CHEM 100 Sample Test Chapter 5 SAMPLE TEST -CHPATER 5 Freshman Chemistry, La Tech-CHEM 100 sample, Test 3-Chapter 5. 1. When a homogeneous liquid mixture is formed from solid KNO3 and water, the KNO3 is called a a. solution. b. solute. c. solvent. d. melt. 2. A supersaturated solution a. contains more solute than a saturated solution. b. has extra solute at the bottom. c. has an extremely high concentration. d. is intensely colored. 10. Which salt below is insoluble? a. Na2NO3. b. BaCl2. c. PbCl2. d. NH4SO4. 11. How much 12.6 M HCl is required to make 75.0 mL of 3.50 M HCl? a. 20.8 mL b. 58.8 mL c. 270 mL d. 0.588 mL 12. An increase in oxidation number during the course of a reaction is called a. oxidation. b. reduction. c. disproportionation. d. titration. 3. Sugar is best classified as a. a strong electrolyte. b. a nonelectrolyte. c. a weak electrolyte. d. insoluble. 13. The following species with the highest oxidation number for manganese is b. MnO4-. c. MnO2. d. a. MnSO4. Mn2O3. 14. The oxidation number of I in IF5 is a. -1/5. b. +1/5. c. -5. d. +5. 4. The compound NaCl is best classified as a. a strong electrolyte. b. a nonelectrolyte. c. a weak electrolyte. d. insoluble. 5. The compound NaC2H3O2 is best classified as a. an acid. b. a base. c. a salt. d. a nonelectrolyte. 6. 7. 15. The reaction below that is NOT a redox reaction is a. 2 C2H6(g) + 7 O2(g) Æ 4 CO2(g) + 6 H2O (l). b. 2 AgNO3(aq) +Cu(s)Æ 2Ag(s) +C u(NO3)2(aq). c. AgNO3(aq) + HCl(aq) Æ AgCl(s) + HNO3(aq). d. 6 CO2(g) + 6 H2O(l) Æ C6H12O6(aq) + 6 O2(g). When a solution of CuCl2 and one of AgNO3 are mixed, the net ionic equation is a. Cu2+(aq) + 2 Cl-(aq) + 2 Ag+(aq) + 2 NO3-(aq) --> Cu2+ (aq) + 2 NO3-(aq) + 2 AgCl(s). b. CuCl2(aq)+ 2 AgNO3(aq) --> Cu(NO3)2(aq) + 2 AgCl(s). c. Cu2+(aq) + 2 NO3-(aq) --> Cu(NO3)2(aq). d. Cl-(aq) + Ag+ (aq) --> AgCl(s). When a solution of BaNO3 and one of Na2SO4 are mixed, what is/are the spectator ion(s) ? 16. For Pb(s) + PbO2(s) + 2 H2SO4(aq) Æ 2 PbSO4(s) + 2 H2O(l), the substance that is reduced during the reaction is a. Pb(s). b. PbO2(s). c. H2SO4(aq). d. PbSO4(s). Ba(NO3)2(aq) + Na2SO4(aq) --> BaSO4(s) + 2NaNO3(aq) a. Na+ and NO3-. b. SO42-. d. there are no spectator ions. c. Ba2+. 17. Which compound will not dissolve in water? a. KCl b. NH4NO3 c. CaS d.MgSO4 e.NaNO3 18. Which compound will dissolve in water? a. BaSO4 b.MgS c.AgCl d.Al(OH)3 e.Na2SO4 8. The (w/w %) percent by mass KNO3 of a solution prepared by dissolving 5.34 g of KNO3 in 34.7 g of water is a. 15.4. b. 13.3. c. 8.18. d. 5.34. 19. Which compounds will not dissolve in water at 20°C? CaSO4 PbCl2 KBr KNO3 I II III IV 9. The molarity of a solution made by dissolving 2.38 g of NH4NO3 (f.w.=80.06 g/mol) in 25.0 mL of solution is a. 0.0952 M. b. 95.2 M. c. 1.19 M. d. 0.119 M. 25 a. b. c. d. e. d. Al+ + OH- → AlOH e. Al3+ + 3OH- → Al(OH)3 I & II II & III III & IV I & IV III & IV 24. Which of the following is not a property of acids? a. Acids taste sour. b. Acids produce gas bubbles when reacting with limestone. c. Acids neutralize bases. d. Acids form precipitates on reaction with metals. e. Acids increase the hydrogen ion concentration of water when dissolved in it. 20. Which statement about the reaction below is true? NaCl + NH4NO3 → NaNO3 + NH4Cl a. All compounds in the reaction are soluble in water and no reaction occurs. b. NaNO3 is insoluble in water and will precipitate. c. NH4Cl is insoluble in water and will precipitate. d. Both NaNO3 and NH4Cl are insoluble in water and will precipitate. e. NH4NO3 is insoluble in water and no reaction will occur. 21. Which statement about the reaction below is true? Pb(NO3)2 + Na2SO4 → PbSO4 + 2NaNO3 a. All compounds in the reaction are soluble in water and no reaction occurs. b. PbSO4 is insoluble in water and will precipitate. c. NaNO3 is insoluble in water and will precipitate. d. Both NaNO3 and PbSO4 are insoluble in water and will precipitate. e. Pb(NO3)2 is insoluble in water and no reaction will occur. a. b. c. d. e. 23. a. b. c. a. b. c. d. e. 25. What is the correct formula for the hydronium ion? HNH4+ OHH3O+ H+ a. b. c. d. e. 26. What is the correct formula for the hydroxide ion? H NH4+ OHH3O+ H+ 27. Which statement about strong acids is true? a. Strong acids are weak electrolytes. b. Strong acids are very concentrated. c. Strong acids are almost entirely converted to ions when dissolved in water. d. Acetic acid is a strong acid. e. All of the above are true. 28. Which statement about bases is false? a. Bases increase the hydroxide ion concentration of water when dissolved in it. b. Bases turn red litmus paper blue. c. Bases taste bitter. d. Ammonia is a base. e. Bases increase the hydronium ion concentration of water when dissolved in it. 22. What is the net ionic equation for the reaction of AgNO3 and KBr? + Ag + Br- → AgBr Ag2+ + Br- → AgBr2 Ag2+ + Br2- → AgBr K+ + NO3- → KNO3 K2+ + NO3- → K(NO3)2 What is the net ionic equation for the reaction of AlCl3 and NaOH. Al3+ + OH3- → AlOH Na3+ + 3Cl- → NaCl3 Na+ + Cl- → NaCl 29. All of the following are strong electrolytes except: 26 a. b. c. d. e. HCl NaOH NH4OH H2SO4 HNO3 a. b. c. d. e. 30. Which of the following is a nonelectrolyte? HBr Mg(OH)2 NaCl C6H12O6 KI a. b. c. d. e. 31. Which statement about neutralization reactions is false? The reaction of a strong base with a strong acid is an example of a neutralization reaction. Neutralization reactions produce salts. The net ionic equation for a neutralization reaction shows the formation of water. Organic acids can neutralize bases. All of the above are true. 32. Which of the following factors cause exchange reactions to occur? formation of a gas only formation of a precipitate only formation of water only formation of a gas or a precipitate formation of a gas, precipitate or water a. b. c. d. e. 33. What species is the reducing agent in the reaction below? HCl + Mg → MgCl2 + H2 HCl Mg MgCl2 H2 Mg and H2 a. b. c. d. e. d. O2 and CaO e. CaO 34. What species is the oxidizing agent in the reaction below? Ca + O2 → CaO a. Ca b. Ca and O2 c. O2 a. b. c. d. e. 35. Which of the following is a reducing agent? O2 F2 Br2 I2 Na a. b. c. d. e. 36. Which of the following represents an oxidation half reaction? Na+ + 1e- → Na Mg → Mg2+ + 2eCu2+ + 1e- → Cu Al3+ + 3e- → Al O + 2e- → O2- a. b. c. d. e. 37. Which of the following represents a reduction half reaction? F- → F2 + 2eNi2+ → Ni3+ + 1eS + 2e- → S2K → K1+ + 1ePb → Pb2+ + 2e- a. b. c. d. e. 38. Which substance is oxidized in the reaction below? NaNO3 + Pb → NaNO2 + PbO NaNO3 NaNO2 Pb PbO none of the above a. b. c. d. e. 39. Which substance is reduced in the reaction below? Na2SO4 + 4C → Na2S + 4CO Na2S Na2SO4 CO S none of the above 40. What is the oxidation number of Cl in Cl2O5? 27 a. b. c. d. e. 41. +2 -2 -3 -5 +5 What is the oxidation number of H in MgH2? a. -1 b. +1 c. 0 d. +2 e. -2 42. What is the oxidation number of F in F2? a. -1 b. +1 c. 0 d. +2 e. -2 b. c. d. e. CO2 O2 H2O O2 and CO2 47. a. b. c. d. e. 48. a. b. c. d. e. Which element is most reactive? Mg Ag Ba Sn Ni Which element is least reactive? Zn Pb Fe Al Cu 49. Which single replacement reaction will not occur? a. Mg + CaSO4 → MgSO4 + Ca b. Ba + HCl → BaCl2 + H2 c. Al + SnCl2 → AlCl3 + Sn d. H2 + AgNO3 → HNO3 + Ag e. Mg + CuSO4 → Cu + MgSO4 43. What is the oxidation number of P in PO43-? a. -3 b. +3 c. -2 d. +5 e. -5 50. How many grams of NaOH are present in 25.0 mL of a 0.1000 M NaOH solution? a. 100 g b. 2.50 × 10-3 g c. 0.100 g d. 2.50 g e. 25.0 g 44. What is the oxidation number of N in NH4+? a. +1 b. -1 c. 0 d. +3 e. -3 45. Which species is oxidized in the reaction below? I2O5 + CO → I2 + CO2 a. CO2 b. I2 c. I2O5 d. CO e. CO and CO2 51. What is the molarity of a solution that results when 14.2 g of (NH4)3PO4 is dissolved in water and diluted to exactly 250.0 mL? a. 1.52 M b. 0.238 M c. 56.8 M d. 0.381 M e. 1.07 × 10-4 M 46. Which species is oxidized in the reaction below? CH4 + O2 → CO2 + H2O a. CH4 52. Determine the ammonium ion concentration of a solution that results when 4.53 g of (NH4)2SO4 is dissolved in water and diluted to exactly 100.0 mL. 28 a. b. c. d. e. 0.686 M 0.343 M 1.03 M 1.37 M 2.51 M b. c. d. e. 0.0469 moles 3.00 × 10-3 moles 46.9 moles 0.938 moles 58. How many moles of ions are in 285 mL of 0.0150 M MgCl2? a. 4.128 × 10-3 mol b. 5.26 × 10-2 mol c. 5.26 × 10-1 mol d. 1.28 × 10-2 mol e. 1.05 × 10-1 mol 53. To what volume must 25.0 g of BaCl2 be diluted to yield a solution that is 0.600 M? a. 240. mL b. 400. mL c. 800. mL d. 480. mL e. 200. mL 54. A 50.0 mL sample of 0.108 M H2SO4 is diluted to 250.0 mL. What is its new molarity? a. 0.542 M b. 0.0216 M c. 0.184 M d. 0.461 M e. 0.108 M 59. A solution is made by dissolving 12.5 g of LiCl in enough water to make 500.0 mL of solution. How many moles are in 35.0 mL of solution? a. 0.0206 mol b. 0.295 mol c. 0.590 mol d. 0.0103 mol e. 0.438 mol 55. To which volume should a 25.0 ml sample of 1.50 M Na2SO4 be diluted to yield a final solution that is 0.300 M in sodium ions? a. 375 mL b. 125 mL c. 250 mL d. 4.95 mL e. 4950 mL 60. A solution is made by dissolving 60.0 g of AlCl3 in enough water to make 250.0 mL of solution. How many moles of ions are in 5.00 mL of solution? a. 5.00 × 10-3 mol b. 9.00 × 10-3 mol c. 1.25 × 10-3 mol d. 1.01 × 10-3 mol e. 3.60 × 10-2 mol 56. Which of the methods described below will yield 500 mL of a 0.100 M KMnO4 solution? a. Add exactly 500 mL of water to 7.90 g of KMnO4. b. Dissolve 15.8 g KMnO4 in water and dilute to exactly 500 mL. c. Add exactly 500 mL of water to KMnO4. d. Dissolve 7.90 g of KMnO4 in water and dilute to exactly 500 mL. e. Dilute 220 mL of 1.00 M KMnO4 to exactly 500 mL. 61. How many grams of AgCl will precipitate from the reaction of 37.0 mL of 0.280 M AgNO3 with excess NaCl solution? a. 149 g b. 189 g c. 1.49 g d. 1.89 g e. 0.60 g 62. Hydrochloric acid solutions are often standardized by the reaction below. How many grams of CaCO3 are required to exactly react with 50.0 mL of 0.155 M HCl? 57. How many moles are in 125.0 mL of 0.375 M KCl? a. 3.00 moles 29 CaCO3(s) + 2HCl(aq) → CaCl2(aq) + H2O(l) + CO2(g) a. 0.341 g b. 0.566 g c. 0.387 g d. 0.194 g e. 0.283 g 63. Oxalic acid, H2C2O4, reacts with Y(NO3)3 as shown by the equation below. What weight of yttrium oxalate is produced from 50.0 mL of 0.265 M Y(NO3)3 and excess oxalic acid? b. c. d. e. 0.1018 M 0.03122 M 0.1021 M 0. 09453 M 67. A 25.00 mL sample of H2SO4 solution is neutralized by exactly 41.63 mL of 0.1363 M NaOH. What is the molarity of the H2SO4 solution? a. 0.2270 M b. 0.2726 M c. 0.06815 M d. 0.1135 M e. 0.05675 M 68. A 35.00 mL sample of HNO3 solution is neutralized by exactly 42.63 mL of 0.4153 M Ba(OH)2. What is the molarity of the HNO3 solution? a. 0.5058 M b. 0.1265 M c. 0.2529 M d. 0.2077 M e. 1.012 M 69. A 25.00 mL sample of H3PO4 solution is neutralized by exactly 54.93 mL of 0.04345 M Ca(OH)2. What is the molarity of the H3PO4 solution? a. 0.2148 M b. 0.09546 M c. 0.2897 M d. 0.06363 M e. 0.1432 M 70. Ammonia and sulfuric acid react according to 2Y(NO3)3(aq) + 3H2C2O4(aq) → Y2(C2O4)3(s) + 6HNO3(aq) a. 5.85 g b. 2.93 g c. 1.82 g d. 1.46 g e. 3.64 g 64. Determine the mass of BaSO4 that is produced by the reaction of 45.0 mL of 0.155 M H2SO4 and 60.0 mL of 0.125 M BaCl2. BaCl2(aq) + H2SO4(aq) → BaSO4(s) + 2HCl(aq) a. 0.775 g b. 3.24 g c. 1.62 g d. 1.79 g e. 1.45 g 65. Ammonia and sulfuric acid react according to the equation given below. How many milliliters of 0.110 M sulfuric acid are required to exactly neutralize 25.0 mL of 0.0840 M NH3 solution? 2NH3(aq) + H2SO4(aq) → (NH4)2SO4(aq) a. 5.85 g b. 9.55 g c. 1.82 g d. 1.46 g e. 3.64 g 66. A 25.00 mL sample of HCl solution is neutralized by exactly 31.22 mL of 0.08152 M NaOH. What is the molarity of the HCl solution? a. 0.08152 M the equation below. How many milliliters of 0.110 M sulfuric acid are required to exactly neutralize 25.0 mL of 0.0840 M ammonia solution? 2NH3(aq) + H2SO4(aq) → (NH4)2SO4(aq) a. b. c. d. e. 12.5 mL 25.0 mL 4.77 mL 9.55 mL 19.1 mL Answers to Sample Test 1. > b 2. > a 3. > b 4. > a 30 solute. contains more solute than a saturated solution. a non-electrolyte. a strong electrolyte. 47. 48. 49. 50. 51. 52. 53. 54. 55. 56. c. Ba e. Cu a. Mg + CaSO4 → MgSO4 + Ca c. 0.100 g d. 0.381 M a. 0.686 M e. 200. mL b. 0.0216 M c. 250 mL d. Dissolve 7.90 g of KMnO4 in water and dilute to exactly 500 mL. 57. b. 0.0469 moles 58. d. 1.28 × 10-2 mol 59. a. 0.0206 mol 60. e. 3.60 × 10-2 mol 61. c. 1.49 g 62. c. 0.387 g 63. b. 2.93 g 64. c. 1.62 g 65. b. 9.55 g 66. b. 0.1018 M 67. d. 0.1135 M 68. e. 1.012 M 69. d. 0.06363 M 70. d. 9.55 mL 5. > c a salt. 6. > d Cl-(aq) + Ag+ (aq) --> AgCl(s). 7. > a Na+ and NO3-. 8. > b 13.3. 9. > c 1.19 M. 10. > c PbCl2. 11. > a 20.8 mL 12. > a oxidation. 13. > b. MnO4-. 14. > d +5. 15. > c AgNO3(aq) + HCl(aq) Æ AgCl(s) + NO3(aq). 16. > b. PbO2(s). 17. e. CaS 18. e. Na2SO4 REF: Section 5.1 19. a. I & II 20. a. All compounds in the reaction are soluble in water 21. b. PbSO4 is insoluble in water and will precipitate 22. a. Ag+ + Br- → AgBr 23. e. Al3+ + 3OH- → Al(OH)3 24. d. Acids form precipitates on reaction with metals. 25. c. H3O+ 26. c. OH27. c. Strong acids are almost entirely converted to ions when dissolved 28. e. Bases increase the hydronium ion concentration of water when dissolved in it. 29. c. NH4OH 30. d. C6H12O6 31. e. All of the above are true. 32. e. formation of a gas, precipitate or water 33. b. Mg 34. c. O2 35. e. Na 36. b. Mg → Mg2+ + 2e37. c. S + 2e- → S238. c. Pb 39. d. S 40. e. +5 41. a. -1 42. c. 0 43. d. +5 44. e. -3 45. d. CO 46. a. CH4 31
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