148 The Recycling Exchange and Nanotechnology : Towards a Zero Waste Economy BRADLEY R. FITCH, CHRISTOPHER J. BUNTEL, YIYANG (JENNY) WANG, STEVEN K. HAU and TIMOTHY M. LONDERGAN Intellectual Ventures 3150 139th Ave SE, Bellevue, WA 98005 E-mail:[email protected] Abstract The current recycling market is highly disaggregated, with thousands of players and transactional middlemen, leading to significant inefficiencies. Growing regulatory and consumer pressures to ensure that products are disposed of and recycled responsibly have led to the need to develop better approaches for efficient recycling. One such approach, termed a Recycling Exchange, involves a centralized platform which can serve as an independent verifier of recyclable and recycled materials. Additionally, it serves as a data consolidator and financial engine that incentivizes producers and consumers to close the loop on the recycling process. In this approach, nanomaterial tags are embedded in the products, allowing them to be easily tracked within the platform. These nano materials can be tracked from the beginning to the end of a product’s useful life, thus enabling disparate stakeholders to realize value from products even after they have been discarded. Coupling nanotechnology with a Recycling Exchange concept can help catalyze the shift to a zero waste economy. Keywords : nanotechnology, tagging and tracking, recycling exchange platform, zero waste economy, recycling inefficiency. 1. Introduction R. Buckminster Fuller once said, “Pollution is nothing but the resources we are not harvesting. We allow them to disperse because we've been ignorant of their value.” With increasing levels of global consumption straining a finite supply of resources, 149 Fuller’s sentiment has never been more important. In addition, in view of limited landfill space and increasing regulatory and consumer pressure for extended producer responsibility, there is a growing need to track materials throughout product lifecycles and ensure that products are disposed of and recycled responsibly. Not only is proper disposal beneficial for the environment, it also ensures that the thousands of workers in scrap yards around the world are not exposed to potentially hazardous materials. Waste has value. In 2012, the US alone will generate more than 250 million tons of municipal solid waste, the materials content of which is estimated to be around 136 million tons. This waste ends up in the already limited landfill space, thereby discarding the intrinsic energy value and material content of the recyclable fraction, the value of which has been estimated at US$60 billion1,2,3. Recycling and reuse can decrease the amount of material sent to landfills and can also increase raw material supply. However, few mechanisms and methods currently exist to capture a product’s intrinsic end-of-life value. 1.1. Plastics Plastics are involved in nearly every aspect of daily life, providing myriad benefits, and are ubiquitous in consumer and industrial products. However, plastics also account for a large portion of the solid waste stream: 10% by weight and 26% by volume4. Since 1950, global consumption of plastic products has experienced an annual growth rate of 9%, increasing to over 280 million metric tonnes in 20115. Of this volume, about two-thirds are used in packaging and other non-durable goods to be disposed of after a single use. Assuming a (relatively high) recycling rate of 20%, this would yield about 150 million tonnes of plastic that ends up in the landfill every year. 150 1.2. End-of-Life Pressures Because plastics do not biodegrade and can remain in the environment for thousands of years, manufacturers face increasing pressure to ensure responsible disposal and recycling of their products at end-of-life. One such pressure arises from government regulation requiring certain industries to prevent improper disposal of their products. For example, the EU has established policy directives related to the end-of-life of vehicles (ELV) and waste electrical and electronic equipment (WEEE). Pressure can also come in the form of vendor-supplier relationships, as some players can have a major impact on their supply chain. For example, Walmart, a company which has implemented a sustainability goal of zero waste and has significant influence in the supply chain, has required vendors to redesign and reduce the amount of packaging that goes into their products6. Additional pressure can also come from consumers, who are becoming increasingly environmentally conscious and can influence manufacturers by demanding responsible practices or by basing purchasing decisions on a product’s perceived “greenness.” Consumer power in this area has been enhanced by the increased availability of information regarding “green” products, companies, practices, and lifestyles due to the growth of online and mobile information and market access. 2. Challenges in the Current Ecosystem 2.1. Manufacturers The primary challenge for manufacturers responding to these pressures is the inability to track products once they are purchased by the end-user. Because it is difficult to distinguish one type of plastic from another when they are found together in an assortment of mixed-waste plastic, the source of the polymer or manufacturer of the recycled product is currently impossible to track. During the sorting and separation process, plastics are washed and ground to 151 small pieces, thereby eliminating any identifying physical markings. Manufacturers interested in the details of the end-of-life of their products are therefore unable to verify precisely how much of their product is recycled or landfilled. 2.3. Consumers Consumers are an integral part of the end-of-life of products. While municipalities and local governments can facilitate recycling and landfilling alternatives, it is ultimately up to the consumer to make the decision to recycle, landfill, or illegally dispose of discarded products. Because behavioral changes can be difficult to effect, the sudden availability of a variety of recycling options does not guarantee that items will be properly sorted and recycled. For example, requiring that recyclables be clean and separated into glass, paper, plastic, etc., may increase the value of the recyclables but can actually reduce recycling efficacy because cleaning and separating materials takes additional time and effort, with little to no added benefit to the end-user. Recycling rates increase when single-stream recycling (or commingling) is allowed, simply because it is more convenient and readily understood by end-users. 2.2. Recycling Industry The recycling industry is highly fragmented, and there is little transparency in the quality and price of recyclables. It is a highly disaggregated marketplace, with thousands of players and transactional middlemen, leading to significant inefficiencies. For recyclable buyers, quality and price can be inconsistent from shipment to shipment. Sellers, meanwhile, carry the liability for their shipments. A buyer who receives a shipment and determines that the quality does not match the seller’s description may choose not to pay, with the seller having to bear the cost of returning the shipment. This lack of information and transparency in the recycling industry drives up risk and the cost of doing business. 152 3. Nanotechnology and Recycling Nanotechnology, often referred to as “nanotech”, has been a topic of intense activity in the scientific community over the past few decades. Nanotechnology is generally described as the manipulation of matter on the atomic and molecular scale, ranging from 1 to 100 nanometers7. Research efforts to manipulate and control matter on these extremely small scales have led to the discovery of unique optical, mechanical, electrical, magnetic, and other properties that are not typically present in bulk matter. Electronics, medicine, energy storage and production, biomaterials, catalysts, and cosmetics are among the many potential applications on which nanotechnology can have an impact. The continued growth and interest in nanotechnology and nanoscience has driven efforts to discover an increasing number of applications relevant to improving the quality of life for humankind. Many of the current solid waste and recyclable sorting and separation methods are tedious and can often be expensive, leading to inefficiencies. Even methods to improve these inefficiencies by tagging and tracking waste and recyclables with tags, such as RFIDs and barcodes, are often insufficient, as the tags may be unintentionally removed during the product’s lifetime or difficult to authenticate and track using standard tag reading technologies. Nanotechnology affords new opportunities to interact with and gain insight into the products and materials with which people interact. One novel application is the capability to tag and track materials from manufacture to end-of-life. Nanoscale materials and structures can be utilized as “tags” and can be directly incorporated into or onto the product during the manufacturing process. The small size of the materials and structures renders them invisible to the naked eye without altering the “macro” properties of the system. The nanoscale material and structures can be robust and can be used to “track” a material through its end-of-life. 153 3.2. Exemplary Uses of Nanotechnology for Recyclable Tagging and Tracking Nanomaterials and nanostructures may be ideal technologies for use in the tagging and tracking of products throughout their lifecycles. Such nanomaterials and nanostructures have been described in previous publications, including, for example, U.S. Patent Publication No. 2011/0043331 A18 and U.S. Patent No. 8,227,1799. In the technology described by Pradeep and Sajanlal, inorganic or metal nanomaterialscan be tuned by changing the size and shape of the nanomaterial in order to obtain unique Raman, fluorescence, and infrared optical properties. Incorporating additional chemical molecules/ions/species onto the nanomaterial surface can further improve these properties. Due to their unique optical signatures and small size, these nanomaterials can easily act as tags to track a product throughout its lifecycle. Hong, meanwhile, describes methods to utilize nanomaterials, such as carbon nanotubes and nanowires, to create multilayered nanostructures and patterns. These can then be used to create unique property signatures for tagging and tracking applications. These nanomaterials and nanostructures can be added into or onto plastics, electronics, and other consumer items as nano-sized physical tags with unique property signatures. The nano-sized tag cannot be easily removed and can be interrogated using various optical, electronic, and magnetic detection methods at any point during the lifecycle of the tagged product for authentication in order to allow easier tracking. Since such tags can be tuned to have a unique property signature, they can be used by chemical and product manufacturers to uniquely identify and track their products throughout their lifecycles. Products entering the waste stream at their end-of-life can be effectively separated and sorted by the different identifying tags used by each chemical and product manufacturer and can then 154 be sent to the appropriate chemical and product manufacturer for recycling and reuse. This ready identification process will minimize and reduce the amount of potential recoverable and recyclable waste ending up in landfills. In addition, the use of such nano-sized tags will provide chemical and product manufacturers with documentable evidence that their products are not disposed of in landfills; this will be especially important as more stringent governmental regulations relating to electronic waste dumping are enforced. The potential impact of nanotechnology on improving quality of life through applications in health, energy, and other areas of sustainability is of on-going interest in the research community. However, as with any new technology, there is considerable debate among the scientific community regarding the future implications of nanotechnology and nanomaterials on the environment and on human health. Accordingly, concerns have been raised as to the necessity and appropriate level of government regulation of nanotechnology. 4. Infrastructure 4.1. The Recycling Exchange While nanotechnology can enable plastics to be tagged and tracked, further steps must be taken in order to address the challenges outlined above. Since materials retain value even after disposal, identifying them at the end of their useful life can benefit all stakeholders in the product’s lifecycle. One means of capturing this value is with a Recycling Exchange, which acts as an end-oflife trading platform for recycled materials. Such a platform would also enable other secondary markets relating to recycling, such as insurance, shipping, logistics, sustainability rankings, and incentive platforms. The Recycling Exchange can be a technology and data provider for all aspects related to recycling. It can serve as an 155 independent verifier of recyclable and recycled materials, as well as a data consolidator and financial engine that incentivizes producers and consumers to close the loop on recyclables. In such a trading scheme, materials are assigned credits, the value of which can be based on a number of variables, such as material or commodity value, intrinsic energy value, whether and how many times the material has previously been recycled, and carbon value (accounting for carbon avoidance and possibly linked with carbon market platforms). Credits are realized upon disposal and can be bought, sold, and traded, just like any tradable commodity. 4.2. Lifecycle of a Pellet An example of how the Recycling Exchange could work during the lifecycle of a product is depicted in Figure1. In this example, the life cycle of a polyethylene terephthalate (PET) pellet is matched against the stages of the Recycling Exchange, which serves as a platform that collects, tracks, and verifies whether the product ends up in the recycling stream. Fig. 1: Lifecycle of a PET pellet. 156 The first stage in the PET pellet lifecycle is the removal of oil from an underground reserve or the production of hydrocarbons from a bio-based source. The chemicals are then sent to a materials manufacturer, who forms pellets by refining the virgin raw chemicals and materials and producing them to size (pellets, flakes, etc.). Nanotechnology-based tagging and tracking technologies can be embedded into the raw plastic materials during this process. The specific details on the tags used for the pellets are then sent to the Recycling Exchange and stored in a central database. Plastic pellets containing unique tags are then sent to various OEM product manufacturing companies for incorporation into various consumer products. At the OEM stage, the tagged pellets are processed using extrusion, injection molding, blow molding, and other film molding techniques to form a product, such as a plastic bottle. The OEMs can incorporate additional unique nanotechnology tagging and tracking technologies onto the product to improve the sorting and separation process further down the line in the plastics lifecycle. The specific details on the tags used in the product are again sent to the Recycling Exchange and stored in a central database. Additional tags containing information regarding material origin, material recycling locations, and promotions, incentives, and discounts available to consumers can also be incorporated into the product, with the relevant details stored in the Recycling Exchange database. Consumers who purchase the product at a retailer can scan and read the additional tags placed onto the product by the OEM using smart phones and devices, thus receiving useful information regarding the product origin, its proper end-of-life disposition, discounts and coupons from retailers or OEMs, etc. When the product is scanned, information regarding the product’s location or other attributes may be tracked and updated to the central database of the Recycling Exchange. After use, the consumer discards the product into the recycling waste stream according to the 157 instructions provided by scanning the tag. The consumer may receive a financial incentive for placing the product in the appropriate recycling container. At the next stage,a waste management company collects the recycling waste and sends it to a recycling facility where the different recyclable materials are sorted and separated according to the unique tag embedded onto or into the product. Tags that were embedded into or onto the product may be authenticated and separated out and binned for a subsequent recycling step. This information can be sent to the Recycling Exchange to verify and match the information on the database regarding the product. In this manner, the unique tags can allow each manufacturer to confirm the quantity of their products that ends up in the recycling process. The pre-sorted tagged products can then be cleaned, crushed, and flaked. For certain plastics, the flaked material may be chemically broken down and recovered. These materials can be sent back the materials manufacturer or OEM to be reused into the same or new products. 5. Benefits for All Stakeholders Nanotechnology offers novel solutions to facilitate recycling by differentiating otherwise fungible materials and making end-oflife transactions more efficient. New nanoscale materials represent an ideal approach because they do not alter the material’s “macro” properties, are not visible to the naked eye, and can be incorporated as tags by the manufacturer, allowing them to be used to track materials. The Recycling Exchange can be a platform through which nanomaterials can be tracked at the end of a product’s useful life, thus enabling disparate stakeholders to realize value from materials even after they have been discarded. The benefits of such an approach include: 1. Reduction in zero-value dumping of used materials. 158 2. Mitigation of extended producer responsibility costs for manufacturers at a product’s end-of-life. 3. Higher value in recycledapplications through verification of a material’s history. 4. Development of new and higher value uses of end-of-life materials. 5. Improved design for environmentally friendly products. 6. Higher brand recognition/customer loyalty for participating companies. 7. More transparent and efficient markets. 8. Less waste and increased recycling, thereby benefitting the environment and society. Big things have nano-sized beginnings. Coupling nanomaterials with a Recycling Exchange concept can help catalyze the shift to a zero waste economy. References 1. Herndon, Andrew. Trash Worth $40 Billion When Saved From Landfill. Retrieved Feb 28, 2013, from http://www.business week.com/news/2012-04-03/trash-saved-by-waste-managementworth-up-to-40-billion. 2. Wright, Shawn. (2012) Study shows landfilled resources worth billions. Waste & Recycling News, 18, 9, 1-27. 3. Municipal Solid Waste Generation, Recycling, and Disposal in the United States Tables and Figures for 2010 (US Environmental Protection Agency), 2011. Retrieved February 28, 2013, from http://www.epa.gov/wastes/nonhaz/municipal/pubs/2010_MSW_Tabl es_and_Figures_508.pdf. 4. Kopeliovich, Dmitri. (2013) Plastics Recycling. Retrieved February 28, from http://www.substech.com/dokuwiki/doku.php?id=plastics_ recycling. 5. PlasticsEurope (Association of Plastics Manufacturers), 2012. Plastics – The Facts 2012. Retrieved February 28, 2013, from http://www. plasticseurope.org. 159 6. Walmart Global Responsibility (2013). Retrieved February 28, 2013, from http://corporate.walmart.com/global-responsibility/environmentsustainability/packaging. 7. What is Nanotechnology? (2013). Retrieved February 26, 2013, from http://www.nano.gov/nanotech-101/what/definition. 8. Pradeep, T.; Sajanlal, P. R. (2011) U.S. Patent Publication No. 2011/0043331 A1. 9. Hong, S.; Park, S. Y.; Namgung, S. (2012) U.S. Patent No. 8,227,179.
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