CHEM%1212K% Final%Exam% Summer%2011% 1.%%At%a%particular%temperature,%Kc%=%2.5%x%1010%for%the%reaction%% 2SO2(g)%+%O2(g)% %%2SO3(g)%% % What%is%Kc%for%the%reaction%SO3(g)% %%SO2(g)%+%½%O2(g)% % % A)%4.0%x%10J11% % B)%1.6%%x%10J21% % C)%6.3%x%10J6% % D%6.3%x%1020%% % E)1.6%x%105% % % 2.%%The%value%of%K%at%308%K%is%6.5x104%for%the%reaction%of%NO(g)%with%chlorine%gas%to% form%NOCl(g).%%If%PNO%=%%0.35%bar%and%PNOCl%%=%0.10%bar%at%equilibrium,%then%what%is%the% equilibrium%partial%pressure%of%the%chlorine%gas?% % % A)%2.3%x%105% % B)%4.3%x%10J6% % C)%1.9%x%103% % D)%5.4%x%10J4% % E)%1.3%x%10J6% % % 3%%Which%statement%is%true?% % % A)%All%reaction%quotients%are%equilibrium%constants.% % B)%If%K%>%Q,%then%the%reaction%must%shift%to%the%reactants%(left)%to%reJattain%% % % %%%%%%equilibrium.% % C)%If%Q%<%K,%then%the%reaction%is%nonspontaneous.% % D)%Not%all%equilibrium%constants%are%reaction%quotients.% % E)%If%Q%>%K,%the%reaction%must%proceed%in%a%direction%to%reduce%the%amount%of%% % % %%%%%%products%present%or%increase%the%amount%of%reactants.% % % 4.%%Which%species%is%least%likely%to%be%completely%deprotonated%in%aqueous%solution?% % % A)%HNO3% % B)%%HF% % C)%HCl% % D)%HBr% % E)%HClO4% % % % % % Form%A% 1% CHEM%1212K% Final%Exam% Summer%2011% 5.%%What%is%the%expression%for%the%reaction%quotient%for%the%reaction:% % %4NO2(g)%+%O2(g)% %2N2O5(s)% % 2 (PN 2 O 5 ) % A)%%% Q = %% (PNO 2 ) 4 (PO 2 ) % (PN 2 O 5 ) % B)% Q = % 4 (P ) (P ) NO O 2 2 € % % C)% Q = (PNO 2 ) 4 (PO 2 ) % %€ 1 % D)% Q = % (PN 2 O 5 ) 2 € % 1 % E)% Q = % (PNO 2 ) 4 (PO 2 ) € % % 6.%%Which%statement%is%true?% %€ % A)%NH3%is%a%BronstedJLowry%base%because%it%is%a%proton%donor.% % B)%The%bromide%ion%is%a%Lewis%base,%but%not%a%BronstedJLowry%base.% % C)%Water%can%be%a%BronstedJLowry%acid%AND%a%Lewis%base,%depending%on% % conditions.% % D)%Metal%cations%tend%to%be%Lewis%acids%due%to%their%ability%to%donate%electron%%% % %%%%%%pairs.% % E)%HSO4J%is%neither%an%acid%nor%a%base%under%any%theory.% % % % 7.%%At%425oC,%K%=%4.18%x%10J9%for%the%reaction%2HBr(g)% %H2(g)%+%Br2(g).%%If%0.20%bar%of% HBr(g),%and%0.010%bar%of%both%H2(g)%and%Br2(g)%are%introduced%into%a%container,%then% which%expression%best%represents%the%equilibrium%pressure%of%HBr?% % % A)%0.20%–%x% % B)%0.20%–%2x% % C)%0.20%+%x% % D)%0.20%+%2x% % E)%0.010%+%x% % % % % Form%A% 2% CHEM%1212K% Final%Exam% Summer%2011% % 8.%%What%is%the%conjugate%base%of%HPO42J%?% % % A)%PO43J% % B)%H3PO4% % C)%H2PO4J% % % D)%HPO4% % E)%H2PO4% % % % 9.%%What%is%the%pH%of%a%0.0147%M%solution%of%KOH%at%room%temperature?% % % A)%1.83% % B)%12.17% % C)%13.98% % D)%12.47% % E)%1.53% % % % 10.%Which%base%is%weakest?. . . A)%BrO4J% % B)%BrO3J% C)%IO4J% D)%BrOJ% E)%IOJ% % % 12.%%Which%statement%regarding%a%solution%of%0.0100%M%NaNO2%is%true?% % % A)%The%pH%of%the%solution%is%acid%because%HNO2%is%a%weak%acid%that%% %% % %%%%%%undergoes%acid%hydrolysis%to%produce%H3O+%in%solution.% % B)%The%pH%of%the%solution%is%neutral%because%it%was%made%from%a%strong%base% % %%%%%and%a%weak%acid.% % C)%The%pH%of%the%solution%is%basic%because%NaOH%is%a%strong%base%that%% %% % %%%%%undergoes%base%hydrolysis%to%produce%OHJ%in%solution.% % D)%The%pH%of%the%solution%is%acidic%because%the%conjugate%acid%of%NaOH%%%% % undergoes%acid%hydrolysis%to%produce%H3O+%in%solution.% % E)%The%pH%of%the%solution%is%basic%because%the%conjugate%base%of%HNO2%% % % %%%%%%undergoes%base%hydrolysis%to%produce%OHJ%in%solution.% % % Form%A% %%% % %% %%%%% % 3% CHEM%1212K% Final%Exam% Summer%2011% 13.% 100%mL%of%each%of%the%following%solutions%is%mixed.%%Which%one%of%the%mixed% solutions%is%a%buffer?%% A)% 1.0%M%CH3NH2(aq)%+%0.6%M%KOH(aq)%% B)% 1.0%M%CH3NH3Cl(aq)%+%1.0%M%KOH(aq)%% C)% 1.0%M%CH3NH2(%(aq)%+%0.8%M%HNO3(aq)%% D)% 1.0%M%NH4Cl(aq)%+%0.8%M%HCl(aq)%% E)% 2.0%M%CH3NH2(%(aq)%+%2.2%M%HNO3aq)%% % % % 14.%%A%100.0%mL%sample%of%0.0200%M%propanoic%acid%(monoprotic,%Ka%=%1.3%x%10J5)%is% titrated%with%0.100%M%NaOH.%%What%is%the%pH%of%the%system%once%1.00%mL%of%NaOH% have%been%added?% % % A)%1.70% % B)%3.61% % C)%7.00% % D)%4.89% % E)%10.7% % % % 15.% Which%statement%regarding%the%reaction%of%HCN%with%NH3%is%true?% % A)%NH3%is%the%proton%donor.% B)%The%N%of%HCN%is%the%electron%pair%donor.% C)%A%coordinate%covalent%bond%is%broken.% D)%A%coordinate%covalent%bond%is%formed.% E)%None%of%these%statements%is%true.% % % % 16.%%What%concentration%of%HNO2%is%required%to%produce%a%solution%whose%pH%is%1.26?%% The%Ka%for%HNO2%is%7.2%x%10J4% % % A)%4.25%M% % B)%9.75%M% % C)%1.16%M% % D)%0.055%M% % E)%3.96%M. % % % % % % Form%A% 4% CHEM%1212K% Final%Exam% Summer%2011% 17.%%Identify%the%most%likely%analyte%and%titrant%(listed%in%that%order)%based%on%the% curve%below.%! % % % % % % % A)%NaOH,%HCl% % % % % % B)%HBr,%LiOH% % % % % %% % C)%H2SO4,%KOH% % D)%Ba(OH)2,%HNO3% % E)%CH3COOH,%NaOH% % % % 18.%%What%is%the%pH%of%a%buffer%composed%of%0.50%M%CH3COOH%and%0.50%M%NaCH3COO% after%0.020%mol%of%HCl%has%been%added%to%1.0%L%of%the%buffer%solution?%%Assume%no% change%in%volume.%%The%Ka%of%CH3COOH%is%1.8%x%10J5%and%the%Kb%of%NaOH%is%108.% % % A)%3.56% % B)%4.71% % C)%4.74% % D)%6.44% % E)%4.78% % ! 19.%%What%is%the%oxidation%state%for%Mn%in%Ca(MnO4)2?% % % A)%+8% % B)%+7% % C)%+6% % D)%+2% % E)%0% % % % Form%A% 5% CHEM%1212K% Final%Exam% Summer%2011% % 20.%%The%molar%solubility%of%PbI2%in%water%at%25oC%is%0.0015.%%What%is%the%Ksp%for%PbI2% at%that%temperature?% % % A)%3.6%x%10J8% % B)%3.4%x%10J9% % C)%6.8%x%10J9% % D)1.4%x%10J8% % E)0.29% % % % 21.%What%effect%(and%why)%does%the%addition%of%Na2CO3%have%on%the%solubility%of% ZnCO3?% % % % A)%The%solubility%increases%due%to%complex%ion%formation.% % B)%The%solubility%decreases%due%to%complex%ion%formation.% % C)%The%solubility%decreases%due%to%the%common%ion%effect.% % D)%The%solubility%increases%due%to%the%common%ion%effect.% % E)%The%solubility%increases%as%a%result%of%both%the%common%ion%effect%and%% % % %%%%%complex%ion%formation.% % % % % Use%the%unbalanced%oxidationJreduction%reaction%to%answer%questions%22J23.% % Cr2O72J(aq)%+%Zn(s)%%%Zn2+(aq)%+%Cr3+(aq)% % 22.%%What%is%the%oxidizing%agent?% % % A)%Zn(s)% % B)%Cr2O72J(aq)% % C)%Zn2+(aq)% % D)%Cr3+(aq)% % E)%There%is%no%reducing%agent.% % % 23.%%What%is%the%sum%of%the%coefficients%when%the%reaction%is%balanced%in%acid?% % % A)%4% % B)%5% % C)%18% % D)%30% % E)%64% % Form%A% 6% CHEM%1212K% Final%Exam% Summer%2011% % 24.%%Which%answer%option%correlates%the%values%of%Gibbs%free%energy,%cell%potential,% and%the%equilibrium%constant%for%a%galvanic%cell?% % % % % % Gibbs!free!energy! ! K! ! Eocell! % A)%%%%% % +% % % >%1%% %%%%%%%%%%%%%%%%J% % B)%% % +% % % <%1% % %%+% % C)%% % J% % % >%1% % %%+% % D)%% % J% J% % % <%1% % %%+% % E)%% % % % >1% % %%J% % % % 25.%%Calculate%the%value%of%the%equilibrium%constant%(T%=%298%K)% % % Pb(s)%+%2Ag+(aq)%%%Pb2+(aq)%+%Ag(s)% Eocell%=%+0.93%V% % % A)%J1.8%x%105% % B)%1.3%x%1031% % C)%7.7%%x%1030% % D)%1.5%x%1031% % E)%2.9%x%1031% % % 26.%%Which%statement%regarding%the%galvanic%cell%represented%by%the%line%notation% below%is%true?% Pt!H2(g)!H+(aq)%|| Cl (aq)!AgCl(s)!Ag(s)% % % A)%Anions%must%flow%into%the%anode%to%maintain%charge%balance.% % B)%Platinum%is%an%inert%electrode%in%both%halfJcells.% % C)%Solid%silver%metal%is%produced%at%the%anode.% % D)%Electrons%flow%from%the%cathode%to%the%anode.% % E)%The%standard%hydrogen%electrode%(SHE)%is%the%cathode% % % 27.%The%rate%constant%for%the%decomposition%of%cyclobutane%(C4H8)%at%1000oC%is%% 87%M01sJ1.%%If%the%initial%concentration%of%cyclobutane%is%2.00%M,%what%percent%of%it% decomposes%in%0.010%seconds?% % % A)%8.0%% % B)%64%% % C)%42%% % D)%36.%% % E)%20.%% − Form%A% 7% CHEM%1212K% Final%Exam% Summer%2011% % % % 28.%%Determine%the%rate%law%from%the%data%given.% Experiment! Initial![NO]! Initial![O2]! Initial!rate!(M/s)! 1% 0.0110% 0.0130% 0.00321% 2% 0.0220% 0.0130% 0.00640% 3% 0.0110% 0.0260% 0.0128% 4% 0.0330% 0.0130% 0.00960% 5% 0.0110% 0.0360% 0.0288% % % A)%rate%=%k[O2][NO]% % B)%rate%=%k[O2]2[NO]% % C)%rate%=%k[O2]% % D)%rate%=%k[O2][NO]2% % E)%rate%=%k[NO]% % % 29.%%%A%galvanic%cell%was%constructed%using%the%Zn2+/Zn%and%H2/H+%(standard% hydrogen%electrode)%halfJcells%under%the%following%conditions.%%What%is%Ecell%%at%% 298%K%?% % % Zn2+(aq)%+%2eJ%%%Zn(s)% % Eo%=%J0.76%V% + J % 2H %+%2e %%%H2% % % Eo%=%0.00%V% % [Zn2+]%=%0.010%M% % [H+]%=%2.5%M% % PH2%=%0.30%atm% % % A)%0.86%V% % B)%0.76%V% % C)%0.53%V% % D)%0.31%V% % E)%1.21% % % 30.%How%many%hours%are%required%to%plate%25.00%g%of%nickel%metal%from%1.00%M% NiSO4(aq),%using%a%current%of%3.00%C/s?% % % A)%7.6%h% % % B)%3.8%h% % C)%8.3%h% % D)%2.6%h% % E)%255%h% % Form%A% 8% CHEM%1212K% Final%Exam% Summer%2011% 31.%%If%the%rate%constant%for%a%given%reaction%is%33%MJ1sJ1%at%298%K%and%45%MJ1sJ1%at%675% K,%then%what%is%the%activation%energy%for%the%reaction?% % % A)%1.4%kJ/mol% % B)%140%kJ/mol% % C)%J1.4%kJ/mol% % D)%3.9%kJ/mol% % E)%There%is%not%enough%information%to%determine%the%activation%energy.% % 32.%%A%main%group%element%should%always%have:% % % % A)%partially%filled%d%orbitals.% % B)%its%last%valence%electron%filling%an%s%or%p%orbital.% % C)%properties%of%a%nonJmetal.% % D)%a%large%ionization%energy.% % E)%a%large%electronegativity.% % 33.%%Which%structure%is%a%feasible%transition%state%for%the%single%step%(elementary)% reaction%O%+%H2O%%%2OH%?% % % A)%% % % % % B)% % % % %%% % % % % % D)% % % % % % C)%% % % E)% % Form%A% 9% CHEM%1212K% Final%Exam% Summer%2011% 34.%%What%characteristic%is%most%influential%in%characterizing%a%hydride%as%saline%or% metallic?% % % A)%electron%affinity% % B)%ionization%energy% % C)%atomic%radius% % D)%electronegativity% % E)%ionic%radius% % % 35.%%Elements%of%which%group%are%likely%to%form%3Jcenter,%2Jelectron%bonds?%% % % % A)%Group%I% % B)%Group%II% % C)%Group%III% % D)%Group%V% % F)%Group%VI% % % Use%the%following%mechanism%to%answer%questions%36%and%37.% % 1)%ClOJ%(aq)%+%H2O(l)% %HClO(aq)%+%OHJ(aq)% % (fast)% % 2)%IJ(aq)%+%HClO(aq)% %HIO(aq)%+%ClJ(aq)% % % (slow)% J J % 3)%OH (aq)%+%HIO(aq)% %H2O(l)%+%IO (aq)% % % (fast)% % 36.%%Identify%the%intermediates.% % % A)%ClOJ,%HIO,%H2O% % B)%HClO,%H2O%,OHJ,%HIO% % C)%ClOJ,%IJ,%IOJ,%ClJ% % D)%IJ,%IOJ% % E)%HClO,%OHJ,%HIO% % % % % % % % % % % % % % % % Form%A% 10% CHEM%1212K% Final%Exam% Summer%2011% 37.%%Which%reaction%progress%diagram%most%accurately%portrays%the%mechanism?% % A)% % % % % % % D)% % B)%%%% %%%%%%%%%%%%%%%%% %%%%%%%%%%%%% C)%%%%%%%%% % % % E)%None%of%these% %%%%%%%%%%%%% % % % % 38.%%How%do%alkali%and%alkaline%earth%metals%(except%Be)%react%in%water?%%Assume%that% each%answer%option%lists%all%products.% % % A)%They%produce%hydrogen%gas%and%hydroxide%ions.% % B)%They%produce%water%and%hydroxide%ions.% % C)%They%produce%protons%and%water.% % D)%They%produce%Lewis%acids%(metal%cations)%hydroxide%ions.% % E)%They%do%not%react%with%water.% % % % % % % % Form%A% 11% CHEM%1212K% Final%Exam% Summer%2011% 39.%%Which%are%logical%products%for%the%reaction%of%4LiH%+%%AlCl3?% % % A)%3LiCl%+%LiAlH4% % B)%LiAlH4%+%LiCl% % C)%3LiClH%+%AlH% D)%LiHCl%+%AlCl3% % % E)%They%do%not%react.% % % 40.%%Which%statement%about%the%coordination%complex%below%is%true.% % % % % % % % % % % A)%The%oxidation%state%for%the%Co%is%0.% B)%The%coordination%number%for%the%complex%is%four.% C)%The%complex%is%chiral.% D)%The%complex%has%a%geometric%isomer.% E)%The%complex%rotates%the%plane%of%polarized%light.% 41.%%Which%statement%regarding%[Fe(OH)6]4J%is%true?% % A)%It%is%diamagnetic.% % B)%Its%electron%configuration%is%t2g6.% % C)%If%the%ligands%were%replaced%with%NH3,%the%configuration%would%be%t2g4eg2.% % D)%Both%B%and%C%are%true.% % E)%It%is%highJspin.% % % 42.%%The%coordination%complexes%below%exhibit%what%type%of%isomerism?% % [CrCl(NH3)5]Br%and%[CrBr(NH3)5]Cl% % % A)%coordination% % B)%linkage% % C)%ionization% % D)%hydration% % E)%geostereoisomerism% Form%A% 12% CHEM%1212K% Final%Exam% Summer%2011% 43.%%What%happens%to%the%5%degenerate%d%orbitals%when%the%nickel(II)%cation%forms% the%complex%[Ni(NH3)6]2+?% % % A)%The%orbitals%spit%so%that%there%are%three%d%orbitals%with%higher%energy%than%%% % %%%%%%the%other%two.% % B)%The%orbitals%split%so%that%there%are%two%%orbitals%with%higher%energy%than%% % % %%%%%%the%other%three.% % C)%The%five%orbitals%remain%degenerate%but%have%a%higher%energy%than%before%% % % %%%%%complex%formation.% % D)%The%five%orbitals%remain%degenerate%but%have%a%lower%energy%than%before%% % % %%%%%%complex%formation.% % E)%None%of%the%above.% % % % 44.%%What%is%the%coordination%number%for%Pd%in%the%complex%[Pd(en)2)]Cl2?% % % %%%%%%%%%%%%%%%% %%%%%%%%%%en% %%%%%%%%%%%%%%%%%%% % %%%%%%%%%%%%%%%%%%%%%%%%%% % % % % % A)%1% % B)%2% % % % C)%4% % D)%6% % E)%8% % 46.%%Which%ion%is%least%likely%to%exist?% % % A)%V3+% % B)%Mn7+% % C)%Co9+% % D)%Cu2+% % E)%Cr6% % 47.%%How%many%unpaired%electrons%would%you%expect%for%the%central%metal%to%have%in% the%complex%[Fe(CN)6]4J%?% % % A)%4% % B)%5% % C)%2% % D)%1% % E)%0% % % Form%A% 13% CHEM%1212K% Final%Exam% Summer%2011% 48.%%Which%oxides%are%(or%can%be)%basic?% % % % % I.%%%Na2O% % % II.%%SO3% % % III.%Al2O3% % % IV.%P2O5% % % A)%I%and%III% % B)%I%only% % C)%II%and%IV% % D)%II%and%III% % E)%II,%III,%and%IV% % % 49.%%Which%statement%is%false?% % % % A)%Co%has%a%greater%atomic%radius%than%Rh.% % B)%Cr6+%has%a%smaller%ionic%radius%than%Cr3+% % C)%Co2+%has%a%smaller%atomic%radius%than%Fe2+.% % D)%Zn%has%a%smaller%atomic%radius%than%Ni.% % E)%Ru%and%Os%have%almost%the%same%atomic%radii.% % % 50.%%Which%statement%regarding%the%noble%gases%is%false?% % % % A)%All%members%of%the%group%have%complete%octets.% % B)%All%members%of%the%group%occur%in%the%atmosphere%are%monatomic%gases.% % C)%Fluorine%is%the%most%electronegative%of%the%noble%gases.% % D)%There%are%no%known%compounds%containing%noble%gases.% % E)%None%of%these%statements%are%false.% % % % Form%A% 14% CHEM%1212K% Final%Exam% Summer%2011% 51.%%Which%of%these%molecules%is%chiral?% % %%%%%%%%%%%%%%I.% % % % % % % % % %%%%%%%%%%%%%%%II.% % % %%%%%%%%III.% % % % % % % % % % % % % % % % % A)%I%only% B)%II%only% C)%III%only% D)%I%and%II% E)%II%and%III% Form%A% 15% CHEM%1212K% Final%Exam% Summer%2011% 52.%%Doping%germanium%with%which%element%results%an%nJtype%semiconductor?% % % A)%arsenic% % B)%gallium% % C)%carbon% % D)%tin% % E)%oxygen% ! 53.%%Which%statement%regarding%molecular%orbital%theory%is%false?% % % A)%Constructive%interference%leads%to%a%bonding%molecular%orbital%that%is% % always%lower%in%energy%than%the%constituent%atomic%orbitals.% % B)%Destructive%interference%leads%to%an%antibonding%molecular%orbital%that%is% % always%higher%in%energy%than%the%constituent%atomic%orbitals.% % C)%A%linear%combination%of%N%atomic%orbitals%results%in%N%molecular%orbitals.% % D)%Degenerate%molecular%orbitals%have%different%energies.% % E)%Molecular%orbitals%are%filled%according%to%the%Aufbau%principle%to%give%the% % molecular%electronic%configuration.% % % 54.%%For%molecular%orbital%theory%regarding%bulk%solids,%which%of%the%following% statements%is%true?% % % A)%The%molecular%orbitals%are%close%enough%in%energy%that%a%band%forms% % rather%than%discrete%orbitals.% % B)%The%distance%between%the%bands%is%called%the%energy%gap.% % C)%The%lower%energy%band%is%called%the%conduction%band.%% % D)%A%small%band%gap%results%in%a%material%being%an%insulator.% % E)%Conductors%do%not%have%a%valence%band.% ! 55.%%Which%of%the%following%theories%of%bonding%best%explains%conductivity%in%metals?% % A) Molecular%orbital%theory% B) Valence%bond%theory% C) VSEPR% D) Electronegativity% E) Band%gap%theory% % Form%A% 16%
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