11.2 specific heat 11.3 calorimetry How much heat needed to raise T?? Exercise calorimeter- insulating, ~ no heat exchanged w outside 2. A 50-g sample of copper is at 25°C. If 1,200 J of energy is added to the copper by heat, what is its final temperature? Define specific heat c: SI unit: J/kg•ºC Q c = Q/m∆T (eq. 11.2) mass of object c depends on material Exercise read (p.336): c of H2O, effect on environment Quick Quiz 11.1 Imagine you have 1 kg each of iron, glass, and water, and that all three samples are at 10ºC. (Rank the samples from lowest to highest temperature after 100 J of energy is added to each by heat. (b) Rank them from least to greatest amount of energy transferred by heat if enough energy is transferred so that each increases in temperature by 20ºC. www College Physics W04 Prof. Kinoshita 11.4 latent heat, phase changes 3 phases of matter: solid, liquid, gas Phase change: solid ↔ liquid freezing/melting liquid ↔ gas boiling/condensation sublimation solid ↔ gas fluid, heat capacity cw, mass m -> Q from ∆T: Q = m cw ∆T (from eq. 11.2) object under study Heat transferred from colder to warmer object => Qcold = – Qhot (eq. 11.4) 15. An aluminum cup contains 225 g of water and a 40-g copper stirrer, all at 27°C. A 400-g sample of silver at an initial temperature of 87°C is placed in the water. The stirrer is used to stir the mixture gently until it reaches its final equilibrium temperature of 32°C. Calculate the mass of the aluminum cup. 18. A combination of 0.250 kg of water at 20.0°C, 0.400 kg of aluminum at 26.0°C, and 0.100 kg of copper at 100°C is mixed in an insulated container and allowed to come to thermal equilibrium. Neglect any energy transfer to or from the container and determine the final temperature of the mixture. www College Physics W04 Prof. Kinoshita 11.4 all involve changes to internal energy Require heat to change phase of substance: Exercise 23. What mass of steam that is initially at 120°C is needed to warm 350 g of water and its 300-g aluminum container from 20°C to 50°C? cAl = 0.215 cal/g•ºC Q = ± mL (eq. 11.5) (no change in T) Latent heat - specific to phases, substance Latent heat of fusion Lf solid ↔ liquid vaporization Lv liquid ↔ gas So, if we add heat at const rate to e.g. solid H2O, T vs t (p. 338-9): ice -> water understandable at molecular level (p. 340) water -> steam College Physics W04 Prof. Kinoshita Follow problem-solving strategy (p. 340): 1) consistent units 2) Q=mc∆T only for no phase change Q=mLf for solid ↔ liquid for liquid ↔ gas Q=mLv 3) sign (±) heat gain or loss www College Physics W04 Prof. Kinoshita www 11.5 energy transfer by conduction 11.5 What about multiple layers with different materials? (read, p. 344) 3 ways to transfer heat: conduction, convection, radiation conduction (read) • molecular-level energy transfer over macroscopic distances • no net movement of matter Tc heat conducts warm -> cold Th Q Define heat transfer rate: "R value" Read p. 344 on units for R value area A Exercise what does P depend on, and how? • ∆T • distance L • x-sectional area of conducting material • material's conductivity, k (work examples) College Physics W04 Prof. Kinoshita Ri www 39. A copper rod and an aluminum rod of equal diameter are joined end to end in good thermal contact. The temperature of the free end of the copper rod is held constant at 100°C, and that of the far end of the aluminum rod is held at 0°C. If the copper rod is 0.15 m long, what must be the length of the aluminum rod so that the temperature at the junction is 50°C? College Physics W04 Prof. Kinoshita www
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