Ambient Air Quality Monitoring Report Castlegar, British Columbia Ministry of Environment KOOTENAY REGION ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia: Particulate Matter - 1990 to 2007 Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia Preface Acknowledgements The following report was prepared by Paul Willis and Robert Newell of the Ministry of Environment. We would like to thank Chris Marsh, and Garry Bell, air technicians (Ministry of Environment) responsible for maintaining the monitoring equipment, and further thanks to Julia Beatty (Ministry of Environment), and Dr. Carl Schwarz (Simon Fraser University) for their contributions to the report. Cover Photos Courtesy of: ‘Pristine’ Castlegar: Ministry of Transportation ‘Hazy’ Castlegar: OurBC.com ii ENVIRONMENTAL QUALITY The following report is one in a series of air quality reports being issued by the Kootenay Regional Office for all communities in the region where air quality is monitored. The intention of the Regional Office of the Ministry of Environment is to publish air quality reports on our website (http://www.env.gov.bc.ca/epd/regions/kootenay/aq_reports/index.htm) to provide the information to industry and local government, other stakeholders and the public at large. By providing such information in a readily understood format, the Ministry of Environment hopes local environmental quality conditions can be better understood, and better decisions regarding air quality management can be made. Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia Prepared by: Ministry of Environment Environmental Quality Section 205 Industrial Road G Cranbrook, B.C. V1C 6H3 August, 2008 iii ENVIRONMENTAL QUALITY Particulate Matter - 1990 to 2007 Ambient Air Quality Monitoring Report Castlegar, British Columbia Executive Summary The Castlegar airshed refers to an air mass which extends through the valley system surrounding the confluence of the Columbia River and the Kootenay River. The airshed extends approximately 15 km either side of the Kootenay and Columbia rivers and 30 km along each valley axis. In addition, the Castlegar airshed extends approximately 20 km north into the foothills of the Selkirk Mountain Range. The Selkirk Mountain Range surrounds Castlegar and, thus, heavily influences the containment and dispersion of air pollutants within the airshed. PM in Castlegar currently is monitored by a device known as a “Partisol” manual sampler 1 . The device was located on top of the Castlegar Fire Hall. The sampler and devices like this Partisol have been used for air quality monitoring purposes since 1990. Air quality data is extrapolated from analysis of air filters collected from the Partisol system. Collection of filters is conducted on six-day cycle ensuring that data is produced for every day of the week (i.e., Tuesday, Monday, Sunday, etc.). The air quality monitoring program has been in place in Castlegar for approximately 18 years (since 1990), allowing air quality trends in the Castlegar airshed to begin to emerge. Data indicates that Castlegar’s PM levels have decreased in recent years from the early 1990s. Mean annual PM concentrations exceeded the World Health Organization objective of 20 μg/m3 for the majority of the first half of the 1990s; however, yearly PM means have not exceeded the objective in over a decade. Furthermore, the most recent year of air quality monitoring (2007) produced one of the lowest PM means observed during the 18-year monitoring period. In addition, health indicators such as exposure levels have decreased dramatically over the last 18 years. Whether PM concentrations and health indicators will continue to decrease is uncertain; however, the decrease in PM and health indicators from the first five years of the monitoring program to the last five years of monitoring is apparent. PM in Castlegar originates from many sources including fugitive dust from traffic, woodstove smoke, industrial emissions, slash burning activities, and forest fires. The extent a source of PM might impact the Castlegar airshed depends on many factors, such as the time of the year. For example, PM generated from vehicular traffic could increase during months of high tourism. 1 A manual sampler is an air sampler that does not have automated mass measurement and communication capabilities. iv Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY A vast amount of evidence exists to support the concern that airborne particulate matter (PM) poses a significant health risk to humans. In response to such a concern, the Ministry of Environment (MoE) has implemented air quality monitoring programs in various communities throughout British Columbia. The following report provides an assessment of the results of the monitoring program established in the Castlegar airshed. The report was prepared by the MoE in an effort to inform the public, local government, and industry on the air quality conditions within the Castlegar airshed based on PM data collected during the years of 1990 to 2007. The purpose of the report is to provide insight on how to effectively manage the local air quality conditions of Castlegar. Ambient Air Quality Monitoring Report Castlegar, British Columbia ENVIRONMENTAL QUALITY The MoE has compared data collected from the Castlegar airshed monitoring program (from 1990 to 2007) with air quality standards used in British Columbia and, currently, Castlegar airshed does not appear to be a major concern in terms of ambient air PM concentrations. However, air quality monitoring will continue in the Castlegar airshed on a routine frequency, to ensure we understand whether PM levels continue to remain below B.C. air quality objectives. A “safe” level of exposure for PM does not exist, meaning PM impacts public health even at low levels. So although PM levels in Castlegar comply with provincial air quality objectives, the public, government and industry should be constantly cooperating and striving to improve air quality within the Castlegar airshed. v Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia Table of Contents Preface ................................................................................................................................ ii Executive Summary ......................................................................................................... iv 2.0 Air Quality Objectives/Standards ............................................................................. 5 2.1 Provincial Objectives ............................................................................................... 5 2.1.1 Air Quality Index ............................................................................................... 5 2.2 National Ambient Air Quality Objectives (NAAQOs) ............................................. 5 2.2.1 Reference Levels ................................................................................................ 6 2.2.2 Exposure Estimates ............................................................................................ 6 2.3 Canada-wide Standards (CWS) Agreement.............................................................. 6 2.4 Comparison of Federal and Provincial Air Quality Criteria ..................................... 7 2.5 World Health Organization (WHO) Objective ......................................................... 8 3.0 Air Quality Monitoring in Castlegar ....................................................................... 9 4.0 Airshed Description ................................................................................................. 11 4.1 Influences on Air Quality: Emissions .................................................................... 12 4.1.1 Provincial Overview ........................................................................................ 12 4.2 Influences on Air Quality: Weather and Terrain ................................................... 15 5.0 Air Quality in Castlegar .......................................................................................... 19 5.1 Results and Trends .................................................................................................. 20 6.0 Conculsions and Recommendations ........................................................................ 28 For More Information .................................................................................................... 30 vi Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY 1.0 Introduction ................................................................................................................. 1 1.1 Particulate Matter and Health Effects ...................................................................... 3 Appendices ....................................................................................................................... 31 Appendix A - Glossary and Abbreviations ................................................................... 31 Appendix B – NAAQO Exposure Calculations............................................................ 37 Appendix C - Central Tendency and Statistical Significance ....................................... 38 Appendix D - ANOVA Tests ........................................................................................ 41 Appendix D1 - ANOVA Applied to Yearly Data ......................................................... 42 Appendix D2 - Two-Way ANOVA Applied to City Comparisons .............................. 43 Appendix D3 - ANOVA Applied to Monthly Data ...................................................... 44 Appendix D4 - ANOVA Applied to Day of Week Data .............................................. 45 Appendix D5 - Two-Way ANOVA Applied to 2007 Comparison with 1990 to 2006 46 Appendix E - G-Test Statistics ..................................................................................... 47 Appendix F - Yearly PM Comparisons to Objective .................................................... 48 Appendix G1 PM Air Quality Sampling in Castlegar .................................................. 50 Appendix G2 Air Quality Sampling and Parameters in Kootenay Region .................. 51 Appendix H1 - PM10 Data for 1990 .............................................................................. 54 Appendix H2 - PM10 Data for 1991 .............................................................................. 55 Appendix H3 - PM10 Data for 1992 .............................................................................. 56 Appendix H4 - PM10 Data for 1993 .............................................................................. 57 Appendix H5 - PM10 Data for 1994 .............................................................................. 58 Appendix H6 - PM10 Data for 1995 .............................................................................. 59 Appendix H7 - PM10 Data for 1996 .............................................................................. 60 Appendix H8 - PM10 Data for 1997 .............................................................................. 61 Appendix H9 - PM10 Data for 1998 .............................................................................. 62 Appendix H10 - PM10 Data for 1999 ............................................................................ 63 Appendix H11 - PM10 Data for 2000 ............................................................................ 64 Appendix H12 - PM10 Data for 2001 ............................................................................ 65 Appendix H13 - PM10 Data for 2002 ............................................................................ 66 Appendix H14 - PM10 Data for 2003 ............................................................................ 67 Appendix H15 - PM10 Data for 2004 ............................................................................ 68 Appendix H16 - PM10 Data for 2005 ............................................................................ 69 Appendix H17 - PM10 Data for 2006 ............................................................................ 70 Appendix H18 - PM10 Data for 2007 ............................................................................ 71 vii Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia Figure 1. Relative sizes of particulate matter..............................................................2 Figure 2. Air quality monitoring sites in Kootenay Region........................................9 Figure 3. Partisol sampler in Castlegar .....................................................................10 Figure 4. Map of Castlegar airshed ...........................................................................11 Figure 5. Human-caused sources of inhalable particulate matter (PM10) ................13 Figure 6. Human-caused sources of respirable (fine) particulate matter (PM2.5) .....................................................................................................14 Figure 7. Daily airflow within valleys ......................................................................16 Figure 8. Thermal stratification resulting from temperature inversion.....................17 Figure 9. Annual cycle of mixing heights at Castlegar airshed ................................18 Figure 10. Comparison of particulate matter concentrations between various B.C. communities ............................................................................................21 Figure 11. Particulate matter data compared with previous years ............................22 Figure 12. NAAQO exposure in Castlegar ...............................................................23 Figure 13. NAAQO exposure comparison between Castlegar, Golden, Nelson ......24 Figure 14. Percentages of days in a month with values exceeding NAAQ objective ..................................................................................................25 Figure 15. PM10 in Castlegar airshed by month ........................................................26 Figure 16. PM10 in Castlegar airshed by day of week ...............................................27 Figure A1. Histogram of Castlegar PM10 data distribution.......................................38 Figure A2. Histogram of the natural logarithm of Castlegar PM10 data ...................39 Figure A3. Annual variation of the mean and range of PM10 in Castlegar ...............40 Figure A4. Yearly PM10 values compared to air quality objective ...........................48 Table 1. Comparison of provincial and federal air quality criteria .............................7 Table 2. World Health Organization (WHO) objectives for PM ................................8 Table 3. Summary of annual PM10 in Castlegar from 1990 to 2007 .......................19 Table A1. Results from z- test analysis applied to yearly data .................................49 Table A2 Dates and types of the PM monitoring programs in Castlegar .................50 Table A3 Dates and parameters measured at Kootenay Region air quality monitoring sites.......................................................................................51 viii Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Figures and Tables Ambient Air Quality Monitoring Report Castlegar, British Columbia 1.0 Introduction Many pollutants are known to have detrimental effects on human and environmental health. The common ones monitored in B.C. are: nitrogen dioxide, sulphur dioxide, total reduced sulphur, carbon monoxide, ozone, formaldehyde, and PM. However, in most Kootenay Region communities, including Castlegar, PM is the most serious health concern. As such, this was our primary monitoring focus and this report will deal only with the assessment of PM. “Particulate matter” may sound like a scientific expression, but it breaks down into simple concepts. Particulates are tiny solid or liquid particles that come in many shapes and sizes, and are from many different sources. The majority of particulates that have a negative effect on human health are 10 micrometres or less in diameter (PM10). A micrometre (µm) is a millionth of a metre, so PM10 is roughly the same size as bacteria. Like bacteria, PM10 is invisible to the naked eye and small enough to be inhaled into our lungs. Figure 1 demonstrates that PM comes in a wide range of sizes and differs in chemical composition and source. Collectively, PM10 includes the coarse fraction (PM10-2.5), the fine fraction (PM2.5-0.1), and the ultra-fine fraction (PM<0.1). Fine particulate matter is small enough to enter our airways and lungs as we breathe. The fine fraction (PM2.5) comprises of particles smaller than 2.5 µm that generally are formed by chemical reactions. PM2.5 often is generated directly through combustion or burning; however, PM2.5 also may be created indirectly from reactions in the atmosphere (secondary PM). Common sources of PM2.5 include smoke from burning of yard waste, 2 A geographic area that, because of topography, meteorology, and/or climate, is frequently affected by the same air mass. 1 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY There is mounting evidence that airborne particulate matter or PM, poses a significant health concern prompting the Ministry of Environment (MoE) to institute a network of monitoring for PM. The data resulting from the monitoring has been compiled and analysed by the MoE for this report to inform the public, local government, and industry about PM levels in the Castlegar airshed 2 . This document will also discuss trends in air quality data and factors that have possibly influenced the levels of PM measured in the community. By providing this information it is hoped that local air quality conditions can be better understood and decisions regarding air quality management will be well informed. Ambient Air Quality Monitoring Report Castlegar, British Columbia slash burning, residential woodstoves, exhaust from automobiles, and industrial smoke stacks. In addition to sources associated with human activities, PM2.5 is also generated through natural processes such as forest fires. Figure 1: Relative sizes of particulate matter. The coarse fraction consists of particles between 2.5 µm and 10 µm in diameter. Particles of this size often assume the form of fugitive dust, which consists of finely ground rock and clay, and come from both human and natural sources. The most common source of fugitive dust caused by human activity is unpaved roads, or paved roads that have had sand and salt applied for winter travelling. In spring, when the roads are no longer frozen or wet, traffic grinds up the gravel into finer and finer particles. These are then either thrown into the air by passing traffic, or picked up by strong winds. Other sources of coarse fraction PM include industrial emissions (e.g., fly-ash) and sea salt. Depending on meteorological conditions, it is possible for the particles to stay suspended for hours or days, resulting in poor air quality. Natural sources of fugitive dust are river, lake, and reservoir banks and dust storms, problems that affect communities like Castlegar when water levels are low. 2 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Secondary PM is formed through atmospheric reactions involving oxides of nitrogen, sulphur dioxide, volatile organic compounds, and/or ammonia from natural (e.g., tree metabolism, wildfires) or human-caused emissions (e.g., industrial processes, vehicles). High concentrations of secondary PM can produce an effect known as blue haze. Blue hazes impair visibility of scenic landscape and can be economically detrimental to communities with high tourism such as Castlegar. Secondary PM of the fine fraction may remain suspended in the atmosphere for extended periods of time (depending on meteorological conditions) resulting in prolonged periods of poor air quality. Ambient Air Quality Monitoring Report Castlegar, British Columbia 1.1 Particulate Matter and Health Effects Two types of PM exist that produce adverse health effects in people: inhalable PM and respirable PM. Inhalable particulate matter, also known as PM10, is composed of particles small enough to be carried into our airways. However, some of these particles are large enough to get trapped in the larger airways and do not reach the smallest cavities within our lungs. Respirable particulate matter consists of the fine and ultrafine fractions of PM (also termed as PM2.5) and is composed of particles small enough to travel into the deepest parts of our lungs. PM can cause a range of health effects in people, from annoying symptoms such as a runny nose to increased premature mortality in extreme cases. Recent studies have associated PM with longer-term health effects such as lung cancer. Based on evidence from epidemiological studies, the effects of exposure to PM10 and PM2.5 concentrations are reflected in: ¾ Increases in mortality due to cardiorespiratory diseases. ¾ Increases in hospitalization due to cardiorespiratory diseases. ¾ Decreases in lung function in children and asthmatic adults. ¾ Increases in respiratory stresses that can lead to absenteeism from work or school and a restriction in activities. ¾ Chronic effects including increased development of chronic bronchitis and asthma in some adults, and reduced survival. Particulate matter can cause a range of effects … from annoying symptoms to premature mortality. Those most susceptible to PM-related health impacts are children, the elderly, asthmatics, and people with pre-existing cardiorespiratory diseases. 3 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY PM is the air pollutant of greatest concern in the Castlegar airshed and throughout the Kootenay Region. There are two main reasons for the concern over this pollutant: 1) these particles are small enough to enter our airways and lungs as we breathe, and 2) the emission sources typically found in interior B.C. tend to produce significant amounts of PM. Ambient Air Quality Monitoring Report Castlegar, British Columbia ENVIRONMENTAL QUALITY Previous medical studies have determined that no apparent safe lower threshold for adverse health effects exists for PM 3 . Such a finding has prompted governments to review and strengthen air quality criteria for PM in order to reduce the risks to Canadians 4 . 3 http://www.healthservices.gov.bc.ca/pho/pdf/phoannual2003.pdf WGAQOG (1999) National Ambient Air Quality Objectives for Particulate Matter. Part 1: Science Assessment Document. A report by the CEPA/FPAC Working Group on Air Quality Objectives and Guidelines. Minister, Public Works and Government Services. 4 4 Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia 2.0 Air Quality Objectives/Standards To evaluate air quality, objectives and standards have been introduced that provide what are considered to be acceptable levels of PM10 and PM2.5 in British Columbia. 2.1 Provincial Objectives More recent health evidence suggests that PM2.5 poses a greater health risk than do the coarser fractions. In response to this concern, the MoE has established (in the spring of 2008) an air quality objective for PM2.5 of 25 µg/m3 (24-hour average) 6 . 2.1.1 Air Quality Index The air quality index (AQI 7 ) is the most familiar indicator of air quality to British Columbians, providing the public with a meaningful measure of outdoor air quality via daily reports available on the Internet. It is determined by comparing air quality measures for contaminants such as ozone, carbon monoxide, and PM to levels established by the federal or provincial governments. In provincial AQI calculations, PM10 levels are compared to reference levels of 25, 50, and 100 µg/m3 (comparable to provincial reference Levels A, B and C, respectively). The data analysis of this report uses the reference levels of the AQI system to count the number of days in a year that each level is exceeded and reports the percentage of days that each level is exceeded. Along with these guidelines, British Columbia also references other national standards described below. 2.2 National Ambient Air Quality Objectives (NAAQOs) 8 5 For more information about NAAQO, see: http://www.hc-sc.gc.ca/ewh-semt/alt_formats/hecssesc/pdf/pubs/air/naaqo-onqaa/particulate_matter_matieres_particulaires/summary-sommaire/98ehd220.pdf 6 Air quality objectives established by MoE in the spring of 2008 are currently in the review phase among provincial stakeholders and are subject to change. 7 A numerical index of particulate matter, ozone and other common air pollutants. From the AQI, we can effectively rate air quality as “Good”, “Fair”, “Poor”, or “Very Poor”. For guidance on how to calculate the AQI, see http://a100.gov.bc.ca/pub/aqiis/air.info. 8 National Ambient Air Quality Objectives: http://www.hc-sc.gc.ca/ewh-semt/pubs/air/naaqo-onqaa/indexeng.php 5 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Recognizing the threat that PM10 poses to human health, the MoE established an air quality objective for PM10 of 50 µg/m3 (24-hour average) in 1995. This level is comparable to the maximum acceptable level in the National Ambient Air Quality Objective (NAAQOs) system 5 or a provincial Level B objective. Ambient Air Quality Monitoring Report Castlegar, British Columbia The NAAQOs identify benchmark levels of protection for people and the environment. NAAQOs guide federal, provincial, territorial and regional governments in making riskmanagement decisions, playing an important role in air quality management. Permitting of local emission sources, air quality index calculations, and the development of provincial objectives all make use of the NAAQOs. The NAAQO system defines three objectives: a maximum desirable level, a maximum acceptable level, and a maximum tolerable level. With the exception of the maximum tolerable objective, the NAAQOs are viewed as effects-based, long term air quality goals determined by statistical analysis of reported epidemiological effects. Although negative health effects can occur at any level of PM, the CEPA/FPAC 9 Working Group on Air Quality Objectives and Guidelines recommended reference levels of 25 µg/m3 (24 hour average) for PM10 and 15 µg/m3 (24 hour average) for PM2.5. These levels were intended to represent estimates above which there are demonstrated (i.e., statistically significant) effects on human health and the environment. They were not intended to be used as enforceable air quality objectives, but as the basis for establishing goals for long-term air quality management. 10 2.2.2 Exposure Estimates Risk to human health is believed to increase linearly with PM concentrations. Hence, a simple estimate of exposure, and therefore risk, can be estimated by summing the concentration above a threshold or reference level over a specific period of time. The method used in this report to calculate exposure is explained in Appendix B. 2.3 Canada-wide Standards (CWS) Agreement Under the Canada-wide Accord on Environmental Harmonization, the Canadian Environment Ministers (with the exception of Quebec) ratified the Canada-wide Standards (CWS) for PM and ozone in July 2000 11 . The CWS process is expected to provide new tools for the management of environmental issues of national interest. The standards for particulates are based on daily average PM2.5 measurements over three consecutive calendar years. The 98th percentile is often used in analyses and comparisons because it reduces the bias caused by a single extremely high reading. For 9 Canadian Environmental Protection Act Federal-Provincial Advisory Committee CEPA/FPAC Working Group on Air Quality Objectives and Guidelines (1999) National Ambient Air Quality Objectives for Particulate Matter. Part 1: Science Assessment Document. Minister, Public Works and Government Services. 11 Canada-wide Standards Agreement: http://www.ccme.ca/ourwork/air.html?category_id=99 10 6 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY 2.2.1 Reference Levels Ambient Air Quality Monitoring Report Castlegar, British Columbia each year, the 98th percentile of the daily averages is determined and then averaged for the last three calendar years. This value, referred to in this report as the CWS Indicator, can then be compared to the standard and to other communities. The adopted standard for PM2.5 is 30 µg/m3. Although there was no standard or objective set by the CWS for PM10, the previously described “CWS Indicator” is used to analyze historical trends in ambient air quality in this report. 12 Three reference levels (A, B, and C) have been defined in B.C. for PM10 based on the NAAQO system of the federal government (see Table 1). Achieving Level A concentrations (less than 25 μg/m3) creates an atmosphere of good air quality where humans and environment can flourish. Subscribing to Level B concentrations (25 to 50 μg/m3) will provide sufficient protection for the health of the majority of individuals but may allow discomfort to occur in sensitive individuals. At Level C concentrations (50 to 100 μg/m3), risks to human health become more severe, and concentrations of PM must be reduced to adequately protect human health. Table 1. Comparison of provincial and federal air quality criteria. The AQI rating (in the above table) converts the concentrations of PM10 pollutants to a common-language, unit-less scale to indicate health implications. To clarify, threshold levels of PM10 are identified by describing what the quality of ambient air in a day would be if said threshold is surpassed. For example, if the average PM10 concentration throughout a day is below 25 μg/m3, the day is described to have “good” air quality (in terms of PM10). However, if the day experienced a higher average PM10 above 50 μg/m3, 12 The B.C provincial government has an objective for PM10, and the federal government has a standard for PM2.5. but there is no common objective or standard for both pollutants. 7 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY 2.4 Comparison of Federal and Provincial Air Quality Criteria Ambient Air Quality Monitoring Report Castlegar, British Columbia PM10 would have exceeded both the “good” and “fair” thresholds, and the day is considered to be of “poor” air quality. 2.5 World Health Organization (WHO) Objectives WHO has defined long term objectives for both coarse PM and fine PM. To minimize health issues related to PM, WHO recommends maintaining average yearly fine PM levels at concentrations below 10 μg/m3. Similarly, WHO recommends yearly averages of coarse PM should not exceed 20 μg/m3. The coarse and fine PM objectives defined by WHO are used in the current report for statistical analysis to determine whether yearly PM means exceed objectives (see Appendix F). The current report only makes use of the coarse PM objective (20 μg/m3) because the report analyzes long term trends in coarse PM but does not examine trends in fine PM. Table 2. World Health Organization (WHO) objectives for PM. 13 For more information on WHO air quality objectives, refer to http://whqlibdoc.who.int/hq/2006/WHO_SDE_PHE_OEH_06.02_eng.pdf 8 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY The PM targets defined by NAAQO are useful in determining whether daily averages of PM are complying with air quality objectives. However, when examining the long term trends in ambient air PM concentrations, air quality data is converted to yearly means (rather than using daily means for trend analysis). NAAQO PM target levels are intended for daily average values and are not applicable to yearly mean values; therefore, yearly means are compared to air quality objectives designed by the World Health Organization (WHO) 13 . Ambient Air Quality Monitoring Report Castlegar, British Columbia 3.0 Air Quality Monitoring in Castlegar To characterize PM levels in B.C., MoE has been monitoring PM levels throughout the province for a number of years. Figure 2 displays the locations where air quality monitoring is done in the Kootenays, and the types of pollutants sampled. While the earliest monitoring dates back to the early 1970’s, the large-scale monitoring effort began in 1989. Figure 2. Air quality monitoring sites in Kootenay Region. The locations identified depict all operating air quality in the Kootenay Region stations on January 1, 2006. 9 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY PM levels are measured to determine the exposure concentrations of people in B.C. communities. Monitoring enables regulators and policymakers to identify the air quality impacts of current sources and determine the impacts of new sources or emission control measures. Monitoring over long periods of time allow communities to assess trends that will show if air quality is getting better or worse. In addition, long term monitoring allows comparison with standards and objectives to assess how Castlegar’s air quality is doing in relation to health standards. Comparisons can also be done between the air quality in Castlegar and in other B.C. communities where air quality is monitored. Ambient Air Quality Monitoring Report Castlegar, British Columbia The air quality monitoring station is located on the roof the Fire Hall within Castlegar (see Figure 2). Coarse particulate matter has been monitored from this rooftop location and a nearby senior centre since 1990. The data available for analysis in the current report was collected during the interval of 1990 to 2007, so this report discusses PM10 trends occurring in Castlegar over an 18-year period. A PM2.5 (fine fraction) monitoring program has not yet been implemented in Castlegar. Figure 3. Partisol sampler in Castlegar. The images show the Partisol manual sampler located on the Fire Hall of Castlegar. 10 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Air quality in the Castlegar airshed is monitored using a manual, non-continuous air sampler (Figure 3). Manual samplers draw air at a predetermined flow rate through a filter of known mass. Air is drawn through the filter over a duration specified by the operator of the sampler (duration is usually 24 hours). After air passes through a filter, the filter is removed from the sampler and analyzed in a laboratory setting. Ambient PM concentrations are calculated by dividing the gain in filter mass (after air has passed through the filter) by the product of sampling period and sampling flow rate. Different fractions of particulate matter (i.e., coarse and fine) can be localized on filters through the use of varying sizes of sampling head inlets. Chemical composition of particulate matter may be determined through additional analyses of the filters; however, such analyses are not performed on a routine basis. Ambient Air Quality Monitoring Report Castlegar, British Columbia 4.0 Airshed Description ENVIRONMENTAL QUALITY Generally speaking, an airshed is a body of air affected by any source of air pollutant or emission within (or associated with) the air mass. For example, a Castlegar resident burning their yard waste will exert an effect (i.e., increase PM concentrations) within the Castlegar airshed but likely will not affect air quality in Nelson or Grand Forks. For the purposes of airshed management, the Castlegar airshed extends approximately 15 km either side of the Kootenay and Columbia Rivers and 30 km along each valley axis. The airshed also includes a valley area directly north of Castlegar extending approximately 20 km (see Figure 4). The Castlegar airshed is bound roughly by the mountainous terrain that defines the valley region. Figure 4. Map of Castlegar airshed. The Castlegar airshed is bounded roughly by the mountainous terrain surrounding Castlegar. 11 Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia 4.1 Influences on Air Quality: Emissions 4.1.1 Provincial Overview Though provincial summaries may not reflect relative source contributions in individual communities such as Castlegar, they are useful as benchmarks for comparison. For both PM10 and PM2.5, the contributions from area sources 16 (e.g., fireplaces, wood stoves and backyard burning), mobile sources (e.g., diesel trucks), and road dust are important to local air quality. Area sources are numerous and/or widespread and are located in close proximity to where we live. Point sources 17 of PM in the region include industrial operations, such as wood and pulp mills. As summarized in Figures 5 and 6, these are the key points from the 2000 Emissions Inventory with regard to PM in the B.C. Interior: PM10 ¾ Point sources contribute 45% of PM10 emissions, with 23% coming from the wood industry and 11% coming from the pulp and paper industry. ¾ Area sources are collectively responsible for 46% of PM10 emissions; 25% are from prescribed burning, 11% are from agricultural practices and 9% are from residential fuel wood combustion. PM2.5 ¾ Area sources account for almost half (49%) of PM2.5 emissions, with significant contributions from prescribed burning (33%) and residential fuel wood combustion (13%). ¾ Point sources contribute 40% of PM2.5 emissions, with 20% from the wood industry and 12% the from the pulp and paper industry. 14 MWLAP (2004) 2000 Emissions Inventory Analysis Report. Note that the estimates contained in this report include neither natural sources such as wildfires and biogenic emissions, nor fugitive road dust. 15 Primary pollutants are the chemicals that are emitted directly into the atmosphere. Secondary pollutants are the result of primary pollutants reacting chemically or physically to form different compounds. 16 An emission source of pollutants that covers a large, and sometimes poorly defined, area. 17 An emission source of pollutants that remains in a small identifiable area. 12 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY The sources of PM vary from community to community and from season to season. Based on the year 2000 provincial emissions inventory 14 , an estimated 850 thousand tonnes of PM were released into the atmosphere as primary pollutants 15 . Note that this estimate is only for emissions that result from human activities (i.e., anthropogenic emissions). Ambient Air Quality Monitoring Report Castlegar, British Columbia Figure 5. Human-caused sources of inhalable particulate matter (PM10) The figure displays information for areas outside the Lower Mainland, and exclude natural sources, such as wildfires or biogenic emissions, and fugitive road dust. Source: 2000 Emissions Inventory Analysis Report, MWLAP. 2004. 18 Particles that are not directly emitted into the atmosphere, but are produced by chemical and physical processes. See Appendix A: Secondary Pollutant. 18 Lowenthal D.H., D. Wittorff, and A.W. Gertler (1994) CMB Source Apportionment During REVEAL Final Report. Air Resources Branch, British Columbia Ministry of Environment, Lands and Parks. 20 Pryor S.C. and D. Steyn (1994) Visibility and ambient aerosols in south-western British Columbia during REVEAL. British Columbia Ministry of Environment, Lands and Parks. 21 ARB (1994) 1990 British Columbia Emissions Inventory of Common Air Contaminants, Air Resources Branch, British Columbia Ministry of Environment, Lands and Parks, Victoria, B.C., December. 22 “Biogenic” sources are a subset of natural sources and include only those sources that result from biological activity. Biogenic emissions represent a significant portion of the natural source emissions. VOC, NOx, and the greenhouse gases can all be emitted from biogenic sources. 13 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Secondary particles 18 were not considered in the emissions inventory estimates, although studies limited to the Lower Fraser Valley indicate that they may comprise up to 50% of the fine PM collected during the summer. Sulphur dioxide (SO2), nitrogen oxides (NOx), various hydrocarbons, and ammonia (NH3) are important gases involved in the formation of secondary particles 19,20 . Major sources of SO2 include the cement, pulp and paper, and petroleum industries, as well as motor vehicles 21 . Approximately 75% of NOx emissions in the Lower Mainland are from motor vehicles and marine vessels. Motor vehicles, solvent usage and vegetation 22 contribute to over 70% of hydrocarbon emissions. Agricultural use of fertilizers is the dominant source of NH3. Figure 6. Human-caused sources of respirable (fine) particulate matter (PM2.5) The figure displays information for areas outside the Lower Mainland, and exclude natural sources, such as wildfires or biogenic emissions, and fugitive road dust. Source: 2000 Emissions Inventory Analysis Report, MWLAP. 2004. Figures 5 and 6 depict general models for relative contributions of PM emission sources in B.C. airsheds (outside the Lower Mainland); however, every airshed has a unique mix of emissions and sources specific to their air quality. In particular, albeit a rigorous emission inventory has not been generated for the Castlegar airshed, contributions from airshed sources clearly appear to deviate from the models exhibited in Figures 5 and 6. For example, road dust and lake bed fugitive dust are major contributors to coarse PM in Castlegar airshed; however, such sources are not heavily represented in Figure 5. Although Figures 5 and 6 are general models and are not entirely accurate representations of relative sources of PM in Castlegar airshed, certain contributors to PM in Castlegar airshed are consistent with the model. For example, prescribed burning is a significant contributor to PM in the Castlegar airshed, and such an activity is estimated to comprise 25% of PM10 emissions and 32% of PM2.5 emissions in B.C. airsheds (outside of Lower Mainland) according to the models in Figures 5 and 6 respectively. In addition, residential woodstove combustion and pulp mills are included in the PM emissions 14 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia models (Figures 5 and 6), and coincidentally, woodstoves and Celgar pulp and paper mill as well as the Interfor (previously Pope and Talbot) sawmill are significant sources of PM within Castlegar’s airshed. 4.2 Influences on Air Quality: Weather and Terrain Aside from both human-caused and naturally occurring emission sources, there are other factors that play an important role in ambient air conditions. Of primary importance are the influences of complex terrain (i.e., deep valleys) and weather conditions. Winds in the airshed generally are aligned with the valley orientation (north-northeast to southsouthwest), which may be the result of either valley channelling or diurnal valley flows (Figure 7). In either case, the City of Castlegar is more susceptible to PM emissions from these directions. Wind speed and direction are important drivers of ambient air pollutant levels. Generally speaking, low wind speeds, like those often encountered during stagnant winter time conditions, impede the ability of the atmosphere to disperse pollutants. Of course, wind direction dictates whether pollutants from any one source are being carried towards or away from an air quality sampler. 23 Environmental Management Act http://www.env.gov.bc.ca/epd/main/ema.htm. A Guide to the Open Burning and Smoke Control Regulation http://www.bclaws.ca/EPLibraries/bclaws_new/document/ID/freeside/34_145_93 24 Model burning bylaw http://www.env.gov.bc.ca/epd/bcairquality/reports/model-bylaw-backyardburning.html 15 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY The provincial government has implemented a number of programs to reduce the amount of PM emitted into the atmosphere. Regulations have been passed to reduce smoke from land-clearing fires and wood stoves 23 . A model bylaw 24 has been developed to assist municipal governments in designing regulations restricting burning of yard waste on residential property. In addition, efforts to phase out beehive burners (large domed incinerators used by lumber mills to burn wood waste) are proceeding, initially focusing on the most smoke-sensitive areas of the province. Figure 7. Daily airflow within valleys. Airflow during the daytime tends to be upslope and up-valley. During the night time this tendency reverses and denser, cooler air pools in valley bottoms. Source: The Cooperative Program for Operational Meteorology, Education, and Training (COMET®) Web site at http://meted.ucar.edu/ of the University Corporation for Atmospheric Research (UCAR), funded by the National Weather Service. ©2002, UCAR. All Rights Reserved. The community of Castlegar frequently experiences temperature inversions because Castlegar airshed is surrounded by steep valley walls. Valley landforms often experience a phenomenon known as a temperature inversion. During a temperature inversion, cold air sinks to and remains within a valley floor because colder air is denser than warmer air. Warmer air does not mix with the colder air because of the density differential, and the colder air remains trapped within the valley. Temperature inversions are most prevalent during night (see Figure 7 to see valley flow over a daily period); however, they also can occur during daytime particularly during the winter. The community of Castlegar frequently experiences temperature inversions because Castlegar airshed is surrounded by steep valley walls. 16 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Figure 8. Thermal stratification resulting from temperature inversion. The warm layer of air on top of the cold layer creates an inversion layer that traps emissions close to the ground. Graphic courtesy of Environment Waikato, Government of New Zealand. There are many flood control and hydroelectric dams located near Castlegar on the Kootenay and Columbia rivers. The large waterbodies (reservoirs) resulting from such dams, exert thermal effects 25 on the Castlegar airshed by contributing to cloud masses which inhibit the “break-up” of the inversions. The resulting effect is a prolonged period of inversion resulting in poor air quality and increased incidences of adverse health in residents (especially people with respiratory problems, children, and the elderly) within the airshed. Because terrain has such a significant impact on the composition of a body of air, an airshed often is defined by geographical features. The Castlegar airshed in particular, is shaped and influenced by the Selkirk Mountain Range and the valley regions surrounding the confluence of the Kootenay and Columbia rivers. The described landforms significantly influence the containment and dispersion of air pollutants in Castlegar’s airshed. The distance between the surface and the inversion layer is called the “mixing depth”, and it has a major influence on the dispersion capability of the atmosphere. (The 25 Differences in temperatures and ability to retain heat between land surfaces and water bodies. 17 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia Figure 9. Annual cycle of mixing heights in Castlegar airshed, (elevation 495 m). The graph displays the variability in monthly vertical movement of air (mixing height) occurring in Castlegar. Starting from the base (surface) elevation of 495 m (metres above sea level), the mean mixing height in winter (December and January) is approximately 850 m, (or 355 m above the base) compared to almost 3,200 m (or 2,705 m above base) in summer (July). Source: GEM-Scribe VI model output data from Jan 2002 to June 2007, courtesy of Environment Canada, Pacific Yukon Region. “SE” refers to a statistical term, “standard error”. “SD” refers to a statistical term, “standard deviation”. 18 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY analogous term “mixing height” is used for the height above sea level.) The greater the mixing depth or height, the greater the volume of air in which pollution emitted at the ground can mix, resulting in lower concentrations. The height of this mixing layer is driven primarily by hours of sunlight and is therefore seasonal in nature. Figure 9 demonstrates that the long hours of sunlight in summer cause a much greater mixing height, and the winds are more effective in dispersing pollution. Conversely, in winter, the small amount of sunlight results in very low mixing heights, so pollution does not get dispersed, and PM concentrations can rise. Ambient Air Quality Monitoring Report Castlegar, British Columbia 5.0 Air Quality in Castlegar As mentioned above, the PM aspect of air quality is measured in Castlegar via a Partisol manual sampler. PM10 concentrations have been monitored in Castlegar since 1990. Table 1 summarizes the results of the PM10 monitoring from the beginning of the monitoring program to 2007. The mean and maximum values for each year refer to averages of hourly data over a 24hour period and are measured in micrograms per cubic metre (µg/m3). The percentage of days with fair, poor, and very poor air quality refer to days when particulate matter concentrations exceed NAAQO levels. Days with fair air quality have PM10 levels exceeding Level A (25 µg/m3), poor days exceed Level B (50 µg/m3), and very poor days exceed Level C (100 µg/m3). The Exposure Indicator is the cumulative value of PM10 amounts that exceed the reference health level of 25 µg/m3 throughout a year (see Appendix B for the method of calculation). The CWS Indicator adopts the algorithm for the Canada-Wide Standard for PM2.5 and is calculated by averaging the current year 98th percentile value with the values of two previous years. CWS Indicators are used for community cross comparison. 19 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Table 3. Summary of annual PM10 in Castlegar from 1990 to 2007. Ambient Air Quality Monitoring Report Castlegar, British Columbia The general trend for PM in Castlegar over the last 18 years (1990 to 2007) appears to be an overall decrease in ambient PM levels. Statistical testing 26 applied to yearly means (see Appendix D1) confirms the observed difference between higher PM values in previous years and lower values in more recent years is significant. In particular, distinctive differences between means from the first five years of monitoring (1990 to 1994) and means from the last three years of monitoring (2005 to 2007) are apparent. More specifically, the identified years in the early 1990s appear to have experienced much higher levels of PM than observed in recent years. In fact, the PM means of every year in the early 1990s (1990 to 1994) exceed the WHO objective of 20 μg/m3, and all PM means of the three most recent years of monitoring are below the objective. Data from the most recent three years of monitoring have produced the lowest mean PM values observed in the entire monitoring period (see Table 2). This improvement in air quality may be linked to improvements in emission control technology implemented at the local pulp mill between 1991 and 1994. In comparison to other communities, Castlegar appears to experience the mid-range of PM levels observed throughout B.C. (see Figure 10 for a comparison with selected B.C. communities). According to statistical testing (see Appendix D2), the Castlegar airshed mean PM concentrations were below that of Golden but higher than Burnaby. Castlegar mean PM values displayed no statistical difference from the values of Invermere and Prince George. MoE uses the terms “clean”, “threatened”, and “degraded” to describe the air quality within an airshed. The Radium airshed would be classified as “clean”, and the Golden airshed is considered “degraded”. Castlegar air quality (in terms of PM10) is classified as “threatened”, but Castlegar airshed does not experience PM levels that would be considered “degraded”. Statistical analysis was applied to PM data collected from the communities represented in Figure 10 for the years of 2003 to 2006 27 . Results from statistical analysis indicate that not only do significant differences exist between the mean PM values of Castlegar and certain cities (such as Golden), but a significant differences exist between city and year for PM, as well. To clarify, a difference in PM values appears to occur from year to year depending on the city in which PM was measured. For example, Golden experienced high PM concentrations in 2003 relative to other years in the 2003 to 2006 period because unusually high forest fire activity occurred in the vicinity of the community. In contrast, Burnaby data does not display a discrepancy between 2003 and the remainder of 26 Even though calculated averages from data sets superficially may appear to be different in value, the ranges of the data sets may greatly overlap, and, thus, the PM levels estimated from the data sets would be far too similar to accept that a distinct difference exists regardless of apparent differences in data averages. Consequently, statistical tests are employed to determine the likelihood of whether PM levels estimated from one data set are significantly and distinctly different from levels of another data set. 27 Airshed comparison analysis was conducted solely for the years of 2003 to 2006 because data for all communities is available only for that period. 20 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY 5.1 Results and Trends Ambient Air Quality Monitoring Report Castlegar, British Columbia the 2003 to 2006 period because the Burnaby airshed was relatively unaffected by the forest fires near Golden. 50 Burnaby 40 Golden 35 Invermere 30 Prince George 25 Castlegar 20 15 10 5 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 1993 1992 1991 1990 0 Year Figure 10. Comparison of particulate matter concentrations between various B.C. communities. The above graph displays a comparison of mean annual PM10 concentrations with other communities in British Columbia from 1990 to 2006. Figure 11 illustrates that 2007 was a year of relatively low PM concentrations compared with other years in Castlegar’s full 18-year monitoring period (1990 to 2007). Results from statistical analysis (see Appendix D5) confirmed that 2007 was a year with particularly low PM concentrations. In fact, the yearly PM mean for 2007 was lower than all other calculated yearly PM means derived from 1990 to 2007 data (see Table 2) 28 . This could be associated with changes in production or improvements at the Pope and Talbot sawmill (now Interfor), and/or the Celgar pulp mill, both of which are industries within the Castlegar airshed. 28 Such an observation is not statistically significant. 2007 has shown statistically significant differences with means from 1990, 1991, 1993, and 1994 only. 21 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY 3 Inhalable Particulate Matter ( μg/m ) 45 Ambient Air Quality Monitoring Report Castlegar, British Columbia Statistical tests were conducted to compare the monthly means in 2007 with the combined monthly means of 1990 to 2006 (see Appendix D5). Although PM values in 2007 appear (with statistical significance) to be low relative to other years of the 18-year monitoring period, the monthly means calculated for both 2007 and 1990 to 2006 data sets appear to fluctuate from month to month. These monthly fluctuations assume the same pattern in 2007 data as in 1990 to 2006 data. More specifically, PM values will fluctuate throughout the year due to changes in environmental conditions that occur with change in season (i.e., primarily changes in solar heating and winds), and PM fluctuation patterns essentially remain the same from year to year. Figure 11 illustrates similarities in seasonal PM changes from year to year. 1990 to 2006 3 2007 25 20 15 10 5 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Month Figure 11. 2007 particulate matter data compared with previous years. The bars representing the 1990 to 2006 series are derived from mean PM values calculated for all data collected between 1990 and 2006. Figure 12 displays NAAQO exposure values derived from Castlegar airshed PM data over the 18-year monitoring period. Exposure values depict the number of days in a year PM concentrations exceed the NAAQ Objective of 25 µg/m3. The degree to which PM concentrations exceed the objective also is incorporated into the exposure concentrations. Similar to yearly PM concentrations, exposure values have decreased in recent years. Data from the most recent three years of monitoring indicates a dramatic decrease in PM exposure has occurred from the early 1990s. Aside from exposure experienced in 1996, 22 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Inhalable Particulate Matter ( μg/m ) 30 PM exposure during the last three years of monitoring were the lowest exposure PM exposure experienced values observed in the 18-year monitoring period. Exposure in 1996 during the last three years can be considered anomalous because the of monitoring are of the value is an unusually greater magnitude lowest exposure values lower than the previous (1995) and succeeding (1997) years by 76% and observed in the 18-year 79% respectively. monitoring period. Although exposure appears to have increased gradually over the last three years, this increase should not be cause for concern since 2007 exposure is significantly less than the exposure mean of all monitored years (1990 to 2007). Thus, 2007 exposure can be considered as relatively low despite the apparent upward trend occurring over the last three years of monitoring. 400 NAAQO Exposure 350 300 250 200 150 100 50 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 1993 1992 1991 1990 0 Year Figure 12. NAAQO exposure in Castlegar. The line graph displays the 98th percentiles of PM10 yearly data sets in micrograms (µg/m3). The bars display NAAQO exposure values depicting excesses of PM10 above the health objective of 25 µg/m3. Refer to Appendix B for a description on the calculation of NAAQO exposure. 23 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia Figure 13 provides context for the exposure level displayed in Figure 12, by comparing PM exposure levels in Castlegar airshed to exposure levels in Golden 29 and Nelson airsheds. Golden and Nelson are communities also within the Kootenay Mountain Region having similar populations to Castlegar. However, despite geographical proximity and similarity in population size, Figure 13 illustrates that Castlegar residents experience far less exposure to PM10 pollution than Golden. In contrast, Nelson and Castlegar appear to have relatively similar exposure levels and the community with higher PM concentrations appears to have alternated several times over the period indicated in Figure 13 (1992 to 2006). 800 Castlegar 700 Golden NAAQO Exposure 500 400 300 200 100 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 1993 1992 0 Year Figure 13. NAAQO exposure comparison between Castlegar, Golden, and Nelson. Figure 14 displays the percentages of days within a month that experience PM concentrations exceeding the NAAQ Objective of 25 μg/m3. Statistically significant differences exist from month to month between calculated proportions of days in a month that exceed the objective. The highest proportions of days are observed in the months of February, March, and August. February and March, in particular, experience remarkably high levels of PM and are the only months which PM values exceed 100 μg/m3 (referred to in Figure 14 as “Very Poor Days”). A possible explanation for the high frequency of days exceeding air quality objectives in February and March is an increase in the production of fugitive dust 29 As mentioned earlier, Golden airshed is classified as “degraded”. 24 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Nelson 600 Ambient Air Quality Monitoring Report Castlegar, British Columbia associated with spring in Castlegar. Castlegar begins to warm in February/March when snow and ice that covers road surfaces begins to melt. The winter traction material on roads which is trapped in snow and ice, thaws in early spring releasing sand and gravel. Vehicular action grinds this material into finer particles and stirs it up, increasing the amount of fugitive dust in the atmosphere. The resulting fugitive dust dramatically increases the PM10 concentrations within ambient air; therefore, Castlegar experiences a high number of fair, poor, and very poor days during February and March (see Figure 14). 50% Fair Days Precentage of Days in Month 45% Poor Days 40% Very Poor Days 35% 30% 25% 20% 15% 10% 5% 0% Jan Feb Mar Apr May Jun Jul Month Aug Sep Oct Nov Dec Figure 14. Percentages of days in a month with values exceeding NAAQ objective. The above graph displays the percentage of days that exceed NAAQO levels in Castlegar during the period of 1990 to 2007 (n=262). The percentage of very poor (100 µg/m3), poor (50 µg/m3), and fair days (25 µg/m3) measured in each month are shown by the bars. Figure 16 displays the monthly PM data averaged over the 18-year monitoring period. After conducting statistical tests (see Appendix D3), significant differences between monthly data only appear to be associated with February, March, and August. In 25 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY August also experiences a high proportion of days exceeding air quality objectives. The probable explanation for increased PM in August is forest fires. Much of the wildfire activity in the Kootenays occurs during August; therefore, an elevated amount of PM is emitted into the atmosphere during the month. Ambient Air Quality Monitoring Report Castlegar, British Columbia particular, February and March are significantly greater than every month of the year 30 (except August and November 31 ). In addition, August values are greater (according to statistical testing) than June, September, and December; however, no significant difference is apparent between the high PM values observed in February and March 32 . Results from analyzing monthly data are coincident with the percentages of days exceeding air quality objectives levels (see Figure 14): February and March exhibiting the highest proportions of fair/poor/very poor air quality days and August exhibiting high (but not highest) proportions of fair/poor days. 25 20 15 10 5 0 Jan Feb Mar Apr May Jun Jul Month Aug Sep Oct Nov Dec Figure 15. PM10 in Castlegar airshed by month. The bars represent monthly means of daily PM10 concentrations collected during the period of 1990 to 2007. Statistical tests were applied to PM data categorized by day of week and averaged over the 18-year monitoring period (see Appendix D4), and a distinctive difference in PM levels appears to occur between Friday and Sunday. The difference between the days is much higher concentrations of PM appear to occur on Fridays than Sundays (see Figure 16). The explanation for such a discrepancy could relate to a combination of commuter and tourist traffic. Because Friday is a weekday (i.e., a common workday), heavy 30 However, February PM levels do not appear to be different from July’s but March PM levels are statistically greater than those of July. 31 November appears to be mid to high range in PM values. November PM ranges overlap with every month (even the high PM months of March and February) except June. However, the statistical evidence suggest November PM levels is different (higher) than June’s is weak. 32 Such an observation suggests that August may not be the highest month for PM; however, August PM levels are high enough that their ranges significantly overlap with ranges observed in February and March. 26 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Inhalable Particulate Matter ( μ g/m3) 30 Ambient Air Quality Monitoring Report Castlegar, British Columbia Another noted difference in daily PM levels appears to occur between PM values of Fridays and those of Monday. The difference is possibly a result of incorporating PM values collected on public holidays (i.e., long weekends) into the Monday mean. Low commuter traffic occurs on public holidays; therefore, a PM mean which represents the entirety of Mondays within a year would be expected to be slightly less than the mean of other weekdays 33 . A less significant difference in PM levels is observed to occur between Thursdays and Sundays in the manner that Thursday PM levels appear to be slight higher than Sunday levels. The difference is likely a result of incorporating PM values collected on weekends where tourists may have taken a vacation day on Friday to extend a weekend trip. In such cases, Thursday could be a travelling day and therefore be associated with both commuter and tourist traffic. Consequently, PM values appear be slightly elevated on Thursdays. However, since Friday is typically a standard work day, the difference between Thursday PM and the weekend is supported only weakly by statistical evidence. 33 Statistical differences associated with Monday data only are observed as a difference between Monday and Friday PM values. 27 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY commuter traffic commonly is associated with the day. However, in addition to commuters, traffic resulting from tourism increases on Fridays because many people travel to their tourist destination on Fridays to arrive by the weekend. In contrast, Sundays may have high tourist traffic (because people are returning from their tourist destination); however, the day is associated very little commuter traffic. Furthermore, many businesses are closed on Sundays; therefore, vehicular traffic is further diminished because Castlegar residents generally perform weekend errands and shopping on Saturdays. In summary, Friday PM values are generally high due to a combination of heavy commuter and tourist traffic, and Sunday PM values are often low because of low commuter traffic and decreased amount of open businesses in Castlegar. 25 20 15 10 5 0 Monday Tuesday Wednesday Thursday Friday Saturday Sunday Day of Week Figure 16. PM10 in Castlegar airshed by day of week. The bars represent PM10 concentration data collected over the duration of 1990 to 2007 and averaged for each day of the week. 28 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Inhalable Particulate Matter ( μ g/m3 ) Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia 6.0 Conclusions and Recommendations In summary: ¾ Air quality has undergone dramatic improvement since the early 1990s. This is partially due to improvements between 1991 and 1994, in emission control technology at the pulp mill located within the Castlegar airshed. ¾ Every year, several days exist when PM levels exceed national guidelines for acceptable air quality, putting the air quality in Castlegar in the “threatened” category. Such days are of concern to public health officials. ¾ Days with PM concentrations that exceed standards often are observed in February, March, and August. The high levels of PM in the aforementioned months result from a combination of natural and human causes. ¾ The steep valley walls surrounding Castlegar increases the airshed’s susceptibility to temperature inversions (especially during winter) trapping PM near ground level. Inversions during periods of higher emissions from sources such as road dust and wood burning appliances may result in increased incidences of adverse health effects to residents within Castlegar airshed. ¾ Differentiating between sources and types of PM within Castlegar airshed is difficult because only discrete PM10 data is available. A more comprehensive PM monitoring program incorporating continuous PM2.5 and PM10 measurements, is needed to inform airshed management decisions. ¾ Based on data from the full 18-year monitoring period, Castlegar airshed appears to fall within the mid-range in terms of ambient air concentrations of PM within various airsheds throughout B.C. However, PM levels have been particularly low during the most recent three years of monitoring, and continued air quality monitoring will provide insight on whether Castlegar is becoming a community with “cleaner” air than most others in B.C ¾ Since there is a high potential for inversions in Castlegar, the community should be concerned about ambient PM levels. Even low or moderate levels of PM emissions can be magnified by the effects of inversions, resulting in negative health effects. Furthermore, the community should be attempting to reduce levels 29 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY ¾ In particular, 2007 may have experienced the lowest mean PM concentration observed in 18 years. Ambient Air Quality Monitoring Report Castlegar, British Columbia of PM since there is no minimum health impact level or ‘safe’ level of PM10 or PM2.5 34 . The following are some recommendations to improve current air quality in Castlegar: ¾ Residents who wish to use wood as fuel source should be encouraged to buy more efficient wood heat appliances (woodstoves). ¾ Local municipalities should continue to identify different/additional techniques that could result in more efficient winter road maintenance and reduction of road dust. Examples of such measures are more frequent street cleaning, coarser sand for roadways, and possibly the use of magnesium chloride to keep roadways clear of ice. A recent collaboration between MoE and the Ministry of Transportation and Highways has resulted in the development of a ‘best management practises’ document. This can be found at: http://www.env.gov.bc.ca/epd/bcairquality/reports/topic_Dust.html ¾ Local municipalities are encouraged to engage in air quality management planning. A tool to assess the need for planning and the options to consider has been developed and can be accessed at: http://www.cleanairbc.com/ Additional information on air quality management planning can be found at: airshedplan_provframework.pdf ¾ Bylaw enactment and enforcement is another tool often used to improve local air quality. The following sites offer examples to help guide local levels of government in bylaw development: Backyard burning bylaw template: http://www.env.gov.bc.ca/air/particulates/pdfs/bylaw.pdf 34 http://www.healthservices.gov.bc.ca/pho/pdf/phoannual2003.pdf 30 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY ¾ Residents should be educated in techniques of efficient woodstove operation, selection of fuel, and proper storage and curing of wood. Ambient Air Quality Monitoring Report Castlegar, British Columbia For More Information The Environmental Quality Branch of the Ministry of Environment has several reports on air quality at http://www.bcairquality.ca/reports/topic_Monitoring.html A report on Air Quality in the Kootenays 1993-1999 is available at http://www.env.gov.bc.ca/epd/regions/kootenay/aq_reports/pdf/kootenay_air_quality_rep ort.pdf B.C. provincial legislation related to air quality is described at http://www.env.gov.bc.ca/epd/bcairquality/regulatory/air-regulations.html The 2003 Provincial Health Officer annual report about air quality in British Columbia can be found at http://www.env.gov.bc.ca/epd/bcairquality/reports/phoannual2003.html Ministry of Environment Contact: Paul Willis 205 Industrial Rd. G, Cranbrook, B.C. V1C 6H3 Phone: (250) 489-8540 Fax: (250) 489-8506 Email: [email protected] Public feedback is welcomed 31 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY The Environmental Protection Division of the Ministry of Environment in the Kootenay Region has information at http://www.env.gov.bc.ca/epd/regions/kootenay/index.htm Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendices 98th percentile In a sequential list of data values, the 98th percentile is the data value that is 98 percent of the way through the list from the smallest reading (or 2 percent below the highest reading). The absolute maximum reading is not used for analysis because an unusually high reading may be the result of outlier (or suspect) data and can distort the analysis unduly. Aerosol A particle of solid or liquid matter that can remain suspended in the air because of its small size (generally under one micron). Air pollution Degradation of air quality resulting from unwanted chemicals or other materials occurring in the air. Airshed A geographic area that, because of topography, meteorology, and/or climate, is frequently affected by the same air mass. In general, it is that body of air in which management strategies of any individual emission source can have a discernible effect. Air Quality Index (AQI) Reports levels of ozone, particulate matter, and other common air pollutants. Higher AQI ratings for a pollutant indicate higher levels of contaminants in an airshed. For guidance on how to compute the AQI, see http://a100.gov.bc.ca/pub/aqiis/air.info. Anthropogenic Produced by human activities. ARB Air Resources Branch, Ministry of Environment Area source An emission source of pollutants that covers a large, and sometimes poorly defined, area – sometimes call non-point source (e.g., prescribed burning and residential fuel wood combustion). Note: A single residential wood burning appliance is considered a small source of emissions, but many appliances together can emit a significant amount of emissions, and are collectively thought of as an area source, instead of many small point sources. 32 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix A - Glossary and Abbreviations Biogenic Having to do with living organisms as sources. For example, major sources of biogenic emissions in the Kootenay Region are trees. Carbon monoxide (CO) A colourless, odourless, poisonous gas, produced by incomplete burning of carbon-based fuels. Central tendency In statistics, a measure of the middle or center of a set of data. The arithmetic mean is the most commonly used, but median, mode, and geometric mean are also used. CEPA/FPAC The Canadian Environmental Protection Act FederalProvincial Advisory Committee directs the development and assessment of National Ambient Air Quality Objectives (NAAQOs) for airborne pollutants. Coarse fraction Particulate matter with diameter between 2.5 and 10 microns (PM10-2.5). Also referred to as “inhalable particulate matter.” CWS Indicator A measure of the severity of maximum levels of PM2.5 concentration. The 98th percentile of the daily means is determined for each year, then averaged for the last three calendar years (which reduced the influence of a particularly bad year). This value can then be compared to a given standard and to other communities. Though the CWS standard for particulate matter is limited to PM2.5 concentrations, this report adopts this algorithm for PM10 analysis and comparison purposes. Emissions Inventory (EI) A list of air pollutants emitted into a community's atmosphere in amounts (commonly tonnes) per day or year, by type of source. Exposure Indicator A measure of the accumulated exposure to PM10 over a specified time (typically one year), taking into account both the concentration of PM10 and the length of time of exposure. Larger exposures indicate an increased risk to human health. Fine fraction Particulate matter with diameter less than 2.5 microns; PM2.5. Also referred to as “respirable particulate matter”. Fugitive dust PM10 from finely ground rock and clay, origination from human sources such as sand and gravel traction material applied to roads in winter, or from natural sources such as exposed lake beds and river banks. 33 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Haze Atmospheric aerosol of sufficient concentration to be visible. The particles are so small that they cannot be seen individually but are still effective at attenuating light and reducing visual range. Inversion An increase in temperature with height, which is the reverse of the normal cooling with height in the atmosphere. Warm air at ground level tends to rise, but because warmer air is already above it, vertical air movement is minimized, trapping atmospheric pollutants in the lower troposphere, and resulting in higher concentrations of pollutants at ground levels than would usually be experienced. Mean In statistics, an “average” (arithmetic mean) calculated by dividing the total of all values of a set of data by the number of values. (In special circumstances, the geometric mean is used instead) Median In statistics, the value closest to the middle in a ordered list of data values. MoE B.C. Ministry of Environment. (formerly Ministry of Water, Land, and Air Protection - MWLAP). MELP B.C. Ministry of Environment, Lands and Parks. (predecessor to MWLAP). μg/m3 Micrograms per cubic metre (concentration) μm Micrometres (10-6 m) (diameter) Mobile sources Motor vehicles and other moving objects that release pollution; mobile sources include cars, trucks, buses, planes, trains, motorcycles, and gasoline-powered lawn mowers. Mobile sources are divided into two groups: road vehicles, which include cars, trucks, and buses, and non-road vehicles, which includes trains, planes, and lawn mowers. MWLAP B.C. Ministry of Water, Land and Air Protection (formerly Ministry of Environment, Lands and Parks and now the Ministry of Environment). NAPS National Air Pollution Surveillance Network. NAPS was established by Environment Canada to monitor and assess the air quality in Canadian urban regions. 34 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia NAAQO National Ambient Air Quality Objectives. Health-based pollutant concentration objectives, developed by Environment Canada and used as objectives and standards in B.C. NAAQS National Ambient Air Quality Standards. Health-based pollutant concentration limits established by the United States Environmental Protection Agency that apply to outside air. Nitrates (NO3-) The gases and aerosols that have origins in the gas-to-aerosol conversion of nitrogen oxides, e.g., NO2; of primary interest are nitric acid and ammonium nitrate. Nitrogen oxides (NOx) Gases formed mainly from atmospheric nitrogen and oxygen when combustion takes place under conditions of high temperature and high pressure; considered a major air pollutant and precursor of ozone. NOx NO + NO2 + poorly defined fraction of other NOx species (given conventional analyzers). Ozone (O3) A major component of smog. Ozone is not emitted directly into the air but is formed by the reaction of volatile organic compounds (VOCs) and NOx in the presence of heat and sunlight. Particulate matter (PM) A generic term referring to liquid or solid particles suspended in the air. PM2.5 Particulate matter less than 2.5 microns in diameter: the fine fraction of PM, also called respirable particulate matter. Tiny solid or liquid particles, generally soot and aerosols. The size of the particles (2.5 microns or smaller, about 0.0001 inches or less) allows them to easily enter the air sacs deep in the lungs where they may cause adverse health effects. PM2.5 also causes visibility reduction. PM10 Particulate matter less than 10 microns in diameter, including both coarse and fine fractions, also called inhalable particulate matter. Tiny solid or liquid particles of soot, dust, smoke, fumes, and aerosols. The size of the particles (10 microns or smaller, about 0.0004 inches or less) allows them to easily enter the respiratory system where they may be 35 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Ambient Air Quality Monitoring Report Castlegar, British Columbia Ambient Air Quality Monitoring Report Castlegar, British Columbia PM10-2.5/PMcoarse Particulate matter between 2.5 and 10 microns in diameter; the coarse fraction of PM. Particles that are typically generated by mechanical grinding or crushing (e.g. road dust) but can include soot, ash and pollen (biogenic) particles. These particles are less likely to enter the air sacs of the lungs but instead are trapped by the mucous membranes and other lung defenses. Coarse particles are not deemed as dangerous to human health as PM2.5 but are, nevertheless, associated with inflammatory symptoms such as asthma and other respiratory ailments. Point source An emission source of pollutants that remains in a small identifiable area (e.g., an industrial plant) Primary particle The fraction of PM2.5 or PM10 that is directly emitted from combustion and fugitive dust sources. Primary pollutant The emissions discharged from a source that either retain their form or are transformed into secondary pollutants. Secondary particle The fraction of PM10 and PM2.5 that is formed in the atmosphere. Secondary particles are products of the chemical reactions between primary pollutant gases, such as nitrates, sulphur oxides, ammonia, and organic products. SO2 See Sulphur dioxide Sulphur dioxide (SO2) A pungent, colourless gas formed as a byproduct of the combustion of fossil fuels. TEOM Tapered element oscillating microbalance. An instrument for the continuous measurement of PM. Ultrafine fraction Particulate matter with diameter less than 0.1 microns. WHO World Health Organization. The World Health Organization has identified objectives for yearly PM means and recommends means (calculated by averaging daily PM values over a year) should remain below objective levels. The objective for PM10 is 20 μg/m3, and the objective for PM2.5 is 10 μg/m3. 36 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY deposited, resulting in adverse health effects. PM10 also causes visibility reduction and is a criteria air pollutant. Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix B – NAAQO Exposure Calculations Exposure calculations are based on the assumption that there is a concentration (25 μg/m3) below which there is minimal risk to health, and above which there exists a statistically significant greater health response. This reference level can be exceeded either by a short period of exposure to high concentrations, or a longer period of exposure to lower concentrations. Although there are many different ways to calculate exposure, the values cited in this report were calculated based on the NAAQO definition. This method assumes that PM10 has negligible health effects until the daily mean exceeds a reference health level of 25 µg/m3. For days in which this threshold is exceeded, the difference between the daily mean and the reference level is computed, divided by 10, and rounded up to the nearest whole number. After this is done for each day in a particular year, the numbers are summed to provide an overall measure of exposure. An objective level of NAAQO exposure has not been identified; however, exposure values may be used in both interannual and inter-site comparisons. Because the monitoring in Castlegar is done on a non-continuous basis, many days, for many years, did not have a daily mean for PM10. Thus, exposure values were extrapolated from the days for which daily means were available. For example, suppose that for a given year, 58 daily means were available and the NAAQO exposure calculation is applied to this 58 day dataset, with a resultant value of 85. An estimate for the year can then be achieved by assuming that the days sampled are representative of PM levels over the entire year and scaling the level of exposure accordingly. Thus, for our example, since the year had 365 days, we can multiply 85*(365/58) = 534.9 to get an estimate of the NAAQO exposure for this year. 37 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY An exposure calculation is a technique to combine the AMOUNT of a pollutant to which we are exposed, and the TIME that we are exposed to the pollutant. At the two extremes, a low concentration of a pollutant could be in the air for several months, yielding an exposure, but the same exposure would result if there was a high concentration of the pollutant for a few days and clean air for the rest of the time. (One of the assumptions is that these two types of exposures will have similar effects on human health.) Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix C – Central Tendency and Statistical Significance 35 The arithmetic mean is the most commonly used measure of central tendency (see Table 2 and Figure 10). The mean accounts for every value in a population and, thus, is the most effective measure of central tendency in a normally distributed 36 population. However, the mean is not appropriate for highly skewed distributions 37 and is less effective than other measures of central tendency when extreme values are prevalent. Environmental data often is highly skewed and arithmetic means tend to be unduly influenced by extreme events; thus, such measures are not representative “typical” or “central” tendencies. Instead, obtaining geometric mean or log transforming could be viable alternatives for determining central tendency provided values are positive and distribution is positively skewed. Castlegar PM10 data appears to be a typical example of environmental time series data because data distribution is skewed (see Figure A1). Figure A1. Histogram of Castlegar PM10 data distribution 35 Although this report explains the concepts of statistics needed to understand Castlegar’s air quality, other reference material should be consulted to understand all the details of the report. Some statistical results have been included for those conversant with advanced statistical concepts. 36 The normal distribution (the “bell-shaped curve” which is symmetrical about the mean) is a theoretical function commonly used in inferential statistics as an approximation to sampling distributions. Normal distributions are symmetric with scores more concentrated in the middle than in the tails. 37 A distribution is skewed if one of its tails is longer than the other. A positive skew means that it has a long tail in the positive direction (sometimes called “skewed to the right”) and a negative skew has a long tail in the negative direction (sometimes called “skewed to the left”). 38 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY In statistics, central tendency is a measure of the location of the middle or the centre of a distribution of data. The definition of “middle” or “centre” purposely is left somewhat vague to enable the term “central tendency” to refer to a wide variety of measures. Ambient Air Quality Monitoring Report Castlegar, British Columbia A common statistical approach to find the best central tendency measure is to transform the data in some manner so they approximate a normal distribution. In the case of the Castlegar data, the natural logarithm of the original data results in a more normally distributed curve (see Figure A2). 200 180 160 140 100 80 60 40 20 0 0 1 2 3 4 5 6 LN [Particulate Matter (μ g/m3) Figure A2. Histogram of the natural logarithm of Castlegar PM10 data Central tendency is extrapolated from the transformed data. Calculation method consists of obtaining yearly averages from transformed data. Confidence intervals at the 95% level 38 are calculated for estimated means. 39 Figure A3 displays means of log transformed data with the confidence intervals (range in blue vertical lines) for each year. An overall mean for all years is calculated by obtaining the (arithmetic) mean from the yearly means when values are in logarithmic form. The total mean and corresponding confidence intervals are demarcated in Figure A3 with a black horizontal line and dashed horizontal lines, respectively. One should note that means based on log transformed data do not provide specific information on the actual concentrations of PM in Castlegar. Rather, log transformed data serves to expose which years deviate from the norm (overall average). 38 In other words, the mean is considered statistically significant within these upper and lower limits with 95% confidence, or nineteen times out of twenty. Means outside of this range cannot be considered similar and represent statistical departures from typical values. 39 A test for autocorrelation (estimated to be less than .2) suggests that there is little autocorrelation; hence, the ambient levels between years can be considered independent of each other. 39 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Count 120 Ambient Air Quality Monitoring Report Castlegar, British Columbia 3.50 3.00 2.50 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 1993 1992 1991 1990 2.00 Year Figure A3. Annual variation of the mean and range of PM10 in Castlegar. The above figure depicts the statistical significance of yearly levels of PM10. The red circles represent the annual geometric mean of PM10 data, and show that several years were significantly different than the overall mean of all data. Figure A3 is a particularly useful graph for determining which yearly sets of data significantly deviate from the total average data range. In specific reference to Castlegar, deviations are observed with the years 1991, 1993, 1994, 2005, 2006, and 2007. A year’s data is considered to deviate from the overall average when the 95% confidence interval pertaining to the year is outside of the 95% confidence interval constructed for the overall mean. Yearly data from 1991, 1993 and 1994 appear to exceed the concentration range, and data from 2005, 2006, and 2007 fall below the concentration range. Investigation into the possible reasons certain deviate from the average data range is beyond the scope of this report; however, parties involved with airshed management planning may wish to conduct such investigations before executing management plans. 40 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY LN[Particulate Matter (mg/m3)] 4.00 Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D – ANOVA Tests A two-way ANOVA was employed on data organized by two categorical designations. For example, in the air quality comparison between Castlegar and various other B.C. communities, variables were defined by both the city and the year in which data was collected. A two-way ANOVA conducts comparison analyses for both category designations and determines whether the categories interact with one another. Category interaction essentially describes whether a difference between variables would be observed depending on both variables rather than just one. In the city comparison example, interaction effects determine whether yearly variables are different from one another depending on the city in which the data was collected. ANOVA analysis examines overall differences between variables; however, specific differences between variables are not accounted for in the analysis. In order to determine whether specific variables differ from one another (i.e., is March data different from June data?) post hoc analysis is required. For the one-way ANOVA tests, Tukey’s post hoc analysis was employed, and, for two-way ANOVA, hypothesis testing was applied. An assumption made before applying a parametric statistical process such as ANOVA to the data is that the data normally distributed. Such an assumption is violated by the heavy right tail skew associated with the data distribution (see Figure A1); therefore, a natural logarithmic transform is applied to data before conducting ANOVA to ensure data conforms (roughly) to a normal distribution. See Appendix C for clarification. 41 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY ANOVA tests were applied to data in which multiple comparisons were made. For example, comparison analysis involving monthly data require more that one comparison because twelve data sets (one for each month) are included in the analysis. Therefore, the analysis takes the form: January compared with February, January compared with March, March compared with April, etc. ANOVA tests allow for all possible comparison to be made, and the output of the tests provides insight on whether authentic differences between variables (such as months in the described example) exist. Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D1 – ANOVA Applied to Yearly Data Sum-of-Squares 26.465 262.839 df 17 1078 Mean-Square 1.557 0.244 F-ratio 6.385 P 0 Tukey’s Post Hoc ENVIRONMENTAL QUALITY Source Year Error 42 Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D2 – Two-Way ANOVA Applied to City Comparisons Source City Year Interaction Error Sum-of-Squares 37.611 0.656 10.427 550.059 df 4 3 12 1552 Mean-Square 9.403 0.219 0.869 0.354 F-ratio 26.53 0.617 2.452 P 0 0.604 0.004 Castlegar And Burnaby Source Hypothesis Error SS 15.952 550.059 df 1 1552 MS 15.952 0.354 F 45.008 P 0 Castlegar And Golden Source Hypothesis Error SS 1.135 550.059 df 1 1552 MS 1.135 0.354 F 3.202 P 0.074 Castlegar And Invermere Source Hypothesis Error SS 0.014 550.059 df 1 1552 MS 0.014 0.354 F 0.039 P 0.844 Castlegar And Prince George Source Hypothesis Error SS 0.091 550.059 df 1 1552 MS 0.091 0.354 F 0.257 P 0.612 43 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Hypothesis Testing Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D3 – ANOVA Applied to Monthly Data . Source Sum-of-Squares Df Mean-Square F-ratio P Month Error 18.706 270.598 11 1084 1.701 0.25 6.812 0 Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Jan 1 0.01 0 1 1 0.99 1 0.45 1 1 0.77 1 Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 1 1 0.02 0 0 0.22 0.97 0 0.06 0.83 0 1 0 0 0 0.03 0.63 0 0.01 0.34 0 1 1 0.99 1 0.48 1 1 0.79 1 1 1 0.95 0.16 1 1 0.41 1 1 0.59 0.02 1 0.88 0.09 1 1 0.97 0.71 1 1 0.84 1 0.04 0.79 1 0.07 1 0.94 0.15 1 1 0.96 0.98 1 0.23 1 44 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Tukey’s Post Hoc Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D4 – ANOVA Applied to Day of Week Data Source Day of Week Error Sum-of-Squares 4.956 284.348 df 6 1089 Mean-Square 0.826 0.261 F-ratio 3.164 P 0.004 Monday Tuesday Wednesday Thursday Friday Saturday Sunday Monday 1 0.939 0.966 0.599 0.047 0.968 0.95 Tuesday Wednesday Thursday Friday Saturday Sunday 1 1 0.994 0.47 1 0.364 1 0.986 0.392 1 0.44 1 0.874 0.986 0.087 1 0.389 0.001 1 0.447 1 45 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Tukey’s Post Hoc Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix D5 – Two-Way ANOVA Applied to 2007 Comparison with 1990 to 2006. . Sum-of-Squares df Mean-Square F-ratio P Year Group 6.022 1 6.022 24.708 0 Month 6.578 11 0.598 2.454 0.005 Interaction Error 3.194 261.265 11 1072 0.29 0.244 1.191 0.288 ENVIRONMENTAL QUALITY Source 46 Ministry of Environment Kootenay Region Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix E – G-Test Statistics G-tests were used to analyse monthly differences in proportion of days that exceed the NAAQO air quality target of 25 μg/m3. Basically, the test examines whether days that exceed the target are in relatively the same proportions (from month to month) with days that do not exceed the target. Value G df P Minimum Expected 59.3 11 p<0.001 20.1 Month Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec Total Does Not Exceed Objective 23 (22.5) 32 (20.1) 44 (22.7) 17 (21.5) 10 (22.0) 14 (21.5) 17 (22.0) 32 (22.5) 17 (21.5) 15 (22.0) 24 (21.5) 17 (22.2) 262 Exceeds Objective 71 (71.5) 52 (63.9) 51 (72.3) 73 (68.5) 82 (70.0) 76 (68.5) 75 (70.0) 62 (71.5) 73 (68.5) 77 (70.0) 66 (68.5) 76 (70.8) 834 Total 94 84 95 90 92 90 92 94 90 92 90 93 1096 Values in parenthesis are expected values. 47 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Contingency Table Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix F – Yearly PM Comparisons to Objective Figure A4. Yearly PM10 values compared to air quality objective. The above figure displays yearly average values for PM10 concentrations. Error bars represent 95% confidence intervals. The line representing the air quality objective is aligned with the 20 μg/m3 mark upon the y-axis. 48 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY The current report frequently refers to the air quality objective of 20 μg/m3. Figure A4 displays how the yearly means of PM10 compare to the objective. The error bars in Figure A4 depict 95% confidence intervals, and PM10 concentrations are assumed to fall within the range of a year’s interval during 95% of the year. Therefore, if a confidence interval overlaps the objective, 20 μg/m3 may be considered a relatively regular (i.e., within 95% range of PM10 concentrations) concentration for a day within the year to which the interval pertains. Ambient Air Quality Monitoring Report Castlegar, British Columbia Table A1. Results from z-test analysis applied to yearly data. The above table summarizes the results from statistical comparisons between the air quality objective of 20 μg/m3 ambient air concentration of PM10. The “Difference” column indicates whether a yearly PM10 average is lower, higher, or similar (i.e., not different) than the objective level according to statistical output. The “Statistical Evidence” column displays the degree to which statistical output supports a claim that a yearly average is different from the objective. 49 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Z-tests were employed to determine how yearly PM10 means deviate from the objective of 20 μg/m3 (see Table 2). No yearly means appear to exceed the objective with statistical significance. Analysis of the first five years of monitoring (1990 to 1994) indicates the mean yearly PM10 values of the early 1990s were significantly higher than the air quality objective. In the more recent years of 2005, 2006, and 2007 PM levels appear to fall below the air quality objective. Ambient Air Quality Monitoring Report Castlegar, British Columbia Appendix G1 – Particulate Matter Air Quality Sampling in Castlegar Start – End Date Parameter Sampling Type and Frequency MoE Site Identification Mar 1985 – Feb 1987 TSP Discrete Manual, 1-in-6 days Mar 1987 – Sep 1991 TSP Discrete Manual, 1-in-6 days Apr 1990 – Sep 2002 PM10 Discrete Manual, 1-in-6 days Apr 2001 – present PM10 Discrete Manual, 1-in-6 days Centennial Library 0250003 Senior Citizen Centre E206931 Senior Citizen Centre E206931 Fire Hall E243617 50 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Table A2. Dates and types of the PM monitoring programs in Castlegar. PM10 refers to coarse particulate matter. TSP refers to “Total Suspended Particulate”. Ambient Air Quality Monitoring Report Castlegar, British Columbia Some communities have had samplers located in several sites within their boundaries. If there was more than one site, the quantity is listed in parentheses after the community name. The Dates of Operation list the first and last dates of any sampling for each airshed, but are not specific for each parameter. The Parameters Measured lists all parameters that have been measured at each site. Not all parameters have been measured at all times. Golden underwent a Source Apportionment Study, hence had some specialized sampling equipment. Legend Total suspended TSP NO2 Nitrogen dioxide particulates PM10 Particulate matter (up to 10 μm diameter) NO Nitric oxide PM2.5 Particulate matter (up to 2.5 μm diameter) SO2 Sulphur dioxide PM Coarse PM10-2.5 CO Dustfall Dustfall Metals TRS O3 Heavy metals: arsenic, cadmium, zinc Total reduced sulphur Ozone Carbon monoxide An instrument for measuring Aethalometer elemental (black) carbon PM Instruments that measure specific speciation chemicals found in emissions VOC Volatile organic compounds Met Meteorological (weather) data Table A3. Dates and parameters measured at Kootenay Region air quality monitoring sites. Airshed Canal Flats Castlegar (9 sites) Dates of Operation February 1974 – January 1985 March 1985 - present 51 Parameters Measured Dustfall TSP PM10 Dustfall Metals TRS NO2 SO2 CO Met Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix G2 – Air Quality Sampling Sites and Parameters in Kootenay Region Communities Ambient Air Quality Monitoring Report Castlegar, British Columbia Cranbrook Creston Dates of Operation Apr 1985 – Mar 1991 May 1990 – Sep 1993 Apr 1994 – Nov 1998 Mar 2001 – Sep 2006 September 1990 – present Elk Valley (4 sites) April 1978 – present Elkford October 1982 – March 1993 Golden (4 sites) January 1992 – present Grand Forks August 1973 – present Invermere Kimberley July 1993 - present May 1988 – present 52 Parameters Measured TSP PM10 Met PM10 PM2.5 CO NO2 O3 SO2 Met TSP PM10 PM2.5 Dustfall TSP PM10 Dustfall PM10 PM2.5 PM coarse Aethalometer PM speciation VOC NO2 NO CO O3 SO2 Met TSP PM10 PM2.5 Dustfall Met PM10 TSP PM10 SO2 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Airshed Ambient Air Quality Monitoring Report Castlegar, British Columbia Dates of Operation Kokanee Park Nelson July 2001 – August 2002 March 1985 – present Radium Revelstoke July 1998 - 2007 May 1989 – present Skookumchuck August 1987 – July 2005 Slocan April 1985 – May 1986 November 1991 - present Sparwood January 1982 – present Trail (15 sites) February 1970 - present Ymir May, 1984 – February 1988 53 Parameters Measured PM10 TSP PM10 PM2.5 O3 Met PM10 PM10 PM2.5 Dustfall Met TRS Met TSP PM10 Dustfall TSP PM10 PM2.5 Dustfall TSP PM10 PM2.5 Dustfall Metals CO NO NO2 O3 SO2 Met TSP Dustfall Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Airshed Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 5 11 17 23 29 4 10 16 22 28 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 4 10 16 22 28 PM10 (μg/m3) ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 9 ND ND ND ND ND ND ND 34 ND 35 24 July August September October November December 4 10 16 22 28 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 2 35 25 25 29 ND ND ND ND ND 10 24 42 20 46 16 24 19 24 24 ND 40 20 37 ND 22 78 20 4 38 44 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 54 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H1 - PM10 Data for 1990 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 6 12 18 24 30 5 11 17 23 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 PM10 (μg/m3) 4 35 56 46 ND 20 28 26 61 9 50 60 27 15 35 22 29 62 ND 13 17 17 33 15 17 30 11 ND 21 ND July August September October November December 5 11 17 23 29 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 ND 29 17 36 22 22 12 26 20 15 16 12 20 19 69 26 39 40 29 23 21 41 19 16 18 29 18 8 18 11 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 55 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H2 - PM10 Data for 1991 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 1 7 13 19 25 31 6 12 18 24 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 PM10 (μg/m3) ND ND ND ND ND ND 23 14 14 50 28 26 64 18 46 36 13 16 7 27 13 55 21 ND ND 20 30 24 20 27.6 6.5 July August September October November December 5 11 17 23 29 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 16 12 28 12 25 27 19 18 11 30 25 15 13 20 12 41 25 14 26 15 20 ND 23 24 ND 13 31 31 32 22 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 56 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H3 - PM10 Data for 1992 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 1 7 13 19 25 31 6 12 18 24 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 6 12 18 24 30 PM10 (μg/m3) 5 8 6 83 53 19 20 33 27 16 21 38 33 23 37 64 15 15 17 8 ND ND ND ND ND ND 26 18 38 26 22 July August September October November December 6 12 18 24 30 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 28 14 17 25 ND 56 21 29 24 11 36 46 37 33 43 47 18 18 44 ND 31 32 35 ND ND ND 12 26 35 15 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 57 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H4 - PM10 Data for 1993 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 2 8 14 20 26 1 7 13 19 25 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 1 7 13 19 25 PM10 (μg/m3) 24 34 54 24 40 43 18 21 14 10 34 102 52 18 30 58 16 23 31 18 18 ND 31 13 28 32 22 ND 12 28 July August September October November December 1 7 13 19 25 31 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 20 24 28 ND ND ND ND ND 25 24 18 8 4 21 30 27 23 17 20 15 18 21 ND ND ND 20 11 20 32 44 16 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 58 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H5 - PM10 Data for 1994 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 3 9 15 21 27 2 8 14 20 26 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 PM10 (μg/m3) 17 6 25 12 29 25 15 26 16 29 19 21 28 8 40 22 14 11 29 22 14 53 67 ND 40 44 17 11 10 28 July August September October November December 2 8 14 20 26 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 21 29 ND 37 14 12 10 15 12 24 22 17 29 15 ND 14 22 16 11 29 11 26 20 10 43 25 6 17 20 22 29 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 59 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H6 - PM10 Data for 1995 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 4 10 16 22 28 3 9 15 21 27 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 PM10 (μg/m3) 32 16 22 10 5 15 22 14 12 46 12 23 39 22 17 ND ND ND ND ND 21 9 ND 16 17 14 20 17 11 16 July August September October November December 2 8 14 20 26 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 ND 18 18 13 19 19 ND ND ND 23 15 12.5 11.9 11.3 7.3 13.1 15.3 13.3 15.8 16 7 20.3 11.9 16.4 10.8 ND ND ND ND 8 14.8 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 60 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H7 - PM10 Data for 1996 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 4 10 16 22 28 3 9 15 21 27 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 3 9 15 21 27 PM10 (μg/m3) 23.8 27.1 37.7 31.1 2.8 ND 9.1 28.1 57.7 25.2 48.2 43.9 37 39.6 24.3 41.4 32.4 14.8 14.5 8.5 5.6 18.2 16.6 13.9 13.5 12.3 14.7 13.2 6.8 9.8 July August September October November December 3 9 15 21 27 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 13.6 8.3 16.4 15.5 24 8 ND 28 28 10 13 10 9 11 28 25 41 25 ND 31 18 31 30 28 22 20 9 37 14 13 28 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 61 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H8 - PM10 Data for 1997 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 5 11 17 23 29 4 10 16 22 28 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 4 10 16 22 28 PM10 (μg/m3) 14 28 16 14 24 9 38 21 18 26 24 22 22 ND 13 ND ND ND ND ND 25 ND 16 ND 16 19 33 12 13 25 July August September October November December 4 10 16 22 28 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 47 36 21 ND 39 63 38 46 71 49 29 21 18 8 8 ND 18 22 24 37 33 26 25 20 9 8 16 12 24 15 13 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 62 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H9 - PM10 Data for 1998 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 6 12 18 24 30 5 11 17 23 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 PM10 (μg/m3) 25 15 14 29 24 24 103 42 25 40 35 12 25 16 13 19 19 30 31 13 13 20 8 19 12 14 10 22 14 17 July August September October November December 5 11 17 23 29 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 8 21 16 17 25 6 22 14 14 22 18 19 ND 28 9 ND 13 18 29 16 23 28 15 19 15 12 22 16 ND ND Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 63 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H10 - PM10 Data for 1999 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 1 7 13 19 25 31 6 12 18 24 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 PM10 (μg/m3) 53 27 16 30 11 21 26 26 88 34 31 20 37 13 35 33 10 26 ND ND 27 11 11 21 21 9 11 6 14 15 14 July August September October November December 5 11 17 23 29 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 11 13 16 12 9 18 32 14 ND 13 6 8 16 5 19 19 21 16 13 17 24 24 19 27 15 17 27 ND ND 19 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 64 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H11 - PM10 Data for 2000 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 1 7 13 19 25 31 6 12 18 24 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 6 12 18 24 30 PM10 (μg/m3) 19 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 11 17 23 7 15 20 12 22 10 9 6 8 12 12 July August September October November December 6 12 18 24 30 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 21 ND 9 10 5 9 ND 38 7 16 8 13 15 12 9 8 12 17 10 ND ND ND ND ND ND 13 21 26 7 5 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 65 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H12 - PM10 Data for 2001 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 2 8 14 20 26 1 7 13 19 25 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 1 7 13 19 25 PM10 (μg/m3) 11 16 11 9 13 21 10 70 19 31 31 13 21 16 14 20 17 17 11 16 59 12 9 15 16 13 15 28 21 19 July August September October November December 1 7 13 19 25 31 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 12 18 21 23 28 11 16 16 20 21 14 ND ND ND ND ND 11 14 21 23 11 25 14 31 21 13 7 14 10 7 12 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 66 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H13 - PM10 Data for 2002 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 3 9 15 21 27 2 8 14 20 26 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 PM10 (μg/m3) 6 11 7 10 20 16 30 36 13 23 20 15 ND ND 16 11 11 11 17 8 10 12 17 17 16 14 17 12 17 21 July August September October November December 2 8 14 20 26 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 18 22 15 20 25 32 27 43 ND 60 28 40 13 21 16 37 30 9 17 17 12 26 11 11 19 14 12 11 15 11 ND Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 67 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H14 - PM10 Data for 2003 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 4 10 16 22 28 3 9 15 21 27 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 PM10 (μg/m3) ND 20 20 15 17 15 26 24 ND 13 31 33 42 79 23 28 19 8 15 20 19 11 18 12 13 18 17 11 18 18 July August September October November December 2 8 14 20 26 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 18 19 24 14 53 33 12 29 28 9 18 12 13 10 24 13 28 25 2 23 17 25 9 12 28 ND 12 17 19 16 13 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 68 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H15 - PM10 Data for 2004 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 4 10 16 22 28 3 9 15 21 27 5 11 17 23 29 4 10 16 22 28 4 10 16 22 28 3 9 15 21 27 PM10 (μg/m3) ND 6 8 19 14 26 30 18 24 24 27 18 11 14 10 10 15 12 26 13 16 16 14 6 21 13 ND ND 23 9 July August September October November December 3 9 15 21 27 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 11 7 21 18 22 13 20 10 12 15 9 19 9 12 10 ND ND ND ND ND ND 10 13 34 10 14 13 20 22 10 14 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 69 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H16 - PM10 Data for 2005 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 5 11 17 23 29 4 10 16 22 28 6 12 18 24 30 5 11 17 23 29 5 11 17 23 29 4 10 16 22 28 PM10 (μg/m3) 12 13 23 10 11 8 16 8 15 11 8 13 11 14 18 ND ND 8 9 13 16 20 27 10 9 11 ND 13 10 ND July August September October November December 4 10 16 22 28 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 1 7 13 19 25 1 7 13 19 25 31 ND 12 14 29 36 25 29 28 45 26 23 ND 7 9 18 14 7 20 8 15 24 15 12 13 10 16 21 8 ND ND 12 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 70 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H17 - PM10 Data for 2006 Ambient Air Quality Monitoring Report Castlegar, British Columbia Month Day January February March April May June 6 12 18 24 30 5 6 11 17 23 1 7 13 19 25 31 6 12 18 24 30 6 12 18 24 30 5 11 17 23 29 PM10 (μg/m3) ND ND 16 12 4.3 16 15 60 10 7 28 26 17 6 17 21 16 12 18 10 11 17 20 8 ND ND ND ND ND ND ND July August September October November December 5 11 17 23 29 4 10 16 22 28 3 9 15 21 27 3 9 15 21 27 2 8 14 20 26 2 8 14 20 26 ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 18 Values in bold depict days with PM10 exceeding NAAQ objectives. ND = No data available for the day. 71 Ministry of Environment Kootenay Region ENVIRONMENTAL QUALITY Appendix H18 - PM10 Data for 2007
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