How to Count Atoms 1. The symbol of an element represents one atom of that element. e.g., Ba = 2. A subscript is a number written at the lower right corner behind the symbol of an element. If there is more than one atom of the element, then a subscript is used to indicate the number of atoms. e.g., Cl2 = 3. A subscript outside a bracket multiples all the elements inside the brackets. e.g., Ca3(PO4)2 Ca = ________ P = ________ O = ________ 3. A coefficient is a number written in front of a chemical symbol and indicates the number of atoms of that element or number of molecules e.g., 3C = ____ 2NaCl = _______________________ 2 H2O _____ molecules of H2O _____ H (hydrogen) _____ O (oxygen) 3 Na2SO4 _____ molecules of Na2SO4 _____ Na (sodium) _____ S (sulphur) _____ O (oxygen) 4 Pb(NO3)2 _____ molecules of Pb(NO3)2 _____ Pb (Lead) _____ N (nitrogen) _____ O (oxygen) Count the atoms present in the different compounds by using the coefficients and subscripts. K2CO3 Type of Atom # of Atoms ______________ ______ ______________ ______ ______________ ______ Ba3(PO4)2 Type of Atom # of Atoms _______________ ______ _______________ ______ _______________ ______ Pb(NO3)2 Type of Atoms # of Atoms ______________ ______ ______________ ______ ______________ ______ Na2CrO4 Type of Atom # of Atoms ______________ ______ ______________ ______ ______________ ______ 3 CaCl2 Type of Atom # of Atoms _______________ ______ _______________ ______ 2 (NH4)2Cr2O7 Type of Atoms # of Atoms ______________ ______ ______________ ______ ______________ ______ ______________ ______ NH4C2H3O2 Type of Atom # of Atoms ______________ ______ ______________ ______ ______________ ______ ______________ ______ 4 Al2(CO3)3 Type of Atom # of Atoms ________________ ______ ________________ ______ ________________ ______ Chemical Equations We use equations to represent __________________________ 2 Types: 1. __________________________: potassium iodide + lead (II) nitrate potassium nitrate + lead (II) iodide 2. _______________________: -skeleton equation: We often use subscripts in brackets to identify the __________ of a compound/element (s) (l) (g) (aq) - _________________ - _________________ - _________________ - _________________________________ Law of Conservation of Mass The law of conservation of mass states that the total mass of the reactants is always __________________ to the total mass of the products So... ____________________________________________________________ Because of this law, we must _________________ chemical equations. The molecules are ________________ and the atoms are _________________but we must ensure that there are equal numbers of atoms before and after the reaction. i.e. if I start with 5 hydrogen atoms, I must end with ____________________________. Rules for balancing: 1. Balance all ________________________ first 2. If possible, balance ____________________________ as a "chunk" 3. Balance any non-metals other than ____________________________ 4. Balance _______________________ 5. Balance _______________________ 6. ___________________ both sides of the reaction to ensure all atoms are balanced! Balance these reactions: KI(aq) + Pb(NO3)2(aq) KNO3(aq) Al H2SO4 Al(SO4)3 + + C3H8 + FeCl3 CaO + O2 CO2 Fe + Cl2 H2O Ca(OH)2 H2O Mg(OH)2 + + + PbI2(s) H2 H2O Hint: Sometimes… Mg + H2 Hint: If you have __________ on one side and __________ on the other... write H2O as HOH and balance the _____________ ions first C2H6 + O2 CO2 + H2O Hint: If you end up with a half O2 molecule... _________________________ Classification of Chemical Reactions Chemists have identified millions of different compounds, so there must be millions of different chemical reactions to form them. When scientists are confronted with an overwhelming number of things, they tend to classify them into groups, in order to make them easier to study and understand. One popular classification scheme for chemical reactions breaks them up into five major categories or types. Types of Chemical Reactions: 1. Synthesis - A synthesis reaction involves two or more substances combining to make a more complex substance. The reactants may be elements or compounds, and the product will always be a compound. The general formula for this type of reaction can be shown as; A + B ----> AB or element or compound + element or compound -----> compound Some examples of synthesis reactions are shown below; 2H2(g) + O2(g) ----> 2H2O(g) C(s) + O2(g) ----> CO2(g) CaO(s) + H2O(l) ----> Ca(OH)2(s) 2. Decomposition - In a decomposition reaction, one substance is broken down into two or more, simpler substances. This type of reaction is the opposite of a synthesis reaction, as shown by the general formula below; AB ----> A + B or Compound ------> element or compound + element or compound Some examples of decomposition reactions are shown below; C12H22O11(s) ----> 12C(s) + 11H2O(g) Pb(OH)2(cr) ----> PbO(cr) + H2O(g) 2Ag2O(cr) ----> 4Ag(cr) + O2(g) 3. Single Displacement - In this type of reaction, a neutral element becomes an ion as it replaces another ion in a compound. The general form of this equation can be written as; In the case of a positive ion (cation) being replaced: A + BC ----> B + AC or In the case of a negative ion (anion) being replaced: A + BC ----> C + BA in either case we have; element + compound ----> element + compound Some examples of single displacement reactions are shown below: Zn(s) + H2SO4(aq) ----> ZnSO4(aq) + H2(g) 2Al(s) + 3CuCl2(aq) ---> 2AlCl3(aq) + 3Cu(s) Cl2(g) + KBr(aq) ----> KCl(aq) + Br2(l) 4. Double Displacement - Like dancing couples, the compounds in this type of reaction exchange partners. The basic form for this type of reaction is shown below; AB + CD ----> CB + AD or Ionic Compound + Ionic Compound ----> Ionic Compound + Ionic Compound Some examples of double displacement reactions are shown below; AgNO3(aq) + NaCl(aq) ----> AgCl(s) + NaNO3(aq) ZnBr2(aq) + 2AgNO3(aq) ----> Zn(NO3)2(aq) + 2AgBr(cr) H2SO4(aq) + 2NaOH(aq) ----> Na2SO4(aq) + 2H2O(l) 5. Combustion - When organic compounds like propane are burned, they react with the oxygen in the air to form carbon dioxide and water. The reason why these combustion reactions will stop when all available oxygen is used up is because oxygen is one of the reactants. The basic form of the combustion reaction is shown below; hydrocarbon + oxygen ----> carbon dioxide and water Some examples of combustion reactions are; CH4(g) + 2O2(g) ----> 2H2O(g) + CO2(g) 2C2H6(g) + 7O2(g) ----> 6H20(g) + 4CO2(g) C3H8(g) + 5O2(g) ----> 4H2O(g) + 3CO2(g) Oxidation When ______________________ reacts in a chemical reaction, the general name for the reaction is oxidation. The _________________ of the reaction will determine the name given to the reaction. Corrosion: the ___________ reaction of oxygen with another substance Metal and oxygen: forms a ________________________ Nonmetal and oxygen: forms a ___________________________________ Combustion: the _____________________ reaction of oxygen with a hydrocarbon Complete combustion: the rapid reaction of oxygen with a hydrocarbon to form only ____________________________________________________ and energy. This reaction happens when there is______________ of oxygen around and it consumes _____________ of the fuel. The flame is very hot and _________________. Incomplete combustion: the rapid reaction of oxygen with a hydrocarbon to form water and some combination of _______________________________________________ and energy. This reaction happens when there is _______________oxygen available. The flame is cooler and ______________________. Indicators Acids and Bases An acid is a substance that produces ___________________ in solution, __ (aq). Examples: Most solutions of acids or bases are ____ and _______. Therefore they cannot be distinguished from ordinary water by appearance alone. The simplest way to i) When hydrochloric acid, HCl is placed in solution it dissociates into distinguish them from water is to use an indicator. An indicator is a substance ________________________ that changes _________ as the concentration of ___ and ___ changes. ii) When sulfuric acid, H2SO4 is placed in water it dissociates into ________________________________ Indicator Acids are created when _______________________ react with water. SO2 + H2O NO2 + H2O A base is a substance that produces __________________ in solution, ___ Acid Base Neutral Litmus Paper Phenolpthalein (aq). Bromthymol Blue Examples: red cabbage i) When sodium hydroxide, NaOH is placed in solution it dissociates into __________________ Concentration of Acids and Bases/pH ii) When calcium hydroxide, Ca(OH)2 is placed in solution it dissociates into __________________ Concentration is defined as the amount of _______ per quantity of __________. Bases are created when __________________________ react with water Li2O + H2O FeO + H2O Characteristics of Acids & Bases Substances have long been classified as acids or bases according to some general properties which are summarized below. Acid Properties Base Properties pH ________________________ pH ______________________ Conducts_________ when disolved in water Conducts __________ when disolved in water __________________ taste ________________ taste corrosive corrosive. slippery feel The concentration of a product can easily be altered by ____________________ or the _______________________. ___________ is the universal solvent. When you determine the concentration of hydrogen ions in solution (amount of H+ ions/ total solution volume) you are determining the ___ of that particular solution. pH stands for, “the power of hydrogen”. The pH of a substance can be determined a number of different ways, such as with the use of pH paper, an electronic pH meter or mathematically. The pH scale ranges from _________. 0 7 Acids have a pH ______________ Bases have a pH ________________ Neutral substances have a pH _____________ 14 The pH scale is actually a measure of the number of H+ ions in a solution. If there are a lot of H+ ions, the pH is very low. If there are a lot of OHions, that means the number of H+ ions is very low, so the pH is high. While the pH scale ranges from 0 to 14 and each pH unit represents a factor of The pH of a substance depends on both _______________ (how many ions dissociate?) and _____________________ (how much is dissolved in solution?) Neutralization Reactions Neutralization occurs when _________________ and ___________ are mixed to make ______ and a ________. Neutralization reactions are a special type of _____________ ________________ reaction. The general word equation for a neutralization is: _______. A change in pH from 4 to 5 is a(n) _____________ increase/decrease in [H+] A change in pH from 3 to 8 is a(n) _____________ increase/decrease in [H+] A change in pH from 11 to 2 is a(n) _____________ increase/decrease in [H +] Strength of Acids and Bases Example: Aqueous solutions of hydrobromic acid and beryllium hydroxide undergo a neutralization reaction to produce water and beryllium bromide. Strong acid – Complete the following equations: Example: ___ H2SO4 (aq) + ___ LiOH (aq) HCl(aq) H+(aq) + Cl-(aq) When hydrogen chloride molecules enter an aqueous solution, 100% of the ___ Ca(OH)2 (aq) + ___ H3PO4 (aq) hydrogen chloride molecules dissociate. As a result the solution contains the same percent of H+ ions and Cl- ions: 100% Strong base – Which acid and base would you react together to produce the following salts: i) KNO3 Examples: NaOH, ii) MgCO3 Mg(OH)2
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