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d OILFIELD ENVIRONMENTAL & COMPLIANCE, INC. (OEC) lle QUALITY SYSTEM MANUAL Revision 18 – JULY 2014 tro Locations Covered Administrative Offices & Volatile Organics Department 2010 Preisker Lane, Suite F Santa Maria, CA 93454 on Main Laboratory & Sample Receiving 307 Roemer Way Santa Maria, CA 93454 (805) 922-4772 nc Julius Carstens Laboratory Director & Vice President U Lisa Race Technical Director Taft Field Services Office 101 Adkisson Way Taft, CA 93268 (661) 762-9143 Laboratory Quality System Authority Mary Ann Long Operations Director Carrie McCrillis Quality Director (Includes ‘Quality System Authority’ above) Laboratory Signature Authority Meredith Sprister Project Manager Marissa Censullo Project Manager This Quality System Manual governs the quality program for all operating units of the laboratory, as shown on the organization chart presented in the manual. Quality System Manual Page 2 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. TABLE OF CONTENTS SECTION PAGE 4 4 4 4 3.8 3.9 Reference Materials Handling and Storage of Reference Standards and Materials Labeling & Documentation of Reference Standards, Reagents, and Materials on 3.7.1 3.7.2 3.7.3 tro SECTION 3 – QUALITY ASSURANCE FUNCTIONS 3.1 Quality Policy & Objectives 3.2 Change Management 3.3 Document and Record Management 3.4 Corrective & Preventive Action (CAPA) 3.5 Control of Non-Conforming Work 3.6 Method Validation 3.7 Measurement Traceability lle SECTION 2 – PERSONNEL, ORGANIZATION AND RESPONSIBILITIES 2.1 Responsibility and Lines of Authority FIGURE 2A –Organization Chart 2.2 Job Descriptions 2.3 Data Integrity, Ethics & General Training d SECTION 1 – INTRODUCTION 1.1 Quality System Manual 1.2 Scope of Testing 1.3 Glossary & Acronyms Audits Management Review 8 8 9 9 12 14 14 15 15 17 18 19 20 20 21 21 22 23 24 24 24 24 25 25 SECTION 5 – LABORATORY FUNCTIONS 5.1 Accommodations & Environmental Conditions Figure 5A – Preisker Location Figure 5B – Roemer Location 5.2 Purchasing Services and Supplies 5.3 Sample Management 5.4 Equipment 5.5 References for Analytical Methods 5.6 Quality of Test Results Table 5C Essential Quality Control Elements 27 27 27 28 28 29 29 30 32 34 U nc SECTION 4 – CLIENT SERVICE FUNCTIONS 4.1 Client Confidentiality 4.2 Review of Requests, Tenders and Contracts 4.3 Complaints 4.4 Subcontracting of Tests 4.5 Reporting of Results 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 3 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. 37 38 40 42 44 47 48 49 50 51 53 55 56 APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) 57 tro APPENDIX C – OEC EQUIPMENT LIST lle d APPENDIX A – CONTACT & QUALIFICATIONS OF PERSONNEL Julius Carstens Laboratory Director Mary Ann Long Operations Director Carrie McCrillis Quality Director & Human Resources Representative Lisa Race Technical Director & Safety Officer Meredith Sprister Project Manager (Lead) Marissa Censullo, Project Manager Kristie Mikel Department Manager, Microbiology, Bioassay & Wet Chemistry Drew Miller Department Manager, Volatile Organics Parwinder Parmar Department Manager, Metals & Instrumental Inorganics Dwain Zsadanyi Department Manager, Semi-Volatile Organics Pete Alcocer Oil Production Operations Consultant Brandon Ganster Oil Production Taft Operations Supervisor 62 75 APPENDIX E – DATA CAPABILITY TABLES INORGANICS METALS TPH ORGANICS VOLATILE ORGANICS SEMI-VOLATILE ORGANICS 76 76 77 78 78 83 on APPENDIX D – SAMPLE TREATMENT: HOLDING TIMES & CONTAINERS 86 86 87 88 89 90 91 92 93 94 U nc APPENDIX F – QC DATA EVALUATION FLOWCHARTS Evaluation of Initial Calibration Evaluation of Continuing Calibration Evaluation of Method Blank and Instrument Blank Results Evaluation of Sample Results for Inorganics Analytes Evaluation of Sample Results for Organic Analyses Evaluation of Surrogate Compound Recoveries Evaluation of Laboratory Control Sample & Duplicate (LCS/LCSD) Evaluation of Matrix Spike & Duplicate (MS/MSD) Recoveries Evaluation of Duplicate Sample (DUP) and/or MS Duplicate (MSD) Precision 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 4 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. SECTION 1 – INTRODUCTION QUALITY SYSTEM MANUAL The objective of the OEC Quality System Manual is to outline the quality organization for the laboratory. The Quality System Manual sets the standard under which all laboratory operations are performed including the laboratory's organization, objectives, and operating philosophy. The Quality System Manual defines the policies, procedures, and documentation required to meet the objectives of sampling and analytical services provided. lle 1.1 d OILFIELD ENVIRONMENTAL & COMPLIANCE INC. (OEC) is an analytical laboratory and field support company located in Santa Maria, California. It is operated as a commercial environmental laboratory, specializing in the analytical testing of solids, liquids, air, and product matrices. It is the goal of OEC to provide clients with data that is valid, defensible and reproducible while meeting their specific needs. tro The Quality Director ensures that OEC policies and objectives for quality are documented by reference or inclusion in the Quality System Manual. The Quality System Manual is communicated to, understood by, and implemented by all personnel concerned. Where the Quality System Manual does not document laboratory requirements, a separate SOP will do so. on In the following sections, detailed information will be given on OEC procedures for personnel qualifications, sample collection, CoC documentation, sample handling, storage and disposition, equipment calibrations and maintenance, reagents, SOPs, quality control procedures and data reduction, validation and verification. SCOPE OF TESTING The laboratory scope of analytical testing services includes those listed in Appendices D & E. 1.3 GLOSSARY & ACRONYMS Refer to the SOP [GEN-DEFIN], Acronyms & Definitions for a complete listing of laboratory terms and acronyms. Acceptance criteria – Criteria often applied to data drawn from existing sources (“secondary “ data) addressing the adequacy of existing information. Accuracy – The average of results of same sample compared to amount of known analyte in sample. Audit – A systematic and independent examination to determine whether quality activities and related results comply with planned arrangements and whether these arrangements are implemented effectively and are suitable to achieve objectives. Bias – The systematic or persistent distortion of a measurement process that causes errors in one direction. Blank – A sample containing none of the analytes of interest subjected to the usual analytical process to establish a zero baseline. It is used to detect contamination during sample handling preparation and/or analysis. Chain-of-custody (CoC) – An unbroken trail of accountability that ensures the physical security of samples, data and records. U nc 1.2 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 5 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. U nc on tro lle d Comparability – A measure of the confidence with which a method or set of data can be compared to another. Conformance – an affirmative indication or judgment that a product or service comply with the relevant specification, contract or regulation. Continuing Calibration Verification (CCV) – The protocol to check the calibration curve on a batch basis to verify that it is still valid. The normal check is to test one of the original midlevel calibration standards and verify that the RPD is within the acceptance range of the method. Corrective action – Any measures taken to rectify conditions adverse to quality and where possible, to prevent recurrence. Data quality – A measure of the degree of acceptability or use of data for a particular purpose. Data reduction – The process of transforming the number of data items by arithmetic or statistical calculations, standard curves and concentration factors and assemble them into a more useful form. Data validation – An analyte-/sample-specific process that extends the evaluation of data beyond method, procedural or contractual compliance to determine the analytical quality of a specific data set. Data verification – The process of evaluating the completeness, correctness and conformance/compliance of a specific data set against the method, procedural, or contractual specifications. Detection limit – The lowest concentration or amount of the target analyte that can be determined to be different from zero by a single measurement at a stated level of probability. Used to distinguish samples that do not contain a specific analyte from samples that contain low concentration of the analyte. Duplicates – For each batch analyzed, a sample duplicate, laboratory control duplicate and a matrix duplicate will be added for quality control purposes to demonstrate precision in performing the analysis. Field blank – A clean analyte-free sample which is carried to the sampling site and then exposed to sampling conditions, returned to laboratory and treated as an environmental sample. It is used to provide information about contaminants that may be introduced during sample collection, storage and transport. Holding time (HT) – The period of time a sample may be stored before analysis. Initial Calibration Verification (ICV) – Immediate analysis of standards from a different manufacturer than that of the calibration standards to check suitability of a calibration curve. Internal Standard (IS) – Compounds added to the sample after sample preparation for qualitative and quantitative analysis. The compounds serve to give a standard of retention time and instrument response. Laboratory Control Sample (LCS) – A sample made with reagent water and known amounts of target analytes. It is analyzed with a batch to serve as quality control on the sample preparation process. Matrix spike sample (MS) – A sample prepared by adding a known amount of the target analyte to a specified amount of a matrix. It is used to determine the effect of the matrix on a method’s recovery efficiency. Method – A body of procedures and techniques for performing an activity, systematically presented in the order in which they are to be executed. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 6 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. tro lle d Method blank (MB) – A blank prepared and analyzed exactly like the sample to indicate if a bias has been introduced into the analytical procedure. Method Limit (ML) or Method Detection Limits (MDL) – Minimum level of a target analyte that can be determined with 99% confidence. Reporting Limit (RL) or Practical Quantitation Levels (PQL) – The lowest level that can be reliably achieved during routine laboratory operating conditions within specified limits of precision and accuracy. The number given is selected by multiplying the standard deviation results from the MDL procedure. Precision – A measure of agreement among repeated measurements of the same property under identical conditions. It is generally expressed in terms of the standard deviation. Quality assurance – The sum of all quality control performed, the reporting of the data and improvement made to ensure that processes are of the quality needed. Quality control – Procedure to evaluate a single aspect of an analyte or test. Spike – A substance that is added to an environmental sample to increase the concentration of the target analyte by a known amount. It is used to measure accuracy. Spike duplicates are used to assess measurement precision. Standard Operating Procedure (SOP) – A document that details the method for an operation, analysis or action with thoroughly prescribed techniques and steps to be followed. It is officially approved as the method for performing certain tasks. SI Prefix Abbreviation Value M k d c m μ n 10 3 10 -1 10 -2 10 -3 10 -6 10 -9 10 p 10 nc Mega Kilo Deci Centi Milli Micro Nano on Units – All units used to qualify any incoming samples must be properly identifiable. The laboratory utilizes SI and additional units in our measuring systems. Listed below are common industry units of measure. SI Units (NIST) Pico 6 SI Parameter Base Unit Abbreviation Mass Length Time Temperature Amount of Substance Electric Current Luminous Intensity Gram Meter Second Kelvin Mole Ampere Candela g m s K mol A cd -12 U Additional common industry units L – Liter (volume parameter accepted for use with SI) Hence: mL – milliliter (0.001 L) μL – microliter (0.000001 L) Ω = Ohm: V=IR (used for DI water purity measurement) ºC = Centigrade: ºC = K – 273.15 ºF = Fahrenheit: ºF = 9/5(ºC) + 32 ppb – parts per billion (normally μg/L for aqueous samples or μg/kg for solid samples) ppm – parts per million (normally mg/L for aqueous samples or mg/kg for solid samples) ACRONYMS not otherwise defined Blk – Blank °C – degrees Celsius 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 7 of 94 Rev 18 – JULY 2014 lle Corrective Action & Preventive Action calibration Chain of custody Dissolved oxygen Demonstration of Competency Environmental Protection Agency grams per liter gas chromatography/mass spectrometry inductively coupled plasma-mass spectrometry Initial calibration verification Initial Demonstration of Capability Pound per Square Inch Laboratory Control Sample Laboratory Fortified Blank Milligrams per Kilogram Milligrams per Liter Matrix Spike Matrix Spike Duplicate Oilfield Environmental and Compliance, Inc. Practical Quantitation Limit Quality Assurance Quality Control Quality System Manual Reporting Limit Relative Percent Difference Relative Standard Deviation Standard Operating Procedures Spike Standard Micrograms per Liter Ultraviolet Volatile Organic Compound Whole Effluent Toxicity I N C. d C O M P L I A N C E, tro – – – – – – – – – – – – – – – – – – – – – – – – – – – – – – – – & U nc CAPA cal COC DO DOC EPA g/L GC/MS ICP-MS ICV IDoC lb/in2 LCS LFB mg/Kg mg/L MS MSD OEC PQL QA QC QSM RL RPD RSD SOPs spk std µg/L UV VOC WET E N V I R O N M E N T A L on O I L F I E L D 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 8 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. SECTION 2 – PERSONNEL, ORGANIZATION AND RESPONSIBILITIES lle d Oilfield Environmental & Compliance, Inc. (OEC) is a legally identifiable organization located in Santa Maria, California. Through application of the policies and procedures outlined in this chapter, the laboratory assures that it is impartial and that personnel are free from undue commercial, financial, or other pressures that might influence their technical judgment. The laboratory is responsible for carrying out testing activities that meet the requirements of the relevant standards and that meet the needs of the client. 2.1 tro OEC management is committed to quality and to the quality system as stated in the Quality Policy, which is upheld through the application of related policies and procedures. A complete training program is administered to new employees prior to their handling client samples. Through proper training new employees are made aware of causes of unethical or illegal actions during analysis. The use of operating procedures specifying appropriate and inappropriate instrument and system manipulation practices, comprehensive system audits, a corrective action program, electronic and hard copy post-analysis data audits, and external performance evaluations contribute to quality workmanship from OEC employees. RESPONSIBILITY AND LINES OF AUTHORITY on OEC “SENIOR MANAGEMENT” includes the titles Laboratory Director, Technical Director, Operations Director and Quality Director. The term “MANAGEMENT” additionally includes the titles Project Managers and Department Managers. Approved signatories for the laboratory include the Senior Management and Project Managers. The Laboratory Director has overall responsibility for the technical operations and establishment of total laboratory policies, including the required quality of laboratory operations. nc OEC senior management is responsible for the policies, procedures, changes and delegation of responsibilities related to the Quality System. OEC management assumes specific responsibility for maintenance of the Quality System. This includes defining roles and responsibilities to personnel, approving documents, providing required training, providing a procedure for confidential reporting of data integrity issues, and periodically reviewing data, procedures, and documentation. Management also ensures that audit findings and corrective actions are completed within required schedules. U The Laboratory Director appoints designated alternates during the absence of any laboratory Management as defined above. The Laboratory Director is responsible for defining the minimal level of education, qualifications, experience, and skills necessary for all positions in the laboratory and that technical staff have demonstrated capabilities in their tasks. Training is kept up to date as described in this manual by periodic review of training records and through employee performance review. The Department Managers ensure technical competence of personnel operating equipment, performing tests, or evaluating results, and limits authority to perform laboratory functions to those appropriately trained and/or supervised. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 9 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. nc on tro lle d FIGURE 2A –ORGANIZATION CHART Refer to Appendix A for contact information and resumes of key personnel 2.2 JOB DESCRIPTIONS U Job descriptions are available for all positions that manage, perform, or verify work affecting data quality. Job descriptions include the specific tasks for each position. 2.2.1 Laboratory Director Has full authority through the President, is ultimately responsible for all laboratory activities, and is the highest-level manager. The laboratory director is responsible for overall laboratory operations and management compliance with the Quality System defined in this Quality Manual. Supervises all laboratory activities including staffing, training, procurement, safety, productivity and quality assurance. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 10 of 94 Rev 18 – JULY 2014 C O M P L I A N C E, I N C. Defines the minimum qualification level of education and training for all laboratory positions to properly carry out the duties assigned to them; Ensures that personnel are free from any commercial, financial and other undue pressures which might adversely affect the quality of their work; Supervises all laboratory certification and accreditation processes; Acts as technical consultant for clients as necessary. Acts as technical consultant for laboratory operations as necessary. Responsible for appointing alternates for critical laboratory positions when necessary. Operations Director The Operations Director manages and directs the analytical production departments of the laboratory. Reports directly to the Laboratory Director and assists in determining the most efficient instrument utilization. Continuously assess and improve the production throughput of departments; Continuously assess production capacity and improves capacity utilization; Continuously assess turnaround time and addresses any problems that may hinder meeting the required and committed turnaround time from the various departments; Oversees that sufficient instrumentation, personnel and supplies are available to realize production goals; Oversees that scheduled instrument maintenance is completed; Evaluates utilization of supplies for efficiency improvements; Ensures all production departments are adhering to all relevant aspects of the quality system; Oversees that all quality parameters related to projects are within method and client specified requirements; Responsible for the validity of analytical data and overall legal defensibility of data; Monitors the level of internal/external non-conformances for all production departments and implements preventive or corrective action when necessary. Monitors and improves the training of all production personnel in cooperation with the Department Managers; Acts as technical consultant for clients as necessary. nc on tro 2.2.2 & lle E N V I R O N M E N T A L d O I L F I E L D Quality Director The Quality Director designs and oversees the Quality System and Quality Assurance Program, and maintains any certifications thereto. Reports directly to the Laboratory Director and has full authority in aspects of laboratory activities related to quality. Responsible for acquisition and maintenance of laboratory certification; Maintains and updates the Quality System Manual; Designs, maintains and monitors all other components of the Quality System, including, but not limited to: o Corrective & Preventive Action System (CAPA); o Document Control System; o Demonstration of Capability for methods, equipment and personnel; o Control Chart evaluation and Control Limit Updates; o Orientation & Training Program; U 2.2.3 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 11 of 94 Rev 18 – JULY 2014 C O M P L I A N C E, I N C. o Management Review; o Change Management System; o Proficiency Testing; o Internal Auditing; o Continual Improvement. Responsible for all laboratory and analytical QA/QC requirements & procedures; Ensures laboratory Quality System requirements correlate with regulatory and client requirements; Responsible for external audit responses and defines or acts as a consulting resource for required corrective actions; Notifies laboratory management of deficiencies; Serves as a technical resource for QA matters; Trains personnel in quality procedures. Technical Director The Technical Director is responsible for all technical aspects of laboratory function, including instrumentation, analytical production, method development, improvements, regulatory and project compliance issues. Investigation of equipment technology and regularly reports/recommends to upper management laboratory apparatus status and needed improvements or updates; Determines the need for new production services and researches available methods. Determines the equipment and personnel needed to perform development. Oversees development and installation of new laboratory methods and equipment; Responsible for content maintenance of the LIMS system; Serves as a technical resource for current and future client base, and for major projects, as necessary; Ensures the laboratory remains current with relevant testing regulations and provides any technical training as required; Attends client or industry meetings where a laboratory technical representative is beneficial; Works with Business Development as a technical resource for the preparation of contract and bid proposals, as necessary; Reviews all aspects of SAPs, QAPPs, work plans, contracts and bids to provide feedback, alternative solutions as necessary, and communicates with Operations and Quality as needed to ensure project/client specific requirements are met; Supports Quality and Operations by providing technical solutions and input as appropriate for laboratory procedures, data quality issues, data validation, corrective actions and continuous improvement; U nc on tro 2.2.4 & d E N V I R O N M E N T A L lle O I L F I E L D 2.2.5 Project Manager Responsible for the final review of sample results and related quality control; Ensures that all quality parameters related to projects are within method and client specified requirements; Compiles result packages and approves analytical reports issued by the laboratory; 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 12 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. Works with Business Development as a resource for the preparation of bid proposals, as necessary; Acts as primary contact and in-house advocate for clients. Department Manager Responsible for the daily laboratory operation and adherence to quality standards; Supervises and trains chemists and other personnel within the analytical group; Verifies chain-of-custody and assures that appropriate analyses are performed within required ‘holding’ and ‘turn-around’ times; Responsible for secondary review and approval of analytical raw data; Reports any QC problems and performs necessary corrective actions to restore quality control. Submits systematic corrective action reports to the Quality Director; Prepares and maintains logbooks and documentation of department activities; Responsible for the content and accuracy of department documents; Schedules and performs instrument validation, calibration and preventive maintenance; Monitors and evaluates performance of preventive and corrective maintenance on analytical and support equipment. Instructs personnel in proper procedures for maintenance and related documentation as necessary. 2.3 DATA INTEGRITY, ETHICS & GENERAL TRAINING 2.3.1 ORIENTATION TRAINING – New employees are given an orientation upon arrival. Standard Operating Procedures (SOPs) for the laboratory Health and Safety Plan, Data Integrity and Ethics, Client Confidentiality, and Corrective Action Preventive Action (CAPA) are included in this orientation. All SOPs have training verification forms as part of the document, and these forms are filled out and maintained in the employee’s training file. on tro lle d 2.2.6 nc DATA INTEGRITY is the result of the processes that together assure valid data of known and documented quality. OEC management emphasizes integrity procedures by providing ethical and complete training for a position before allowing any employee to handle client samples. U It is necessary that employees understand that any infractions of the laboratory data integrity procedures will result in an investigation that could lead to very serious consequences such as immediate termination, or civil/criminal prosecution. New employees are required to read the Data Integrity and Ethics procedures and complete the associated Training Verification Form(s). Signatures on these forms are used to document the employee’s understanding and obligation to data integrity. Training records regarding data integrity and ethics are signed and dated by senior management. Data integrity procedures and evidence of inappropriate actions are reviewed annually through regularly scheduled internal audits or periodically through in-depth data or records review and are updated by management. 2.3.2 REPORTING INFRACTIONS – Employees can confidentially report ethic and data integrity issues by having (1) unrestricted access to senior management, (2) the assurance not to be treated unfairly for reporting ethics and data integrity breaches, and (3) anonymous reporting. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 13 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d Any potential data integrity issue is handled confidentially until a follow-up evaluation, full investigation, or other appropriate actions have been completed and the issues clarified. Inappropriate activities are documented, including disciplinary actions, corrective actions, and notifications of clients, if applicable. These documents are maintained for a minimum of 5 years. ANALYTICAL TRAINING – Oilfield Environmental & Compliance, Inc. allows only trained personnel to perform specific tasks in the laboratory. Proper training documentation includes a completed training form and a completed Initial Demonstration of Capability (IDoC). All employees are properly trained before they are assigned tasks that can affect data quality. IDoCs must be performed whenever there is a new analyst or a significant change in the analytical instrumentations. Proficiency is demonstrated by preparing and analyzing four replicates of Quality Control Check with recovery results within 70-130% or current laboratory defined control limits and RPD ≤ 20%. Management assumes the responsibility to assure personnel are trained and necessary records of training are kept on-file. tro 2.3.3 lle Senior Management will determine the need for an investigation of data integrity issues. Allegations will remain confidential to the extent necessary. All documentation for investigations of an inappropriate data integrity activity shall include notifications of clients, corrective actions taken, and any disciplinary actions involved. on Upon completion of orientation, the supervisor of the new employee will oversee the training of specific tasks in the laboratory. U nc The initial training for a new task will contain the following steps: a) All documentation involved with a new and unfamiliar task will be read and understood by the trainee. b) Instruction in the proper use of all equipment utilized in the task the trainee is learning. c) Instruction in the location of all necessary reagents required and proper techniques for measuring and preparing these reagents. d) Instruction in the proper procedure for tasks assigned including any prep work, if needed. e) Instruction for all quality control procedures for the task assigned. f) Instruction in all safety procedures for the task assigned. g) Training will be under the direct supervision of the supervisor or senior analyst. During the training period, the trainee may sign laboratory notebooks or logbooks, but the senior analyst or supervisor that is responsible for the data generated must cosign these records. h) The trainee will demonstrate proficiency in the new task before they can operate independently. This demonstration for a test method is accomplished by the completion of a demonstration of capability. Additionally the supervisor or senior analyst must sign the training form to show approval of competency. i) Each step of the training process is documented. j) Management will determine on-going training by assessment of the company’s need for training for new equipment or new positions or for cross training for existing positions. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 14 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. SECTION 3 – QUALITY ASSURANCE FUNCTIONS d The Oilfield Environmental & Compliance, Inc. (OEC) Quality System is documented in this Quality System Manual and associated quality system documents. Together they describe the policies, objectives, principles, responsibilities, accountability, and implementation plan of the organization for ensuring quality in its work processes and services. lle 3.1 QUALITY POLICY & OBJECTIVES The quality policy is signed and dated as a component of this manual, and is issued under the authority of the highest level of laboratory management, which demonstrates management’s commitment to integrity, ethics, the quality system and associated standards. All of the OEC objectives and policies are documented and the laboratory personnel are required to know and implement them in their work. tro Quality Policy – At Oilfield Environmental & Compliance, Inc. (OEC) the purpose of the quality control program is to produce data of known quality that meets the requirements of standard analytical methods and client needs. The objective of the quality assurance activities is to provide a system of evaluation of analytical data throughout operations, and to have quality control data that will define analytical results in terms of accuracy, precision, completeness and defensibility. Our policy is a dedication to provide quality environmental testing by upholding the highest quality standards in a professional and ethical manner. This dedication requires ongoing commitment and continually improves the quality of our work. on Quality Objectives – Objectives are achieved by performing quality assurance with every group of samples analyzed. The quality assurance is verified by checking sample duplicates, spikes, spike duplicates, laboratory control samples and blanks. In addition, surrogate recoveries are measured if applicable to the method. The quality control data generated with the samples is usually supplied to the client with standard analytical reports. The quality of data generated is confirmed by its assessment against the following objective parameters: nc Accurate – The degree of accuracy is determined by the agreement between an observed value and an accepted reference or true value. Accuracy is ensured by the adherence to quality handling protocols and use of dual source certified reference materials for all possible methodologies. Accuracy is monitored through the performance of quality control check samples, matrix spikes, laboratory quality control spikes, and surrogate/internal standard spikes. U Precise – The degree of precision is determined by the difference in resultant value of two identically prepared items. Precision is ensured by adherence to protocols for replicate analyses. Precision is monitored by the performance of sample and/or field duplicates, matrix spike and control spike duplicates, and the subsequent calculation of relative standard deviation (RSD) or relative percent difference (RPD). Representative – The degree of representation is expressed by how accurately and precisely a point defines the mean characteristics of a population, parameter variations at a specific sampling point, or an environmental condition within a defined boundary. Proper representation is ensured by adherence to proper sample treatment protocol including EPA approved methodologies, adherence to holding times and analysis of field duplicate samples. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 15 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d Complete – The degree of completion is determined by the amount of valid data returned from any sampling set compared to the expected amount under normal conditions. Completeness is ensured by adherence to all quality protocols for every sample received. OEC makes a concerted effort to provide the most complete resultant data possible for every sampling set. lle Comparable – The degree of comparability is determined by the precision of one data set to another. Comparability is ensured by adherence to standard operating procedures and consistent detection levels. Detection levels are evaluated annually to provide documented proof of limit appropriateness. External comparability is ensured by the use of common reporting units and general reporting protocols. 3.2 CHANGE MANAGEMENT tro Defensible – The degree of defensibility of a specific data set is measured by the completeness of documentation and traceability to certified standards for comparison. OEC strives to provide the best quality for our clients and as such, all samples are documented and treated as if their results will be scrutinized for legal purposes. on OEC maintains a change control system that encompasses all critical processes to the laboratory. This includes new entries or changes to LIMS, equipment, staff, documents (forms & records), methods (external documents), or Standard Operating Procedures (SOPs). The SOP for Change Management defines the change procedures for each type of laboratory critical function. nc All changes made within the laboratory are performed in such a manner as to fully document all components of the change, fully train all affected personnel before a change is put into effect, and verify all necessary approvals prior to making changes. Obsolete documents or references are removed as soon as a change goes into effect to minimize the possibility for error or confusion. 3.3 DOCUMENT AND RECORD MANAGEMENT U To demonstrate that quality has been achieved, OEC maintains a document management system that includes distributing, reviewing, modifying and controlling all text. This management system includes both current and obsolete documents. 3.3.1 Controlled Documents are uniquely identified, issued, tracked and kept current as part of quality management. Many of the controlled documents are also approved documents which means they need to be signed and dated. All controlled documents are identified by such methods as issued date, revision number, page number, total number of pages or a mark indicating the end of document and signature of approving authority. Approved copies of documents are available in the appropriate areas of the laboratory. Controlled documents are distributed by the Quality Director or Department Managers. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 16 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. 3.3.1.1 OEC retains documents that are both internal and external. A master list of controlled internal and external documents is maintained by the Quality Director. The list is updated periodically. lle d a) Internal documents include SOPs, QC files, Client folders, logbooks, forms, safety manuals and the Quality System Manual. b) External documents include reference methods and standards, instrument user manuals, certificates of analysis and certificates of traceability. tro 3.3.1.2 Changes may be performed by handwritten modification to a hard copy document, on a temporary basis, with a date and identifier (initials) accompanying the change. When changes are necessary, the obsolete documents are removed. Changes made to electronic documents must be accompanied by a change tracking function. Amendments to documents are incorporated into a new revision and reissued as soon as practicable. Obsolete Documents – All invalid or obsolete documents are removed, and except for the archived copy, destroyed. This will prevent unintended use. Obsolete documents retained for legal use or historical knowledge preservation are appropriately marked and stored in the OEC storage area and kept for a period of ten years. 3.3.3 Standard Operating Procedures (SOPs) are documents that give a detailed description of how laboratory processes may be accurately reproduced. They are used to ensure consistency of application of common procedures. There are two types: 1) test method SOPs, which have specifically required details, and 2) general use SOPs that document the more general organizational procedures. Copies of all SOPs are accessible to all personnel. Each SOP indicates the effective date, the revision number, and the signature(s) of the Laboratory Director, the Quality Director and when applicable the Department Manager and method reference. A list of representative OEC SOPs can be found in Appendix B. nc on 3.3.2 Records are a subset of documents. Records may be on any form of media, including electronic and hard copy. Records allow for the historical reconstruction of laboratory activities related to sample handling and analysis. Oilfield Environmental & Compliance, Inc. (OEC) maintains a record system appropriate to its needs, records all laboratory activities, and complies with applicable standards or regulations as required. U 3.3.4 3.3.4.1 Records of all procedures to which a sample is subjected while in the possession of the laboratory are kept for a period of ten years. OEC retains all original observations, calculations and derived data, calibration records, and a copy of the test report for a minimum of ten years. The laboratory maintains a record management system for control of laboratory notebooks, instrument logbooks, standards logbooks, and records for data reduction, validation, storage and reporting. 3.3.4.2 Records, including electronic records, are easy to retrieve, legible, and protected from deterioration or damage; held secure and in confidence; and are available to accrediting 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 17 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. authorities for a minimum of ten years. All electronic records are backed-up and placed off site. Access to protected records is limited to laboratory management or their designees to prevent unauthorized access or amendment. d 3.3.4.3 In the event that the OEC transfers ownership or goes out of business, records are maintained or transferred according to the clients’ instructions. CORRECTIVE & PREVENTIVE ACTION (CAPA) 3.4.1 PREVENTIVE ACTION – At OEC, preventive action eliminates or minimizes non-conformances and incorrect data through scheduled preventive maintenance on equipment and through the review process. lle 3.4 tro Preventive action includes, but is not limited to, review of QC data to identify quality trends, regularly scheduled staff quality meetings, annual budget reviews, managerial reviews, and other actions taken to prevent problems. All employees have the authority to recommend preventive action procedures, however management is responsible for implementing preventive action. CORRECTIVE ACTION is the action taken to eliminate the causes of an existing nonconformity, defect, or other undesirable situation in order to prevent recurrence (NELAC, 2003). on 3.4.2 nc 3.4.2.1 POLICY – All deficiencies that occur in the OEC laboratory are considered serious and remedial action is taken immediately. This includes data quality, systematic problems, instrument failures or safety practices. Corrective action taken is appropriate for the magnitude of the problem and the degree of risk. U 3.4.2.2 PROCEDURE – The individual that is initially aware of a problem is responsible for initiating corrective action. All deficiencies are investigated and a corrective action plan developed and implemented if determined necessary. a) Selection and Implementation of Corrective Actions – Once a non-conformance is noted, the first action is an investigation to determine the origin of the problem. A Corrective Action Report (CAR) is initiated (See SOP-Corrective Action Preventive Action [GEN-CAPA]) listing cause of problem and possible solution. It is then submitted to the Quality Director to receive a unique number and recorded in the CAPA system. The Quality Director and Department Manager will determine the corrective action to be taken, and the Department Manager will implement the corrective action. b) Monitoring of Corrective Action – The Department Managers will monitor implementation and results of the corrective action. The Quality Director will track, catalog and review the corrective action to assess effectiveness. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 18 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d 3.4.2.3 TECHNICAL CORRECTIVE ACTION – Sample data associated with a failed quality control is evaluated for the need to be reanalyzed or qualified. When quality control results are unacceptable, all pertinent information is documented on a CAR and submitted with raw data for review. lle a) The analyst is responsible for initiating and recommending corrective actions. Analysts routinely implement corrective actions for data with unacceptable QC measures. First level correction may include re-analysis for obvious cause without further assessment. If the test method SOPs addresses the specific actions to take, they are followed. Otherwise, corrective actions start with assessment of the cause of the problem. tro b) The Department Manager will review corrective action reports and suggest improvements, alternative approaches, and procedures where needed. c) If the data reported are affected adversely by the nonconformance, the client is notified in writing. The discovery of a non-conformance for results that have already been reported to the client must be immediately evaluated for significance of the non-conformance, its acceptability to the client, and determination of the appropriate corrective action. nc on 3.4.2.4 POLICY FOR EXCEPTIONALLY PERMITTING DEPARTURES FROM DOCUMENTED POLICIES AND PROCEDURES – OEC allows the release of non-conforming data only with approval on a case-by-case basis by the appropriate Department & Project Manager. Where additional expertise is required, approval may be necessary from Senior Management. Planned departures from procedures or policies do not require audits or investigations. Examples of exceptions would be insufficient sample volume, expired holding time, or sample data not affected by the results. Permitted departures for non-conformances are fully documented and the reason for the departure along with qualification for acceptance is included with report data given to the client. CONTROL OF NON-CONFORMING WORK NON-CONFORMING WORK is work that does not meet acceptance criteria or requirements. Non-conformances can include unacceptable quality control results departures from standard operating procedures or test methods. Requests for departures from laboratory procedures are approved by the Laboratory Director and documented. U 3.5 3.5.1 OEC policy for control of non-conforming work is to identify the non-conformance, determine if it will be permitted, and take appropriate action. All employees have the authority to stop work on samples when any aspect of the process does not conform to laboratory requirements. 3.5.2 The procedure for investigating and taking corrective action of non-conforming work is described in Section 3.4.2 Corrective Action. Employees should immediately notify their 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 19 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d Department Manager of any non-conformance. The Department Manager evaluates the significance of the nonconforming work and takes corrective action immediately. The client is notified if their data has been impacted. The Department Manager authorizes the resumption of analysis on all non-conformance work. METHOD VALIDATION Oilfield Environmental & Compliance, Inc. (OEC) ensures the quality of its analysis by using test methods approved by EPA and other industry-recognized analytical methods. OEC also guarantees quality analysis by having all analysts demonstrate capability of performing the test methods that they are assigned and that all methods are validated before being put to use. Refer to Section 5.5 (References for Analytical Methods) for a source listing of reference methods. 3.6.1 Demonstration of Competency (DoC), Initial & Continuing – OEC confirms that it is capable of generating data of acceptable accuracy and precision on all methods before employing them. This is accomplished by having all analysts complete a Demonstration of Competency to establish ability to perform the methods. tro lle 3.6 Initial Test Method Evaluation – For chemical analyses, the Initial Test method evaluation involves the determination of the Method Detection Limits (MDL), confirmation of the Reporting Limit (RL, also known as PQL: Practical Quantitation Limits), an evaluation of precision and bias, and an evaluation of the selectivity of the method. Additional studies may be required dependent on the specific instrumentation and method. The SOP for Equipment Validation, Calibration & Maintenance [GEN-EVCM] describes this process in detail. nc 3.6.2 on A DoC is performed for each analyte whenever the method, analysts, analytes, or instrument type is changed. The DoC is documented for each SOP (test method) and matrix performed. These records are maintained in the training files for each analyst. The Department Manager certifies that staff members in their area of expertise are trained and authorized to perform all tests for which we are accredited by signing the SOP training form. U 3.6.2.1 MDL – The method detection limit (MDL) is the minimum concentration of a target analyte that can be measured and reported with 99% confidence that the value is above zero. MDLs must be updated on an annual basis and the studies are kept on file in the laboratory. Analytical reports requiring ‘J’ flag reporting will display the MDL value for a particular analyte with values between the MDL and RL provided as estimates. 3.6.2.2 RL & PQL – After the MDL is determined, a reporting limit (RL), or practical quantitation limit (PQL), must be established. The RL calculation may vary depending on the type and sensitivity of a particular method. An example of a standard RL calculation is as follows: RL = standard deviation of 7 replicates * 10. The lowest calibration standard is equal to the RL. The RL will always be greater than the MDL. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 20 of 94 Rev 18 – JULY 2014 O I L F I E L D & C O M P L I A N C E, I N C. Precision and Accuracy – The OEC objective for precision and accuracy is to equal or exceeds the precision and accuracy defined by the analytical methods on similar samples. Data quality objectives for accuracy and precision are method specific, and are defined in the SOP for each method. d 3.6.3 E N V I R O N M E N T A L lle PRECISION is the degree to which a set of observations or measurements of the same property, obtained under similar conditions, conform to themselves. Precision is usually expressed as standard deviation, variance, or range, in either absolute or relative terms. Laboratory control limits are established for measurements of laboratory duplicates, duplicate laboratory control samples and matrix spike duplicates for quantitative tests when applicable. 3.7 MEASUREMENT TRACEABILITY tro For ACCURACY, the laboratory control limits are established for measurements of external standards, laboratory control samples, matrix spike samples and internal performance evaluation check samples for quantitative tests. Accuracy is ensured for all possible methods using two separate standard sources. When these sources differ in exceedance of method specification a third source must be obtained to act as the decisive reference. nc on Measurement quality assurance comes in part from traceability of standards to certified materials. In general, calibration is performed with at least five levels of concentration to cover the working range. All equipment used that affects the quality of test results are calibrated (1) prior to equipment being put into service, (2) annually or more frequently if specified by the method, (3) if the analytical response has changed beyond method tolerance, (4) whenever there is a significant modification of the instrument or the method. The calibration standards are traceable to national standards of measurement or manufacturers’ certification. U Measurements from laboratory equipment provide the uncertainty required by test method or client. If traceability of measurements to SI units is not possible or not relevant, evidence for correlation of results through inter-laboratory comparisons, proficiency testing, or independent analysis is provided. All equipment that affects the quality of test results are calibrated according to the minimum frequency suggested by the manufacturer, by regulation, by method, or as needed. Clients can verify that required uncertainty is achieved by reviewing the internal quality control data, if requested. 3.7.1 Reference Materials where commercially available, reference materials are traceable to national standards of measurement, or to Certified Reference Materials, usually by a Certificate of Analysis. Internal reference materials, such as working standards or intermediate stock solutions, are checked as far as technically and economically possible. a) Stock standard solutions are prepared from neat substances or purchased from vendors with certified analyte concentrations. New stock standard solutions are verified against existing standards prior to use. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 21 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. b) Standard preparation is documented in analyst logbooks. Results are stored with calibration data for the method. lle d c) Working standards are verified against certified standards from a second vendor, a different lot or a different preparation from neat substances. Working standards are prepared from stock standard solutions by volumetric dilution with method-specific solvents. When these sources differ in exceedance of method specification a third source must be obtained to act as the decisive reference. d) Specific working standard concentrations and diluents are documented in laboratory SOPs for each method. Handling and Storage of Reference Standards and Materials The laboratory manages and transports reference standards and materials in a way that protects their integrity. Reference standard and material integrity is protected from incompatible materials by being kept in separate areas. The integrity is also protected by minimizing exposure to degrading environments or materials. Reference standards and materials are stored according to manufacturer’s recommendations and separately from working standards or samples. 3.7.3 Labeling & Documentation of Reference Standards, Reagents, and Materials Reference standards and materials are tracked from purchase, receipt, and storage through disposal. Expiration dates are the date on the bottle or six months from date bottle is opened, whichever comes first. on tro 3.7.2 U nc 3.7.3.1 Records for all standards, reagents, reference materials, and media include: a) manufacturer/vendor name (or traceability to purchased stocks or neat compounds) b) manufacturer’s Certificate of Analysis or purity c) date of receipt d) reference to the method of preparation e) date of preparation f) recommended storage conditions g) expiration date after which the laboratory shall not use. h) preparer’s initials (if prepared) 3.7.3.2 In methods where the purity of reagents is not specified, analytical reagent grade is used. If the purity is specified, that is the minimum acceptable grade. 3.7.3.3 All containers of standards, reagents, or materials, whether original or prepared, are labeled with an expiration date. 3.7.3.4 All containers of prepared standards and reference materials have a unique identifier, preparation name, expiration date, preparer’s name and preparation date. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 22 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. 3.8 d 3.7.3.5 Standard preparation records are kept in the LIMS system and provide traceability to purchased stocks or neat compounds, reference to the method of preparation, date of preparation, expiration date, and preparer's initials. AUDITS Internal Audits – At OEC the review of the appropriateness and adequacy of the Quality Assurance Program is ongoing. To identify and contain problems with the Quality Program, reviews may be done monthly, quarterly and at the least, annually. Personnel may not audit their own activities except when it can be demonstrated that an effective audit will be carried out. tro 3.8.1 lle AUDITS measure laboratory performance and verify compliance with accreditation/ certification and project requirements. Audits specifically provide management with an on-going assessment of the quality system. They are also instrumental in identifying areas where improvement in the quality system will increase the reliability of data. OEC is subject to both internal and external audits. on 3.8.1.1 Annually, the laboratory prepares a schedule of internal audits to be performed during the year. These audits verify compliance with the requirements of the quality system, including analytical methods, SOPs, ethics policies, and other laboratory policies. The Quality Director (or other members of Laboratory Management) will plan and execute the scheduled audits and reviews. All audits, audit findings and any corrective action taken as a result of an audit will be documented. 3.8.1.2 Notification of clients for events that cast doubt on the validity of the results is completed within 24 hours. nc 3.8.1.3 Review of the auditing process is done to ensure that corrective actions that were needed were implemented and effective. 3.8.2 External Audits – It is OEC’s policy to cooperate and assist with all external audits, whether performed by clients or an accrediting authority. All external audits are fully documented and tracked to closure. U 3.8.2.1 Management ensures that all areas of the laboratory are accessible to auditors as applicable and that appropriate personnel are available to assist in conducting the audit. 3.8.2.2 Any findings related to an external audit follow corrective action procedures. 3.8.2.3 Management ensures that corrective actions are carried out within the timeframe specified by the auditor(s). 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 23 of 94 Rev 18 – JULY 2014 O I L F I E L D 3.9 E N V I R O N M E N T A L & C O M P L I A N C E, I N C. MANAGEMENT REVIEW lle the suitability of policies and procedures; reports from managerial and supervisory personnel; the outcome of recent internal audits; corrective and preventive actions; assessments by external bodies; the results of inter-laboratory comparisons or proficiency tests; changes in the volume and type of the work; client feedback; complaints; and, other relevant factors, such as quality control activities, resources and staff training. tro a) b) c) d) e) f) g) h) i) j) d In accordance with a predetermined schedule and procedure described herein, the laboratory management periodically and at least annually conducts a review of the laboratory's quality system and environmental testing activities to ensure their continuing suitability and effectiveness, and to introduce necessary changes or improvements. The review shall take account of the following: Findings from management reviews and the actions or findings that arise from them are recorded in the minutes and CAPA system as necessary. The management ensures that those actions are carried out within an appropriate and agreed timeframe. Laboratory management evaluates actions from previous reviews in each meeting and maintains records of any further findings or actions as necessary. 3.9.2 MANAGEMENT REVIEW REQUIREMENTS on 3.9.1 nc 3.9.2.1 Review Input – The input to management review shall include information on a) results of audits, b) customer feedback, c) process performance and product conformity, d) status of preventive and corrective actions, e) follow-up actions from previous management reviews, f) changes that could affect the quality management system, and g) recommendations for improvement. U 3.9.2.2 Review Output – The output from the management review shall include any decisions and actions related to a) improvement of the effectiveness of the quality management system and its processes, b) improvement of product related to customer requirements, c) resource needs, and d) new findings and actions, as necessary 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 24 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. SECTION 4 – CLIENT SERVICE FUNCTIONS 4.1 CLIENT CONFIDENTIALITY lle d Oilfield Environmental & Compliance, Inc. (OEC) works in partnership with clients to monitor the laboratory’s performance in executing the client’s requests. Each request is reviewed to determine the nature of the request and the laboratory's ability to comply with the request within the confines of prevailing statutes and/or regulations without risk to the confidentiality of other clients. The laboratory confidentiality policy is to not divulge or release any information to a third party without proper authorization. All electronic data (storage or transmissions) are kept confidential, based on technology and laboratory limits, as required by client or regulation. 4.2 tro For further details, refer to the SOP for Client Interaction, Confidentiality & Complaint Handling [ADMClient]. REVIEW OF REQUESTS, TENDERS AND CONTRACTS on Senior Management and specifically the Technical Director are responsible for the review of all new work for Oilfield Environmental & Compliance, Inc. (OEC). The Technical Director determines if it has the necessary accreditations and resources, including schedules, equipment, deliverables, and personnel to meet the work request. By using the review process, the management is able to determine if it has adequate resources to meet the requirements of the client. The contract will specify clearly defined requirements and test methods. nc The client is informed of the results of the review. Business Development or Management will inform the client of any deviation from the contract including the test method or sample handling processes. All differences between the request and the final contract are resolved and recorded before any work begins. It is necessary that the contract be acceptable to both the laboratory and the client. U When the client needs amendments to the original contract, the review process is repeated. The participating personnel are given copies of the amendments. 4.3 COMPLAINTS Oilfield Environmental & Compliance, Inc. values its customers and provides them with high-quality analytical testing with the shortest possible turn-around time. OEC reviews all complaints and 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 25 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. determines appropriate action as quickly as possible to assure the customer that complaints are addressed and corrected. This includes requests to verify results or analytical data. 4.4 lle d All customer complaints are documented by the person receiving the complaint and referred to the appropriate Management and Quality Director to be addressed. If it is determined that a complaint is without merit, it is documented, and the client is contacted. If it is determined that the complaint has merit, a corrective action is initiated. See Section 3.4.2 of this manual or the SOP for corrective actions for procedure details. SUBCONTRACTING OF TESTS tro A SUBCONTRACT LABORATORY is defined as a laboratory external to Oilfield Environmental & Compliance, Inc. (OEC) that performs analyses for this laboratory. When subcontracting analytical services, OEC assures work requiring accreditation is placed with a state of California accredited laboratory or one that meets applicable statutory and regulatory requirements for performing the tests. A list of subcontractors and their test methods with certifications is maintained. on OEC notifies the client of the intent to subcontract the work when presenting the contract by stating what methods the laboratory does not perform and need to be subcontracted. When possible, the laboratory gains the approval of the client to subcontract their work prior to implementation of a specific work order, customarily through electronic mail. nc The laboratory performing the subcontracted work is identified in the final report. OEC assumes responsibility to the client for the subcontractor’s work, except in the case where a client or a regulating authority specified which subcontractor is to be used. 4.5 REPORTING OF RESULTS The result of each test carried out at Oilfield Environmental & Compliance, Inc. is reported accurately, clearly, unambiguously, objectively and complies with all specific instructions contained in the test method. U The laboratory report should contain all necessary information that is pertinent, including but not limited to: a) all results from analyses performed. b) any discrepancies that may have occurred. 4.5.1 Analytical Reports – Each test report generated contains the following information (unless not required by the client): a) a title b) the name and address of the laboratory c) the name and address of the client if applicable 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 26 of 94 Rev 18 – JULY 2014 d) e) f) g) h) i) & C O M P L I A N C E, I N C. the identification of the test method used an unambiguous identification of the sample(s), including the client identification code the date of sample receipt the test results with failures identified and units of measurement the name, function, and signature of the person authorizing the test report, and the date of issue at the laboratory’s discretion, a statement that the report shall not be reproduced except in full without written approval of the laboratory qualification of results with values outside the working range lle j) E N V I R O N M E N T A L d O I L F I E L D Quality Control Report – A QC report is generated with each sample delivery group, when applicable or desired by client, and contains the following: a) Method Blank Report which includes results of analyte found in the MB and detection limit for the analyte b) Laboratory Control Sample Report that includes percent recovery of analyte in the LCS, relative percent difference of LCS/LCSD and control limits for percent recovery and RPD. c) Matrix Spike Report that includes percent recovery of analyte in the MS, relative percent difference of MS/MSD, and control limits for percent recovery and RPD. d) Duplicate Report that includes results of analyte found in the sample duplicate, the dilution factor and detection limit for analyte. 4.5.3 Case Narrative – A case narrative with a full explanation and all the necessary documentation will be included in the report where necessary, unless excluded from client reporting requirements. Examples narration prompts include, but are not limited to: a) the chain-of-custody has not been properly administered b) the sample cannot be analyzed because of interference c) quality control results are in nonconformance 4.5.4 Electronic Transmission of Results – All test results transmitted by telephone, fax, telex, e-mail, or other electronic means comply with the requirements of this Quality System Manual and associated procedures to protect the confidentiality and proprietary rights of the client. nc on tro 4.5.2 Amendments to Test Reports – Amended test reports may be handled in two ways: a) if the correction is for anything except actual test results, the report will look the same as the original; a note will be included explaining the correction. b) if a new report is issued because of new test results than the new report will be titled “Revised”. U 4.5.5 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 27 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. SECTION 5 – LABORATORY FUNCTIONS 5.1 ACCOMMODATIONS & ENVIRONMENTAL CONDITIONS lle d Oilfield Environmental & Compliance, Inc. (OEC) operates a commercial environmental analytical laboratory that provides high-quality analytical testing services with a minimum turn-around time. Access to environmental test areas is limited to OEC personnel. Laboratory workspace is arranged to prevent contamination of samples and is kept organized and clean to support environmental testing. Interference from environmental conditions will result in testing being stopped or reanalyzed to assure quality data results. tro OEC laboratory and administrative areas occupy 16,670 square feet of industrial space. The space is divided with separate rooms for administrative offices, sample receiving and storage, volatile analysis, semi-volatile analysis, semi-volatile preparation, metals analysis, metals preparation, oil and gas analysis and wet chemistry to ensure non-contamination of samples. In addition, sensitive laboratory areas are arranged so the flow of a positive-pressure secured air supply helps minimize contamination. U nc on FIGURE 5A – PREISKER LOCATION 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 28 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. U nc on tro lle d FIGURE 5B – ROEMER LOCATION 5.2 PURCHASING SERVICES AND SUPPLIES Oilfield Environmental & Compliance’s (OEC) suppliers for all their reagents and supplies are worldrenowned companies that include companies that are ISO certified. The laboratory has procedures in place for purchasing, receiving, and storage of supplies that affect the quality of environmental tests. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 29 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. Management reviews and approves the supplier of services and supplies and approves technical content of purchasing documents prior to ordering. 5.2.2 OEC purchases reagents and chemical standards for all its tests that conform to the specifications of the Committee on Analytical Reagents of the American Chemical Society. Other grades may be used, provided it is first ascertained that the reagent is of sufficient purity to permit its use without lessening the accuracy of the determination. Upon receipt, bottles are checked for breakage, leakage and expiration date. The certificate of analysis that accompanies the chemical is maintained on file and the chemical stored according to manufacturer’s specifications or for the test method SOP that the reagent will be used. 5.2.3 The purchase of services is primarily limited to annual calibration and maintenance of support equipment and is performed by representatives of the companies where the equipment was purchased. 5.3 SAMPLE MANAGEMENT tro lle d 5.2.1 on Laboratory analyses are performed to produce data representative of conditions when the sample was obtained. To ensure integrity, each sample processed at OEC is checked upon receipt, uniquely identified, stored and disposed of properly, and all relevant information is recorded. The laboratory has a sample acceptance policy that specifies the conditions of a sample upon receipt. The client is immediately notified if these conditions are not met. nc When samples are received at the laboratory, their condition is documented, they are given unique identifiers, and they are logged into the sample tracking system. The laboratory controls and monitors sample movement and usage between laboratory departments utilizing an Internal Chain-of-Custody (ICoC) system. The procedures for preservation checks, sample identification, sample logging, sample dispersal, and sample storage and disposal is found in the SOPs for SAMPLE LOGIN [GEN-LOGIN] & SAMPLE DISPOSAL [GEN-DISPOSAL]. EQUIPMENT U 5.4 5.4.1 (Refer to Appendix B for equipment list) General Equipment Requirements – Oilfield Environmental and Compliance employees operate and maintain a wide variety of analytical equipment for the performance of a variety of chemical analysis. All instruments are subject to preventive maintenance procedures per manufacturer instruction to minimize the occurrence of instrument failure or malfunction. All maintenance is documented in the appropriate laboratory record. 5.4.1.1 Only OEC personnel who are trained and have completed an IDoC are allowed to operate equipment. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 30 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. 5.4.1.2 All equipment is calibrated or checked before being placed into use to ensure that it meets laboratory specifications and the relevant standard specifications. d 5.4.1.3 Instructions and manufacturers manuals are available to laboratory staff to indicate the proper use and maintenance of equipment. lle 5.4.1.4 Equipment that is defective or outside specifications is clearly labeled as being out of service. Small support equipment such as thermometers would be immediately discarded. Support Equipment – Support equipment includes devices for weighing, measuring, heating or cooling standards or samples. These are also purchased from reputable companies and calibration and functionality are verified at the time of receipt. All support equipment is maintained in proper working order and records are kept of all repair and maintenance activities, including service calls. For further details refer to the OEC SOP: Small InstrumentSupport Equipment Calibration & Monitoring 5.4.3 Analytical Equipment – All equipment at OEC is properly maintained, inspected, and cleaned. Maintenance of analytical instruments and other equipment may include regularly scheduled preventive maintenance or maintenance on an as-needed basis due to instrument malfunction and is documented in Instrument Maintenance Logs, which become part of the laboratory’s permanent records. Initial and Continuing Calibration of each instrument is performed according to the test method SOP being carried out. 5.5 REFERENCES FOR ANALYTICAL METHODS 5.5.1 Test Methods for Evaluating Solid Waste: Physical/Chemical Methods, U.S. Environmental Protection Agency, SW-846, Third Edition (September 1986), Final Update I (July 1992), Final Updates II and IIA (September 1994), Final Update IIB (January 1995), and Final Update III (December 1996). nc on tro 5.4.2 Standard Methods for the Examination of Water and Wastewater, American Public Health Association, American Water Works Association, Water Pollution Control Federation, 18th Edition, 1992; 19th Edition 1995; 20th Edition 1999. U 5.5.2 5.5.3 Laboratory Procedures, Stationary Source Test Methods & Vapor Recovery Test Procedures; California Environmental Protection Agency Air Resources Board (CA-EPA ARB). 5.5.4 TPH & LUFT Manuals and Guidance 5.5.4.1 Leaking Underground Fuel Tank & Site Mitigation Unit Manual, Santa Barbara County Fire Department, Fire Prevention Division, January 2007. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 31 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. 5.5.4.2 Leaking Underground Fuel Tank Guidance Manual, California State Water Resources Control Board, September 2012. d 5.5.4.3 Draft Method for Total Petroleum Hydrocarbons and Total Organic Lead, Hazardous Materials Laboratory, California Department of Health Services, Berkeley, CA, February, 1988. Criteria for Identification of Hazardous and Extremely Hazardous Wastes, California Code of Regulations (CCR), Title 22, Division 4.5 5.5.6 HAZCAT: A System of Field Identification and Classification of Commonly Spill Materials, State of California, Division of Occupational Safety and Health, Department of Industrial Relations, September, 1986. 5.5.7 Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Center for Environmental Research and Development Office of Research Development US EPA; TO-14 & TO-15. 5.5.8 Clean Water Act (CWA) Analytical Test Methods, Code of Federal Regulations (CFR), Title 40 Part 136. 5.5.9 ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States. on tro lle 5.5.5 5.5.10 Gas Processors Association (GPA) Standards; 6526 East 60th Street, Tulsa, Oklahoma 74145, United States. 5.5.11 HACH Methods approved/accepted by the USEPA nc 5.5.12 South Coast Air Quality Management District (SCAQMD) Methods, Applied Science & Technology Division, Laboratory Services Branch. 5.5.13 Environmental Monitoring Systems Laboratory, Office of Research and Development, U.S. Environmental Protection Agency; Cincinnati, Ohio 45268. U 5.5.14 U.S. Environmental Protection Agency, Office of Water (4303T), 1200 Pennsylvania Avenue, NW, Washington, DC 20460 5.5.15 STATIC ACUTE BIOASSAY PROCEDURES FOR HAZARDOUS WASTE SAMPLES, Polisini & Miller, California Department of Fish and Game, Water Pollution Control Laboratory. 5.5.16 Standard Test Methods, NACE International, 1440 South Creek Drive, Houston, Texas 77084. 5.5.17 Test Method for Vapor Pressure of Reactive Organic Compounds in Heavy Crude Oil Using Gas Chromatography; David Littlejohn and Donald Lucas, Lawrence Berkeley National Laboratory, Berkeley, California; May 28,2002 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 32 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. QUALITY OF TEST RESULTS 5.6.1 Essential Quality Control Procedures – All essential quality control elements are collected and assessed on a continuing basis. The qualities of test results are recorded in such a way that trends are detectable, and where practicable, are statistically evaluated. There is a Standard Operation Procedure (SOP) for each test method that OEC uses. Each SOP has a section dedicated to the Quality Control criteria. This is often supplemented with quick-reference criteria in a table format. lle d 5.6 tro All laboratory personnel follow the quality control procedures specified in test methods. The most stringent of control procedures is used in cases where multiple controls are offered. If it is not clear which is the most stringent, the control mandated by test method or regulation is followed. on 5.6.1.1 To monitor the validity of environmental tests performed, review includes any one or combination of the techniques below: a) Utilizing certified reference materials and/or internal quality control using secondary reference materials; b) participation in proficiency testing (PT) programs; c) replicate testing using the same or different methods; d) retesting of retained samples; e) correlation of results for different characteristics of a sample. U nc 5.6.1.2 Written procedures to monitor quality controls, including acceptance criteria, are located in the test method SOPs, except where noted, and include such procedures as: a) use of laboratory control samples and blanks to serve as positive and negative controls for chemistry methods; b) use of laboratory control samples to monitor test variability of laboratory results; c) use of calibrations, continuing calibrations, certified reference materials and/or PT samples to monitor accuracy of the test method; d) measures to monitor test method capability, such as limit of detection, limit of quantitation, and/or range of test applicability, such as linearity; e) use of regression analysis, internal/external standards, or statistical analysis to reduce raw data to final results; f) use of reagents and standards of appropriate quality; g) procedures to ensure the selectivity of the test method; 5.6.2 Internal Quality Control Practices – Analytical data generated with QC samples that fall within prescribed acceptance limits indicate the test method is IN CONTROL. QC samples that fall outside QC limits indicate the test method is OUT OF CONTROL (non-conforming) and that corrective action is required or that the data be qualified. OEC QC procedures and QC limits are 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 33 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d included in test method standard operating procedures (SOPs), or where unspecified in the SOPs, are detailed elsewhere. All QC measures are assessed and evaluated on an on-going basis, so that trends are detected. Please refer to Appendix F, QC Data Evaluation Flowcharts for a more detailed description of general standard corrective actions followed by the laboratory. 1. Positive and Negative Controls such as: a) Blanks (negative) b) Laboratory control sample (positive) c) Reference Toxicants (positive) lle 5.6.2.1 The following general controls are used: tro 2. Selectivity is assured through: a) absolute and relative retention times in chromatographic analyses b) two-column confirmation when using non-specific detectors c) two different GC detectors d) use of acceptance criteria for mass-spectral tuning (found in test method SOPs); e) use of the correct method according to its scope assessed during method validation; U nc on 3. Consistency, Variability, Repeatability, and Accuracy are assured through: a) proper installation and operation of instruments according to manufacturer’s recommendations or according to the processes used during method validation b) monitoring and controlling environmental conditions (temperature, access, proximity to potential contaminants) c) selection and use of reagents and standards of appropriate quality d) cleaning glassware appropriate to the level required by the analysis. Cleaning procedures are provided in test method SOPs e) following SOPs and documenting any deviation, assessing for impact, and treating data appropriately f) testing to define the variability and/or repeatability of the laboratory results, such as replicates g) use of measures to assure the accuracy of the test method, including calibration and/or continuing calibrations, use of certified reference materials, proficiency test samples, or other measures 5.6.2.2 Acceptance or rejection criteria are created according to laboratory policy where no method or regulatory criteria exist. Acceptance criteria define the boundary for the appropriate response from laboratory personnel, such as corrective action, reporting with qualifiers, reanalysis, review, and others. 1. Test Method Capability is assured through: a) establishment of the method detection limits where appropriate b) establishment of the practical quantitation limits or reporting level c) establishment of the range of applicability such as linearity 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 34 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. d 2. Data reduction is assured to be accurate by: a) selection of appropriate formulae to reduce raw data to final results such as regression b) periodic review of data reduction processes to assure applicability Item Method Blank (MB) [Negative Control] Lab Control Sample (LCS) or Blank Spike (BS) & Duplicate (LCSD or BSD) [Positive Control, Accuracy & Precision(DUP)] Matrix Spike & Duplicate (MS/MSD) [Positive Control, Accuracy & Precision(MSD)] Sample Duplicate (DUP) [Precision] Surrogate spikes Frequency 1/batch Continuing Calibration Verification Method specific or determined by laboratory Per method requirement Method specific or determined by laboratory Per method requirement Method specific or determined by laboratory Per method requirement Method specific or determined by laboratory Per method requirement Method specific or determined by the laboratory on Initial calibration Verification Acceptance Criteria Method specific or reporting limit tro 1/batch lle 5.6.2.3 The following table summarizes the key elements of a quality control system for a laboratory performing chemical analyses. In addition to any instrument criteria, the essential validation for any sample batch includes a demonstration of Positive Control, Negative Control, Accuracy & Precision. Refer to Appendix F for assessment of each QC item and appropriate corrective actions. TABLE 5C ESSENTIAL QUALITY CONTROL ELEMENTS Start of each analytical run Method specific or determined by laboratory U nc 5.6.2.3.1 Method Blanks (MB) – A reagent or MB is prepared and analyzed with each batch of 20 or fewer samples of the same matrix. Sample batches may not exceed 24 hours. The volume of the blank should be approximately equal to the sample. Analysis of the blank verifies that method interferences caused by contaminants in solvents, reagents and equipment are known and minimized. Target analyte should be non-detected in a method blank, providing evidence of negative control for the batch. 5.6.2.3.2 Laboratory Control Samples (LCS) – Standard reference materials or LCS from an independent source are introduced periodically (at least once per batch during testing activity) into the testing scheme to evaluate testing procedure. Duplicate LCS (LCSD) may be analyzed in lieu of MS/MSD if necessary. The LCS provides evidence to evaluate laboratory positive control (detectable spike result), accuracy (spike recovery), and if an LCSD is performed, precision (relative percent difference between duplicates). 5.6.2.3.3 Matrix Spikes and Matrix Spike Duplicates (MS/MSD) – One sample in every batch (20 or fewer samples of similar matrix) is spiked in duplicate at a level, which provides a final concentration greater than or similar to the original concentration before dilution. This provides evidence to evaluate laboratory 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 35 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. accuracy (spike recovery) and precision (relative percent difference between duplicates). d 5.6.2.3.4 Sample Duplicate (DUP) – One sample in every batch (20 or fewer samples of similar matrix) is analyzed in duplicate. This provides evidence to evaluate laboratory precision (relative percent difference between duplicates). Data Review – Oilfield Environmental & Compliance, Inc. reviews all data generated in the laboratory for compliance with method, regulatory, laboratory and, where appropriate, client requirements. tro 5.6.3 lle 5.6.2.3.5 Surrogate Spikes – SURROGATES are substances with chemical properties and behaviors similar to the analytes of interest used to assess method performance in individual samples. Surrogates are added to all samples (in test methods where surrogate use is appropriate) prior to sample preparation or extraction. Surrogate recovery results are compared to the acceptance criteria as published in the mandated test method. on The analyst should perform primary data review by compiling the results of the above validation samples onto the appropriate laboratory records and LIMS system. The analyst electronically signs his work in LIMS and should sign and date his own records. Any handwritten correction must be crossed out with a single line and be dated and initialed. All method QC parameters are verified either on the instrument data system or in LIMS, and documented on a Data Review Checklist (DRCL) where appropriate. If the batch contains any QC issues, a corrective action report should be completed and submitted to the Department Manager with the raw data. nc The Department Manager or a qualified peer should perform secondary review by examining the raw data, verifying the QC compliance of each data set and approving the preliminary sample and QC results in the raw data file and LIMS. The reviewer should counter-sign and date (may be electronic or hard-copy) the logbooks and the raw data. Any QC problems should be noted in the batch case narrative or as a corrective action report. U Any corrective action or narrative must be reviewed and related samples validated as necessary by the Department Manager or Quality Director prior to Project Management review. Project Management performs the tertiary project-level review of all results and generates client reports. 5.6.4 Control of Data – All pertinent data that are subject to transcription, calculation, or other manual manipulation is checked in a systematic manner. All commercial software used at OEC is in an application range that is considered sufficiently validated for use in the laboratory, and is verified internally before use. OEC’s procedure to ensure that reported data is free from transcription and calculation errors, and all quality data has been calculated correctly, is to have all quality control data reviewed by the Analyst, Department Manager and Project Manager before being released to the client. Computers and software used for processing or storage are protected, maintained, and secured 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 36 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. through measures such as multiple backups, document controls, locked access, and control of the laboratory environment. U nc on tro lle d ACKNOWLEDGMENT: This manual was created with help from the INELA Template ver.1 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 37 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX A – CONTACT & QUALIFICATIONS OF PERSONNEL To contact your desired party, dial the OEC main number at (805) 922-4772 and either ask for them by name or if prompted for an extension, use as listed: Title Email Julius Carstens Laboratory Director [email protected] Mary Ann Long Operations Director [email protected] Carrie McCrillis Quality Director & Human Resources Rep. [email protected] x1101 Lisa Race Technical Director & Safety Officer [email protected] x1310 Direct: (805) 354-7302 Marissa Censullo Project Manager [email protected] x1111 Direct: (805) 354-7303 Meredith Sprister Project Manager [email protected] x1112 Direct: (805) 354-7304 Kristie Mikel Department Manager, Microbiology, Bioassay & Wet Chemistry [email protected] x1320 x1100 Direct: (805) 354-7301 x1201 lle tro on Drew Miller Phone d Name Department Manager, Volatile Organics [email protected] x1701 Department Manager, Metals & Instrumental Inorganics [email protected] x1300 Department Manager, Semi-Volatile Organics [email protected] x1501 Pete Alcocer Oil Production Operations Consultant [email protected] x1401 Brandon Ganster Oil Production – TAFT Operations Supervisor [email protected] Gracie Venegas* Client Services [email protected] x1301 Direct: (805) 354-7305 Cynthia Crawford* Accounting Coordinator [email protected] x1102 Danna Whiteaker* Accounting [email protected] X1103 Kevin Calcagno* Sales & Contracts Rep. [email protected] Direct: (805) 354-7306 John Hatzman* Sales & Contracts Rep. [email protected] Direct: (805) 354-7307 Parwinder Parmar U nc Dwain Zsadanyi Direct: (661) 847-8098 * Included for contact reference information only, qualifications not included 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 38 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Julius Carstens Laboratory Director (Page 1of 2) d QUALIFICATIONS I N C. lle Mr. Carstens has been the owner and primary operator of OEC since 1997. Prior to that, he acquired extensive experience in the environmental and oil production analytical fields through education and hands-on experience in both a laboratory and field environment. EDUCATION & CERTIFICATIONS tro B. S. Biochemistry, 1995, California Polytechnic State University, San Luis Obispo, CA B. S. Soil Science, 1995, California Polytechnic State University, San Luis Obispo, CA Registered Environmental Assessor (California Environmental Protection Agency. REA # 06476) OSHA HAZWOPER 8-hour Supervisor & 40-hour Trained (OSHA 29 CFR 1910.120) SECORP Industries Safety Class for H2S California Water Environment Association (Laboratory Analyst # 311) on EXPERIENCE 1997-Present U nc Laboratory Director- Mr. Carstens manages operations for the analytical laboratory and field service firm. He has over 20 years laboratory experience in the analysis of environmental samples and has worked on numerous field sampling projects during this time. Mr. Carstens has extensive experience in the areas of air, gas, soil/water, and petroleum analysis, EPA protocols, and field sampling. He is responsible for overall management of technical operations, technical consulting functions, personnel development and business operations including the direction of the financial and marketing departments. Mr. Carstens’ consulting responsibilities include advising clients of the appropriate sampling and analytical protocols primarily related to, air and oil testing. He is integrally involved in data interpretation with the clients on such projects. He has also participated in the development of new sampling and analysis protocols for the measurement of gas and petroleum characteristics. 1993-1997 Cirrus Environmental, Santa Maria, CA Soil & Chemist/Project Coordinator - Responsible as project coordinator for laboratory based projects. Performed chemical analysis for laboratory and coordinated specific organic and inorganic analyses. Provided client consultation to determine the analytical methods most appropriate for their project. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 39 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Julius Carstens 1990-1993 Cal Poly State University, San Luis Obispo, CA (Page 2of 2) d Laboratory Director I N C. lle Worked as a laboratory technician to determine the change in cation exchange of soils amended with synthetic organic polymers. Also worked on the bio-degradation rate of diesel fuel, gasoline, and motor oil, using in situ bacteria CO2 respiration rates. MONITORING PROJECTS - Limited scope of monitoring projects that Mr. Carstens has performed: tro Venoco Inc., South Ellwood Oil & Gas Facility, Santa Barbara, CA He performed sample design, equipment selection, and analytical methods, for the determination of petroleum and H2S odor being emitted by the loading of a petroleum barge. Sampling points and interval of sampling was determined while on the barge for a 48-hour period. This remote site was tested on two separate occasions during the loading of 75,000 barrels of crude oil. Over 60 samples were taken during each loading event. Results of C1-C6 hydrocarbons, fixed gases, and hydrogen sulfide, were available to the client within a 3-day period. nc on Torch Operating Co. HS&P Facility, Lompoc, CA Worked with Torch staff and Santa Barbara APCD to determine the accuracy of Del Mar Testing Unit located at HS&P. OEC provided a staff of technicians to gather 45 minute interval sampling from a produced gas stream. This sampling event ran continuously for 72 hours. All samples were analyzed for hydrogen sulfide. The data from these tests assisted Torch in proper equipment replacement of the Del Mar unit. With the installation of a new gas processing system, OEC was asked to conduct weekly sampling and analysis of HS&P waste gas for hydrogen sulfide and mercaptans. OEC is also on call for the analysis of butane & propane mix, being produced by the HS&P facility. Analysis consists of field sampling, field-testing, and laboratory testing. U Dole Dried Fruit Co. Raisin Facility, Fresno, CA While working for Cirrus Environmental, Inc., Mr. Carstens designed and implemented a two-week study of PM 10 emissions. The objective of the test program was to determine the PM 10 emissions from raisin dust, and determine if this facility was operating within their APCD permit. Four high volume samples were located around the perimeter of the testing facility. The method used during this test program was 40CFR Part 50 App. B PM10 High Volume Method. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 40 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Mary Ann Long Operations Director (Page 1 of 2) d QUALIFICATIONS I N C. lle Ms. Long has over 18 years hands-on experience as a chemist, supervisor and laboratory manager in the environmental field. EDUCATION & CERTIFICATION B.S., Biology, California State University, San Bernardino, 1979 Laboratory Analyst Grade 3 by CWEA Certified Manager by Institute of Certified Professional Managers First Aid and CPR tro on AFFILIATIONS California Water Environment Association (CWEA); Tri-Counties Regional Section of CWEA EXPERIENCE nc 2011–Current Operations Director (2014-Current) – Responsible for oversight of all department function and optimization of all production processes for the laboratory. U Volatile Organics Department Manager (2011-2013) – Responsible for the scheduling, maintenance, and verifying QA/QC parameters were met for all data from the Volatile Organics Laboratory. She was primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 41 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Mary Ann Long Operations Director (Page 2 of 2) Colorado State University, Center for Environmental Management of Military Lands – Camp Roberts, CA d 2011 I N C. 1996–2010 tro lle Environmental Technician – Assisted in the preparation of environmental documents according to the National Environmental Policy Act (NEPA) and California Environmental Quality Act (CEQA) requirements. Included the tracking of NEPA documents on the Share Point database. Reviewed and commented on environmental reports, technical documents, sampling data and Environmental Condition of Property (ECOP) documents. Assisted in site visits to activities and tenants on Camp Roberts to review environmental requirements and ensure compliance with laws and regulations. Provided contractor oversight for environmental projects. Oversaw the collection, management, and disposal of hazardous waste through satellite accumulation sites and the central accumulation points. Creek Environmental Laboratory/Centauri Labs – San Luis Obispo, CA on 2000-2010 Laboratory Manager – Managed every aspect of the laboratory operations from setting goals to organizing, leading, and monitoring for the production of defensible data. Conducted the hiring, training and review of laboratory staff. Responsible for implementation and reporting of State Performance Evaluation Program. Involved with meeting criteria to maintain the Laboratories State Certification. Performed detailed second party review of analytical data. Used the Laboratory Information System (LIMS-Promium) extensively to monitor work flow in the laboratory. Maintained adequate supplies for the smooth functioning of the laboratory. U nc 1996-2000 Inorganic Chemist – Principal analyst for the determination of metals by Inductively Coupled Plasma (ICP), Atomic Absorption (AA), and mercury by cold-vapor AA. Performed the chemical and physical analysis of drinking water, wastewater, and solid samples performed according to EPA methods and Standard Methods. Used the LIMS system for sample status and reporting. Maintained laboratory equipment for peak performance. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 42 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Carrie McCrillis & C O M P L I A N C E, Quality Director & Human Resources Representative (Page 1of 2) d QUALIFICATIONS I N C. tro lle Ms. McCrillis has over 15 years of experience in the environmental laboratory and quality-system management field. Environmental laboratory experience includes performing as an analyst, Quality Manager, safety officer, project manager and laboratory director. Proficient in environmental contract review and data package compilation, EPA methodology and quality control systems, national and state regulatory agency requirements (NELAP/ELAP), ISO QMS, CLP & GLP protocols for data verification and validation. EDUCATION B.S., Chemistry, California Polytechnic State University, San Luis Obispo, CA, 1999 OSHA 40-Hour Hazmat Training Certificate + Refreshers ISO Internal Auditor Training, 2006 (ASQ certified) AFFILIATIONS American Chemical Society (ACS) American Society for Quality (ASQ) nc on EXPERIENCE 2008-Present U Quality Director – Responsibilities include maintenance of OEC Quality Systems, including maintenance of state certification and all documentation related thereto. Including, but not limited to, maintaining and updating all standard operating procedures, Quality System Manual, and the statement of qualifications. Maintenance of quality documentation and organization as necessary related to instrument controls, employee training, corrective & preventive action, performance evaluations, and laboratory audits. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 43 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L Carrie McCrillis 2006-2008 & C O M P L I A N C E, Quality Director & Human Resources Representative Celite, World Minerals Inc., Imerys – Lompoc, CA I N C. (Page 2of 2) d O I L F I E L D ZymaX envirotechnology, inc. – San Luis Obispo, CA tro 2002 – 2005 lle Quality System Specialist – Responsible for the maintenance of the site ISO certification and monitoring of quality system protocols, training, documentation, and internal audits. Performed general supervision and payroll processing for QC laboratory personnel. Participated in implementation and training for multiple enterprise-level software systems including IFS/THERMO-LIMS (ERP), Kronos (Payroll & Timekeeping), & Intelex (quality management software). on 2002-2005 Quality Assurance Officer – Responsibilities include management and revision of the QA Program including maintenance of state certification and all documentation related thereto. Including, but not limited to, all administrative and laboratory standard operating procedures, control documentation for all laboratory instruments, documentation of technical and analytical training for all analysts, documentation and monitoring of laboratory corrective actions, and organization of all performance evaluations and audits. Additionally responsible for the compilation of CLP and contractdesign data packages. nc 2003-2005 Safety Officer – Responsibilities include organization and maintenance of all safety-related hardware, consumables & documentation for the laboratory. Primary contact for any city, county, fire department or OSHA inspections. Responsible for overall employee safety awareness including annual training refreshers. 1999-2002 Cirrus Environmental, Inc. – Santa Maria, CA U 2001-2002 Laboratory Director – Oversaw laboratory operation and supervised all chemists, laboratory technicians and field technicians. Administered the Quality Assurance Program and was responsible for overall laboratory data quality as the primary signatory. Provided guidance for all analytical methodology and procedures. Responsible for the maintenance of laboratory certification through California ELAP. Acted as project manager and technical contact for all clients. 1999-2001 Quality Assurance / Quality Control Officer – Reviewed all analytical data to meet quality control objectives prior to report generation. Responsible for all analytical report generation, including samples, QC and data packages. Responsible for maintenance and revision of the laboratory Quality Assurance Program and any internal or external audits. Maintenance of all laboratory quality documentation and state certification. Former positions held at Cirrus include organic & inorganic analytical chemist and extraction technician. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 44 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Lisa Race & C O M P L I A N C E, Technical Director & Safety Officer (Page 1of 3) d QUALIFICATIONS I N C. lle Ms. Race has over 25 years of experience using organic, inorganic and air toxic methodologies. She brings to OEC a strong working knowledge of applicable regulations regarding air, water, wastewater and hazardous waste testing and disposal. Additionally she brings several years of experience performing all aspects of Environmental Health and Safety function. B.S. Biochemistry, 1984, University of Wyoming Certificate in Hazardous Materials Management (partial) Certificate in D.O.T. shipping and handling Certificate in Fundamental Ergonomics Certificate in Leadership and Management Training (multiple certificates) EXPERIENCE on tro EDUCATION 2008-Present nc Technical Director (2014-Present) – Responsible for overall Technical Compliance of the Laboratory. Includes adherence to regulatory requirements, and research and development for improvement or new methodology. U Laboratory Manager (2008-2014) – Responsible for daily laboratory function and management. Her extensive laboratory experience was utilized to maximize laboratory function and efficiency, and served as a client resource for projects and data consultation. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 45 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L Lisa Race 2001-2008 & C O M P L I A N C E, Technical Director & Safety Officer TEST AMERICA Inc., Morgan Hill, CA I N C. (Page 2of 3) d O I L F I E L D lle Senior Project Manager- Coordinated with clients, laboratory personnel and subcontract laboratories to track and report results for projects. Responsible for all aspects of managing 3 of the top 10 clients including creating quotes, adding or updating bids in the LIMs system, reviewing SOWs and ensuring all project requirements were met. Responsible for creating invoices, EDDs, geotracker EDFs and PDF reports. Responsible for reviewing CLP data packages and training personnel on how to create the final CLP packages using the raw data and the final reports. Cirrus Environmental Inc., Santa Maria, CA on 2000-2001 tro Volatiles Department Manager- Responsible for interviewing, hiring and training new personnel for the department. Set up the 8260 full list, 524 and 624 methods and streamlined the 8015/8021 analyses. Increased productivity by 500%. Set up all new instrumentation and instructed analysts in how to use them. Responsible for scheduling sample analyses and personnel to ensure samples were analyzed within holding time and met TAT. nc Laboratory Director- Oversaw all aspects of the laboratory including certification, training, quality control, sample analysis, field sampling, project management and client contact. Coordinated all subcontract work. Assisted the marketing director in preparing quotes and evaluating and bidding on specific projects. 1994-2001 Environmental Analytical Service Inc., San Luis Obispo, CA U Laboratory Supervisor- Managed the laboratory by creating a smooth flow of information, sample distribution, sample analysis, data reduction and data review and ensured that project specifications were met. Coordinated the flow of information between the laboratory and administration by establishing standard procedures for the dissemination of information and establishing routine meetings between laboratory and administrative staff to discuss current or potential problems. Modified laboratory procedures to reduce the standard sample turnaround time from 20 working days to less than 14 working days. Instituted method modifications which decreased gas usage and resulted in reducing the laboratory gas budget by forty percent. Set up a “rewards” program to improve employee morale. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 46 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Lisa Race C O M P L I A N C E, Technical Director & Safety Officer I N C. (Page 3of 3) Coast to Coast Analytical Services, San Luis Obispo, CA;Tempe, AZ d 1991-1994 & 1987-1991 tro lle Mobile Laboratory Manager- Managed mobile laboratory projects including on and off site client contact, analyzed samples, reviewed data and generated reports. Set up the Los Angeles site long term mobile lab project which resulted in generating a profit rather than a loss for Mobile Lab #2. Responsible for setting up the Arizona mobile laboratory including obtaining all necessary permits and certifications in order to meet Arizona state regulatory requirements. Implemented and audited quality assurance/quality control guidelines. Created and/or updated mobile laboratory Standard Operating Procedures documents. Trained and supervised employees in mobile laboratory procedures. Enseco-CRL, Santa Maria, CA on Environmental Chemist: Organics- Headed and performed all organic operations within 1 year of initial training. Trained and supervised back-up analysts on all organic analyses. Environmental Chemist: Inorganics- Planned and implemented the set-up of the inorganic laboratory by modifying and customizing methodologies, allowing efficient use of available resources while offering a greater variety of services to the customer. Trained and supervised all aspects of the inorganics laboratory. Acted as a back-up analyst for inorganics after moving to organics. Quality Assurance/Quality Control Coordinator- Assumed the major responsibility for responding to quality control questions from clients. Reviewed all data to ensure that it met all quality assurance guidelines prior to release to customers. nc Environmental Health and Safety Coordinator- Conducted hazardous communications training for new and current employees. Managed facility hazardous and non-hazardous waste disposal and recycling per all applicable regulations. Completed required reports on facility emissions per applicable regulations. Trained employees in proper handling and shipping techniques, including dangerous goods shipping. Tracked and updated current chemical inventory. U Program Administration- Gathered information specific to the size and scope of projects including any specific quality assurance/quality control and reporting requirements. Tracked project status from acceptance of samples to release of report, notifying clients of any problems that would affect project specifics. Reviewed final reports prior to release to ensure they met all project specifics. 1984-1987 Wyoming Department of Agriculture-Division of Laboratories, Laramie Analyzed private and municipal waters and wastewaters for all inorganic parameters required. Extracted pesticide residues in foliage samples. Analyzed tissue samples for strychnine using liquid chromatography. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 47 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Meredith Sprister Project Manager (Lead) (Page 1of 1) d QUALIFICATIONS I N C. lle Ms. Sprister has several years of experience in the environmental laboratory industry. She has a strong working knowledge of applicable methods and regulations regarding air, water, wastewater and hazardous waste testing and disposal. She has an analytical background with environmental methods and instrumentation. EDUCATION B.A. Environmental Studies, Minor in Music, 2008, University of California, Santa Barbara tro EXPERIENCE 2010-Present Creek Environmental Laboratories, San Luis Obispo, CA nc 2009-2010 on Ms. Sprister is responsible for final laboratory data review, report generation and dissemination. She serves as primary client contact for laboratory and project activity. Other responsibilities include creating invoices, EDDs, Geotracker EDFs and loading data to client-specific databases. Ms. Sprister is also the primary contact for the compilation of CLP data packages. Previous responsibilities include performance of extractions and analyses in the Wet Chemistry & Inorganics Department. U Inorganics & Wet Chemist / Laboratory Technician – Prepared and analyzed soil, drinking water and aqueous samples on laboratory machinery including ICP-MS, ICP-OES, Mercury by Cold Vapor AA and Flame AA. Performed STLC and TCLP extractions and analyses. Performed wet chemistry tests including Ferrous Iron, Orthophosphate, Fluoride by ISE, Hexavalent Chromium in water and soil, MBAS and Chemical Oxygen Demand. Performed short holding time tests including pH, turbidity, EC, color, odor and salinity. Proficient at all EPA Metals digestion methods including 3050, 3060, 3005, 200.7/.8 and 3010. Performed instrument maintenance. 2006-Present Drive Customs, San Luis Obispo, CA Website Manager & Bookkeeper – Development and maintenance of a fully functional website including photos, services and contact information. Bill paying, invoice preparation, basic accounting and reconciliation using QuickBooks. Internet promotion, business card and logo design. Preparation of lease paperwork, dealer agreements and other technical documents. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 48 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, Marissa Censullo Project Manager (Page 1of 1) d QUALIFICATIONS I N C. tro lle Ms. Censullo has several years of experience in the environmental laboratory industry. She has a strong working knowledge of applicable methods and regulations regarding air, water, wastewater and hazardous waste testing and disposal. She has an analytical background with environmental methods and instrumentation. EDUCATION B.S. Environmental Science and Policy, 2010, Concentration in Environmental Science, University of South Florida, St. Petersburg FL EXPERIENCE on 2011-Present U nc Ms. Censullo is responsible for final laboratory data review, report generation and dissemination. She serves as primary client contact for laboratory and project activity. Other responsibilities include creating invoices, EDDs, Geotracker EDFs and loading data to client-specific databases. Previous responsibilities include performance of extractions and analyses in the Wet Chemistry & Inorganics Department. Jun-Dec 2010 U.S.G.S. Coastal and Marine Science Center, St. Petersburg, FL INTERNSHIP – Retrieved, organized, and analyzed environmental data that had been collected on physical, chemical and nutrient variables for waters in Florida Bay and Biscayne National Park. Used ArcGIS software to produce digital products including shapefiles overlain on an interactive map, and a series of graphs linked to shapefiles. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 49 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Kristie Mikel & C O M P L I A N C E, Department Manager, Microbiology, Bioassay & Wet Chemistry (Page 1of 1) d QUALIFICATIONS I N C. lle Ms. Mikel has several years of experience in the environmental laboratory industry. She has a strong working knowledge of applicable methods and regulations regarding water, wastewater and hazardous waste testing and disposal. She has an analytical background with environmental methods and instrumentation. EDUCATION B.S. Microbiology with Minor in Psychology, 2001, Cal Poly State University, San Luis Obispo, CA CPR Certified Licensed Real Estate Broker tro EXPERIENCE on 2013-Present Ms. Mikel is responsible for the scheduling, maintenance, and verifying QA/QC parameters are met for all data from the Microbiology, Bioassay and Wet Chemistry Department. She is primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. Abalone Coast Analytical – San Luis Obispo, CA nc 2011-2013 Laboratory Manager – Bacteriology, Microbiology & Chemistry; Responsibilities included: Media Prep, QA/QC, Reports and Testing, and management of lab personnel. U 2001-Present 1998-2008 Independent Real Estate Broker – San Luis Obispo, CA Tom Mel Beauty Center – San Luis Obispo, CA Manager – Managed a high-end boutique plus a full-service salon with 16 hairstylists, 2 estheticians and a manicurist/pedicurist. Resulting from salon growth and strong product sales, bought a building in downtown San Luis Obispo and later expanded in 2005. Helped develop and customize a computerized client management, product inventory, and sales tracking system – more than doubling company profit margin. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 50 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Drew Miller & C O M P L I A N C E, Department Manager, Volatile Organics (Page 1of 1) d QUALIFICATIONS I N C. lle Mr. Miller over 5 years of experience in the environmental laboratory field including working as a principal chemist for the inorganics department, performing method development, instrument troubleshooting, maintenance, and repair, and supervision. tro EDUCATION B.S., Biological Sciences, California Polytechnic State University, San Luis Obispo, 2008 on EXPERIENCE 2008–Present nc Volatile Organics Department Manager (2014-Present) – Responsible for the scheduling, maintenance, and verifying QA/QC parameters are met for all data from the Volatile Organics Laboratory. He is primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. U Inorganics Department Manager (2012-2014) – Mr. Miller was responsible for the scheduling, maintenance, and verifying QA/QC parameters are met for all data from the Wet Chemistry and Metals laboratories. He was primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within these laboratories. Inorganics Analyst & Principal Chemist (2008-2011) – Mr. Miller scheduled, maintained consumable inventory, performed instrument maintenance, method development, and assisted with training for all wet chemistry and metals methodologies. Additionally, he performed as the primary contact for external auditors of the department. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 51 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Parwinder Pal Parmar & C O M P L I A N C E, Department Manager, Metals & Instrumental Inorganics (Page 1 of 2) d QUALIFICATIONS I N C. lle Mr. Parmar has over 15 years of hands-on experience as a chemist and supervisor in the metals analysis of solids and liquids using EPA methodologies. His experience also includes analytical work in the wet chemistry and wine industry methodologies. B.Sc., Biology and Chemistry, Punjabi University, Patiala (India), 1996 M.Sc., (Microbial and Food Technology) – Dept. of Biotechnology, Punjabi University, Patiala (India), 1998 PhD., Dept. of Biotechnology, Punjabi University, Patiala (India), 2003 EXPERIENCE on tro EDUCATION & CERTIFICATION 2012–Present nc Mr. Parmar is responsible for the scheduling, maintenance, and verifying QA/QC parameters are met for all data from the Metals & Instrumental Inorganics Department. He is primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. 2005-2012 BC Laboratories Inc. Bakersfield, CA U Metals Department Supervisor - Mr. Parmar was responsible for the scheduling, maintenance, and verifying QA/QC parameters were met for all data from the Metals Department. He was primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 52 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L Parwinder Pal Parmar 2001-2005 & C O M P L I A N C E, Department Manager, Metals & Instrumental Inorganics Curtis & Tompkins Ltd., Berkley, CA I N C. (Page 2 of 2) d O I L F I E L D Master Winery, India tro 1998-2000 lle Chemist - Mr. Parmar was responsible for the digestion and analysis of soil and water samples for metals analysis using ICP/ICP-MS, Hydra AA Mercury analyzer and Flame AA. He also performed wet chemistry analyses for the Wet Chemistry department as requested. U nc on Chemist - Mr. Parmar was responsible for the chemical analysis, monitoring of fermentation and handling of the microbial work associated with producing wine. He was also responsible for entering the data associated with the work into a database. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 53 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Dwain Zsadanyi & C O M P L I A N C E, Department Manager, Semi-Volatile Organics (Page 1of 2) d QUALIFICATIONS I N C. lle Mr. Zsadanyi has over 30 years hands-on experience as analyst and department manager running GC/MS for trace analysis of priority pollutants, hazardous substance list compounds, fuels in soil and water. Interpretation of mass spectra. Maintenance and cleaning of HP GC/MC’s, autosamplers and purge-and-trap units. Training of new analysts. Method development and data interpretation. B.S., Chemistry, California Polytechnic State University, San Luis Obispo, 1982 Teaching Credential in Physical Science, California Polytechnic State University, San Luis Obispo, 1986 OSHA 40 Hour HazWoper Certificate + Refreshers AFFILIATIONS on tro EDUCATION American Chemical Society nc EXPERIENCE 2006–Present U Mr. Zsadanyi is responsible for the scheduling, maintenance, and verifying QA/QC parameters are met for all data from the Semi-Volatile Organic Laboratory. He is primarily responsible for any new method development, the analysis of proficiency testing (PT) samples, analysis of MDL / RL / DoCs for all supervised personnel, and training of technicians and analysts within this department. 2005–2006 Creek Environmental Laboratory – San Luis Obispo, CA Project Manager – Provided technical client services & project coordination. Performed data review, provided result interpretation, and performed analyses as necessary. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 54 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L Dwain Zsadanyi 1994–2005 & C O M P L I A N C E, Department Manager, Semi-Volatile Organics ZymaX envirotechnology, inc. – San Luis Obispo, CA I N C. (Page 2of 2) d O I L F I E L D lle 2001–2005, Project Manager – Responsible for data review, interpretation of analytical results and providing technical advice to clients. In charge of research and method development. 1990 – 1994 tro 1994–2001, Semi-Volatile Laboratory Manager – Responsible for operation of Semi-Volatile Organics GC/MS group. Primary duties included critical review of all data, final report generation, method development, staffing and scheduling. Additional duties included sample preparation, analysis, data interpretation, and instrument calibration and maintenance. Coast to Coast Analytical Services – San Jose and San Luis Obispo, CA 1984–1986 on Organics GC/MS Chemist – Performed volatile and semi-volatile methods. Sample preparation, analysis, data reduction and processing. Method development for new procedures/analysis (including low DL SIM analysis). Maintenance and repair of analytical equipment. Review and approval of reports. Organizing and scheduling workload and personnel. Purchasing/acquisition of supplies. California Polytechnic State University – San Luis Obispo, CA nc Laboratory Instructor – Plan, conduct and evaluate lessons. Record keeping and report writing of student performance. 1986–1990 Teacher – Various California School Districts 1969–1972 Food Inspector – U.S. Army U Analysis and inspection of food for army procurement. Site inspection of vendor facilities. Analysis for wholesomeness and specification requirements. Random sampling and sample preparation for QC reporting of consignments. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 55 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Pete Alcocer & C O M P L I A N C E, Oil Production Operations Consultant (Page 1of 1) d QUALIFICATIONS I N C. lle Mr. Alcocer has been involved in using bioremediation techniques in the field such as microbial bacteria remediation, vapor extraction, and excavation. In performing soil, water, gas, and oil sampling in accordance with EPA and ASTM guidelines, Mr. Alcocer has gained experience and expertise in using such field analyzers as the vapor probe, OVA-128, PID, LEL, Oxygen sensor, and Draeger type reagent tubes. U.S. Marine Corps, 1975-1978, Field Communications Training SECORP Industries Safety Class for H2S Environmental Hazardous Materials Technology Certificate, 1993, Allan Hancock College, Santa Maria, CA OSHA HAZWOPER 40-hourTrained (OSHA 29 CFR 1910.120) EXPERIENCE on tro EDUCATION 1984-Present nc Mr. Alcocer is involved in the majority of OEC’s field sampling program, providing independent field analyses of crude and refined gas/oil product for central California oil production companies. Field tests have included on-site tank testing for Reid vapor pressure, LPG/gasoline, specific gravity, moisture content, corrosivity, and various air monitoring analyses. Mr. Alcocer’s laboratory responsibilities include GC analysis of hydrocarbons in gases and liquids by FID and TCD per ASTM methods, and hydrogen sulfide by FPD. He provides comprehensive crude oil profiles, which include API gravity, kinematic viscosity, total sulfur content, salt content, flashpoint, and quantitative distillation. U 1983–1984 RMR Contractors, Santa Maria, CA Welder/Independent Contractor- Mr. Alcocer worked as a pipeline welder, certified under ASME B31-3. He performed construction and repair of oil, gas, and steam pipelines. 1980-1982 D & R Contractors Welder- Mr. Alcocer’s duties included oilfield pipeline construction and pipefitting, including major structural welding. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 56 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L Brandon Ganster & C O M P L I A N C E, Oil Production Taft Operations Supervisor (Page 1of 1) d QUALIFICATIONS I N C. lle Mr. Ganster has several years of experience in the environmental laboratory industry. In performing soil, water, gas, and oil sampling in accordance with EPA and ASTM guidelines, Mr. Ganster has gained experience and expertise in using multiple types of field analyzers. He has a scientific background with environmental and oilfield methods. B.S., Biology, California Polytechnic State University, San Luis Obispo, 2008 SECORP Industries Safety Class for H2S OSHA HAZWOPER 40-hour Trained (OSHA 29 CFR 1910.120) EXPERIENCE on tro EDUCATION 2011-Present nc Mr. Ganster is responsible for the overall operations in the Taft offices of OEC. Included are any field activities originating from this location. This includes staff management for, or performance of, any field services or operations for the collection or analysis of samples. 2002-2011 Bravo Pizza Plus, Atascadero, CA U Store Manager: Managed 12 employees, hiring and terminating, overseeing restaurant bills, bank deposits, payroll, customer/employee satisfaction, quality control, inventory/ordering, advertisement, meetings with potential large clients, establishment of new restaurant. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 57 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) Document ID Title ADM Administrative Procedures ADM-BILLING ADM-CHANGE Project Billing & Accounting Practices Change Management ADM-CLIENT Client Confidentiality, Complaint Handling ADM-ETHICS Ethics Training & Policies ADM-HSP Health & Safety Plan ADM-Management Employee Management ADM-OEM OEC Employment Manual ADM-Purch Material Procurement ADM-SOP Standard Operating Procedures ADM-Training ADM-Vehicle Orientation & Training Program OEC Vehicle Procedures GEN General Laboratory Procedures GEN-Audit Internal Audit Program GEN-CAPA Corrective & Preventive Action GEN-Defin GEN-DISPOSAL GEN-DOC d lle tro Data Reduction, Validation & Reporting Acronyms & Definitions Sample & Waste Disposal Document Control Electronic Data Generation & Record Retention nc GEN-EDATA on GEN-Data rev 06/13/2014 Equipment Validation, Calibration & Maintenance GEN-EXTR-CALWET California Waste Extraction Test (CALWET) GEN-EXTR-TCLP TCLP Extraction - EPA 1311 GEN-INT Manual Integration GEN-LOGIN Sample Login & Dispersal GEN-POWER Power Shutdown & Startup Guide GEN-SECM Small Instrument - Support Equipment Calibration & Monitoring F Field Operations Procedures F-AirMonitor Air Monitoring & Sampling Procedures F-AUGER F-GasVaporProbe Manual Hand Auger Field Sampling Gas Vapor Probe Installation & Sampling F-GEOPROBE Geoprobe System Instructions U GEN-EVCM 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 58 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) Document ID Title F-GOR GWR GOR & GWR Sampling Protocol F-GWMonitor Groundwater Monitoring Field Sampling F-HOST HOST Vapor Pressure Sampling Method F-NG Natural Gas Cylinder Sampling F-NGL Natural Gas Liquid Cylinder Sampling F-SAMPLING General Field Sampling Operations F-SRB Sulfate Reducing Bacteria Field Sampling F-SurfaceWater Surface Water Sampling F-Tedlar Tedlar Bag Gas Sampling FA-Dew Point Draeger FA-Freeze Valve Dew Point testing by Draeger Tube (Gas Detector Tube) Water Vapor Content of Gaseous Fuels by Measurement of Dew Point Temperature Freeze Valve Method FA-H2S Draeger Hydrogen Sulfide testing by Draeger Tube (Gas Detector Tube) FA-H2S HACH Field Analysis of H2S in Water using HACH FA-pH Field Analysis of pH FC-Guadalupe IN-ME IN-Hardness IN-Hg d lle tro Site-Specific Courier Instructions: Guadalupe Inorganics – Metals Department Procedures Calcium & Total Hardness by Calculation Mercury Analysis by CVAA Mercury Digestion for CVAA Analysis Metals Preparation by EPA 200.2 nc IN-Hg-DIGEST IN-ME-PREP-200 on FA-Dew Point rev 06/13/2014 Metals Preparation by EPA 3000 Series Methods IN-ME-ICP Metals Analysis by ICP IN-ME-ICPMS Metals Analysis by ICPMS U IN-ME-PREP-3000 IN-WC Inorganics – Wet Chemistry Department Procedures IN-AB# Acid and Base Number by Color-Indicator Titration IN-Alkalinity Total Alkalinity (SM2320B) IN-Ammonia Ammonia as Nitrogen by Ion Selective Electrode (EPA 350.3 & SM4500NH3) IN-Chlorophyll Chlorophyll-a by Spectrophtometry IN-COD Chemical Oxygen Demand IN-Conductivity Specific Conductance (SM2510B) 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 59 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) Document ID Title IN-CrVI Hexavalent Chromium by Colorimetry IN-Cyanide Total Cyanide IN-Fe Ferrous Iron IN-FP Ignitability / Flashpoint (EPA 1010) IN-IC(Anions) Anions by Ion Chromatography (EPA 300.0) IN-MBAS Anionic Surfactants as MBAS IN-O&G Hexane Extractable Oil & Grease IN-pH pH Measurement IN-Phenol Total Phenolics IN-PoP Total Phosphorus & Ortho Phosphate by Ascorbic Acid Colorimetry IN-RXCNS Reactive Cyanide & Sulfide IN-S Total Sulfide IN-SETT Settleable Solids IN-TDS IN-TKN Total Dissolved Solids Total Kjeldahl Nitrogen IN-TOC Total & Dissolved Organic Carbon IN-TSS IN-Turbidity d lle tro Total Solids Total Suspended Solids Nephelometric Turbidity Volatile Solids nc IN-VS on IN-TS rev 06/13/2014 Microbiology & Bioassay Department Procedures MB-Bioassay Acute Bioassay for Hazardous Waste MB-BOD Biological Oxygen Demand MB-Cl Residual Chlorine MB-DO Dissolved Oxygen MB-Hardness Hardness by EDTA Titration MB-HUB Hydrocarbon Utilizing Bacteria MB-SRB Sulfate Reducing Bacteria OG Oil & Gas Production Analysis Department Procedures OG-ADA Determination of ADA in Water OG-API API Gravity of Petroleum (Hydrometer Method) OG-BS&W Determination of Water and Sediment in Crude Oil By Centrifuge Method U MB 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 60 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) Document ID Title OG-BTU (NATGAS) Natural Gas Analysis by GC/TCD OG-COHSE Crude Oil Headsapce Extraction OG-CORR Corrosion Inhibitor OG-DISSGAS Dissolved Compounds in Gas Extracts OG-DIST Distillation of Petroleum Products OG-DMETER Specific Gravity (Relative Density) by Density Meter OG-GOR-EXTR Gas-Oil Ratio Extraction OG-GWR-EXTR Gas-Water Ratio Extraction OG-H2S Hydrogen Sulfide in Gaseous Fuels (Lead Acetate Reaction Rate Method) OG-H2SMER H2S and Mercaptans in Oil and Sludge OG-HOST Vapor Pressure of ROC in Heavy Crude Oil by GC OG-HYDROMETER Specific Gravity by Hydrometer OG-oPO4 Orthophosphate by Colorimetry OG-P Total Phosphorus by Colorimetry OG-PSIMPLE Peak Simple Chromatography Software OG-RATIO Gas Oil Ratio OG-RVPTVP OG-S(XRF) OG-SCAQMD d lle tro Reid Vapor Pressure Reid Vapor Pressure (RVP) to True Vapor Pressure (TVP) Sulfur in Petroleum Products by Energy-Dispersive X-Ray Fluorescence Spectroscopy SCAQMD METHOD 307-91 Determination of Sulfur in a Gaseous Matrix Determination of Water and Sediment in Crude Oil By Centrifuge nc OG-SEDIMENT on OG-RVP rev 06/13/2014 Shrinkage Factor OG-TCDA TCDA Analysis by GC OG-TRS TRS from Stationary Sources by GC/SCD OG-V Vanadium OG-VISC Kinematic Viscosity of Liquids U OG-SHRINK SV Semi-Volatile Organics Department Procedures SV-CLEAN-GPC Gel Permeation Chromatography SV-CLEAN-SAC Sulfuric Acid Cleanup - EPA 3665A SV-CLEAN-SGC Silica Gel Cleanup - EPA 3630C SV-CLEAN-SC Sulfur Cleanup - EPA 3660B SV-EXTR-AQ Extraction of Aqueous - EPA3510C 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 61 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX B – STANDARD OPERATING PROCEDURES (SOP) Document ID Title SV-EXTR-Fractionation Fractionation of Extracts SV-EXTR-PROD Extraction of Products SV-EXTR-SO Ultrasonic Extraction of Solids - EPA 3550B SV-DIOXANE 1,4-Dioxane by GC/MS SV-GLYCOL Glycol Analysis by GC/FID SV-Methanol Methanol Analysis by GC/FID SV-PCB Polychlorinated Biphenyls (PCBs) by GC/(ECD)2 SV-PEST Organochlorine Pesticides by GC/(ECD)2 SV-PNASIM PNA Analysis by GC/MS in SIM Mode SV-SARA SARA Fractionation & Analysis SV-D2887 Simulated Distillation by ASTM D2887 SV-SVOC Semi-Volatile Organic Compounds by GC/MS SV-TPH(FID) Semi-Volatile Petroleum Hydrocarbons by GC/FID SV-TPH(GCMS) Semi-Volatile Petroleum Hydrocarbons by GC/MS SV-TPH(LGVOL) Semi-Volatile TPH Determination by Large Volume Injection & GC/FID VO-524.2 VO-624 VO-GRO(FID) d lle tro Volatile Organics Department Procedures Volatile Organic Analysis of Drinking Water Volatile Organic Analysis by EPA 624 GRO-TPH Determination by GC/FID (LUFT & EPA 8015B) Aromatic Volatile Organics by GC/PID nc VO-PID on VO rev 06/13/2014 TPH & Related VOC Determination by GC/MS VO-VOC Volatile Organic Analysis (EPA 8260B) VO-AIR Volatile Organic Compounds in Air U VO-TPH&VOC 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 62 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Burrell Wrist Action Shaker Igloo 2.8 Cu. Ft. Fridge Mettler 5GO Portable DO Meter Mettler Toledo pH Meter with Probe Pentair Fleck 5800 LXT Water Softener Precision Low Temp 815 BOD Incubator Precision Thelco Model 6 Incubator Precision Thelco Model 6 Incubator Stir Plate, Small Benchtop Thermolyne Mirak Stir Plate YSI 5100 DO Meter Detector, wavelength analyses Digi Block A Digi Block A Controller Digi Block B Digi Block B Controller Hood air monitor (ALNOR) Hood #3 Hood,#3 Hood,#4 Metals reduction, acid/heat (Block C, in hood #3) Metals reduction, acid/heat (Block D, in hood #3) Metals reductor keypad (in hood #3) Metals reductor keypad (in hood #3) Safety Shower/eye wash station Scale – Balance, Top-Loading Stir Plate Auto Sampler (ICP1) Auto Sampler (ICPMS) Autosampler (ICP2) Computer HG2 ICP1 (ICAP 6300 DUO) ICP1 Computer ICP2 (Perkin Elmer) ICP2 Computer ICPMS (not in service) ICPMS ICPMS Computer Mercury Analyzer (Quick Trace) Mercury Autosampler Mercury Peristaltic Pump Peristaltic Pump (ICP2) Peristaltic Pump (ICPMS) Rotators –#1 Rotators –#2 Computer R-OEC1 (KC laptop) Computer R-OEC3 (RD laptop) Computer R-OEC4 (JH laptop) Air Compressor (Coleman) Air Compressor (Coleman) motor MB Room MB Room MB Room MB Room MB Room MB Room MB Room MB Room MB Room MB Room MB Room ME Prep ME Prep ME Prep ME Prep ME Prep ME Prep ME Prep ME Prep 1439 26355 none B319308057 B312145455 none lle none Fisher Sci 14-493-1205 sp72725 5100-115v Thermo Spectronic Vendor CPI George T. Hall Co. Inc. Vendor CPI George T. Hall Co. Inc. AirGard 200 Genie Genie 105N0911 727990000000 SCP 'DigiPrep MS' MSX0307400469 SCP 'DigiPrep MS' 2110040031 'DigiPrep MS keypad 'DigiPrep MS keypad HAWS Mettler HF-400 1205 Elemental Scientific CETAC ASX-520 Perkin Elmer S10 Dell Inc. OptiPlex GX520 Thermo Scientific Dell Inc. OptiPlex 960 Optima 3300DV HP Pavilion 9000 PE Sciex Elan 6100 Perkin Elmer Elan 9000 Dell Inc. OptiPlex 330 CETAC (M-6100) CETAC (ASX-400) CETAC Gelson Mini Plus3 Environmental Express LARS LANDE Rotary Extractor KPX0407400972 KP30050506 None 12843372 C1685108816350 X2DXS-HS-TSP-16-121011 020605A520 102S7125004 1V4RHB1 20095011 960QVK1 069N9122701 MXP402040B 939907 AJ12510809 GCJ8481 090602QT6 090603ASX-4 100608-DMP 610M1006 610M6007 None None Dell Inc. Latitude E5520 BR8RKQ1 Premium Plus A.O.Smith 'Century' B28410964 BY07-16 U nc on ME Prep ME Prep ME Prep ME Prep ME Prep ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room ME Room Offsite Offsite Offsite OG Closet OG Closet fl-ply-548-450-s01 tro ME Prep FG4 LE438 d PROPERTY DESCRIPTION ME Prep I N C. 3SGE170004 S1125602.5 S1125602.7 TSS 81362 none none 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 63 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Generator, zero air (in Samp closet) Generator, zero air GAUGE (in closet) Mass flow controller (sample closet) Pressure Filter Pressure Filter Pressure Filter Pressure Filter (in Sample Closet) Pressure Filter (in Sample Closet) Helium Detector Portable Typewriter Atmospheric pressure regulator Bomb Ignition Unit, Para Bomb, Cylinder, (Oxy calorimeter) Bomb, Oxygen, calorimeter Centrifuge Centrifuge 2 Chromatography Data System Chromatography Data System Chromatography Data System Computer GAS1 Computer GAS10 Computer GAS11 Computer GAS4 Computer GAS5 Computer GAS8 Computer GAS9 Controller, Interface SCD Density meter, AP PAAR Density meter, keypad Field Equipment - Hand Auger Field Equipment - Hoe Field Equipment - Shovel #1 Field Equipment - Shovel #2 Flash Point machine Gas Chromatograph (GAS1)(TCD1) Gas Chromatograph (GAS2)(TCD2) Gas Chromatograph (GAS3)(SCD1) Gas Chromatograph (GAS4)(FID1) Gas Chromatograph (GAS5)(SCD2) Gas Chromatograph (GC) (not in use) Gas Chromatograph (GC) (not in use) Gas Chromatograph (GC)(SCD2) HACH - Hydrogen Sulfide Test Kit HACH - Hydrogen Sulfide Test Kit Heater box Heating Chauffage (Heizung) Hood,#15 Hood,#16 OG Closet OG Closet OG Closet OG Closet OG Closet OG Closet OG Closet OG Closet OG Office OG Office OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Nitrox 'UHP-352A' PMR1-010972 GFC 17 none none none Millipore 142mm dia Millipore Model (969-4650) IBM 'Wheelwriter 5' NuTech L-K Industries Inc. Peak Simple 202, 4ch Peak Simple 202, 4ch Peak Simple 202, 4ch 037A0089 99232-17 not available-in use none none none YT30-142-HW none 205556 3 sets on bottom 9004 2901 EB Lot 0793 101A19940C20092988 L341EB 03240E 201358 N1148W N1341W N4397 Dell Inc. OptiPlex 390 Dell Inc. OptiPlex 390 Dell Inc. OptiPlex 390 Dell Inc. OptiPlex 390 7H2ZTR1 3VCF7V1 7H2YTR1 7H2XTR1 Hydrometer - API (-1-11) OG Room nc lle on tro Para Para d PROPERTY DESCRIPTION U I N C. Dell Inc. OptiPlex 390 Sievers 355 DMA 48 DMA 48 4KXJ7V1 1220 190091 107136559520 GCA/Precision Sci HP 5890 HP 5890 HP 5890 HP 5890 Agilent 5890 Series II Agilent 7890A (G3440A) Agilent 5890 Series II Agilent 5890 Series II HACH (HS-WR) HACH (HS-C) Thermolyne 45500 Type F4391 Hamilton/ SafeAire Hamilton/ SafeAire none none none 2443A04188 2750A19263 2843A19402 CN10847057 3336A56889 multiple Lot A2241A Lot A2198A 4550020104955 77066 FH-414C-A FH-414D-A 116317, 116314, 16602, 116316 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 64 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM Model # Hydrometer - API (15-21) OG Room multiple Hydrometer - API (19-31) OG Room multiple Hydrometer - API (19-41) Hydrometer - API (20-26) Hydrometer - API (29-41) Hydrometer - API (29-51) Hydrometer - API (39-51) Hydrometer - API (40-46) Hydrometer - API (45-51) OG Room OG Room OG Room OG Room OG Room OG Room OG Room multiple multiple multiple multiple Hydrometer - API (49-61) OG Room Hydrometer - API (55-75) Hydrometer - API (59-71) Hydrometer - API (65-70) OG Room OG Room OG Room Hydrometer - API (69-81) OG Room Hydrometer - API (79-91) Hydrometer - API (89-101) Hydrometer - API (90-100) OG Room OG Room OG Room tro multiple multiple multiple multiple on OG Room multiple OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Hydrometer - SG (1.0-1.22) OG Room multiple Hydrometer - SG (1.15-1.2) Hydrometer - SG (1.18-1.25) Hydrometer - SG (1.2-1.45) OG Room OG Room OG Room multiple Hydrometer - SG (1.4-1.65) OG Room multiple Hydrometer - SG (1.6-1.85) Hydrometer - SG (1.8-2.5) OG Room OG Room multiple nc Hydrometer - Baum Scale (0-12) Hydrometer - Salometer (0-100) Hydrometer - Salometer (0-27) Hydrometer - SG (0.5-0.65) Hydrometer - SG (0.64-0.71) Hydrometer - SG (0.65-1.0) Hydrometer - SG (0.7-0.77) Hydrometer - SG (0.7-0.8) Hydrometer - SG (0.76-0.83) Hydrometer - SG (0.8-0.85) Hydrometer - SG (0.8-0.9) Hydrometer - SG (0.82-0.89) Hydrometer - SG (0.85-0.90) Hydrometer - SG (0.88-0.95) Hydrometer - SG (0.94-1.01) U SERIAL # multiple multiple multiple 975047, 77-1023, 77-1017, 77-1026, 19714, 19764, 771019, 974997 73529, FH740, 57-2002, 226908, 260732, 149420, 274002, 273998, 19318, 273996, 274003, 273988, 537001 52465, 52850 14-1227, 14.1257 MA-131, 52271 52773, 52456 87804 60783 16519, 63546 65972, 65977, P51160, P51176, 1006 65813 P56884, A651, 76776, 76783 A18054 196480, 8823, 87804, 87807, 8828 87575 982399 NONE 274018, 247008, 274009, 274010, 274013, 274012, 274016, 8799 1264300-326 758612 5111026 85230, 85233 K56558 54765 A65256 96341, 24348 K55741 L94448 57566, 130311 C54071 M10426 A69162 A79015 95494, 28137, 28573, 280227, 57568, 37803 K66286 K67476 28566, 28781, 28671, 87240 28575, 28242, 18853, 162307, 39283 19546, 51199 70976 d LOCATION lle PROPERTY DESCRIPTION Hydrometer - API (9-21) I N C. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 65 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Hydrometer Bases - Brass - 11 Hydrometer Bases - Glass - 21 Imersion Circulator Isotemp Imersion Circulator Isotemp Motor (attached to Oxy calorimeter) Muffle Furnace NACE - FUEL Sampling Kit Oil Bath, MGW 'Lauda' Oven, heating (in hood #16) Oven, heating, 'Turkey' (in hood #16) Oxygen analyzer, portable Power Supply, electrothermal Pressure Gauge (0-100 psi) glycerin Pressure Gauge (0-100 psi) Non glycerin Pressure Gauge (0-1000 psi) Non glycerin Pressure Gauge (0-160 psi) Non glycerin Pressure Gauge (0-200 psi) non glycerin Pressure Gauge (0-200 psi) glycerin Pressure Gauge (0-200 psi) glycerin Pressure Gauge (0-200 psi) non glycerin Pressure Gauge (0-30 psi) Pressure Gauge (0-30 psi) glycerin Pressure Gauge (0-30 psi) Non glycerin Pressure Gauge (0-300 psi) glycerin Pressure Gauge (0-300 psi) non glycerin Pressure Gauge (0-60 psi) glycerin Pressure Gauge (0-60 psi) Non glycerin Pressure Gauge (0-60 psi) Non glycerin Pressure Gauge (0-600 psi) glycerin Printer Printer - Fax,Scan,Copy Printer - Fax,Scan,Copy Pump #1 - Sampling - Intrinsically Safe Pump #2 - Sampling - Intrinsically Safe Refractometer - Portable Refrigerator #7, products (O&G) Regulator, temperature Reid Vapor Pressure Bath Reid Vapor Pressure Gauge (0-100psi) OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Fisher 730 Cole Parmer Model#1266-02 Para Thermo FB1415M Millipore Cat# xx6403730 T-1 Neycraft General Electric Teledyne 320A-B MC242X1 Wika Gauge LR NONE None 404363 891040 A50MEB 1257090730460 008603P A14045 not available-in use 168962 90200 10586765 OEC-G-011 OEC-G-010 OG Room Wika Gauge OEC-G-002 Wika Gauge OEC-G-001 US Gauge OEC-G-012 BR BR Matheson Ashcroft Wika Gauge LR Wika Gauge OEC-G-005 OEC-G-006 OEC-G-007 OEC-G-008 OEC-G-016 OEC-G-009 OEC-G-013 OG Room Wika Gauge OEC-G-014 OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Wika Gauge Wika Gauge Wika Gauge HP Laser Jet P2035 Brother (MFC-8680DN) Brother (MFC-7460DN) Xtech Instr. Inc. Xtech Instr. Inc. Extech RF40 none Resistotherm Koehler #K11450 Koehler Reid Vapor Pressure Gauge (0-15psi) OG Room Koehler (multiple) Reid Vapor Pressure Gauge (0-5psi) OG Room Koehler (multiple) Reid Vapor Pressure Gauge (0-60psi) OG Room Koehler Reid Vapor Pressure Vapor Chamber OG Room Koehler Rough Pump - SCD2 OG Room Edwards-RV3 U nc lle on OG Room OG Room OG Room OG Room OG Room OG Room OG Room tro OG Room d PROPERTY DESCRIPTION OG Room I N C. OEC-G-004 OEC-60-002 OEC-G-003 OEC-G-015 VNB3226003 U62341M0J605348 U62701A3N978631 3128 3392 none not available-in use R82640314-N OEC-100 F7524-01-1P, F7524-01-1B, F1596-01-1I, F1596-01-1M, F7524-01-10 F6419-01-1P, F0877-01-1C, F6419-01-1F LOGO-60-3 1B:4055, 1B:5541, 1B:5542, 1B:5543 Worn Off 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 66 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Rough Pump - SCD3 Safety Shower/eye wash station Sulfur Analyzer, X-RAY Fluor. Sulfur Detector, Chemiluminescence (SCD1) Sulfur Detector, Chemiluminescence (SCD2) Sulfur Detector, Chemiluminescence (SCD3) (not in use) Syringe Pump #1 Syringe Pump #2 OG Room OG Room OG Room Edwards-RV3 SPEAKMAN ASOMA 200 666134788 None 4093 OG Room Sievers 350B none OG Room Sievers SCD 350B OG Room Agilent Model G6644A OG Room OG Room KD Scientific #LEGATO 200 KD Scientific #LEGATO 200 Thermometer OG Room multiple Thermometer - Field - PA Thermometer - GOR#2 Thermometer - Infrared Thermometer - Infrared Field - BG Thermometer - Infrared Field - PA Thermometer - Lisa Office Thermometer - Lisa Office Thermometer - Lisa Office Thermometer - Pete Alcocer Torque Wrench Preset 20ft/lbs-40ft/lbs (Static Proof) Vacuum Pump Vacuum Pump Vacuum Pump Vacuum Pump (not in use) Water Bath Rubbermaid 10 gal - GOR#1 Water Bath Rubbermaid 10 gal - GOR#2 Water Bath, GCA Water Bath, Stainless Steel GOR#1 Water Bath, Stainless Steel GOR#2 X-Ray Fluorescence (XRF) Spectrometer, energy dispersive OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Computer OECSVR3 Computer oec-t1 Laboratory Information Management System (LIMS) Computer OEC13 Computer OEC20 Computer OEC29 Computer OEC6 0393-378 US10849005 lle tro on Koehler Fisher - IR Fisher - IR Fisher - IR Koehler OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room OG Room Ever Safe Reieke Corp. (Model W01685PT03) Edwards RV3 OGT DDA-P184-AA General Electric Edwards Rubbermaid Rubbermaid Cat # 76000 Precision 183 Precision 181 OG Room AMTEK ASOMA Phoenix II Preisker Computer Room Preisker Computer Room Preisker Computer Room Preisker Computer Room Preisker Office Preisker Office Preisker Office Preisker Office Rackable Systems Inc. #S5000PSL Dell Computer Corporation PowerEdge 840 nc U Computer OEC-P1 d PROPERTY DESCRIPTION OG Room I N C. 700605 D200012 A67129, 161512, 87174, 310794, 261568, M88749, AC13831, 207209, M88621, 4C3253, 541002, 540983, 541005, 502950, 310780, 745122, ASTM 10F, 741289, 1458 M88536 745203 130379810 130544019 130544023 763389 2299 2302 211030 None 27475964 none 1218 none none 14AN/2 9512-360 601111160 15151 A0072ABB GP4MJH1 Dell Inc. PowerEdge T110 II 8C1FLS1 Promium, Element ver.6.07:2016 Dell Inc. OptiPlex 360 Dell Inc. OptiPlex 380 Dell Inc. OptiPlex 3010 Dell Inc. OptiPlex 360 G5NQXH1 5525ZQ1 2YT8YV1 9VQRML1 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 67 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Preisker Office Preisker Office Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Preisker Storage Prep Room Prep Room Prep Room Prep Room Prep Room Prep Room-Hd7 Prep Room-Hd7 Prep Room-Storage Prep Room-Storage Prep Room-Storage Prep Room-WC Prep Room-WC Prep Room-WC Roemer Computer Closet Roemer Computer Closet Roemer Computer Closet Roemer Computer Closet Roemer Computer Closet Roemer Computer Closet Roemer Front Office Roemer Outside Cage Roemer Project Managers Roemer Project Managers Roemer Project Managers Roemer Project Managers Roemer Storage Roemer Storage Computer OEC-R1 Computer OECR-DMZ SERIAL # Dell Inc. OptiPlex 780 Dell Inc. OptiPlex 360 Dell Inc. OptiPlex 330 Dell Inc. OptiPlex 330 Dell Inc. Vostro 230 Dell Inc. OptiPlex 380 Dell Inc. OptiPlex 360 Dell Inc. OptiPlex 380 Dell Inc. OptiPlex 360 VWR R429GA14 F09X4P1 H5NQXH1 B9D30G1 8XLF4F1 FF56CP1 HVX3PL1 9WHQML1 5524ZQ1 J5NQXH1 N31S-617753-05 Presto-Tilt'Ndrain Big Griddle Presto-Tilt'Ndrain Big Griddle GCA/Precision Sci TP-Link-TL-WA901ND Westco-114-8400-01 Westco-114-8301-01/02 6795-400D 6795-400D PC100 Metrohm-831 Metrohm-728 Metrohm-832 2012 645 5011 155 Dell Inc. PowerEdge T300 GV0XJK1 Dell Inc. PowerEdge 1900 B1MDGD1 PowerConnect 2324 CNOP4194282984C70155 Compaq Pro UPS500 5278201J91Y0HY Dell Inc. Vostro 230 FDY2CP1 Dell Inc. OptiPlex 380 8BWNZQ1 Dell Inc. OptiPlex 780 D09X4P1 Dell Inc. OptiPlex 390 3VCG7V1 Dell Inc. OptiPlex 380 HVX3PL1 COMBI/PAL Branson Max Booster 123099 Neslab CFT-75 199218069 on Computer OEC10 Model # lle LOCATION Computer OEC7 Computer OEC8 Computer LAB03 Computer Lab05 Computer LAB06 Computer LAB10 Computer LAB14 Computer OEC14 Computer OEC21 Computer OEC5 Refrigerator #2 VGL Dolly Computer Workstation-LAB11 Electric Skillet, Evaporaor Electric Skillet, Evaporaor Flashpoint Unit-FulKontrol Router, Wireless-N Easy Distillation Controller Easy Distillation Heating Unit (Hotblock) Hotplate, Corning Hotplate, Corning Hotplate, Corning Karl Fischer Coulometer 831 Karl Fischer Stirrer 728 Karl Fischer Thermoprep 832 Rev 06/30/2014 - CM tro PROPERTY DESCRIPTION nc Computer R-OEC2 (SCRAP Laptop) Power Connector, Dell Power supply, UPS Computer OEC18 Cylinder Dolly U Computer OEC11 Computer OEC26 Computer OEC28 Computer OEC30 Auto Sampler CTC Liquid Branson cage, sonicator Chiller, Neslab 208/230V 9.7 AMP (not in service) Roemer Storage I N C. d O I L F I E L D 13513003314 1463 1463 143312290126 143312290136 none 1247 none 5156 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 68 of 94 Rev 18 – JULY 2014 E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Computer OEC1 Computer OEC22 Computer OEC23 Model # SERIAL # Roemer Storage Neslab CFT-75 694279212 Roemer Storage Neslab Thermo Flex 900 R100050038 Roemer Storage Neslab Merlin 1175 Roemer Storage Roemer Storage Roemer Supervisor Office Roemer Supervisor Office Roemer Supervisor Office SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SAMPLE Rec. SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room HP 59822B 5972 nc U 10515 2009 4465 3435A01885 Dell Inc. OptiPlex 360 16NQXH1 Dell Inc. OptiPlex 380 8BWPZQ1 Dell Inc. OptiPlex 390 JGQZKS1 Dell Inc. OptiPlex 330 2YMGCG1 253.165021 AirGard 200 Genie Scientific CU2026MA-1A WB70426086 TSS 81352 none 14011320015191 Cobra II Cobra II Cobra II Cobra II Agilent 6850 (G2880A) G2614A G2614A HP 7673B HP 7673B HP 7673B HP 7673B HP 7673B HP 7673B Massey MF-4 SP48-216C (1) HP7673B HP 7673B HP 7673B HP 6890 Plus HP 7673B HP 7673B HP 7673B HP 7673B HP 7673B HP 7673B HP 7673B COB167102508 1130-0605 1147-0905 COB180070510 CN30520433 CN44631260 CN84651351 3306A31363 3205A28236 3331A32853 2731A27823 3138A27453 3201A27823 on Brother Printer Computer LAB7 Copier Freezer, Kenmore Hood air monitor (ALNOR) Hood #22 Hood, #2 Ice System, Scotsman Refrigerator #8 (Large Walk-in) Auto Sampler (CobraII) (GC3) Auto Sampler (CobraII) (GC5) Auto Sampler (CobraII) (GC6) Auto Sampler (CobraII) (GCMS2) Auto Sampler (GCMS10) Auto Sampler Carousel Auto Sampler Carousel Auto Sampler Controller Auto Sampler Controller (GC8) Auto Sampler Controller (GCMS6) Auto Sampler Controller (not in service) Auto Sampler Controller (not in service) Auto Sampler Controller (not in service) Auto Sampler Fan (GC5) Auto Sampler Fan (GC8) Auto Sampler Injector (GC1) Auto Sampler Injector (GC8) Auto Sampler Injector (GC9) Auto Sampler Injector (GC9) Auto Sampler Injector (GCMS1) Auto Sampler Injector (GCMS6) Auto Sampler Tower (not in service) Auto Sampler Tower (not in service) Auto Sampler Tray Auto Sampler Tray (GC1) Auto Sampler Tray (GC8) Auto Sampler Tray (GC9) Auto Sampler Tray (GCMS1) Auto Sampler Tray (GCMS6) LOCATION lle Chiller, Neslab 208/230V 9.7AMP (not in service) Chiller, Thermo Fisher 115V, 11.1 AMP (ICP) Chiller, Thermo Scientific 208/230V, 10.1 AMP (ICPMS) Ionization Gauge Controller Mass Selective Detector Rev 06/30/2014 - CM tro PROPERTY DESCRIPTION I N C. d O I L F I E L D HP 7673B HP 7673B 2950A20230 GT031710A US44910092 US00024473 3429A39421 3009A21046 3242A32714 3704A09238 3328A32563 3342A33539 3221A28664 CN84651351 2942A20870 3506A37974 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 69 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Auto Sampler Tray (not in service) Auto Sampler Tray (not in service) Auto Sampler Tray (not in service) Auto Sampler Tray (not in service) Auto Sampler Tray (not in service) Auto SamplerTower (not in service) Computer Gas2 Computer GC1 Computer GC3 Computer GC5 Computer GC6 Computer GC8 Computer GC9 Computer GCMS10 Computer GCMS2 Computer GCMS6 Computer GCMS7 Computer LAB2 Computer OEC 33 Computer OEC 34 Fan GC1 Fan GC3 Gas Chromatograph (GC) (MS10) Gas Chromatograph (GC) (MS14) Gas Chromatograph (GC) (MS2) Gas Chromatograph (GC) (MS6) Gas Chromatograph (GC) (MS7) Gas Chromatograph (GC)(MS1) Gas Chromatograph (GC1) Gas Chromatograph (GC3) Gas Chromatograph (GC5) Gas Chromatograph (GC6) Gas Chromatograph (GC8) Gas Chromatograph (GC9) – Large Volume Injection Glass case, sonicator (hood #3) Hood air monitor (ALNOR) Hood #5 Hood air monitor (TEL) Hood #1 Hood, #5 Hood,#1 Ionization Gauge Controller Ionization Gauge Controller Ionization Gauge Controller Mass Selective Detector (MS10) Mass Selective Detector (MS14) Mass Selective Detector (MS2) Mass Selective Detector (MS6) Mass Selective Detector (MS7) Mass Selective Detector (not in service) Modular Accelerated Column Heater (MACH) (not in service) SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room HP 7673A HP 7673A HP 7673B HP 7673A HP 7673B HP7673B OptiPlex330 Dell Inc. Vostro 230 Dell Inc. Vostro 230 Dell Inc. Vostro 230 Dell Inc. OptiPlex 380 Dell Inc. Vostro 230 Dell Inc. OptiPlex 330 Compaq Evo D510 SFF Dell Inc. Vostro 230 Dell Inc. Vostro 230 Dell Inc. OptiPlex 330 Dell Inc. OptiPlex 330 Dell Inc. OptiPlex 360 Dell Inc. OptiPlex 3010 Honeywell HT 808 Massey MF-4 Agilent 6850 (G2630A) Agilent 6890A HP 5890 GC Series II HP 5890 Series II Agilent 6890N HP 5890 HP 5890 Series II HP 5890 Series II HP 5890 Series II HP 5890 Series II HP 5890 Series II 2718A08788 2718A08839 2942A20870 3246A30420 3342A3539 3224A31065 BQLS4H1 FJK3NN1 FJM2NN1 FJK2NN1 HVX4PL1 FJM1NN1 8XLF4F1 6X32KN9XA030 FJM3NN1 FJN1NN1 99D30G1 79D30G1 G5NQXH1 CQ4CGX1 no SN no SN US00002632 US00042238 3118A35482 3235A46821 CN10445037 3223A43525 3223A42509 2623A08375 3133A37065 3019A28656 3235A44680 lle tro on nc d PROPERTY DESCRIPTION U I N C. SV Room Agilent 6890 (G1530A) SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room AirGard 200 TEL AFA50 Genie Scientific Labconco HP 59822B HP 59822B HP 59822B Agilent 5973 (G2577A) Agilent 5973N/6890 5971 5971 Agilent 5973N 5971 SV Room LTM A58/A68PS US00024443 not available-in use TS 81351 none None 7520 2432 6392 US30945080 US62510092/US00028725 3118A02486 3114A02129 US44647056 2919A00438 1225 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 70 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Model # SERIAL # SV Room LTM A58/A68PS 1145 SV Room LTM A58/A68PS 1191 SV Room LTM A58/A68PS SV Room SV Room SV Room SV Room SV Room SV Room SV Room SV Room TAFT VWR Scientific-Revco Danby 'Designer' Emerson OR300A unknown unknown unknown unknown Nitrox Dell Optiplex 390 TAFT 1017 lle not available-in use 1196070021003920 63426502 240-980093 none none 3165524-28003 Hedy 211 Dell Inspiron 3521 TAFT TAFT TAFT TAFT TAFT Taft - Main Area RV12 HP5890 202 350B SCD355 Dell Inc. OptiPlex 390 96-2034907 Taft - Main Area MRT15CPEWO LA63409474 Taft - Main Area VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room Xitech Varian OI Analytical Varian Varian EST Model 8100 EST Model 8100 EST Model 8100 Entech 7016D Entec Model 3100A Dell Inc. Vostro 230 Dell Inc. Vostro 230 003392 13485 14117 14056 15123 14103 14032 13985 1391 1325 FJL1NN1 FJL3NN1 Dell Inc. OptiPlex 330 Dell Inc. OptiPlex 330 Hewlett-Packard Compaq dc7800 Small Form Factor Dell Inc. Optiplex 330 Dell Inc. Vostro 230 G9KMZY1 C9D30G1 Dell Inc. Vostro 230 Dell Inc. OptiPlex 330 FF53CP1 3YMGCG1 Kenmore 253.280… WB22349282 nc U d LOCATION on Modular Accelerated Column Heater (MACH) (not in service) Modular Accelerated Column Heater (MACH) 6890 – GC1 Modular Accelerated Column Heater (MACH) 6890 – GC3 Refrigerator, #5 (8081/8062 Stds.) Refrigerator, #6 (8015/8270 Stds.) Refrigerator, Emerson (small)(Stds) TCLP Extracation Vessels (N0.1) TCLP Extracation Vessels (N0.1) TCLP Extracation Vessels (N0.1) TCLP Extracation Vessels (N0.2) Zero Air Generator Computer Workstation - LH-OEC1 Computer Workstation - LH-OEC1 (Laptop) Edwards Pump Gas Chromatograph (OG GC03) Peak Simple SRI SCD Sievers Sievers Interface Controller Computer Workstation - T-OEC1 TAFT Sample Storage Refrigerator: White-Westinghouse Vacuum Pump Auto Sampler Archon (51 Pos) (GC4) Auto Sampler Archon (51 Pos) (GC7) Auto Sampler Archon (51 Pos) (MS9) Auto Sampler Archon (51 Pos) (MS11) Auto Sampler Archon (81 Pos) (MS12) Auto Sampler Archon (81 Pos) (MS5) Auto Sampler Archon (81 Pos) (MS13) Auto Sampler Tree (MS8) Canister Cleaner Entec Model 3100A Computer GC4 Computer GC7 Computer GCMS11 Computer GCMS5 Computer GCMS8 Computer GCMS9 Rev 06/30/2014 - CM tro PROPERTY DESCRIPTION Computer LAB02 VO Room Computer LAB05 Computer LAB12 Computer MS13 Computer OEC9 Computer Spare GCMSXX Cylinder Dolly Freezer (soil samples) VO Room VO Room VO Room VO Room VO Room VO Room VO Room I N C. 1220 0590-100 1220 JBC5LS1 2UA8150D55 4KXJ7V1 FJL2NN1 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 71 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Freezer, Kenmore (Stds) Gas Chromatograph (GC) (MS11) Gas Chromatograph (GC) (MS12) Gas Chromatograph (GC) (MS13) Gas Chromatograph (GC) (MS5) Gas Chromatograph (GC) (MS8) Gas Chromatograph (GC) (MS9) Gas Chromatograph (GC4) Gas Chromatograph (GC7) Gas Leak Detector Helium Detector Hood Air Flow Monitor VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room Hood, #17 VO Room Hot Plate (near Hood #17) Ionization Gauge Controller (GCMS8) Ionization Gauge Controller (MS11) Ionization Gauge Controller (MS12) Ionization Gauge Controller (MS5) Ionization Gauge Controller (Not Used) Lamp Power Supply (GC4) Lamp Power Supply (GC7) Mass Selective Detector (MS11) Mass Selective Detector (MS12) Mass Selective Detector (MS13) Mass Selective Detector (MS5) Mass Selective Detector (MS8) Mass Selective Detector (MS9) Oven for Entec 3100A Oven, Drying Power Supply, GCMS8 computer Power Supply, MS8 Entech instruments Preconcentrator, GCMS8 Purge unit, coupled ports (out of svc) Purge unit, coupled ports (MS11) Purge unit, coupled ports (MS12) Purge unit, coupled ports (MS13) Purge unit, coupled ports (MS5) Purge unit, coupled ports (MS9) Purge unit, coupled ports (out of svc) Purge Unit, Tekmar/DOHRMANN (GC4) Purge Unit, Tekmar/DOHRMANN (GC7) Purge Unit, Tekmar/DOHRMANN (out of svc) Refrigerator #3 (Aqueous samples) Refrigerator, small (stds) Rotators – Vol #3 Rotators – Vol #4 Scale – Balance, Top-Loading VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room nc U WB24445575 WB0326162 US10309009 US00035756 US00022331 US10145036 US10250006 CN10820018 2950A26689 2938A24839 E583001 205556 d VO Room SERIAL # Frigidaire Model # FKFH21F7HWD 253.267321 Agilent 6850N (G2630A) Agilent 6890 Plus+ Agilent 6890 Plus+ Agilent 6890N (G1530N) Agilent 6890N Agilent 6850N (G2630A) HP 5890 Series II HP 5890 Series II GOW-MAC 21-150 Varian 9694650 Tel-UK AFA 500 Fisher Science 'Contempra Fume' Corning “PC-400D” Agilent 59864B Agilent 59864B HP 59864A HP 59864A Agilent 59864B Model 4430 Model 4430 Agilent 5973N HP 5973 Agilent 5973 Netcore Agilent 5973N Agilent 5973N Agilent 5975C Thermo Sci 3513ET Quincy Lab Model: 40GC APC Back-Ups XS 1500 APC Back-Ups XS 1500 Entech 7200 (EST) Encon (EST) Encon (EST) Encon (EST) Encon (EST) Encon (EST) Encon (EST) Encon Velocity XPT 14-8900-OOT Velocity XPT 14-8900-OOT on Freezer (soil samples) (frost free) Model # lle LOCATION Rev 06/30/2014 - CM tro PROPERTY DESCRIPTION I N C. none 33307993520 US6017416 US60111438 1191 1466 US6018823 C131530155 11488-1-952 US21884505 US92522749 US03340488 US10441770 US10442515 US81819247 1482080191829 G4-005254 1098 334011404E & 165092601P 313011404E and P 165092601 E&334011404P 31701403E & P 31601403E & P 286072103 E&P US04260003 US03248004 VO Room Velocity XPT 14-8900-OET US04350002 VO Room VO Room VO Room VO Room VO Room Beverage-Air' Black & Decker Environmental Express Environmental Express OHAUS – Scout Pro 8045920 None None 7123260661 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 72 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Scale – Balance, Top-Loading Scale-Balance, Top loading (#14) Sonicator, cleaning (in hood #17) Stirrer (in hood, Vols. #17) Three wheel bike w/basket, Blue Three wheel bike w/basket, Red Torr Meter/Support Two Wheel Bike Universal Gas Flowmeter Vacuum Pump (MS11) Vacuum Pump (MS12) Vacuum Pump (MS5) Vacuum Pump (MS5) Vacuum Pump (MS8) Vacuum Pump (MS8) Vacuum Pump (out of svc) Vacuum Pump (Spare) Vacuum Pump, Entech Preconcentrator Vacuum Pump, Rough for Entec 3100A VGL Dolly Zero Air Generator Zero Headspace Extractor Zero Headspace Extractor Zero Headspace Extractor Zero Headspace Extractor Zero Headspace Extractor Zero Headspace Extractor Zero Headspace Extractor VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room VO Room - Outside cage WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Instrument Room WC Storage WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room OHAUS – Scout Pro Ohaus SP202 Fisher FS 30 Corning “PC-400D” 7123260277 B224021293 not available-in use 33307993520 lle 120911002 US12C53096 996165850 76221154 46280950 16934709 16981995 982180770 Ingersoll Rand 1203564 35900E 1100 Series-G1313A 1100 Series-G1312A 1100 Series-G1316A HP Pro 30000 MT 1100 Series-G1379A SEDEX75 HP Pro Curve-J409OA Emerson OR300 Shimadzu (TOC-5000A) Shimadzu (ASI-5000A) LQ-590 FisherSci-14-493-1205 Shimadzu (ASI-5000A) BottleBuret 50 BottleBuret 50 Harrier15/80 Beckman 356529 IEC HACH-16500-16 CN00006756 US72102135 US72100948 4592102402 MXL024295D JP40719711 0170588D TW328NZOUT 63426502 36N01407A 36902235 FSQY168939 1685060538998 36902235 DB C5528 10 0 1833 MSE-9696/08/1d 7L003 428-22363 870108633 tro Agilent ADM1000 Edwards RV3 Edwards RV3 Edwards RV3 Edwards RV3 Edwards RV3 Edwards RV3 GAST DDA-P704-AA Edwards RV3 VACUBRAND ME1 VACUBRAND MZ2 Saf-T-Cart Parker HPZA-30000 Millipore #1 Millipore #4 Millipore #5 Millipore #C Millipore #13 Millipore #14 Environmental Express on nc HPLC-Agilent Interface HPLC-ALS HPLC-Bin Pump HPLC-Col Comp HPLC-Computer Workstation HPLC-Degasser HPLC-SEDEX75 LAN/HUB, HP ProCurve Refrigerator, Floor Unit TOC (Total Organic Carbon) Analyzer TOC Auto Sampler TOC Printer Stir Plate, Small Benchtop Auto Sampler for TOC Buret, Bottletop (Hood 7) Buret, Bottletop (Hood 7) Cenrifuge, Benchtop Model Centrifuge, Floor model Centrifuge, Table Model COD-Hotblock Computer LAB11 U Cole Parmer Model# 68801-03 d PROPERTY DESCRIPTION Air Compressor I N C. 36144613 30770001 none none none none none none none 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 73 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM PROPERTY DESCRIPTION LOCATION Model # Computer Workstation-LAB14 Computer Workstation-LAB15 Computer Workstation-OEC22 Condensor/vaporizer (#1) - Hood 13 Condensor/vaporizer (#2) - Hood 11 Condensor/vaporizer (#3) - Hood 14 Condensor/vaporizer (#4) - Hood 12 Conductivity meter Dessicator, glass (round) Dessicator, plastic cabinet, (Square) Dessicator, plastic cabinet, (Square) Dismembrator, sonic (HOOD #10) Dismembrator, sonic (HOOD #12) Dismembrator, sonic (HOOD #13) Distillation - Ammonia Distillation - Cyanide Distillation - Phenol Distillation – TKN Flashpoint (Automated) WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room Dell Opiplex 3010 Dell Opiplex 3010 Optiplex 380 Caliper TurboVap II Caliper TurboVap II Caliper TurboVap II Caliper TurboVap II Myron L none Fisher Scientific Sanko Fisher Sci 500 Fisher Sci 500 Fisher Sci 500 Easy Distillation Easy Distillation Easy Distillation Easy Distillation Tanaka APM-7 WC/SV Prep Room J2 Scientific AccuPrep MPS PLH-1097-1.0 WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room AirGard 200 Genie 5' Single Sash Genie 5' Single Sash Genie 8' Double Sash none Genie 5' Single Sash Genie SafeAire SafeAire St. Charles Genie Metrohm 819 Metrohm 819 Metrohm 788 Metrohm 788 Metrohm 830 Metrohm 830 Metrohm 833 Metrohm 833 Metrohm 818 Metrohm 818 Metrohm 820 Metrohm 820 Dell Inc. OptiPlex 330 Custom Vulcan A1750 Delonghi SafeHeat Blue M' Isotemp 650G 13-246-506G TSS 81360 None U SERIAL # Muffle Furnace WC/SV Prep Room Oven Oven #1 (Fisher Sci) WC/SV Prep Room WC/SV Prep Room d 42946185601 18134347033 TV0553N12804 TV0445N12717 TV0730N3880 TV0842N14837 172519 none none lle tro nc on Gel Permeation Cleanup Instr. (Hood #6) Hood air monitor (ALNOR) (Hood#11) Hood, #10 Hood, #10 Hood, #6 Hood, #7 Hood, #8 Hood,#11 Hood,#12 Hood,#13 Hood,#14 Hood,#9 IC Detector 1 IC Detector 2 IC Filtration Sample Processor 1 IC Filtration Sample Processor 2 IC Interface unit 1 IC Interface unit 2 IC Liquid Handling Unit 1 IC Liquid Handling Unit 2 IC Pump 1 IC Pump 2 IC Separation Center 1 IC Separation Center 2 IC1 Computer Workstation IC2 Computer Workstation I N C. BCK09035896A BBW04112875 BCK08054855A Control Unit: 20531 Test Unit: 23271 None none None 81360 PP22E-3 OP22A-9 PA-3-8 None 1819001003198 1819001006114 1788001006141 1788001007106 1830002003158 1830002006117 1833001002200 1833001008123 1818011003129 1818011005207 1820022003126 1820023005180 HQLS4H1 DCL0613104 12A-1631 103N0065 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 74 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, APPENDIX C – OEC EQUIPMENT LIST Rev 06/30/2014 - CM LOCATION Model # SERIAL # Oven, drying Oven, drying, ThermoSci Oven, drying, ThermoSci pH Meter, VWR pH Meter, VWR Pipet, Automatic: 0.5-10uL Pipettor, 100-1000uL Pipettor, 10-100uL Pipettor, 20-200uL Pipettor, 20-200uL Pipettor, 500-5000uL Printer Printer Refrigerated Recirculator Refrigerator, Floor Unit Scale – Balance, Top-Loading Scale – Balance, Top-Loading Sep. Funnel Shaker, Floor model Spectrophotometer – SPEC 20 Spectrophotometer – SPEC 20 Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stir Plate, Small Benchtop (Hood 8) Stirrer Stirrer Hotplate, Cole-Parmer Stirrer Hotplate, Cole-Parmer Stirrer, Fisher Sci Thermometer, Electric Thermometer, Electric Thermometer, Electric Thermometer, Electric Thermometer, Electric Turbidimeter, HF Scientific Turbidimeter, HF Scientific Turbidimeter, LciMOTTE Vacuum Pump Vacuum Pump Vortex Mixer WILKS Infra Cal TOG/TPH Analyzer Scale – Balance, Top-Loading Scale – Balance, Top-Loading Scale – Balance, Top-Loading Scale – Balance, Top-Loading Scale – Balance, Top-Loading Scale – Balance, Top-Loading Scale – Balance, Top-Loading WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room WC/SV Prep Room Weigh Room Weigh Room Weigh Room Weigh Room Weigh Room Weigh Room Weigh Room Thermo Scientific Precision Precision-51221126 Precision-51221126 'SR601C' sympHony ‘SB90M5 sympHony’ Eppenorf Research 10 Eppenorf Research Plus 1000 ThermoLabSystems 4500 Eppenorf Research 200 Eppenorf Research 200 Eppenorf Research Plus 5000 Bother-MFC-7460DN HP Lasejet P2035 Cordley SANYO-SR-360X Ohaus PA214 OHAUS – CS-200 Glas-Col 099A VS5504 4001/4 4001/4 FisherSci-14-493-1205 FisherSci-14-493-1205 FisherSci-14-493-1205 FisherSci-14-493-1205 FisherSci-14-493-1205 FisherSci-14-493-1205 FisherSci-14-511-01 Corning 'PC-410' HS19C-P HS19C-P 'Thermix 120S' FisherSci-15-077-29 FisherSci-15-077-29 FisherSci-15-077-29 FisherSci-15-077-29 FisherSci-15-077-29 Micro 100 Series-20001 Micro 100 Series-20001 LciMOTTE '2020' DOA-P704-AA DOA-P704-AA FisherSci-02215365 HATR-T2 A&D – HF-400 OHAUS – Scout Pro (SP) 202 OHAUS – AS200 OHAUS – AV313 OHAUS – SP202 OHAUS – SP202 OHAUS – SP601 604171 604171 600091525 4406 D04628 2388848 N262313 U13540 3605278 Q24320B R2606613 U62701L3N261757 VNB3B67021 not available-in use 951073348 8329230036 89562 473480 3SGL297001 3SGE170004 C1685100816369 C1685100816351 106N1036 C1685100816337 105NO819 105NO822 7G3 350401113803 10210906 3161107 105NO822 91173791 101605096 2902013918 24020134 72498811 406180 20848 1156-1699 1008622631 308608627 8009018 12702 12843372 7123260283 2741 8028041093 B224021292 B224021299 B211775945 lle tro on nc d PROPERTY DESCRIPTION U I N C. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 75 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX D – SAMPLE TREATMENT: HOLDING TIMES & CONTAINERS 8015 mod./LUFT by GC or LUFT by GC/MS GC (8015,8021) GC/MS (8260) Volatile Organic Compounds TPH diesel, diluent, crude, motor oil, (TEPH), C10-C40 PNA, BNA, PNA-SIM or Pesticides/PCBs TCLP Volatiles TCLP Semivolatiles Oil & Grease (HEM) or (SGT-HEM) Inorganic Analyte Analysis Mercury STLC or DI WET or TCLP extraction Anions by IC aq soil aq soil aq 524.2*/624/8260B aq soil 8015 mod./LUFT by aq GC or LUFT by GC/MS soil 625/8270C aq 8081 / 8082 soil aq 8260 soil aq 8270 soil 2 VOAs 4 oz jar or tube 3 VOAs 4 oz jar or tube 3 VOAs 3 VOAs 4 oz jar 1 L amber 4 oz jar 1 L amber 4 oz jar 1 L amber 8 oz jar 1 L amber 8 oz jar HCl 4 ± 2⁰C HCl 4 ± 2⁰C pH<2, HCl 4 ± 2⁰C 4 ± 2⁰C 1664A aq 1 L amber aq soil aq soil aq soil aq soil aq soil aq soil aq soil aq soil aq aq aq soil aq aq aq soil aq aq 250 mL poly HNO3 6 mo. 4 oz jar 4 ± 2⁰C 6 mo. 250 mL poly HNO3 28 days 4 oz jar 4 ± 2⁰C 28 days 1 L amber glass 6 mo. 6 mo. 4 ± 2⁰C 4 oz jar Hg 28 days Hg 28 days 250 mL poly Br, Cl, F, SO4: 28 days 4 ± 2⁰C NO2, NO3, PO4: 48 hr 4 oz jar 250 mL poly 4 ± 2⁰C 14 days 4 oz jar 1 L poly NaOH;4±2⁰C 14d/24hr if S- present 4 oz jar 4 ± 2⁰C 14 days 500 mL am poly NaOH;Zn(C2O2H3)2;4±2⁰C 7 days 4 oz jar 4 ± 2⁰C 250 mL poly 4 ± 2⁰C ASAP 4 oz jar 250 mL poly 4 ± 2⁰C 28 days 250 mL poly 4 ± 2⁰C 14 days 500 mL poly H2SO4;4±2⁰C 28 days 4 oz jar 4 ± 2⁰C 250 mL am glass HCl; 4±2⁰C 28 days 250 mL poly 4 ± 2⁰C 48 hr 500 mL glass 4 ± 2⁰C n/a 4 oz jar 250 mL poly 4 ± 2⁰C 7 days 1 L poly 4 ± 2⁰C 48 hr *Contact OEC for complete sampling instructions 200.7 / 200.8 6010B / 6020 7470 7471 CAL WET/DIWET 1311 300.0 SW-846: 7.3.3.2 & 7.3.4.2 4500CN-C/E 9014 nc Reactive Cyanide & Reactive Sulfide Preserve Cyanide, Total/Amenable/Free Sulfides, Total 9030B & 9034 Conductivity Alkalinity 4500-H+ B/9040B 9045C 2510B 2320B Ammonia or TKN 4500NH3-D Total Organic Carbon Turbidity 5310B 2130B Flashpoint/Ignitability 1010 Residues, Total, TDS, TSS, TVS Residue, Settleable 2540B, C, D 2540F U pH 4 ± 2⁰C 4 ± 2⁰C 4 ± 2⁰C 4 ± 2⁰C HCl (prefer)or H2SO4 28 days incl. extraction on Metals by ICP or ICP/MS Analytical Extraction Hold Time Hold Time 14 days n/a 14 days n/a 14 days n/a 14 days n/a 14 days n/a 7 days or 1 day (524.2) 14 days n/a 40 days 7 days 40 days 14 days 40 days 7 days 40 days 14 days 14 days 14 days 14 days 14 days 40 days 14 days 14 days 14 days Container d TPH gasoline (TVPH), C4-C10 or C4-C12 BTEX / MtBE / Oxygenates Matrix lle Method tro Organic Analyte Analysis 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 76 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES EPA Method Matrix & Reporting Limit DW (mg/L) AQ (mg/L) SO (mg/kg) Bromide 0.05 0.4 5 Chloride 0.4 0.4 5 Fluoride 0.1 0.4 5 Nitrate or Nitrite as N 0.4 0.4 5 Orthophosphate as P 0.05 0.4 5 Sulfate 0.4 0.4 5 Alkalinity 10 --Ammonia as N 0.1 5 Total Kjeldahl Nitrogen 0.25 20 Biochemical Oxygen Demand (BOD) 4 --& Carbonaceous BOD (CBOD) Chemical Oxygen Demand (COD) 20 --Chlorine, Total & Free 0.1 0.1 --Conductivity 2 μmhos/cm --Cyanide, Total / Amenable 0.04 / 0.02 0.4 Flashpoint (Ignitability) 1 ⁰F 1 ⁰F MBAS 0.05 0.05 --Analyte SM2320B SM 4500-NH3 D SM5210B on EPA 410.4 / SM 5220D SM4500-Cl G EPA 120.1 / SM2510B SM 4500CN-C,E / 9014 EPA 1010 SM 5540C EPA 1664A / 1664A SGC WILKS Screen SM4500-O G EPA 9040B/9045 SM5530 & EPA 420.1 tro EPA 300.0 lle d INORGANICS nc Oil & Grease / TRPH Oil & Grease / TRPH Oxygen, Dissolved pH (Corrosivity) Phenolics, Total Reactive Cyanide Reactive Sulfide Salinity Solids, Settleable (SETT) Solids, Total / % Moisture Solids, Total Dissolved (TDS) Solids, Total Suspended (TSS) Solids, Volatile (VS) EPA SW-846 7.3 U SM2520B SM2540F SM2540B SM2540C SM2540D SM2540G SM4500-S= E / EPA 9034 & 376.1 SM 5310B EPA 180.1 / SM2130B Sulfide, Total Total & Dissolved Organic Carbon Turbidity 5 10 1 0.1 unit 0.05 0.1 0.4 1 0.1 10 10 10 10 100 ----0.1 unit --0.5 2 ----0.5% ------- 2 --- 0.5 0.5 NTU 1 --- 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 77 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) DW / AQ (mg/L) SO (mg/kg) 0.2 0.05 0.02 0.02 0.01 0.1 0.005 0.2 0.01 0.01 0.02 0.05 0.01 0.025 0.05 0.01 --0.005 0.005 0.05 1 0.05 0.1 0.01 1 0.01 0.02 0.05 0.05 0.05 0.02 0.05 10 2.5 1 1 0.5 5 0.25 10 0.5 0.5 1 2.5 0.5 5 2.5 0.5 --0.5 0.25 2.5 25 2 --0.5 25 0.5 1 2.5 2.5 2.5 1 1 on nc U ICP Methods EPA 200.7 & 6010B DW (mg/L) 0.05 0.002 0.002 0.002 0.001 0.025 0.001 0.1 0.003 0.001 0.002 0.05 0.001 0.001 0.1 0.002 0.0002 0.001 0.003 0.05 0.1 0.002 0.05 0.001 0.2 0.02 0.001 0.001 0.02 --0.005 0.005 ICP/MS Methods EPA 200.8 & 6020 AQ SO (mg/kg) (mg/L) 0.1 20 0.004 1 0.005 0.5 0.004 1 0.002 0.5 0.05 10 0.002 0.5 0.2 25 0.006 1 0.002 0.5 0.004 1 0.1 20 0.002 0.5 0.002 0.5 0.2 25 0.004 1 --0.5 0.002 1 0.006 20 0.1 25 0.2 1 0.004 20 0.01 --0.002 0.5 0.4 50 0.04 5 0.002 0.5 0.002 4 0.04 5 ----0.01 2 0.01 2 tro Analyte d Chromium, Hexavalent Hardness, Total Hardness, Total Iron, Ferrous Mercury Phosphorus, Total & o-PO4 Matrix & Reporting Limits Aluminum Antimony Arsenic Barium Beryllium Boron Cadmium Calcium Chromium Cobalt Copper Iron Lead Lithium Magnesium Manganese Mercury Molybdenum Nickel Phosphorus Potassium Selenium Silicon Silver Sodium Strontium Thallium Tin Titanium Tungsten Vanadium Zinc Matrix & Reporting Limits AQ (mg/L) SO (mg/kg) 0.01 2.5 10 --2 --0.050 --0.0002 0.1 0.025 --- Analyte lle Method METALS SM 3500 Cr-B & 7196A SM2340B SM2340C SM 3500 Fe-B 245.1 /7470/7471 EPA 365.3 / SM 4500-P E 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 78 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) Matrix & Reporting Limit Analyte TPH ORGANICS Volatile LUFT EPA 8015 & GCMS SO (mg/kg) 50 0.5 TPH-Gasoline from TPH-Motor Oil TPH-Gasoline 50 10 10 50 50 50 0.5 tro TO-15 0.1 0.05 0.02 0.1 0.1 0.5 lle TPH-Crude Oil TPH-Diesel TPH-Diluent TPH-Mineral Oil TPH-Motor Oil TPH-Crude Oil Semi-Volatile EPA 8015 / LUFT Semi-Volatile GCMS / LUFT (where different 8015) AQ (μg/L) d EPA Method 50 AIR (ppbv) 200 APPENDIX E – DATA CAPABILITY TABLES (continued) TPH-Gasoline U 524.2 / 624 / 8260B DW (μg/L) Methanol Benzene Toluene Ethylbenzene Xylenes (total) Methyl-t-butyl ether (MtBE) nc EPA 8021 Analyte on EPA Method VOLATILE ORGANICS Volatile LUFT EPA 8015 & GCMS EPA 8015 Total THM Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane 2-Chloroethylvinyl ether Chloroform 1.0 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1 0.5 Matrix & Reporting Limit AQ (μg/L) SO (mg/kg) 50 0.5 1000 5 0.5 0.5 0.5 0.5 0.5 0.005 0.005 0.005 0.005 0.005 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1 0.5 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 79 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Matrix & Reporting Limit AQ (μg/L) SO (mg/kg) 0.5 0.005 0.5 0.005 0.5 0.005 1 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 0.5 0.005 d Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,3-Dichloropropene (Total) Ethylbenzene 1,2-Dibromoethane (EDB) Hexachlorobutadiene Isopropylbenzene 4-Isopropyl Toluene Methylene chloride Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride DW (μg/L) 0.5 0.5 0.5 lle Analyte U nc on tro EPA Method VOLATILE ORGANICS 524.2 / 624 / 8260B (continued) 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.005 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 80 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) t-Amyl Methyl Ether (TAME) t-Butyl alcohol (TBA) Diisopropyl Ether (DIPE) Ethanol (EtOH) Ethyl t-Butyl Ether (EtBE) Methyl-t-butyl ether (MtBE) Acetone Acetonitrile Acrolein Acrylonitrile Allyl Chloride 2-Butanone (MEK) Carbon Disulfide Chloroprene Ethyl Methacrylate 2-Hexanone Iodomethane Isobutyl Alcohol Methyl Isobutyl Ketone (MIBK) Methyl Methacrylate 2-Propanol Propionitrile 1,1,2-Trichloro-1,2,2-Trifluoromethane (Freon 113) Vinyl Acetate Matrix & Reporting Limit AQ (μg/L) SO (mg/kg) 0.5 0.5 5 0.5 AQ (μg/L) 0.5 10 0.5 500 0.5 0.5 0.005 SO (mg/kg) 0.005 0.025 0.005 5 0.005 0.005 5 100 10 10 10 10 2 20 10 10 5 100 10 30 10 150 0.05 10 5 0.5 5 1 2 20 0.1 0.005 0.1 1 2 0.5 0.005 2 0.005 U nc on tro Appendix & Specialty m,p-Xylene o-Xylene Xylenes (Total) DW (μg/L) 0.5 0.5 0.5 DW (μg/L) 0.5 2 0.5 d 6 Oxygenates (8260) Analyte lle EPA Method VOLATILE ORGANICS 524.2 / 624 / 8260B (continued) 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 81 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) Gasoline (C4 – C12) Acetone Benzene Benzyl chloride Bromodichloromethane Bromoform Bromomethane 1,3-Butadiene Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane Cyclohexane Dibromochloromethane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane (EDC) 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans-1,3-Dichloropropene 1,2-Dichloro-1,1,2,2-Tetrafluoroethane (Freon 114) Diisopropyl Ether (DIPE) 1,4-Dioxane Ethanol Ethyl Acetate Ethylbenzene Ethyl t-Butyl Ether (EtBE) 4-Ethyltoluene Heptane Hexachlorobutadiene Hexane 2-Hexanone Isopropyl alcohol (IPA) Methylene chloride 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 U nc on tro lle TO-15 Full List Matrix & Reporting Limit AIR (ppbv) 200 Analyte d EPA Method VOLATILE ORGANICS TPH 0.5 0.5 0.5 2 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 82 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) Methyl Ethyl Ketone (MEK) Methyl Isobutyl Ketone (MIBK) Methyl-t-butyl ether (MtBE) Naphthalene Propylene Styrene t-Amyl Methyl Ether (TAME) t-Butyl alcohol (TBA) 1,1,2,2-Tetrachloroethane Tetrachloroethene (PCE) Tetrahydrofuran Toluene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane (TCA) 1,1,2-Trichloroethane Trichloroethene (TCE) Trichlorofluoromethane (Freon 11) 1,1,2-Trichlorotrifluoroethane (Freon 113) 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl acetate Vinyl chloride Xylenes (total) Matrix & Reporting Limit AIR (ppbv) 0.5 0.5 0.5 1 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 d Analyte 0.5 0.5 0.5 0.5 0.5 0.5 U nc on tro lle EPA Method VOLATILE ORGANICS TO-15 Full List (continued) 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 83 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) Acenaphthene Acenaphthylene Aniline Anthracene Azobenzene Benz(a)anthracene Benzo (b) fluoranthene Benzo (k) fluoranthene Benzo (a) pyrene Benzo (g,h,i) perylene Benzoic acid Benzyl alcohol Bis(2-chloroethoxy)methane Bis(2-chloroethyl)ether Bis(2-chloroisopropyl) ether Bis(2-ethylhexyl) phthalate 4-Bromophenyl phenyl ether Butyl benzyl phthalate 4-Chloroaniline 2-Chloronaphthalene 4-Chlorophenyl phenyl ether Chrysene Dibenz (a,h) anthracene Dibenzofuran Di-n-butyl phthalate 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene 3,3'-Dichlorobenzidine Diethyl phthalate Dimethyl phthalate 2,4-Dinitrotoluene 2,6-Dinitrotoluene Di-n-octyl phthalate Fluoranthene Fluorene Hexachlorobenzene d 10 10 10 10 10 10 10 10 10 10 10 10 5 10 10 5 10 10 10 10 5 10 10 10 10 10 10 10 5 10 10 5 5 10 10 10 10 U nc on tro EPA 625 / 8270C Matrix & Reporting Limit AQ (mg/L) SO (mg/kg) 0.1 50 0.05 10 0.02 10 0.1 50 0.1 50 0.5 50 0.5 50 lle EPA Method Analyte SEMI-VOLATILE ORGANICS TPH-Crude Oil TPH-Diesel EPA 8015 / LUFT TPH-Diluent TPH-Mineral Oil TPH-Motor Oil GCMS / LUFT TPH-Crude Oil (where different from 8015) TPH-Motor Oil 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 84 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) lle d Matrix & Reporting Limit AQ (mg/L) SO (mg/kg) 10 0.1 5 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.25 10 0.1 5 0.1 5 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 5 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 0.1 10 10 U nc on tro EPA Method Analyte SEMI-VOLATILE ORGANICS EPA 625 / 8270C Hexachlorobutadiene (continued) Hexachlorocyclopentadiene Hexachloroethane Indeno (1,2,3-cd) pyrene Isophorone 2-Methylnaphthalene Naphthalene 2-Nitroaniline 3-Nitroaniline 4-Nitroaniline Nitrobenzene N-Nitrosodimethylamine N-Nitrosodi-n-propylamine N-Nitrosodiphenylamine Phenanthrene Pyrene Carbazole 1,2,4-Trichlorobenzene 4-Chloro-3-methylphenol 2-Chlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 4,6-Dinitro-2-methylphenol 2-Methylphenol 3 & 4-Methylphenol 2-Nitrophenol 4-Nitrophenol Pentachlorophenol Phenol 2,4,5-Trichlorophenol Pyridine 2,4,6-Trichlorophenol Specialty 8270 Creosote PNA-SIM EPA 8270M Acenaphthene Acenaphthylene Anthracene Benz(a)anthracene Benzo (b) fluoranthene Benzo (k) fluoranthene Benzo (a) pyrene Benzo (g,h,i) perylene Chrysene Dibenz (a,h) anthracene 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.005 0.005 0.005 0.005 0.005 0.005 0.005 0.01 0.005 0.01 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 85 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX E – DATA CAPABILITY TABLES (continued) 1,4-Dioxane Analyte Pesticides 608 / 8081A alpha-BHC alpha-Chlordane Aldrin beta-BHC delta-BHC 4,4'-DDD 4,4'-DDE 4,4'-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Endrin Endrin Aldehyde Endrin Ketone gamma-BHC gamma-Chlordane Heptachlor Heptachlor Epoxide Methoxychlor Chlordane, Technical Toxaphene nc on tro EPA Method lle EPA 1625M Matrix & Reporting Limit AQ (mg/L) SO (mg/kg) 0.1 0.005 0.1 0.005 0.1 0.005 0.1 0.01 0.1 0.005 0.1 0.005 AQ (μg/L) 1 Matrix & Reporting Limit AQ (μg/L) SO (mg/kg) Prod (mg/kg) 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.1 0.003 0.9 0.5 0.02 6 0.5 0.02 6 d EPA Method Analyte SEMI-VOLATILE ORGANICS PNA-SIM (continued) Fluoranthene EPA 8270M Fluorene Indeno (1,2,3-cd) pyrene Naphthalene Phenanthrene Pyrene U PCBs 608 / 8082 PCB-1016 PCB-1221 PCB-1232 PCB-1242 PCB-1248 PCB-1254 PCB-1260 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.02 0.02 0.02 0.02 0.02 0.02 0.02 4 4 4 4 4 4 4 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 86 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS Evaluation of Initial Calibration EVALUATION OF INITIAL CALIBRATION lle d Analyze calibration blank and calibration standards tro Calculate either the correlation coefficients or the average response factors for each analyte. Does the correlation coefficient or the average response factor meet method specified limits? Isolate and correct the source of the non-linearity. on Yes No nc Analyze initial calibration verification (ICV) standard and calculate % recoveries or %D of average response factors for each analyte. U Is the % recovery or %D data within method specified limits? No Is the % recovery or %D data within method specified limits? No Yes Isolate and correct ICV recovery problem then reanalyze ICV. Yes Begin analysis of method blanks, samples and QC spikes 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 87 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Continuing Calibration EVALUATION OF CONTINUING CALIBRATION on Yes Isolate and correct the source of the problem. Yes Reanalyze the CCV and calculate % recoveries or %D of average response factors for each analyte. Is the % recovery or %D data within method specified limits? No Reanalyze CCV and/or reanalyze calibration standards to generate a new calibration curve. Then reanalyze ICV. U nc Continue sample analysis. lle No tro Is the % recovery or %D data within method specified limits? d Analyze continuing calibration verification (CCV) standard and calculate % recoveries or %D of average response factors for each analyte. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 88 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Method Blank and Instrument Blank Results EVALUATION OF METHOD BLANK AND INSTRUMENT BLANK RESULTS d Are method blank and/or instrument blank results less than the RL (Reporting Limit) for a target analyte? lle Reanalyze blanks and samples as appropriate. Yes No tro Isolate and remove the source of the contamination. on Yes Has this contamination affected the sample results? (Is the blank response >5% of any related sample response?) Report blank results with an appropriate footnote. U nc Report blank results as ND (not detected). No 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 89 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Sample Results for Analytes EVALUATION OF SInorganic AMPLE RESULTS FOR INORGANICS ANALYTES lle d Is the appearance of the sample or the prepared sample normal? No Is the sample result within the calibration range? No Is the precision of the duplicate analysis within method-specified limits? nc Yes Is the matrix spike recovery within method specified limits? Yes U Dilute sample to midrange and re-analyze. on Yes tro Consider filtering or diluting the sample before analysis. (If diluted, raise the RL appropriately.) Yes Report the results. No Reanalyze the sample and the sample duplicate. No Is the post-digestion MS recovery within methodspecified limits? Yes Report the results, but qualified due to matrix interference. No Consider qualifying the sample(s) using the method of standard additions. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 90 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Sample Results for Organic Analyses EVALUATION OF SAMPLE RESULTS FOR ORGANIC ANALYSES For GC/MS analyses, are samples analyzed within the 12-Hour Tune window? Reanalyze outlying samples. d No Review peak integration and retention limits. No No Yes Correct problem and reanalyze appropriate samples. No Yes Correct problem and reanalyze appropriate samples. Has this change affected sample results? tro Are retention times consistent and within retention time windows (0.06 RRT units for GC/MS methods? lle Yes Are internal standard areas within method-specified limits? Yes on Are surrogate recoveries within method-specified or laboratoryestablished control limits? No Refer to flowchart for evaluation of surrogate recoveries. Yes nc Are target analyte concentrations within the initial calibration range? U Report the results. Dilute samples to mid-range and reanalyze. Yes Are obvious matrix interferences present? Yes Cleanup the sample using the appropriate technique(s) and reanalyze using the same or modified procedure. No If there are positive results, are they confirmed in the conformational analysis? (Req’d for GC/PID/ECD only; MS is considered confirmatory.) Yes No Adjust RL values to reflect any changes (dilutions, etc.) in the modified analytical procedure. No Report the negative confirmation results as Not Detected (ND). 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 91 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Surrogate Compound Recoveries EVALUATION OF SURROGATE COMPOUND RECOVERIES Yes Report the results. Yes Reanalyze the affected samples to confirm the interference. No No tro Is there matrix interference present for any analyte? lle Are the surrogate % recoveries within method-specifies or labestablished control limits? d Calculate surrogate % recoveries for each sample batch. Yes on Are all the surrogate recoveries above the upper limit and the sample result(s) all ND? No Did the sample produce an emulsion, or did a precipitate form during the extraction step? Yes Report the results qualified with appropriate footnote. nc No U Reanalyze the sample(s) and calculate the surrogate %recoveries. Are the surrogate % recoveries within method-specifies or labestablished control limits? No Report the results from the second analysis. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 92 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) EVALUATION OF LABORATORY CONTROL SAMPLE & DUPLICATE (LCS/LCSD) Analyze LCS (& LCSD as appropriate). Yes No No on Are RPD values within methodspecified or laboratoryestablished control limits? Yes No Are % recovery & RPD values within method-specified or laboratory-established control limits? Yes Reanalyze (or re-extract & reanalyze) all associated samples. U nc Report LCS results. Isolate and correct the source of the problem. Reanalyze LCS/LCSD. tro Are % recovery data within method-specified or laboratoryestablished control limits? lle d Evaluation of Laboratory Quality Control Sample & Duplicate 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 93 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation of Matrix Spike Recoveries EVALUATION OF MATRIX SPIKE & DUPLICATE (MS/MSD) RECOVERIES Yes Report the results. Report results with a qualifier indicating that native sample analyte levels are too high to reflect any degree of accuracy. tro No lle Is the matrix spike % recovery data within method-specified or lab-established control limits? d Calculate % recoveries of all matrix spike analytes in the MS & MSD samples. Is the matrix spike level at least five times the level of a spike analyte found in the un-spiked sample? No Yes Yes Reanalyze the sample and its MS/MSD. Are any of the matrix-spiked analytes positive detections (above RL) in the samples? on Subtract related sample contribution. nc No U Are there matrix interferences present? Dilute if necessary and reanalyze. Yes Report the results with a qualifier indicating that matrix interference is present. No Are the results for the associated LCS within control limits? or Yes Report the results qualified with an appropriate footnote. No Reanalyze all the samples and the matrix spiked sample in the batch. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com Quality System Manual Page 94 of 94 Rev 18 – JULY 2014 O I L F I E L D E N V I R O N M E N T A L & C O M P L I A N C E, I N C. APPENDIX F – QC DATA EVALUATION FLOWCHARTS (CONT.) Evaluation ofUPLICATE Duplicate Sample(DUP) and/orAND Matrix Results PRECISION EVALUATION OF D SAMPLE /OR Spike MS DDuplicate UPLICATE (MSD) No Is the sample homogenous? No on Yes lle Yes Report the results. tro Is the RPD data within methodspecified or lab-established control limits? d Calculate the relative %difference (RPD) for duplicate sample results or for duplicate matrix spike results. Are the sample results less than five times the RL? Yes Report the results with a qualifier concerning the nonhomogenous nature of the sample. Report the results with a footnote indicating that the high RPD is due to the results being near the PQL. No U nc Reanalyze the duplicates or duplicate matrix spikes. If reanalysis also produces similar out-of-control results, report the results qualified with an appropriate footnote. 307 ROEMER WAY | SANTA MARIA | CA 93454 | (805)922 -4772 | FAX (805)925-3376 | oecusa.com
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