JEE MAIN 2015 ONLINE EXAMINATION DATE : 10-04-2015 TEST PAPER WITH SOLUTIONS & ASNWER KEY JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 PHYSICS PART - A : PHYSICS 1. Shown in the figure are two point charges +Q and – Q inside the cavity of a spherical shell. The charges are kept near the surface of the cavity on opposite sides of the centre of the shell. If 1 is the surface charge on the inner surface and Q1 net charge on it and 2 the surface charge on the outer surface and Q2 net charge on it then (1) 1 0, Q1 0 2 0, Q 2 0 (2) 1 0, Q1 0 2 0, Q 2 0 (3) 1 0, Q1 0 2 0, Q 2 0 (4) 1 0, Q1 0 2 0, Q 2 0 Ans. Sol. (2) Net charge inside cavity is zero Q1 = 0 and 1 = 0 There is no effect of +Q, –Q and induced charge on inner surface on the outer surface hence Q2 = 0, 2 = 0 2. A 10V battery with internal resistance 1 and a 15V battery with internal resistance 0.6 are connected in parallel to a voltmeter (see figure). The reading in the voltmeter will be close to Ans. Sol. (1) 11.9 V (2) (2) 13.1 V (3) 12.5 V (4) 24.5 V 10 15 1 0.6 10 25 13.1V E= 1 1 = 2.67 1 0 .6 Page || 1 PHYSICS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 3. Consider a thin uniform square sheet made of a right material . If its side is ‘a’, mass m and moment of inertia about one of its diagonals, then : (1) > Ans. Sol. ma2 12 (2) = ma2 12 (3) ma2 ma2 << 24 12 (4) = ma2 24 (2) For uniform thin square sheet 1 = 2 = 3 = ma2 12 2 4. If it takes 5 minutes to fill a 15 litre bucket from a water tap of diameter Ans. the flow is (density of water = 103 kg/m3 and viscosity of water = 10–3Pa.s) close to (1) 11,000 (2) 550 (3) 1100 (4) 5500 (4) Sol. cm then the Reynolds number for dm SAV dt 2 15 1 103 10 –4 V 5 60 V = 0.05 m/s Re = SVD 10 3 0.5 = 2 10 – 2 10 – 3 5500 Ans. Page || 2 PHYSICS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 5. A parallel beam of electrons travelling in x-direction falls on a slit of width d (see figure). If after passing the slit, an electron acquires momentum py in the y-direction then for a majority of electrons passing through the slit (h is Planck's constant) : (1) |py| d > h Ans. Sol. (2) |py| d >> h (3) |py| d < h (4) |py| d ~ h (1) d sin = . sin = 1 d <d h | py | h d | py | h < |py| d Option (1) 6. A simple harmonic oscillator of angular frequency 2 rad s–1 is acted upon by an external force F = sin t N. If the oscillator is at rest in its equilibrium position at t = 0, its position at later times is proportional to : (1) cos t – Ans. Sol. 1 sin 2t 2 (2) sin t + 1 cot 2t 2 (3) sin t + 1 sin 2t 2 (4) sin t – 1 sin 2t 2 (4) F = ma a sin t dv sin t dt 0 t dV sin t dt 0 0 V – cos t + 1 x 0 t dx ( cos t 1)dt 0 Page || 3 PHYSICS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 x = – sin t + t 7. A proton (mass m) accelerated by a potential difference V files through a uniform transverses magnetic field B. The field occupies a region of space by width ‘d’. If ‘’ be the angle of deviation of proton from initial direction of motion (see figure,) the value of sin will be (1) B d q 2mV Ans. (2) Sol. sin = d R sin = dqB mu sin = Bd (2) Bd q 2mV (3) B qd 2 mV (4) qV Bd 2m q 2mV 1 2 qV mu 2 8. Ans. A bat moving at 10ms–1 towards a wall sends a sound signal of 8000 Hz towards it. On reflection it hears a sound of frequency f. The value of f in Hz is close to (speed of sound = 320 ms–1) (1) 8000 (2) 8424 (3) 8258 (4) 8516 (4) Page || 4 PHYSICS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 Sol. Frequency incident on wall = V f V 10 Reflected frequency reaching bat = 9. If the capacitance of a nanocapacitor is measured in terms of a unit ‘u’ made by combining the electronic charge ‘e’, Bohr radius ‘a0’, Planck's constant ‘h’ and speed of light ‘c’ then. e 2h (1) u = ea 0 Ans. Sol. Ans. (2) u e 2c ha 0 hc (3) u = 2 e a0 (4) u = e 2a 0 hc (4) [u] = [e]a[a0]b[h]c[c]d [M–1L–2T+4A+2] = [A1T1]a [L]b[ML2T–1]c[LT–1]d [M–1L–2T+4A+2] = [MCLb+2c+d Ta–c–dAa] a = 2, b = 1, c = – 1, d = – 1 u= 10. V 10 f = 8516 Hz V 10 e 2a 0 hc x and y displacements of a particle are given as x(t) = a sin t and y(t) = a sin 2t. Its trajectory will look like. (1) (2) (3) (4) (1) Page || 5 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 Sol. PHYSICS At t = 0, x(t) = 0 ; y(t) = 0 x(t) is a sinusoidal function hence option(1) At t = 2 x (t) = a y (t) = 0 11. Diameter of a steel ball is measured using a vernier callipers which has divisions of 0.1 cm on its main scale (MS) and 10 divisions of its vernier scale (VS) match 9 divisions on the main scale. Three such measurements for a ball are given as : S.No. MS (cm) VS divisions 1 0.5 8 2 0.5 4 3 0.5 6 Ans. Sol. If the zero error is – 0.03 cm, then mean corrected diameter is : (1) 0.53 cm (2) 0.56 cm (3) 0.59 cm (3) Least count = 0.01 cm d1 = 0.5 + 8 × 0.01 + 0.03 = 0.61 cm d2 = 0.5 + 4 × 0.01 + 0.03 = 0.57 cm d3 = 0.5 + 6 × 0.01 + 0.03 = 0.59 cm Mean diameter = 12. (4) 0.52 cm 0.61 0.57 0.59 = 0.59 cm 2 Ans. Sol. In an unbiased n-p junction electrons diffuse from n-regionto p-region because : (1) electrons travel across the junction due to potential difference (2) electron concentration in n-region is more as compared to that in p-region (3) only electrons move from n to p region and not the vice-versa (4) holes in p-region attract them (2) T 13. A block of mass m = 0.1 kg is connected to a spring of unknown spring constant k. It is compressed to a x distance x from rest. After approaching half the distance from equilibrium position, it hits another block 2 and comes to rest momentarily, while the other block moves with a velocity 3ms–1. the total initial energy of the spring is (1) 0.3 J (2) 0.6 J (3) 1.5 J (4) 0.8 J Page || 6 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 Ans. Sol. PHYSICS (2) Apply momentum conservation 0.1u + m(0) = 0.1(0) + m(3) 1 1 0.1u 2 m(3)2 2 2 Solving u = 3 2 1 2 1 x 1 kx K (0.1)3 2 2 2 2 2 3 2 Kx 0.9 4 1 2 Kx 0.6J 2 14. In an ideal gas at temperature t, the average force that a molecule applies on the walls of a closed container depends on T as Tq. A good estimate for q is (1) 1 4 (2) 2 (3) 1 2 (4) 1 Ans. Sol. (4) Pressure V2rms Force V2rms T 15. A very long (length L) cylindrical galaxy is made of uniformly distributed mass and has radius R (R << L). A star outside the galaxy is orbiting the galaxy in a plane perpendicular to the galaxy and passing through its centre. If the time period of star is T and its distance from the galaxy's axis is r, then : (1) T r Ans. (1) Sol. F= (2) T r (3) T r2 (4) T2 r3 2GM m Lr 2 2GMm 2 mr T Lr Tr 16. Ans. de-Broglie wavelength of an electron accelerated by a voltage of 50 V is close to (|e| = 1.6 × 10–19 C, me = 9.1 × 10–31 kg, h = 6.6 × 10–34 Js) : (1) 1.2 Å (2) 2.4 Å (3) 0.5 Å (4) 1.7 Å (4) Page || 7 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 Sol. = h = mv PHYSICS h 2mqV = 1.7Å 17. Suppose the drift velocity d in a material varied with the applied electric field E as d E . Then V – graph for a wire made of such a material is best given by : Ans. Sol. (1) (2) (3) (4) (2) i = neAVd i E i2 E i2 V 18. Ans. When current in a coil changes from 5 A to 2 A in 0.1 s, average voltage of 50V is produced. The self inductance of the coil is : (1) 1.67 H (2) 6H (3) 3 H (4) 0.67 H (1) Sol. EMF = Ldi dt 52 50 = L 0.1sec L= 50 0.1 5 1.67H 3 3 Page || 8 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 19. PHYSICS If one were to apply Bohr model to a particle of mass 'm' and charge 'q' moving in a plane under the influence of a magnetic field 'B', the energy of the charged particle in the nth level will be : hqB (1) n 4m Ans. (1) Sol. qVB = hqB (2) n m mv 2 r n hqB (4) n 8m ....(i) nh = mvr 2 multiply both hqB (3) n 2m ....(ii) qBnh m2 v 2 2 qBh 1 2 = mv 4m 2 qBh KE = n 4m 20. Ans. Sol. A 25 cm long solenoid has radius 2 cm and 500 total number of turns. It carries a current of 15 A. If it is equivalent to a magnet of the same size and magnetization M (magnetic moment/volume), then M is : (1) 3 Am–1 (4) (2) 30000 Am–1 (3) 300 Am–1 (4) 30000 Am–1 NiA M (mag. moment / volume) = A = = Ni 500 15 25 10 – 2 = 30000 Am–1 21. Ans. You are asked to design a shaving mirror assuming that a person keeps it 10 cm from his face and views the magnified image of the face at the closest comfortable distance of 25 cm. The radius of curvature of the mirror would then be : (1) 60 cm (2) 24 cm (3) 30 cm (4) – 24 cm (1) Page || 9 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 /////////////// ///// //// / / / // O 10 cm Sol. PHYSICS 15 cm 1 1 1 + = ( 10 ) 15 f f = –30 cm R = – 60 cm 22. Ans. Sol. If a body moving in a circular path maintains constant speed of 10 ms–1, then which of the following correctly describes relation between acceleration and radius ? (1) (2) (3) (4) (1) V = constant a= V2 r ra = constant 23. A block of mass m = 10 kg rests on a horizontal table. The coefficient of friction between the block and the table is 0.05. When hit by a bullet of mass 50 g moving with speed , that gets embedded in it, the block moves and come to stop after moving a distance of 2m on the table. If a freely falling object were to acquire speed Ans. after being dropped from height H, then neglecting energy losses and taking g = 10 ms–2, the value 10 of H is close to : (1) 0.2 km (Bonus) (2) 0.3 km (3) 0.5 km (4) 0.4 km Page || 10 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 Sol. PHYSICS Momentum conservation 0.05V = 10V0 V0 0 – V02 = 2(–g)2 V0 = 2 object falling from height H. 24. V = 2gH 10 H = 40 m = 0.04 km No option match (Bonus) In the circuits (a) and (b) switches S1 and S2 are closed at t = 0 and are kept closed for a long time. The variation of currents in the two circuits for t 0 are roughly shown by (figures are schematic and not drawn to scale : E ___ R (b) (a) i (1) (2) t E ___ R (a) (b) i (3) (4) t Ans. Sol. (4) For capacitor circuit i = i0e–t/RC Rt 1 e L For inductor circuit i = i0 Page || 11 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 25. If two glass plates have water between them and are separated by very small distance (see figure), it is very difficult to pull them apart. It is because the water in between forms cylindrical surface on the side that gives rise to lower pressure in the water in comparison to atmosphere. If the radius of the cylindrical surface is R and surface tension of water is T then the pressure in water between the plates is lower by : (1) 2T R (2) 4T R Ans. () Sol. 1 1 Excess pressure = T r r 1 2 = 26. Ans. Sol. PHYSICS T R (3) T 4R (4) T 2R r1 R r2 0 A uniform solid cylindrical roller of mass 'm' is being pulled on a horizontal surface with force F parallel to the surface and applied at its centre. If the acceleration of the cylinder is 'a' and it is rolling without slipping then the value of 'F' is : (1) ma (2) 2 ma (4) ma = F – f ............(i) (3) 5 ma 3 (4) 3 ma 2 a F f 2 mR fR 2 mR 2 a fR 2 R ma f 2 Put in equation (i) ma = F – ......(ii) ma 2 Page || 12 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 3ma 2 F= 27. An electromagnetic wave travelling in the x-direction has frequency of 2 × 1014 Hz and electric field amplitude of 27 Vm–1. From the options given below, which one describes the magnetic field for this wave ? (1) B(x, t) (9 10 –8 T)jˆ –8 (2) B(x, t) (9 10 T)iˆ sin 2(1.5 10 –8 x 2 1014 t) sin 1.5 10 –6 x 2 1014 t –8 (3) B(x, t) (9 10 T)kˆ sin 2(1.5 10 –6 x 2 1014 t) Ans. Sol. PHYSICS (4) B(x, t) (3 10 –8 T)jˆ sin 2(1.5 10 –8 x 2 1014 t) (3) = 2 × 2 × 1014 Hz B0 = 27 E0 = = 9 × 10–8 Tesla C 3 10 8 Oscillation of B can be only along ĵ or k̂ direction. Option (3) 28. Ans. Sol. A telescope has an objective lens of focal length 150 cm and an eyepiece of focal length 5 cm. If a 50 m tall tower at a distance of 1 km is observed through this telescope in normal setting, the angle formed by the image of the tower is , then is close to : (1) 15° (2) 60° (3) 30° (4) 1° (2) f0 150 MP = f 5 = 30 e 0 = 50 1 = rad 1000 20 = MP × 0 = 30 = 1 20 3 = 1.5 rad 2 = 1.5 × 180 = 86º Page || 13 PHYSICS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 29. An ideal gas goes through a reversible cycle a b c d has the V - T diagram shown below. Process d a and b c are adiabatic. The corresponding P - V diagram for the process is (all figures are schematic and not drawn to scale) : (1) (2) P (3) P a b d c (4) d c a b V Ans. Sol. V (3) In VT graph ab-process : Isobaric line passes through origin, temperature increases. bc process : Adiabatic, pressure decreases. cd process : isobaric, volume decreases. da process : Adiabatic, pressure increase. Page || 14 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 30. (1) Ans. Sol. PHYSICS A thin disc of radius b = 2a has concentric hole of radius 'a' in it (see figure). It carries uniform surface charge '' on it. If the electric field on its axis at height 'h' (h << a) from its centre is given as 'Ch' then value of 'C' is : (2) 4a 2a 0 (3) 8a 0 (4) a 0 (2) Electric field due to complete disc (R = 2a) x 1 2 R x2 E1 = 2 0 h h 1 1 2a 2 2 2 0 4a h Electric field due to disc (R = a) E1 = 2 0 h 1 2 0 a Electric field due to given disc. E = E 1 – E2 E2 = h = 4 a 0 option (2) Page || 15 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 CHEMISTRY PART - B : CHEMISTRY 1. Ans. Sol. 2. Photochemical smog consists of excessive amount of X, in addition to aldehydes, ketones, peroxy acetyl nitrile (PAN), and so forth. X is : (1) CH4 (2) O3 (3*) CO2 (4) CO (3) The reaction 2N2O5(g) 4NO2(g) + O2(g) follows first order kinetics. The pressure of a vessel containing only N2O5 was found to increase from 50 mm Hg to 87.5 mm Hg in 30 min. The pressure exerted by the gases after 60 min. will be (Assume temperature remains constant) : (1) 125 mm Hg (2*) 106.25 mm Hg (3) 116.25 mm Hg (4) 150 mm Hg (2) 2N2O5(g) 4NO2(g) + O2(g) t=0 50 0 0 t = 30 50 – 2x 4x x 87.5 = 50 + 3x 3x = 37.5 x = 12.5 PN2O5 after 30 min = 50 – 25 = 25 t1 / 2 = 30 min. Ans. Sol. Hence after 60 min, (two half lives), PN2O5 remaining = Hence decrease in PN2O5 = 50 – 12.5 = 37.5 torr.. PNO 2 = 2 37.5 = 75 torr 50 = 12.5 torr.. 4 37.5 = 18.75 torr 2 Ptotal = 12.5 + 75 + 18.75 = 106.25 torr. PO2 = COOK Electrolysis 3. A COOK A is : (1) (2*) (3) (4) n Ans. Sol. (2) Page || 16 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 4. Ans. Sol. 5. Ans. Sol. 6. Ans. Sol. 7. Ans. CHEMISTRY The correct statement on the isomerism associated with the following complex ions, (a) [Ni(H2O)5NH3]2+, (b) [Ni(H2O)4(NH3)2]2+ and (c) [Ni(H2O)3(NH3)3]2+ is : (1) (a) and (b) show geometrical and optical isomerism (2) (b) and (c) show only geometrical isomerism (3*) (b) and (c) show only geometrical isomerism (4) (a) and (b) show geometrical and optical isomerism (3) (a) does not show G.I.(b) and (c) show G.I.but all isomers are optically inactive. If the principal quantum number n = 6, the correct sequence of filling of electrons will be : (1) nsnp(n – 1)d(n – 2)f (2) ns(n – 1)d(n – 2)fnp (3) ns(n – 2)fnp(n – 1)d (4*) ns(n – 2)f(n – 1)dnp (4) Following Aufbau principle for filling electrons. After understanding the assertion and reason, choose the correct option. Assertion : In the bonding molecular orbital (MO) of H2, electron density is increased between the nuclei. Reason : The bonding MO is A + B, which shows destructive interference of the combining electron waves. (1*) Assertion is correct, reason is incorrect. (2) Assertion is incorrect, reason is correct. (3) Assertion and reason are correct, but reason is not the correct explanation for the assertion. (4) Assertion and reason are correct and reason is the correct and reason is the correct explanation for the assertion. (1) Bonding molecular orbital results in increased electron density between nuclei due to constructive interference of combining electron waves. The geometry of XeOF4 by by VSEPR theory is : (1) pentagonal planar (2) octahedral (3*) square pyramidal (4) trigonal bipyramidal (3) O Sol. F F 8. A compound A with molecular formula C10H13Cl give a white precipitate on adding silver nitrate solution. A on reacting with alcoholic KOH gives compound B as the main product. B on ozonolysis gives C and D. C gives Cannizaro reaction but not aldol condensation. D gives aldol condensation but not Cannizaro reaction. A is : Xe F sp3d2 hybridized with one position occupied by lone pair.. F (1) C6H5–CH2–CH2–CH2–CH2–Cl (3) CH2–CH2–CH3 CH2–Cl (2) C 6H5 – CH2 – CH2 – CH – CH3 | Cl (4*) C6H5–CH2–C Cl Ans. Sol. CH3 CH3 (4) Page || 17 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 9. Ans. Sol. 10. Ans. Sol. 11. Ans. Sol. 12. Ans. Sol. 13. Ans. Sol. 14. Ans. CHEMISTRY The correct order of thermal stability of hydroxides is : (1) Ba(OH)2 < Ca(OH)2 < Sr(OH)2 < Mg(OH)2 (2) Ba(OH)2 < Sr(OH)2 < Ca(OH)2 < Mg(OH)2 (3) Mg(OH)2 < Ca(OH)2 < Sr(OH)2 < Ba(OH)2 (4*) Mg(OH)2 < Sr(OH)2 < Ca(OH)2 < Ba(OH)2 (4) Larger cation is able to stabilize polyatomic anion more than smaller cation. Which of the following is not an assumption of the kinetic theory of gases ? (1) Gas particles have negligible volume (2) A gas consists of many identical particels which are in continual motion (3*) At high pressure, gas particles are difficult to compress (4) Collisions of gas particles are perfectly elastic (3) No such assumption is made by KTG. In the presence of small amount of phosphorous, aliphatic carboxylic acids react with chlorine or bromine to yield a compound in which -hydrogen has been replaced by halogen. This reaction is known as : (1) Wolff-Kischner reaction (2) Etard reaction (3) Rosenmund reaction (4*) Hell-Volhard-Zelinsky reaction (4) In the isolation of metals, reaction process usually results in : (1) Metal sulphide (2) metal carbonate (3) metal hydroxide (4*) metal oxide (4) Usually calcination results in metal oxides as metal carbonates, hydroxides, all decompose to oxides. In the long form of the periodic table, the valence shell electronic configuration of 5s25p4 corresponds to the element present in : (1) Group 17 and period 6 (2) Group 17 and period 5 (3) Group 16 and period 6 (4*) Group 16 and period 5 (4) Valence shell number indicates period number. ns2np4 correspond to group 16. Gaseous N2O4 dissociates into gaseous NO2 according to the reaction N2O4(g) 2NO2(g) At 300 K and 1 atm pressure, the degree of dissociation of N2O4 is 0.2. If one mole of N2O4 gas is contained in a vessel, then the density of the equilibrium mixture is : (1*) 3.11 g/L (2) 4.56 g/L (3) 1.56 g/L (4) 6.22 g/L (1) Sol. M Th MOb = 1 + (2 – 1) = 1.2. MOb = and d= 92 1.2 PM 1 92 = = 3.116 g/L RT 1.2 0.082 300 Page || 18 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 15. Ans. Sol. 16. Ans. Sol. CHEMISTRY Match the polymers in column-A with their main used in column-B and choose the correct answer : Column-A Column-B (A) Polystyrene (i) Paints and lacquers (B) Glyptal (ii) Rain coats (C) Polyvinyl chloride (iii) Manufacture of toys (D) Bakelite (iv) Computer discs (1) (A) - (ii), (B) - (i), (C) - (iii), (D)- (iv) (2*) (A) - (iii), (B) - (i), (C) - (ii), (D)- (iv) (3) (A) - (ii), (B) - (iv), (C) - (iii), (D)- (i) (4) (A) - (iii), (B) - (iv), (C) - (ii), (D)- (i) (2) (A) - Manufacture of toys (iii) (B) - Points & lacquers (i) (C) - Rain coats (ii) (D) - Complete discs. (iv) The optically inactive compound from the following is : (1) 2-chloropentane (2) 2-chloropropanal (3*) 2-chloro-2-methylbutane (4) 2-chlorobutane (3) CH3 – CH2 – CH2 – CH – CH3 | Cl CH3 – CH – CHO | Cl CH3 | CH3 – CH2 – C – CH3 | Cl CH3 – CH2 – CH – CH3 | Cl 17. Ans. Sol. Complex hydrolysis of starch gives : (1*) glucose only (3) galactose and fructose in equimolar amounts (1) Starch is a polymer of glucose. (2) glucose and fructose in equimolar (4) glucose and galactose in equimolar amounts Page || 19 CHEMISTRY JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 18. Ans. The heat of atomixation of methane and ethane are 360 kJ/mol and 620 kJ/mol, respectively. The longest wavelength of light capable of breaking the C-C bond is (A vogadro number = 6.02 × 1023, h = 6.62 × 10–34 J s): (1) 2.48 × 103 nm (2*) 1.49 × 103 nm (3) 2.49 × 104 nm (4) 2.48 × 104 nm (2) Sol. CH4(g) C(g) + 4H(g) 4 EC–H = 360 KJ/Mol. EC–H = 90 KJ/Mol. and C2H6(g) 2C(g) + 6H(g) EC–C + 6 90 = 620 EC–C = 80 kJ/mol NA hc = 80 1000 J 6.02 10 23 6.62 10 –34 3 10 8 80000 –7 = 14.9 10 m = 1.49 10–6 m = 1.49 103 nm. = 19. Ans. Sol. 20. The following statements relate to the adsorption of gases on a solid surface. Identify the incorrect statement among them : (1) On adsorption decrease in surface energy appears as heat (2) Enthalpy of adsorption is negative (3*) On adsorption, the residual forces on the surface are increased (4) Entropy of adsorption is negative (3) Adsorption takes place due to the presence of residual forces on the surface. After adsorption, these are decreased. Arrange the following amines in the order of increasing basicity : NH2 (1) CH3NH2 < NH2 < < OCH3 NH2 < (3) OCH3 Ans. Sol. NH2 H 3CO < < CH3NH2 OCH3 NO2 NH2 NH2 < < CH3NH2 OCH3 pKa = 10.64 NH2 O2N NH2 < CH3NH2 (4*) NH2 < NO2 NO2 NO2 NH2 < (2) NH2 < (4) CH3–NH2 NH2 NH2 pKa = 4.62 NH2 NH2 pKa = 0.98 pKa = 5.29 Page || 20 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 21. Ans. Sol. 22. CHEMISTRY Permanent hardness in water cannot be cured by : (1) Treatment with washing soda (2*) Boiling (3) Ion exchange method (4) Calgon's method (2) Boiling can remove only temporary hardness caused by bicarbonates of Ca2+, Mg2+. Ans. A solution at 20ºC is composed of 1.5 mol of benzene and 3.5 mol of toluene. If the vapour pressure of pure benzene and pure toluene at this temperature are 74.7 torr and 22.3 torr, respectively, then the total vapour pressure of the solution and the benzene mole fraction in equilibrium with it will be, respectively : (1) 35.0 torr and 0.480 (2) 30.5 torr and 0.389 (3*) 38.0 torr and 0.589 (4) 35.8 torr and 0.280 (3) Sol. xBenzene = 1.5 = 0.3, xtoluene = 0.7 5 PT = 74.7 0.3 + 0.7 22.3 = 22.41 + 15.61 = 38.02 torr and ybenzene = 22.41 = 0.589 38.02 OCOCH3 COOH 23. Ans. Sol. 24. Ans. Sol. 25. Ans. Sol. 26. Ans. Sol. is used as : (1) Antihistamine (2) Antacid (4) Aspirin is non-narcotic analgesic. (3) Insecticide (4*) Analgesic The cation that will not be precipitated by H2S in the presence of dil HCl is: (1) Pb2+ (2) As3+ (3*) Co2+ (4) Cu2+ (3) Co2+ is precipitated when we have sufficient S2– concentration. The least number of oxyacids are formed by: (1) Nitrogen (2*) Fluorine (3) Chlorine (2) Fluorine only forms HOF as it cannot show multiple oxidation states. (4) Sulphur Which molecule/ion among the following cannot act as a ligand in complex compounds? (1*) CH4 (2) CN– (3) Br– (4) CO (1) CH4 does not have lone pair. Page || 21 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 27. CHEMISTRY Ans. A sample of a hydrate of barium chloride weighing 61 g was heated until all the water of hydration is removed. The dried sample weighed 52g. The formula of the hydrated salt is: (atomic mass, Ba = 137 amu, Cl = 35.5 amu) (1) BaCl2 + H2O (2) BaCl2 + 4H2O (3) BaCl2 + 3H2O (4*) BaCl2 + 2H2O (4) Sol. BaCl2.xH2O BaCl2 + xH2O. mH2O = 61 – 52 = 9g nH2O = 9 1 = 18 2 mBaCl2 = 52 28. Ans. Sol. 29. Ans. Sol. nBaCl2 = 52 1 1 1 = simplest formula = : =1 :2 208 4 4 2 BaCl2.2H2O A variable, opposite external potential (Eext) is applied to the cell Zn|Zn2+ (1 M) || Cu2+ (1M) | Cu, of potential 1.1 V. When Eext < 1.1 V and Eext > 1.1 V respectively electrons flow from : (1) Cathode to anode in both cases (2) cathode to anode and anode to cathode (3) anode to cathode and cathode to anode (4*) anode to cathode in both cases (4) Electrons flow from anode to cathode always. 1.4 g of an organic compound was digested according to Kjeldahl's method and the ammonia evolved was absorbed in 60 mL of M/10 H2SO4 solution. The excess sulphuric acid required 20 mL of M/10 NaOH solution for neutralization. The percentage of nitrogen in the compound is : (1) 24 (2) 5 (3*) 10 (4) 3 (3) Organic compound NH3 (1.4g) 2NH3 + H2SO4 (NH4)2SO4 H2SO4 + 2NaOH Na2SO4 + 2H2O nNH3 + 20 nNH3 = 1 1 1 1 = 60 2 10 1000 10 1000 12 2 10 – = 1000 1000 100 nN = nNH3 = 0.01 30. Ans. Sol. mN = 0.01 14 = 0.14 g % of N = 0.14 100 = 10%. 1.4 An aqueous solution of a salt X turns blood red on treatment with SCN– and blue on treatment with K4[Fe(CN)6]. X also gives a positive chromyl chloride test. The salt X is : (1) CuCl2 (2) Cu(NO3)2 (3*) FeCl3 (4) Fe(NO3)3 (3) FeCl3 gives chromyl chloride test, Fe 3 SCN – blood red color.. and Fe3 K 4 [Fe(CN)6 ] Fe 4 [Fe(CN)6 ]3 (blue) Page || 22 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 PART - C : MATHEMATICS 1. Ans. The number of ways of selecting 15 teams from 15 men and 15 women, such that each team consists of a man and a woman, is : (1) 1880 (2) 1120 (3) 1240 (4) 1960 (3) Sol. 15 16 31 = 1240 6 2. The area (in square units) of the region bounded by the curves y + 2x2 = 0 and y + 3x2 = 1, is equal to : 1 3 (1) (2) Ans. (4) Sol. y 2x 2 0 are parabola and y 3x 2 1 3 4 (3) 3 5 (4*) 4 3 point of intersection of these two curves are (1, – 2) & (–1, –2) 1 2 2 Area bounded by these two curves = 2 {(1 – 3 x ) – (–2x )} dx 0 1 2 = 2 (1 – x ) dx 0 x3 =2 x– 3 1 0 2 = 2 – 0 3 = 4 3 Page || 23 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 3. Ans. In a certain town, 25% of the families own a phone and 15% own a car; 65% families own neither a phone nor a car and 2,000 families own both a car and a phone. Consider the following three statements : (a) 5% families own both a car and a phone (b) 35% families own either a car or a phone (c) 40,000 families live in the town Then, (1) Only (b) and (c) are correct (2) Only (a) and (c) are correct (3*) All (a), (b) and (c) are correct (4) Only (a) and (b) are correct (3) Sol. 65 + 25 – x + x + 15 – x = 100 105 – x = 100 x=5 5 40000 = 2000 100 family live in the town. and 4. If y(x) is the solution of the differential equation (x + 2) Ans. equal to : (1) 2 (2) Sol. (x + 2) y= (2*) 0 dy = (x + 2)2 – 13 dx dy = x2 + 4x – 9, x – 2 and y(0) = 0, then y(– 4) is dx (3) –1 (4) 1 dy 13 = (x + 2) – dx x2 x2 + 2x – 13 n(x + 2) + C at x = 0, y = 0 c = 13 n2 2 x2 + 2x – 13 n|x + 2| + 13 n2 2 Now y(–4) = 8 – 8 – 13n|–4 + 2| + 13n2 = 0 y= 2 5. x lim e – cos x is equal to : x0 sin 2 x (1) 2 Ans. (2) 3 (3) 5 4 (4*) 3 2 (4) x 4 x6 x2 x 4 1 x 2 ...... – 1 – ........ 2! 3! 2! 4! Sol. lim x0 = x3 x5 x – ...... 3! 5! 2 3 2 Page || 24 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 6. Ans. Sol. If Roll's theorem holds for the function f(x) = 2x3 + bx2 + cx, x [–1, 1], at the point x = (1) 1 (2) 2 (3) f(1) = f(–1) 2+b+c=–2+b–cc=–2 f'(x) = 6x2 + 2bx + c (3*) –1 1 , then 2b + c equals : 2 (4) –3 2 1 1 = 6 + 2b + c 2 2 3 1 +b=c=0b= 2 2 Now 2b + c = 1 – 2 = – 1 = 7. Ans. Sol. If the tangent to the conic, y – 6 = x2 at (2, 10) touches the circle, x2 + y2 + 8x – 2y = k (for some fixed k) at a point (, ); then (, ) is : 7 6 6 10 4 1 , , , (1) – (2) – (3) – 17 17 17 17 17 17 (4) y' = 2x at (2, 10), y' = 4 tangent y – 10 = 4(x – 2) y = 4x + 2 4x – y + 2 = 0 Pass (, ) 4 - + 2 = 0 = 4 + 2 ........ (1) and 2x + 2y y ' + 8 - 2 y ' = 0 y' = 2x 8 2 8 4 2 2y 2 2 from 1 & 2 we get = 8. ........ (2) 8 2 , = 17 17 Let X be a set containing 10 elements and P(X) be its power set. If A and B are picked up at random from P(X), with replacement, then the probability that A and B have equal number of elements, is : (1) Ans. Sol. 8 2 , (4*) – 17 17 20 (210 – 1) 2 20 (2) C10 210 (3) (210 – 1) 210 20 (4*) C10 2 20 (4) Total number of subsubsets of set X = 210 = 1024 number of subsets with one element = 10C1 Number of subsets with two elements = 10C2 : : Number of subsets with 10 elements = 10C10 A & B are taken from P(X) from 210 subsets so total ways = 210,210 Number of ways such that A and B have equal number of elements = (10C0)2 + (10C1)2 + (10C2)2 + ...... + (10C10) 2 = 20C10 20 Probability = C10 10 2 .210 Page || 25 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 9. The distance, from the origin, of the normal to the curve, x = 2 cos t + 2t sin t, y = 2 sin t – 2t cos t at t = , 4 is : Ans. Sol. (1) 4 (3) (2) 2 (3*) 2 (4) 2 2 dx = – 2sin t + 2sin t + 2t cos t = 2t cost dt dy = 2cos t – 2cos t + 2 t sin t = 2t sin t dt dy = tan t dx so slope of normal = – m| t 4 1 tan t =–1 equation of normal a + t = y– 2 + 2 2 = – 1 (x – 4 2 – 2 2) x+y–2 2 =0 distance of normal form –2 3 = 10. Ans. Sol. 1 1 =2 0 – 1 If A = , then which one of the following statements is not correct ? 1 0 (1) A3 – = A(A – ) (2) A3 + = A(A3 – ) (3*) A2 + = A(A2 – ) (3) (4) A4 – = A2 + 0 – 1 0 – 1 – 1 0 A2 = = =– 1 0 1 0 0 – 1 A3 = –A A4 = – A2 = A5 = A Now (1) A3 – = – A – A(A – ) = A2 – A = – – A (2) A3 + = – A + A(A3 – ) = A(–A –) = – A2 – A = – A (3) A2 + = – A( + ) = –2A A2 + A(A2 – ) (4) A4 – = – = 0 A2 + = – + = 0 Page || 26 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 11. Ans. Sol. 12. The contrapositive of the statement "If it is raining, then I will not come", is : (1) If will come, then it is raining (2) If will not come, then it is not raining (3) If will not come, then it is raining (4*) If will come, then it is not raining (4) Let p : It is raining q : I will not come contrapositive of p q is ~ q ~ p If I will come then if is not raining Let a and b be two unit vectors such that | a + b | = 3 . If c = a + 2 b + 3( a × b ), then 2| c | is equal to: (1*) (2) 55 Ans. (1) Sol. |a +b|= (3) 51 43 (4) 37 3 | a + b |2 = 3 1 + 1 + 2.1.1 cos = 3 cos = = 1 2 3 ....... (1) | a + b |2 = | a |2 | b |2 – | a . b |2 1 |a+b| = 1– 2 2 2 3 | a + b |2 = 2 | c | = | a + 2 b + 3( a × b )|2 = ( a + 2 b + 3| a × b |). ( a + 2 b + 3( a × b )) = | a |2 + 4 a . b + 9| a × b |2 + 4| b |2 1 3 = 1 + 4 + 4 + 9 2 4 =7+ |c |= 27 55 = 4 4 55 2| c | = 2 55 Page || 27 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 13. An ellipse passes through the foci of the hyperbola, 9x2 – 4y2 = 36 and its major and minor axes lie along the transverse and conjugate axes of the hyperbola respectively. if the product of eccentricities of the two conics is 1 , then which of the following points does not lie on the ellipse ? 2 13 (1) 2 , 6 Ans. (3) Sol. 1 3 (3) 2 13, 2 (2) ( 13 , 0) 39 (4) 2 , 3 x2 y2 – 1 4 9 focii are 13,0 and – 13 ,0 13 2 eccentricity of hyperbola is eH = Let equation ellipse is x2 a2 y2 b2 1 1 eccentricity of ellipse is eE = e2E = 1 – 1 b2 =1– 2 13 a Ellipse passes through ( 13 ,0) Equation of ellipse b = a 13 a2 13 b2 a2 12 13 ....(1) a2 = 13 =1 b= 12 x2 y2 + =1 13 12 13 39 , 6 and , 3 which is passes through ( 13 ,0) , 2 2 14. Let the tangents drawn to the circle, x2 + y2 = 16 from the point P(0, h) meet the x-axis at points A and B. If the area of APB is minimum, then h is equal to : (1) 4 2 (2) 4 3 (3) 3 2 Ans. (1) Sol. Equation of tangent from (0, h) to the circle is y – h = m (x – 0) y = mx + h touch the circle h2 y = ± 16 – 1 x + h h 1 m2 = 4 h = 4 1 m2 Area of PAB is = = 8h 1 (h) 2 2 h – 16 (4) 3 3 = 4h2 h2 – 16 h 2 h2 – 16(4h) – 2h2 . 2 2 2h d h – 16 = 2 2 dh h – 16 h – 16 =0 h = 4 2 Page || 28 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 15. The largest value of r for which the region represented by the set { C/| – 4 –i| r} is contained in the region represented by the set {z C/ |z –1| |z+i|}, is equal to : (1) Ans. Sol. 3 2 2 Ans. Sol. (2) (3) 2 2 17 (4) 5 2 2 (4) |– 4 – i| r circle centre (4, 1) radius = r |z – 1| |z + i| straight line y = –x maximum r = 16. MATHS 4 1 5 1 1 2 5 2 2 8 The points 0, , (1, 3) and (82, 30) : 3 (1) form an acute angled triangle. (3) form an obtuse angled triangle (2) 2 AB = 3 (1 – 0)2 3 – 8 BC = 82 – 12 30 – 3 2 CA = 82 – 0 2 30 – 8 (2*) lie on a straight line (4) form a right angled triangle. 10 3 = 27 10 2 3 82 10 3 Clearly AB + BC = CA A,B,C are collinear 30 17. The value of (r 2)(r – 3) is equal to : r 16 Ans. (1) 7775 (4) (2) 7785 30 Sol. Given = (r 2 30 – r – 6) = r 16 (r r 1 (3) 7770 (4) 7780 15 2 – r – 6) – (r 2 – r – 6) r 1 15 30 2 15 2 30 r – r – r – r = – 6(30 –15) r 1 r 1 r 1 r 1 = 8215 – 345 - 90 = 7780 Page || 29 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 18. Ans. Sol. If the points (1, 1, ) and (–3, 0, 1) are equidistant from the plane, 3x + 4y – 12z + 13 = 0, then satisfies the equation : (1) 3x2 – 10x + 21 = 0 (2) 3x2 + 10x – 13 = 0 (3) 3x2 – 10x + 7 = 0 (4) 3x2 + 10x + 7 = 0 (3) |3 + 4 – 12 + 13| = |–9 + 0 – 12 + 13| |20 – 12| = 8 12– 20 = ± 8 12= 20 ± 8 = 1, 7 3 7 3 3x2 – 10x + 7 = 0 = 1 or = 19. Ans. Sol. MATHS a = 2+ b (1) (45º, 75º) (3) In a ABC, a 2 3 b 1 tan 7 7 x2 – 1 x + =0 3 3 3 and C = 60º. Then the ordered pair (A, B) is equal to : (2) (75º, 45º) (3) (105º, 15º) ab 3 3 = a–b 3 1 (4) (15º, 105º) 3 1 A–B a–b C cot = cot 30º = 1 2 ab 3 2 A–B = 45 2 A + B = 120 A = 105º, B = 15º x 1 1 20. The least value of the product xyz for which the determinant 1 y 1 is non-negative is : 1 1 z (1) – 8 Ans. (1) (2) –1 (3) –2 2 (4) –16 2 x 1 1 Sol. 1 y 1 0 1 1 z xyz + 2 – y – x – z 0 xyz + 2 x + y + z 3 (xyz)1/3 put (xyz)1/3 = t t3 – 3t + 2 0 (t – 1)(t2 + t – 2) 0 (t – 1)2(t + 2) 0 t –2 (xyz)1/3 – 2 xyz – 8 Page || 30 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 21. x –1 y 1 z , ( –1) and x + y + z + 1= 0 = 2x – y +z + 3 is –1 1 If the shortest distance between the lines 1 3 (1) Ans. Sol. , then a value of is : 32 19 (2) 19 32 (3) – 16 19 (4) – 19 16 (1) Any plane x + y + z (2x – y + z + 3) = 0 (2+ 1)x + (1 – )y + (1 + )z + 3+ 1 = 0 parallel to given line if (2+ 1) – 1(1 – ) + 1.(1 + ) = 0 = – 2 2 1 ....(1) by (1) 2 1 – (1 – ) 0 3 1 Also 22. Ans. Sol. 2 1 = 0, – 2 (1 – ) (1 ) 32 102 2 1 3 = 0, or = 32 19 Let the sum of the first three terms of an A.P. be 39 and the sum of its last four terms be 178. If the first term of this A.P. is 10, then the median of the A.P. is : (1) 29.5 (2) 26.5 (3) 28 (4) 31 (1) 10 + (10 + d) + (10 + 2d) = 39 d=3 tn = 10 + (n – 1)3 = 3n + 7 Also (3n + 7) + (3n – 3 + 7) + (3n – 9 + 7) = 178 n = 14 23. 2 median= t 7 t 8 28 31 = 29.5 2 2 Let L be the line passing through the point P(1, 2) such that its intercepted segment between the co-ordinate axes is bisected at P. If L1 is line perpendicular to L and passing through the point (–2, 1), then the point of intersection of L and L1 is 4 12 (1*) , 5 5 3 23 (2) , 5 10 3 17 (3) , 10 5 11 29 (4) , 20 10 Ans. (1) Sol. Line L is 2x + y = 4 Line L1 is x – 2y = – 4 4 12 intersection point is , 5 5 Page || 31 MATHS JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 x 24. For x > 0, let f(x) = 1 log t 1 t dt . Then f(x) + f x is equal to 1 (1) 1 log x 2 4 (2) 1 (log x )2 4 (3) logx (4*) 1 (log x )2 2 Ans. (4) Sol. 1 f(x) + f = x x 1 (log x)2 logt dt = 2 t If y + 3x = 0 is the equation of a chord of the circle, x2 + y2 – 30x = 0, then the equation of the circle with this chord as diameter is (1) x2 + y2 – 3x – 9y = 0 (2) x2 + y2 + 3x + 9y = 0 2 2 (3*) x + y – 3x + 9y = 0 (4) x2 + y2 + 3x – 9y = 0 Ans. (3) Sol. x2 + y2 – 30x + (y + 3x) = 0 25. 3 – 30 ,– centre – 2 2 centre lies on y + 3x = 0 = 9 circles is x2 + y2 – 3x + 9y = 0 26. A factor is operating in two shifts, day and night, with 70 and 30 workers respectively. If per day mean wage of the day shift workers is Rs. 54 and per day mean wage of all the worker is Rs. 60, then per day mean wage of the night shift workers (in Rs.) is (1) 75 (2) 69 (3) 66 (4) 74 Ans. (4) Sol. 70x 30 y = 60 3y = 600 – 7x 100 27. The integral (x 1) 3y = 600 – 378 (x = 54) y= 222 = 74 3 dx 3/4 ( x – 2 )5 / 4 is equal to 1 1 x 1 4 (1) 4 C x – 2 4 x 1 4 (2*) – C 3x –2 1 4 x – 2 4 (3) – C 3 x 1 1 x – 24 (4) 4 C x 1 Ans. (2) Sol. = dx x–2 ( x 1) 2 x 1 dt 3t 5/4 = 5/4 –4 3 t1 / 4 1 dt x–2 dx =t 2 3 ( x 1) x 1 1 4 x 1 4 = – +C 3x –2 Page || 32 JEE (MAIN) ONLINE EXAMINATION 2015 | DATE:10-04-2015 28. MATHS If 2 + 3i is one of the roots of the equation 2x3 – 9x2 + kx – 13 = 0, k R, then the real root of this equation (1) exists and is equal to 1 (3*) exists and is equal to (2) exists and is equal to – 1 2 1 2 (4) does not exist Ans. (3) Sol. 2 + 3i + 2 – 3i + = = 29. 9 2 9 1 –4= 2 2 2x If f(x) = 2tan–1x + sin–1 1 x2 (1) 2 , x > 1, then f(5) is equal to 65 (2) tan–1 156 (3) 4tan–1(5) (4*) Ans. (4) Sol. 2tan–1x + sin–1sin(2tan–1x) 2tan–1x + – 2tan–1x = If the coefficients of the three successive terms in the binomial expansion of (1 + x)n are in the ratio 1 : 7 : 42, then the first of these terms in the expansion is (1) 6th (2) 7th (3) 8th (4) 9th Ans. (2) n Sol. Cr – 1: nCr : nCr + 1 30. r 1 n–r 1 7 8r = n + 1 r 1 1 = 6 n–r 7r = n – 6 r=7 Page || 33 10TH MAY 2015
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