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Shureclean Plus VK9 Page 1 of 10
Revision Date 04/09/2014
Print Date 05/11/2014
SHURECLEAN PLUS VK9
Concentrated Neutral Detergent For Manual Use
Description
Shureclean Plus is a concentrated, neutral, high-foaming liquid detergent designed for general-purpose application in the food,
beverage and dairy industries.
Key properties
Shureclean Plus contains a concentrated blend of high foaming detergents and emulsifiers. Its balanced neutral formulation
provides effective cleaning especially against oils and fats. It can be used on most types of surfaces
including plastics and soft metals such as aluminium.
Shureclean Plus is recommended for manual and soak cleaning of all food preparation equipment, cooking vessels and utensils. It
can also be used for cleaning floors, walls and work surfaces.
Shureclean Plus is high foaming and free rinsing. It is suitable for manual application with a cloth, brush or spray applicator and also
for soak tank cleaning.
Benefits
•
Highly economical
•
Multi-purpose product
•
Suitable for manual use
•
Suitable for soft or hard water
•
Non-perfumed product
Use instructions
Use Shureclean Plus at concentrations between 0.1-1% v/v depending on type and degree of soiling. For specific details please
refer to individual method cards.
Technical data
Appearance:
Clear, pale brown liquid
Relative Density at 20ºC:
1.03
pH (1% solution at 20ºC):
neutral
Chemical Oxygen Demand (COD):400 gO2/kg
Nitrogen Content (N):
none
Phosphorous Content (P):
none
The above data is typical of normal production and should not be taken as a specification.
Safe handling and storage information
Store in original closed containers or (where applicable) in an approved bulk tank, away from extremes of temperatures. Full
guidance on the handling and disposal of this product is provided in a separate Material Safety Data Sheet.
Product compatibility
Shureclean Plus when applied at the recommended concentration and temperature is safe for use on materials
commonly found in the processed food industry. Always rinse surfaces thoroughly after use (within 1 hour). In the event of
uncertainty it is advisable to evaluate individual materials before any prolonged use.
Test method
Not applicable
Available pack sizes
Article code
Pack size
7509888
Bulk
7509854
2 x 5L
7509292
20L
7509293
200L
The information contained in this document bulletin is to our best knowledge, true and accurate, but all recommendations or suggestions are made
without guarantee, since the conditions of use are beyond our control. The supplier disclaims any liability incurred in connection with the use of these
data or suggestions.
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SAFETY DATA SHEET
According to Regulation (EC) No 1907/2006
SHURECLEAN PLUS VK9
1.
IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product Name:
SHURECLEAN PLUS VK9
MSDS Code:
MSDS1645
Supplier:
Hugh Crane Cleaning Equipment Ltd
South Walsham Road, Acle
Norwich, NR13 3ES
Telephone:
Tel 01493 750072
Fax 01493 751854
Emergency Telephone:
For medical or environmental emergency only: call 0800 052 0185
Relevant Identified Uses Of The Substance Or Mixture And Uses Advised Against
Identified Uses:
For professional use only
AISE-P301 – General Purpose cleaner. Manual process.
AISE-P302 – General Purpose cleaner. Spray and Wipe Manual process.
Soaking bath. Manual process (AISE_CS_I01 & AISE_CS_I10)
Uses advised against:
Uses other than those identified are not recommended
2.
HAZARDS IDENTIFICATION
Classification Of The Substance Or Mixture
The product has been classified and labelled in accordance with Regulation (EC) No 1272/2008.
Skin Irrit. 2 (H315)
Eye Dam. 1 (H318)
Classification in accordance with Directive 1999/45/EC and corresponding national legislation
Indication of danger:
Xi - Irritant
Risk phrases:
R41 - Risk of serious damage to eyes.
Label elements:
Signal word:
Contains:
Hazard statements:
Precautionary statements:
Other hazards:
Danger
Sodium alkylbenzenesulphonate (Sodium Dodecylbenzenesulfonate), sodium alkylethersulphate
(Sodium Laureth Sulfate).
H315 - Causes skin irritation
H318 - Causes serious eye damage
P280 - Wear eye or face protection
P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a POISON CENTRE, doctor or physician
No other hazards known. The product does not meet the criteria for PBT or vPvB in accordance
with Regulation (EC) No 1907/2006, Annex XIII.
3.
COMPOSITION / INFORMATION ON INGREDIENTS
Mixtures
Ingredient(s)
EC No.
CAS No.
REACH No.
Classification
Classification (EC)
1272/2008
Sodium
290-656-6
90194-45-9
[1]
Xn R22
H318 Eye Dam 1
Alkylbenzenesulphonate
Xi R38-41
H302 Acute Tox 4
H315 Skin Irrit 2
Sodium Alkylethersulphate
Polymer *
68585-34-2
01-2119488639-16
Xi R38-41
H318 Eye Dam 1
H315 Skin Irrit 2
H412 Aquatic Chronic 3
Bronopol (INN)
200-143-0
52-51-7
No data available
Xn R21/22
H302 Acute Tox 4
Xi R37/38-41 H312 Acute Tox 4
N R50
H335 STOT SE 3
H315 Skin Irrit 2
H318 Eye Dam 1
H400 Aquatic Acute 1
* Polymer.
For the full text of the R, H and EUH phrases mentioned in this Section, see Section 16.
Workplace exposure limit(s), if available, are listed in subsection 8.1.
Notes
Weight %
10-20
3-10
0.01 – 0.1
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[1] Exempted: ionic mixture. See Regulation (EC) No 1907/2006, Annex V, paragraph 3 and 4. This salt is potentially present, based on calculation,
and included for classification and labelling purposes only. Each starting material of the ionic mixture is registered, as required.
[2] Exempted: included in Annex IV of Regulation (EC) No 1907/2006. [3] Exempted: Annex V of Regulation (EC) No 1907/2006.
[4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006.
4.
FIRST AID MEASURES
Description Of First Aid Measures
Inhalation:
Get medical attention or advice if you feel unwell.
Skin contact:
Wash skin with plenty of lukewarm, gently flowing water. Take off immediately all contaminated
clothing and wash it before re-use. If skin irritation occurs: Get medical advice or attention.
Eye contact:
Immediately rinse eyes cautiously with lukewarm water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTRE, doctor
or physician.
Ingestion:
Rinse mouth. Immediately drink 1 glass of water. Get medical attention or advice if you feel
unwell.
Self-protection of first aider:
Consider personal protective equipment as indicated in subsection 8.2.
Most Important Symptoms And Effects, Both Acute And Delayed
Inhalation:
No known effects or symptoms in normal use.
Skin contact:
Causes irritation.
Eye contact:
Causes severe or permanent damage.
Ingestion:
No known effects or symptoms in normal use.
Indication Of Any Immediate Medical Attention And Special Treatment Needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can
be found in section 11.
5.
FIRE FIGHTING MEASURES
Extinguishing media:
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or
alcohol-resistant foam.
Special hazards arising from
the substance or mixture:
No special hazards known.
Advice for firefighters:
As in any fire, wear self contained breathing apparatus and suitable protective clothing
including gloves and eye/face protection.
6.
ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment
And Emergency Procedures:
Wear eye-face protection.
Environmental precautions:
Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water.
Methods and material for
containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust).
Reference to other sections:
For personal protective equipment see Section 8.For disposal considerations see Section 13
7.
HANDLING & STORAGE
Precautions For Safe Handling
Measures To Prevent Fire & Explosion: No special precautions required.
Measures Required to Protect the Environment: For environmental exposure controls see section 8.
Advice On General Occupational Handle in accordance with good industrial hygiene and safety practice. Keep away from food,
Hygiene:
drink and animal feeding stuffs. Do not mix with other products unless advised by Sealed Air.
Wash hands before breaks and at the end of workday. Wash face, hands and any exposed skin
thoroughly after handling. Take off immediately all contaminated clothing. Wash contaminated
clothing before reuse. Use personal protective equipment as required. Avoid contact with eyes.
Use only with adequate ventilation.
Conditions for safe storage,
Store in accordance with local and national regulations. Keep only in original container. Store in a
including any incompatibilities: closed container. For conditions to avoid and incompatible materials see section 10.
Specific end use(s):
No specific advice for end use available.
8.
EXPOSURE CONTROL / PERSONAL PROTECTION
Control Parameters
Workplace exposure limits
Air limit values, if available:
Biological limit values, if available:
Recommended monitoring procedures, if available:
Additional exposure limits under the conditions of use, if available:
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DNEL/DMEL and PNEC values
Human exposure
DNEL oral exposure - Consumer (mg/kg bw)
Ingredient(s)
Short term –
Local effects
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
No data available
Short term –
Systemic effects
No data available
No data available
No data available
Long term –
Local effects
No data available
No data available
No data available
Long term – Systemic
effects
No data available
No data available
No data available
Short term –
Local effects
No data available
No data available
No data available
Short term – Systemic
effects (mg/kg bw)
No data available
No data available
No data available
Long term –
Local effects
No data available
No data available
No data available
Long term – Systemic
effects (mg/kg bw)
No data available
No data available
No data available
Short term –
Local effects
No data available
No data available
No data available
Short term – Systemic
effects (mg/kg bw)
No data available
No data available
No data available
Long term –
Local effects
No data available
No data available
No data available
Long term – Systemic
effects (mg/kg bw)
No data available
No data available
No data available
DNEL inhalatory exposure - Worker (mg/m3)
Ingredient(s)
Short term –
Local effects
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
No data available
Short term –
Systemic effects
No data available
No data available
No data available
Long term –
Local effects
No data available
No data available
No data available
Long term – Systemic
effects
No data available
No data available
No data available
DNEL inhalatory exposure - Consumer (mg/m3)
Ingredient(s)
Short term –
Local effects
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
No data available
Short term –
Systemic effects
No data available
No data available
No data available
Long term –
Local effects
No data available
No data available
No data available
Long term – Systemic
effects
No data available
No data available
No data available
Surface water, marine
(mg/l)
No data available
No data available
0.0008
Intermittent (mg/l)
No data available
No data available
0.0025
Sewage treatment plant
(mg/l)
No data available
No data available
0.43
Soil (mg/kg)
Air (mg/m3)
No data available
No data available
0.5
No data available
No data available
No data available
DNEL dermal exposure - Worker
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
DNEL dermal exposure – Consumer
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Environmental exposure
Environmental exposure – PNEC
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Surface water,
fresh (mg/l)
No data available
No data available
0.001
Environmental exposure - PNEC, continued
Ingredient(s)
Sediment, freshwater
(mg/kg)
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
0.041
Sediment, marine
(mg/kg)
No data available
No data available
0.00328
Exposure controls
The following information applies for the uses indicated in subsection . If available, please refer to the product information sheet for
application and handling instructions. Normal use conditions are assumed for this section.
Recommended safety measures for handling the undiluted product:
Covering activities such as filling and transfer of product to application equipment, flasks or buckets.
Appropriate engineering controls: If the product is diluted by using specific dosing systems with no risk of splashes or direct skin
contact, the personal protection equipment as described in this section is not required.
Appropriate organisational controls: Avoid direct contact and-or splashes where possible. Train personnel.
Personal Protective Equipment
Eye / face protection:
Safety glasses or goggles (EN166)
Hand protection:
Chemical resistant protective gloves (EN374). Verify instructions regarding permeability and
breakthrough time, as provided by the gloves manufacturer. Consider specific local use
conditions such as risk of splashes, cuts, contact time and temperature.
Shureclean Plus VK9 Page 5 of 10
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Suggested gloves for prolonged contact:
Material:
Penetration Time:
Material Thickness:
Suggested gloves for protection against splashes:
Material:
Penetration Time:
Material Thickness:
Butyl rubber
>=480 min
>=0.7mm
Nitrile rubber
>= 30 min
>=0.4 mm
In consultation with the supplier of protective gloves, a different type providing similar protection
may be chosen.
Body protection:
No special requirements under normal use conditions
Respiratory protection:
No special requirements under normal use conditions
Environmental exposure controls: No special requirements under normal use conditions
Recommended safety measures for handling the diluted product:
Recommended Maximum Concentration (%): 3
Appropriate engineering controls: Use only in well ventilated areas.
Appropriate organisational controls: No special requirements under normal use conditions
Personal Protective Equipment
Eye / face protection:
No special requirements under normal use conditions
Hand protection:
Rinse and dry hands after use. For prolonged contact, protection for the skin may be necessary.
Body protection:
No special requirements under normal use conditions
Respiratory protection:
No special requirements under normal use conditions
Environmental exposure controls: No special requirements under normal use conditions
9.
PHYSICAL & CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Information in this section refers to the product unless it is specifically stated that substance data is listed.
Physical State:
Liquid
Colour:
Clear pale brown
Odour:
Product specific
Odour Threshold:
Not applicable.
pH:
approx 6 (neat)
Melting/Freezing point/(°C):
Not determined
Initial Boiling point & range (°C): Not determined
Substance Data, Boiling Point
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value (ºC)
No data available
>100
No data available
Method
Atmospheric Pressure (hPa)
Method Not Given
Flash point (°C):
Not applicable.
Sustained Combustion:
Not determined
Evaporation Rate:
Not determined.
Flammability (solid/gas):
Not determined
Upper/Lower Flammability Limit %: Not determined
Substance Data, Flammability or explosive limits, if available
Vapour Pressure:
Substance Data, Vapour Pressure
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Not determined.
Value (Pa)
No data available
No data available
0.0051
Method
Temperature (ºC)
OECD 104 (EU A.4)
20
Method
Temperature (ºC)
Method not given
20
23
Vapour Density:
Not determined
Relative Density:
1.03 g/cm³ (20°C)
Solubility in / Miscibility with Water: Fully miscible
Substance Data, Solubility in Water
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value (Pa)
No data available
Soluble
280
Substance Data, Partition Coefficient N-Octanol/Water (log Kow): See Section 12.
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Autoignition Temperature:
Not determined
Decomposition Temperature:
Not determined
Viscosity:
Approx 300 mPa.s (20ºC)
Explosive properties:
Not explosive.
Oxidising properties:
Not oxidising.
Other information
Surface Tension (N/m):
Not determined
Corrosion to Metals (According to IMDG/ADR Regulation): Not determined.
Substance Data, Dissociation content, if available.
Ingredient(s)
Value
Bronopol (INN)
9.56 (pKa)
Method
Method not given
Temperature (ºC)
21
10.
STABILITY & REACTIVITY
Reactivity:
No reactivity hazards known under normal storage and use conditions.
Chemical stability:
Stable under normal storage and use conditions.
Possibility of hazardous reactions: No hazardous reactions known under normal storage and use conditions.
Conditions to avoid:
None known under normal storage and use conditions.
Incompatible materials:
None known under normal use conditions.
Hazardous decomposition products: None known under normal storage and use conditions.
11.
TOXICOLOGICAL INFORMATION
Information On Toxicological Effects
No data is available on the mixture
Substance data, where relevant and available, are listed below.
Acute toxicity –
Acute oral toxicity
Ingredients
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Acute dermal toxicity
Ingredients
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Acute inhalative toxicity
Ingredients
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
End point
Value (mg/kg)
No data available
>2000
305
Species
Method
Rat
Rat
OECD401 (EU B.1)
OECD401 (EU B.1)
Value (mg/kg)
No data available
>2000
>2000
Species
Method
Rat
Rat
OECD402 (EU B.3)
OECD401 (EU B.1)
Value (mg/l)
No data available
No data available
No data available
Species
Method
LD50
LD50
End point
LD50
LD50
End point
Irritation and corrosivity -Skin irritation and corrosivity
Ingredients
Result
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
Irritant
Bronopol (INN)
Irritant
Eye irritation and corrosivity
Ingredients
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Result
No data available
Severe Damage
Severe Damage
Respiratory tract irritation and corrosivity
Ingredients
Result
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
No data available
Sensitisation - Sensitisation by skin contact
Ingredients
Result
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
Not sensitising
Bronopol (INN)
No data available
Species
Method
Rabbit
Rabbit
OECD404 (EU B.4)
OECD404 (EU B.4)
Species
Method
Rabbit
Rabbit
OECD405 (EU B.5)
Method not given
Species
Method
Species
Method
Guinea Pig
OECD 406 (EU B.6) / GPMT Read Across
Exposure Time (h)
Exposure Time (h)
Exposure Time (h)
Exposure Time (h)
Exposure Time (h)
Exposure Time (h)
Exposure Time (h)
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Sensitisation by inhalation
Ingredients
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Result
No data available
No data available
No data available
Species
Method
Exposure Time (h)
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Carcinogenicity
Ingredient(s)
Effect
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No evidence for carcinogenicity, negative test results
Bronopol (INN)
No data available
Mutagenicity
Ingredients
Result (in vitro)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Method
(in vitro)
No data available
No evidence for mutagenicity,
negative test results
No evidence for mutagenicity,
negative test results
Result (in vivo)
Method
(in vivo)
No data available
No evidence for mutagenicity,
negative test results
No data available
OECD 476 (Chinese
Hamster Ovary)
Method not given
Toxicity for reproduction
Ingredient(s)
Sodium
Alkylbenzenesulphonate
Sodium
Alkylethersulphate
End
point
NOAEL
Specific effect
Developmental
toxicity
Bronopol (INN)
Value
(mg/kg bw/d)
No data
available
86.6
Species
Method
Rat
OECD 416
(EU B.35)
Oral
Exposure
Time
Remarks & other
effects reported
No known significant
effects or critical
hazards.
No data
available
Repeated dose toxicity - Sub-acute or sub-chronic oral toxicity
Endpoint
Value
Ingredient(s)
(mg/kg bw/d)
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
NOAEL
50
Bronopol (INN)
No data available
Species
Method
Exposure
time (days)
Specific effects &
organs affected
Method not given
Sub-chronic dermal toxicity
Endpoint
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
NOEL
Bronopol (INN)
Value
(mg/kg bw/d)
No data available
>12.5
Species
Method
Exposure
time (days)
Specific effects &
organs affected
Method not
given
No data available
Sub-chronic inhalation toxicity
Endpoint
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value
(mg/kg bw/d)
No data available
No data available
No data available
Species
Method
Exposure
time (days)
Specific effects &
organs affected
Chronic toxicity
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
STOT – Single Exposure
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Exposure
route
End
point
Value
(mg/kg bw/d)
No data available
No data available
No data available
Affected organ(s)
No data available
No data available
No data available
Species
Method
Exposure
time
Specific effects &
organs affected
Remark
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STOT – Repeated Exposure
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Aspiration Hazard:
Potential Adverse Health
Effects And Symptoms:
Affected organ(s)
No data available
No data available
No data available
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see
section 9 for dynamic viscosity and relative density of the product.
Effects and symptoms related to the product, if any, are listed in Section 4
12.
ECOLOGICAL INFORMATION
Toxicity
No data is available on the mixture.
Substance data, where relevant and available, are listed below
Aquatic short-term toxicity -Aquatic short-term toxicity – fish
Ingredient(s)
Endpoint
Value (mg/l)
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
LC50
1-10
Bronopol (INN)
LC50
41.2
Aquatic short-term toxicity – crustacea
Ingredient(s)
Endpoint
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
EC50
Bronopol (INN)
EC50
Value (mg/l)
No data available
1-10
1.4
Aquatic short-term toxicity – algae
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value (mg/l)
No data available
7.5
0.4 – 2.8
Endpoint
EC50
EC50
Species
Method
Exposure Time
Brachydanio rerio
Oncorhynchus Mykiss
OECD 203, Semi Static
Method not given
96 hrs
96 hrs
Species
Method
Exposure Time
Daphnia
Not specified
OECD 202, static
Method not given
48 hrs
48 hrs
Species
Method
Exposure Time
Not specified
Not specified
DIN 38412, Part 9
Method not given
72 hrs
72 hrs
Aquatic short-term toxicity - marine species
Ingredient(s)
Endpoint
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value (mg/l)
No data available
No data available
No data available
Species
Method
Exposure Time
Impact on sewage plants - toxicity to bacteria
Ingredient(s)
Endpoint
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
EC10
Bronopol (INN)
EC20
Value (mg/l)
No data available
300-500
2
Inoculum
Method
Exposure Time
Activated Sludge
Method not given
OECD 209
0.5 hrs
150 mins
Aquatic long-term toxicity –
Aquatic long-term toxicity – fish
Ingredient(s)
Endpoint
Value (mg/l)
Species
Method
Exposure
time
NOEC
EC50
No data available
0.1 – 0.13
39.1
Not specified
Oncorhynchus Mykiss
Method not given
OECD 210
365 days
49 hrs
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Aquatic long-term toxicity – crustacea
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
End
point
NOEC
NOEC
Value (mg/l)
Species
Method
Exposure
time
No data available
0.18 – 0.72
0.27
Daphnia sp.
Daphnia Magna
Method not given
OECD 211 flowthrough
21 days
21 days
Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s)
End
Value
Species
Method
point
(mg/kg dw sediment)
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
NOEC
0.72 – 0.9
Method not given
Bronopol (INN)
No data available
Exposure
time
3 days
Effects
observed
Effects
observed
Effects
observed
Shureclean Plus VK9 Page 9 of 10
Revision Date 04/09/2014
Print Date 05/11/2014
Terrestrial Toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:
Ingredient(s)
End
Value
point
(mg/kg dw sediment)
Bronopol (INN)
LD50
>500
Species
Method
Eisenia Fetida
OECD 207
Exposure
time
14 days
Effects
observed
Terrestrial toxicity - plants, if available:
Terrestrial toxicity - birds, if available:
Terrestrial toxicity - beneficial insects, if available:
Terrestrial toxicity - soil bacteria, if available:
Persistence And Degradability
Abiotic degradation
Abiotic degradation - photodegradation in air, if available:
Abiotic degradation - hydrolysis, if available:
Ingredient(s)
Half Life Time in Fresh water
Bronopol (INN)
No data available
Method
OECD 111
Evaluation
Rapidly hydrolysible
Remark
Abiotic degradation - other processes, if available:
Biodegradation - Ready biodegradability - aerobic conditions
Ingredient(s)
Inoculum Analytical Method
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
DT50
Method
>60% in 28 days
OECD 301B
Evaluation
No data available
Readily Biodegradable
No data available
Ready biodegradability - anaerobic and marine conditions, if available:
Degradation in relevant environmental compartments, if available:
The surfactant(s) contained in this preparation comply with the biodegradability criteria as laid down in Regulation (EC) No 648/2004 on detergents.
Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their
direct request or at the request of a detergent manufacturer.
Bioaccumulative Potential
Partition coefficient n-octanol/water (log Kow)
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value
No data available
0.95 – 3.9
0.18
Bioconcentration Factor (BCF)
Ingredient(s)
Sodium Alkylbenzenesulphonate
Sodium Alkylethersulphate
Bronopol (INN)
Value
No data available
No data available
No data available
Mobility In Soil
Adsorption/Desorption to soil or sediment
Ingredient(s)
Adsorption coefficient
Log Koc
Sodium Alkylbenzenesulphonate
No data available
Sodium Alkylethersulphate
No data available
Bronopol (INN)
No data available
Method
Evaluation
Method not given
Method not given
Low potential for bioaccumulation
No bioaccumulation expected
Method
Evaluation
Desorption coefficient
Log Koc(des)
Method
Soil / sediment
type
Remark
Remark
Evaluation
Results of PBT and vPvB assessment: Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.
Other adverse effects:
No other adverse effects known.
13.
DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Waste from residues / unused
The concentrated contents or contaminated packaging should be disposed of by a
Products:
certified handler or according to the site permit. Release of waste to sewers is discouraged.
The cleaned packaging material is suitable for energy recovery or recycling in line with local
legislation.
European Waste Catalogue:
20-01-29 – detergents containing dangerous substances.
Empty Packaging
Recommendation:
Suitable cleaning agents:
Dispose of observing national or local regulations.
Water, if necessary with cleaning agent.
Shureclean Plus VK9 Page 10 of 10
Revision Date 04/09/2014
Print Date 05/11/2014
14.
TRANSPORT INFORMATION
ADR, RID, ADN, IMO/IMDG, ICAO/IATA
UN number:
Non dangerous goods.
UN proper shipping name:
Non dangerous goods.
Transport hazard class(es):
Packing group:
Environmental Hazards
Special precautions for user:
Non dangerous goods.
Non dangerous goods.
Non dangerous goods.
Non dangerous goods.
Transport in bulk according to Annex II of MARPOL
73/78 and the IBC Code:
The product is not transported in bulk tankers.
15.
REGULATORY INFORMATION
Safety, Health And Environmental Regulations/Legislation Specific For The Substance Or Mixture
Authorisations or Restrictions (Regulation [EC] No 1907/2006, Title VII Respectively Title VII) : Not applicable.
Ingredients According to EC
Detergents Regulations 648/2004:
Chemical safety assessment:
Anionic Surfactants
15-30%
2-Bromo-2-Nitropropane-1,3-Diol
A chemical safety assessment has not been carried out on the mixture
16.
OTHER INFORMATION
The information in this document is based upon our best present knowledge. However it does not constitute a guarantee for any
specific product features and does not establish a legally binding contract.
MSDS code:
MSDS Revision Date:
Reason for Revision:
MSDS1645
04 September 2014
Overall design adjusted in accordance with Amendment 453/2010, Annex II of Regulation
(EC) No 1907/2006.
Classification procedure:
The classification of the mixture is in general based on calculation methods using substance
data, as required by Regulation (EC) No 1272/2008. If for certain classifications data on the
mixture is available or for example bridging principles or weight of evidence can be used for
classification, this will be indicated in the relevant sections of the Safety Data Sheet. See section
9 for physical chemical properties, section 11 for toxicological information and section 12 for
ecological information.
Full text of the R, H and EUH
H302
phrases mentioned in section 3: H312
H315
H318
H335
H400
H412
R21
R22
R37
R38
R41
R50
Abbreviations and acronyms:
Harmful if swallowed.
Harmful in contact with skin.
Causes skin irritation
Causes serious eye damage.
May cause respiratory irritation.
Very toxic to aquatic life.
Harmful to aquatic life with long lasting effects
Harmful in contact with skin.
Harmful if swallowed.
Irritating to respiratory system.
Irritating to skin.
Risk of serious damage to eyes.
Very toxic to aquatic organisms.
AISE
The international Association for Soaps, Detergents and Maintenance Products
ATE
Acute Toxicity Estimate
DNEL Derived No Effect Limit
EUH
CLP Specific hazard statement
PBT
Persistent, Bioaccumulative and Toxic
PNEC Predicted No Effect Concentration
REACH number - REACH registration number, without supplier specific part
vPvB
very Persistent and very Bioaccumulative
End of Safety Data Sheet