Material Safety Data Sheet Glyphosate 450 g/L 1. IDENTIFICATION Product Name Glyphosate 450 g/L Other Names No Data Available Uses A non-selective foliar herbicide for control of a wide range of annual and perennial grasses and broadleaved weeds. Chemical Family No Data Available Chemical Formula C3H8NO5P Chemical Name Glyphosate 450 g/L Product Description No Data Available Contact Information Organisation Location Telephone Ask For Redox Pty Ltd 2 Swettenham Road Minto NSW 2566 Australia 11 Mayo Road Wiri Auckland 2104 New Zealand +61-2-97333000 MSDS Officer Poisons Information Centre Westmead NSW 1800-251525 131126 Chemcall Australia New Zealand 1800-127406 0800-243622 +64-4-9179888 National Poisons Centre New Zealand 0800-764766 +64-9-2506222 2. HAZARD IDENTIFICATION ADG Code Non-Dangerous Goods according to the criteria of the Australian Dangerous Goods Code (ADG Code). SWA Hazard Classification Hazardous according to the criteria of Safe Work Australia [NOHSC:1008(2004)] Categories Xi Irritant Risk Phrases R36/38 Irritating to eyes and skin. Safety Phrases S36/37/39 Wear suitable protective clothing, gloves and eye/face protection. S24/25 Avoid contact with skin and eyes. HSNO Hazard Classification 9.1B; 9.1D Poisons Schedule (Aust) 5 This Material Safety Data Sheet may not provide exhaustive guidance for all HSNO Controls assigned to this substance. The EPA (New Zealand) web site should be consulted for a full list of triggered controls and cited regulations. 3. COMPOSITION/INFORMATION ON INGREDIENTS Ingredients Chemical Entity Formula CAS Number Proportion Glyphosate No Data Available 1071-83-6 45 % Inert Ingredients (non-hazardous) No Data Available Redox Pty Ltd Corporate Office Sydney Locked Bag 15 Minto NSW 2566 Australia 2 Swettenham Road Minto NSW 2566 Australia All Deliveries: 4 Holmes Road Minto NSW 2566 Australia Form 21047, Revision 3, Page 1 of 9, 07-Jul-2015 04:19:35 Phone Fax E-mail Web ABN +61 2 9733 3000 +61 2 9733 3111 [email protected] www.redox com 92 000 762 345 Australia Adelaide Brisbane Melbourne Perth Sydney Balance % New Zealand Auckland Christchurch Hawke’s Bay Malaysia Kuala Lumpur USA Los Angeles 50 TH ANNIVERSARY 1965 – 2015 Material Safety Data Sheet Glyphosate 450 g/L 4. FIRST AID MEASURES Description of necessary measures according to routes of exposure Swallowed Immediately rinse mouth with water. If swallowed do not induce vomiting. Immediately give plenty of water. Never give anything by mouth to an unconscious person. Seek medical immediate attention. Eye If in eyes, hold eyelids apart and flush the eye continuously with large amounts of water for at least 15-20 minutes. Seek medical attention if symptoms persist. Skin If skin or hair contact occurs, immediately remove contaminated clothing and wash skin with soap and water. Seek medical attention if symptoms persist. Inhaled If inhaled, remove victim to fresh air. Remove contaminated clothing and loosen remaining clothing. Allow patient to assume most comfortable position and keep warm. Seek medical attention if symptoms persist. Advice to Doctor Treat symptomatically based on judgement of doctor and individual reactions of patient. Medical Conditions Aggravated by Exposure No information available on medical conditions aggravated by exposure to this product. 5. FIRE FIGHTING MEASURES General Measures Clear fire area of all non-emergency personnel. Stay upwind. Keep out of low areas. Eliminate ignition sources. Move fire exposed containers from fire area if it can be done without risk. Flammability Conditions No Data Available Extinguishing Media In case of fire, use appropriate extinguishing media most suitable for surrounding fire conditions. Use water spray, Foam, Dry Chemical, or carbon dioxide. Fire and Explosion Hazard Not a fire or explosion hazard. Hazardous Products of Combustion Combustion may produce Oxides of nitrogen and phosphorous. This product or spray solutions of this product react with galvanized or unlined steel (except stainless steel) containers and tanks to produce hydrogen gas which may form a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder's torch, lighted cigarette or other ignition source. Avoid contact of the concentrate with strong alkalis and alkaline materials. Such contact may release isopropylamine vapour with a strong fish like odour, which is an irritant to eyes. Special Fire Fighting Instructions Do NOT allow fire fighting water to reach waterways, drains or sewers. Store fire fighting water for treatment. Personal Protective Equipment Fire fighters should wear a positive-pressure self-contained breathing apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers, boots and gloves) or chemical splash suit. Flash Point 200 °C CLosed Cup Lower Explosion Limit No Data Available Upper Explosion Limit No Data Available Auto Ignition Temperature No Data Available Hazchem Code No Data Available 6. ACCIDENTAL RELEASE MEASURES General Response Procedure Shut off all possible sources of ignition. Avoid accidents, clean up immediately. Increase ventilation. Avoid walking through spilled product as it is slippery when spilt. Use clean, non-sparking tools and equipment. Clean Up Procedures Soak up spilled product using absorbent non-combustible material such as sand or soil. Avoid using sawdust or cellulose. When saturated, collect material into suitable, labelled, dry, sealable containers and hold for safe disposal. Liquid spills that soak into the ground should be dug up, place in plastic-lined metal drums, and dispose of leaking container in accordance with instructions provided under DISPOSAL. Any received spilled liquid should be similarly collected and disposed of. Containment Stop leak if safe to do so. Decontamination Thoroughly scrub floor with a strong industrial type detergent solution and rinse with warm water. Environmental Precautionary Measures Do not allow product to reach drains, sewers or waterways. If product does enter a waterway, advise the Environmental Protection Authority or your local Waste Authority. Evacuation Criteria Evacuate all unnecessary personnel. Personnel involved in the clean up should wear full protective clothing as listed in section 8. Form 21047, Revision 3, Page 2 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L Personnel involved in the clean up should wear full protective clothing as listed in section 8. Personal Precautionary Measures 7. HANDLING AND STORAGE Handling Ensure an eye bath and safety shower are available and ready for use. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Take precautionary measures against static discharges by bonding and grounding equipment. Avoid contact with eyes, skin and clothing. Do not inhale product vapours. Avoid contamination of seed, feed or foodstuffs. Avoid contact with eye, skin and clothing, avoid breathing vapour or spray mist. Use with adequate ventilation. Keep container closed. Storage Store in a cool, dry, well-ventilated area. Keep containers tightly closed when not in use. Inspect regularly for deficiencies such as damage or leaks. Protect against physical damage. Store away from incompatible materials as listed in section 10. Do NOT store with seed, animal feed or foodstuffs. Do not store for prolonged periods in direct sunlight. This product is not classified dangerous for transport according to The Australian Code for the Transport of Dangerous Goods By Road and Rail. Container Store in original packaging as approved by manufacturer. Spray solutions of this product should be mixed, stored or applies using only stainless steel, aluminium, fiberglass, plastic or plastic-lined containers. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION General No exposure standard has been established for this product by The Safe Work Australia (SWA). NOTE: The exposure value at the TWA is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. These exposure standards are guides to be used in the control of occupational health hazards. All atmospheric contamination should be kept to as low a level as is workable. These exposure standards should not be used as fine dividing lines between safe and dangerous concentrations of chemicals. They are not a measure of relative toxicity. Exposure Limits No Data Available Biological Limits No information available on biological limit values for this product. Engineering Measures A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Adequate ventilation should be provided so that exposure limits are not exceeded. Personal Protection Equipment RESPIRATOR: Respiratory protection should not be required for normal use and handling. During periods of abnormal exposure to heavy spray or mist, use NIOSH/MSHA approved equipment for pesticide vapor/mist is recommended. The respirator use limitations specified by NIOSH/MSHA or the manufacturer must be observed (AS1715/1716). EYES: Chemical safety goggles during mixing/pouring operations or other activities in which eye contact with undiluted material is likely to occur (AS1336/1337). HANDS: Impervious elbow length chemical protective (e.g. rubber) gloves are recommended (AS2161). CLOTHING: Long-sleeved protective clothing and safety footwear (AS3765/2210). Work Hygienic Practices Wash hands and contaminated skin after handling. Clothing soaked with a solution of this material should be promptly removed and laundered before use. Food, beverages and tobacco products should not be stored or consumed where this material is in use. Always wash hands before smoking, eating, drinking or using the toilet. Wash contaminated clothing before storage or reuse. Provide eyewash fountains and safety showers in close proximity to points of potential exposure. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid Appearance Homogenous Liquid, Free from any suspended matter and sediment Odour Slight amine-like odour Colour Blue pH 4.0 - 8.5 Vapour Pressure No Data Available Relative Vapour Density No Data Available Boiling/Melting Point No Data Available Solubility Soluble in water Form 21047, Revision 3, Page 3 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L Freezing Point No Data Available Specific Gravity 1.199 - 1.22 Flash Point 200 °C CLosed Cup Auto Ignition Temp No Data Available Evaporation Rate No Data Available Bulk Density No Data Available Corrosion Rate No Data Available Decomposition Temperature No Data Available Density No Data Available Specific Heat No Data Available Molecular Weight No Data Available Net Propellant Weight No Data Available Octanol Water Coefficient No Data Available Particle Size No Data Available Partition Coefficient No Data Available Saturated Vapour Concentration No Data Available Vapour Temperature No Data Available Viscosity No Data Available Volatile Percent No Data Available VOC Volume No Data Available Additional Characteristics Solubility: Insoluble in common organic solvent Corrosivity: Slightly corrosive to iron Potential for Dust Explosion Product is a liquid. Fast or Intensely Burning Characteristics No Data Available Flame Propagation or Burning Rate of Solid Materials No Data Available Non-Flammables That Could No Data Available Contribute Unusual Hazards to a Fire Properties That May Initiate or Contribute to Fire Intensity No Data Available Reactions That Release Gases or Vapours No Data Available Release of Invisible Flammable Vapours and Gases No Data Available 10. STABILITY AND REACTIVITY Chemical Stability This material is stable for at least five years under normal conditions of warehouse storage. Heated facilities are not required. Conditions to Avoid Do not mix, store or apply the product or spray solutions of the product in galvanised steel or unlined steel (except stainless steel) containers or spray tanks. Avoid contact of the concentrate with strong alkalis and alkaline materials. Such contact may release isopropylamine vapour with a strong fish like odour, which is an irritant to eyes. Materials to Avoid Incompatible with mild steel, zinc, alkalis, galvanised and unlined steel, and sources of ignition. This product or spray solutions of this product react with galvanized or unlined steel (except stainless steel) containers and tanks to produce hydrogen gas which may form a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder's torch, lighted cigarette or other ignition source. Non-corrosive to stainless steel, polyethylene and plastics. Hazardous Decomposition Products Combustion may produce Oxides of nitrogen and phosphorous. This product or spray solutions of this product react with galvanized or unlined steel (except stainless steel) containers and tanks to produce hydrogen gas which may form a highly combustible gas mixture. This gas mixture could flash or explode, causing serious personal injury, if ignited by open flame, spark, welder's torch, lighted cigarette or other ignition source. Avoid contact of the concentrate with strong alkalis and alkaline materials. Such contact may release isopropylamine vapour with a strong fish like odour, which is an irritant to eyes. Form 21047, Revision 3, Page 4 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L Hazardous Polymerisation Polymerization Does not occur, this product can react with caustic (Basic materials to liberate heat). This is not a polymerization but rather a chemical neutralization in an acid base reaction. 11. TOXICOLOGICAL INFORMATION General Information Acute Oral LD50: >10,000 mg/Kg Acute Dermal LD50 Rabbit: >5,000 mg/Kg Chronic toxicity: Studies of glyphosate lasting up to 2 years, have been conducted with rats, dogs, mice, and rabbits, and with few exceptions no effects were observed. Laboratory studies show that glyphosate produces reproductive changes in test animals very rarely and then only at very high doses (over 150 mg/kg/day). It is unlikely that the compound would produce reproductive effects in humans. Glyphosate does not appear to be teratogenic, mutagenic or carcinogenic. EyeIrritant May cause eye irritation. Risk of serious eye damage. Direct contact may cause temporary eye irritation and conjunctivitis. Ingestion May be harmful if swallowed. Ingestion has been reported to produce gastrointestinal discomfort with irritation of the mouth, nausea, vomiting and diarrhea. Oral ingestion of large quantities of concentrated product has been reported to result in hyper-tension and pulmonary edema. Inhalation may be harmful if inhaled. Occupational exposure to this product has been reported to cause respiratory tract irritation. Symptoms include coughing, sneezing, wheezing, and blood-tinged mucous. SkinIrritant May cause skin irritation. Prolonged contact may cause skin irritation. Carcinogen Category 0 12. ECOLOGICAL INFORMATION Ecotoxicity Supplier Data: Glyphosate is not harmful to wild birds. The dietary LC50 in both mallards and bobwhite quail is greater than 4500ppm. Technical glyphosate acid is practically nontoxic to fish and may be slightly toxic to aquatic invertebrates. the reported 96-hour LC50 values for other aquatic species include greater than 10 mg/l in Atlantic oysters, 924 mg/l in fiddler crab and 281 mg/l in shrimp. The 48-hour LC50 for glyphosate in Daphnia(water flea), an important food source for freshwater fish, is 780 mg/l. Some formulations may be more toxic to fish and aquatic species due to the surfactants used in the formulation. There is a very low potential for the compound to build up in the tissues of aquatic invertebrates or other aquatic organisms. Glyphosate is nontoxic to honeybees. It;s oral and dermal LD50 is greater than 0.1 mg/bee. The reported contact LC50 values for earthworms in soil are greater than 5000 ppm. Alternatively Sourced Data: Birds: Glyphosate is slightly toxic to birds. Oral LD50 (Bob-white Quail): 4500 mg/Kg Oral LD50 (Mallard duck): 4500 mg/Kg Aquatic Organisms: Technical glyphosate acid is slightly toxic to aquatic invertibrates. LC50/96hr (Rainbow Trout): 86 mg/L LC50/96hr (Bluegill sunfish): 120 mg/L LC50/96hr (Dahnia): 780 mg/L Other Animals: Glyphosate is non-toxic to honey bees Data from the New Zealand EPA (CCID): ACUTE (9.1B) SPECIES: Skeletonema costatum (diatom) TYPE OF EXPOSURE: DURATION: 96 hr ENDPOINT: EC50 VALUE: 1.2 mg/L (based on chlorophyll a decrease) REFERENCE SOURCE: EG & G Bionomics (1978a) Toxicity of seven test materials to the marine alga, Skeletonema costatum. Marine Research Laboratory, Pensacola, Florida, EG & G Bionomics (Unpublished report No. BP-78-4-031 submitted by Monsanto Ltd). Glyphosate (EHC 159, 1994) [INCHEM] ACUTE (9.1D) SPECIES: Bluegill sunfish TYPE OF EXPOSURE: DURATION: 96 hr Form 21047, Revision 3, Page 5 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L ENDPOINT: LC50 VALUE: 45 ppm (= 45 mg/l) REFERENCE SOURCE: [EPA PESTOX DATABASE] CHRONIC (9.1B) SPECIES: Marine diatom; Skeletonema costatum TYPE OF EXPOSURE: DURATION: 7 day ENDPOINT: EC50 VALUE: 0.77 ppm (= 0.77 mg/l) REFERENCE SOURCE: [USEPA ecotox db] CHRONIC (9.1D) SPECIES: Salmo gairdnerii TYPE OF EXPOSURE: DURATION: 21 day ENDPOINT: NOEC VALUE: 52 mg/L REFERENCE SOURCE: ABC Inc. (1989e) Flow-through toxicity of glyphosate to rainbow trout (Salmo gairdnerii) for a 21-day duration period. Columbia, Missouri, Analytical Biochemistry Laboratories, Inc. (Unpublished report No. 37695 submitted by Monsanto Ltd). Glyphosate (EHC 159, 1994) [INCHEM] Persistence/Degradability Glyphosate is moderately persistent in soil, with an estimated average half-life of 47 days. Reported field half-live's range from 1 to 174 days. It is strongly adsorbed to most soils, even those with lower organic and clay content. In water glyphosate is strongly adsorbed to suspended organic and mineral matter and is broken down primarily by microorganisms. Its half-life in pond water ranges from 12 days to 10 weeks. Glyphosate may be translocated throughout the plant, including tot he roots. It is extensively metabolized in some plants. while remaining intact in others. Data from the New Zealand EPA (CCID): Rapidly Degradable: No DEGRADATION Readily degradable = No [N-CLASS] Mobility Absorption studies indicate that glyphosate has a very low mobility. Environmental Fate Do NOT let product reach waterways, drains and sewers. Bioaccumulation Potential Data from the New Zealand EPA (CCID): Bioccumulative: No Species: Lepomis macrochirus (Fish, fresh water) Exposure period: 35 day at 22 degree C Concentration: BCF: = .63 Elimination: yes Method: OECD Guide-line 305 E "Bioaccumulation: Flow-through Fish Test" Year: GLP: yes Test substance: as prescribed by 1.1 - 1.4 Remark: METHOD: Conducted in general accordance with OECD Guideline 305E. The only discrepancy is that one test concentration was used and the guideline suggests that two or more be used. However, the one concentration used of 12 ppm is higher than the maximum water concentration expected from the use of glyphosate herbicides and a relatively low bioconcentration was shown. Additional test levels would not have affected this conclusion. This study is considered scientifically valid. Source: Monsanto Bruxelles Test condition: TEST CONDITION: Concentration = 12 ppm 14C-labelled glyphosate (29) Monsanto Report MSL-9303 Uptake, Depuration and Bioconcentration of 14C Glyphosate to Bluegill Sunfish (Lepomis macrochirus) Part II. Characterization and Quantification of Glyphosate and its Metabolites (Includes results of Forbis, 1988; ABC study of bioconcentration on glyphosate in bluegill sunfish (MSL-9304) [IUCLID 2000] Environmental Impact No Data Available 13. DISPOSAL CONSIDERATIONS General Information Dispose of in accordance with all local, state and federal regulations. All empty packaging should be disposed of in accordance with Local, State, and Federal Regulations or recycled/reconditioned at an approved facility. Special Precautions for Land Fill Contact a specialist disposal company or the local waste regulator for advice. Wastes resulting from the use of this product that can not be used or chemically reprocessed should be disposed of in a landfill approved for pesticide disposal or in accordance with applicable regulations. Form 21047, Revision 3, Page 6 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L 14. TRANSPORT INFORMATION ADG Code Non-Dangerous Goods according to the criteria of the Australian Dangerous Goods Code (ADG Code). Air IATA Proper Shipping Name Glyphosate 450 g/L Class No Data Available Subsidiary Risk(s) No Data Available UN Number No Data Available Hazchem No Data Available Pack Group No Data Available Special Provision No Data Available Land Australia: ADG Proper Shipping Name Glyphosate 450 g/L Class No Data Available Subsidiary Risk(s) No Data Available No Data Available UN Number No Data Available Hazchem No Data Available Pack Group No Data Available Special Provision No Data Available New Zealand: NZS5433 Proper Shipping Name Glyphosate 450 g/L Class No Data Available Subsidiary Risk(s) No Data Available No Data Available UN Number No Data Available Hazchem No Data Available Pack Group No Data Available Special Provision No Data Available United States of America: US DOT Proper Shipping Name Glyphosate 450 g/L Class No Data Available Subsidiary Risk(s) No Data Available No Data Available UN Number No Data Available Hazchem No Data Available Pack Group No Data Available Special Provision No Data Available Form 21047, Revision 3, Page 7 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L Sea IMDG Proper Shipping Name Glyphosate 450 g/L Class No Data Available Subsidiary Risk(s) No Data Available UN Number No Data Available Hazchem No Data Available Pack Group No Data Available Special Provision No Data Available EMS No Data Available Marine Pollutant No 15. REGULATORY INFORMATION General Information No Data Available EPA (New Zealand) Hazardous Substances and New Organisms Act (HSNO) HSR000767 Poisons Schedule (Aust) 5 AICS Name GLYCINE, N-(PHOSPHONOMETHYL)- 16. OTHER INFORMATION Related Product Codes GLYPHE1000, GLYPHE1001, GLYPHE1002, GLYPHE1003, GLYPHE1004, GLYPHE1005, GLYPHE2000, GLYPHE2001, GLYPHE3000, GLYPHE3001, GLYPHE4000, GLYPHE4800, GLYPHE4802, GLYPHE6800, GLYPHE7800 Revision 4 Revision Date 04 Jun 2015 Key/Legend < Less Than > Greater Than AICS Australian Inventory of Chemical Substances atm Atmosphere CAS Chemical Abstracts Service (Registry Number) cm² Square Centimetres CO2 Carbon Dioxide COD Chemical Oxygen Demand deg C (°C) Degrees Celcius EPA (New Zealand) Environmental Protection Authority of New Zealand deg F (°F) Degrees Farenheit g Grams g/cm³ Grams per Cubic Centimetre g/l Grams per Litre HSNO Hazardous Substance and New Organism IDLH Immediately Dangerous to Life and Health immiscible Liquids are insoluable in each other. inHg Inch of Mercury inH2O Inch of Water K Kelvin kg Kilogram kg/m³ Kilograms per Cubic Metre Form 21047, Revision 3, Page 8 of 9, 07-Jul-2015 04:19:35 Material Safety Data Sheet Glyphosate 450 g/L lb Pound LC50 LC stands for lethal concentration. LC50 is the concentration of a material in air which causes the death of 50% (one half) of a group of test animals. The material is inhaled over a set period of time, usually 1 or 4 hours. LD50 LD stands for Lethal Dose. LD50 is the amount of a material, given all at once, which causes the death of 50% (one half) of a group of test animals. ltr or L Litre m³ Cubic Metre mbar Millibar mg Milligram mg/24H Milligrams per 24 Hours mg/kg Milligrams per Kilogram mg/m³ Milligrams per Cubic Metre Misc or Miscible Liquids form one homogeneous liquid phase regardless of the amount of either component present. mm Millimetre mmH2O Millimetres of Water mPa.s Millipascals per Second N/A Not Applicable NIOSH National Institute for Occupational Safety and Health NOHSC National Occupational Heath and Safety Commission OECD Organisation for Economic Co-operation and Development Oz Ounce PEL Permissible Exposure Limit Pa Pascal ppb Parts per Billion ppm Parts per Million ppm/2h Parts per Million per 2 Hours ppm/6h Parts per Million per 6 Hours psi Pounds per Square Inch R Rankine RCP Reciprocal Calculation Procedure STEL Short Term Exposure Limit TLV Threshold Limit Value tne Tonne torr Millimetre of Mercury TWA Time Weighted Average ug/24H Micrograms per 24 Hours UN United Nations wt Weight Form 21047, Revision 3, Page 9 of 9, 07-Jul-2015 04:19:35
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