I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y PaPSaT doctoral course co- organized with BOKU, and TU Graz Puu-23.6090 ADVANCES IN BIOREFINERIES (8 ECTS) June 29 - July 3, 2015 COURSE DESCRIPTION The aim of the course is to provide an in-depth understanding of the currently existing and novel lignocellulosic biorefinery concepts and the key-economic barriers and regulatory policies affecting commercial implementation of lignocellulosic biorefineries. In the first part, the mechanical, chemical, biochemical and engineering fundamentals of biomass pretreatment and fractionation processes are reviewed and discussed. Main emphasis is laid on the downstream processes because they account for more than 60% of the total costs. Supercritical fluids, near critical water, gas-expanded liquids and new, reactive solvents such as ionic liquids as well as homogeneous and heterogeneous catalysis will be introduced in detail. The second part of the course will provide an overview on the conversion routes of the isolated lignocellulosic components, cellulose, hemicellulose, lignin and resins into high value-added platforms, building blocks, intermediates and final products. Finally, some business cases of commercial biorefineries will be introduced. Lecturers: Prof. Herbert Sixta, Aalto University School of Chemical Technology, Finland Dr. Stefan Böhmdorfer, University of Natural Resources and Life Sciences (Boku), Austria Prof. Claudia Crestini, University of Rome Tor Vergata, Italy Dr. Ed de Jong, Vice-President Development, Avantium, Netherlands Prof. Wolgang Gindl-Altmutter, University of Natural Resources and Life Sciences (Boku), Austria Prof. Roger Gläser, University of Leipzig, Germany Dr. Susanne Lux, Graz University of Technology, Austria Prof. Berndt Nidetzky, Graz University of Technology, Austria Dr. Daniela Painer, Graz University of Technology, Austria Prof. Christoph Pfeifer, University of Natural Resources and Life Sciences (Boku), Austria Prof. Antje Potthast, University of Natural Resources and Life Sciences (Boku), Austria Prof. Thomas Rosenau, University of Natural Resources and Life Sciences (Boku), Austria Professor Stefan Schleicher, Institute für Volkswirtschaftslehre, University of Graz Prof. Matthäus Siebenhofer, Graz University of Technology, Austria Prof. Adriaan van Heiningen, Forest Bioproducts Research Institute, University of Maine, USA LOCATION Graz, Austria, Inffeldgasse 13, Hörsaal (lecture hall) i8 http://portal.tugraz.at/portal/page/portal/zid/p_infrastruktur/hoersaele/hoersaal?roomID=16583 COURSE FEE The course fee is 400 euros. PaPSaT and FPIRC students do not have to pay the fee. Also students who study in Aalto University School of Chemical Technology and have the course in their accepted study plan can attend the course for free, as well as students from TU Graz, University of Graz, and BOKU. More information about the payment of the course fee will be given later. REGISTRATION Registration should be made by 31 May 2015: https://www.webropolsurveys.com/S/E4CD06A5507E3349.par Course leader: Prof. Herbert Sixta, herbert.sixta(at)aalto.fi Course arrangements: Planning Officer Leena Hauhio, leena.hauhio(at)aalto.fi I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y SCHEDULE Monday 29.6. Lecturer 8:00 - 8:30 Registration 8:30 - 9:15 Introduction to biorefineries including the historical background Herbert Sixta 9:30 - 10:15 Introduction to biorefineries including the historical background Herbert Sixta Coffee Pretreatment of biomass: Impregnation phenomena, pretreatment processes 10:45 - 11:30 Pretreatment of biomass: Impregnation phenomena, 11:45 - 12:30 pretreatment processes 10:15- 10:45 Lunch Pretreatment of biomass: Impregnation phenomena, 13:30 - 14:15 pretreatment processes Adriaan van Heiningen Adriaan van Heiningen 12:30 - 13:30 Adriaan van Heiningen 14:30 - 15:15 Chemistry of lignocellulosic constitutents 15:15 - 15:45 Coffee 15:45 - 16:30 Chemistry of lignocellulosic constitutents Stefan Böhmdorfer 16:45 - 17:30 Chemistry of lignocellulosic constitutents Stefan Böhmdorfer Stefan Böhmdorfer Tuesday 30.6. 8:30 - 9:15 Commercial and novel fractionation methods Herbert Sixta 9:30 - 10:15 Commercial and novel fractionation methods Herbert Sixta 10:15 - 10:45 Coffee 10:45 - 11:30 Commercial and novel fractionation methods 11:45 - 12:30 Green Chemistry: principles 12:30 - 13:30 Lunch 13:30 - 14:15 Green Chemistry: synthesis routes Thomas Rosenau 14:30 - 15:15 Green Chemistry: cellulose solvents and their chemistry Thomas Rosenau Coffee Bioprocess engineering: biochemical pretreatment of biomass, 15:45 - 16:30 production of chemicals Bioprocess engineering: biochemical pretreatment of biomass, 16:45 - 17:30 production of chemicals Herbert Sixta Thomas Rosenau 15:15 - 15:45 Bernd Nidetzky Bernd Nidetzky Wednesday 01.07. 8:30 - 9:15 Biorefinery analytics: characterization of process streams Antje Potthast 9:30 - 10:15 Biorefinery analytics: monomers, oligomers, polymers Antje Potthast 10:15 - 10:45 Coffee 10:45 - 11:30 Separation and purification: mass transfer and its applications 11:45 - 12:30 Separation and purification: mass transfer and its applications 12:30 - 13:30 Lunch 13:30 - 14:15 Separation and purification: mass transfer and its applications Daniela Painer/Matthäus Siebenhofer 14:30 - 15:15 Catalysed conversion of renewables to sustainable chemicals Roger Gläser Matthäus Siebenhofer Susanne Lux/Matthäus Siebenhofer I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y and fuels Coffee Catalysed conversion of renewables to sustainable chemicals 15:45 - 16:30 and fuels 15:15 - 15:45 17:30 Thursday 02.07 8:30 - 9:15 Buffé / Networkinf event Catalysed conversion of renewables to sustainable chemicals and fuels 9:30 - 10:15 Thermochemical conversion of forest biomass 10:15 - 10:45 Coffee Thermochemical conversion of forest biomass Lignin biorefinery: production and characteristics of lignin-based 11:45 - 12:30 products 10:45 - 11:30 Lunch Lignin biorefinery: production and characteristics of lignin-based 13:30 - 14:15 products Lignin biorefinery: production and characteristics of lignin-based 14:30 - 15:15 products Roger Gläser altogether Roger Gläser Adriaan van Heiningen Adriaan van Heiningen Claudia Crestini 12:30 - 13:30 Claudia Crestini Claudia Crestini 15:15 - 15:45 Coffee 15:45 - 16:30 Biofuel Martin Mittelbach/S. Schober 16:45 - 17:30 Biofuel Nikolaus Schwaiger Friday 03.07 8:30 - 9:15 9:30 - 10:15 Biofuel Hemicellulose biorefinery: production and characteristics of hemicellulose-based products Christoph Pfeifer Ed de Jong Coffee Hemicellulose biorefinery: production and characteristics of 10:45 - 11:30 hemicellulose-based products Polymer reinforcement with cellulose fibers. Basic concepts, 11:45 - 12:30 limitations and opportunities Ed de Jong Wolfgang GindlAltmutter Lunch Polymer reinforcement with cellulose fibers. Basic concepts, 13:30 - 14:15 limitations and opportunities Wolfgang GindlAltmutter 10:15 - 10:45 12:30 - 13:30 14:30 - 15:15 Economic and ecological aspects of biomass refining Stefan Schleicher 15:30 - 16:15 Economic and ecological aspects of biomass refining Stefan Schleicher 16:15 - 17:00 Coffee I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y Dr. Stefan Böhmdorfer Stefan Böhmdorfer received his PhD at Boku University in 2009 for synthetic and analytic work on Vitamin E model compounds. He is currently an assistant professor at Boku´s Department of Chemistry and pursues his habilitation in the field of Biorefinery analytics. His research is centered on method development for the chemical analysis of biomass based process streams. Prof. Claudia Crestini Dr. Claudia Crestini is member of the International Academy of Wood Science and chairwoman of the Interuniversity Consortium for Materials Science and Technology. She is a director of a Research Group consisting of 3 Post-doctoral Fellows, 1 Ph D Student, 1 Graduate Student. She is author of 2 books and has over 120 publications on international refereed journals, and over 50 scientific oral contributions at international conferences, meetings and schools. Her papers have been cited over 1700 times and her h-index is 33 (Google Scholar). Her research activity is now mainly directed towards the following topics: Structural characterization of polyphenolic biomolecules by advanced heteronuclear NMR techniques and quantitative 2D heterocorrelated NMR spectroscopy; Development of new materials from lignins and tannins; Study of supramolecular association-dissociation behavior in lignin; Development of supported catalysts and biomimetic catalysts for the activation of oxygen and hydrogen peroxide to the selective oxidation and functionalization of natural substances; Biocatalysis in processes of lignin degradation, with a special focus on the study of manganese peroxidase, laccases and laccase-mediator systems; Detection of radical species by 31P- based spin trap systems in oxidative systems: Lipoxigenase, laccase, bleaching solutions. Dr. Ed de Jong Ed de Jong graduated at Agricultural University Wageningen, the Netherlands and also defended his PhD thesis at the Agricultural University Wageningen, the Netherlands on the degradation of lignocellulose by white-rot fungi (1993). He has been research associate for 3 years at the University of British Columbia, Vancouver, Canada at the group of Jack Saddler, on the use of softwood species for biofuels application. He has been Head of the Department of Fibre and Paper Technology, Food and Biobased Research, Wageningen University & Research Centre, The Netherlands. He joint Avantium Chemicals in 2007. He is currently VP Development – responsible for PublicPrivate partnerships of Avantium, feedstock selection and Catalytic Biomass Conversion of carbohydrates into building blocks for polyesters such as PEF an improved replacement of PET. He is involved in site selection for the first commercial demonstration plant for the YXY technology. He is member of the board of the Topconsortium Knowledge and Innovation BioBased Economy (TKI-BBE). He is co-chair of the IEABioenergy Task 42 on biorefineries. Prof. Wolgang Gindl-Altmutter Wolgang Gindl-Altmutter received his PhD in 2000 from University of Natural Resources and Life Sciences (Boku). The topic of his thesis was “Climate induced variability of wood formation, lignification and wood quality”. He currently holds a chair as a full professor of Bio-based Fibre Materials, and he is Head of Institute at BOKU Vienna. His research interests include: past activities on basic and applicationoriented projects on wood adhesion, and on structure-mechanical property relationships in cellulosic materials. Presently, focus is on fibrillated cellulose, its production, properties, and application perspectives. He has more than 140 scientific publications. I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y Dr. Susanne Lux Susanne Lux received her PhD in 2009 from Graz University of Technology, Austria. She is currently an assistant professor in Institute of Chemical Engineering and Environmental Technology Graz University of Technology, Graz, Austria. Her research focus include chemical reaction engineering, homogeneous and heterogeneous catalytic reactions, process intensification, and reactive separations. Daniela Painer Daniela Painer graduated in 2013 as Dipl.-Ing. from Graz University of Technology, Austria. She is currently a university assistant in Institute of Chemical Engineering and Environmental Technology, Graz University of Technology. Her main research field is reaction engineering. Prof. Christoph Pfeifer Christoph Pfeifer studied chemical engineering at the Vienna University of Technology, and obtained his PhD at 2005. He is currently a full professor for Process Engineering of Renewable Resources at University of Natural Resources and Life Sciences (Boku), Austria. His research focuses on thermo-chemical conversion of biomass and other carbonaceous feedstock materials (waste, residues from agriculture and forestry, coal, etc.). Especially gasification (atmospheric and pressurized), combustion and hydrothermal carbonization is dealt with. Moreover, catalytic gas cleaning of producer gas from thermo-chemical biomass conversion is investigated. In the team process optimisation using simulation software tools and generally fundamental know-how about cold flow modelling of fluidized bed systems is available. Prof. Antje Potthast Antje Potthast received her PhD in 1998 from Dresden University of Technology and Habilitation in 2003 from University of Natural Resources and Life Sciences (Boku), Austria. Her current position is Associate Professor at the Department of Chemistry, BOKU, with specialization “Biopolymer analysis” and Co-leader in Christian-Doppler-Laboratory with specialization "Advanced cellulose chemistry and analytics". She has more than 180 scientific publications. Prof. Thomas Rosenau Thomas Rosenau studied chemistry at Dresden University of Technology, Germany, and received his Doctoral degree (Chemistry and Toxicology) 1997. Year 2003 he was granted Habilitation for organic chemistry, University of Natural Resources and Life Sciences (BOKU), Austria. Since 2005 he has been professor, Chair of Wood, Pulp and Fiber Chemistry at BOKU, Austria. Since 2008 he has been also a co-leader at the Christian Doppler Laboratory: "Advanced cellulose chemistry and analytics". I N TE R N A TI O N A L D O C T O R A L P R O G R A M M E I N B I O P R O D U C T S TE C H N O L O G Y Prof. Matthäus Siebenhofer Matthäus Siebenhofer studied technical chemistry and chemical engineering at Graz University of Technology, and obtained his PhD at 1983. After working several years in industry he returned to the University, and since 2005 he has been a professor at the Institute of Chemical Engineering and Environmental Technology, Graz University of Technology, Austria. From 2008 he has also been the Head of the Institute of Chemical Engineering and Environmental Technology. Prof. Herbert Sixta Herbert Sixta studied chemistry at the University of Innsbruck, Austria, and obtained his Ph.D. on heterogeneous catalysis involving Fischer Tropsch reactions in 1982. After 25 years in industry he accepted a call to the Helsinki University of Technology in 2007. He currently holds a chair in Biorefineries at the Department of Forest Products Technology. From 2014 He has also been the Head of the Department of Forest Products Technology. His research focuses on the conversion of existing pulp mills to biorefineries, novel fractionation technologies, the characterization and design of ionic liquids for the dissolution and regeneration of lignocellulosic polymers.
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