1. No category

Calibration and Reference
Sample
for
AC DHA classic analyzer
Box no.
Sample no.
Lot no.
Sample name
25115.610
51.15.610
008
n-Paraffin Calibration
Standard
25115.520
50.16.512
011
Quantitative Reference
Standard
25116.510
51.16.501
005
Qualitative RFA sample
For reordering samples use the Boxno. mentioned above.
AC Analytical Controls BV
Innsbruckweg 35
3047 AG Rotterdam
The Netherlands
Phone: +31-(0)10-462 4811
Fax: +31-(0)10-4626330
E-mail: [email protected]
PAC LP
8824 Fallbrook Dr.
Houston, Texas 77064
USA
Phone: +1-281 940 1803
Fax: +1-281 580 0719
E-mail: [email protected]
AC Analytical Controls Asia Pacific Pte Ltd
61, Science Park Road,
#03-09/10 The Galen, Singapore Science
Park III, Singapore 117525
Phone: +65-6412 0890
Fax. +65-6412 0899
E-mail: [email protected]
Revised, April 2009
Expiry date samples
Box no.
Sample no. Lot no.
Sample
name
Date
prepared
Expiry
Date
March
2008
March 2013
25115.610 51.15.610
008
n-Paraffin
Calibration
Standard
25115.520 50.16.512
011
Quantitative April 2009
Reference
Standard
April 2009
25116.510 51.16.501
005
Qualitative Aug 2008
RFA sample
Aug 2013
2
Index
Page
Sample verification
4
Important sample information
4
System Configuration
5
n-Paraffin Calibration Standard
Sample Part no. 51.15.610
6
Quantitative Reference Standard
Sample Part no. 50.16.512
9
Qualitative RFA Sample
Sample Part no. 51.16.501
14
Material Safety Data Sheet
39
3
Sample verification
Each AC standard is carefully manufactured and shipped using our high quality
procedures. A sample booklet is included with the standards and contains
detailed chromatographic information about the sample. To overcome any
wrong interpretation of the results it is necessary to check your actual AC
standard run performed on site with the example chromatogram in the booklet.
If any discrepancy is found, we advise you to contact AC before continuing
analyzing your samples.
Important sample information
Store the ampoules in a freezer. They contain a mixture of low boiling
components. So once opened, the lifetime is limited!
WARNING - Light hydrocarbons are toxic. Avoid inhaling fumes and contact
with any part of the body.
WARNING - Light hydrocarbons are extremely flammable. The fumes and
vapors from light hydrocarbons are easily ignited. Keep this
material away from flames, sparks and other sources of heat.
WARNING - Oxygenated hydrocarbons, such as alcohols and ethers, may be
harmful or toxic and are extremely flammable.
CAUTION - The broken glass ampoule has sharp edges which may cause
cuts to the skin. Take care when breaking the top of this
ampoule.
WARNING - Carbon Disulfide (CS2) is highly toxic. Utilize this chemical only
in a Fume hood. Avoid inhaling fumes. CS2 is easily absorbed
through the skin. Avoid any contact with any part of your body.
WARNING - Carbondisulfide (CS2 ) is extremely flammable. The flash point of
CS2 is very low:-30°C. Fume and vapors are heavier than air
and will travel long distances. Do not use CS2 nearopen flames,
sparks or sources of heat. Do not use open containers or vials of
CS2 near hot injectors or detectors on the gaschromatograph.
WARNING - Carbondisulfide (CS2 ) boils at very low temperature: 45°C.
When storing or working with CS2 never expose a container or
vial containing CS2 to temperature excee ding 45°C.
WARNING - Carbon Disulfide evaporates very quickly. Handle one vial at the
time and seal the vial immediately after preparation.
4
System configuration
All information illustrated in this sample booklet is obtained by configuring the GC to
the following setup and by making the adjustments given below.
The obtained RFA data is the average of approximately 50 RFA analyses on different
AC Detailed Hydrocarbon Analyzers (AC DHA).
System
Column
Sample size
Split ratio
Inlet temperature
Detector temperature
Oven
: AC DHA analyzer
: 100 meter x 0.25 mm ID x 0.5 m
: 0.2 l
: 100:1
: 250 C
: 250 C
: Initial temperature
35 C
Initial time
13 min
First Program Rate
10 C/min
First Hold Temperature
45 C
First Hold Time
15 min
Second Program Rate
1 C/min
Second Hold Temperature
60 C
Second Hold Time
15 min
Third Program Rate
1.9 C/min
Third Hold Temperature
200 C
Third Hold Time
5 min
5
n-Paraffins Calibration Standard
Box no. 25115.610
6
n-Paraffins Calibration Standard
Storage instructions
The n-paraffin mix is shipped as a concentrated liquid suspension of normal alkanes.
The vial contains approximately 1.0 grams, and must be diluted with Carbon
Disulfide prior to use. Store the mixture in the refrigerator prior to preparation. Do not
heat the concentrated liquid suspension.
Sample preparation
The DHA analysis is based on the principle of referring component retention times to
the retention times of n-paraffins according to the Kovats index. The retention times
of n-paraffins are measured with two standards, a natural gas standard and a nparaffin standard. The n-paraffin standard, part number 25115.610, consists of
n-paraffins from C5 to C14. This measurement should be carried out on a regular
basis to prevent erroneous storage of retention times of the n-paraffins.
Preparing a n-paraffins C5 to C14 standard
 Fill a 2 ml vial with 0.1 gram of the n-paraffins standard
 Add to the vial approximately 1 ml CS2. This will give a solution of approximately 1
mass% per component
 Seal the vial and shake well
 Place the vial in the desired position of the automatic liquid sampler tray
7
n-Paraffins Calibration Standard
8
Quantitative Reference Standard
Box no. 25115.520
9
Quantative Reference Standard
Storage instructions
Store the ampoules in a freezer. They contain a quantitative mixture of low boiling
components. So once opened, lifetime is limited!
Sample information
#
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
Component
n-Pentane
Cyclopentane
2,3-Dimethylbutane
1-Hexene
n-Hexane
Benzene
Cyclohexane
4-Methyl-1-Hexene
2,2,4-Trimethylpentane
n-Heptane
Methylcyclohexane
Toluene
1t,2-Dimethylcyclohexane
n-Octane
1c,2-Dimethylcyclohexane
Ethylbenzene
1c,2t,4t-Trimethylcyclohexane
1c,2t,3c-Trimethylcyclohexane
1c,2t,4c-Trimethylcyclohexane
o-Xylene
1,1,2-Trimethylcyclohexane
n-Nonane
n-Propylbenzene
1,2,4-Trimethylbenzene
n-Decane
1,2,3-Trimethylbenzene
2,3-Dihydroindene
t-Decahydronaphtalene
n-Undecane
1,2,4,5-Tetramethylbenzene
n-Dodecane
Pentamethylbenzene
n-Tetradecane
Category
C5nP
C5N
C6iP
C6nOP
C6nP
C6A
C6N
C7iOP
C8iP
C7nP
C7N
C7A
C8N
C8nP
C8N
C8A
C9N
C9N
C9N
C8A
C9N
C9nP
C9A
C9A
C10nP
C9A
C9A
N
C11nP
C10A
C12nP
C11A
C14nP
Mass %
1.10
1.10
2.05
1.45
2.05
2.20
2.05
1.60
5.00
3.50
4.15
2.20
impurity of 15
5.00
5.00*
4.50
4.15*
impurity of 17
impurity of 17
4.15
impurity of 17
4.50
5.00
4.50
4.25
5.00*
impurity of 26
4.25
3.55
4.95
3.30
4.95
4.50
BP °C
36.1
49.2
58.0
63.3
69.0
80.1
80.7
87.1
99.2
98.4
101.0
111.0
123.0
126.0
BP °F
97.0
120.6
136.4
145.9
156.2
176.2
177.3
188.8
210.6
209.1
213.8
231.8
253.4
258.8
136.0
138.0
276.8
280.4
144.0
219.2
151.0
159.0
169.0
174.0
176.0
303.8
318.2
336.2
345.2
348.8
187.0
196.0
197.0
216.0
232.0
254.0
368.6
384.8
386.6
420.8
449.6
489.2
* Adding the main component and its impurities gives the total mass% per component.
NOTE - Maximal acceptable deviation of analysis results is 0.3% mass absolute per
component.
10
Quantitative Reference Standard
(1 of 3)
11
Quantitative Reference Standard
(2 of 3)
12
Quantitative Reference Standard
(3 of 3)
13
Qualitative RFA Sample
Box no. 25116.510
14
Qualitative RFA Sample
Part no. 25116.510
This sample can be used for peak identification only.
Storage instructions
Store the ampoules in a freezer prior to use. Once opened, lifetime is limited!
Analysis Mode: PIANO
Totals by Group Type & Carbon Number (in Weight Percent).
Carbon
Number
1
2
3
4
5
6
7
8
9
10
11
12
13
14
Totals
Paraffins
I-paraffins
Aromatics
Naphthenes Olefins
0.000
0.000
0.000
4.134
3.249
2.389
1.170
0.827
0.240
0.094
0.066
0.067
0.242
0.026
0.000
0.000
0.000
0.080
4.256
9.990
5.739
8.532
2.730
1.067
0.213
0.377
0.017
0.000
0.000
0.000
0.000
0.000
0.000
1.923
6.838
13.741
9.548
5.230
1.143
0.576
0.000
0.000
0.000
0.000
0.000
0.000
0.192
1.111
1.404
1.899
0.767
0.201
0.075
0.000
0.000
0.000
0.000
0.000
0.000
0.000
2.569
2.444
2.097
0.386
0.270
0.069
0.031
0.000
0.020
0.000
0.000
0.000
0.000
4.214
10.266
17.857
17.248
25.386
13.556
6.662
1.527
1.020
0.279
0.026
12.504
33.001
5.649
7.886
98.041
Oxygenates
Total C13+
Total Unknowns
Grand Total
38.999
0.000
0.000
1.959
100.000
15
Totals
ID
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
Component name
Propane
i-Butane
n-Butane
2,2-Dimethylpropane
3-Methylbutene-1
i-Pentane
Pentene-1
2-Methylbutene-1
n-Pentane
Isoprene
t-Pentene-2
c-Pentene-2
2-Methylbutene-2
1t,3-Pentadiene
1c,3-Pentadiene
2,2-Dimethylbutane
Cyclopentene
4-Methylpentene-1
3-Methylpentene-1
Cyclopentane
2,3-Dimethylbutane
2,3-Dimethylbutene-1
2-Methylpentane
2-Methyl-1,4-pentadiene
3-Methylpentane
2-Methylpentene-1
Hexene-1
2-Ethylbutene-1
n-Hexane
t-Hexene-3
c-Hexene-3
t-Hexene-2
2-Methylpentene-2
3-Methylcyclopentene
3-Methyl-c-pentene-2
O13
c-Hexene-2
O14
3,3-Dimethylpentene-1
2,2-Dimethylpentane
Index
300.0
361.6
400.0
413.0
454.7
473.2
487.9
494.9
500.0
504.7
507.2
515.2
520.2
522.5
534.6
536.8
554.7
558.0
559.7
566.1
567.5
569.5
571.4
580.5
584.3
588.5
589.4
599.0
600.0
601.8
603.0
604.5
606.8
609.4
610.2
612.4
613.9
616.2
620.0
624.4
16
ID
41
42
43
44
45
46
47
48
49
50
51
52
53
54
55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
Component name
Unidentified
Methylcyclopentane
2,4-Dimethylpentane
2,3,3-Trimethylbutene-1
Cyclic Diolefin or Triolefin
Unidentified
2,2,3-Trimethylbutane
Cyclic Diolefin or Triolefin
O17
3,4-Dimethylpentene-1
4,4-Dimethyl-c-pentene-2
2,4-Dimethylpentene-1
1-Methylcyclopentene
Benzene
2-Ethylpentene-1
3-Methylhexene-1
3,3-Dimethylpentane
5-Methylhexene-1
Cyclohexane
2-Methyl-t-hexene-3
Diolefin (hexadiene)
2-Ethyl-3-methylbutene-1
Unidentified
4-Methylhexene-1
4-Methyl-t/c-hexene-2
2-Methylhexane
2,3-Dimethylpentane
1,1-Dimethylcyclopentane
/TAME
Cyclohexene
3-Methylhexane
3,4-Dimethyl-c-pentene-2
1c,3-Dimethylcyclopentane
1t,3-Dimethylcyclopentane
3-Ethylpentane
1t,2-Dimethylcyclopentane
2,2,4-Trimethylpentane
3-Methyl-c-hexene-3
t-Heptene-3
n-Heptane
17
Index
626.0
626.9
630.5
631.8
633.9
635.2
636.0
637.6
642.1
643.4
646.4
647.8
648.9
649.7
650.8
652.1
655.3
656.7
659.0
660.3
661.5
662.2
663.0
663.8
666.1
667.6
669.3
672.1
674.1
676.1
679.4
682.3
685.0
686.0
687.6
689.3
694.6
698.1
700.0
ID
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
100
101
102
103
104
105
106
107
108
109
110
111
112
113
114
115
116
117
118
119
Component name
c-Heptene-3
2-Methyl-2-hexene
3-Methyl-t-hexene-3
t-Heptene-2
3-Ethylpentene-2
c-Heptene-2
2,3-Dimethylpentene-2
3-Ethylcyclopentene
Unidentified
O29
1c,2-Dimethylcyclopentane
Methylcyclohexane
1,1,3-Trimethylcyclopentane
O35
O36
Ethylcyclopentane
2,5-Dimethylhexane
2,2,3-Trimethylpentane
2,4-Dimethylhexane
Unidentified
O37
1c,2t,4-Trimethylcyclo3,3-Dimethylhexane
Unidentified
Unidentified
1t,2c,3-TrimethylcycloO39
2,3,4-Trimethylpentane
O40
Toluene
O41
O42
O43
Unidentified
2,3-Dimethylhexane
2-Methyl-3-ethylpentane
1,1,2-Trimethylcyclopentane
O44
2-Methylheptane
4-Methylheptane
18
Index
701.4
702.2
703.4
705.4
707.3
710.9
714.8
715.7
719.4
720.1
721.5
722.4
725.7
729.9
732.2
735.2
736.8
737.7
738.8
740.2
742.2
744.4
745.9
750.5
751.1
751.8
752.6
754.6
756.5
758.1
759.9
761.0
759.7
762.6
765.3
766.4
767.3
768.2
771.1
772.4
ID
Component name
120
121
122
123
124
125
126
127
128
129
130
131
132
133
134
135
136
137
138
139
140
141
142
143
144
145
146
147
148
149
150
151
152
153
154
155
156
157
158
159
3-Methyl-3-ethylpentane
3,4-Dimethylhexane
1c,3-Dimethylcyclohexane
3-Methylheptane
1c,2t,3-Trimethylcyclopentane
3-Ethylhexane
1t,4-Dimethylcyclohexane
1,3-Octadiene
1,1-Dimethylcyclohexane
2,2,5-Trimethylhexane
3c-Ethylmethylcyclopentane
Unidentified
3t-Ethylmethylcyclopentane
2t-Ethylmethylcyclopentane
1,1-Methylethylcyclopentane
2,2,4-Trimethylhexane
1t,2-Dimethylcyclohexane
t-Octene-4
1c,2c,3-Trimethylcyclopentane
1t,3-Dimethylcyclohexane
n-Octane
Octene-2
I2
i-Propylcyclopentane
O52
Unidentified
O53
N1
2,2,3,4-Tetramethylpentane
2,3,4-Trimethylhexane
N2
Unidentified
N3
2,3,3-Trimethylhexene-1
2,3,5-Trimethylhexane
2,2-Dimethylheptane
Unidentified
1,1,4-Trimethylcyclohexane
N4
2,2,3-Trimethylhexane
19
Index
773.3
773.7
775.9
777.8
778.6
779.3
780.3
782.1
784.9
787.2
788.0
789.0
789.8
790.8
791.4
792.9
794.5
795.5
797.8
799.0
800.0
804.0
805.9
807.6
810.0
810.6
812.8
814.1
815.8
817.8
819.4
821.0
821.8
823.7
826.2
827.9
828.8
831.4
832.5
833.6
ID
Component name
160
161
162
163
164
165
166
167
168
169
170
171
172
173
174
175
176
177
178
179
180
181
182
183
184
185
186
187
188
189
190
191
192
193
194
195
196
197
198
199
2,4-Dimethylheptane
Unidentified
4,4-Dimethylheptane
2,6-Dimethylheptane
2,5-Dimethylheptane
3,5-Dimethylheptane
3,3-Dimethylheptane
1,1,3-Trimethylcyclohexane
N7
N8
Ethylbenzene
N11
1c,2t,4t-Trimethylcyclohexane
Unidentified
I3
N12
m-Xylene
p-Xylene
2,3-Dimethylheptane
3,4-Dimethylheptane
3,4-Dimethylheptane
I4
4-Ethylheptane
4-Methyloctane
2-Methyloctane
3-Ethylheptane
3-Methyloctane
1c,2t,4c-Trimethylcyclohexane
I5
o-Xylene
I6
Unidentified
I7
N18
N19
I8
N20
Nonene-1
i-Butylcyclopentane
Unidentified
20
Index
835.4
836.4
837.6
840.8
842.2
843.5
844.8
846.5
849.7
850.7
851.3
852.6
853.5
854.4
856.5
895.5
861.3
862.4
863.9
865.8
866.7
869.0
870.6
872.0
877.8
873.0
879.0
880.2
881.1
882.1
883.4
884.6
885.7
887.4
888.2
889.9
890.7
892.0
892.9
893.5
ID
Component name
200
201
202
203
204
205
206
207
208
209
210
211
212
213
214
215
216
217
218
219
220
221
222
223
224
225
226
227
228
229
230
231
232
233
234
235
236
237
238
239
N22
I9
N24
t-Nonene-3
n-Nonane
1,1-Methylethylcyclohexane
Unidentified
N25
t-2,2,5,5-Tetramethylhexene-3
i-Propylbenzene
N27
c-Nonene-3
I10
i-Propylcyclohexane
I11
2,2-Dimethyloctane
2,4-Dimethyloctane
N29
2,6-Dimethyloctane
2,5-Dimethyloctane
n-Butylcyclopentane
I13
N30
3,3-Dimethyloctane
Unidentified
n-Propylbenzene
3,6-Dimethyloctane
3-Methyl-5-ethylheptane
N32
Unidentified
1,3-Methylethylbenzene
1,4-Methylethylbenzene
1,3,5-Trimethylbenzene
I15
Unidentified
I16
I17
1,2-Methylethylbenzene
2-Methylnonane
Unidentified
21
Index
895.6
897.0
898.2
899.2
900.0
902.7
904.1
905.5
906.8
912.1
914.4
915.7
916.7
917.8
918.7
922.0
924.8
929.4
931.8
933.0
936.9
937.7
938.7
942.7
944.6
946.3
948.1
948.8
952.6
953.6
954.3
956.2
961.8
963.9
964.0
965.8
968.0
970.3
971.9
973.2
ID
240
241
242
243
244
245
246
247
248
249
250
251
252
253
254
255
256
257
258
259
260
261
262
263
264
265
266
267
268
269
270
271
272
273
274
275
276
277
278
279
Component name
3-Ethyloctane
3-Methylnonane
Unidentified
I19
1,2,4-Trimethylbenzene
I20
i-Butylcyclohexane
I21
I22
N37
Decene-1
I24
i-Butylbenzene
I25
sec-Butylbenzene
n-Decane
N38
1,2,3-Trimethylbenzene
1,3-Methyl-i-propylbenzene
1,4-Methyl-i-propylbenzene
I28
I29
2,3-Dihydroindene
I30
Unidentified
1,2-Methyl-i-propylbenzene
Unidentified
N40
Unidentified
1,3-Diethylbenzene
1,3-Methyl-n-propylbenzene
I33
1,4-Diethylbenzene
1,4-Methyl-n-propylbenzene
n-Butylbenzene
1,3-Dimethyl-5-ethylbenzene
1,2-Diethylbenzene
N41
Unidentified
1,2-Methyl-n-propylbenzene
22
Index
974.7
977.5
981.1
981.8
983.5
985.0
986.2
987.1
988.1
991.2
992.8
993.5
995.9
996.6
997.9
1000.0
1002.9
1007.0
1009.5
1013.2
1018.0
1019.0
1019.7
1024.9
1026.4
1028.1
1032.1
1033.5
1037.9
1039.8
1042.5
1045.0
1045.8
1046.4
1047.5
1049.6
1051.8
1054.4
1056.5
1058.0
ID
280
281
282
283
284
285
286
287
288
289
290
291
292
293
294
295
296
297
298
299
300
301
302
303
304
305
306
307
308
309
310
311
312
313
314
315
316
317
318
319
Component name
I36
I37
I38
1,4,Dimethyl-2-ethylbenzene
1,3-Dimethyl-4-ethylbenzene
I39
1,2-Dimethyl-4-ethylbenzene
I41
1,3-Dimethyl-2-ethylbenzene
I43
Unidentified
Undecene-1
1,4-Methyl-t-butylbenzene
1,2-Dimethyl-3-ethylbenzene
1,2-Ethyl-i-propylbenzene
n-Undecane
Unidentified
1,4-Ethyl-i-propylbenzene
1,2,4,5-Tetramethylbenzene
1,2,3,5-Tetramethylbenzene
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
5-Methylindan
I43
4-Methylindan
Unidentified
1,2-Ethyl-n-propylbenzene
2-Methylindan
1,2-Methyl-n-butylbenzene
1,3-Di-i-propylbenzene
n-Pentylbenzene
1,2-di-i-Propylbenzene
Unidentified
1,4-di-i-Propylbenzene
Tetrahydronaphthalene
Unidentified
23
Index
1059.4
1062.9
1065.8
1068.0
1069.7
1071.3
1075.2
1079.8
1080.8
1084.4
1087.1
1090.6
1091.9
1093.2
1097.4
1100.0
1102.2
1103.4
1105.1
1109.0
1112.2
1113.5
1116.2
1118.6
1120.5
1121.6
1127.8
1132.2
1133.2
1134.7
1136.1
1138.6
1141.3
1143.3
1149.4
1153.9
1157.7
1159.5
1163.5
1166.3
ID
Component name
320
321
322
323
324
325
326
327
328
330
331
332
333
334
335
336
337
338
339
340
341
342
343
344
345
346
347
348
349
350
351
352
353
354
355
356
357
358
359
360
Naphthalene
4-Ethyl,1-t-butylbenzene
I45
I46
I47
I48
1,3-di-n-Propylbenzene
A5
Unidentified
n-Dodecane
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
1,2,4-Triethylbenzene
Unidentified
Unidentified
Unidentified
1,4-Methyl-n-pentylbenzene
Unidentified
Unidentified
Unidentified
Unidentified
n-Hexylbenzene
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
Unidentified
I49
Unidentified
Unidentified
1,2,3,4,5-Pentamethylbenzene
Unidentified
24
Index
1168.6
1174.1
1178.3
1179.9
1184.1
1187.6
1188.7
1190.3
1194.1
1200.0
1204.6
1208.6
1210.0
1214.3
1215.4
1217.4
1223.3
1225.6
1228.7
1231.6
1233.4
1236.3
1238.0
1242.9
1244.3
1246.5
1249.2
1252.1
1253.7
1257.2
1261.1
1263.1
1264.9
1266.3
1267.8
1269.8
1272.0
1274.3
1275.9
1281.6
ID
361
362
363
364
365
366
Component name
2-Methylnaphthalene
Unidentified
Unidentified
Unidentified
Unidentified
n-Tridecane/1-Methylnaphthalene
Index
1284.6
1288.2
1290.8
1295.6
1297.2
1300.0
NOTE - The index can slightly differ per system due to system and column
configuration.
25
Qualitative RFA sample
Part no. 251160.510
(1 of 13)
26
Qualitative RFA sample
Part no. 251160.510
(2 of 13)
27
Qualitative RFA sample
Part no. 251160.510
(3 of 13)
28
Qualitative RFA sample
Part no. 251160.510
(4 of 13)
29
Qualitative RFA sample
Part no. 251160.510
(5 of 13)
30
Qualitative RFA sample
Part no. 251160.510
(6 of 13)
31
Qualitative RFA sample
Part no. 251160.510
(7 of 13)
32
Qualitative RFA sample
Part no. 251160.510
(8 of 13)
33
Qualitative RFA sample
Part no. 251160.510
(9 of 13)
34
Qualitative RFA sample
Part no. 251160.510
(10 of 13)
35
Qualitative RFA sample
Part no. 251160.510
(11 of 13)
36
Qualitative RFA sample
Part no. 251160.510
(12 of 13)
37
Qualitative RFA sample
Part no. 251160.510
(13 of 13)
38
Material safety data sheet
Date Prepared: September 2007
Qualitative RFA Sample
Chemical Product Information:
Qualitative RFA Sample
AC Analytical Controls Part number: 25116.510
Gravimetric standard (naphtha)
Chemical Product Information:
Gravimetric standard (naphtha)
AC Analytical Controls Part number: 25115.520
n-Paraffin Mixture
Chemical Product Information:
n-Paraffin Mixture
AC Analytical Controls Part number: 25115.610
Mixbox 20002.001 contains all samples mentioned above, 1 each.
Section 1 - Manufacturer data
AC Analytical Controls BV
Innsbruckweg 35
3047 AG Rotterdam
The Netherlands
Phone: +31-(0)10-462 4811
Fax: +31-(0)10-4626330
E-mail: [email protected]
PAC LP
8824 Fallbrook Dr.
Houston, Texas 77064
USA
Phone: +1-281 940 1803
Fax: +1-281 580 0719
E-mail: [email protected]
AC Analytical Controls Asia Pacific Pte Ltd
61, Science Park Road,
#03-09/10 The Galen, Singapore Science
Park III, Singapore 117525
Phone: +65-6412 0890
Fax. +65-6412 0899
E-mail: [email protected]
Section 2 - Chemical identity/hazardous ingredients
n-Paraffin Calibration Standard
Chemical name
Petroleum-Paraffin
Mixture consisting
of:
Alkanes Mixture
n-Hexane
CAS#
OSHA
PEL/TWA
ACGIH
TLV/TWA
8030-30-6
300ppm
300ppm
110-54-3
50ppm
50ppm0-6
39
%Mass
Mass
Mixture
Quantitative Reference Standard
Chemical name
Petroleum Naphtha
consisting of:
Alkanes, Cycloalkanes,
Alkanes and Aromatic
Hydrocarbons
Benzene
Toluene
Ethylbenzene
n-Propylbenzene
0-Xylene
1,2,3-Trimethylbenzene
1,2,4-Triemthylbenzene
1,2,4,5Tetramethylbenzene
n-Pentane
n-Hexane
n-Heptane
n-Octane
n-Nonane
Cyclohexane
CAS#
8030-306
OSHA
PEL/TWA
300ppm
ACGIH
TLV/TWA
300ppm
%Mass
Mass
Mixture
Mixture
71-43-2
108-88-3
100-41-4
103-65-1
95-47-6
95-63-6
95-63-6
95-93-2
1 ppm
100 ppm
100 ppm
NE
100 ppm
25 ppm
25 ppm
25 ppm
10 ppm
100 ppm
100 ppm
NE
100 ppm
25 ppm **
25 ppm **
25 ppm **
Balance
1-3
2-3
4-6
4-6
4-5
4-6
4-6
4-6
109-66-0
110-54-3
142-82-5
111-65-9
111-84-2
110-82-7
1000 ppm
50 ppm
400 ppm
300 ppm
200 ppm
300 ppm
600 ppm
50 ppm
500 ppm
300 ppm
200 ppm
300 ppm
4-6
4-6
4-6
4-6
4-6
4-6
 Classified by ACGIHasa “Suspected Human Carcinogen” (A2)
 ** for Trimethylbenzenes
Chemical Families: Hydrocarbons-Chemical Synonyms: NA
Qualitative RFA Sample
 Chemical Name: Petroleum Naphtha, consisting of hydrocarbons C4 - C12
 CAS Number: 86290-81-5
40
Section 3 - Physical/chemical data
n-Paraffin Calibration Standard
Special Gravity [H2O=1]:
Melting Point [°C]:
Evaporation rate [n-butyl acetate=1]:
Boiling Point [°C]:
Vapor Pressure [PSI (Reid)]:
Vapor Density [Air = 1]:
Solubility in Water:
Appearance and Odor:
0.72 - 0.76
NA
NA
36 - 280
7 - 15
3.5
Insoluble: ( X )
Soluble: ( )
Clear to light colored liquid with gasoline
like odor
Quantitative Reference Standard
Special Gravity [H2O=1]:
Melting Point [°C]:
Evaporation rate [n-butyl acetate=1]:
Boiling Point [°C]:
Vapor Pressure [PSI (Reid)]:
Vapor Density [Air = 1]:
Solubility in Water:
Appearance and Odor:
0.72 - 0.76
NA
NA
36 - 280
7 - 15
3.5
Insoluble: ( X )
Soluble: ( )
Clear to light colored liquid with a
gasoline like odor
Qualitative RFA Sample
Special Gravity [H2O=1]:
Melting Point [°C]:
Boiling Point [°C]:
Vapor Pressure [mbar, 20°C]:
Vapor Density [Air = 1]:
Solubility in Water:
Appearance and Odor:
odor
0.7 - 0.8
< -20
38 - 205
50 - 400
4
Insoluble: ( X )
Soluble: ( )
Clear to light colored liquid with typical
Disclaimer: This Material Safety Data sheet is offered without charge to the
customers of AC Analytical Controls. Data is the most currently available to AC
Analytical Controls at the time of preparation and is issued as a matter of
information only, no warranty as to its accuracy or completeness is expressed or
implied.
41
Section 4 - Fire/explosion data
This product is extremely flammable!
Flash Point:
<-40 °C
Flammable Limits:
LEL: (1.3 )
UEL: ( 7.6 )
Extinguishing Media: Carbon dioxide, dry chemical powder, foam or water fog.
Mixture will float on water and can reignite on surface.
Special Fire Fighting Procedures: Wear full protective clothing and self
contained positive pressure breathing apparatus certified by NIOSH when fighting
chemically related fires.
Unusual Fire and Explosion Hazards: Volatile and highly flammable. Vapor may
travel a considerable distance to the source of ignition and flash back. Container
explosion may occur under fire conditions.
Section 5 - Reactivity data
Stability: Stable: ( X ) Unstable: ( )
 Conditions to avoid: Heat, sparks, open flames, open containers and poor
ventilation.
 Incompatibility (materials to avoid): Oxidizing agents.
 Hazardous Decomposition or By-products: Incomplete combustion may
generate carbon monoxide and other toxic materials.
Hazardous Polymerization:
May Occur: ( ) Will Not Occur: ( X )
Section 6 - Health hazard/emergency first aid
Route(s) of Entry: Inhalation? (Yes) Skin? (Yes) Ingestion? (Yes)
Inhalation: Harmful if inhaled. Vapor or mist is irritating to the mucous membranes
and upper respiratory tract. May produce liver and kidney damage. Symptoms of
exposure may include burning sensation, coughing, wheezing, laryngitis, shortness
of breath, headache, nausea, vomiting and CNS depression. If inhaled, remove to
fresh air. If breathing is difficult, give oxygen. Contact Physician.
42
Eye Contact: Vapor or mist is irritating to the eyes. Contamination of the eyes
should be treated by immediate and prolonged irrigation with copious amounts of
water by separating the eyelids with the fingers. Contact Physician.
Skin Contact: Causes skin irritation. In case of contact, immediately wash the skin
with soap and copious amounts of water. Remove and wash contaminated clothing
promptly.
Ingestion: Harmful or fatal if swallowed. Call “Poison Control Center” for
assistance. Contact Physician immediately.
Health Hazard Acute/Chronic: This chemical is an eye and mucous membrane
irritant and central nervous system depressant. Acute exposure causes irritation,
gastrointestinal tract discomfort and narcosis.
Medical Conditions Generally Aggravated by Exposure:
Preclude from exposure those persons susceptible to dermatitis.
Section 7 - Spill/disposal data
Spill Control: Shut off all sources of ignition. Wear full protective clothing and self
contained positive pressure breathing apparatus certified by NIOSH. Absorb spilled
chemical in an absorbent recommended for solvent spills of this type and remove
to a safe location for disposal. Comply fully with all federal, state and local
regulatory notification requirements.
Waste Disposal: Burn in a chemical incinerator equipped with an afterburner and
scrubber. Comply fully with all federal, state and local regulations.
Section 8 - Safety measures/equipment
Ventilation: Adequate ventilation is required to protect personnel from exposure to
chemical vapors exceeding PEL and to minimize fire hazards.
Respiratory: Use NIOSH approved respirator equipment.
Eyes: Safety glasses are considered minimum equipment. Chemical safety
goggles or face shield may be necessary depending on quantity of material and
conditions of use. Emergency eye wash fountains should be available in the vicinity
of any possible exposure.
43
Skin: Chemical-resistant protective gloves and clothing are recommended. The
choice of protective gloves or clothing must be based on chemical resistance and
other user requirements. Generally, BUNA-N offers acceptable chemical
resistance. Individuals who are acutely and specifically sensitive to this chemical
may require additional protective clothing.
Storage: Store in a cool dry place. Keep away from heat, sparks and oxidizing
agents. Proper storage must be determined based on other materials stores and
their hazards and potential chemical incompatibility. Store in an acceptable
protected and secure flammable liquid storage cabinet or room.
Section 9 - Special precautions
Unless otherwise noted, the above information pertains only to the solvent and
similar types of components in the sample.
When no toxicity data is provided, it is prudent to handle this chemical as
hazardous. Furthermore, since individual chemical hypersensitivity cannot be
predicted, every chemical should be handled with due respect.
Section 10 – Transport information
By air:
The samples are transported as excepted quantity.
UN code:
UN 3316
Proper shipping name: Chemical kit
Class:
9
Key to abbreviations
ACGIH
CAS
IARC
LEL
NA
ND
NE
NIOSH
NTP
OSHA
PEL
TLV
TWA
UEL
American Conference of Governmental Industrial Hygienists
Chemical Abstract Service
International Agency for Research on cancer
Lower Exposure Limit
Not Available
No Data
Not Established
National Institute for Occupational Safety and Health
National Toxicology Program
Occupational Safety and Health
Permissible Exposure Limit
Threshold Limit Value
Time Weighted Average
Upper Exposure Limit
44
Notes
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
45
Notes
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
46
Notes
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
47
Notes
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
................................................................................................................................
ACG66510.001: 00.01.110
Copyright
This document is property of AC Analytical Controls, Rotterdam, the Netherlands.
No part of this document may be reproduced, stored in a retrieval system and/or
transmitted in any form without prior written permission of the publisher.
48