Boletín de novedades Marzo - Abril 2015 Nanomateriales Marzo - Abril 2015 Boletín de novedades Índice PUBLICACIONES CIENTÍFICAS Index-Report-FLAG 1. Imagen y nanosondeo de capas de grafeno para interconexiones mediante microscopía de fuerza ató... 2 2. Variación espacial de la función de trabajo en películas de TiN nanocristalino medidas mediante... 2 3. Nanopartículas metálico-sólidas lípidas como herramientas coloidales para catalizadores de sopo... 3 4. Preparación y propiedades de fibras de nanocompuestos de celulosa/plata 3 5. Nanopartículas: síntesis y aplicaciones en ciencias de la vida y tecnología medioambiental 4 6. Nanofabricación de biomateriales esféricos a base de virus del mosaico de tabaco utilizando un ... 4 PATENTES 7. Método para fabricar estructuras nanoporosas 5 8. Método bio-inspirado para la obtención de nanocompuestos dinámicos multifuncionales 5 9. Materiales nanocompuestos para almacenamiento de hidrógeno e alta capacidad 6 10. Método para fabricar nanoestructura y artículos nanoestructurados 6 11. Método para producir nanopartículas de metal 7 NOTICIAS 12. Químicos fabrican nuevo nanomaterial a base de silicona 8 13. Nueva técnica podría brindar herramienta para el control de calidad de nanocompuestos 8 14. Nuevos metamateriales ópticos a nanoescala rompen barreras digitales de la conectividad 9 15. Modelado de nanoestructuras de materiales complejos 9 16. Científicos desarrollan microscopio de fuerza atómica para visualizar imágenes dinámicas de neu... 10 17. Nuevo sistema de metrología puede detectar defectos a nanoescala 10 18. Materiales antibacterianos casi perfectos 11 Marzo - Abril 2015 Boletín de novedades Índice 19. Investigadores combinan biomateriales antioxidantes con nanocristales de calcio para crear mate... 11 20. UE publica guía de nanomateriales para empleados y trabajadores 11 MERCADO 21. Mercado mundial para nanomateriales 13 22. Mercado global de nanotubos de carbono 2015-2019 13 23. Mercado global para nanomateriales de alto impacto: Nanocelulosa, nanotubos de carbon, grafeno ... 14 LEGISLACIÓN 24. E2490 Guía de estándares para la medición de la distribución del tamaño de partículas de nanoma... 15 EVENTOS 25. Conferencia internacional sobre nanociencia, nanotecnología y materiales avanzados 16 26. FM&NT-2015 – Materiales funcionales y nanotecnologías 16 27. ICANM 2015: Conferencia internacional y exhibición sobre nanomateriales avanzados 17 AYUDAS/SUBVENCIONES 28. EPA: Seguridad química para la sustentabilidad – Salud y seguridad ambiental de nanomateriales ... 18 Pág. 2 Marzo - Abril 2015 Boletín de novedades Nanomateriales PUBLICACIONES CIENTÍFICAS Imagen y nanosondeo de capas de grafeno para interconexiones mediante microscopía de fuerza atómica conductiva Publicada en IOPscience - Publicaciones Científicas sobre Nanoherramientas, 16/04/2015 Graphene is a promising material to replace Cu-interconnect metallization under a width of 10 nm. We report a method for evaluating the graphene interconnect wiring structure by conductive atomic force microscopy (C-AFM), which enables the direct measurement of the two-dimensional (2D) resistance distribution and the coverage evaluation of multilayer graphene (MLG) grown on Ni interconnects using a 300 mm damascene process. The resistivity of exfoliated two-layer graphene was measured and a reasonable value of 30 ???cm was obtained. We also measured the resistance of the MLG/Ni stack of 350 nm L/S patterns and confirmed the conduction paths of the MLG/Ni stack. It is demonstrated that the coverage of MLG on Ni interconnects can be estimated more precisely by C-AFM than by backscattered electron scanning electron microscopy (BSE-SEM) observation. C-AFM is demonstrated to be a potential technique for the local conductance evaluation of next-generation interconnects. ver más... Variación espacial de la función de trabajo en películas de TiN nanocristalino medidas mediante microscopía de efecto túnel en modo dual Publicada en IOPscience - Publicaciones Científicas sobre Nanoherramientas, 16/02/2015 We explored novel approach to measure spatial variation of work function (WF) on polycrystalline 20-nm-thick TiN films by using simultaneous measurements of tunneling current and interaction force in scanning tunneling microscopy. Upon processing at 860 °C in N 2 atmosphere, the mean grain size increased from 3–5 to 20–30 nm. For multi-facet grains, facet-dependent variation of the WF was observed in the maps. Three WF values were ascribed to (001) and (111) crystal planes of cubic TiN. The area fraction of high-WF facets increased from 55% for as-grown to 70% for processed films. ver más... Volver al índice Pág. 3 Marzo - Abril 2015 Boletín de novedades Nanomateriales Nanopartículas metálico-sólidas lípidas como herramientas coloidales para catalizadores de soporte meso-macroporosos Publicada en ACS Nano - Publicaciones Científicas sobre Nanoherramientas, 28/01/2015 Meso–macroporous silica containing iron oxide nanoparticles (15–20 nm) was synthesized by formulating solid lipid nanoparticles and metallosurfactant as both template and metal source. Because of the high active surface area of the catalyst, the material exhibits an excellent performance in a Fenton-like reaction for methylene blue (MB) degradation, even at low amount of iron oxide (5% TOC after 14 h). ver más... Preparación y propiedades de fibras de nanocompuestos de celulosa/plata Publicada en ScienceDirect - Publicaciones Científicas sobre Nanoproductos, 22/01/2015 Publication date: 22 January 2015. Source: Carbohydrate Polymers, Volume 115. Author(s): Ran Li , Meng He , Tong Li , Lina Zhang. We prepared cellulose/silver nanocomposite fibers by soaking the cellulose fibers in AgNO3 aqueous solution, which was heated at 80°C for 24h to synthesize Ag nanoparticles in situ. The structure and properties of the composite fibers were characterized by FT-IR, X-ray diffraction (XRD), scanning electron microscopy (SEM), transmitting electron microscopy (TEM), thermo-gravimetric analysis (TGA) and tensile testing. The content and diameter of the Ag nanoparticles (NPs) increased from 0.15% to 2.40% and from 7.2nm to 12.5nm, respectively. In our findings, the pores of the cellulose fiber at wet state were used as a microreactor to synthesize Ag nanopariticles. The cellulose/Ag nanocomposite fibers exhibited good mechanical properties and thermal stability. Antibacterial experiment revealed excellent antibacterial activity of the cellulose nanocomposite fibers against Staphylococcus aureus. The cellulose/silver nanocomposite fibers would have great potential in antibacterial textile and wound handling due to easy industrialization. ver más... Volver al índice Pág. 4 Marzo - Abril 2015 Boletín de novedades Nanomateriales Nanopartículas: síntesis y aplicaciones en ciencias de la vida y tecnología medioambiental Publicada en IOPscience - Publicaciones Científicas sobre NanodispositivosNanosistemas, 30/12/2014 This work focuses on the synthesis, functionalization, and application of gold and silver nanoparticles, magnetic nanoparticles Fe 3 O 4 , combination of 4-ATP-coated silver nanoparticles and Fe 3 O 4 nanoparticles. The synthesis methods such as chemical reduction, seeding, coprecipitation,and inverse microemulsion will be outlined. Silica- and amino-coated nanoparticles are suitable for several applications in biomedicine and the environment. The applications of the prepared nanoparticles for early detection of breast cancer cells, basal cell carcinoma, antibacterial test, arsenic removal from water, Herpes DNA separation, CD4 + cell separation and isolation of DNA of Hepatitis virus type B (HBV) and Epstein–Barr virus (EBV) are discussed. Finally, some promising perspectives will be pointed out. ver más... Nanofabricación de biomateriales esféricos a base de virus del mosaico de tabaco utilizando un método de flujo continuo Publicada en ACS Nano - Publicaciones Científicas sobre Nanoherramientas, 17/12/2014 Nanomanufacturing of nanoparticles is critical for potential translation and commercialization. Continuous flow devices can alleviate this need through unceasing production of nanoparticles. Here we demonstrate the scaled-up production of spherical nanoparticles functionalized with biomedical cargos from the rod-shaped plant virus tobacco mosaic virus (TMV) using a mesofluidic, continued flow method. Production yields were increased 30-fold comparing the mesofluidic device versus batch methods. Finally, we produced MRI contrast agents of select sizes, with per particle relaxivity reaching 979,218 mM–1 s–1 at 60 MHz. These TMV-based spherical nanoparticle MRI contrast agents are in the top echelon of relaxivity per nanoparticle. ver más... Volver al índice Pág. 5 Marzo - Abril 2015 Boletín de novedades Nanomateriales PATENTES Método para fabricar estructuras nanoporosas Publicada en Espacenet - Patentes sobre Nanodispositivos-Nanosistemas 2, 18/02/2015 A method of making a nanoporous structure comprising a matrix and at least one nanosized pore within the matrix, wherein the method comprises contacting at least a portion of a templated matrix with an acid solution, wherein the templated matrix comprises a matrix that selected from the group consisting of an organic polymer, a sol-based ceramic, an inorganic salt, an organoaluminate, and combinations thereof, and one or more nanosized templates within the matrix, wherein each nanosized template comprises a core that comprises an inorganic oxide, to dissolve at least a portion of the inorganic oxide of at least one of the cores and form the at least one nanosized pore within the matrix thereby forming the nanoporous structure. ver más... Método bio-inspirado para la obtención de nanocompuestos dinámicos multifuncionales Publicada en Espacenet - Patentes sobre Nanodispositivos-Nanosistemas 2, 04/02/2015 A method for a polymeric or nanocomposite material. The method includes assembling a multiphase hard-soft structure, where the structure includes a hard micro- or nano-phase, and a soft micro- or nano-phase that includes a polymeric scaffold. In the method, the polymeric scaffold includes dynamically interacting motifs and has a glass transition temperature (Tg) lower than the intended operating temperature of the material. ver más... Volver al índice Pág. 6 Marzo - Abril 2015 Boletín de novedades Nanomateriales Materiales nanocompuestos para almacenamiento de hidrógeno e alta capacidad Publicada en Espacenet - Patentes sobre Nanoproductos 2, 02/02/2015 A novel hydrogen absorption material is provided comprising a mixture of a lithium hydride with a fullerene. The subsequent reaction product provides for a hydrogen storage material which reversibly stores and releases hydrogen at temperatures of about 270 DEG C. ver más... Volver al índice Pág. 7 Marzo - Abril 2015 Boletín de novedades Nanomateriales Método para fabricar nanoestructura y artículos nanoestructurados Publicada en Espacenet - Patentes sobre Nanodispositivos-Nanosistemas 1, 28/01/2015 A method of making a nanostructure and nanostructured articles by depositing a layer to a major surface of a substrate by plasma chemical vapor deposition from a gaseous mixture while substantially simultaneously etching the surface with a reactive species. The method includes providing a substrate; mixing a first gaseous species capable of depositing a layer onto the substrate when formed into a plasma, with a second gaseous species capable of etching the substrate when formed into a plasma, thereby forming a gaseous mixture; forming the gaseous mixture into a plasma; and exposing a surface of the substrate to the plasma, wherein the surface is etched and a layer is deposited on at least a portion of the etched surface substantially simultaneously, thereby forming the nanostructure. The substrate can be a (co)polymeric material, an inorganic material, an alloy, a solid solution, or a combination thereof. The deposited layer can include the reaction product of plasma chemical vapor deposition using a reactant gas comprising a compound selected from the group consisting of organosilicon compounds, metal alkyl compounds, metal isopropoxide compounds, metal acetylacetonate compounds, metal halide compounds, and combinations thereof. Nanostructures of high aspect ratio and optionally with random dimensions in at least one dimension and preferably in three orthogonal dimensions can be prepared. ver más... Método para producir nanopartículas de metal Publicada en Espacenet - Patentes sobre Nanomateriales 3, 10/12/2014 The present specification relates to a method for producing metal nanoparticles. ver más... Volver al índice Pág. 8 Marzo - Abril 2015 Boletín de novedades Nanomateriales NOTICIAS Químicos fabrican nuevo nanomaterial a base de silicona Publicada en Science Daily - Nanomaterials, 26/03/2015 A new process uses silicon telluride to produce multilayered two-dimensional semiconductor materials in a variety of shapes and orientations. ver más... Nueva técnica podría brindar herramienta para el control de calidad de nanocompuestos Publicada en Nanotechnology News Today - Carbon Nanotubes News, 23/03/2015 Layered nanocomposites containing tiny structures mixed into a polymer matrix are gaining commercial use, but their complex nature can hide defects that affect performance. Now researchers have developed a system capable of detecting such defects using a "Kelvin probe" scanning method with an atomic force microscope. The ability to look below the surface of nanocomposites represents a potential new quality-control tool for industry. ver más... Volver al índice Pág. 9 Marzo - Abril 2015 Boletín de novedades Nanomateriales Nuevos metamateriales ópticos a nanoescala rompen barreras digitales de la conectividad Publicada en Nanowerk - Nanotechnology News, 18/03/2015 A new study finds that new optical materials could serve as the nuts and bolts of future ultra-high-speed optical computing components. These 'nonlinear metamaterials', which possess physical capabilities not found in nature, may be the building blocks that allow major companies like IBM and Intel to move from electronic to optical computing. ver más... Modelado de nanoestructuras de materiales complejos Publicada en Science Daily - Nanomaterials, 18/03/2015 Brookhaven physicists have illustrated how advances in computing and applied mathematics can improve the predictive value of models used to design new materials. ver más... Volver al índice Pág. 10 Marzo - Abril 2015 Boletín de novedades Nanomateriales Científicos desarrollan microscopio de fuerza atómica para visualizar imágenes dinámicas de neuronas Publicada en PhysOrg.com - Nanofisica news, 13/03/2015 Researchers at the Max Planck Florida Institute for Neuroscience and Kanazawa University (Japan) have succeeded in imaging structural dynamics of living neurons with an unprecedented spatial resolution. ver más... Nuevo sistema de metrología puede detectar defectos a nanoescala Publicada en AZoNano.com_Nanoanalysis | News, 25/02/2015 Research at the University of Huddersfield will lead to major efficiency gains and cost savings in the manufacture of flexible solar panels. It has also resulted in an exceptional number of scholarly articles co-authored by a Libyan scientist who is completing his doctoral studies as a participant in the EU-backed project. ver más... Volver al índice Pág. 11 Marzo - Abril 2015 Boletín de novedades Nanomateriales Materiales antibacterianos casi perfectos Publicada en Nanowerk - Nanotechnology News, 19/02/2015 Ruthless with bacteria, harmless to human cells. New, durable antibacterial coatings of nanocomposites will in future help to improve the hygiene of sportswear, and used in medicine, will reduce the rate of infections and shorten the times of in-patient hospital admissions. ver más... Investigadores combinan biomateriales antioxidantes con nanocristales de calcio para crear material parecido al hueso Publicada en AZoNano.com_Nanomaterials | News Feed, 31/12/2014 onnecting the femur to the tibia, the anterior cruciate ligament (ACL) rupture is one of the most devastating injuries in sports. No other injury has sidelined more athletes for a season or even the rest of a career. ver más... Volver al índice Pág. 12 Marzo - Abril 2015 Boletín de novedades Nanomateriales UE publica guía de nanomateriales para empleados y trabajadores Publicada en Nanowerk - Nanotechnology News, 18/12/2014 This Guidance document offers an overview of the issues surrounding the safe use of manufactured nanomaterials in the workplace, sets out the broad outlines of preventive action and provides a practical tool for complying with specific aspects of ensuring workers' safety, such as risk assessment and risk management. ver más... Volver al índice Pág. 13 Marzo - Abril 2015 Boletín de novedades Nanomateriales MERCADO Mercado mundial para nanomateriales Publicada en Research and Markets - Nanotechnology Market Publications, 28/02/2015 Nanomaterials (also called nanoparticles or nanopowders) are increasingly becoming part of our daily lives. Their novel properties, that are not apparent in larger forms of the same material, has led to their desirability and exploitation in a wide range of applications. Nanomaterials can be defined as substances that are intentionally produced, manufactured or engineered to have specific properties and one or more dimensions typically between 1 and 100 nanometres. Most nanomaterials are produced in multi-ton volumes in varying sizes, shapes, and also in surface coatings. Nanomaterials cover a range of materials inorganic metal and metal oxide nanomaterials, carbon-based nanomaterials and polymeric particulate materials in a variety of forms. ver más... Mercado global de nanotubos de carbono 2015-2019 Publicada en Vertical Markets Research Portal_Nanotechnology Market Research Reports, 21/01/2015 Carbon nanotubes are cylinder-shaped graphite sheets. They may consist of a single layer (SWCNTs) or many layers (MWCNTs). They have high thermal and electrical conductivity and are utilized in a wide variety of applications. Some high growth applications of carbon nanotubes are in electronic devices, electrochemical sensors and biosensors, transistors, lithium-ion (li-ion) batteries, hydrogen storage cells, cathode ray tubes, electrostatic discharge protection and electrical shielding applications. TechNavio's analysts forecast the Global Carbon Nanotubes market to grow at a CAGR of 14.84 percent over the period 2014-2019. ver más... Volver al índice Pág. 14 Marzo - Abril 2015 Boletín de novedades Nanomateriales Mercado global para nanomateriales de alto impacto: Nanocelulosa, nanotubos de carbon, grafeno y nanomateriales 2-D Publicada en MarketPublishers.com - Nanomateriales, 01/12/2014 Many industries including electronics, automotive, aerospace, telecommunications and healthcare are exploring the use of high impact nanomaterials such as nanocellulose, carbon nanotubes and graphene. Other 2-D nanomaterials such as silicene, graphyne, graphdiyne, grapahane and molybdenum disulfide are under intense study. CNTs and graphene are the strongest, lightest and most conductive fibers known to man, with a performance- per-weight greater than any other material. ver más... Volver al índice Pág. 15 Marzo - Abril 2015 Boletín de novedades Nanomateriales LEGISLACIÓN E2490 Guía de estándares para la medición de la distribución del tamaño de partículas de nanomateriales en suspensión mediante espectroscopía de correlación fotónica (PCS) ha sido reaprobada, disponible como E2490-09(2015) Publicada en ASTM International's Committee E56 on Nanotechnology New Standards, 13/04/2015 5.1 PCS is one of the very few techniques that are able to deal with the measurement of particle size distribution in the nano-size region. This Guide highlights this light scattering technique, generally applicable in the particle size range from the sub-nm region until the onset of sedimentation in the sample. The PCS technique is usually applied to slurries or suspensions of solid material in a liquid carrier. It is a first principles method (that is, calibration in the standard understanding of this word, is not involved). ver más... Volver al índice Pág. 16 Marzo - Abril 2015 Boletín de novedades Nanomateriales EVENTOS Conferencia internacional sobre nanociencia, nanotecnología y materiales avanzados Publicada en NanoConferences.com - Nanotechnology Events, 10/04/2015 The scope of this conference is to capitalize on immensely growing field of nanoscience and nanotechnology drawing in experts from across international and national academic community as well as industry to bridge the gap between industry and academia. ver más... FM&NT-2015 – Materiales funcionales y nanotecnologías Publicada en Fundación Phantoms - Nanotechnology Events , 02/02/2015 October 5 – 8, 2015. Vilnius, Lithuania. FM&NT became an international forum attracting participants not only from the countries of Baltic sea region, but also from the rest of EU, Norway, Russia, Ukraine, Belarus, Kazakhstan, Taiwan, Korea, Georgia, Turkey, Serbia, etc. The diverse country list is an indication of the importance of the conference for scientists working in various fields. ver más... Volver al índice Pág. 17 Marzo - Abril 2015 Boletín de novedades Nanomateriales ICANM 2015: Conferencia internacional y exhibición sobre nanomateriales avanzados Publicada en SAFENANO - Nanotechnology Events, 02/02/2015 August 10-12, 2015. Ottawa, Canada. The ICANM2015 organizing committee warmly invite you to attend the ICANM 2015 conference. ICANM2015 takes place in Ottawa, Canada. Nestled on the banks of the majestic Ottawa, Rideau and Gatineau Rivers, Ottawa is one of the most beautiful G8 capitals in the world. Ottawa is also rich in culture and heritage with its many national institutions, parklands, waterways and historic architecture. It provides a spectacular environment for meeting and networking. ver más... Volver al índice Pág. 18 Marzo - Abril 2015 Boletín de novedades Nanomateriales AYUDAS/SUBVENCIONES EPA: Seguridad química para la sustentabilidad – Salud y seguridad ambiental de nanomateriales (STAR-C2) Publicada en Nano.gov - Nanotechnology Funding and Grant, 10/04/2015 Proposals in this topic focus on how to characterize engineered/ manufactured nanomaterials-ENMs (including nano-bio and other emerging compounds) in complex biological and environmental media and how to efficiently evaluate and predict potential for risks across the material life cycle associated with use of ENMs in consumer products. ver más... Volver al índice Para más información: Programa Nacional de Vigilancia Tecnológica e Inteligencia Competitiva (VINTEC) Dirección Nacional de Estudios (DNE) · Subsecretaría de Estudios y Prospectiva Ministerio de Ciencia, Tecnología e Innovación Productiva de la Nación Godoy Cruz 2320 3 piso · (C1425FQD) · Buenos Aires · Argentina Tel: (011) 4899-5300 int. 3004 · [email protected] · www.mincyt.gob.ar Entidades que colaboraron: Trabajo realizado por:
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