Name:_______________________________ Date:_________________ Hr:____ AP CHEMISTRY Ch 9 (Sect 1 & 5) – Covalent Bonding: Orbitals QUIZ COVALENT BONDING: ORBITALS TOTAL: /20 You may use your chemistry textbook, class notes, handouts, labs, or any other notes you make. You may only collaborate with students currently enrolled in AP Chemistry at GHS. You may not use any adults, the internet, or other electronic resources for this quiz. You may choose not to collaborate with another student (please respect the decision of those who choose to work on their own). Show all work with appropriate significant figures for full credit. Free Response (20 points) Your responses to these questions will be scored on the basis of the accuracy and relevance of the information cited. Explanations should be clear and well organized. Specific answers are preferable to broad, diffuse responses. 1. (3 points) Label each of the following as being paramagnetic or diamagnetic. Justify your responses. (a) Barium (b) Mercury (c) Mercury(II) ion 2. (2 points) How many of the atoms in a molecule of nitric acid must occur in the same plane? Justify your response. (a structural formula is shown below, but lone pairs are not) Page 1 of 2 2013 Name:_______________________________ Date:_________________ Hr:____ AP CHEMISTRY Ch 9 (Sect 1 & 5) – Covalent Bonding: Orbitals QUIZ 3. (6 points) Using the data supplied, estimate the lattice energy for magnesium chloride. Be thorough and clear in showing all of your work. Report your answer to the appropriate number of significant figures. Reaction or Process kJ/molrxn Enthalpy of formation of MgCl2 –641.3 First ionization energy of Mg 735 Second ionization energy of Mg 1445 Electron affinity of Cl –349 Bond dissociation energy of Cl2 239 Enthalpy of sublimation of Mg 150. 4. (9 points) For each of the following species, draw valid octet satisfying Lewis structures (with equivalent resonance structures where appropriate). Assign formal charges to each atom in each structure. Predict the hybridization of each atom in each structure. Be sure to be neat and organized as your present your information. (i) CO32- (ii) CO2 (iii) CO I affirm that the work shown on this quiz is entirely my own effort and that no resources other than those specified were used. ____________________________________ Student Signature Page 2 of 2 2013
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