg B- Write the names of the following Compounds according to the IUPAC system : 1) 2- Pentanol 2) 3- methyl pentane 3) 2- ethyl -1- pentene 4) 4- methyl -2- hexyne 5) 2, 3- dimethyl butanoic acid 6) 1- chloro -4- Nitro benzene Reduction Third : A- problem H20 + Cu+2 2H+ + Cu0 oxidation 1- The oxidizing agent is : Gopper 2- The reducing agent is : Hydrogen 3- The Anode is : Hydrogen 4- The Cathode is : Copper 5- The cell Digram : H2 2H+pt Cu+2 Cu 0 6- The electromotive Force (e.m.f) = Oxidation potential of Anode – oxidation potential of cathode = Zero – ( - 0.34 ) = + 0.34 volt Spontenlus reaction Generate electric current Direetion of current . From the anode to cathode. B- Explain briefly the following : The rate of chemical reaction : the change in Concentration of reactants or proudest per unit time. The factors affecting the rate of chemical reactions . 1 Nature of reactants : Type of bonding in the reactants : Ionic reactants undergo very fast reactions. While covalent bonded reactants undergo slow reactions. 2 Concentration while of reactants : the larger the number of reacting molecules the greater the chance of collision and the greater of reaction rate. 3 Temperature : A raise in temperature causes an increase in the proportion of activated molecules and consequently an increase in the rate of chemical reaction . 4- Increasing the pressure an the gaseous system : the reaction under equilibrium, a shift in the direction whose volume is less.
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