Plants and equipment for water treatment and processing of fluids Innovative concepts and technologies for integrated environmental protection RC.MANNESMANN LTD. – Mail: [email protected] / [email protected] 1 Companyprofile M-Mannesmann GmbH The company M-Mannesmann GmbH Remscheid, Germany, is one of the leading companies specialized in new processes of water- and waste water treatment and recycling. Especially recycling processes for the recovery of water and elements as well as their renewed application in circuits gain more and more importance because of increased environmental pollution and consequently decreasing resources. M-Mannesmann has extraordinary qualifications in the area of water chemistry and membrane technology. M-Mannesmann offers a complete range of applications from pure water treatment up to the recirculation of process water for integrated environmental protection, from process engineering and manufacture up to plant construction and „after sale service“ – complete solutions for the customers. Tests in own laboratories and pilot-scale tests allow a detailed estimation and dimensioning of the required cleaning procedure in difficult cases. Today, a staff of 25 employees is at our command to serve our customers. The majority of employees are engineers, chemists and technicians from a variety of disciplines. Our highly qualified staff regularly attend internal and external advanced professional training courses. They also pass on their knowledge in scientific lectures. M-Mannesmann has 4 agencies in Germany and international agencies in:Turkey, Belgium, the Netherlands, Spain, Brasilia and Mexico. The company is a member of the specialised Water and Waste Water Technology Group of the VDMA [German Machinery and Plant Manufacturers Association] and of the DGMT [German Association for Membrane Technology]. This year M-Mannesmann has ben nominated for the „Milestones 2002“ NRW-enconomy price and has won the 2. place for the category: „Technologic innovations”. M-Mannesmann is working with an engineering and consulting company, specialized in developing process concepts in the area of chemical and automotive industry. The Company has a staff of 4 engineers. M-Mannesmann, is working with an engineering company, specialized in chemical/physical treatment for different areas. 2 [email protected] [email protected] Range of Services Development Analysis Membrane screening and trials in own laboratory and pilot plants Pre-engineering and scale-up Design and plant construction Process engineering Plant manufactoring Assembly After sales service and maintenance RC.MANNESMANN LTD. - İSTANBUL / TÜRKİYE 3 Delivery programm Turn key plants for water and waste water processing Micro-, ultra- and nanofiltration plants Reverse osmosis plants Desalination plants Gravel filter plants Neutralisation plants Water recycling plants Sewage treatment plants Biomembrane plants Chemicals 4 Standard program: Water and process water treatment plants Ultrapure water desalination Gravelfilter Ionexanger Chemical-physical sewage treatment plants 5 Ultrafiltation plants Reverse osmosis plants Ultrapure water desalination Water treatment plants for pharma and cosmetic industry • Prefiltration, Softener • Multystage reverse osmosis • Mixed bed desalination • Flow rate: 5.000 l/h Water quality permate (RO): < 4 µS/cm Water quality (mixed bed): < 0,1 µS/cm Visualy, fullautomatic plant operation GMP, FDA 6 Desalination plants Water treatment for power plants and boiler feed • Prefiltration • Anti scaling • Reverse osmosis plants • Flow rate: 2.000 m³/d Water quality permate (RO): < 20 µS/cm Availability: 7 > 98% Sea water desalination • Prefiltration / pretreatment • Multistage reverse osmosis • Flow rate: 0,1 – > 100 m³/h Desalination rate (TDS 36.000 mg/l): ca. 99% WHO standards for drinking water (TDS): << 1.000 mg/l Energy consumption (with energy recovery): 8 < 5 kW / m³ Wind-powered Sea water desalination Turnkey Solutions . . . • Pre – investigation • Project conception • Technical development • Site Preparation • Manufacturing / construction • Commissioning • Service / Operation Synwater plant: 3.000 m³/d ... crafted from the full range of our common skills Ultrafiltration / reverse osmosis plant Off-shore wastewater purification Ultrafiltration wastewater treatment plant on a gas platform in the North Sea Operating data Skimmer for oil separation 2 fully automatic ultrafiltration plants Total filtration surface of 2 x 4,2 m² Off-shore design Extra explosion proof (EEX Zone 2, gas groupe IIA,temp.class T3) Performance data Filtrate nominal capacity: Oil contained permeat: Temperature: Operating pressure: UF-plant for purification of gas condensates 2 x 1.200 l/h << 40 ppm 10 - 90 °C 2 - 5 bar Gaz de France off-shore gas platform / Northse 10 Sewage treatment plant I Patented recycling process for the foodindustry • Sewage treatment plant (SBR) • Flocculation • Reverse osmosis • UV - desinfection • Flow rate : 22.000 l/h Water recycling: > 70 % Trinking water quality (German TrinkwVO) Reduction of COD/BOD, N and P Recycling plant at Durst Malz, Gernsheim 11 Sewage treatment plant II MBR-plant Simmerath, Aachen Nitrification / Denitrification Permeate flux: 30 m³/h Membrane-typ: UF-Puron Membrane-surface: 2 x 500 m² 12 The BIOLEADER Process: Sludge Reduction means Costs Savings • developed by Kurita Water • since 1995: 29 industrial scale plants are installed in Japan • imb+frings watersystems will introduce this BIOLEADER process in Europe high efficiency: ozone dosage about 1 % of COD-influent for up to 100 % reduction of surplus sludge cost effective process: requiring only 0.1 to 0.5 kWh / kg COD-influent 13 Process water recycling I Waste water purification for lorry washing with silo cleansing • Ultrafiltration plant • Flow rate: 2.000 l/h • Concentrate treatment • Fully automatic process Recycling of water > 80% Reduction of costs for water and disposal Less chemical costs 14 Process water recycling II Cooling water recycling for PVC industry • Gravel filter plant • Flow rate : 500 m³/h • Mikrofiltration plant • Flow rate: 2.000 l/h • Concentrate treatment Separation of oil and particles High quality process water Reduction of disposal costs 15 Automotiv Industry I Oil-water purification • Pretreatment: pressure filter • Ceramic ultrafiltration plant • Ceramic membranes (30 m²) • Capacity: 3.500 l/h Ultrafiltration plant Prolongated time of degreaser exposure: 20 up to 40 times Hydocarbones in concentrate: up to 300.000 ppm Hydocarbones in permeate: less 3 - 7 ppm 16 Automotiv Industry II Waste water free paint shop: DaimlerChrysler AG, Sindelfingen Patented process • Step 1: ultrafiltration plant • Step 2: reverse osmosis plant • Step 3: evaporator No waste water Closed loop Emission free Less corrosive effects Process at DaimlerChrysler, Sindelfingen Less disposal (~ 1% of treated waste water) 17 Automotiv Industry III Metal processing with the IonGard-NF-process 1. Process step: Degreasing 2. Process step: Phosphating 3. Process step: Cathodic painting Material throughput Degreasing Rinsing Phosphating Rinsing CDP Rinsing Anolyte cycle UF NF Emulsion separation RO Concentrate separation Neutralisation sludge disposal UF Nanofiltration plant at Ford-Cologne part line Closed loop for heavy metals and phosphate Reuse of the concentrate as replisher for phosphating no contamination of sodium and nitrate in phosphate bath Reuse of the filtrate as rinsing water after degreasing Reuse of the filtrate for degreasing 18 Production process chemical industry Treatment fo process water in the chemical industry • Multi-stage ultrafiltration plant with concentrate stage • Fully automatic plant • Modular system Recycling of product and process water Savings in fresh water Chemical free process Low energy costs 19 Membrane plant at Omya, Emden Production process food industry New treatment process for treatment of palm oil emulsions • Separation of emulsions by crossflow membrane filtration • Fully automatic NF/UF-plant • Output: 7.000 l emulsion / h High product output High product quality Compact and new plant technology 20 Project plant for Accichem, Malaysia Pilote plants / projects I Production and improve of high quality Mg(OH)2 Product circulation Concentrate Fresh water Reaction medium Reactor UF RO Pilotproject at K+S, Heringen Step 1: Reactor => hydrox. precipitation Step 2: Microfiltration Step 3: Multi-stage microfiltration 21 high quality products GMP quality 90 % recycling of water Pilote plants / projects II Separation of organic acids out of fermentation Step 1: Fermentation Step 2: Ultrafiltration: Separation of biomass Step 3: Cristallisation of salts Production of high quality organic salts 22 Pilote plants / projects III Leachate water treatment of a special waste landfill Container plant / mobile lab Revers osmosis plants / vessels Step 1: Nitrification / Denitrification Step 2: Ultrafiltration Step 3: High pressure RO Step 4: Low pressure RO Biomembrane Cleaning of leachate water Immobilizing of concentrate 23 Lab scale membrane plants Laboratory plants Flatsheet testing plant Type I Plant Type I : 1. Flatsheet testing plant 2. For small volumes Plant Type II und III: 1. Microfiltration 2. Ultrafiltration 3. Low pressure NF/RO 4. 70 bar Revers osmosis 5. Exx-safe 24 Multimembrane plant Type II Patents Elimination of heavy metals and other pollulants from industrial waste water Method of treating the circulation water from wet-wash spray botths Method for treating an electrolyte used for electrophoretic painting Method for treating solvent-containing process liquids Method for treating wate water, especially from malt house and breweries Process for the preparation of crystalline magnesium hydroxide 25 References • • • • • • • • • • • • • • • • BASF AG Benteler Werke GmbH Bosch AG British American Tabacco DaimlerChrysler AG Degussa AG Drahtcord-Pirelli FORD AG InfraServ Knapsack KG K+S AG Lurgi Life Science GmbH Maxim Kosmetik GmbH Saarstahl GmbH ThyssenKrupp AG Vinyl Building Products Corp. ZF Getriebe AG RC.MANNESMANN LTD. İSTANBUL / TÜRKİYE – [email protected] / [email protected] 26
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