High Performance Piezoelectric and Magnetoelectric Textured Ceramics By Yongke Yan

High Performance Piezoelectric and Magnetoelectric Textured Ceramics
By Yongke Yan
Background: Oriented relaxor-PT single crystals possess ultrahigh piezoelectric coefficient and
electromechanical coupling factor k33 on the order of > 2000 pC/N and ~ 0.9 respectively, far
outperforming the state-of-art Pb(Zr,Ti)O3 (PZT) polycrystalline ceramics. However, the application of
single crystal has been limited due to the high production cost. To overcome the high production cost and
limited size of single crystal, we have developed <001> textured relaxor-PT/PZT piezoelectric ceramics
via templated grain growth (TGG) method, which show the property comparable to that of single crystal
but the cost close to that of traditional ceramics.
(a)
(200)
(210)
(211)
Highly Textured Ceramics: We have synthesized a series of highly textured ceramics, such as
PMN-PT, PMN-PZT, and Mn doped PMN-PZT.
(111)
•
(110)
Texturing Process: A method called templated grain growth (TGG) was developed to fabricate
textured ceramics. In order to obtain the textured ceramics, micro-sized template crystals are aligned
in the ceramic matrix powders using tape-casting method. During high temperature sintering,
epitaxial growth occurs on the template seeds giving rise to textured grains. This method is based on
industrial well-established ceramic process, which guarantees low cost.
(100)
•
(b)
Intensity (a.u.)
-5BT, f=0.99
<001>BT
-0BT
-1BT
-3BT, f=0.98
111
(c)
-1BT, f=0.98
001
101
-0BT, f=0
20
30
40
50
2 theta (deg.)
60
20 µm×20 µm
1 100 µm×100 µm
June, 2014 High Energy Density Textured Ceramics: We have demonstrated the texture microstructure yielded
a giant magnitude of d·g coefficient with value of 59000 × 10-15 m2 N-1 (comparable to that of the
single crystal counterpart and 359% higher than that of the best commercial compositions).
(a)
60
Company 1
Company 3
g33 (×10-3 Vm N-1)
50
(b) 6
Company 2
T-PMN-PZT
30
(ii)
20
(i)
10
BNT-based
PMN-PT
KNN-based
T-PMN-PZT
5
(iii)
40
d33(T)/d33(R)
•
4
3
2
1
0
0
200
400
600
800 1000 1200
0
300
d33 (pC N-1)
•
600
900 1200 1500 1800
d33(T) (pC N-1)
Radially Textured Ceramics: We have demonstrated PMN-PT cylinders with ~98% <100>C texture
along the radial direction. A giant enhancement in the magnitude of electromechanical coupling
factor (k31=kh=0.60, and kl=0.7) was obtained for textured cylinder, and d31×g31 was measured to be
6766×10-15 m2/N which is 3 to 6 times higher than that of commercial PZT compositions.
Sample
PZT-4a
PZT-5Aa
PZT-5Ha
PZT-8a
T-PMN-28PT-50%-Cb
R-plate
T-plate
T-cylinder
ε33T/ε0
1200
1700
3400
1000
2996
2781
2591
2820
tanδ
0.003
0.020
0.025
0.004
0.003
0.020
0.006
0.006
s11E
12.3
16.4
16.4
11.5
13.6
12.1
18.8
18.8
k31
0.33
0.34
0.39
0.30
0.43
0.35
0.57
0.60
2 kl
0.50
0.70
kp
0.56
0.60
0.65
0.51
0.66
0.92
d31
(pC/N)
122
171
274
97
259
208
371
411
g31
(10 Vm/N)
11.1
11.4
9.11
10.9
9.8
8.2
16.2
16.5
-3
d31×g31
(10-15 m2/N)
1354
1949
2496
1057
2538
1703
6003
6766
June, 2014 •
Cofired Magnetoelectric Composite: We have demonstrated integration of textured piezoelectric
with the cost-effective low-temperature co-fired layered structure to achieve strong magnetoelectric
coupling. Using the co-fired composite, a strategy was developed based upon the hysteretic response
of nickel-copper zinc ferrite magnetostrictive materials to achieve peak magnetoelectric response at
zero DC bias, referred as self-biased magnetoelectric response. These features present significant
advancement toward development of high sensitivity magnetic field sensors and energy harvesters.
(a)
(b)
Pb
Nb
Ni
Zn
Ag
Atomic percentage
100
80
60
Ag
Mg
Ti
Cu
Fe
Ba
Pb
Fe
40
20
0
-20
0
10
20
30
(422)
(511)
(400)
(211)
(200)
(210)
T-PMN-PT
(111)
(100)
Intensity (a.u.)
140 µm
NCZF
(222)
(d)
(110)
(c)
(220)
(311)
Distance (µm)
R-PMN-PT
Screen printing
(a)
20
30
40
(b)
50
3
0.3
unit: mm
1.5
2
50 with cofired
Enhanced magnetoelectric effect in longitudinal-longitudinal mode laminate
green tape
interdigitated electrodes: We demonstrated a low-temperature cofiring(c)technique to embed the
interdigitated electrodes inside the piezoelectric ceramic layer to achieve longitudinally (L) poled
magnetoelectric (ME) laminates. The ME voltage coefficient of this L-L mode composite was found
to be 4.41 V cm-1 Oe-1 at 1 kHz, which is 340% higher than that of L-T (transversal) mode.
IDE electrode
cofired sample
si
gas flow in
ga
(d)
n
Aerosol jet printing
sh
ea
th
aerosol
Screen printing
(a)
(b)
0.3
unit: mm
1.5
green tape
14
2
20
2
3
2
50
Pneumatic atomization
(c)
IDE electrode
(e)
focusd beam
substrate
x,y,z stage
(f)
cofired sample
th
aerosol
ga
si
gas flow in
ea
(d)
n
Aerosol jet printing
sh
•
14
2
20
2
2 theta (degree)
60
3 June, 2014 •
ME composite with different microstructures and connectivities: The 0–3 particulate composite
can be achieved with ferrite particle well dispersed in the matrix of PZT. The αME of this composite
can be obtained with the magnitude of 0.1 V/cm.Oe. By increasing the interphase contact area, this
value can be further improved to ~0.2 V/cm.Oe via a core-shell structure. To minimize the leakage
problem from the low resistivity ferrite phase, 2-2 ferrite/PMN-PT co-fired laminates was developed,
with an significant improvement of the αME (0.8 V/cm.Oe) in compared with the 0-3 particulate ME
composites. By optimizing the piezoelectric material via texturing, the αME of the cofired 2-2
laminates can be further improved to 1.3 V/cm.Oe. By utilizing longitudinal poling via the co-fired
IDE, a large αME with the magnitude of 4.4 V/cm.Oe can be obtained from L-L mode.
V/cm.Oe
0–3 composite
2–2 composite
4.4
(5) Cofired IDE
Sintered composites only
@1 kHz
(4) Texturing
((3) Cofired M-P-M
1.3
(1) solid state
t
te
sintering
(2) maximized
interphase contact
0.8
0.2
0.1
20nm
1 µm
paticulate
core-shell
L-T mode
L-L mode
Selected Publications:
l
Y. Yan, Y. Zhou, and S. Priya, “Enhanced electromechanical coupling in Pb(Mg1/3Nb2/3)O3-PbTiO3
<001>C radially textured cylinders”, Applied Physics Letters, 104, 012910 (2014).
l
Y. Yan, K.-H. Cho, D. Maurya, et al., “Giant energy density in [001]-textured Pb(Mg1/3Nb2/3)PbZrO3-PbTiO3 piezoelectric ceramics”, Applied Physics Letters, 102, 042903 (2013).
l
Y. Yan, Y. Wang, S. Priya, “Electromechanical behavior of [001]-textured Pb(Mg1/3Nb2/3)O3-PbTiO3
ceramics”, Applied Physics Letters, 100, 192905 (2012)
l
Y. Yan, K.-H. Cho, S. Priya, “Piezoelectric properties and temperature stability of Mn-doped
Pb(Mg1/3Nb2/3)-PbZrO3-PbTiO3 textured ceramics”, Applied Physics Letters, 100, 132908 (2012).
l
Y. Yan, K.-H. Cho, S. Priya, “Templated grain growth of <001>-textured 0.675Pb(Mg1/3Nb2/3)O3–
0.325PbTiO3 piezoelectric ceramics for magnetic field sensors”, Journal of the American Ceramic
Society, 94 [6] 1784 – 179 3 (2011).
l
Y. Yan, Y. Zhou, and S. Priya, “Enhanced magnetoelectric effect in longitudinal-longitudinal mode
laminate with cofired interdigitated electrodes”, Applied Physics Letters, 104, 032911 (2014).
l
Y. Yan, Y. Zhou, and S. Priya, “Giant self-biased magnetoelectric coupling in cofired textured
layered composites”, Applied Physics Letters, 102, 052907 (2013).
4 June, 2014