Catalyst Rate yourself on LTs 7.9, 7.10, 7.11, and 7.13 End Dry Ice and Universal Indicator Today’s Learning Targets LT 7.9 – I can compare and contrast the Arrhenius, Bronsted – Lowry, Lewis definition of acids and bases LT 7.10 – I can compare and contrast the similarities and differences between a strong acid/base and a week acid/base. LT 7.11 – I can calculate the pH or pOH of a strong acid/base. LT 7.13 – I can identify the conjugate acid/base pair in a chemical reaction. Furthermore, I can use this definition to explain the amphoteric nature of water. Layout of Today’s Class Independent Review of Acids/Bases from last year using the website Packet must be completed by the end of class. You may do the review online or you can participate in one or more of the small “mini – lectures” Lecture 1 (LT 7.9) – Arrhenius, Bronsted Lowry, and Lewis acids and bases Lecture 2 (LT 7.10) – Strong vs. Weak acids/bases Lecture 3 (LT 7.11) – pH, pOH, and calculating pH/pOH Lecture 4 (LT 7.13) – Conjugate Acids/Bases (Only covered in honors last year) Neutralization Reactions Recall, one of the most common types of reactions are acid/base reactions or neutralization reactions We have various definitions of acids and bases, but they all react with characteristic properties. NOTE –We will review some of the material from last year, but it is expected that you study all material previously taught. Arrhenius Acid/Base Arrhenius’ theory of acids/bases focuses on what molecules contain An Arrhenius acid contains a H+ An Arrhenius base contains an OH- Bronsted – Lowry Acid/Base When Arrhenius’ definition covers many acids/bases, acid/base reactions are not about containing H+ or OH A Bronsted-Lowry acid is any compound that gives H+ during the reaction A Bronsted-Lowry base is any compound that accepts H+ during the reaction. We will use this definition most of the time in this class Lewis Acid/Base Ultimately, acid/base reactions are not about H+, but about the accepting or donating of electron pairs. A Lewis acid is an electron pair acceptor A Lewis base is an electron pair donor Every acid/base in the previous two categories are also acids/bases in this category Broadest definition Class Example Identify the acid/base as Arrhenius, Bronsted – Lowry, and/or Lewis: Table Talk Identify the acid/base as Arrhenius, Bronsted – Lowry, and/or Lewis: Strong vs. Weak Acid/Base • Acids/Bases can be classified as strong or weak based on how much it disassociates. • Disassociate – To break apart • Acids/Bases that completely dissociate are called strong acids/bases • Acids/Bases that only partially dissociate are called weak acids/bases. These are in equilibrium with one another Dissociation Strong Acids/Strong Bases to Memorize Strong Bases Strong Acids 1. 2. 3. 4. 5. 6. 7. 8. LiOH NaOH KOH RbOH CsOH Ca(OH)2 Sr(OH)2 Ba(OH)2 1. 2. 3. 4. 5. 6. 7. HBr HCl HI HNO3 H2SO4 HClO3 HClO4 I. pH The concentrations of acids and bases are often very low. We use the pH scale to convey the concentration of H+ The pH scale is 0-14. Acid = pH 0-7 Base = pH 7-14 Neutral chemicals = pH of 7. pH/pOH We calculate the pH by: pH=-log([H+]) We calculate pOH by: pOH=-log([OH-]) For strong acids and bases, the concentration of the compound is the [H+] or [OH-] For bases, we only know [OH-], so we need to first calculate pOH and then convert to pH using the equation: pH = 14 – pOH Class Example What is the pH of a 0.231 M solution of NaOH? Table Talk What is the pH of a 0.512 M solution of HNO3? Conjugate Acid/Base Pairs As with any reaction, there is a forward and reverse reaction for acid/base reactions. Consider the following example: HX + H2O ⇌H3O+ + XIn the forward reaction HX is the acid because it donates H+ and H2O is the base because it accepts H+. In the reverse reaction, H3O+ is now the acid and X- is now the base. The pair of HX and X- are known as an conjugate acid-base pair Conjugate Acid/Base Pairs Every acid has a conjugate base that is formed when a proton (H+) is removed Every base has a conjugate acid that forms when a proton is added Class Example Identify the acid, base, conjugate acid, and conjugate base in the following reaction. Identify the acid/base as Arrhenius, Bronsted – Lowry, and/or Lewis: NH3 + H2O NH4+ + OH- Table Talk Identify the acid, base, conjugate acid, and conjugate base in the following reaction. Identify the acid/base as Arrhenius, Bronsted – Lowry, and/or Lewis: HSO3- + H2O SO32- + H3O+ Exit Ticket 1 Identify the acid, base, conjugate acid, and conjugate base in the reaction below. Furthermore, identify the acid and base as either Arrhenius, Bronsted – Lowry, Lewis, or some combination of the 3. HCl + NH3 NH4+ + Cl2. What is the difference between a strong acid and a weak acid? 3.You have a 0.42 M solution of NaOH. What is the pH? Is it acidic, basic, or neutral? Closing Time Read: 15.6, 15.7, 16.1, 16.2, and 16.11 Homework:
© Copyright 2024